Mid–late Holocene monsoon climate retrieved from seasonal Sr/Ca and δO records of Porites lutea corals at Leizhou Peninsula, northern coast of South China Sea

South China Sea (SCS) is a major moisture source region, providing summer monsoon rainfall throughout Mainland China, which accounts for more than 80% total precipitation in the region. We report seasonal to monthly resolution Sr/Ca and δ¹⁸O data for five Holocene and one modern Porites corals, each covering a growth history of 9–13 years. The results reveal a general decreasing trend in sea surface temperature (SST) in the SCS from 6800 to 1500 years ago, despite shorter climatic cycles. Compared with the mean Sr/Ca–SST in the 1990s (24.8 °C), 10-year mean Sr/Ca–SSTs were 0.9–0.5 °C higher between 6.8 and 5.0 thousand years before present (ky BP), dropped to the present level by 2.5 ky BP, and reached a low of 22.6 °C (2.2 °C lower) by 1.5 ky BP. The summer Sr/Ca–SST maxima, which are more reliable due to faster summer-time growth rates and higher sampling resolution, follow the same trend, i.e. being 1–2 °C higher between 6.8 and 5.0 ky BP, dropping to the present level by 2.5 ky BP, and reaching a low of 28.7 °C (0.7 °C lower) by 1.5 ky BP. Such a decline in SST is accompanied by a similar decrease in the amount of monsoon moisture transported out of South China Sea, resulting in a general decrease in the seawater δ¹⁸O values, reflected by offsets of mean δ¹⁸O relative to that in the 1990s. This observation is consistent with general weakening of the East Asian summer monsoon since early Holocene, in response to a continuous decline in solar radiation, which was also found in pollen, lake-level and loess/paleosol records throughout Mainland China. The climatic conditions 2.5 and 1.5 ky ago were also recorded in Chinese history. In contrast with the general cooling trend of the monsoon climate in East Asia, SST increased dramatically in recent time, with that in the 1990s being 2.2 °C warmer than that 1.5 ky ago. This clearly indicates that the increase in the concentration of anthropogenic greenhouse gases played a dominant role in recent global warming, which reversed the natural climatic trend in East Asian monsoon regime.     

The 2003 November 14 occultation by Titan of TYC 1343-1865-1: II. Analysis of light curves

We observed a stellar occultation by Titan on 2003 November 14 from La Palma Observatory using ULTRACAM with three Sloan filters: u^′, g^′, and i^′ (358, 487, and 758 nm, respectively). The occultation probed latitudes 2° S and 1° N during immersion and emersion, respectively. A prominent central flash was present in only the i^′ filter, indicating wavelength-dependent atmospheric extinction. We inverted the light curves to obtain six lower-limit temperature profiles between 335 and 485 km (0.04 and 0.003 mb) altitude. The i^′ profiles agreed with the temperature measured by the Huygens Atmospheric Structure Instrument [Fulchignoni, M., and 43 colleagues, 2005. Nature 438, 785–791] above 415 km (0.01 mb). The profiles obtained from different wavelength filters systematically diverge as altitude decreases, which implies significant extinction in the light curves. Applying an extinction model [Elliot, J.L., Young, L.A., 1992. Astron. J. 103, 991–1015] gave the altitudes of line of sight optical depth equal to unity: 396±7 and 401±20 km (u^′ immersion and emersion); 354±7 and 387±7 km (g^′ immersion and emersion); and 336±5 and 318±4 km (i^′ immersion and emersion). Further analysis showed that the optical depth follows a power law in wavelength with index 1.3±0.2. We present a new method for determining temperature from scintillation spikes in the occulting body's atmosphere. Temperatures derived with this method are equal to or warmer than those measured by the Huygens Atmospheric Structure Instrument. Using the highly structured, three-peaked central flash, we confirmed the shape of Titan's middle atmosphere using a model originally derived for a previous Titan occultation [Hubbard, W.B., and 45 colleagues, 1993. Astron. Astrophys. 269, 541–563].     

