An Eocene/Oligocene blueschist‐/greenschist facies P–T loop from the Cycladic Blueschist Unit on Naxos Island,Greece: Deformation‐related re‐equilibration vs. thermal relaxation

Geothermobarometric and geochronological work indicates a complete Eocene/early Oligocene blueschist/greenschist facies metamorphic cycle of the Cycladic Blueschist Unit on Naxos Island in the Aegean Sea region. Using the average pressure–temperature (P–T) method of thermocalc coupled with detailed textural work, we separate an early blueschist facies event at 576 ± 16 to 619 ± 32°C and 15.5 ± 0.5 to 16.3 ± 0.9 kbar from a subsequent greenschist facies overprint at 384 ± 30°C and 3.8 ± 1.1 kbar. Multi‐mineral Rb–Sr isochron dating yields crystallization ages for near peak‐pressure blueschist facies assemblages between 40.5 ± 1.0 and 38.3 ± 0.5 Ma. The greenschist facies overprint commonly did not result in complete resetting of age signatures. Maximum ages for the end of greenschist facies reworking, obtained from disequilibrium patterns, cluster near c. 32 Ma, with one sample showing rejuvenation at c. 27 Ma. We conclude that the high‐P rocks from south Naxos were exhumed to upper mid‐crustal levels in the late Eocene and early Oligocene at rates of 7.4 ± 4.6 km/Ma, completing a full blueschist‐/greenschist facies metamorphic cycle soon after subduction within c. 8 Ma. The greenschist facies overprint of the blueschist facies rocks from south Naxos resulted from rapid exhumation and associated deformation/fluid‐controlled metamorphic re‐equilibration, and is unrelated to the strong high‐T metamorphism associated with the Miocene formation of the Naxos migmatite dome. It follows that the Miocene thermal overprint had no impact on rock textures or Sr isotopic signatures, and that the rocks of south Naxos underwent three metamorphic events, one more than hitherto envisaged.     

Thermomechanics of an extensional shear zone,Raft River metamorphic core complex,NW Utah

A detailed structural and microstructural analysis of the Miocene Raft River detachment shear zone (NW Utah) provides insight into the thermomechanical evolution of the continental crust during extension associated with the exhumation of metamorphic core complexes. Combined microstructural, electron backscattered diffraction, strain, and vorticity analysis of the very well exposed quartzite mylonite show an increase in intensity of the rock fabrics from west to east, along the transport direction, compatible with observed finite strain markers and a model of ``necking'' of the shear zone. Microstructural evidence (quartz microstructures and deformation lamellae) suggests that the detachment shear zone evolved at its peak strength, close to the dislocation creep/exponential creep transition, where meteoric fluids played an important role on strain hardening, embrittlement, and eventually seismic failure.Empirically calibrated paleopiezometers based on quartz recrystallized grain size and deformation lamellae spacing show very similar results, indicate that the shear zone developed under stress ranging from 40 MPa to 60 MPa. Using a quartzite dislocation creep flow law we further estimate that the detachment shear zone quartzite mylonite developed at a strain rates between 10⁻¹² and 10⁻¹⁴ s⁻¹. We suggest that a compressed geothermal gradient across this detachment, which was produced by a combination of ductile shearing, heat advection, and cooling by meteoric fluids, may have triggered mechanical instabilities and strongly influenced the rheology of the detachment shear zone.     

Structures,kinematic analysis,rheological parameters and temperature-pressure estimate of the Mesozoic Xingcheng-Taili ductile shear zone in the North China Craton

The NE to ENE trending Mesozoic Xingcheng-Taili ductile shear zone of the northeastern North China Craton was shaped by three phases of deformation. Deformation phase D₁ is characterized by a steep, generally E–W striking gneissosity. It was then overprinted by deformation phase D₂ with NE-sinistral shear with K-feldspar porphyroclasts forming a subhorizontal low-angle stretching lineation on a steep foliation. During deformation phase D₃, lateral motion accommodated by ENE sinistral strike-slip shear zones dominated. Associated fabrics developed at upper greenschist metamorphic facies conditions and show the deformation characteristics of middle- to shallow crustal levels. In some parts, the older structures have been in turn overprinted by late-stage sinistral D₃ shearing. Finite strain and kinematic vorticity in all deformed granitic rocks indicate a prolate ellipsoid (L-S tectonites) near plane strain. Simple shear-dominated general shear during D₃ deformation is probably of general significance. The quartz c-axis textures indicate prism-gliding with a dominant rhomb <a> slip and basal <a> slip system formed mainly at low-middle temperatures. Mineral deformation behavior, quartz c-axis textures, quartz grain size and the Kruhl thermometer demonstrate that the ductile shear zone developed under greenschist facies metamorphic conditions at deformation temperatures ranging from 400 to 500 °C. Dislocation creep is the main deformation mechanism at a shallow crustal level. Fractal analysis showed that the boundaries of recrystallized quartz grains had statistically self-similarities. Differential stresses deduced from dynamically recrystallized quartz grain size are at around 20–39 MPa, and strain rates in the order of 10⁻¹² to 10⁻¹⁴ s⁻¹. This indicates deformation of granitic rocks in the Xingcheng-Taili ductile shear zone at low strain rates, which is consistent with most other ductile shear zones. Hornblende-plagioclase thermometer and white mica barometer indicate metamorphic conditions of medium pressures at around ca. 3–5 kbar and temperatures of 400–500 °C within greenschist facies conditions. The main D₃ deformation of the ENE-trending sinistral strike-slip ductile shearing is related to the roll-back of the subducting Pacific plate beneath the North China Craton.     

