Geochronology and geochemistry of Palaeozoic intrusive rocks in the Rockvale region,southern New England Orogen,New South Wales

Palaeozoic intrusive rocks of the New England Batholith from the Rockvale district in the southern New England Orogen form three distinct associations: (i) the Carboniferous Rockvale Adamellite, a member of the Hillgrove Suite of deformed S‐type granitoids; (ii) a small I‐type igneous complex on the northwestern margin of the Rockvale Adamellite: several members of this complex have similar chemical compositions to the most mafic members of the Moonbi Suite of New England Batholith I‐types; and (iii) a suite of dyke rocks ranging in composition from calc‐alkaline lamprophyre through hornblende and biotite porphyrite to aplite. Ion‐microprobe U‐Pb zircon analysis indicates intrusion of the Rockvale Adamellite at 303 ±3 Ma (weighted mean ²⁰⁶Pb/²³⁸U age; 95% confidence limits). Preliminary investigation of zircon inheritance within the Rockvale Adamellite is consistent with chemical and isotopic indications of derivation of New England Batholith S‐type granitoids from a relatively juvenile protolith. Deformation of the Rockvale Adamellite occurred after complete crystallization of the pluton and prior to emplacement of dykes and I‐type intrusives. K‐Ar biotite and hornblende ages show broadly synchronous intrusion of I‐type magmas and lamprophyre dykes at ca 255 Ma, indicating that mantle magmatism associated with lamprophyres was contemporaneous with the crustal production of I‐type melts. Chemical similarities between the most mafic Moonbi Suite members and calc‐alkaline lamprophyres may also indicate a direct mantle contribution to some I‐type magmas.     

Timing of emplacement and deformation of the Tia Granodiorite,southern New England Fold Belt,NSW: Implications for the metamorphic history

The Tia Granodiorite, a Hillgrove Suite pluton in the southern New England Fold Belt, intruded complexly deformed metasediment and metabasite belonging to the Tia Complex, which at the time of intrusion had already been affected by two deformation events at low‐T moderate‐P metamorphic conditions and two overprinting deformation events at high‐T low‐P metamorphic conditions. Emplacement took place during D₅ thrusting associated with limited uplift as low‐P amphibolite facies metamorphism prevailed. Large‐scale warping during D₆ was followed by a second penetrative thrusting event (D₇) that caused further uplift and was initiated under lower amphibolite facies conditions.

The granodiorite has been dated at ～ 300 Ma using magmatic zircon, an age which is thought to approximate the emplacement age and thus D₅. Biotite grains associated with D₇ uplift yield a Rb/Sr age of 264±1.3 Ma. D₅ and D₇ appear to have formed during one extended high‐T metamorphic event because intervening retrogression is lacking in spite of extensive hydrous fluxing, as indicated by numerous syn‐D₆ quartz veins. This thermal event coincided with the opening of the extensional Permian basins.     

Structural fabric evidence for indentation tectonics in the Nambucca Block,southern New England Fold Belt,New South Wales

