P–T estimates from the Nellore schist belt (India) and evidence for superimposed metamorphic events

The Nellore schist belt (NSB) is one of the prominent schist belts of southern India. It is thrust over an unmetamorphosed Proterozoic sedimentary sequence (Cuddapah Basin) in the west and in turn is overthrust by the Eastern Ghats Granulite Terrain (EGGT) in the east. Metamorphic grade has been considered to be either greenschist to amphibolite facies or else to show high- and low-grade groups of rocks. Detailed mineralogical and P, T studies on representative rock types across the high- to low-grade groups (metapelite and metadacite from the high- and low-grade groups respectively) near Vinjamuru reveal that there are high (M1) and medium (M2) grade metamorphic events. While metapelite documents both M1 and M2 events, metadacite shows only the M2 event, thus indicating the presence of high- and medium-grade groups of rocks in the NSB. The stable mineral assemblage during the early prograde part of M1 was Qtz+St₁+Ms₁+Pl₁+Bt±Grt, which subsequently suffered high-grade metamorphic conditions (T∽715–765°C and P∽8·6–9·2 kbar) leading to the demise of St₁ and melting of Ms₁. In contrast, medium-grade metamorphism (M2) is characterized by the stable association of St₂+Qz. Quantitative geothermobarometry suggests T=520–570°C and P=6·1-6·8 kbar, and these results show good consistency with the average P, T estimates obtained from the THERMOCALC program. This metamorphic episode is probably coeval with the 900 Ma granulite facies metamorphic event in the EGGT. The superimposition of M2 over M1 probably has led to widespread retrogression of the high-grade rocks to medium grade, thereby giving the general impression of a greenschist to amphibolite facies gradation. © 1998 John Wiley & Sons, Ltd.     

High-temperature 'clockwise'P-T paths and melting in the development of regional migmatites: an example from southern Brittany, France

The Southern Brittany Migmatite Belt (SBMB), which evolved through the metamorphic peak between c. 400 Ma and c. . 370 Ma ago, consists of a heterogeneous suite of high-grade gneisses and anatectic migmatites, both metatexites and diatexites. Rare garnet-cordierite gneiss layers record evidence of an early prograde P-T path. In these rocks, growth-zoned garnet cores and a sequence of included mineral assemblages in garnet, from core to rim, of Qtz + Ilm + Ky, Pl + Ky + St + Rt + Bt and Pl + Sil + St + Rt + Bt constrain a prograde evolution during which the reactions Ilm + Ky + Qtz→ Aim + Rt, Ms + Chl→ St + Bt + Qtz + V and St + Qtz→ Grt + Sil + V were crossed. Parts of this prograde evolution are preserved as inclusion assemblages in garnet in all other rock types. In all rock types, garnet has reverse zoned rims, and garnet replacement by cordierite and/or biotite and plagioclase suggests the following reactions have occurred: Grt + Sil + Qtz→ Crd → Hc ± Ilm, Bt + Sil + Qtz → Crd ± Hc → Ilm → Kfs + V and (Na + Ca + K + Ti) + Grt → Bt + Pl + Qtz. Microstructural analysis of reaction textures in conjunction with a petrogenetic grid has enabled the construction of a tightly constrained 'clockwise' P–T path for the SBMB. The high-temperature part of the path has a steep dT/dP slope characteristic of near isothermal decompression. It is proposed that the P-T path followed by the SBMB is the result of the inversion, by overthrusting, of a back-arc basin and that such a tectonic setting may be applicable to other high-temperature migmatite terranes. The near isothermal decompression is at least partly driven by the upward (diapiric) movement of the diatexite/anatectic granite core of the SBMB.     

