Serpentinization-driven extension in the Ronda mantle slab (Betic Cordillera,S. Spain)

We investigate the stress regimes acting during serpentinization and faulting of the largest known subcontinental lithospheric peridotite body, namely the Ronda peridotites (Betic Cordillera, S. Spain). Petrological and structural analyses on serpentinites grown along fault planes crosscutting the peridotite slab, reveal that they were developed during three superposed stress tensors: the oldest one (E1) is characterized by NW–SE sub-horizontal compression; the intermediate one consists in NE–SW to ENE–WSW extension with orthogonal compression (E2); and the youngest one (E3) shows a sub-vertical maximum stress axis and NW–SE sub-horizontal extension. During serpentinization, maximum and minimum stress axes flip between a NW–SE horizontal position and a vertical one in the whole peridotite body (E1 and E3), while E2 represents an intermediate stress stage. Field relationships and previous petrological and geochronological data indicate that serpentinization and associated stress tensors are coeval with intrusive leucogranite dikes crosscutting the peridotites, thus constraining these processes to 19–22 Ma and occurring at upper continental crust depths (P < 4 kbar). Gravity data reveal that the average density of the Ronda mantle slab (~ 2.7–2.8 g/cm³) shows a negligible contrast with the surrounding crustal rocks, thus suggesting that the peridotite body is serpentinized in a great proportion. Our preferred tectonic model to account for the evolution of the Ronda peridotites in the upper crust considers that E1 compression was linked to the collision of the Alborán continental domain with the Iberian passive margin during the Gibraltar Arc formation. Subsequently, the sudden onset of extension recorded within the peridotite slab (E2 and E3) was favored by serpentinization-driven buoyancy.     

The building blocks of continental crust: Evidence for a major change in the tectonic setting of continental growth at the end of the Archean

Oceanic arcs are commonly cited as primary building blocks of continents, yet modern oceanic arcs are mostly subducted. Also, lithosphere buoyancy considerations show that oceanic arcs (even those with a felsic component) should readily subduct. With the exception of the Arabian–Nubian orogen, terranes in post-Archean accretionary orogens comprise < 10% of accreted oceanic arcs, whereas continental arcs compose 40–80% of these orogens. Nd and Hf isotopic data suggest that accretionary orogens include 40–65% juvenile crustal components, with most of these (> 50%) produced in continental arcs.Felsic igneous rocks in oceanic arcs are depleted in incompatible elements compared to average continental crust and to felsic igneous rocks from continental arcs. They have lower Th/Yb, Nb/Yb, Sr/Y and La/Yb ratios, reflecting shallow mantle sources in which garnet did not exist in the restite during melting. The bottom line of these geochemical differences is that post-Archean continental crust does not begin life in oceanic arcs. On the other hand, the remarkable similarity of incompatible element distributions in granitoids and felsic volcanics from continental arcs is consistent with continental crust being produced in continental arcs.During the Archean, however, oceanic arcs may have been thicker due to higher degrees of melting in the mantle, and oceanic lithosphere would be more buoyant. These arcs may have accreted to each other and to oceanic plateaus, a process that eventually led to the production of Archean continental crust. After the Archean, oceanic crust was thinner due to cooling of the mantle and less melt production at ocean ridges, hence, oceanic lithosphere is more subductable. Widespread propagation of plate tectonics in the late Archean may have led not only to rapid production of continental crust, but to a change in the primary site of production of continental crust, from accreted oceanic arcs and oceanic plateaus in the Archean to primarily continental arcs thereafter.     

Integrated potential-field and seismic constraints on the structure of the Archean metasedimentary English River belt,Western Superior craton,Canada

The English River Subprovince is a prominent belt of metasedimentary rocks in the Archean Western Superior Province. The structure of its western half was investigated by using techniques of enhancement and automatic interpretation of magnetic data, and integration of magnetic-derived information with seismic and gravity data. The results indicate that a suite of exposed felsic plutons that intruded the belt at ca. 2698 Ma extends under most of the metasedimentary rocks that are exposed at the surface. The thickness of the metasedimentary rocks is interpreted to be less than 1 km in areas where it is underlain by the members of this intrusive suite. In other areas, the metasedimentary rocks attain thicknesses of 3–4 km and appear to be underlain by rocks similar to the gneissic rocks that are exposed in the adjacent metaplutonic Winnipeg River Subprovince. The integration of enhanced magnetic data with gravity data indicates that the large gravity anomaly that extends along the English River belt correlates well spatially and morphologically with the extensive suite of felsic intrusions that underlies the belt, suggesting that the crustal component of the gravity anomaly is related to this suite of intrusions. We interpret the source of the gravity anomaly as a dense unit comprising anhydrous mineral assemblages that formed within these felsic intrusions in response to low-pressure, high-temperature metamorphism that affected the belt at ca. 2691 Ma. On the basis of geochronological, geological and geophysical constraints, we propose that this metamorphic episode is linked to the continuation of magmatism at depth after the emplacement of the ca. 2698 Ma felsic plutons, being ultimately related to the advection of mantle heat into the crust during a period of regional extension.     