Structural studies of Lower Permian sequences exposed on wave‐cut platforms within the Nambucca Block, indicate that one to two ductile and two to three brittle — ductile/brittle events are recorded in the lower grade (sub‐greenschist facies) rocks; evidence for four, possibly five, ductile and at least three brittle — ductile/brittle events occurs in the higher grade (greenschist facies) rocks. Veins formed prior to the second ductile event are present in some outcrops. Further, the studies reveal a change in fold style from west‐southwest‐trending, open, south‐southeast‐verging, inclined folds (F₁ ⁰) at Grassy Head in the south, to east‐northeast‐trending, recumbent, isoclinal folds (F₁ ⁰; F₂ ⁰) at Nambucca Heads to the north, suggesting that strain increases towards the Coffs Harbour Block. A solution cleavage formed during D₁ in the lower grade rocks and cleavages defined by neocrystalline white mica developed during D₁ and D₂ in the higher grade rocks. South‐ to south‐southwest‐directed tectonic transport and north‐south shortening operated during these earlier events. Subsequently, north‐northeast‐trending, open, upright F₃ ² folds and inclined, northwest‐verging, northeast‐trending F₄ ² folds developed with poorly to moderately developed axial planar, crenulation cleavage (S₃ and S₄) formed by solution transfer processes. These folds formed heterogeneously in S₂ throughout the higher grade areas. Later northeast‐southwest shortening resulted in the formation of en échelon vein arrays and kink bands in both the lower and higher grade rocks. Shortening changed to east‐northeast‐west‐southwest during later north‐northeast to northeast, dextral, strike‐slip faulting and then to approximately northwest‐southeast during the formation of east‐southeast to southeast‐trending, strike‐slip faults. Cessation of faulting occurred prior to the emplacement of Triassic (229 Ma) granitoids. On a regional scale, S₁ trends east‐west and dips moderately to the north in areas unaffected by later events. S₂ has a similar trend to S₁ in less‐deformed areas, but is refolded about east‐west axes during D₃. S₃ is folded about east‐west axes in the highest grade, multiply deformed central part of the Nambucca Block. The deformation and regional metamorphism in the Nambucca Block is believed to be the result of indenter tectonics, whereby south‐directed movement of the Coffs Harbour Block during oroclinal bending, sequentially produced the east‐west‐trending structures. The effects of the Coffs Harbour Block were greatest during D₁ and D₂.     

Early Permian strike-slip basin formation and felsic volcanism in the Manning Group,southern New England Orogen,eastern Australia

The Manning Group is characterised by rapidly filled strike-slip basins that developed during the early Permian along the Peel--Manning Fault System in the southern New England Orogen. Typically, the Manning Group has been difficult to date owing to the lack of fossiliferous units or igneous rocks. Thus, the timing of transition from an accretionary convergent margin in the late Carboniferous to dominantly strike-slip tectonic regimes that involved development and emplacement of the Great Serpentinite Belt (Weraerai terrane) is not well constrained. One exception are rhyolites of the Ramleh Volcanics that were erupted into the Echo Hills Formation. These developed along the dextral Monkey Creek Fault splay east of the Peel--Manning Fault System. Zircons extracted from the Ramleh Volcanics yield a U–Pb (SHRIMP) age of 295.6?±?4.6?Ma that constrains the minimum age of deposition in this basin to earliest Permian. Whole-rock geochemistry indicates these are peraluminous felsic melts enriched in LREE and incompatible elements with strong depletions in U, Nb, Sr and Ti. These are similar in age and composition to the nearby S-type Bundarra and Hillgrove plutonic supersuites. We suggest that extensive movement along the east-dipping Peel--Manning Fault System was responsible, not only for strike-slip basin development at the surface (Manning Group), but was also the locus for crustal melting that was responsible for generating S-type felsic melts that utilised hanging-wall fault splays as conduits to the surface or to coalesce in the crust as batholiths exclusively to the east of the Peel--Manning Fault System.     

Structural inversion of the Tamworth Belt: Insights into the development of orogenic curvature in the southern New England Orogen,Australia

The middle to late Permian Hunter Bowen Event is credited with the development of orogenic curvature in the southern New England Orogen, yet contention surrounds the structural dynamics responsible for the development of this curvature. Debate is largely centred on the roles of orogen parallel strike-slip and orogen normal extension and contraction to explain the development of curvature. To evaluate the dynamic history of the Hunter Bowen Event, we present new kinematic reconstructions of the Tamworth Belt. The Tamworth Belt formed as a Carboniferous forearc basin and was subsequently inverted during the Hunter Bowen Event. Kinematic reconstructions of the Tamworth Belt are based on new maps and cross-sections built from a synthesis of best-available mapping, chronostratigraphic data and new interpretations of depth-converted seismic data. The following conclusions are made from our study: (i) the Hunter Bowen Event was dominantly driven by margin normal contraction (east–west shortening; present-day coordinates), and; (ii) variations in structural style along the strike of the Tamworth Belt can be explained by orthogonal vs. oblique inversion, which reflects the angular relationship between the principal shortening vector and continental-arc margin. Given these conclusions, we suggest that curvature around the controversial Manning Bend was influenced by the presence of primary curvature in the continental margin, and that the Hastings Block was translated along a sinistral strike-slip fault system that formed along this oblique (with respect to the regional east–west extension and convergence direction) part of the margin. Given the available temporal data, the translation of the Hastings Block took place in the Early Permian (Asselian) and therefore preceded the Hunter Bowen Event. Accordingly, we suggest that the Hunter Bowen Event was dominantly associated with enhancing curvature that was either primary in origin, or associated with fault block translation during the Early Permian. This model differs to previously proposed reconstructions where curvature largely formed by orogen parallel strike-slip transportation during the Hunter Bowen Event.     