Jarosite stability on Mars

Jarosite, a potassium (sodium) iron sulphate hydrated mineral, has recently been identified on the martian surface by the Opportunity rover. Using recent thermochemical data [Drouet and Navrotsky, 2003, Geochim. Cosmochim. Acta 67, 2063-2076; Forray et al., 2005, Geochim. Cosmochim. Acta, in press], we calculate the equilibrium decomposition curve of jarosite and show that it is thermodynamically stable under most present martian pressures and temperatures. Its stability makes jarosite potentially useful to retain textural, chemical, and isotopic evidence of past history, including possible biological activity, on Mars.     

Climate changes and recent glacier behaviour in the Chilean Lake District

Atmospheric temperatures measured at the Chilean Lake District (38°–42°S) showed contrasting trends during the second half of the 20th century. The surface cooling detected at several meteorological stations ranged from − 0.014 to − 0.021 °C a^− 1, whilst upper troposphere (850–300 gpm) records at radiosonde of Puerto Montt (41°26′S/73°07′W) revealed warming between 0.019 and 0.031 °C a^− 1. Regional rainfall data collected from 1961 to 2000 showed the overall decrease with a maximum rate of − 15 mm a^− 2 at Valdivia st. (39°38′S/73°05′W). These ongoing climatic changes, especially the precipitation reduction, seem to be related to El Niño–Southern Oscillation (ENSO) phenomena which has been more frequent after 1976. Glaciers within the Chilean Lake District have significantly retreated during recent decades, in an apparent out-of-phase response to the regional surface cooling. Moreover, very little is known about upper troposphere changes and how they can enhance the glacier responses. In order to analyse their behaviour in the context of the observed climate changes, Casa Pangue glacier (41°08′S/71°52′W) has been selected and studied by comparing Digital Elevation Models (DEMs) computed at three different dates throughout the last four decades. This approach allowed the determination of ice elevation changes between 1961 and 1998, yielding a mean thinning rate of − 2.3 ± 0.6 m a^− 1. Strikingly, when ice thinning is computed for the period between 1981 and 1998, the resulting rate is 50% higher (− 3.6 ± 0.6 m a^− 1). This enhanced trend and the related area loss and frontal retreat suggests that Casa Pangue might currently be suffering negative mass balances in response to the upper troposphere warming and decreased precipitation of the last 25–30 yr, as well as debris cover would not prevent the glacier from a fast reaction to climate forcing. Most of recent glaciological studies regarding Andean glaciers have concentrated on low altitude changes, namely frontal variations, however, in order to better understand the regional glacier changes, new data are necessary, especially from the accumulation areas.     

High-resolution bispectrum speckle interferometry and two-dimensional radiative transfer modeling of the Red Rectangle

We present the first diffraction-limited K-band image of the Red Rectangle with 76 mas resolution, an H-band image with 75 mas resolution, and an RG 715 filter image ( 800 nm wavelength) with 78 mas resolution (corresponding to 25 AU for a distance of 330 pc). The H and K images were reconstructed from 6 m telescope speckle data and the RG 715 image from 2.2 m telescope data using the speckle masking bispectrum method. At all wavelengths the images show a compact, highly symmetric bipolar nebula, suggesting a toroidal density distribution of the circumstellar material. No direct light from the central binary can be seen as it is obscured by a dust disk or circumbinary torus. Our first high-resolution H−K color image of the nebula shows a broad red plateau of H−K≈ 2^m in the bright inner regions.The optical and near-infrared images and the available photometric continuum observations in a wide range of ultraviolet to centimeter wavelengths enabled us to model the Red Rectangle in detail using a two-dimensional radiative transfer code. Our model matches both the high-resolution images and the spectral energy distribution of this object very well, making the following picture much more certain. The central close binary system with a total luminosity of 3000 L is embedded in a very dense, compact circumbinary torus which has an average number density n_H ≈5×10¹² cm⁻³, an outer radius of the dense inner region of R≈30 AU (91 mas), and a ρ∝r⁻² density distribution. The full opening angle of the bipolar outflow cavities in our model is 70°. By comparing the observed and theoretical images, we derived an inclination angle of the torus to the line of sight of 7°±1°.The radiative transfer calculations show that the dust properties in the Red Rectangle are spatially inhomogeneous. The modeling confirms that the idea of large grains in the long-lived disk around the Red Rectangle (Jura et al., 1997 [ApJ, 474, 741]) is quantitatively consistent with the observations. In our models, unusually large, approximately millimeter-sized grains dominate the emission of the compact, massive torus. Models with smaller average grain sizes can possibly be found in future studies, for instance, if it turns out that the radio spectrum is not mainly caused by continuum dust emission. Therefore, the large grains suggested by our models require further confirmation by both new observations and radiative transfer calculations. Assuming a dust-to-gas ratio ρ_d/ρ_g of 0.005, the dense torus mass is 0.25 M. The model gives a lower limit of 0.0018 M, for the mass of the large particles, which produce a gray extinction of A≈ 28^m, towards the center. A much smaller mass of submicron-sized dust grains is presumably located in the polar outflow cavities, their conical surface layers, and in the outer low-density parts of the torus (where ρ∝r⁻⁴, in the region of 30 AUr 2000 AU corresponding to 0.^′′09–6^′′).     