Subduction initiation in the Neo‐Tethys: constraints from counterclockwise P–T paths in amphibolite rocks of the Nagaland Ophiolite Complex,India

High‐P metamorphic rocks that are formed at the onset of oceanic subduction usually record a single cycle of subduction and exhumation along counterclockwise (CCW) P–T paths. Conceptual and thermo‐mechanical models, however, predict multiple burial–exhumation cycles, but direct observations of these from natural rocks are rare. In this study, we provide a new insight into this complexity of subduction channel dynamics from a fragment of Middle‐Late Jurassic Neo‐Tethys in the Nagaland Ophiolite Complex, northeastern India. Based on integrated textural, mineral compositional, metamorphic reaction history and geothermobarometric studies of a medium‐grade amphibolite tectonic unit within a serpentinite mélange, we establish two overprinting metamorphic cycles (M₁–M₂). These cycles with CCW P–T trajectories are part of a single tectonothermal event. We relate the M₁ metamorphic sequence to prograde burial and heating through greenschist and epidote blueschist facies to peak metamorphism, transitional between amphibolite and hornblende‐eclogite facies at 13.8 ± 2.6 kbar, 625 ± 45 °C (error 2σ values) and subsequent cooling and partial exhumation to greenschist facies. The M₂ metamorphic cycle reflects epidote blueschist facies prograde re‐burial of the partially exhumed M₁ cycle rocks to peak metamorphism at 14.4 ± 2 kbar, 540 ± 35 °C and their final exhumation to greenschist facies along a relatively cooler exhumation path. We interpret the M₁ metamorphism as the first evidence for initiation of subduction of the Neo‐Tethys from the eastern segment of the Indus‐Tsangpo suture zone. Reburial and final exhumation during M₂ are explained in terms of material transport in a large‐scale convective circulation system in the subduction channel as the latter evolves from a warm nascent to a cold and more mature stage of subduction. This Neo‐Tethys example suggests that multiple burial and exhumation cycles involving the first subducted oceanic crust may be more common than presently known.     

Metamorphism in the New England Orogen,eastern Australia: a review

Abstract

This paper summarises current knowledge on metamorphism within the entire New England Orogen (NEO) of eastern Australia. Rocks recording metamorphic assemblages characteristic of each of the three metamorphic facies series (high, medium and low P/T) have been identified within the orogen. These include high P/T blueschists and eclogites, mid P/T orogenic metamorphism and low P/T contact aureoles and sub-regional high-temperature–low-pressure (HTLP) metamorphism (regional aureoles). Metamorphism is described as it relates to six tectonic phases of development of the NEO that together comprise two major cycles of compression–extension. Medium–high-grade contact metamorphism spans all six tectonic phases while low-grade burial and/or orogenic metamorphism has been identified for four of the six phases. In contrast, exposure of high P/T eclogites and blueschists, and generation of sub-regional low P/T metamorphism is restricted to extensional phases of the orogen. Hallmarks of the orogen are two newly identified zones of HTLP metamorphism, the older of which extends for almost the entire length of the orogen.

1. KEY POINTS

2. The orogen is dominated by low-temperature rocks while high-temperature amphibolite to granulite facies rocks are restricted to small exposures in HTLP complexes and contact aureoles.

3. Blueschist metamorphism falls into two categories; that associated with subduction during the Currabubula-Connors continental arc phase occurring at depths of ～13–30?km; and the other of Cambrian–Ordovician age, exposed within a serpentinite melange and associated with blocks of eclogite. The eclogite, initially from depths of ～75–90?km, appears to have been entrained in the deep crust for an extended period of geological time.

4. A comprehensive review of contact metamorphism in the orogen is lacking and as studies on low-grade metamorphism are more extensive in the southern part of the orogen than the north, this highlights a second research gap.

     

An example of high-pressure low-temperature metamorphic rocks from an island-arc: the Paikon Series (Innermost Hellenides, Greece)

Abstract The Paikon Series is considered to be a volcanic arc sequence with a mainly neritic sedimentary sequence and bimodal tholeiitic volcanism of early Mesozoic age. The metamorphic assemblages are syn- to post-kinematic with respect to a pre-Tithonian tectonic phase and range from the lawsonite-chlorite-albite facies through transitional Na-amphibole-greenschist facies to the chlorite sub-zone of the greenschist facies. The metamorphic imprint of the Paikon Series corresponds to a temperature range from less than 330° C to ± 450° C under a total pressure from 3 kbar to 6–7 kbar. The overprinting of these facies on an earlier blueschist assemblage, related either to a subduction zone or to a tectonic overpressure caused by thrusting, is suspected.     