Deformation condition determination and strain analysis: Application of microstructural and microthermometry study of the Zamanabad Shear Zone (East of Iran)

Microstructural analysis and microthermometry are useful methods for determining the deformation evolution. To address this issue, rheological behavior of quartz, feldspar and calcite in veins and host rocks during deformation, are presented in the mylonite zone of the dextral reverse Zamanabad Shear Zone (ZSZ), in northern part of Sistan Suture Zone (SSZ), in east of Iran. Microstructure evidences revealed two evolution stages of high and low temperature deformation. Quartz microstructures in the ZSZ show abundant evidences for early high-temperature plastic deformation (e.g. Bulging recrystallization (BLG)) which are as microstructures with SW directed ductile shearing in the central parts of the ZSZ. This shear zone shows progressively decreasing strain away from the central of shear zone toward the wall. High-temperature microstructures are overprinted partly or completely during shearing by the later low-temperature deformation (e.g. Pressure solution, fractures, veinlets). Microstructural observations of veins (quartz and calcite) confirms the results of microstructures in the host rock, as quartz veins occurred from peak metamorphic conditions (<400°C) and then in lower P–T conditions have been formed calcite veins (~250°C). According to microthermometric studies, two primary fluid groups are observed in quartz veins: (1) fluids trapped during peak deformation conditions, with higher-salinity, They were initially trapped at ~300–400°C, (2) smaller fluids by trapping of low-salinity inclusions at ~240–180°C that related to subsequent phases of shear zone exhumation in lower deep. Microthermometry results and microstructural analysis indicate deformation under lower greenschist facies conditions for the ZSZ, and then exhumation of the early of high-temperature rocks within regime of ductile-brittle transition to brittle.     

The Plankogel detachment of the Eastern Alps: petrological evidence for an orogen‐scale extraction fault

The so‐called Plankogel detachment is an east‐west trending, south‐dipping low‐angle structure that juxtaposes the high‐P rocks of the eclogite type locality of the eastern European Alps against amphibolite facies rocks to the south. It occurs in both the Saualpe and Koralpe Complex in eastern Austria. During Cretaceous intracontinental subduction, the footwall and the hangingwall units of the Plankogel detachment were buried to different crustal levels as inferred by pseudosection modelling and conventional thermobarometry: ~23–24 kbar and 640–690 °C for the eclogite facies units in the footwall of the detachment and ~12–14 kbar and 550–580 °C for the amphibolite facies metapelites in the hangingwall. Despite the different peak metamorphic conditions, both sides of the detachment display a common overprint at conditions of ~10 kbar and 580–650 °C. From this, we infer a two‐stage exhumation process and suggest that this two‐stage process is best interpreted tectonically in terms of slab extraction during Eoalpine subduction. The first stage of exhumation occurred due to the downward (southward) extraction of a lithospheric slab that was localized in the trace of the Plankogel detachment. The later stage, however, is attributed to more regional erosion‐ or extension‐driven processes. Since the Plankogel detachment is geometrically related to a crustal‐scale shear zone further north (the Plattengneiss shear zone), we suggest that both structures are part of the same extraction fault system along which the syn‐collisional exhumation of the Eoalpine high‐P units of the Eastern Alps occurred. The suggested model is consistent with both the mylonitic texture of the Plattengneiss shear zone and the overall ambiguous shear sense indicators present in the entire region.     

Recrystallisation,phase mixing and strain localisation in peridotite during rapid extrusion of sub-arc mantle lithosphere