Computation of the space and time evolution of equilibrium-line altitudes on Andean glaciers (10°N–55°S)

A previous study of Fox [Fox, A.N. 1993. Snowline altitude and climate at present and during the Last Pleistocene Glacial Maximum in the Central Andes (5°–28°S). Ph.D. Thesis. Cornell University.] showed that for a fixed 0 °C isotherm altitude, the equilibrium-line altitude (ELA) of the Peruvian and Bolivian glaciers from 5 to 20°S can be expressed based on a log–normal expression of local mid-annual rainfall amount (P). In order to extrapolate the function to the whole Andes (10°N to 55°S) a local 0 °C isotherm altitude is introduced. Two applications of this generalised function are presented. One concerns the space evolution of mean inter-annual ELA for three decades (1961–1990) over the whole South American continent. A high-resolution data set (grid data: 10′ for latitude/longitude) of mean monthly air surface temperature and precipitation is used. Mean annual values over the 1961–1990 period were calculated. On each grid element, the mean annual 0 °C isotherm altitude is determined from an altitudinal temperature gradient and mean annual temperature (T) at ground level. The 0 °C isotherm altitude is then associated with the annual precipitation amount to compute the ELA. Using computed ELA and the digital terrain elevation model GTOPO30, we determine the extent of the glacierised area in Andean regions under modern climatic conditions. The other application concerns the ELA time evolution on Zongo Glacier (Bolivia), where inter-annual ELA variations are computed from 1995 to 1999. For both applications, the computed values of ELA are in good agreement with those derived from glacier mass balance measurements.     

Thermosteric sea level rise for the past 50 years; comparison with tide gauges and inference on water mass contribution