Mineralogy and Petrology of the Red Hill Alkaline Igneous Complex, New Hampshire, U.S.A.

The Red Hill intrusion, New Hampshire is one of the alkalineintrusions making up the White Mountain Magma Series. Earlierwork has shown that it consists of several units with ring-or plug- like form, in order of intrusion: Outer Coarse Syenite(OCS) plus Nepheline Sodalite Syenite (NSS Fire Tower Sycnite(FTS); Garland Peak Syenite (GPS) Watson Ledge Quartz Syenite(WLQS) Interior Fine Granite (IFG). New studies have revealedtrends of increasing alkalinity in both the OCS (OCS-AOCS-B)and NSS (NSS-A-B-C). Conventional K-Ar and Rb-Sr age datingon separated minerals and bulk rocks show that the OCS, NSS,FTS, and GPS have indistinguishable ages at 198.5?1.5 Ma whilethe IFG formed about 10 Ma later. These values are believedto represent intrusion ages. Amphiboles from the NSS vary from ferro-pargasites through taramitesto katophontes and pyroxenes from ferrosalites to aegirine-augitesthese trends follow the increasing degree of under- saturationin the NSS-A-C series. The NSS-A contain mafic syenite xenolithsas well as partially resorbcd salitic pyroxene cores withinamphiboles. Mineral and isotope data are consistent with theseinclusions being cognate suggesting derivation from more-basicparental magmas. Pyroxenes and amphiboles from saturated andoversaturated rocks vary from ferro-salites to ferro-hedenbergitesand hastingsites to ferro-edenites, respectively, but OCS-Bshow fractionation towards aegirine-augites and katophorites. Mineral assemblages crystallized close to the quartz-fayalite-magnetitebuffer at a pressure of about 1–1.5 kb under essentiallyfluid-saturated conditions. It seems likely that the complexformed by emplacement of fractionated magmas derived from alower-level magma chamber which initially contained a basalticparent magma. The first pulse of magma had an overall compositionsimilar to OCS plus NSS and was intruded as a sheet-like bodywhich differentiated in situ to give a central unit of highlyundersaturated magma (NSS-C). NSS-C samples with relativelyradiogenic Sr isotope compositions were modified by introductionof country-rock Sr via circulating fluids. Fractional crystallizationof alkali-rich amphiboles from critically undersaturated magma(NSS-A?) in the lower- level chamber led to the developmentof saturated and oversaturated magmas. These were intruded intothe OCS/NSS unit along ring fractures to form the FTS and GPSunits. Rock and mineral compositions, including isotope data,are consistent with the IFG forming by partial melting of countryrock and being intruded along pre-existing planes of weaknesssome 10 Ma after the main complex was formed.     

Structure and metamorphism of the Calliope Volcanic Assemblage: Implications for middle to Late Devonian orogeny in the northern New England Fold Belt

The Late Silurian to Middle Devonian Calliope Volcanic Assemblage in the Rockhampton region is deformed into a set of northwest‐trending gently plunging folds with steep axial plane cleavage. Folds become tighter and cleavage intensifies towards the bounding Yarrol Fault to the east. These folds and associated cleavage also deformed Carboniferous and Permian rocks, and the age of this deformation is Middle to Late Permian (Hunter‐Bowen Orogeny). In the Stanage Bay area, both the Calliope Volcanic Assemblage and younger strata generally have one cleavage, although here it strikes north to northeast. This cleavage is also considered to be of Hunter‐Bowen age. Metamorphic grade in the Calliope Volcanic Assemblage ranges from prehnite‐pumpellyite to greenschist facies, with higher grades in the more strongly cleaved rocks. In the Rockhampton region the Calliope Volcanic Assemblage is part of a west‐vergent fold and thrust belt, the Yarrol Fault representing a major thrust within this system.

