Structural and tectonostratigraphic evolution of the Upper Cretaceous–Eocene sequence in Malaqet–Mundassah–El Saah Range,Oman Mountains,United Arab Emirates and Oman

The Malaqet–Mundassah area lies on the western flank of the Northern Oman Mountains in the UAE and Oman. This area is a well-exposed example of Alpine thrusted and folded Ophiolitic assemblage and post-obduction autochthonous sequences. The hinge zones of the thrust propagation folds accommodated stronger deformation compared with the weaker deformation that occurred in the other parts of these folds. In this area, there have been three main tectonic shortening events, two associated with the formation of unconformities (pre-Late Campanian and Cretaceous/Tertiary) and one during the deposition of megabreccia and conglomerates units (Early–Middle Eocene). Each event continued mildly during the deposition of sediments above. Tectonism was accompanied by sea level changes so that the Malaqet–Mundassah area experienced two marine regressions and two transgressions between the Late Cretaceous and the Oligocene times. Activity of northwest striking (NE-dipping) thrust faults and similarly trending thrust-propagation folds is responsible for the formation of a local basin, the Malaqet–El Saah basin in which the Simsima, Muthaymimah, Saah, and Tawi Uwayyir formations of the area were deposited. The syn-sedimentary activity of thrusts, folds and strike-slip faults is documented in thickness variations, stratigraphic onlapping of formations towards the fold hinges, and the presence of megabreccia and conglomerate deposits not found elsewhere in the foreland basin.     

Diagenesis of the Khuff Formation (Permian–Triassic), northern United Arab Emirates

This diagenetic study (including fieldwork, petrographic, fluid inclusion, and stable isotope investigations) deals with the outcrop of Upper Permian–Lower Triassic carbonate rocks, which are equivalent to the Khuff Formation. The studied succession, which outcrops in the Ras Al Khaimah region, northern United Arab Emirates, comprises three formations, including the Bih, the Hagil, and the Ghail formations. The study focuses on unraveling the conditions and fluid compositions encountered during diagenesis of the succession. Emphasize is also made on linking diagenesis to major stratigraphic surfaces and to highlight reservoir property evolution and heterogeneity of the studied rocks. The evolution of fluids and related diagenetic products can be summarized as follows: (1) formation of near-surface to shallow burial, fine-crystalline dolomite (dolomite matrix) through pervasive dolomitization of carbonate sediments by modified marine pore waters; (2) formation of coarse-crystalline dolomite cement by highly evolved marine pore waters (13–23 wt.% NaCl eq.) at elevated temperatures (120–208°C), and (3) calcite cementation by highly saline fluid (20–23 wt.% NaCl eq.) at high temperature (170–212°C). A final calcite cement generation has been formed by the percolation of meteoric fluids during uplift. Fracture- and vug-filling diagenetic minerals are mainly restricted to the mid-Bih breccia marker level, suggesting preferential focused fluid flow through specific stratigraphic surfaces as well as along tectonic-related structures. Reservoir properties have been evolved as result of the interplay of the original sedimentary texture and the diagenetic evolution. Porosity is higher in the Bih Formation, which is dominated by dolomitized packstones and grainstones, than in the Hagil and Ghail formations, consisting mainly of dolomitized mudstones and wackestones. Image analyses were used to quantify the visual porosity in thin sections. The highest porosity values were measured in the Bih Formation, which is characterized by significant amounts of vug- and fracture-filling cements. This feature is attributed to the increase of porosity owing to substantial dissolution of abundant intergranular and vug-filling cements. In contrast, the Hagil and Ghail formations, which consist of finer-grained rock than the Bih Formation, were less cemented, and thus, the porosity enhancement by cement dissolution was insignificant.     