In this paper we compare sea level trends observed at a few selected tide gauges of good quality records with thermosteric (i.e., due to ocean temperature change) sea level trends over 1950–1998 using different gridded ocean temperature data sets from Levitus et al. (2000) [Levitus, S., Stephens, C., Antonov, J.I., Boyer, T.P., 2000. Yearly and Year-Season Upper Ocean Temperature Anomaly Fields, 1948–1998. U.S. Gov. Printing Office, Washington, D.C. pp. 23.], Ishii et al. (2003) [Ishii, M., Kimoto, M., Kachi, M., 2003. Historical ocean subsurface temperature analysis with error estimates, Mon. Weather Rev., 131, 51–73.] and Levitus et al. (2005) [Levitus S., Antonov, J.I., Boyer, T.P., 2005. Warming of the world ocean, 1955–2003. Geophys. Res. Lett. 32, L02604. doi:10.1029/2004GL021592.]. When using the Levitus data, we observe very high thermosteric rates at sites located along the northeast coast of the US, north of 37°N. Such high rates are not observed with the Ishii data. Elsewhere, thermosteric rates agree reasonably well whatever the data set. Excluding the northeast US coastline sites north of 37°N, we compare tide gauge-based sea level trends with thermosteric trends and note that, in spite of a significant correlation, the latter are too small to explain the observed trends. After correcting for thermosteric sea level trends, residual (observed minus thermosteric) trends have an average value of 1.4 ± 0.5 mm/year, which should have an eustatic (i.e., due to ocean mass change) origin. This result supports the recent investigation by Miller and Douglas (2004) [Miller, L., Douglas, B.C., 2004. Mass and volume contributions to 20th century global sea level rise. Nature 428, 406–408.] which suggests that a dominant eustatic contribution is needed to explain the rate of sea level rise of the last decades observed by tide gauges, and shows that Cabanes et al. (2001) [Cabanes, C., Cazenave, A., Le Provost, C., 2001. Sea level rise during past 40 years determined from satellite and in situ observations. Science 294, 840–842.] arrived at an incorrect conclusion due to peculiarities in the gridded Levitus et al. (2000) [Levitus, S., Stephens, C., Antonov, J.I., and Boyer, T.P., 2000. Yearly and Year-Season Upper Ocean Temperature Anomaly Fields, 1948–1998. U.S. Gov. Printing Office, Washington, D.C. pp. 23.] data set.     

Molecular cores of the high-latitude cloud MBM 40

Towards the high-latitude cloud MBM 40, we identify 3 dense molecular cores of M0.2–0.5 M, and sizes of 0.2 pc in diameter embedded in the H I cloud of 8 M which is observed to be extended along the northeast–southwest direction. The molecular cloud is located almost perpendicularly to the H I emission. We confirm the previous result of Magnani et al. that MBM 40 is not a site for new star formations. We found a very poor correlation between the H I and the IRAS 100 μm emissions, but the CO (1–0) and 100 μm emissions show a better correlation of W_CO/I₁₀₀=1±0.2 K km s⁻¹ (MJy sr⁻¹)⁻¹. This ratio is larger by a factor of ≥5 than in dense dark clouds, which may indicate that the CO is less depleted in MBM 40 than in dense dark clouds.     

Estimation of the dissociation energy of CO+ from spectroscopic data

The potential energy curves for theX ² Σ⁺ andB ² Σ⁺ states of CO⁺ have been constructed by the Rydberg-Klein-Rees (RKR) method as modified by van der Sliceet al. The dissociation energy is estimated to be 7.70±0.19 eV by the method of curve fitting using the five parameter Hulburt-Hirschfelder’s function. The estimated value is in good agreement with the value (7.839 eV) given by Misraet al. Carefull observation of the results reveals that accurateD ₀ value for CO⁺ is 8.33 eV     

Anisotropy of Mg isotopic fractionation during evaporation and Mg self-diffusion of forsterite in vacuum

Evaporation of solid materials under low-pressure conditions could play important roles in chemical and isotopic fractionations in the early solar system. We have studied anisotropy of isotopic fractionation of ²⁶Mg and ²⁵Mg during kinetic evaporation of forsterite (Mg₂SiO₄), which is potentially a powerful tool to understand thermal histories of crystals in the early solar system. Ion-microprobe depth profiling revealed that the Mg isotopic zoning profiles of forsterite evaporated at 1500-1700 °C are notably differing along the a-, b-, and c-axes, which can be attributed to anisotropy in self-diffusion coefficient of Mg (D) and an isotopic fractionation factor for evaporation of Mg (α). The D and α were obtained from zoning profiles by applying the diffusion-controlled isotopic fractionation model of Wang et al. [1999. Evaporation of single crystal forsterite: Evaporation kinetics, magnesium isotope fractionation, and implications of mass-dependent isotopic fractionation of a diffusion-controlled reservoir. Geochim. Cosmochim. Acta 63(6), 953-966.].The D is largest and smallest along the a- and c-axes, respectively. The activation energy of 560-670 kJ/mol indicates that Mg diffusion at 1500-1700 °C occurred in the intrinsic diffusion regime.The α seems to be larger along the a- or c-axes than along the b-axis. The α along the a- or c-axes show weak temperature dependence. The α along all the crystallographic orientations is closer to unity than that expected from the kinetic theory of gases. These lines of evidence suggest that surface processes such as breaking of bonds and surface diffusion are responsible for the isotopic fractionation.     