The Anita Peridotite, in southwestern New Zealand, is a ∼1 × 20 km ultramafic massif that was rapidly extruded from beneath a Cretaceous arc within the 4 km wide mylonitic Anita Shear Zone. The peridotitic body contains a spectacular array of textures that preserve evidence for changing temperature, stress, and deformation mechanisms during the exhumation process. Olivine and orthopyroxene microstructures and lattice-preferred orientations (LPO) record a three-phase deformation history. Dislocation glide on the C- and E-type slip systems is recorded by coarse pre-mylonitised olivine grains, and occurred under hydrous conditions at T ∼650 °C, stress ∼200–700 MPa and strain rate ∼10⁻¹⁵ s⁻¹, probably within hydrated sub-arc mantle lithosphere. Rare protomylonite pods record deformation by dislocation creep in porphyroclasts and dislocation-accommodated grain boundary sliding in the matrix on {0kl}[100] in olivine and (100)[001] in orthopyroxene, under conditions of T ∼730–770 °C, stress ∼52–700 MPa and strain rate ∼10⁻¹⁵ s⁻¹. The massif, however, is dominated by mylonite and ultramylonite that wrap the protomylonite pods, comprising mostly fine-grained olivine neoblasts that lack internal distortions and have uniform LPOs. These textures indicate deformation occurred by grain-size sensitive (GSS) creep at T ∼650 °C, stress ∼69–137 MPa and strain rate ∼10⁻¹⁵ s⁻¹, and thus during conditions of cooling and decreasing stress. GSS creep became more dominant with time, as the proportion of randomly-oriented neoblasts increased and formed interlinked networks that accommodated much of the strain. Grain boundary pinning allowed GSS creep to be maintained in polyphase regions, following mixing of olivine and orthopyroxene, which may have occurred by grain boundary transport in a fluid phase during a “creep cavitation” process. The results indicate that the Anita Peridotite recrystallised and underwent rheological weakening at a constant strain rate, with strain distributed across the entire section. This widespread deformation caused rapid exhumation of the peridotite from the lithospheric mantle into the overlying arc crust. The massif therefore records multiple overprinting phases of deformation under mantle and crustal conditions associated with the rapid exhumation of a large orogenic peridotite.     

Geothermobarometry in metasediments of the southern Grossvenediger area (Tauern Window, Austria)

Metasediments in the southern Grossvenediger area (Tauern Window, Austria) were studied along a cross-section through rocks of increasing metamorphic grade from the margin of the Tauern Window in the south to the base of the Upper Schieferhülle, including the Eclogite Zone, in the north. In the southern part of the cross-section there is no evidence for a pre-late Alpine metamorphic history in the form of high-pressure relics or pseudomorphs. Mineral assemblages are characterized by the stability of tremolite + calcite, biotite + calcite and biotite + chlorite + calcite. In the northern part a more complete Alpine metamorphic evolution is preserved. Primary high-pressure assemblages are dolomite + quartz, tremolite + zoisite, zoisite + dolomite + quartz + phengite I and probably tremolite + dolomite + phengite I. Secondary, post-kinematic assemblages [tremolite + calcite, talc + calcite, phengite II + chlorite + calcite (+ quartz), biotite + chlorite + calcite, biotite + zoisite + calcite] formed as a result of the dominant late Alpine metamorphic overprint. The occurrence of biotite + zoisite + calcite is confined to the northernmost area and defines a biotite–zoisite–calcite isograd. P–T estimates based on standard thermobarometric techniques and on stability relationships of tremolite + calcite + dolomite + quartz and zoisite give consistent results. P–T conditions of the main Tertiary metamorphic overprint were 525° C, P= 7.5 ± 1 kbar in the northern part of the cross-section. The southern part was metamorphosed at lower temperatures of 430–470° C. The Si-content of phengites from this area is almost as high as that of phengites from the Eclogite Zone (Si^max= 3.4 pfu). Pressures > 10 kbar at 420° C are suggested by phengite barometry according to Massone & Schreyer (1987). In the absence of high-pressure relics or pseudomorphs, these phengites, which lack late Alpine re-equilibration, are the only record that rocks of the southern part probably also experienced an early non-eclogitic high-pressure metamorphism.     

Relative timing of deformation and two-stage gold mineralization at the Hutti Mine, Dharwar Craton, India

Gold mineralization at Hutti is confined to a series of nine parallel, N–S to NNW–SSE trending, steeply dipping shear zones. The host rocks are amphibolites and meta-rhyolites metamorphosed at peak conditions of 660±40°C and 4±1 kbar. They are weakly foliated (S₁) and contain barren quartz extension veins. The auriferous shear zones (reefs) are typically characterized by four alteration assemblages and laminated quartz veins, which, in places, occupy the entire reef width of 2–10 m, and contain the bulk of gold mineralization. A <1.5 m wide distal chlorite-sericite (+biotite, calcite, plagioclase) alteration zone can be distinguished from a 3–5 m wide proximal biotite-plagioclase (+quartz, muscovite, calcite) alteration zone. Gold is both spatially and temporally associated with disseminated arsenopyrite and pyrite mineralization. An inner chlorite-K-feldspar (+quartz, calcite, scheelite, tourmaline, sphene, epidote, sericite) alteration halo, which rims the laminated quartz veins, is characterized by a pyrrhotite, chalcopyrite, sphalerite, ilmenite, rutile, and gold paragenesis. The distal chlorite-sericite and proximal biotite-plagioclase alteration assemblages are developed in microlithons of the S₂–S₃ crenulation cleavage and are replaced along S₃ by the inner chlorite-K-feldspar alteration, indicating a two-stage evolution for gold mineralization. Ductile D₂ shearing, alteration, and gold mineralization formed the reefs during retrograde evolution and fluid infiltration under upper greenschist to lower amphibolite facies conditions (560±60°C, 2±1 kbar). The reefs were reactivated in the D₃ dextral strike-slip to oblique-slip environment by fault-valve behavior at lower greenschist facies conditions (ca. 300–350°C), which formed the auriferous laminated quartz veins. Later D₄ crosscutting veins and D₅ faults overprint the gold mineralization. The alteration mineralogy and the structural control of the deposit clearly points to an orogenic style of gold mineralization, which took place either during isobaric cooling or at different levels of the Archean crust. From overlaps in the tectono-metamorphic history, it is concluded that gold mineralization occurred during two tectonic events, affecting the eastern Dharwar craton in south India between ca. 2550 – 2530 Ma: (1) The assemblage of various terranes of the eastern block, and (2) a tectono-magmatic event, which caused late- to posttectonic plutonism and a thermal perturbation. It differs, however, from the pre-peak metamorphic gold mineralization at Kolar and the single-stage mineralization at Ramagiri. Notably, greenschist facies gold mineralization occurred at Hutti 35–90 million years later than in the western Dharwar craton. Editorial handling: G. Beaudoin     