A Late Devonian unconformity followed minor folding of the Calliope Volcanic Assemblage, but no cleavage was formed. The unconformity does not represent a collision between an exotic island arc and continental Australia as previously suggested.     

Oil-generating coals of the San Juan Basin, New Mexico and Colorado, U.S.A.

Coal beds of the Upper Cretaceous Fruitland Formation in the San Juan Basin of northwestern New Mexico and southwestern Colorado have significant liquid hydrocarbon generation potential as indicated by typical Rock-Eval Hydrogen Indexes in the range of 200–400 mg hydrocarbon/g organic carbon (type II and III organic matter). Small, non-commercial quantities of oil have been produced from the coal beds at several locations. The oils are characterized by high pristane/phytane (ca 4) and pristane/n-C₁₇ ratios (ca 1.2), abundant C₂₁₊ alkanes in the C₁₀₊ fraction with a slight predominance of odd carbon-numbered n-alkanes, abundant branched-chain alkanes in the C₁₅₊ region, and a predominance of methylcyclohexane in the C₄----C₁₀ fraction. The oils are indigenous to the Fruitland Formation coals and probably migrated at thermal maturities corresponding to vitrinite reflectance values in the range 0.7–0.8%. Although the oils found to date are not present in commercial amounts, these findings illustrate the potential of some coals to generate and expel oil under conditions of moderate thermal heating.     

Petrological,geochemical and geochronological evidence for a Neoproterozoic ocean basin recorded in the Marlborough terrane of the northern New England Fold Belt

Petrological, geochemical and radiogenic isotopic data on ophiolitic‐type rocks from the Marlborough terrane, the largest (～700 km²) ultramafic‐mafic rock association in eastern Australia, argue strongly for a sea‐floor spreading centre origin. Chromium spinel from partially serpentinised mantle harzburgite record average Cr/(Cr + Al) = 0.4 with associated mafic rocks displaying depleted MORB‐like trace‐element characteristics. A Sm/Nd isochron defined by whole‐rock mafic samples yields a crystallisation age of 562 ± 22 Ma (2σ). These rocks are thus amongst the oldest rocks so far identified in the New England Fold Belt and suggest the presence of a late Neoproterozoic ocean basin to the east of the Tasman Line. The next oldest ultramafic rock association dated from the New England Fold Belt is ca530 Ma and is interpreted as backarc in origin. These data suggest that the New England Fold Belt may have developed on oceanic crust, following an oceanward migration of the subduction zone at ca540 Ma as recorded by deformation and metamorphism in the Anakie Inlier. Fragments of late Neoproterozoic oceanic lithosphere were accreted during progressive cratonisation of the east Australian margin.     

Ophiolitic and metamorphic rocks in the Percy Isles and Shoalwater Bay region,New England Fold Belt,central Queensland

