Organic carbon flow in the Ob, Yenisey Rivers and Kara Sea of the Arctic region

Stable carbon isotope and elemental C/N ratios of the organic fraction of a set of samples along a transect in the Ob and Yenisey Rivers into the Kara Sea in the Arctic were measured. Previously, the concentrations of 239,240Pu and 137Cs in these same samples had been determined. The coupled measurements were carried out to assess possible connectivity between organic carbon flow into the Kara Sea and transport of radioactive nuclides in this marine environment. Organic carbon flow into the Kara Sea is influenced significantly by terrigenous sources carried by the Ob and Yenisey Rivers. The carbon isotope-organic carbon relationship provides evidence that a rich source of terrigenous carbon exists in the riverine system. A weak, but significant relationship between stable carbon isotope ratio and 137Cs suggests that most of the 137Cs is derived from riverine particles, as compared to Pu which is also derived from in situ scavenging within the water column.     

Particulate matter fluxes in the southern and central Kara Sea compared to sediments: Bulk fluxes, amino acids, stable carbon and nitrogen isotopes, sterols and fatty acids

The Kara Sea is one of the arctic marginal seas strongly influenced by fresh water and river suspension. The highly seasonal discharge by the two major rivers Yenisei and Ob induces seasonal changes in hydrography, sea surface temperature, ice cover, primary production and sedimentation. In order to obtain a seasonal pattern of sedimentation in the Kara Sea, sediment traps were deployed near the river mouth of the Yenisei (Yen) as well as in the central Kara Sea (Kara) within the framework of the German–Russian project “Siberian River run-off; SIRRO”. Two and a half years of time-series flux data were obtained between September 2000 and April 2003 and were analyzed for bulk components, amino acids, stable carbon and nitrogen isotopes as well as sterols and fatty acids.Sediment trap data show that much of the annual deposition occurred under ice cover, possibly enhanced by zooplanktonic activity and sediment resuspension. An early bloom of ice-associated algae in April/May occurred in the polynya area and may have been very important to sustain the life cycles of higher organisms after the light limitation of the winter months due to no/low insolation and ice cover. The strong river input dominated the months June–August in the southern part of the Kara Sea. The central Kara Sea had a much shorter productive period starting in August and was less affected by the river plumes. Despite different time-scales of sampling and trapping biases, total annual fluxes from traps were in the same order of magnitude as accumulation rates in surface sediments. Terrestrial organic carbon accumulation decreased from 10.7 to 0.3 g C m⁻² a⁻¹ from the riverine source to the central Kara Sea. Parallel to this, preservation of marine organic matter decreased from 10% to 2% of primary productivity which was probably related to decreasing rates of sedimentation.     

Assessment of potential transport of pollutants into the Barents Sea via sea ice--an observational approach

The present estimates of ice drift in the Arctic include utilization of satellite imagery data (special sensor microwave/imager) and a reconstruction of air pressure for the period 1899-1998. A significant part of the sea ice in the Arctic Ocean has its origin in the Kara Sea and melts in the Greenland and the Barents Sea (BS). Consequently there may be a particular risk of pollutants in the Kara Sea entering the food webs of the Greenland and BS. The ice export from the Kara Sea between 1988 and 1994 was about 208,000 km2 (154 km3) per year. The import of ice into the BS was during the same period 161,000 km2 (183 km3) per year while the ice drift through the Fram Strait into the Greenland Sea was 583,000 km2 (1859 km3) per year. Ice which formed adjacent to the Ob and Yenisey rivers in early January, drifted into the BS within two years (with a probability of about 50%.     

Trace contaminant concentrations in the Kara Sea and its adjacent rivers, Russia.