Hydrogeochemistry and pollution assessment of quaternary–tertiary aquifer in the Liwa area,United Arab Emirates

This study presents the data on the hydrochemical characteristics and isotope chemistry of Liwa aquifer, which could be useful to clarify the hydrochemical facies and hydrogeological regime in the study area. Electric conductivity and total dissolved solid values show that the investigated water is slightly brackish, due to the effect of evaporation and the occurrences of evaporite rocks in the adjacent Sabkhas of Abu Dhabi. Major cations and anions arranged according to their decreasing concentrations are: Na⁺ > Ca⁺² > K⁺ > Mg⁺² and Cl⁻ > HCO₃ ⁻ > SO₄⁻², respectively. As sodium is the dominate cation and chloride is the prevailing anion, hydrochemically the groundwater of Liwa can be classified as Na–Cl rich, predominantly chloridic. Ion concentrations increase towards the northeast and presumably coincide with the lithological sources of ions. Factors affecting the hydrochemistry of the groundwater of the investigated area include the effect of weathering of soil and rocks, evaporation and agricultural activities. Stable isotopes of oxygen and hydrogen show that the shallow aquifers contain a single water type that originated in a distinct climatic regime. This water type deviates from the local meteoric water line, as well as from the Eastern Mediterranean Meteoric Water Line, suggesting potential evaporation of recharged water prior to infiltration. The waters are poor in tritium, and thus can be considered generally as indication for recharge prior to 1952. The degradation of groundwater quality can be attributed to evaporation and agricultural practices in most cases.     

Chondrichthyans from the Menuha Formation (Late Cretaceous: Santonian–Early Campanian) of the Makhtesh Ramon region,southern Israel

Exposures of the Menuha Formation (Santonian–Early Campanian, Mount Scopus Group) in the Makhtesh Ramon region of the southern Negev have produced numerous chondrichthyan teeth. The isolated teeth represent at least ten different species: Cretalamna appendiculata, Cretoxyrhina mantelli, Squalicorax falcatus?, S. kaupi, Scapanorhynchus rapax, S. raphiodon?, Carcharias samhammeri, Carcharias cf. C. holmdelensis?, and two other fish (Hadrodus priscus and a pycnodont). This assemblage has important implications for Late Cretaceous chondrichthyan palaeobiogeography. The majority of teeth were contained within a glauconite-rich, yellow-brown, soft chalk that included oysters (Pycnodonte vesicularis?), trace fossils (Planolites, Thalassinoides, and Chondrites), phosphatic peloids, and foraminiferans (globigerinids). The teeth were collected mainly through surface-sampling and sieving. The Menuha Formation probably represents a temperate to subtropical, shallow, open-shelf environment deposited during the formation of the Ramon anticline. Reworked conglomeratic chalks in the western section represent marginal facies derived from this structural uplift. With little to no published material describing the chondrichthyan fauna of the Menuha Formation, these data improve interpretations of its palaeoenvironment. Interpretation of the palaeoenvironment of the formation is important for understanding the larger stratigraphic/tectonic framework of the Ramon monocline region of southern Israel.     

The diverse Cretaceous neobatrachian fauna of South America: Uberabatrachus carvalhoi,a new frog from the Maastrichtian Marília Formation,Minas Gerais,Brazil

Herein we report on a new anuran genus and species, Uberabatrachus carvalhoi, from exposures of the Marília Formation (Maastrichtian) at the well-known fossil site “Ponto 1 do Price” near Peirópolis, Uberaba, Brazil. The holotype consists of an articulated partial skeleton characterized by a broad, well-ossified skull lacking dermal ornamentation, eight procoelous presacral vertebrae, and posteriorly deflected, cylindrical sacral diapophyses; these features, together with the possible presence of a discrete palatine, are consistent with neobatrachian affinities. It clearly differs from the neobatrachian Baurubatrachus, also from the Marília Formation, in having a skull lacking exostosis and with a different temporal architecture, among other features. It also differs from the still unnamed neobatrachian recovered from the Adamatina Formation in the presence of paired frontoparietals with narrow supraorbital flanges in the anterior orbital region and maxilla-squamosal contact. The new frog is not referable to any of the neobatrachian taxa known from the Aptian–Albian Crato Formation owing to different cranial features (e.g., position of the jaw articulation, relative width of the braincase, and morphology of the frontoparietal). With respect to the extant neobatrachians in the context of recent phylogenetic hypotheses, the cylindrical sacral diapophyses of Uberabatrachus contrast with the dilated diapophyses occurring in australobatrachian hyloids and microhyloid ranoids, whereas the procoelous presacral column is unlike the diplasiocoelous condition of most other ranoids. This evidence together with the combination of features of Uberabatrachus suggests a placement among nobleobatrachian hyloids, although this combination is not shared with any extant or extinct species for which skeletal information is known. From the foregoing we conclude that Uberabatrachus represents a new nobleobatrachian taxon, a record that reinforces the hypothesis of a diversified neobatrachian fauna in South America by the Cretaceous and is consistent with the previous proposal that neobatrachian early diversification is related to the breakup of Gondwana.     