藏北羌塘中北部红脊山地区蓝闪石+硬柱石变质矿物组合的特征及其意义

蓝闪石+硬柱石是羌塘中北部红脊山地区首次发现的呈北西—南东走向展布的硬柱蓝闪片岩带中典型的低温高压变质矿物组合。蓝闪石呈浅蓝灰色,纤柱状;硬柱石无色,多呈团块状,较均匀地与蓝闪石混杂分布。电子探针分析表明,蓝闪石主要为铁蓝闪石和青铝闪石,硬柱石为较典型的硬柱石。硬柱蓝闪片岩呈(透镜状)构造岩块分布,与围岩呈断层接触,原岩主要为变质玄武岩及少量辉(长)绿岩、基性火山碎屑岩,围岩为变质砂岩、板岩和少量碳酸盐岩。红脊山硬柱蓝闪片岩带伴有构造混杂岩发育,二者共存构成红脊山地区北羌塘甜水河陆块与南羌塘查多岗日陆块之间的分界线。     

Geothermobarometry, P–T paths and metamorphic field gradients of high-pressure rocks from the Adula Nappe, Central Alps

Metabasic rocks from the Adula Nappe in the Central Alps record a regional high‐pressure metamorphic event during the Eocene, and display a regional variation in high‐pressure mineral assemblages from barroisite, or glaucophane, bearing garnet amphibolites in the north to kyanite eclogites in the central part of the nappe. High‐pressure rocks from all parts of the nappe show the same metamorphic evolution of assemblages consistent with prograde blueschist, high‐pressure amphibolite or eclogite facies conditions followed by peak‐pressure eclogite facies conditions and decompression to the greenschist or amphibolite facies. Average PT calculations (using thermocalc ) quantitatively establish nested, clockwise P–T paths for different parts of the Adula Nappe that are displaced to higher pressure and temperature from north to south. Metamorphic conditions at peak pressure increase from about 17 kbar, 640 °C in the north to 22 kbar, 750 °C in the centre and 25 kbar, 750 °C in the south. The northern and central Adula Nappe behaved as a coherent tectonic unit at peak pressures and during decompression, and thermobarometric results are interpreted in terms of a metamorphic field gradient of 9.6 ± 2.0 °C km^?1 and 0.20 ± 0.05 kbar km^?1. These results constrain the peak‐pressure position and orientation of the nappe to a depth of 55–75 km, dipping at an angle of approximately 45° towards the south. Results from the southern Adula Nappe are not consistent with the metamorphic field gradient determined for the northern and central parts, which suggests that the southern Adula Nappe may have been separated from central and northern parts at peak pressure.     

Dehydration veins in diagenetic and very-low-grade metamorphic rocks: features of the crustal seismogenic zone and their significance to mineral facies

Abstract Declining temperatures during decay of a hydrothermal system, or during uplift and erosion, tend to result in veins involving progressive hydration reactions, e.g. veins with laumontite cutting prehnitepumpellyite facies rocks, and stilbite veins cutting laumontite veins. In contrast, examples are described of analcime replacement of heulandite along fractures in heulanditized vitric tuff, of replacement of analcime by albite along fractures in quartz-analcime rock, of joint-controlled replacement of heulandite in tuff by laumontite + quartz + (Na, K)-feldspars, of replacement of laumontite by prehnite + quartz along fractures in alumontitized vitric tuff, and of laumontitebearing feldspathic sandstones cut by vein assemblages of quartz and prehnite ° Calcite. The vein mineral assemblage, sometimes with pumpellyite and/or epidote in the prehnite-bearing veins, tends to spread as a zone of dehydration into the adjacent country rock. Except perhaps for albite replacement of analcime, and for laumontite replacement of heulandite, these open-system reactions involve cation activity ratios in the fluid. All involve dehydration. They are favoured by an increase in temperature, and except under certain situations where P-T equilibrium curves have negative slopes, are favoured by a fall in P_H2O. Evidence indicates that in at least some cases the triggering mechanism was a drop in P_H2O; this may be a widespread phenomenon associated with brittle fracture in the seismogenic upper crust. This may cause fluid pressure to drop from values approaching lithostatic to nearer hydrostatic, and equilibrium may be displaced to yield a less hydrous assemblage that appears as a dehydration vein and vein verge. The dehydration vein assemblage may be diagnostic of a higher grade mineral facies and adds to the mineral complexity attributable to varying permeabilities and fluid pressures in upper crustal strata. Mineral facies are likely to be more uniformly distributed in higher grade rocks from below the brittle-ductile transition zone. Reactions involving complex solid solutions are inappropriate as facies boundaries.     