Recent organic matter accumulation in relation to some climatic factors in ombrotrophic peat bogs near heavy metal emission sources in Finland

Accumulation of organic matter (OM) was studied in four ombrotrophic peat bogs in Finland: Harjavalta (vicinity of a Cu–Ni smelter), Outokumpu (near a closed Cu–Ni mine), Alkkia (Ni-treated site) and Hietajärvi (a pristine site). At each sampling site, two peat cores (15 × 15 × 100 cm) were taken. Age-dating of peat was determined using ²¹⁰Pb method (CRS model). The local annual temperature sum and precipitation for the past 125 years were modeled. The objective was to compare recent net accumulation rates of heavy metal polluted ombrotrophic peat bogs with those of a pristine bog, and to study the relationship between weather and net accumulation rates. Based on ²¹⁰Pb age-dating, the upper 16-cm peat layer at Harjavalta, 35 cm at Outokumpu and 25 cm at Hietajärvi represents 125 years of peat formation, yielding the following average peat accumulation rates: Harjavalta 1.3 mm year^− 1, Outokumpu 2.8 mm year^− 1 and Hietajärvi 2.0 mm year^− 1. At the Alkkia site, the Ni treatment in 1962 had completely stopped the peat accumulation. Net accumulation rates were related to precipitation at Outokumpu, Harjavalta and Hietajärvi sites. In addition, emissions released from the nearby located Cu–Ni smelter could have affected negatively net OM accumulation rate at Harjavalta site.     

The masers of E-type methanol in orion KL and SGR B2

Using a simplified model the statistical equilibrium and radiative transfer equations of E-type-CH₃OH are solved for Orion KL and SgrB2. According to our calculation results and the observation data taken by Matsakiset al. (1980) and Morimotoet al. (1985a, b), the physical conditions of both sources are estimated. In theJ ₂-J ₁ E methanol maser region of Orion KL, the density, kinetic temperature, dust temperature, and the fractional abundance are 0.8–2×10⁶ cm^–3, 150, 30–90 K, 0.8–8×10^–6. In the 4_–1-3₀ E and 5_–1-4₀ E methanol maser region of Sgr B2 the correspondance physical conditions above are 10⁴ cm³, 45, 23 K, and 7×10^–7, respectively.     

Effects of a 2 × CO2 climate on two large lake systems: Pyramid Lake, Nevada, and Yellowstone Lake, Wyoming

The possible effects of trace-gas induced climatic changes on Pyramid and Yellowstone Lakes are assessed using a model of lake temperature. The model is driven by years of hourly meteorological data obtained directly from the output of double-CO₂ experiments (2 × CO₂) conducted with a regional climate model nested in a general circulation model. The regional atmospheric model is the climate version of the National Center for Atmospheric Research/Pennsylvania State University mesoscale model, MM4.Average annual surface temperature of Pyramid Lake for the 2 × CO₂ climate is 15.5 ± 5.4°C (±1 σ), 2.8°C higher than the control. Annual overturn of the lake ceases as a result of these higher temperatures for the 2 × CO₂ climate. Evaporation increases from 1400 mm yr⁻¹ in the control to 1595 mm yr⁻¹ in the 2 × CO₂ simulation, but net water supplied to the Pyramid Lake basin increases from −6 mm yr⁻¹ in the control to +27 mm yr⁻¹ in the 2 × CO₂ simulation due to increased precipitation.For the open water periods, the average annual surface temperature of Yellowstone Lake is 13.2 ± 5.1°C for the 2 × CO₂ climate, a temperature 1.6°C higher than the control. The annual duration of ice cover on the lake is 152 days in the 2 × CO₂ simulation, a reduction of 44 days relative to the control. Warming of the lake for the 2 × CO₂ climate is mostly confined to the near-surface. Simulated spring overturn for the 2 × CO₂ climate occurs earlier in the year and fall overturn later than in the control. Evaporation increases from 544 mm yr⁻¹ to 600 mm yr⁻¹ in the 2 × CO₂ simulation, but net water supplied to the Yellowstone Lake basin increases from +373 mm yr⁻¹ in the control to +619 mm yr⁻¹ due to increased precipitation. The effects of these climatic changes suggest possible deterioration of water quality and productivity in Pyramid Lake and possible enhancement of productivity in Yellowstone Lake.     