High-Al and high-Cr podiform chromitites from the western Yarlung-Zangbo suture zone,Tibet: Implications from mineralogy and geochemistry of chromian spinel,and platinum-group elements

On the basis of their mineral chemistry, podiform chromitites are divided into high-Al (Cr# = 20–60) (Cr# = 100 1 Cr/(Cr + Al)) and high-Cr (Cr# = 60–80) varieties. Typically, only one type occurs in a given peridotite massif, although some ophiolites contain several massifs that can have different chromitite compositions. We report here the occurrence of both high-Cr and high-Al chromitite in a single massif in China, the Dongbo mafic-ultramafic body in the western Yarlung-Zangbo suture zone of Tibet. This massif consists mainly of mantle peridotites, with lesser pyroxenite and gabbro. The mantle peridotites are mainly composed of harzburgites and minor lherzolites; a few dike-like bodies of dunite are also present. Seven small, lenticular bodies of chromitite ores have been found in the harzburgites, with ore textures ranging from massive through disseminated to sparsely disseminated; no nodular ore has been observed. Individual chromitite pods are 1–3 m long, 0.2–2 m wide and strike NW, parallel to the main trend of the peridotites. Chromitite pods 3, 4, and 5 consist of high-Al chromitite (Cr# = 12–47), whereas pods 1 and 2 are high-Cr varieties (Cr# = 73 to 77). In addition to chromian spinel, all of the pods contain minor olivine, amphibole and serpentine. Mineral structures show that the peridotites experienced plastic deformation and partial melting. The mineralogy and geochemistry of the Dongbo peridotites suggest that they formed originally at a mid-ocean ridge (MOR), and were later modified by suprasubduction zone (SSZ) melts/fluids. We interpret the high-Al chromitites as the products of early mid-ocean ridge basalt (MORB) or arc tholeiite magmas, whereas the high-Cr varieties are thought to have been generated by later SSZ melts.     

Mylonitized peridotites of Songshugou in the Qinling orogen,central China: A fragment of fossil oceanic lithosphere mantle

The Songshugou mylonitized peridotites within the Qinling Group metamorphic rocks in Central China are distributed in the northern part of the Shang-Dan Suture Zone (SDSZ) and contain abundant dunites and harzburgites. The dunites were intensely deformed and mylonitized converting the coarse-grained type to medium- and fine-grained types which contain prominent lenticular structure and relict olivine (Ol) porphyroclasts. Mineralogical and geochemical compositions suggest that the protoliths of the mylonitized peridotites were coarse-grained peridotites of lithospheric mantle origin. The harzburgites occur as enclaves within mylonitic peridotites in the form of lenses or veins. The orthopyroxenes in harzburgites were formed at the expense of Ol and have similar compositions to those of metasomatized harzburgites, characterized by low Al₂O₃, CaO and Cr₂O₃ contents. The harzburgites exhibit the gently U-type REE patterns with enriched incompatible elements (Rb, Ba, Sr, Zr and Hf), suggesting the metasomatic origin. The obvious ductile deformation of the large porphyroclastic orthopyroxene (Opx) suggests that the metasomatism occurred before the deformation. Ductile shearing deformation is indicated by the small fold structures and net-style ductile shearing zones within the Songshugou peridotite massif. The process is also result in the alignment of elongated Ol grains from initially coarse-granular via porphyroclastic to fine-granular texture. The relatively low Fo olivine, together with high Al₂O₃, and CaO contents and the abnormally low total PGE abundance in the fine-grained dunites suggest the ingress of melt/fluid during the mylonitization. The presences of significant amount of amphibole in the peridotites indicate the ingress of hydrous fluids. In general, the Songshugou peridotites have similar compositional characteristics with peridotites of Oman and Troodos ophiolites which are fragments of oceanic lithosphere mantle. One coarse-grained dunite has a T_RD age of 875 Ma. Additionally two stages Paleozoic T_RD ages are obtained from medium-grained and fine-grained dunites (491 Ma and 550 Ma; 446 Ma and 476 Ma). The broadly coeval nature of mylonitization with progressive metamorphism of surrounding amphibolites suggested that the Songshugou peridotites were generated before the early Paleozoic deformation. Our data, combined with the previous work on the surrounding HP/UHP metamorphic rocks, demonstrate that the Songshugou mylonitized peridotites represent fragments of the Neoproterozoic fossil oceanic lithospheric mantle that experienced extensive deformation during the Early Paleozoic subduction processes.     

The Corredoiras orthogneiss (NW Iberian Massif): Geochemistry and geochronology of the Paleozoic magmatic suite developed in a peri-Gondwanan arc

The Corredoiras orthogneiss belongs to the intermediate pressure upper units of the Órdenes Complex (Variscan belt, NW Spain), mainly composed by granodioritic orthogneisses, with small bodies of tonalitic orthogneisses, amphibole-rich orthogneisses and metagabbronorites. In this work we study their chemical and isotopic composition, to gain insight into the linkage between plate tectonics and magmatism and to improve the knowledge of the paleogeographic evolution of the European Variscan Belt.Granodioritic and tonalitic orthogneisses range from intermediate to felsic rocks, with K₂O/Na₂O ratios ≈ 1, typical of calc-alkaline rocks, and high Na₂O content, characteristic of I-type granites. Metagabbronorites are basic rocks, but some of them are contaminated by interaction with the felsic magmas, showing enrichment in SiO₂, Na₂O and K₂O. All Corredoiras metaigneous rocks are enriched in large ion lithophile elements (LILE) and light rare earth elements (LREE) relative to high field strength elements (HFSE), resulting in a high LILE/HFSE ratio. These geochemical features are the most characteristic of magmas related to subduction zones; furthermore all orthogneisses display significant negative anomalies in Ta, Nb and Zr, which together with their low contents in Y and Yb match up with granitoids generated in volcanic arcs or subduction zones. SHRIMP U–Pb zircon dating provides a concordia age of 492 ± 3 Ma. Granodioritic orthogneiss has negative εNd_(492 Ma) values (? 2.2 to ? 3.6) and high (⁸⁷Sr/⁸⁶Sr)_i ratios (0.707 to 0.708), on the other hand tonalitic orthogneisses and metagabbronorites have positive εNd_(492 Ma) (1.0 to 2.4) and low (⁸⁷Sr/⁸⁶Sr)_i (0.703 to 0.705), suggesting that granodioritic orthogneisses have a clear crustal influence in their generation, whereas tonalitic orthogneisses and metagabbros can be related to basic magmas extracted from the mantle or from a basic lower continental crust.The Corredoiras chemical characteristics permit us to interpret that this rocks were probably generated in an ensialic island arc and may represent a peri-Gondwanan fragment drifted away to open the Rheic Ocean.     