Multistage metamorphism and deformation in high‐pressure metabasites of the northern Adula Nappe Complex (Central Alps,Switzerland)

Metabasites from the northern Adula Nappe Complex (ANC) display a complex microstructural evolution recording episodes of deformation and metamorphic re‐equilibration that were obliterated in the surrounding phengite‐bearing schists. Pre‐D1 and D1 deformation episodes are preserved as mineral inclusions within garnet cores of some amphibole‐bearing eclogites and record high‐temperature greenschist‐/amphibolite‐facies conditions. D2 produced an eclogite‐facies foliation which developed at 580 ± 70°C and 19 ± 3 kbar. D3 was a composite deformation episode which can be divided into three sub‐episodes D3m, D3a and D3b which occurred as the metamorphism evolved from post‐eclogitic high‐pressure and low‐temperature conditions through to amphibolite‐facies conditions at 590 ± 30°C and 11.7 ± 1.3 kbar. The D3 deformation episode was responsible for the development of the S3 regional‐scale foliation in the surrounding schists, whilst D4 caused the development of an S4 greenschist foliation. The composite nature of the D3 episode indicates that rocks of the northern ANC experienced a protracted post‐eclogitic structural reworking and that the current structure of this part of the Alps is a late‐Alpine feature. Copyright © 2010 John Wiley & Sons, Ltd.     

Cold subduction of the Neotethys: the metamorphic record from finely banded lawsonite and epidote blueschists and associated metabasalts of the Nagaland Ophiolite Complex,India

In this study, we have deduced the thermal history of the subducting Neotethys from its eastern margin, using a suite of partially hydrated metabasalts from a segment of the Nagaland Ophiolite Complex (NOC), India. Located along the eastern extension of the Indus‐Tsangpo suture zone (ITSZ), the N–S‐trending NOC lies between the Indian and Burmese plates. The metabasalts, encased within a serpentinitic mélange, preserve a tectonically disturbed metamorphic sequence, which from west to east is greenschist (GS), pumpellyite–diopside (PD) and blueschist (BS) facies. Metabasalts in all the three metamorphic facies record prograde metamorphic overprints directly on primary igneous textures and igneous augite. In the BS facies unit, the metabasalts interbedded with marble show centimetre‐ to metre‐scale interlayering of lawsonite blueschist (LBS) and epidote blueschist (EBS). Prograde HP/LT metamorphism stabilized lawsonite + omphacite (X_Jd = 0.50–0.56 to 0.26–0.37) + jadeite (X_Jd = 0.67–0.79) + augite + ferroglaucophane + high‐Si phengite (Si = 3.6–3.65 atoms per formula unit, a.p.f.u.) + chlorite + titanite + quartz in LBS and lawsonite + glaucophane/ferroglaucophane ± epidote ± omphacite (X_Jd = 0.34) + chlorite + phengite (Si = 3.5 a.p.f.u.) + titanite + quartz in EBS at the metamorphic peak. Retrograde alteration, which was pervasive in the EBS, produced a sequence of mineral assemblages from omphacite and lawsonite‐absent, epidote + glaucophane/ferroglaucophane + chlorite + phengite + titanite + quartz through albite + chlorite + glaucophane to lawsonite + albite + high‐Si phengite (Si = 3.6–3.7 a.p.f.u.) + glaucophane + epidote + quartz. In the PD facies metabasalts, the peak mineral assemblage, pumpellyite + chlorite + titanite + phengitic white mica (Si = 3.4–3.5 a.p.f.u.) + diopside appeared in the basaltic groundmass from reacting titaniferous augite and low‐Si phengite, with prehnite additionally producing pumpellyite in early vein domains. In the GS facies metabasalts, incomplete hydration of augite produced albite + epidote + actinolite + chlorite + titanite + phengite + augite mineral assemblage. Based on calculated T–M(H₂O), T–M(O₂) (where M represents oxide mol.%) and P–T pseudosections, peak P–T conditions of LBS are estimated at ~11.5 kbar and ~340 °C, EBS at ~10 kbar, 325 °C and PD facies at ~6 kbar, 335 °C. Reconstructed metamorphic reaction pathways integrated with the results of P–T pseudosection modelling define a near‐complete, hairpin, clockwise P–T loop for the BS and a prograde P–T path with a steep dP/dT for the PD facies rocks. Apparent low thermal gradient of 8 °C km^?1 corresponding to a maximum burial depth of 40 km and the hairpin P–T trajectory together suggest a cold and mature stage of an intra‐oceanic subduction zone setting for the Nagaland blueschists. The metamorphic constraints established above when combined with petrological findings from the ophiolitic massifs along the whole ITSZ suggest that intra‐oceanic subduction systems within the Neotethys between India and the Lhasa terrane/the Karakoram microcontinent were also active towards east between Indian and Burmese plates.     