Taxonomy and paleoecology of a new gastropod fauna from dysoxic outer ramp facies of the Lower Cretaceous Agrio Formation,Neuquén Basin,west-central Argentina

Four gastropod species are described from dysaerobic biofacies of the lower part of the Agua de la Mula Member of the Agrio Formation, Neuquén Basin: Metacerithium turriculatum (Forbes, 1845), Nerineopsis acutecarinatum (Behrendsen, 1891) and the new species Ampullina pichinka and Mesalia? kushea. They were active epifaunals and possibly deposit-feeders and/or browsers, and epifaunal to semi-infaunal possibly suspension- or deposit-feeder in the case of M.? kushea, thriving in soft to firm substrates. These gastropods, together with two aporrhaid species, are the dominant components of a typically small-sized, low-diversity macrobenthic fauna that occurs in dark, organic-rich shales. The facies in which this fauna is recorded are thought to represent a transition from lower to upper outer ramp marine settings, in the context of a second-order TST and early stages of a HST. They record a transition from lower dysoxic conditions in the lowest part of the Agua de la Mula Member to upper dysoxic conditions upwards. Two distinct gastropod biofacies were recognized corresponding to the two identified stages: biofacies A, dominated by Protohemichenopus neuquensis and N. acutecarinatum, more tolerant to dysoxic conditions, and biofacies B, dominated by M. turriculatum and Mesalia? kushea, less tolerant to oxygen deficiency.     

First known Cretaceous glaciation: Livingston Tillite Member of the Cadna‐owie Formation,South Australia

A 2 m‐thick diamictite occurs near the base of the Cretaceous Eromanga Basin succession at Trinity Well, at the northern extremity of the Flinders Ranges in South Australia. The diamictite consists of a matrix of silt‐ and clay‐size particles and a framework of sand and coarser materials up to small boulder size. Scanning electron microscope study reveals the presence of numerous quartz grains displaying extreme angularity and surface textures attributed to glacial crushing. Sandy sediments considered as fluvioglacial in origin and a locally developed facies displaying flow structures attributed to solifluction processes constitute the basal 3–5 m of the sequence. In places these directly underlie the diamictite and rest with angularity on Neoproterozoic Adelaidean strata. Conformably above the diamictite at the type locality ‘Recorder Hill’ is a sequence approximately 15 m thick of fine sand and silt units containing lonestones up to ～70 cm diameter and hummocky cross‐stratification. These sediments have been assigned to the Cadna‐owie Formation and are dated on palynology as Berriasian to Valanginian. The occurrence of diamictite containing glacially affected quartz grains contributes to our interpretation that the southern margin of the Eromanga Basin, and at least the adjacent part of the northern Flinders Ranges, were affected by glaciation in the Early Cretaceous. The associated dropstone and solifluction facies and nearby glendonite pseudomorphs after ikaite are further evidence of at least intermittent cold climates at this time.     