EUV line ratios from MgVII and SiIX

Following the work of Burgess et al. (1991), the EUV line ratios from MgVII and SiIX ions have been computed using most appropriate atomic data. The density dependent line ratio R₁ = (2s2p^{3 1}D°–2s²2p^{2 1}D)/ (2s2p^{3 3}S°–2s²2p^{2 3}P₂) and R₂ = (2s2p^{3 1}p°–2s²– –2p^{2 1}D)/(2s2p^{3 3}S°–2s²2p^{2 3}P₂) for MgVII and SiIX are compared with the earlier results of Mason and Bhatia (1978) and Keenan et al. (1986). Electron densities derived using observed R₁ and R₂ ratios from skylab NRL EUV spectra of solar flares and active regions are tabulated along with the values obtained by Keenan et al. (1986).     

Spatially resolved cloud structure on Uranus: Implications of near-IR adaptive optics imaging

Seven-band near-IR adaptive optics imaging of Uranus by the Keck II telescope during 2004, with the assistance of selected Hubble Space Telescope images, provides new constraints on the uranian vertical cloud structure and CH₄ mixing ratio, after tuned deconvolutions are applied to remove significant limb darkening distortions. The most strongly absorbing bands approximately agree with the stratospheric haze model of Rages et al. [Rages, K., Pollack, J.B., Tomasko, M.G., Doose, L.R., 1991. Icarus 89, 359–376]. The next most absorbing bands suggest a CH₄ relative humidity of 50–60% above the 1.2-bar condensation level. Window channels imply effective cloud pressures at 12° S that vary from 9 to 3.5 bars, and reflectivity values that vary from 7 to 4%, as the assumed CH₄ mixing ratio varies from 0.75 to 4%. The shape of the center-to-limb radiance profile is in best agreement with the deep cloud being translucent, with relatively low optical depth, and is most consistent with low methane mixing ratios (0.75–1%) if the cloud particles are conservative. Non-conservative particles provide good fits over a wide range of mixing ratios. If C and S are enhanced by the same factor over solar mixing ratios, then the cloud pressures inferred from near-IR observations would be less than H₂S condensation pressures for methane mixing ratios of 1.3% or greater. The bright band at 45° S must be partly produced by increased particulate scattering at pressures 2 bars to be consistent with its absence in 1.9-μm images and its presence in 0.619-μm images. The reflectivity of the lower clouds declines to nearly negligible values in the northern hemisphere, where I/F observations beyond 50° N are nearly those of a clear atmosphere. The most surprising result is the general lack of scattering originating from the 1.2-bar region where methane is expected to condense. Exceptions occur for discrete features. A large and long-lived discrete feature at 34° S is associated with particulates near 700 mb and 4.5 bars. The highest discrete feature, near 26° N, reached pressures 200 mb and was eleven times brighter than the background atmosphere in K^′ images.     

Etude de la collisionN-uple du probleme desN corps soumis a un potentiel homogene de degre-k aveck>0 cas ouk=2

Rèsumé Le changement de variables simple et adapté au problème de la collision triple utilisé dans un article précédent [3] était lié étroitement à l'homogénéité de l'énergie cinétiqueT (degré 2) et du potentielU (degré-1). Nous allons généraliser ce changement de variables au cas deU homogène de degré —k (k>0) et en déduire l'étude de la collision pour ces cas, en mettant en évidence un cas exceptionnel,k=2.