Ophiolitic and metamorphic rocks of the eastern part of the New England Fold Belt in the Shoalwater Bay region and the Percy Isles are grouped in the Marlborough and Shoalwater terranes, respectively. Marlborough terrane units occur on South Island (Percy Isles) and comprise the Northumberland Serpentinite, antigorite serpentinite with rodingite and more silicic dykes and mafic inclusions, the Chase Point Metabasalt, some 800+ metres of pillow lava, and the intervening South Island Shear Zone containing fault‐bounded slices of mafic and ultramafic igneous rocks, schist, and volcaniclastic sedimentary rocks, and zones of mélange. The Shoalwater terrane, an ancient subduction complex, consists of the Shoalwater Formation greenschist facies metamorphosed quartz sandstone and mudstone on North East Island and on the mainland at Arthur Point, the Townshend Formation, amphibolite‐grade quartzite, schist and metabasalt on Townshend Island, and the Broome Head Metamorphics on the western side of Shoalwater Bay, upper amphibolite facies quartz‐rich gneiss. With the exception of a sliver emplaced onto the western Yarrol terrane, possibly by gravity sliding, Shoalwater terrane rocks show the effects of Late Permian polyphase deformation. The Shacks Mylonite Zone along the northwest edge of the Broome Head Metamorphics marks a zone of oblique thrusting and is part of the major Stanage Fault Zone. The latter is a northeast‐striking oblique‐slip dextral tear fault active during Late Permian west‐directed thrusting that emplaced large ultramafic sheets farther south. Marlborough terrane rocks were emplaced along the Stanage Fault Zone, probably from the arc basement on which rocks of the Yarrol terrane were deposited. Structural trends and the distribution of rock units in the Shoalwater Bay‐Percy Isles region are oblique to the overall structural trend of the northern New England Fold Belt, probably due to the presence of a promontory in the convergent margin active in this region in Devonian and Carboniferous time.     

The Keepit arc: provenance of sedimentary rocks in the central Tablelands Complex,southern New England Orogen,Australia, as recorded by detrital zircon

Detrital zircon from the Carboniferous Girrakool Beds in the central Tablelands Complex of the southern New England Orogen, Australia, is dominated by ca 350–320 Ma grains with a peak at ca 330 Ma; there are very few Proterozoic or Archean grains. A maximum deposition age for the Girrakool Beds of ca 309 Ma is identified. These data overlap the age of the Carboniferous Keepit arc, a continental volcanic arc along the western margin of the Tamworth Belt. Zircon trace-element and isotopic compositions support petrographic evidence of a volcanic arc provenance for sedimentary and metasedimentary rocks of the central Tablelands Complex. Zircon Hf isotope data for ca 350–320 Ma detrital grains become less radiogenic over the 30 million-year record. This pattern is observed with maturation of continental volcanic arcs but is opposite to the longer-term pattern documented in extensional accretionary orogens, such as the New England Orogen. Volcanic activity in the Keepit arc is inferred to decrease rapidly at ca 320 Ma, based on a major change in the detrital zircon age distribution. Although subduction continues, this decrease is inferred to coincide with the onset of trench retreat, slab rollback and the eastward migration of the magmatic arc that led to the Late Carboniferous to early Permian period of extension, S-type granite production and intrusion into the forearc basin, high-temperature–low-pressure metamorphism, and development of rift basins such as the Sydney–Gunnedah–Bowen system.     

Accretion and post-accretion metamorphism in subduction complex terranes of the New England Fold Belt, eastern Australia

Abstract Regional metamorphic rocks that form Late Palaeozoic subduction complexes in central Queensland, Australia, are products of two metamorphic episodes. Synaccretion metamorphism (M1) gave rise to prehnite-pumpellyite and greenschist facies rocks, whereas a subsequent episode (M2) at about 250 Ma formed upper greenschist to upper amphibolite facies rocks of both intermediate- and low-pressure type, probably in a compressive arc or back-arc setting. A similar pattern can be recognized for 1000 km along the New England Fold Belt, although at several localities, where higher grade rocks are exposed, metamorphism was essentially continuous over the M1-M2 interval, with a rapid rise in geothermal gradient at the end of accretion. Where out-stepping of tectonic elements has occurred at long-lived convergent margins elsewhere, similar overprinting of high- by lower-pressure facies series is anticipated, complicating the tectonic interpretation of metamorphism. The discrete character of metamorphic events may be blurred where conditions giving rise to a major episode of accretion and out-stepping are followed by the subduction of a major heat source.     