First occurrence of tyrannosaurid theropods from the Corral de Enmedio Formation (Upper Cretaceous) Sonora,México

The Cabullona Basin in the state of Sonora, Mexico is becoming recognized due to its diversity of southern Laramidian continental vertebrates, especially dinosaurs. In this study we describe and analyze three theropod teeth (ERNO specimens) that were found isolated and surface collected in the Corral de Enmedio Formation (Cabullona Group, Upper Cretaceous). The three specimens possess similar morphological characteristics that match the ones present in Late Cretaceous Laramidian tyrannosaurids, so they were referred to the Tyrannosauridae, probably belonging to a new unknown taxon. The implementation of statistical and cladistic analyses corroborated their taxonomical assignment. ERNO specimens correspond to the first record of tyrannosaurid dinosaurs in the basal Corral de Enmedio Formation, extending the stratigraphic distribution of these dinosaurs in the Cabullona Basin. Although tyrannosaurids have been previously described in the Cabullona Basin, the ERNO specimens of the Corral de Enmedio Formation seem to be different, because they possess more labiolingually compressed teeth. This new evidence could indicate a higher taxonomic diversity of the tyrannosaurid theropods that were present in the Cabullona Basin, adding more information to the Tyrannosauridae diversification on one of the most southern Laramidian regions during the Late Cretaceous.     

Teaching GIS in the Gulf Co-operation Council Universities – With a case study of the geography department, University of the United Arab Emirates

Within universities there has developed a clear theoretical convergence between Geographical Information Systems (GIS) and geography (Antenuccl, 1991). Studies have revealed that one of the qualified departments to teach GIS within universities is the geography department. This study focuses on: the importance of establishing GIS as a major curriculum element within universities. In geography departments, economic geography students require a strong statistical/mathematical background to allow them to work with major databases. They should know how to design a specific database for economic activities, such as agriculture and manufacturing, and tertiary industry and how to relate this database to a map, so that changes can be monitored more accurately. In any aspect of geography spatial location is a key factor and GIS allows spatial patterns to be interpreted with great facility. Therefore it is important that students have a good knowledge not only of computers and related software on economic geography, but also on GIS systems (Burrough, 1993). The work of geography students from the United Arab Emirates (UAE) and other Gulf Co-operation Council (GCC) geography departments is examined to evaluate the importance of training in GIS technology. This paper evaluates the effects of implementing GIS as a tool in teaching economic geography. At present there are 15 geography departments in the GCC which offer economic geography. Of those 15 departments, only 3 provide GIS courses within their curriculum, and 4 have basic equipment, although 6 additional departments are to introduce GIS in the near future. This revised version was published online in July 2006 with corrections to the Cover Date.     

Late Cretaceous (Campanian/Maastrichtian) freshwater to restricted marine mollusc fauna from the Loncoche Formation,Neuquén Basin,west-central Argentina

This study is the first detailed account of freshwater to restricted marine molluscs from the Upper Cretaceous sedimentary rocks in the northern sector of the Neuquén Basin. The fossils are from the Campanian–Maastrichtian Loncoche Formation in southern Mendoza, west-central Argentina, which records the initial connection of the Neuquén Basin to the Atlantic Ocean. Six species of bivalves (Diplodon bodenbenderi, Pleiodon? sp., Isognomon? mechanquilensis, Mactridae? indet., Panopea? sp., and Laternula sp.) and three of gastropods (Paleoanculosa macrochilinoides, Paleoanculosa ameghiniana, and a possible cerithioidean) are described. Specimens were collected from fine to coarse sandstones, which may be massive or with planar stratification, planar-cross stratification or trough-cross stratification, and a few from bioclastic limestones and mudstones. Although the sections are from 50 to 300 m thick, the specimens are found only in the lower 120 m. Molluscs represent autochthonous/parautochthonous assemblages composed of mostly non-broken gastropods and articulated bivalve specimens, some of which show signs of postmortem transport; however, they were not removed far from their original habitat. Review of the habitats of living genera supports the inference of dominantly freshwater palaeoenvironments in the lower and middle part of the Loncoche Formation, with restricted marine influence in the southernmost localities studied where there are a few samples that contain specimens belonging to predominantly marine groups (e.g., Laternula, Panopea).     