Hydrothermal alteration and ore-forming fluids associated with gold-tellurium mineralization in the Dongping gold deposit,China

The Dongping gold deposit hosted in syenites is one of the largest hydrothermal gold deposits in China and composed of ore veins in the upper parts and altered zones in the lower parts of the ore bodies. Pervasive potassic alteration and silicification overprint the wall rocks of the ore deposit. The alteration minerals include orthoclase, microcline, perthite, quartz, sericite, epidote, calcite, hematite and pyrite, with the quartz, pyrite and hematite assemblages closely associated with gold mineralization. The phases of hydrothermal alteration include: (i) potassic alteration, (ii) potassic alteration - silicification, (iii) silicification - epidotization - hematitization, (iv) silicification - sericitization - pyritization and (v) carbonation. Mass-balance calculations in potassic altered and silicified rocks reveal the gain of K₂O, Na₂O, SiO₂, HFSEs and transition elements (TEs) and the loss of REEs. Most major elements were affected by intense mineral reactions, and the REE patterns of the ore are consistent with those of the syenites. Gold, silver and tellurium show positive correlation and close association with silicification. Fluid inclusion homogenization temperatures in quartz veins range from 154 °C to 382 °C (peak at 275 °C–325 °C), with salinities of 4–9 wt.% NaCl equiv. At temperatures of 325 °C the fluid is estimated to have pH = 3.70–5.86, log fO₂ = − 32.4 to − 28.1, with Au and Te transported as Au (HS)₂⁻ and Te₂^2 − complexes. The ore forming fluids evolved from high pH and fO₂ at moderate temperatures into moderate-low pH, low fO₂ and low temperature conditions. The fineness of the precipitated native gold and the contents of the oxide minerals (e.g., magnetite and hematite) decreased, followed by precipitation of Au- and Ag-bearing tellurides. The hydrothermal system was derived from an alkaline magma and the deposit is defined as an alkaline rock-hosted hydrothermal gold deposit.     

40Ar/39Ar and oxygen isotope studies of polymetamorphism from Tinos Island, Cycladic blueschist belt, Greece

Abstract Petrological, oxygen isotope and ⁴⁰Ar/³⁹Ar studies were used to constrain the Tertiary metamorphic evolution of the lower tectonic unit of the Cyclades on Tinos. Polyphase high-pressure metamorphism reached pressures in excess of 15 kbar, based on measurements of the Si content in potassic white mica. Temperatures of 450–500° C at the thermal peak of high-pressure metamorphism were estimated from critical metamorphic assemblages, the validity of which is confirmed by a quartz–magnetite oxygen isotope temperature of 470° C. Some ⁴⁰Ar/³⁹Ar spectra of white mica give plateau ages of 44–40 Ma that are considered to represent dynamic recrystallization under peak or slightly post-peak high-pressure metamorphic conditions. Early stages in the prograde high-pressure evolution may be documented by older apparent ages in the high-temperature steps of some spectra. Eclogite to epidote blueschist facies mineralogies were partially or totally replaced by retrograde greenschist facies assemblages during exhumation. Oxygen isotope thermometry of four quartz–magnetite pairs from greenschist samples gives temperatures of 440–470° C which cannot be distinguished from those deduced for the high-pressure event. The exhumation and overprint is documented by decreasing ages of 32–28 Ma in some greenschists and late-stage blueschist rocks, and ages of 30–20 Ma in the lower temperature steps of the Ar release patterns of blueschist micas. Almost flat parts of Ar–Ar release spectra of some greenschist micas gave ages of 23–21 Ma which are assumed to represent incomplete resetting caused by a renewed prograde phase of greenschist metamorphism. Oxygen isotope compositions of blueschist and greenschist facies minerals show no evidence for the infiltration of a δ¹⁸O-enriched fluid. Rather, the compositions indicate that fluid to rock ratios were very low, the isotopic compositions being primarily controlled by those of the protolith rocks. We assume that the fundamental control catalysing the transformation of blueschists into greenschists and the associated resetting of their isotopic systems was the selective infiltration of metamorphic fluid. A quartz–magnetite sample from a contact metamorphic skarn, taken near the Miocene monzogranite of Tinos, gave an oxygen isotope temperature of 555° C and calculated water composition of 9.1%. The value of δ¹⁸O obtained from this water is consistent with a primary magmatic fluid, but is lower than that of fluids associated with the greenschist overprint, which indicates that the latter event cannot be directly related to the monozogranite intrusion.     