藏南吉隆地区大喜马拉雅结晶杂岩的新生代变质作用和构造意义

大喜马拉雅结晶杂岩位于喜马拉雅造山带的核部,其变质作用的研究是揭示碰撞造山作用和动力学的关键。本文对喜马拉雅造山带中部吉隆地区的大喜马拉雅结晶杂岩中的片麻岩和片岩进行了岩石学和锆石U-Pb年代学的研究,表明这些高级变质岩经历了高角闪岩相的变质作用和部分熔融,以及近等温降压的退变质过程。片麻岩和片岩的峰期变质矿物组合为斜长石+钾长石+黑云母+白云母+石英±石榴子石±钛铁矿和石榴子石+蓝晶石+斜长石+黑云母+白云母+钛铁矿+石英,晚期退变质矿物组合为斜长石+钾长石+黑云母+白云母+夕线石+石英±石榴子石和石榴子石+夕线石+斜长石+黑云母+白云母+钛铁矿+石英。相平衡模拟研究表明,岩石的峰期变质条件为685~755℃和9.5~12kbar,退变质作用条件为675~685℃和6~7.4kbar。锆石U-Pb年代学表明,高级变质岩的部分熔融时间为38~16Ma,熔体结晶时间为17~15Ma。本次研究表明,大喜马拉雅结晶杂岩中、上部并没有普遍经历高压麻粒岩相变质作用,部分地区包括吉隆地区经历的是高角闪岩相变质作用。此外,本文在吉隆地区高级变质的大喜马拉雅结晶杂岩中识别出较低级变质的特提斯喜马拉雅岩系单元。结合已发表的藏南拆离断裂的主要活动时间,本文认为构造楔模型更适用于研究区喜马拉雅造山过程的解释。     

Paleozoic serpentinite-enclosed chromitites from Tehuitzingo (Acatlán Complex, southern Mexico): a petrological and mineralogical study

The serpentinites and associated chromitite bodies in Tehuitzingo (Acatlán Complex, southern Mexico) are in close relationship with eclogitic rocks enclosed within a metasedimentary sequence, suggesting that the serpentinites, chromitites and eclogitic rocks underwent a common metamorphic history.Primary chromites from the chromitite bodies at Tehuitzingo are of refractory-grade (Al-rich) and have a chemical composition similar to that expected to be found in an ophiolitic environment. The chromite grains in chromitites and serpentinites are systematically altered to ‘ferritchromite’. The alteration trend is usually characterized by a decrease in the Al, Mg and Cr contents coupled by an increase in Fe³⁺ and Fe²⁺.The Tehutizingo chromitites have low Platinum Group Elements (PGE) contents, ranging from 102 to 303 ppb. The chondrite-normalized PGE patterns are characterized by an enrichment in the Ir-subgroup elements (IPGE=Os, Ir, Ru) relative to the Pd-subgroup elements (PPGE=Rh, Pt, Pd). In addition, all chromitite samples display a negative slope from Ru to Pd [(Os+Ir+Ru)/(Pt+Pd)=4.78−14.13]. These patterns, coupled with absolute PGE abundances, are typical of ophiolitic chromitites elsewhere. Moreover, all the analyzed samples exhibit chondrite-normalized PGE patterns similar to those found for non-metamorphosed ophiolitic chromitites. Thus, the PGE distribution patterns found in the Tehuitzingo chromitites have not been significantly affected by any subsequent Paleozoic high-pressure (eclogite facies) metamorphic event.The chondrite-normalized PGE patterns of the enclosing serpentinites also indicate that the PGE distribution in the residual mantle peridotites exposed in Tehuitzingo was unaffected by high-pressure metamorphism, or subsequent hydrothermal alteration since the serpentinites show a similar pattern to that of partially serpentinized peridotites present in mantle sequences of non-metamorphosed ophiolites.Our main conclusion is that the chromitites and serpentinites from Tehuizingo experienced no significant redistribution (or concentration) of PGE during the serpentinization process or the high-pressure metamorphic path, or during subsequent alteration processes. If any PGE mobilization occurred, it was restricted to individual chromitite bodies without changing the bulk-rock PGE composition.Our data suggest that the Tehuitzingo serpentinites and associated chromitites are a fragment of oceanic lithosphere formed in an arc/back-arc environment, and represent an ophiolitic mantle sequence from a supra-subduction zone, the chemical composition of which remained essentially unchanged during the alteration and metamorphic events that affected the Acatlán Complex.     