Lithofacies attributes, depositional system and diagenetic properties of the Permian Gharif Formation from Haushi–Huqf area, Central Oman

Over 70 m thick interbedded sandstone, siltstone and claystone of the upper member of the Gharif Formation are exposed in western Huqf area in Oman Interior Sedimentary Basin. The Gharif Formation, particularly its upper member hosts major hydrocarbon reservoir in the subsurface of the Oman Interior Sedimentary Basin. The upper member of the Gharif Formation is comprised of interbedded thick sandstone, siltstone, carbonaceous clays and intraformational conglomerates. The sandstone lithofacies, on average, constitute 10 m thick multistoreyed sequences, which are composed internally of 2–3 m thick and 100 s of metres across vertically and laterally amalgamated sandstone bodies. Two major types of sandstones (types 1 and 2) are identified on the basis of their lithofacies association and internal architecture. The type 1 sandstone constitutes the lower part of the member and is comprised of pebbly to coarse-grained, planar and trough cross-bedded sandstone, plane bedded sandstone and pebble lags at the base of major sandstone bodies. The cross-beds are, on average, 30 cm thick exhibiting a dominant paleoflow direction towards NW (280–300° N). It is interpreted to be deposited by low sinuosity braided streams. The type 2 sandstone constitutes the upper part of the member and is comprised of medium-grained sandstone, trough to low angle plane bedding associated with lateral accretion surfaces. It is commonly interbedded with carbonaceous clays. Silicified plant fragments are commonly distributed in the upper part of the sandstone. Interbedded clays and siltstones are red, mottled and extensively bioturbated due to root burrows. It is interpreted to be deposited by high sinuosity meandering streams. In the uppermost part of the section, several dark grey to black carbonaceous clay/coal beds with plant matter are interbedded with sandstone and red clay indicating development of swampy conditions during onset of the coastal setting in the uppermost part of the formation. About 30 cm thick bioclastic sandstone deposited by the marine coastal bars mark transition from the Gharif Formation to carbonate dominated Khuff Formation. The sandstone of the Gharif Formation is arkosic in composition. Very small amount of cement and negligible compaction of constituent grains in sandstone indicates shallow burial before uplift.     

Toarcian–Aalenian (Early–Middle Jurassic) radiolarian fauna from the Los Molles Formation,Neuquén Basin,Argentina: Taxonomy and paleobiogeographic affinities

This paper reports the occurrence of a Toarcian–Aalenian (Early–Middle Jurassic) radiolarian fauna in the Los Molles Formation, Neuquén Basin, Argentina, as well as comments on its paleobiogeographic affinities. The micropaleontologic analysis was carried out in fine-grained rocks from a turbiditic section of the Los Molles Formation. These samples were first chemically processed using only hydrogen peroxide (H₂O₂), and afterward treated with acetic (CH₃COOH) and hydrofluoric (HF) acids. The first chemical procedure permitted the recovery of only few spongy spumellarians, while the second one enabled to recover more diversified radiolarian assemblages. In general, the studied fauna presents low diversity and abundance, with a strong dominance of spumellarians over nassellarians. The fauna is composed by the genera Paronaella, Homoeoparonaella, Praeconocaryomma, Archaeocenosphaera, Orbiculiformella, Praeparvicingula, and some unidentified spumellarians and nassellarians. According to paleobiogeographic models, the studied Toarcian–Aalenian fauna presents a mid to high latitude affinity. It is possible to infer from those data a bipolar distribution of some taxa, such as Praeparvicingula and probably Praeconocaryomma, between the Northern and Southern hemispheres since the Early Jurassic (Toarcian).     