Tectonic evolution of Proterozoic rocks in the Cimarron Mountains, northern New Mexico, USA

Abstract Portions of three Proterozoic tectonostratigraphic sequences are exposed in the Cimarron Mountains of New Mexico. The Cimarron River tectonic unit has affinities to a convergent margin plutonic/volcanic complex. Igneous hornblende from a quartz diorite stock records an emplacement pressure of 2–2.6 kbar. Rocks within this unit were subsequently deformed during a greenschist facies regional metamorphism at 4–5 kbar and 330 ± 50° C. The Tolby Meadow tectonic unit consists of quartzite and schist. Mineral assemblages are indicative of regional metamorphism at pressures near 4 kbar and temperatures of 520 ± 20° C. A low-angle ductile shear zone separates this succession from gneisses of the structurally underlying Eagle Nest tectonic unit. Gneissic granite yields hornblende pressures of 6–8 kbar. Pelitic gneiss records regional metamorphic conditions of 6–7 kbar and 705 ± 15° C, overprinted by retrogression at 4 kbar and 530 ± 10° C. Comparison of metamorphic and retrograde conditions indicates a P–T path dominated by decompression and cooling. The low-angle ductile shear zone represents an extensional structure which was active during metamorphism. This extension juxtaposed the Tolby Meadow and Eagle Nest units at 4 kbar and 520° C. Both units were later overprinted by folding and low-grade metamorphism, and then were emplaced against the Cimarron River tectonic unit by right-slip movement along the steeply dipping Fowler Pass shear zone. An argon isotope-correlation age obtained from igneous hornblende dates plutonism in the Cimarron River unit at 1678 Ma. Muscovite associated with the greenschist facies metamorphic overprint yields a ⁴⁰ Ar/³⁹ Ar plateau age of 1350 Ma. By contrast, rocks within the Tolby Meadow and Eagle Nest units yield significantly younger argon cooling ages. Hornblende isotope-correlation ages of 1394–1398 Ma are interpreted to date cooling during middle Proterozoic extension. Muscovite plateau ages of 1267–1257 Ma appear to date cooling from the low-grade metamorphic overprint. The latest ductile movement along the Fowler Pass shear zone post-dated these cooling ages. Argon released from muscovites of the Eagle Nest/Tolby Meadow composite unit, at low experimental temperatures, yields apparent ages of c. 1100 Ma. Similar ages are not obtained north-east of the Fowler Pass shear zone, suggesting movement more recently than 1100 Ma.     

Late Cretaceous exhumation history of an extensional extruding wedge (Graz Paleozoic Nappe Complex, Austria)

Late Cretaceous structures within the eastern Graz Paleozoic Nappe Complex define an extruding wedge with north-eastward directed thrusting in eastern portions and strike-slip shear along the margins. Stacking structures are overprinted by south-westward directed extension with low-grade metamorphic rocks in the hangingwall and high-grade basement rocks in the footwall. Pressure–temperature and structural data are obtained from successively opening quartz veins that record various stages of progressive deformation and metamorphism. Fluid inclusion data and related structures show that during extension isothermal decompression from ca. 550°C and 8 kbar down to ca. 450°C and 2 kbar was related to exhumation of rocks from deep crustal levels. The data point to a high geothermal gradient and explain condensed paleo-isotherms due to ductile normal faulting in the eastern areas of the Graz Paleozoic Nappe Complex. The investigated Late Cretaceous structural elements suggest that the Graz Paleozoic Nappe Complex decoupled from the surrounding basement units and operated as a large-scale extension–extrusion corridor that evolved prior to Miocene extrusion tectonics in the Eastern Alps.     