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Study of theN-tuple collision on theN-body problem submitted to a homogeneous potential of degree-k in the case ofk>0 ork=2

In a preceding paper, we used a change of variables which is simple and well adapted to the problem of triple collision and which is closely linked the homogeneousness of the kinetic energyT (degree 2) and the potentialU (degree-1). We will now generalize this change of variables to the case whereU is homogeneous of degree —k(k>0), in order to carry out the study of collision in these cases, bringing out the exceptional casek=2.

     

Spiral structure of galaxies two alternatives

At present the wave theory of the spiral structure of the galaxies includes two alternative viewpoints. Two types of spiral waves—short-wave and long-wave modes—can be excited. According to Lin and Shu (1964) the short-wave modeK is responsible for the spiral structure of the galaxies and, according to Marochniket al. (1972), the long-wave mode (K ₀). In our Galaxy theK -mode corresponds to the wave with an angular rotation velocity _p =11–13 kms^–1 kps^–1 and a radial group velocity directed from the periphery to the center. TheK ₀-mode corresponds to the wave having an angular rotation velocity _p =23 ± 3 kms^–1 kps^–1 and a radial group velocity directed from the center of the Galaxy to its periphery. The theoretical and observational evidences in favour of Marochniket al.'s (1972) model are given.     

Primary production and microbial activity in the euphotic zone of Lake Baikal (Southern Basin) during late winter

Three years of regular weekly/biweekly monitoring of seasonal changes in temperature, transparency, chlorophyll a (CHL) and bacteria [erythrosine-stained microscopic counts and cultivable colony forming units (CFUs)] at the vertical profile in the South basin of Lake Baikal (51°54′195″N, 105°04′235″E, depth 800 m) were evaluated. In more detail, the structure and function of phytoplankton and the microbial loop in the euphotic layer at the same site were investigated during the late-winter–early-spring period under the ice. The depth of euphotic zone (up to 1% of surface irradiation) was 35 to 40 m. Primary production was measured three times a week with the ¹⁴C method in 2, 10, 20, 30 and 40 m. Maximum production was found in 10 m, with lower values towards the surface (light inhibition) and towards the lower layers. The total production in cells larger than 1 μm in the column (0–40 m) was 204–240 mg C d⁻¹ m⁻², 30–40% of it being in cells 1–3 μm (mostly picocyanobacteria), which represented roughly 9% of the total chlorophyll a (estimated from pigment analyses). A major part of phytoplankton biomass was formed by diatoms (Synedra acus Hust., Asterionella formosa Hass. and Stephanodiscus meyerii Genkal & Popovskaya). Total production (including extracellular, dissolved organic matter) was 235–387 mg C day⁻¹ m⁻², and the exudates were readily used by bacteria (particles 0.2–1 μm). This part amounted to 1–5% of cellular production in 2 to 20 m and 11–77% of cellular production in 20–40 m, i.e., in light-limited layers. From 0 to 30 m, chlorophyll a concentration was 0.8 to 1.3 μg l⁻¹, wherefrom it decreased rapidly to 0.1 μg l⁻¹ towards the depth of 40 m. Bacteria (DAPI-stained microscopic counts) reached 0.5–1.4×10⁶ ml⁻¹; their cell volumes measured via image analysis were small (average 0.05 μm⁻³), often not well countable when erythrosine stain was used. Bacterial biomasses were in the range of 6–21 μg C l⁻¹. Numbers of colony forming units (CFUs) on nutrient fish-agar were c. 3–4 orders lower than DAPI counts. The amounts of heterotrophic protists were low, whereby flagellates reached 6 to 87 ml⁻¹ and ciliates, 0.2–1.2 ml⁻¹ (mostly Oligotrichida). Bacterial production was measured in the same depths as primary production using ³H-thymidine (Thy) and ¹⁴C-leucine (Leu) uptake. Consistently, bacterial abundances, biomasses, thymidine and leucine production were higher by 30–50% in layers 2, 10 and 20 m compared with that in the deeper 30 and 40 m, where cellular primary production was negligible. Leucine uptake in the deeper layers was even three times lower than in the upper ones. From the comparison of primary and bacterial production, bacteria roughly use 20–40% of primary production during 24 h in the layers 2 to 20 m.     