Petrogenesis of Neoarchaean volcanic rocks of the MacQuoid supracrustal belt: A back-arc setting for the northwestern Hearne subdomain,western Churchill Province,Canada

Rocks exposed in the MacQuoid-Gibson Lakes region, northwest Hearne subdomain, western Churchill Province, Canada comprise three major lithotectonic assemblages: the Principal volcanic belt; the metasedimentary MacQuoid homocline and; the Cross Bay plutonic complex. Neoarchaean supracrustal rocks of the belt range in age from <2745 to <2672 Ma and were intruded during the interval <2689 to 2655 Ma by diverse plutonic units ranging from gabbro through syenogranite, but greatly dominated by tonalite. Volcanic rocks occur only in the Principal volcanic belt and the MacQuoid homocline, are metamorphosed to amphibolite facies and vary from rare pillowed to common massive basalt and andesite, intercalated with less abundant, thin, dacitic to rhyolitic tuffs, lavas and volcaniclastic rocks. Basalt and andesite are dominated by subalkaline, FeO^T-rich tholeiites with less common calc-alkaline rocks with higher SiO₂ contents and variable trace element contents. Felsic volcanic rocks exhibit calc-alkaline affinities and similarly diverse trace element abundances. The diverse trace element chemistry of the basalt and andesite supports their derivation from a heterogeneous mantle source(s) capable of generating MORB-, Arc-, BABB- and boninite-like rocks. Two geochemically distinct, arc-like suites were generated through contamination of the primary mantle-derived magmas either via assimilation of lower or middle tonalitic crust, or through contamination of their mantle source through subduction. Geochemical features of the felsic volcanic rocks indicate that these formed via both anatexis of crust in the amphibolite ± garnet stability field and via fractionation of more primitive progenitors in mid-upper crustal magma chambers. ɛNd_{t = 2680 Ma} isotopic compositions cluster near depleted mantle, indicating that significant incorporation of older, >2700 Ma crust likely did not occur. ɛNd_{t = 2680 Ma} values for three specimens, one from each of the Arc-like suites and one BABB-like basalt are slightly lower than the remainder, suggesting very minor incorporation of slightly older crust.These features imply that the processes that generated the MacQuoid supracrustal belt required simultaneous tapping of geochemically distinct mantle reservoirs with concomitant anatexis of sialic crust (garnet stability field) and fractionation of felsic magmas in upper crustal magma chambers. Shallow water deposition of abundant volcaniclastic rocks and semipelite along with minor conglomerate and quartzite was broadly contemporaneous with this magmatism. We envisage a geodynamic setting characterized by tectonomagmatic processes similar to those of modern supra-subduction zone back-arc marginal basins such as the Sea of Japan. Therein, an extensional, back-arc setting, likely proximal to continental crust, provides an explanation for a broad swath of diverse mantle-derived rocks intercalated with less common felsic rocks as well as an abundance of immature clastic metasedimentary rocks.     

Zircon recycling and crystallization during formation of chromite- and Ni-arsenide ores in the subcontinental lithospheric mantle (Serranía de Ronda,Spain)

The ultramafic massifs of the Serranía de Ronda (namely Ronda, Ojén and Carratraca) are portions of Proterozoic (∼1.2–1.8 Ga) subcontinental lithospheric mantle (SCLM) affected by partial melting and infiltration of melts. The latter of these events was broadly coeval with the tectonic emplacement of the peridotites into the continental crust in the Early Miocene. This resulted in the formation of chromite and Ni-arsenide ores (Cr-Ni) associated with orthopyroxenites and cordieritites. Six zircons recovered from a massive chromitite sample from the Ronda massif yield both concordant and discordant ages between 2309 ± 37 Ma and 109 ± 15 Ma, and δ¹⁸O between 8.3‰ and 9.4‰. Two Proterozoic ages obtained for zircons of this population (1815 ± 9 Ma and 1794 ± 17 Ma) are identical, within error, to those of zircons reported previously in the garnet pyroxenites of Ronda (1783 ± 37 Ma). Similarly, concordant Early Jurassic (192 ± 13 Ma) and Cretaceous ages (109 ± 15 Ma) obtained from the core and rim, respectively, of a single zircon from the chromitite are also consistent with the ages (180 ± 5 Ma, 178 ± 6 Ma, and 131 ± 3 Ma) already reported for magmatic zircons from corunudum-bearing garnet pyroxenites in the Ronda massif. The observation that chromitites and garnet-pyroxenites contain similar populations of zircons suggests that the parental melts of chromitites inherited zircons from their protolithic garnet pyroxenites, representing relics of oceanic/arc crust recycled in the mantle. Eleven zircons recovered from a massive cordieritite associated with chromitite in the Ronda massif yield scattered concordant and discordant ages between 568 Ma and 21 Ma, with correspondingly variable δ¹⁸O (4.8–13.5‰) and unradiogenic Hf-isotope ratios (ε_Hf(t) from −12.36 to −4.43). The youngest age is concordant at 21.18 ± 0.4 Ma and matches the ages of zircons from the chromitite (weighted average age of 20.4 ± 0.87 Ma, n = 4) and a plagioclasite dyke (scattering between 20.1 ± 0.2 Ma and 17.9 ± 0.1 Ma; n = 11) associated with the Cr-Ni mineralization in the Ojén massif. These zircons show similar unradiogenic Hf-(ε_Hf(t) between −14.5 and −7.6) and heavy O-isotope compositions (δ¹⁸O = 11.3–12.4‰). A sample of the massive cordieritite hosting the chromitites contains abundant zircons that yield scattered concordant, sub-concordant and discordant U-Pb ages varying from 33.8 ± 1 Ma to 781 ± 10 Ma; these zircons (n = 21) have variable U-contents (105–13900 ppm) and Th/U ratios (0.003–0.8). On the basis of O- and Hf-isotope compositions, these zircons define three populations independently of their ages: (1) grains with consistent high δ¹⁸O (6.1–12.7‰) and negative ε_Hf(t) (from −14.42 to −6.88); (2) grains with high δ¹⁸O (7.6–11.1‰) and positive ε_Hf(t) (3.10–4.84); and (3) grains with δ¹⁸O < 5.5‰ typical of mantle values. We suggest that zircons from this cordieritite with U-Pb ages older than Miocene are inherited, and were incorporated physically into the SCLM by fluids or melts produced during dehydration-melting of the crustal rocks wrapping the peridotite massifs. The population of Early Miocene zircons found in the chromitites and associated cordieritites and the plagioclasite dyke in the mineralization of the Ojén massif date the crustal emplacement of the peridotites and, therefore, the formation of the Cr-Ni ores. We propose a model in which the unique Cr-Ni mineralizations found in the ultramafic rocks of the Serranía de Ronda were formed as a result of contamination of the SCLM with crustal components.     