Vorticity analysis in calcite tectonites: An example from the Attico-Cycladic massif (Attica,Greece)

Although calcite tectonites are widespread in nature their use to quantify flow vorticity is limited. We use new (micro-)structural, petrofabric and vorticity data to analyse the kinematics of flow in outcrop-scale calcite mylonite zones. These zones are genetically related to a crustal-scale NE-directed ductile thrust (Basal Thrust) that emplaced the Blueschist over the Basal unit during the exhumation of the Attico-Cycladic Massif. Calcite microstructures reveal that the last stage of deformation occurred at temperatures 200–300 °C achieved by mild heating, which is possibly related with the reburial of the Basal Thrust's footwall. Vorticity analyses were based on the degree of asymmetry of calcite c-axis fabrics as well as on the assumption that the orientation of the long axes of calcite neoblasts within an oblique foliation delineates the direction of instantaneous stretching axis. Both methodological approaches provide consistent estimates with a simple shear component between 55% and 82% (W_n = 0.76–0.96). The use of the stress axis (σ₁) orientation recorded by twin-c-axis-pairs to quantify vorticity generally gives significantly lower simple shear component. Comparison of our vorticity estimates with previous estimates inferred from quartz fabrics and rigid porphyroclasts reveals that exhumation-related deformation in the nappe pile was steady state.     

Late‐stage orogenic loading revealed by contact metamorphism in the northern Appalachians,New York

Pelitic schists from contact aureoles surrounding mafic–ultramafic plutons in Westchester County, NY record a high‐P (~0.8 GPa) high‐T (~790 °C) contact overprint on a Taconic regional metamorphic assemblage (~0.5 GPa). The contact metamorphic assemblage of a pelitic sample in the innermost aureole of the Croton Falls pluton, a small (<10 km²) gabbroic body, consists of quartz–plagioclase–biotite–garnet–sillimanite–ilmenite–graphite–Zn‐rich Al‐spinel. Both K‐feldspar and muscovite are absent, and abundant biotite, plagioclase, sillimanite, quartz and ilmenite inclusions are found within subhedral garnet crystals. Unusually low bulk‐rock Na and K contents imply depletion of alkalic components and silica through anatexis and melt extraction during contact heating relative to typical metapelites outside the aureole. Thermobarometry on nearby samples lacking a contact overprint yields 620–640 °C and 0.5–0.6 GPa. In the aureole sample, WDS X‐ray chemical maps show distinct Ca‐enriched rims on both garnet and matrix plagioclase. Furthermore, biotite inclusions within garnet have significantly higher Mg concentration than matrix biotite. Thermobarometry using GASP and garnet–biotite Mg–Fe exchange equilibria on inclusions and adjacent garnet host interior to the high‐Ca rim zone yield ~0.5 ± 0.1 GPa and ~620 ± 50 °C. Pairs in the modified garnet rim zone yield ~0.9 ± 0.1 GPa and ~790 ± 50 °C. Thermocalc average P–T calculations yield similar results for core (~0.5 ± ~0.1 GPa, ~640 ± ~80 °C) and rim (~0.9 ± ~0.1 GPa, ~800 ± ~90 °C) equilibria. The core assemblages are interpreted to record the P–T conditions of peak metamorphism during the Taconic regional event whereas the rim compositions and matrix assemblages are interpreted to record the P–T conditions during the contact event. The high pressures deduced for this later event are interpreted to reflect loading due to the emplacement of Taconic allochthons in the northern Appalachians during the waning stages of regional metamorphism (after c. 465 Ma) and before contact metamorphism (c. 435 Ma). In the absence of contact metamorphism‐induced recrystallization, it is likely that this regional‐scale loading would remain cryptic or unrecorded.     

The Arinem Te‐Bearing Gold‐Silver‐Base Metal Deposit,West Java,Indonesia

The vein system in the Arinem area is a gold‐silver‐base metal deposit of Late Miocene (8.8–9.4 Ma) age located in the southwestern part of Java Island, Indonesia. The mineralization in the area is represented by the Arinem vein with a total length of about 5900 m, with a vertical extent up to 575 m, with other associated veins such as Bantarhuni and Halimun. The Arinem vein is hosted by andesitic tuff, breccia, and lava of the Oligocene–Middle Miocene Jampang Formation (23–11.6 Ma) and overlain unconformably by Pliocene–Pleistocene volcanic rocks composed of andesitic‐basaltic tuff, tuff breccia and lavas. The inferred reserve is approximately 2 million tons at 5.7 g t^?1 gold and 41.5 g t^?1 silver at a cut‐off of 4 g t^?1 Au, which equates to approximately 12.5t of Au and 91.4t of Ag. The ore mineral assemblage of the Arinem vein consists of sphalerite, galena, chalcopyrite, pyrite, marcasite, and arsenopyrite with small amounts of pyrrhotite, argentite, electrum, bornite, hessite, tetradymite, altaite, petzite, stutzite, hematite, enargite, tennantite, chalcocite, and covellite. These ore minerals occur in quartz with colloform, crustiform, comb, vuggy, massive, brecciated, bladed and calcedonic textures and sulfide veins. A pervasive quartz–illite–pyrite alteration zone encloses the quartz and sulfide veins and is associated with veinlets of quartz–calcite–pyrite. This alteration zone is enveloped by smectite–illite–kaolinite–quartz–pyrite alteration, which grades into a chlorite–smectite–kaolinite–calcite–pyrite zone. Early stage mineralization (stage I) of vuggy–massive–banded crystalline quartz‐sulfide was followed by middle stage (stage II) of banded–brecciated–massive sulfide‐quartz and then by last stage (stage III) of massive‐crystalline barren quartz. The temperature of the mineralization, estimated from fluid inclusion microthermometry in quartz ranges from 157 to 325°C, whereas the temperatures indicated by fluid inclusions from sphalerite and calcite range from 153 to 218 and 140 to 217°C, respectively. The mineralizing fluid is dilute, with a salinity <4.3 wt% NaCl equiv. The ore‐mineral assemblage and paragenesis of the Arinem vein is characteristically of a low sulfidation epithermal system with indication of high sulfidation overprinted at stage II. Boiling is probably the main control for the gold solubility and precipitation of gold occurred during cooling in stage I mineralization.     