Latitudinal UVR-PAR measurements in Argentina: extent of the ‘ozone hole’

The UVR-PAR Argentinean Monitoring Network started its operation in September 1994 recording ultraviolet (UVR) and Photosynthetic Available Radiation (PAR) at a frequency of once per minute, at four sites, throughout the entire year. Four spectroradiometers (GUV-511, Biospherical Instruments, Inc.) were installed at research centers separated by about 8–12 degrees of latitude, extending from the Subantarctic-Fueguian region to the Tropic of Capricorn. The instruments are located in populated areas ranging from 30,000 to 11 million people and with extremely different climate regimes and conditions of tropospheric pollution. Our ground-based data indicated that the irradiance increased steadily from south to north. This increase was also observed in the calculated daily doses of UV-B (280–320 nm); however, daily integrated values for UV-A (320–400 nm) and PAR (400–700 nm) were higher at mid-latitudes (Puerto Madryn, 42°47′S). A similar south-to-north increase was evident in the ratio of the energy at 305 nm and 340 nm wavelengths (with low 305/340 ratios indicating high total ozone column concentration), with low values at Ushuaia (55°01′S) and high values at Jujuy (24°10′S). However, the 305/340 ratios increased significantly over their normal spring values at two sites, Ushuaia and Puerto Madryn, for variable time periods during October-December. Our data suggest that the ozone hole was over South America extending to about 38°S for at least a week during October and about two weeks during November-December of the years of 1994 and 1995. However, it should be noted that the erythemal irradiance, in the area influenced by the ozone hole, was at all times lower than that in Buenos Aires and well below the value at Jujuy (tropical station). This study also indicates that when assessing the impact of solar UVR upon organisms, other variables such as cloud cover, solar zenith angle, day length, latitude, and atmospheric pollution should be considered in addition to total ozone column concentration.     

Late Pleistocene deep-water circulation in the subantarctic eastern Atlantic

We present three new benthic foraminiferal δ¹³C, δ¹⁸O, and total organic carbon time series from the eastern Atlantic sector of the Southern Ocean between 41°S and 47°S. The measured glacial δ¹³C values belong to the lowest hitherto reported. We demonstrate a coincidence between depleted late Holocene (LH) δ¹³C values and positions of sites relative to ocean surface productivity. A correction of +0.3 to +0.4 [‰ VPDB] for a productivity-induced depletion of Last Glacial Maximum (LGM) benthic δ¹³C values of these cores is suggested. The new data are compiled with published data from 13 sediment cores from the eastern Atlantic Ocean between 19°S and 47°S, and the regional deep and bottom water circulation is reconstructed for LH (4–0 ka) and LGM (22–16 ka) times. This extends earlier eastern Atlantic-wide synoptic reconstructions which suffered from the lack of data south of 20°S. A conceptual model of LGM deep-water circulation is discussed that, after correction of southernmost cores below the Antarctic Circumpolar Current (ACC) for a productivity-induced artifact, suggests a reduced formation of both North Atlantic Deep Water in the northern Atlantic and bottom water in the southwestern Weddell Sea. This reduction was compensated for by the formation of deep water in the zone of extended winter sea-ice coverage at the northern rim of the Weddell Sea, where air–sea gas exchange was reduced. This shift from LGM deep-water formation in the region south of the ACC to Holocene bottom water formation in the southwestern Weddell Sea, can explain lower preformed δ¹³C_DIC values of glacial circumantarctic deep water of approximately 0.3‰ to 0.4‰. Our reconstruction brings Atlantic and Southern Ocean δ¹³C and Cd/Ca data into better agreement, but is in conflict, however, with a scenario of an essentially unchanged thermohaline deep circulation on a global scale. Benthic δ¹⁸O-derived LGM bottom water temperatures, by 1.9°C and 0.3°C lower than during the LH at deepest southern and shallowest northern sites, respectively, agree with the here proposed reconstruction of deep-water circulation in the eastern South Atlantic Ocean.