Paleoproterozoic bimodal post-collisional magmatism in the southwestern Amazonian Craton,Mato Grosso,Brazil: Geochemistry and isotopic evidence

This paper discusses geological and geochemical aspects of a Paleoproterozoic volcano-plutonic association that crops out in southwestern Amazonian Craton, Mato Grosso, Brazil. The study area was divided into undeformed and deformed domains, based on structural and geochronology studies. The undeformed domain is composed mainly of felsic explosive and effusive flows. Inter-layered mafic flows of basalts and sedimentary rocks are also present. The deformed domain is mainly composed of titanite and hornblende-bearing monzogranite to syenogranite and biotite monzogranite, while granodiorite is less common. U–Pb single zircon analyses yielded ages of 1.8–1.75 Ga in granites and felsic volcanic rocks for both domains. Basalts from the undeformed domain are phaneritic, fine-grained, and are often hydrothermally altered. They show tholeiitic affinity and are LREE enriched. Their trace element composition resembles those of within-plate associations. The ε_Nd (t = 1.75 Ga) for all these rocks are positive, ranging from 0.12 to 1.49, which reflect a juvenile source. The felsic volcanism comprises subalkaline rocks with high K contents and is divided into two groups: crystal enriched ignimbrites and effusive rhyolites. REE patterns of effusive rocks show negative-Eu anomalies and are smooth in the ignimbrites. Trace element patterns similar to those of the effusive rocks and ignimbrites are found in magmatic rocks derived from sources affected by subduction-related metasomatism. Hornblende and biotite granites occur in the deformed felsic plutonic domain. These rocks show evidence of low-temperature metamorphism and deformation, and in some places, of hydrothermal alteration. The LREE/Nb (or Ta) ratios of these rocks are consistent with those observed in granites of post-collisional settings. The ε_Nd (t = 1.75 Ga) values are slightly negative on average, with few positive values (?1.41 to +2.96). These data are interpreted as indicative of a magmatism produced during a post-collisional event from mixed sources: a metasomatised mantle and a Paleoproterozoic continental crust. An intracontinental shearing with age of 1.7–1.66 Ga created the Teles Pires–Juruena lineament which partially controlled this magmatism.     

Geochronology and Hf isotopes of the bimodal mafic–felsic high heat producing igneous suite from Mt Painter Province,South Australia

The Mt Painter Province of northern South Australia is a site of exceptional suite of Mesoproterozoic high heat producing (HHP) granites and felsic volcanics. These rocks have very high heat production values of > 5 μW m^− 3. The HHP granites, including the Mt Neill, Box Bore, Terrapinna, Wattleowie and Yerila granites, form part of a broadly coeval association of mafic and felsic volcanic rocks that also include the Pepegoona Volcanics, lamprophyres and mafic–intermediate dykes. U–Pb LA-ICPMS zircon dating and Hf-in-zircon isotopic data are used to constrain both the timing and source of these magmatic rocks. U–Pb zircon LA-ICPMS crystallization ages range from ~ 1596 to 1521 Ma and imply a protracted sequence of magmatic events. Initial Hf isotopic compositions of these zircons from both dykes and felsic rocks have overlapping compositional ranges, with ε_Hf values mainly from + 4 to − 2. These Hf values are significantly higher than contemporary crustal values which are likely to have been in the range − 4 to − 20. These data imply that the magmatic suite has both mantle and crustal sources.     

Crustal recycling through intraplate magmatism: Evidence from the Trans-North China Orogen

The North China Craton (NCC) preserves the history of crustal growth and craton formation during the early Precambrian followed by extensive lithospheric thinning and craton destruction in the Mesozoic. Here we present evidence for magma mixing and mingling associated with the Mesozoic tectonic processes from the Central NCC, along the Trans-North China Orogen, a paleo suture along which the Eastern and Western Blocks were amalgamated at end of Paleoproterozoic. Our investigations focus on two granitoids – the Chiwawu and the Mapeng plutons. Typical signatures for the interaction of mafic and felsic magmas are observed in these plutons such as: (1) the presence of diorite enclaves; (2) flow structures; (3) schlierens; (4) varying degrees of hybridization; and (5) macro-, and micro-textures. Porphyritic feldspar crystals show numerous mineral inclusions as well as rapakivi and anti-rapakivi textures. We present bulk chemistry, zircon U–Pb geochronology and REE data, and Lu–Hf isotopes on the granitoids, diorite enclaves, and surrounding basement rocks to constrain the timing of intraplate magmatism and processes of interaction between felsic and mafic magmas. Our LA-ICP-MS zircon U–Pb data show that the pophyritic granodiorite was emplaced at 129.7 ± 1.0 Ma. The diorite enclaves within this granodiorite show identical ages (128.2 ± 1.5 Ma). The basement TTG (tonalite–trondhjemite–granodiorite) gneisses formed at ca. 2.5 Ga coinciding with the major period of crustal accretion in the NCC. The 1.85 Ga age from zircons in the gabbro with positive Hf isotope signature may be related to mantle magmatism during post-collisional extension following the assembly of the Western and Eastern Blocks of the NCC along the Trans-North China Orogen. Our Hf isotope data indicate that the Neoarchean–Paleoproterozoic basement rocks were derived from complex sources of both juvenile magmas and reworked ancient crust, whereas the magma source for the Mesozoic units are dominantly reworked basement rocks. Our study provides a window to intraplate magmatism triggered by mantle upwelling beneath a paleosuture in the North China Craton.     