Trace organic (chlorinated pesticides, PCBs, PAHs and dioxins/furans) and trace metal concentrations were measured in surficial sediment and biological tissues (i.e., worms, crustaceans, bivalve molluscs, and fish livers) collected from the Russian Arctic. Total DDT, chlordane, PCB and PAH concentrations ranged from ND to 1.2, ND to <0.1, ND to 1.5 and <20-810 ng g(-1), respectively, in a suite of 40 surficial sediment samples from the Kara Sea and the adjacent Ob and Yenisey Rivers. High sedimentary concentrations of contaminants were found in the lower part of the Yenisey River below the salt wedge. Total dioxins/furans were analysed in a subset of 20 sediment samples and ranged from 1.4 to 410 pg g(-1). The highest trace organic contaminant concentrations were found in organisms, particularly fish livers. Concentrations as high as 89 ng g(-1) chlordane; 1010 ng g(-1) total DDTs; 460 ng g(-1) total PCBs; and 1110 ng g(-1) total PAH, were detected. A subset of 11 tissue samples was analysed for dioxins and furans with total concentrations ranging from 12 to 61 pg g(-1). Concentrations of many trace organic and metal contaminants in the Kara Sea appear to originate from riverine sources and atmospheric transport from more temperate areas. Most organic contaminant concentrations in sediments were low; however, contaminants are being concentrated in organisms and may pose a health hazard for inhabitants of coastal villages.     

Radiocaesium distribution in the bottom sediments of the Kara Sea

The article presents the results of radiogeochemical studies carried out by the Institute of Geology of Ore Deposits, Petrography, Mineralogy, and Geochemistry, RAS (IGEM RAS), in the Kara Sea and the estuaries of the Ob and Yenisei rivers in 1995–2003. The studies were carried out onboard the Akademik Boris Petrov research vessel, belonging to the Institute of Geochemistry, RAS. Based on studies of circa 1500 samples of bottom sediments, taken from 172 marine and river stations, a map of ¹³⁷Cs distribution in the surface sediments has been compiled. Four zones of radiocesium overactivity (>15 Bk/kg) have been identified: Novaya Zemlya Zone, Vaigach Zone, Ob Zone, and Yenisei Zone. The zones have different radiocesium concentration levels, as well as different input sources, but all of them have formed under the influence of complex geochemical barriers. Data from 47 sectioned cores of bottom sediments, sampled in Ob and Yenisei overactivity zones, demonstrate distinct differences in the vertical radiocesium distribution. These differences have been shown to be due to many-year oscillations of suspended silt discharge, which are main transfer agents of solvable and poorly solvable radiocesium forms and to be independent of sedimentation conditions and the geochemical characteristics of the deposition environment.     

Benthic communities as influenced by nuclear testing and radioactive waste disposal off Novaya Zemlya in the Russian Arctic

On the material of sampling, accomplished in: (i) Chernaya Inlet of the Barents Sea (one of the flats of Novaya Zemlya Nuclear Test Site), (ii) in the Open Kara Sea and (iii) on the shoal off Novaya Zemlya from Stepovogo Fjord to Abrosimov Fjord (sites of radioactive waste disposal with activity 90% from total for the Kara Sea), characteristics of macro-, meio- and microbenthic bottom communities on the areas of potential radioactive danger are presented. Significant changes in macro- and meiobenthic communities are not revealed. In Chernaya Inlet, where three nuclear explosions were held in 1955–1961, disturbances in microbenthic protozoa communities are found. These disturbances expressed in the infusoria elimination from the fauna of the inlet deep-water sites and in morphological abnormality of this group individuals in population, inhabiting low depth of the inlet top. The assumed origin of revealed disturbances is high concentration (by 3–4 orders of magnitude above the background) of plutonium in bottom sediments of the inlet. Similar responses of the microbenthic flagellates are not detected.     

Distribution of 137Cs in the Lena River estuary-Laptev Sea system.