The effect of TiO2 and Fe2O3 on metapelitic assemblages at greenschist and amphibolite facies conditions: mineral equilibria calculations in the system K2O–FeO–MgO–Al2O3–SiO2–H2O–TiO2–Fe2O3

Mineral equilibria calculations in the system K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O–TiO₂–Fe₂O₃ (KFMASHTO) using thermocalc and its internally consistent thermodynamic dataset constrain the effect of TiO₂ and Fe₂O₃ on greenschist and amphibolite facies mineral equilibria in metapelites. The end‐member data and activity–composition relationships for biotite and chloritoid, calibrated with natural rock data, and activity–composition data for garnet, calibrated using experimental data, provide new constraints on the effects of TiO₂ and Fe₂O₃ on the stability of these minerals. Thermodynamic models for ilmenite–hematite and magnetite–ulvospinel solid solutions accounting for order–disorder in these phases allow the distribution of TiO₂ and Fe₂O₃ between oxide minerals and silicate minerals to be calculated. The calculations indicate that small to moderate amounts of TiO₂ and Fe₂O₃ in typical metapelitic bulk compositions have little effect on silicate mineral equilibria in metapelites at greenschist to amphibolite facies, compared with those calculated in KFMASH. The addition of large amounts of TiO₂ to typical pelitic bulk compositions has little effect on the stability of silicate assemblages; in contrast, rocks rich in Fe₂O₃ develop a markedly different metamorphic succession from that of common Barrovian sequences. In particular, Fe₂O₃‐rich metapelites show a marked reduction in the stability fields of staurolite and garnet to higher pressures, in comparison to those predicted by KFMASH grids.     

Amphibolite facies retrograde metamorphism of the Zhujiachong eclogite,SE Dabieshan: 40Ar/39Ar age constraints from argon extraction using UV‐laser microprobe,in vacuo crushing and stepwise heating

The Zhujiachong eclogite in the south‐eastern Dabieshan ultra‐high‐P terrane has been overprinted during retrograde metamorphism, with the development of garnet‐amphibolite mineral assemblages in most rocks in the outcrop. This study is focused on providing age constraints for the retrograde amphibolite facies and greenschist facies mineralogy by ⁴⁰Ar/³⁹Ar dating. By applying a novel approach of combining three different techniques for extracting argon: laser stepwise heating of single grains and small separates, a spot fusion technique by UV‐laser ablation microprobe on polished sections and an in vacuo crushing technique for liberating radiogenic argon from fluid inclusions, it is demonstrated that an internally consistent thermal history can be derived. The ⁴⁰Ar/³⁹Ar ages indicate that phengite formed before 265 Ma, probably during the ultra‐high‐P event. Ages associated with amphibolite facies retrograde metamorphism range from 242 to 217 Ma by the analyses of amphibole. Ages of c. 230 Ma were found for the symplectite matrix that formed during retrogression from eclogite pyroxene. Late stage hydrothermal activity leading to the formation of coarse‐grained paragonite and fluid inclusions in vein amphibole was dated at c. 200 Ma. These age results agree well with the mineral crystallization sequence observed from thin‐sections of the retrograded eclogite: phengite → paragonite and amphibole in matrix → amphibole in the corona.     