U–Pb zircon geochronology and geochemistry of Neoproterozoic volcanic rocks in the Tarim Block of northwest China: implications for the breakup of Rodinia supercontinent and Neoproterozoic glaciations

As the lowest volcanics-bearing unit of the Neoproterozoic succession, the Beiyixi Formation is the key to understanding the early response to the breakup of the Roninia supercontinent in the Tarim Block. The SHRIMP analyses of zircons from the volcanic rocks at the bottom of the Beiyixi Formation yield a weighted mean ²⁰⁶Pb/²³⁸U age of 755 ± 15 Ma. This is interpreted as the eruption age of the Beiyixi volcanic rocks. The Beiyixi volcanic rocks consist of bimodal basalt and dacite-rhyolite with a SiO₂ gap between 55% and 65%. The mafic rocks display negative ɛ_Nd (755 Ma) values (−9.9 to −10.8), moderate enrichment in LILE and variable depletion in Nb, Ta and P, resembling those of the tholeiitic basalts in continental rift. Geochemical and Nd isotopic characteristics suggest that the mafic rocks were derived from partial melting of an enriched lithospheric mantle reservoir. The felsic rocks show negative ɛ_Nd (755 Ma) values (−7.9 to −9.2), negative Nb, Ta, P and Ti anomalies, very high La_N/Yb_N (62–92) ratios and LILE abundances, and may be generated by melting of eclogites or garnet amphibolites in the lower crust, as a result of basalt emplacement into continental crust during continental rifting. The age of 755 ± 15 Ma indicates that the Beiyixi glaciation took place later than 755 Ma and it could be correlated with the Chang’an glaciation in the Yangtze Block and the Sturtian–Rapitan glaciation in other Rodinia Blocks. The geochemical characteristics of the Beiyixi volcanic rocks resemble those of the rift-related magmatism in other Rodinia Blocks, suggesting that the Beiyixi volcanism was a part of global magmatism during the breakup of Rodinia supercontinent. The age and geochemical features of the Beiyixi volcanic rocks also reveal that the mantle plume activity spread to the northwestern margin of the Rodinia supercontinent and probably resulted in the breakup between Australia and Tarim Blocks.     

Geochemical characteristics of the Kuh-e Dom intrusion,Urumieh–Dokhtar Magmatic Arc (Iran): Implications for source regions and magmatic evolution

The Kuh-e Dom Pluton is located along the central northeastern margin of the Urumieh–Dokhtar Magmatic Arc, spanning a wide range of compositions from felsic rocks, including granite, granodiorite, and quartz monzonite, through to intermediate-mafic rocks comprising monzonite, monzodiorite, diorite, monzogabbro, and gabbro. The Urumieh–Dokhtar Magmatic Arc forms a distinct linear magmatic complex that is aligned parallel with the orogenic suture of the Zagros fold-thrust belt. Most samples display characteristics of metaluminous, high-K calc-alkaline, I-type granitoids. The initial isotopic signatures range from εNd (47 Ma) = −4.77 to −5.89 and ⁸⁷Sr/⁸⁶Sr(i) = 0.7069 to 0.7074 for felsic rocks and εNd (47 Ma) = −3.04 to −4.06 and ⁸⁷Sr/⁸⁶Sr(i) = 0.7063 to 0.7067 for intermediate to mafic rocks. This geochemical and isotopic evidence support a mixed origin for the Kuh-e Dom hybrid granitoid with a range of contributions of both the crust and mantle, most probably by the interaction between lower crust- and mantle-derived magmas. It is seem, the felsic rocks incorporate about 56–74% lower crust-derived magma and about 26–44% of the enriched mantle-derived mafic magma. In contrast, 66–84% of the enriched mantle-derived mafic magma incorporates 16–34% of lower crust-derived magma to generate the intermediate-mafic rocks. According to the differences in chemical composition, the felsic rocks contain a higher proportion of crustal material than the intermediate to mafic ones. Enrichment in LILEs and depletion in HFSEs with marked negative Nb, Ba, and Ti anomalies are consistent with subduction-related magmatism in an active continental margin arc environment. This suggestion is consistent with the interpretation of the Urumieh–Dokhtar Magmatic Arc as an active continental margin during subduction of the Neotethys oceanic crust beneath the Central Iranian microcontinent.     