Surface sediment samples in the Laptev Sea have average 137Cs content of 7.1 Bq kg(-1), a value intermediate between that of the western Kara Sea (23 Bq kg(-1) and the East Siberian Sea (4.2 Bq kg-'). Both surface sediment content and sediment inventory of 137Cs in the Laptev Sea sediments show significant variability, and the influence of a variety of environmental factors.137Cs concentrations in the Laptev Sea surface sediments range from 0.8 to 16 Bq kg(-1). There is a marked increase in 137Cs content of surface sediment samples collected near the Lena River delta, and a local enrichment in the 137Cs inventories at these sites is also evident. Fine-grained mixed-layer illite/ smectite rich sediments in the estuary provide effective adsorption sites to fix 137Cs, in spite of desorption processes associated with low salinities in estuarine mixing. The Lena River-Laptev Sea mixing zone is a major site of sea-ice production. River and shelf sediments are incorporated into sea-ice formed in this region (Holmes and Creager, 1974). The irregular 137Cs activity profiles of the Lena River estuary cores indicate disturbance or removal of 137Cs-laden sediments via sea-ice related processes. Lena River and Estuary sediments may have served as a secondary source (i.e. other than direct fallout) of 137Cs in sea-ice. North-east of the Lena River estuary, sediment contains a thin layer of 137Cs-bearing material over an erosion surface. The 137Cs-laden surface layer may be the result of transient deposition of estuarine sediments being delivered by sea-ice or spring floods.     

Modelling the release to the Kara Sea of radioactive waste from the icebreaker Lenin: Version II

In progressing its work for the International Arctic Seas Assessment Project (IASAP), under the auspices of the International Atomic Energy Agency (IAEA), the Source Term Working Group has developed a FORTRAN model to predict a radiation release profile into the Kara Sea from reactor fuel and activated components of the nuclear icebreaker Lenin. The model accounts for the degradation of containment materials through corrosion and other mechanisms, and predicts annual release rates to 4500 years into the future. Version I of the model was developed as a spreadsheet program from the original data gathered by the Working Group and the results were published by Timms et al. (1994); revised information on the method of disposal necessitated a change to the program, which is presented in this paper as Version II. The model is being applied to other marine reactors dumped in the Kara Sea in a programme of work for the IASAP aimed at assessing the collective release profile from all significant dump sites in this region.     

The problem of transfer of radionuclide pollution by sea ice

The problem of the radioactive pollution of the ice cover is discussed in this paper. An estimation of the possible transport of the radionuclides by drifting ice from the Kara Sea into the Arctic Ocean is presented. The conclusion about the importance of the contribution of drifting ice to the contamination of the Greenland coastal water is based on the comparison of estimates of the multiyear export of radioactive drifting ice from the Kara Sea with the observed concentrations of the radionuclides in the Greenland coastal water.     

Radionuclide adsorption to sediments from nuclear waste dumping sites in the Kara Sea

Environmental parameters (salinity, sediment concentration, equilibration time) affecting radionuclide partitioning between sediment and seawater were experimentally investigated for Kara Sea sediments collected from nuclear waste dumping sites in Abrosimov and Stepovogo Bays off Novaya Zemlya. Adsorption kinetics were examined and the influence of salinity and sediment concentration were evaluated over the range of concentrations expected in the bays for the following radionuclides: ^{110 m}Ag; ²⁴¹Am; ¹⁰⁹Cd; ⁶⁰Co; ⁵⁷Co-cobalamine; ¹³⁴Cs; ¹⁵²Eu; ⁵⁴Mn; ¹³³Ba; ¹⁰⁶Ru; and ⁸⁵Sr. The major findings of this investigation are that 1. radionuclide distribution coefficients (K_ds) were most sensitive to variations in sediment character (²⁴¹Am, ⁶⁰Co, ¹⁰⁹Cd) and concentration (⁵⁷Co-cobalamine, ⁸⁵Sr, and ¹³³Ba), 2. distribution coefficients generally decreased with increasing sediment concentration and 3. fast adsorption kinetics (near equilibrium ≈1 day) were observed only for ¹³⁷Cs and ^{110 m}Ag. The observed differences in K_ds for sediments from the two dumpsites exemplifies the importance of undertaking site-specific determinations of K_ds. For purposes of confining radioactive wastes to the dumpsites in Stepovogo and Abrosimov Bays, the findings of this study indicate that based on sediment character alone, Stepovogo Bay will be more effective at retaining radionuclides than Abrosimov Bay. This is unfortunate since less radioactive waste resides in Stepovogo Bay (0.6 PBq) than in Abrosimov Bay (1.4 PBq).     