P–T evolution and tectonic significance of lawsonite-bearing schists from the eastern segment of the southwestern Tianshan,China

Robust quantification of pressure (P)–temperature (T) paths for subduction-related HP/UHP metamorphic rocks is fundamental in recognizing spatial changes in both the depth of detachment from the down-going plate and the thermal evolution of convergent margin sutures in orogenic belts. Although the Chinese southwestern (SW) Tianshan is a well-known example of an accretionary metamorphic belt in which HP/UHP metabasites occur in voluminous host metasedimentary schists, information about the P–T evolution of these rocks in the eastern segment is limited, precluding a full understanding of the development of the belt as a whole. In this study at Kekesu in the eastern segment of the SW Tianshan, we use microstructural evidence and phase equilibrium modelling to quantify the peak and retrograde P–T conditions from two lawsonite-bearing micaschists and an enclosed garnet–epidote blueschist; for two of the samples we also constrain the late prograde P–T path. In the two micaschist samples, relics of prograde lawsonite are preserved in quartz inclusions in garnet, whereas in the metabasite, polymineralic aggregates included in garnet are interpreted as pseudomorphs after lawsonite. For garnet micaschist TK21, which is mainly composed of garnet, phengite/paragonite, albite, chlorite, quartz and relict lawsonite, with accessary rutile, titanite and ilmenite, the maximum P–T conditions for the peak stage are 18.0–19.0 kbar at 480–485°C. During initial exhumation, the retrograde P–T path passed through metamorphic conditions of 15.0–17.0 kbar at 460–500°C. For garnet–glaucophane micaschist TK33, which is mainly composed of garnet, glaucophane, phengite/paragonite, albite, chlorite, quartz, relict lawsonite and minor epidote, with accessary titanite, apatite, ilmenite and zircon, the maximum P conditions for the peak stage are >24.0 kbar at 400–500°C. During exhumation, the P–T path passed through metamorphic conditions of 17.5–18.5 kbar at 485–495°C and 14.0–17.5 kbar at 460–500°C. For garnet–epidote blueschist TK37, which is mainly composed of garnet, glaucophane, epidote, phengite, chlorite, albite and quartz, with accessary titanite, apatite, ilmenite, zircon and calcite, the prograde evolution passed through metamorphic conditions of ~20.0 kbar at ~445°C to P_max conditions of ~21.5 kbar at 450–460°C and T_max conditions of 19.5–21.0 kbar at 490–520°C. During exhumation, the rock passed through metamorphic conditions of 17.5–19.0 kbar at 475–500°C, before recording P–T conditions of <17.5 kbar at <500°C. These results demonstrate that maximum recorded pressures for individual samples vary by as much as 6 kbar in the eastern segment of the SW Tianshan, which may suggest exhumation from different depths in the subduction channel. Furthermore, the three samples record similar P–T paths from ~17.0 to 15.0 kbar, which suggests they were juxtaposed at a similar depth along the subduction interface. We compare our new results with published information from eclogites in the same area before considering the wider implications of these data for the orogenic development of the belt as a whole.     

Evidence for shear heating,Musgrave Block,central Australia

The phenomenon of shear-heating is generally difficult to recognise from petrologic evidence alone. Establishing that shear zones attain higher temperatures than the surrounding country rocks requires independent evidence for temperature gradients. In the Musgrave Block, central Australia, there is a clear spatial association between shear zones and interpreted elevated temperatures. Eclogite facies shear zones that formed at ∼550 Ma record temperatures of ∼650–700°C. Outside the high-pressure shear zones, minerals with low closure temperatures such as biotite (∼450°C in the ⁴⁰Ar–³⁹Ar and Rb–Sr systems), preserve ages >800 Ma, suggesting that these rocks did not experience temperatures greater than about 450°C at ∼550 Ma for any extended period. Thus, the shear zones record temperatures that are ∼200°C higher than the surrounding country rocks. Simple calculations show that the combination of relatively high shear stresses (∼100 MPa) and high strain rates (∼10⁻¹¹ s⁻¹) for short durations (<1 Ma) can account for the observed apparent temperature variations. The evidence indicates that shear heating is the dominant mechanism for localised temperature increases in the shear zones, while the country rock remained at relatively lower temperatures.     