The origin and geochemical evolution of the Woodlark Rift of Papua New Guinea

Geochemical, isotopic, and geochronologic data for exhumed rocks in the Woodlark Rift of Papua New Guinea (PNG) allow a tectonic link to be established with the Late Cretaceous Whitsunday Volcanic Province (WVP) of northeastern Australia. Most of the metamorphic rocks in the Woodlark Rift have Nd isotopic compositions (ε_Nd = + 1.7 to + 6.2) similar to the Nd isotopic compositions of rocks in the WVP (ε_Nd = + 1.3 to + 6.6; Ewart et al., 1992), and contain inherited zircons with 90 to 100 Ma U–Pb ages that overlap the timing of magmatism in the WVP. None of the metamorphic rocks in the Woodlark Rift have the highly evolved Hf and Nd isotopic compositions expected of ancient continental crust. Magmas were erupted in the WVP during the middle Cretaceous as eastern Gondwana was rifted apart. The protoliths of felsic and intermediate metamorphic rocks in the Woodlark Rift are interpreted to be related to the magmatic products produced during this Cretaceous rifting event. Some mafic metamorphic rocks exposed in the western Woodlark Rift (eclogites and amphibolites) are not related to the WVP and instead could have originated as basaltic lavas crystallized from mantle melts at (U)HP depths in the Late Cenozoic, or as fragments of Mesozoic aged oceanic lithosphere.Isotopic and elemental comparisons between basement gneisses and Quaternary felsic volcanic rocks demonstrate that felsic lavas in the D'Entrecasteaux Islands did not form solely from partial melting of metamorphic rocks during exhumation. Instead, the isotopic compositions and geochemistry of Quaternary felsic volcanic rocks indicate a significant contribution from the partial melting of the mantle in this region. When combined with geophysical data for the western Woodlark Rift, this suggests that future seafloor spreading will commence south of Fergusson Island, and west of the present-day active seafloor spreading rift tip.     

Neoproterozoic bimodal magmatism in the Cathaysia Block of South China and its tectonic significance

SHRIMP U–Pb zircon age, geochemical and Sm–Nd isotopic results are reported for the Mamianshan volcanic rocks in the Cathaysia Block of southeastern South China. The Mamianshan volcanic rocks are bimodal in composition and are dominantly transitional to mildly alkaline basalts and subordinate alkaline rhyolite, with an eruption age of 818 ± 9 Ma. The basaltic samples are characterized by LREE-enriched and “humped” trace element patterns, similar to many alkali basalts in continental rifts. Variable ɛNd(T) values between +3.33 and −4.35 indicate that the primary magma of these basalts was derived from an OIB-like mantle source and underwent fractional crystallization plus crustal contamination. The rhyolitic rocks are highly enriched in Th, Ta, Nb, REE, Zr, Hf and Y and depleted in Sr, P, Eu and Ti, sharing affinity to A₁-type granites. Combined with their slightly positive ɛNd(T) values (+0.22 to +0.92), the Mamianshan felsic rocks were most likely generated by partial melting of the regional Paleoproterozoic Mayuan amphibolites. The Mamianshan bimodal volcanic rocks in the Cathaysia Block are coeval with the widespread intraplate magmatism around the Yangtze Block. Our results support the idea that a coherent South China Craton was formed during the ca. 1.0 Ga Sibao orogeny, and it subsequently underwent extensive continental rifting related to mantle plume or superplume activities beneath Rodinia since ca. 825 Ma.     

Metallogeny of South Greenland: A review of geological evolution,mineral occurrences and geochemical exploration data

South Greenland has been the site of historic mining of cryolite, copper, graphite and gold, hosts mineral deposits with gold, uranium, zinc, niobium, tantalum, zirconium, hafnium, REE, iron, titanium, vanadium, fluorite and graphite, and has additional potential for lithium, beryllium, phosphorus, gallium and thorium. Data from stream sediment geochemical surveys document that South Greenland is enriched in a range of these elements relative to the rest of Greenland and to estimates of the upper crust composition. Distribution patterns for individual elements within south Greenland exhibit enriched regions that are spatially related to lithological units, crustal structure and known mineralisation.The Northern Domain of South Greenland includes the southernmost part of the orthogneiss-dominated North Atlantic craton. Orogenic gold mineralisation is hosted by quartz veins and hydrothermally altered rocks associated with shear zones intersecting the Mesoarchaean Tartoq Group of mafic metavolcanic rocks. Geochemical exploration indicates that additional potential for gold mineralisation exists within Palaeoproterozoic supracrustal rocks overlying the Archaean basement.Rocks formed during the Palaeoproterozoic Ketilidian orogeny occupy a major part of South Greenland and has been divided into two domains. The Central Domain is underlain by the Julianehåb igneous complex forming a 100 km wide ENE–WSW zone centrally across South Greenland. Intrusive and extrusive, mostly felsic magmatic rocks were emplaced in two main stages (1850–1830 and 1800–1780 Ma) in a continental arc setting. Positive anomalies in aeromagnetic data indicate that mafic plutons are common in the late igneous complex. Intra-arc mafic metavolcanic rocks contain syngenetic stratabound copper sulphide and epigenetic shear zone-hosted copper–silver–gold mineralisation at Kobberminebugt and Kangerluluk, whereas metasedimentary and metapyroclastic rocks contain stratabound uraninite mineralisation. Orthomagmatic iron–titanium–vanadium mineralisation is hosted by a gabbro. A potential for porphyry-type mineralisation related to the late intrusive stages of the Julianehåb igneous complex is suggested by showings with copper, molybdenum and gold together with stream sediment anomalies for these elements. Vein-type uranium mineralisation occurs in fault zones in the Julianehåb igneous complex related to Mesoproterozoic rifting.The Southern Domain contains an assemblage of Palaeoproterozoic metasedimentary and metavolcanic rocks that underwent moderate to strong deformation, peak HT–LP metamorphism and partial melting with subsequent retrograde exhumation at 1790–1765 Ma. The supracrustal rocks contain syngenetic Au, As, Sb, U, and Zn mineralisation in volcanic or graphite- and sulphide-rich sedimentary environments; graphite was mined historically at two sites. Many stream sediment gold anomalies are located in a NE-trending belt along the boundary between the early Julianehåb complex and the supracrustal rocks to the south. They reflect a number of auriferous quartz vein occurrences, including the Nalunaq gold deposit, hosted in a system of shear zones and probably generated as orogenic gold during Ketilidian accretion. The 1755–1730 Ma, A-type Ilua plutonic suite is the latest magmatic event in the Ketilidian orogen.The 1300–1140 Ma Gardar period involved continental rifting, sedimentation and alkaline magmatism. Numerous dykes and 10 ring-shaped intrusion complexes were formed across South Greenland. An orthomagmatic iron–titanium–vanadium deposit is hosted by troctolitic gabbro. Residual magmas and fluids resulting from extreme magmatic differentiation, possibly combined with assimilation of older crust, created mineral deposits including cryolite that was mined at Ivigtut, large low-grade deposits of uranium–rare earth elements–zinc at Kvanefjeld and tantalum–niobium–rare earth element–zirconium at Kringlerne, in the Ilímaussaq complex, as well as tantalum–niobium–rare earth elements at Motzfeldt Sø in the Igaliko complex.The South Greenland crustal evolution records effects of mantle processes, such as lithospheric extension, subduction and underplating, which resulted in recurrent magma emplacement in tectonically active environments. As such, the geology of South Greenland reflects events and circumstances that are favourable to the generation and preservation of hydrothermal ore-forming fluid systems during the Ketilidian orogeny as well as to the development of extreme rock compositions within the Gardar alkaline igneous province.     