Environment and biology of the Kara Sea: a general view for contamination studies

The recent revelation that over the past 30 years there has been a history of dumping waste including high-level radioactive wastes in the shallow Kara Sea has caused wide-spread concern. The potential impact of these contaminants and other non-nuclear pollutants in the Arctic ecosystem and on human health need to be assessed and, thus, a better insight gained on radioecological processes in cold waters. The present paper proposes a general view on the biology and the environment of the Kara Sea, as a basic tool for the experimental and modelling assessments of the impact of these contaminants.     

Iodine-129 concentrations in marginal seas of the north Pacific and Pacific-influenced waters of the Arctic Ocean

Water sampling during the 1993 IV Russian–US Joint Expedition to the Bering and Chukchi Seas (BERPAC) indicates that Pacific Ocean burdens of the long-lived radionuclide ¹²⁹I are relatively low in the Pacific-influenced Arctic, particularly compared to high latitude waters influenced by the North Atlantic. These low concentrations occur despite the presence of potential submerged anthropogenic sources in the East Sea (Sea of Japan), and in the northwest Pacific Ocean, east of the Kamchatka Peninsula. The concentration of ¹²⁹I entering the Arctic Ocean through Bering Strait, 0.7×10⁸ atoms kg⁻¹, is only slightly higher than observed in deep Pacific waters. Similar concentrations (0.44–0.76×10⁸ atoms kg⁻¹) measured in Long Strait indicate no significant transfer of ¹²⁹I eastward into the Chukchi Sea in the Siberian Coastal Current from the Siberian marginal seas to the west. However, the concentrations reported here are more than an order of magnitude higher than the Bering Strait input concentration estimated (1.0×10⁶ atoms kg⁻¹) from bomb fallout mass balances, which supports other existing evidence for a significant atmospheric deposition term for this radionuclide in surface ocean waters. Near-bottom water samples collected in productive waters of the Bering and Chukchi Seas also suggest that sediment regeneration may locally elevate ¹²⁹I concentrations, and impact its utility as a water mass tracer. As part of this study, two deep ¹²⁹I profiles were also measured in the East Sea in 1993–1994. The near-surface concentration of ¹²⁹I ranged from 0.12 to 0.31×10⁸ atoms kg⁻¹. The ¹²⁹I concentration showed a steady decrease with depth, although because of active deep water ventilation, the entire 3000 m water column exceeded natural concentrations of the radionuclide. Atom ratios of ¹²⁹I/¹³⁷Cs in the East Sea also suggest an excess of ¹²⁹I above bomb fallout estimates, also possibly resulting from atmospheric deposition ultimately originating from nuclear facilities.     

Sorption of radioactive contaminants by sediment from the Kara Sea

The purpose of this study is to quantify some of the parameters needed to perform near-field modelling of sites in the Kara Sea that were impacted by the disposal of radioactive waste. The parameters of interest are: the distribution coefficients (Kd) for several important radionuclides, the mineralogy of the sediment, and the relationship of Kd to liquid-to-solid ratio. Sediment from the Kara Sea (location: 73 degrees 00'N, 58 degrees 00'E) was sampled from a depth of 287 m on August 23/24, 1992. Analysis of the material included mineralogy, grain size and total organic carbon (TOC). Uptake kinetics were determined for 85Sr, 137Cs, 241Am, 99Tc, 1251, 232U and 210Pb and distribution coefficients (Kd) were determined for these radionuclides using batch type experiments. Sorption isotherms, developed for 137Cs, 85Sr and 99Tc, were linear in each case. Increasing the liquid-to-solid ratio strongly increased uptake of 137Cs and moderately increased uptake of 99Tc. Analysis for anthropogenic radionuclides indicated the presence only of 239/240Pu in the sediment with the highest activity (at the top section of the core) being 0.420 Bq kg(-1). Other anthropogenic radionuclides were below detection limits.     