Upper Cretaceous carbonate hosted zinc–lead–barite deposits in Northern Thrust Zone, northern Iraq: petrography and geochemistry

Zinc–lead–barite deposits located in Lefan and Lower Banik localities of about 25 km northeast of Zakho City, Northern Iraq consist of a group of strata-bound sulfides hosted in Upper Cretaceous (Upper Campanian–Maastrichtian) dolomitic limestone. Carbonate-hosted ores contain 3.77% Zn, 2% Pb, and 5% Fe, while in lower Banik, they contain 1.5% Zn, 0.37% Pb, and 1.4% Fe. Diagenetic processes, such as dolomitization and recrystalization in addition to the type of microfacies, provided appropriate physical and chemical conditions that permitted the passage of ore-bearing fluids and participated in precipitation and ore localization. These deposits are precipitated in a platform and developed within the Foreland Thrust Belt. Ore precipitated as infill of intergranular dolomite porosity with replaced dolomite and rudist shells forming disseminated crystals that occupy intergranular pore spaces around dolomite and calcite and as infill of dissolution spaces and fractures.     

Microfacies and age of the Ceahlău Massif carbonate olistoliths (Eastern Carpathians,Romania): Remnants of a lowermost Cretaceous carbonate platform

We carried out a comprehensive facies/microfacies, micropalaeontological and biostratigraphical analysis of several carbonate olistoliths incorporated within a widely developed Albian conglomeratic sequence from the Eastern Carpathians of Romania. The majority of the sampled olistoliths contain a rich assemblage of benthic foraminifera and calcareous green algae. All of the described microfossils represent common lowermost Cretaceous taxa not previously reported from these carbonate elements or from this region. Based on benthic foraminifera assemblages the age of the studied olistoliths is upper Berriasian–lower Valanginian, contrary to the general belief that they are Barremian–Aptian in age. The dominant microfacies types mainly reflect deposition in shallow-water environments and show similarities with synchronous platform carbonates of the central-western Neotethys Ocean. The micropalaeontological and sedimentological data support new interpretations concerning the source area of these carbonate elements and provide new information concerning the evolution of the lowermost Cretaceous carbonate platforms of the Carpathians.     

Propeamussiidae,Inoceramidae, and other Bivalvia from the Lower Cretaceous Puez Formation (Valanginian–Cenomanian; Dolomites,South Tyrol,Italy)

A bivalve assemblage from the Lower Cretaceous Puez Formation at the type locality, Piz de Puez (Dolomites, South Tyrol, northern Italy) is described. Given the large amount of sedimentary rock screened during the course of this study, the <50 bivalves examined here, although occurring in very low abundance, are considered to represent a reasonably comprehensive sample. The assemblage provides insight into an autochthonous, Mesozoic, deep-water bivalve community, which was dominated by glass scallops. Two species are described as new, Parvamussium pizpuezense n. sp. and the giant P. mordsdrum n. sp. Presumably, they lived as epifaunal-reclining carnivores and preyed on various meiofauna, occupying a similar ecologic niche as their modern counterparts. Scarce epifaunal, suspension-feeding Inoceramidae entered only by occasional recruitment of larvae into an environment that is inferred to have been characterised by low levels of suspended nutrients.     

The oldest theropods from the Neuquén Basin: Predatory dinosaur diversity from the Bajada Colorada Formation (Lower Cretaceous: Berriasian–Valanginian), Neuquén,Argentina

Here, we describe new theropod materials (several isolated teeth, an axis, two caudal centra and a proximal left tibia) from the type locality of the Bajada Colorada Formation (Lower Cretaceous, Berriasian–Valanginian). Although fragmentary, the recovered material shows a diverse association of meat-eating dinosaurs for this poorly understood period of time. Three techniques were used to assess the phylogenetic position of the isolated teeth: multivariate (PCA), discriminant and phylogenetic analyses. The morphotypes 1, 2 and 3 (small non-recurved isolated crowns) were regarded as Theropoda indet., as our analyses failed to support a more precise classification. Two large almost complete ziphodont crowns, considered morphotype 4, were identified as belonging to megalosaurid tetanurans by phylogenetic, discriminant and multivariate analyses, thus likely representing the first record of this ancient family in South America, and the youngest worldwide. We refer the axis to a small abelisauroid ceratosaurian based on the following suite of characters; long and pointed epipophyses, a pneumatic foramen in the centrum, the invaginated spinopostzygapophyseal lamina, and the anteroposteriorly long, dorsally convex, and dorsally/posteriorly unexpanded neural spine. The caudal centra can be referred to a theropod, and tentatively to Abelisauroidea, suggesting that they may belong to the same taxon than that represented by the axis. The tibia lacks the incisura tibialis, presents a low, sharp and proximally positioned fibular crest, and has a deep lateral fossa, which is limited dorsally by a coarse, rounded in section and anteriorly directed crest. This combination of features allows to refer it to a large abelisaurid. The Bajada Colorada dinosaur record includes so far a small abelisauroid, a large abelisaurid, a probably medium to large megalosaurid tetanuran, diplodocid and dicraeosaurid sauropods. It shows some similarities with Middle and Upper Jurassic units in central Patagonia, Africa and Portugal, suggesting that no significant dinosaur faunal turnover took place through the Jurassic-Cretaceous event in the southern part of South America.     