U–Pb zircon geochronology and geochemistry from NE Vietnam: A ‘tectonically disputed’ territory between the Indochina and South China blocks

Volcanoplutonic complexes in NE Vietnam have recently been interpreted as intraplate products of the Emeishan plume. Alternatively, mafic–ultramafic rocks have been considered as dismembered Palaeotethyan ophiolites juxtaposed along a tectonic mélange zone. New U–Pb zircon geochronological and geochemical datasets presented here suggest a complex geological history that records collision between the Indochina–South China blocks. Mafic–ultramafic rocks exposed within a tectonic mélange (Song Hien Tectonic Zone) include sub-alkaline pillow basalts that define two geochemically distinct ophiolitic suites (SH-1: N-MORB-like, SH-2: transitional E-MORB-like). Both suites have geochemical signatures suggestive of crustal contamination, compatible with a volcanic passive margin/rift setting. We suggest that SH-1 basalts may correlate with the Devonian–Carboniferous Jinshajiang–Ailaoshan–Song Ma branch of the Palaeotethys and form part of the associated Dian–Qiong belt, whereas SH-2 basalts are co-magmatic with Middle–Late Permian mafic–ultramafic intrusive rocks (dolerites, gabbros, peridotites) that developed in a rift basin, most likely on the margin of the down-going South China plate during west-vergent subduction beneath Indochina. During continental orogenesis and thrust stacking, these ophiolitic rocks were juxtaposed with other lithotectonic blocks within the Song Hien Tectonic Zone. Post-collisional relaxation led to the development of a rift basin (Song Hien rift) comprising Late Permian–Triassic volcano-sedimentary strata including < 270–265 Ma terrigenous sandstones, < 252 Ma mudstones, and c. 254–248 Ma felsic effusives. Granites and granodiorites were emplaced across NE Vietnam between c. 252 and 245 Ma in a syn- to post-collisional setting. The Late Permian–Early Triassic felsic magmatic rocks best correlate with coeval rocks in SW Guangxi and the Central and Western Ailaoshan fold belts (China) and the Truong Son fold belt (Vietnam); together they signal the final to post-collisional stages of Indochina–South China collision. We demonstrate that the analysed magmatic rocks in the Lo-Gam–Song Hien domains of NE Vietnam are not genetically linked to the Emeishan Large Igneous Province in the Yangtze block of South China, as has been previously widely proposed.     

Reprint of “Depositional environment and tectonic implications of the Paleoproterozoic BIF in Changyi area,eastern North China Craton: Evidence from geochronology and geochemistry of the metamorphic wallrocks”

The Changyi banded iron formation (BIF) in the eastern North China Craton (NCC) occurs within the Paleoproterozoic Fenzishan Group. Three types of metamorphic wallrocks interbedded with the BIF bands are identified, including plagioclase gneisses and leptynites, garnet-bearing gneisses and amphibolites. Protolith reconstruction suggests that the protoliths of the plagioclase gneisses and leptynites are mainly graywackes with minor contribution of pelitic materials, the garnet-bearing gneisses are Fe-rich pelites contaminated by clastics, and the amphibolites are tholeiitic rocks. Trace elements of La, Th, Sc and Zr of the plagioclase gneisses and leptynites and the garnet-bearing gneisses support that these meta-sedimentary rocks were probably derived from recycling of Archean rocks with felsic and mafic materials differentiated into different rock types. ²⁰⁷Pb/²⁰⁶Pb ages of detrital zircons from the meta-sedimentary rocks concentrate at 2.7–3.0 Ga, confirming their derivation from the Archean rocks. The presence of several Paleoproterozoic detrital zircons (2240 to 2246 Ma), however, also suggests minor involvement of Paleoproterozoic materials. The Archean detrital zircons have ε_Hf(t) values varying from − 0.7 to 7.6, which mainly fall between the 3.0 Ga and 3.3 Ga average crustal evolution lines on the age vs. ε_Hf(t) diagram, further illustrating that the rocks providing materials for the meta-sedimentary rocks mainly originated from partial melting of a Mesoarchean crust. This is strongly supported by their crust-like trace element distribution patterns (such as Nb, Ta, P and Ti depletion) and ancient Nd depleted mantle model ages (T_DM = 2.9–3.4 Ga). In addition, the remarkably high ε_Hf(t) values (7.5 to 9.3) of the Paleoproterozoic detrital zircons constrain the Paleoproterozoic materials to originate from a depleted mantle. The amphibolites show low SiO₂ (46.5 to 52.8 wt.%) and high MgO (5.68 to 10.9 wt.%) contents, crust-like trace element features and low ε_Nd(t) values (− 4.5 to − 0.3), suggesting that these ortho-metamorphic rocks were mainly derived from subcontinental lithospheric mantle with some contamination by Archean crustal materials. Since an intra-continental environment was required for the formation of the above metamorphic rocks, these rocks not only confine the depositional environment of the Changyi BIF to be an intra-continental rift, but also support the rifting processes of the eastern NCC during Paleoproterozoic.     