Climate and hydrological changes in the Ob River Basin during 1936–2017

Changes in the hydrological regimes of Arctic rivers could affect the thermohaline circulation of the Arctic Ocean. In this study, we analysed spatiotemporal variations in temperature and precipitation in the Ob River Basin regions during 1936–2017 based on data from the Global Precipitation Climatology Center. Changes in discharge and response to climate change were examined based on monthly observed data during the same period. It is indicated the Ob River Basin experienced significant overall rapid warming and wetting (increased precipitation) in the study period, with average rates of 0.20°C (10 year⁻¹) and 5.3 mm (10 year⁻¹), respectively. The annual spatial variations of temperature and precipitation showed different scales in different regions. The discharge in spring and winter significantly increased at a rate of 384.1 and 173.1 m³/s (10 year⁻¹), respectively. Hydrograph separation indicated infiltration and supported that deep flow paths increased the contribution of groundwater to base flow. Meanwhile, the variation of the ratio of Q_max/Q_min suggested that the basin storage and the mechanism of discharge generation have significantly changed. The hydrological processes were influenced by changes of permafrost in a certain in the Ob River Basin. An increase in the recession coefficient (RC) implies that the permafrost degradation in the basin due to climate warming affected hydrological processes in winter. Permafrost degradation affected the Q_max/Q_min more significantly in the warm season than RC due to the enhanced infiltration that converted more surface water into groundwater in the cold season. The impact of precipitation on discharge, including surface flow and base flow, was more significant than temperature at the annual and seasonal scales in the Ob River Basin. The base flow was more obviously influenced by temperature than surface flow. The results of this study are significant for analyses of the basin water budget and freshwater input to the Arctic Ocean.     

New magnetic and paleomagnetic data from the Volodarka section (the Ob River)

New magnetic and paleomagnetic data from the loess-soil Volodarka section (the Ob River) are presented. In particular, a secondary magnetization aligned with the contemporary magnetic field and persisting on heating to 500–600°C is shown to be present. It is shown that the transition zone of the Matuyama-Brunhes reversal is most likely located within the soil complex, consisting of three paleosol horizons separated by two horizons of loesslike loam that belong to the same interglaciation.     

Modeling the Yellow River sediment flux and its deposition patterns under climatological conditions

A numerical sediment transport model was embedded into a coupled wave-tide-circulation model to quantitatively estimate the suspended sediment fluxes (SSF) and distribution in different areas for the Yellow River derived sediment. The model is validated by comparing model simulated sediment deposition rates with those from observations. Simulated results show that the SSF of the Yellow River across two major sections (the Bohai Strait and the 37° N section) are highest during September and October, whereas for the 32° N section the flux is negligibly small (less than 0.1 kg/s). We demonstrate that the sediment flux is primarily driven by the buoyancy forcing of the Yellow River freshwater discharge and modulated by the wind-driven surface wave and circulation patterns in this region. The SSF across the Bohai Strait is about 30 % of the Yellow River discharge, while across the 37° N section it is 15.8 %. Therefore, about 70 % of the total discharged Yellow River sediments are deposited in the Bohai Sea, 14.1 % in the North Yellow Sea, and 13.9 % in the South Yellow Sea. There are two deposition branches in the Yellow Sea. The primary one is located off the eastern tip of the Shandong Peninsula and extends to the southwest off the coastline, which is consistent with the observed “Ω”-shape deposition pattern. This simulated tongue shape deposition pattern is isolated from the north by the strong resuspension off the eastern tip of Shandong Peninsula. The secondary branch extends to the middle of the South Yellow Sea and has been strengthened by resuspension process. The two deposition branches are separated by the wintertime Yellow Sea Warm Current in the bottom layer.     