Mobility and potential bioavailability of traffic-derived trace metals in a ‘wet–dry’ tropical region,Northern Australia

The aqueous mobility and potential bioavailability of metals and metalloids in road runoff in a ‘wet–dry’ tropical location were assessed by analysing metal and metalloid concentrations in particulate, total dissolved and labile dissolved phases in runoff waters. Road-derived Al, Cu, Pb, Sb and Zn concentrations were substantially elevated in runoff when compared to receiving creek waters. Median dissolved concentrations in road runoff exceeded those in creek waters by up to an order of magnitude. Leaching experiments of road sediments confirmed that several metals and metalloids were released in high concentrations from road sediments. Labile Zn and Cu concentrations measured by diffusion gradients in thin films (DGT) showed that almost all dissolved Zn and up to half of dissolved Cu in runoff waters and in road sediment leachate were potentially bioavailable. Comparisons of dissolved metal concentrations in receiving waters affected by road runoff with ecosystem guideline levels, indicated a risk of reaching toxic levels of Cu and Zn in the receiving waters in the absence of adequate treatment or dilution. Low dilution rates of road runoff are likely to occur during late ‘dry’ season/early ‘wet’ season storms which have the potential to produce high metal concentrations derived from long periods of accumulation of road sediment at a time when creek flow rates are at their annual minimum.     

First discovery of a Palaeoproterozoic A-type granite in southern Wuyishan terrane,Cathaysia Block: evidence from geochronology,geochemistry, and Nd–Hf–O isotopes

In this study, a combined study of zircon U–Pb and Hf–O isotopes, as well as whole-rock major and trace elements and Nd isotopes has been conducted for Yangjia gneissic granite from the southern Wuyishan terrane, Southeast China, to constrain its petrogenesis and provide a new window for investigating the tectonic evolution of the Cathaysia basement. U–Pb dating for magmatic zircons yields a ²⁰⁷Pb/²⁰⁶Pb age of ca. 1.80 Ga, interpreted as the emplacement age of the Yangjia granite. The granites have relatively high K₂O, Rb, Ga, Zr, Nb, Y, and Ce contents and show low Al₂O₃, CaO, and Ba concentrations. Their 10,000*Ga/Al ratios range between 2.8 and 3.2. Zircons from the granite have ε_Hf(t) values ranging from ?13.2 to ?7.2, corresponding to T^Hf_DM2 model ages of 2.99 Ga to 2.72 Ga. The zircon δ¹⁸O values range between 6.7‰ and 9.1‰ with an average of 7.7‰. In addition, the whole-rock ε_Nd(t) values of the granites range from ?6.5 to ?5.4 and the T^Nd_DM2 model ages from 2.73 Ga to 2.82 Ga. All these geochemical and Nd–Hf–O isotopic signatures suggest an A-type affinity for the Yangjia granites, and they were likely generated by partial melting of Palaeoproterozoic parametamorphic rocks of the Wuyishan terrane in a post-collisional extensional setting. When our data is combined with existing geochronological data, it provides further evidence for the Palaeoproterozoic basement in the southern Wuyishan terrane, which records a rapid tectonic transition from post-collision to intraplate extension (1.80–1.77 Ga) related to the break-up of the supercontinent Columbia.