Geology and geochronology of the Emu Creek Block (northern New South Wales,Australia) and implications for oroclinal bending in the New England Orogen

The southern part of the New England Orogen exhibits a series of remarkable orogenic bends (oroclines), which include the prominent Z-shaped Texas and Coffs Harbour oroclines. The oroclines are defined by the curvature of Devonian–Carboniferous forearc basin and accretionary complex rock units. However, for much of the interpreted length of the Texas Orocline, the forearc basin is mostly concealed by younger strata, and crops out only in the Emu Creek Block in the eastern limb of the orocline. The geology of the Emu Creek Block has hitherto been relatively poorly constrained and is addressed here by presenting new data, including a revised geological map, stratigraphic sections and new detrital zircon U–Pb ages. Rocks of the Emu Creek Block include shallow-marine and deltaic sedimentary successions, corresponding to the Emu Creek and Paddys Flat formations, respectively. New detrital zircon U–Pb data indicate that these formations were deposited during the late Carboniferous and that strata were derived from a magmatic source of Devonian to Carboniferous age. The sedimentary provenance and detrital zircon age distribution suggest that the sequence was deposited in a forearc basin setting. We propose that the Emu Creek and Paddys Flat formations are arc-distal, along-strike correlatives of the northern Tamworth Belt, which is part of the forearc basin in the western limb of the Texas Orocline. These results confirm the suggestion that Devonian–Carboniferous forearc basin rocks surround the Texas Orocline and have been subjected to oroclinal bending.     

Palinspastic reconstruction of the Grenville terrane in the Blue Ridge Geologic Province,southern and central Appalachians,U.S.A

Examinations of Grenville massifs in the Blue Ridge Geologic Province of Virginia and North Carolina indicate that the country rocks (∼ 1100–1450 Ma) are layered gneisses that were metamorphosed during Grenville orogenesis (∼ 1000–1100 Ma) to amphibolite to granulite facies and intruded by plutonic suites. Subsequently, the Grenville terrane was intruded by a suite of peralkaline granitic plutons (∼ 700 Ma) and progressively overlapped westward by Upper Precambrian to Cambrian sedimentary and volcanic rocks. Following deposition of Upper Precambrian and Palaeozoic rocks, the Blue Ridge Geologic Province was subjected to Taconic metamorphism (∼ 450–480 Ma) which generally increased in intensity southeastward from greenschist (chlorite grade) to upper amphibolite (sillimanite grade) facies. Large-scale late Devonian thrusting (∼ 350 Ma) along the Fries fault system and the Brevard zone-Yadkin fault system produced the present day distribution of juxtaposed Grenville massifs and Palaeozoic metamorphic zones in the Blue Ridge Geologic Province. Palinspastic restoration of the Taconic metamorphic zones to their pre-late Devonian relative positions yields an ∼ 50 km displacement on the Fries fault system near the Grandfather Mountain window and and an ∼ 80 km displacement on the Smith River allochthon farther east. Restoration of the Grenville massifs to this same palinspastic base shows that Grenville metamorphic grade decreased southeastward from the deeper granulite facies (opx + gar) to the shallower granulite facies (opx ± amp) to amphibolite facies.     

Gravel transport,gravel harvesting,and channel-bed degradation in rivers draining the southern olympic mountains,Washington, U.S.A.

The potential for gravel extraction to adversely affect anadromous fish habitat in three gravel-bed rivers of southwestern Washington, U.S.A., prompted the need to determine sustainable rates of gravel removal. This was accomplished by evaluating the components of a long-term sediment mass balance for the three rivers. Average annual gravel transport was determined by three independent methods. The closely agreeing results indicate that annual bedload supply decreases downstream through deposition and storage in response to declining gradient and from attrition during transport, as confirmed by laboratory experiments. A survey of gravel-bar harvesting operations indicates that the annual replenishment rate has been exceeded for up to three decades, often by more than tenfold. Analysis of data from nine stream gauging stations over a 55-yr period indicates degradation of about 0.03 m/yr in these reaches and suggests that bed degradation has produced the difference between the replenishment rates and the volumes of gravel harvested from the river beds and bars.     