Petrology,geochemistry, and geochronology of Paleoproterozoic volcanic and granitic rocks (1.89–1.88 Ga) of the Pitinga Province,Amazonian Craton,Brazil

This paper presents geochemical, petrographic, and geochronological data on the Uatumã magmatism in the Pitinga Province, where it is represented by volcanic rocks from the Iricoumé Group and granitic rocks from the Mapuera Suite. The Iricoumé Group (1.89–1.88 Ga) is constituted of the Divisor Formation (intermediate volcanic rocks), Ouro Preto Formation (acid effusive rocks), and Paraiso Formation (acid crystal-rich ignimbrites, surge deposits, and basic rocks). The volcanic sequence is intruded by granitoids from the Mapuera Suite (1.88 Ga), mainly represented by monzogranites and syenogranites. Structural and field relations suggest that caldera complex collapse controlled the emplacement of volcanics and granitoids of the Mapuera Suite. Subsequent structure reactivations allowed the younger Madeira Suite (1.82–1.81 Ga) to be emplaced in the central portion of the caldera complex. The felsic Iricoumé magmatism is mainly composed of rhyolites, trachydacites and latites, with SiO₂ contents between 64 wt% and 80 wt%. The plutonic rocks from the Mapuera Suite present SiO₂ between 65 wt% and 77 wt%. Volcanic and granitic rocks present identical geochemical characteristics and that is attributed to their co-magmatic character. The felsic volcanic rocks and granites are metaluminous to slightly peraluminous and show affinity with silica-saturated alkaline series or with A-type magmas. They have Na₂O + K₂O between 6.6% and 10.4%, FeO^t/(FeO^t + MgO) varying between 0.76 and 0.99, Ga/Al ratios between 1.5 and 4.9, like typical A-type rocks; and plot in the within-plate or post-collisional fields in the (Nb + Y) vs. Rb diagram. The Nb/Y ratios indicate that these rocks are comparable to A2-type granites. This magmatism can be related to the (i) potassic alkaline series, with low Sr content in the felsic rocks explained by plagioclase fractionation at low pressure and high temperature or, alternatively, (ii) a bimodal association where magma had high crustal influence. The similarity of the Iricoumé felsic magmatism with A2-type granitoids and their high ETRL/Nb ratios suggest its relation with mantle sources previously modified by subduction, probably in a post-collision environment. Alternatively, this can be interpreted as bimodal within-plate magmatism with contamination by crustal melts. In this context, the extreme F, Nb and Zr enrichment of Madeira Suite could be explained by the presence of a thin crust which favored the presence and continuity of convective systems in the upper mantle.     

Formation and evolution of Precambrian continental lithosphere in South China

An overview is presented for the formation and evolution of Precambrian continental lithosphere in South China. This is primarily based on an integrated study of zircon U–Pb ages and Lu–Hf isotopes in crustal rocks, with additional constraints from Re–Os isotopes in mantle-derived rocks. Available Re–Os isotope data on xenolith peridotites suggest that the oldest subcontinental lithospheric mantle beneath South China is primarily of Paleoproterozoic age. The zircon U–Pb ages and Lu–Hf isotope studies reveal growth and reworking of the juvenile crust at different ages. Both the Yangtze and Cathaysia terranes contain crustal materials of Archean U–Pb ages. Nevertheless, zircon U–Pb ages exhibit two peaks at 2.9–3.0 Ga and ~ 2.5 Ga in Yangtze but only one peak at ~ 2.5 Ga in Cathaysia. Both massive rocks and crustal remnants (i.e., zircon) of Archean U–Pb ages occur in Yangtze, but only crustal remnants of Archean U–Pb ages occur in Cathaysia. Zircon U–Pb and Lu–Hf isotopes in the Kongling complex of Yangtze suggest the earliest episode of crustal growth in the Paleoarchean and two episodes of crustal reworking at 3.1–3.3 Ga and 2.8–3.0 Ga. Both negative and positive ε_Hf(t) values are associated with Archean U–Pb ages of zircon in South China, indicating both the growth of juvenile crust and the reworking of ancient crust in the Archean. Paleoproterozoic rocks in Yangtze exhibit four groups of U–Pb ages at 2.1 Ga, 1.9–2.0 Ga, ~ 1.85 Ga and ~ 1.7 Ga, respectively. They are associated not only with reworking of the ancient Archean crust in the interior of Yangtze, but also with the growth of the contemporaneous juvenile crust in the periphery of Yangtze. In contrast, Paleoproterozoic rocks in Cathaysia were primarily derived from reworking of Archean crust at 1.8–1.9 Ga. The exposure of Mesoproterozoic rocks are very limited in South China, but zircon Hf model ages suggest the growth of juvenile crust in this period due to island arc magmatism of the Grenvillian oceanic subduction. Magmatic rocks of middle Neoproterozoic U–Pb ages are widespread in South China, exhibiting two peaks at about 830–800 Ma and 780–740 Ma, respectively. Both negative and positive ε_Hf(t) values are associated with the middle Neoproterozoic U–Pb ages of zircon, suggesting not only growth and reworking of the juvenile Mesoproterozoic crust but also reworking of the ancient Archean and Paleoproterozoic crust in the middle Neoproterozoic. The tectonic setting for this period of magmatism would be transformed from arc–continent collision to continental rifting with reference to the plate tectonic regime in South China.