Long-term benthic population changes (1920–1930s-present) in the Barents and Kara Seas

Bottom sediment was analysed, via grab, trawl and underwater photography in 1991–1992 in the Barents, White, Kara, Norwegian and Greenland Seas, and the large scale features of macrobenthos distribution are described. The maps of alpha-diversity, biomass and trophic zone distribution on the investigated shelf are presented. Statistical assessment of the bottom community structure changes during the last 60–70 years for the Barents Sea area is presented. It is shown that on regional and transregional levels the researched communities are of natural undisturbed character and that the revealed changes may be both the result of natural processes or sampling errors. Local disturbances of benthos composition and structure, supposedly caused by man, are found to be rare not far from the Novaya Zemlya and Murman coasts.     

A 3-D numerical study of salinity variations in the Bohai Sea during the recent years

Salinity is an important component of the marine system. Previous studies indicated that the mean salinity in the Bohai Sea had increased by 2.0 psu in the second half of the 20th century, mainly due to a sharp decrease in the Yellow River runoff, and also the effects of large-scale climatic variations and the intrusions of the North Yellow Sea Water (NYSW). Since 2002, the Yellow River Conservancy Commission has carried out the flow regulation at the beginning of every flood season, resulting in more discharge of the Yellow River freshwater into the Bohai Sea. In this study, the variations of salinity in the Bohai Sea during the recent years are investigated using a well-established three-dimensional baroclinic model, HAMburg Shelf Ocean Model (HAMSOM). The simulation results show that the Yellow River diluted water was mainly discharged into the Laizhou Bay, so the remarkable increase in the Yellow River runoff after 2002 led to a regime shift of salinity in the Laizhou Bay. However, in other parts of the Bohai Sea, salinity variation was influenced by the surrounding rivers or the intrusions of NYSW, and has little relation with the Yellow River runoff. As a whole, advection is more important than diffusion in the salinity distribution, and seasonal oscillation is the main feature of salinity variation. Via several case studies, evaporation and precipitation rates are found to be important in the long-term simulation of salinity.     

Entrainment of fine-grained surface deposits into new ice in the southwestern Kara Sea,Siberian Arctic

The entrainment of bottom deposits (silt and clay) into newly formed ice was investigated in the Amderma/Vaygach flaw lead in the southwestern Kara Sea, Siberian Arctic. Fine-grained bottom deposits and sea ice sediments (SIS) were analyzed by granulometry, scanning electron microscopy and X-ray diffractometry. On average, SIS contain by a factor of four times more silt than the shelf deposits (66.7% vs. 16.3%), and the SIS clay percentage is more than three-fold of the bottom value (31.2% vs. 9.1%). Sand-sized particles are significantly less abundant in SIS compared to bottom sediment (2.1% vs. 74.6%). The preferred entrainment of silt into ice is underpinned by the enhanced silt-to-clay-ratio in SIS compared to bottom deposits. Though silt is preferably entrained into SIS, no evidence was found for preferential ice-entrainment of any silt sub-fraction (coarse, medium or fine). However, sub-angular- and angular-discoidal silt particles are favorably entrained into local sea ice. Clay mineral assemblages in SIS and shelf surface sediments match very well revealing that no individual clay mineral is preferably enriched in SIS or reduced at the bottom. The general textural, compositional and statistical match of fine-grained shelf surface deposits and SIS proves that bottom sediment is the principle source for ice-entrained material in the study area. We propose e.g. wave action and thermohaline convection to take sediment particles upward from the bottom nepheloid layer into the well-mixed 10–40 m deep water column of the Amderma/Vaygach flaw lead, and the turbulent process of suspension freezing to bring sediment particles and frazil crystals into contact, finally leading to the formation of sediment-laden ice. The role of SIS entrainment and export for local/regional shelf erosion and coastal retreat is of minor importance in the SW Kara Sea compared to other circum-Arctic shelf seas. However, the characteristic clay mineral assemblage of local SIS and bottom deposits can help identify the origin of SIS both on regional and Arctic-wide scales.     

水系的分形特征与红河断裂带活动性关系初探

将分形几何学的原理和方法，应用于红河断裂带中南段断错水系的研究。发现断错水系的分维值变化可以反映当地新构造活动的的变化趋势，中段水系的分维值总体上高于南段，南段内部分维值有一定的变化，反映出断裂带的构造活动性由中段尾部向两头增强的趋势。