航空时间域电磁法在澳大利亚新英格兰造山带铜多金属矿靶区优选与评价中的应用

澳大利亚新英格兰造山带构造演化历史复杂,已知铜多金属矿床(点)众多,成矿条件较为优越,是实现铜多金属矿找矿突破的有利区域.通过以航空时间域电磁法测量为核心的工作手段,以航电、磁异常为基础,以"类比—求同"为靶区优选评价指导思想,对新英格兰造山带某探矿权内开展铜多金属矿靶区优选和评价工作.在该地形条件复杂的工作区内,快速、科学有效圈定并优选出铜多金属矿找矿靶区共计9处,其中Ⅰ类找矿靶区3处,Ⅱ类找矿靶区5处,Ⅲ类找矿靶区1处,为在境内外类似工作条件的地区快速有效开展铜多金属矿找矿靶区优选和评价工作提供了参考案例.     

Upper Albian OAE 1d event in the Chihuahua Trough,New Mexico,U.S.A.

Oceanic anoxic events are clues to ocean processes and are correlation datums. In North America only OAE 1a and 2 are well documented. Based on a low-resolution sampling program, a multi-proxy geochemical approach constrained by a biostratigraphic framework was utilized to identify OAE 1d in the upper part of the upper Albian Mesilla Valley Formation near El Paso, Texas. Chronostratigraphic and biostratigraphic evidence indicate that the OAE 1d event in the Mesilla Valley section is located in the lower part of the upper Albian–Cenomanian Ovoidinium verrucosum zone, which correlates with the uppermost Albian Parathalmanninella appenninica and Stoliczkaia dispar zones. The chronostratigraphic age of the geochemical event in the Mesilla Valley Formation is uppermost Albian (97.39–97.30 Ma).The classic geochemical signatures for OAEs are enriched total organic carbon (TOC) concentrations and coupled positive δ¹³C excursions. OAE 1d at this location records TOC values ranging from 0.25 to 0.69 wt.% throughout the Mesilla Valley Formation, where TOC increases during the OAE (21.0–40.0 m) to more than 0.40 wt.%. Interestingly, the organic matter in the Mesilla Valley is dominantly type III, which indicates a pervasive terrigenous source. Although marine organic matter is abundant from the base into the middle of the proposed OAE interval, it is progressively replaced by terrestrial material above the OAE section during progradation. The δ¹³C_organic values record a positive δ¹³C shift of +1.6‰ from −26.41 to −24.80‰ across the stratigraphic interval from 21.0 to 40.0 m, which correlates with OAE 1d.Mn and Fe geochemistry suggest the depositional conditions of the Mesilla Valley Formation were dominated by anoxic and possibly Fe-rich bottom waters, specifically during the time period associated with the OAE 1d event. This interpretation is supported by the presence of Fe enrichment recorded by Fe_Total/Al and Fe_{Highly Reactive}/Fe_T with the lack of Fe_pyrite/Fe_{Highly Reactive} associated with Mn depletion.     

Two belts of HTLP sub-regional metamorphism in the New England Orogen,eastern Australia: occurrence and characteristics exemplified by the Wongwibinda Metamorphic Complex

Abstract

Two north–south-trending belts of high-temperature–low-pressure (HTLP) sub-regional metamorphism have been identified in the New England Orogen of eastern Australia. Metamorphic complexes in the ～1300?km long Early-Permian Inland belt have ages ca 300–290?Ma, and those of the ～400?km long Mid-Permian Coastal belt ca 275–270?Ma. These periods correspond to the beginning and end of an extended (early–mid Permian) phase of subduction rollback and crustal thinning in eastern Australia. This paper describes and incorporates recent work on the Wongwibinda Metamorphic Complex in the southern New England Orogen as a basis for comparison with thirteen other HTLP sub-regional occurrences within the orogen. These are described in as much detail as is currently available. Some outcrops of HTLP rocks in difficult terrain have been subject to limited study and only conditional comparisons can be made. However, a significant number of characteristics shared between the complexes including: their location at the higher-temperature end of broad areas of very low-grade to greenschist facies metamorphic rocks, indicative of tilted crustal blocks; their association with major shear zones; the presence of migmatite at the high-temperature end of a steep metamorphic field gradient; the presence of two-mica granite formed by the melting of the local sedimentary pile; and temporal association with S-type granites; imply a common extension-related mechanism of formation for these HTLP belts. The connection with major faults and shear zones suggests the belts trace major crustal-scale extensional structures that migrated eastwards from ca 300 to 270?Ma.