A garnet–hornblende geothermometer: calibration, testing, and application to the Pelona Schist, Southern California

Abstract A garnet–hornblende Fe–Mg exchange geothermometer has been calibrated against the garnet–clinopyroxene geothermometer of Ellis & Green (1979) using data on coexisting garnet + hornblende + clinopyroxene in amphibolite and granulite facies metamorphic assemblages. Data for the Fe–Mg exchange reaction between garnet and hornblende have been fitted to the equation. In K_D=Δ (X_Ca,g) where K_D is the Fe–Mg distribution coefficient, using a robust regression approach, giving a thermometer of the form: with very satisfactory agreement between garnet–hornblende and garnet–clinopyroxene temperatures. The thermometer is applicable below about 850°C to rocks with Mn-poor garnet and common hornblende of widely varying chemistry metamorphosed at low a_O2. Application of the garnet–hornblende geothermometer to Dalradian garnet amphibolites gives temperatures in good agreement with those predicted by pelite petrogenetic grids, ranging from 520°C for the lower garnet zone to 565–610°C for the staurolite to kyanite zones. These results suggest that systematic errors introduced by closure temperature problems in the application of the garnet–clinopyroxene geothermometer to the ‘calibration’data set are not serious. Application to ‘eclogitic’garnet amphibolites suggests that garnet and hornblende seldom attain Fe–Mg exchange equilibrium in these rocks. Quartzo-feldspathic and mafic schists of the Pelona Schist on Sierra Pelona, Southern California, were metamorphosed under high pressure greenschist, epidote–amphibolite and (oligoclase) amphibolite facies beneath the Vincent Thrust at pressures deduced to be 10±1 kbar using the phengite geobarometer, and 8–9kbar using the jadeite content of clinopyroxene in equilibrium with oligoclase and quartz. Application of the garnet–hornblende thermometer gives temperatures ranging from about 480°C at the garnet isograd through 570°C at the oligoclase isograd to a maximum of 620–650°C near the thrust. Inverted thermal gradients beneath the Vincent Thrust were in the range 170 to 250°C per km close to the thrust.     

新疆吐鲁番—哈密盆地托克逊凹陷早侏罗世孢粉植物群及其意义

吐鲁番—哈密盆地托克逊凹陷早侏罗世地层中产孢粉化石共53属74种。通过对纵向上典型属种及优势组分含量变化规律的分析可划分为两个孢粉组合：Osmundacidites-Protopinus-Cycadopites组合和Cyathidites-Piceaepollenites-Cycadopites组合，它们分别产自八道湾组和三工河组。根据孢粉组合特征及与国内外有关化石群进行比较，八道湾组的时代应属早侏罗世早期；三工河组的时代应为早侏罗世晚期。托克逊地区当时的植被是由银杏、苏铁类和松柏类等乔木．并伴有真蕨类等草本植物组成。古气候应属亚热带气候。     

Anti-clockwise P–T paths in the lower crust: an example from a kyanite-bearing regional aureole, George Sound, New Zealand

The George Sound Paragneiss (GSP) represents a rare Permo-Triassic unit in Fiordland that occurs as a km-scale pillar to gabbroic and dioritic gneiss of c . 120 Ma Western Fiordland Orthogneiss (WFO). It is distinguished from Palaeozoic paragneiss common in western Fiordland (Deep Cove Gneiss) by SHRIMP and laser-ablation U–Pb ages as young as c . 190 Ma and ¹⁷⁶Hf/¹⁷⁷Lu >0.2828 for detrital zircon grains. The Mesozoic age of the GSP circumvents common ambiguity in the interpretation of Cretaceous v. Palaeozoic metamorphic assemblages in the Deep Cove Gneiss. A shallowly dipping S₁ foliation is preserved in the GSP distal to the WFO, cut by 100 m scale migmatite contact zones. All units preserve a steeply dipping S₂ foliation. S₁ staurolite and sillimanite inclusions in the cores of metapelitic garnet grains distal to the WFO preserve evidence for prograde conditions of T  <   650 °C and P <  8 kbar. Contact aureole and S₂ assemblages include Mg-rich, Ca-poor cores to garnet grains in metapelitic schist that reflect WFO emplacement at ≈760 °C and ≈6.5 kbar. S₂ kyanite-bearing matrix assemblages and Ca-enriched garnet rims reflect ≈650 °C and ≈11 kbar. Poorly oriented muscovite–biotite intergrowths and rare paragonite reflect post-S₂ high- P retrogression and cooling. Pseudosection modelling in NCKFMASH defines a high- P anti-clockwise P–T history for the GSP involving: (i) mid- P amphibolite facies conditions; preceding (ii) thermal metamorphism adjacent to the WFO; followed by (iii) burial to high- P and (iv) high- P cooling induced by tectonic juxtaposition of cooler country rock.     