Pressure–temperature evolution of blueschist facies rocks from Sifnos, Greece, and implications for the exhumation of high-pressure rocks in the Central Aegean

The blueschist and greenschist units on the island of Sifnos, Cyclades were affected by Eocene high‐pressure (HP) metamorphism. Using conventional geothermobarometry, the HP peak metamorphic stage was determined at 550–600 °C and 20 kbar, close to the blueschist and the eclogite facies transition. The retrograde P–T paths are inferred with phase diagrams. Pseudosections based on a quantitative petrogenetic grid in the model system Na₂O–CaO–FeO–MgO–Al₂O₃–SiO₂–H₂O reveal coeval decompression and cooling for both the blueschist and the greenschist unit. The conditions of the metamorphic peak and those of the retrograde stages conform to a similar metamorphic gradient of 10–12 °C km^?1 for both units. The retrograde overprint can be assigned to low‐pressure blueschist to HP greenschist facies conditions. This result cannot be reconciled with the (prograde) Barrovian‐type event, which affected parts of the Cyclades during the Oligocene to Miocene. Instead, the retrograde overprint is interpreted in terms of exhumation, directly after the HP stage, without a separate metamorphic event. Constraints on the exhumation mechanism are given by decompression‐cooling paths, which can be explained by exhumation in a fore‐arc setting during on‐going subduction and associated crustal shortening. Back‐arc extension is only responsible for the final stage of exhumation of the HP units.     

Mylonitization in the lower plate of the Buckskin-Rawhide detachment fault,west-central Arizona: Implications for the geometric evolution of metamorphic core complexes

In metamorphic core complexes it is commonly unclear whether lower plate mylonites formed as the down-dip continuation of a detachment fault, or whether they represent a subhorizontal shear zone that was captured by a more steeply dipping detachment fault. Detailed microstructural, fabric, and strain data from mylonites in the Buckskin-Rawhide metamorphic core complex, west-central Arizona, constrain the structural development of the lower plate shear zone. Widespread exposures of ∼22–21 Ma granitoids of the Swansea Plutonic Suite enable us to separate Miocene strain coeval with core complex extension from older deformation. Mylonites across the lower plate consistently record top-to-the-NE-directed shear. Miocene quartz and feldspar deformation/recrystallization mechanisms indicate ∼450–500 °C mylonitization temperatures that were relatively uniform across a distance of ∼35 km in the extension direction. Quartz dynamically recrystallized grain sizes do not systematically vary in the extension direction. Strain recorded in the Swansea Plutonic Suite is also relatively uniform in the extension direction, which is incompatible with models in which lower plate mylonites form as the ductile root of a major detachment fault. Altogether these data suggest the mylonitic shear zone initiated with a ≤4° dip and was unroofed by a more steeply dipping detachment fault system. Lower plate mylonites in the Buckskin-Rawhide metamorphic core complex thus represent a captured subhorizontal shear zone rather than the down-dip continuation of a detachment fault.     

The mechanical and microstructural behaviour of calcite-dolomite composites: An experimental investigation

The styles and mechanisms of deformation associated with many variably dolomitized limestone shear systems are strongly controlled by strain partitioning between dolomite and calcite. Here, we present experimental results from the deformation of four composite materials designed to address the role of dolomite on the strength of limestone. Composites were synthesized by hot isostatic pressing mixtures of dolomite (Dm) and calcite powders (% Dm: 25%-Dm, 35%-Dm, 51%-Dm, and 75%-Dm). In all composites, calcite is finer grained than dolomite. The synthesized materials were deformed in torsion at constant strain rate (3 × 10⁻⁴ and 1 × 10⁻⁴ s⁻¹), high effective pressure (262 MPa), and high temperature (750 °C) to variable finite shear strains. Mechanical data show an increase in yield strength with increasing dolomite content. Composites with <75% dolomite (the remaining being calcite), accommodate significant shear strain at much lower shear stresses than pure dolomite but have significantly higher yield strengths than anticipated for 100% calcite. The microstructure of the fine-grained calcite suggests grain boundary sliding, accommodated by diffusion creep and dislocation glide. At low dolomite concentrations (i.e. 25%), the presence of coarse-grained dolomite in a micritic calcite matrix has a profound effect on the strength of composite materials as dolomite grains inhibit the superplastic flow of calcite aggregates. In high (>50%) dolomite content samples, the addition of 25% fine-grained calcite significantly weakens dolomite, such that strain can be partially localized along narrow ribbons of fine-grained calcite. Deformation of dolomite grains by shear fracture is observed; there is no intracrystalline deformation in dolomite irrespective of its relative abundance and finite shear strain.