1. KEY POINTS

2. Two previously undocumented belts of HTLP subregional metamorphism are identified within the NEO.

3. Available dating indicates that metamorphism occurred along the belts at the beginning and end of a major early–mid Permian extensional phase in eastern Gondwana/Australia.

4. The characteristics of the HTLP complexes including their association with shear zones indicates they may delineate major loci of extension.

     

Retrograde metamorphism of eclogite in the southern Appalachian Mountains,U.S.A.–A case involving seamount subduction?

This work supports a growing body of evidence that the Ashe Metamorphic Suite (AMS) of the eastern Blue Ridge province in North Carolina has an ensimatic origin and is part of a subduction‐related accretionary mélange, marking the Taconic suture between the North American craton and the Inner Piedmont. In a palinspastic reconstruction, the thrust fault at the base of the AMS appears to have intercepted the greatest depths (i.e. highest‐P metamorphic rocks) beneath parts of the AMS now exposed adjacent to the Grandfather Mountain window. The greatest volume of mafic rock is found in these same areas. We suggest that the nascent, subduction‐related, basal thrust fault was deflected downward by an obstacle in the form of an isolated, mafic volcanic edifice on the oceanic crust–a sea mount. Pelitic and mafic rocks dominate the AMS. North of the Grandfather Mountain window, retrograded eclogite occurs in the amphibolite near the base of the AMS. Textures and mineralogy indicate that an original eclogite assemblage was subjected to the following sequence of parageneses: (a) Eclogite(I) facies: omphacite+garnet+quartz, (b) Eclogite(II) facies: omphacite+garnet+epidote+quartz, (c) Symplectic (diopside+plagioclase)+garnet+epidote+quartz, (d) Amphibolite facies: (diopside+plagioclase)+garnet+epidote+hornblende+quartz, (e) Amphibolite facies: plagioclase+garnet+epidote+hornblende+quartz. P–T conditions, estimated from geothermobarometry applied to relevant mineral compositions, are c.720 °C and c.16 kbar for (b) eclogite(II) facies; c.655 °C and c.8.5 kbar for (e) amphibolite facies.     

C-S-Fe relationships and the isotopic composition of pyrite in the New Albany Shale of the Illinois Basin,U.S.A.

The relationship between pyritic sulfur content (S_pyr) and organic carbon content (C_org) of shales analyzed from the New Albany Group depends upon C_org. For samples of <6 wt.% C_org, S_pyt, and C_org are strongly correlated (r = 0.85). For C_org-“rich” shales (>6 wt.%), no S_pty-C_org, correlation is apparent. The degree of Fe pyritization (DOP) shows similar relationships to C_org. These C-S-Fe relationships suggest that pyrite formation was limited by the availability of metabolizable organic carbon in samples where C_org < 6 wt.% and by the availability of reactive Fe for samples where C_org > 6 wt.%. Apparent sulfur isotope fractionations relative to contemporaneous seawater sulfate (Δ³⁴S) for pyrite formation average −40% for non-calcareous shales and −25%. for calcareous shales. Δ³⁴S values become smaller with increasing C_org, S_pyt, and DOP for all C_org-“poar” (<6 wt%) and some C_org-“nch” (<6 wt.%) shales. These trends suggest that pyrite formation occurred in a closed system or that instantaneous bacterial fractionation for sulfate reduction decreased in magnitude with increasing organic carbon content. The isotopic trends observed in the New Albany Group are not necessarily representative of other shales having a comparable range of organic carbon content, e.g. Cretaceous shales and mudstones from the western interior of North America (GAUTIER, 1986). Δ³⁴S values in the remainder of the C_org-rich New Albany Group shales are relatively large (−38 to −47%.) and independent of C_org, S_pyr, and DOP, which suggests that pyrite in these shales formed mostly at or above the sediment-water interface by precipitation from an isotopically uniform reservoir of dissolved H₂S.