P–T evolution in greenstone‐belt mafic amphibolites: an example from Plutonic Gold Mine,Marymia Inlier,Western Australia

The metamorphosed mafic rocks of Archean greenstone belts host major orogenic gold deposits, and may record information about changing pressure–temperature (P–T) conditions that could contribute to understanding of Archean geodynamic processes. Until recently, it was difficult to obtain good constraints on pressure and temperature from these rocks. Here we present results of P–T pseudosection calculations in the NCFMASHTOS (Na₂O–CaO–FeO–MgO–Al₂O₃–SiO₂–H₂O–TiO₂–O–SO₂) system, using as an example typical amphibolite facies metabasaltic rocks from the Plutonic Gold Mine in the Neoarchean Plutonic Well Greenstone Belt (PWGB), Marymia Inlier, Western Australia. The pseudosections together with observed mineral compositions and mineral assemblages in the rocks are used to argue that a previously unrecognized steep pressure increase (from ～3–4 kbar at ～500 °C to ≥8 kbar at ～600 °C) accompanied metamorphism to peak temperatures. The P–T data presented here could be the result of either horizontal or vertical tectonics. Existing models for the early evolution of the PWGB involve nappe stacking supported by relatively cold strong crust, with little overall change in thickness. While the available evidence from the study area and the wider region is not yet sufficient to confirm whether the peak metamorphic conditions were attained by horizontal or vertical tectonic means, the P–T data presented here can provide region‐specific constraints for computer modelling that may provide a more definite answer in the future.     

Mapping a coastal transition in braided systems: an example from the Precipice Sandstone,Surat Basin

The Precipice Sandstone is traditionally interpreted as a braided fluvial deposit that transitions upwards into meandering channel deposits responding to a rise in base level that eventually deposits the overlying alluvial to lacustrine Evergreen Formation. This study found sedimentary evidence of tidal to marine influence within the Precipice Sandstone coincident with avulsion and diversion of the system from southward to northward-flowing channels as the system was transgressed. The north-flowing channels are interpreted to debouch into a shallow restricted marine embayment with tide and wave influence, which provides an alternative insight into this unit and suggests a Lower Jurassic north or northeasterly marine connection. The Precipice Sandstone is a regional aquifer, in places hosts hydrocarbons and has been considered as a storage unit for CO₂ geosequestration. Outcrop analogues can provide geometries to accompany facies interpreted from sedimentary structures that are observable in core, to assist in characterising reservoir heterogeneity.     

Time-series analysis in cyclic stratigraphy: An example from the Cretaceous of the Southern Alps, Italy

The importance of time-series analysis in cyclic stratigraphy is evaluated by comparing three different methods (adaptive multiple taper spectral analysis, auto-/cross-correlation analysis, cova functions) applied to stratigraphic time series from the Early Cretaceous Cismon section in northern Italy. Carbonate content and magnetic susceptibility vary in a quasi-cyclic fashion in this pelagic limestone section and are almost perfectly negatively correlated. The spectral technique requires a high degree of preprocessing of the original data (interpolation and resampling at a regular interval, filtering, inversion) which introduces smoothing and rounding errors. The statistical correlation analysis also requires evenly and (for cross-correlation) correspondingly spaced series. The geostatistical cova functions (a generalization of the cross-variogram) prove to be the most versatile and robust of the methods compared. Cova functions can be calculated from unevenly and noncor-respondingly spaced time series without any preprocessing. This method also retains relatively more of the signal if noise and extreme outliers obscure the picture. The periodicities detected in the Cismon time series fall in the range of Milankovitch cycles. Cycle periods of 45 cm and 80 cm likely correspond to dominant precession and obliquity cycles. Due to the inaccuracy of the Cretaceous time scale periods cannot be matched exactly yet, but cycle ratios are close to expected ratios so that there is great potential for future cyclostratigraphic work to contribute to a substantial improvement of the geologic time scale.