Tooting crater: Geology and geomorphology of the archetype large,fresh, impact crater on Mars

The 27.2 km diameter Tooting crater is the best preserved young impact crater of its size on Mars. It offers an unprecedented opportunity to study impact-related phenomena as well the geology of the crust in the Amazonis Planitia region of Mars. For example, the nearly pristine condition enables the partial reconstruction of the sequence of events for crater formation, as well as facilitates a comparison to deposits seen at the Ries crater in Germany. High-resolution images taken by the High Resolution Imaging Science Experiment (HiRISE) and Context Camera (CTX) on the Mars Reconnaissance Orbiter spacecraft have revealed a wealth of information on the distribution of features within the crater and beyond the rim: a large central peak, pitted material on the floor and terrace blocks, lobate flows interpreted to be sediment flows, impact melt sheets, four discrete layers of ejecta, and an asymmetric secondary crater field. Topographic data derived from the Mars Orbiter Laser Altimeter (MOLA) and stereo HiRISE and CTX images show that the central peak is ～1100 m high, the lowest point of the crater floor is 1274 m below the highest part of the rim, and the crater rim has ～600 m of variability around its perimeter. Layering within the cavity walls indicates ～260 m of structural uplift of the target material, which constitutes ～35% of the total relief of the rim. Abundant evidence is found for water flowing down the cavity walls, and on the surface of the ejecta layers, both of which took place sometime after the impact event. Thickness measurements of the ejecta layers reveal that the continuous blanket is remarkably thin (～3–5 m) in some places, and that the distal ramparts may be ～60 m high. Crater counts made on the ejecta layers indicate a model age of <3 Ma for the formation of Tooting crater, and that the target rocks have a model age of ～240–375 Ma. It is therefore possible that this may be the source of certain basaltic shergottite meteorites ejected at ～2.8 Ma that have crystallization ages which are comparable to those of the basaltic lava flows that formed the target materials for this impact event. The geology and geomorphology of Tooting crater may help in the interpretation of older large impact craters on Mars, as well as the potential role of target volatiles in the impact cratering process.     

Evidence for shear heating,Musgrave Block,central Australia

The phenomenon of shear-heating is generally difficult to recognise from petrologic evidence alone. Establishing that shear zones attain higher temperatures than the surrounding country rocks requires independent evidence for temperature gradients. In the Musgrave Block, central Australia, there is a clear spatial association between shear zones and interpreted elevated temperatures. Eclogite facies shear zones that formed at ∼550 Ma record temperatures of ∼650–700°C. Outside the high-pressure shear zones, minerals with low closure temperatures such as biotite (∼450°C in the ⁴⁰Ar–³⁹Ar and Rb–Sr systems), preserve ages >800 Ma, suggesting that these rocks did not experience temperatures greater than about 450°C at ∼550 Ma for any extended period. Thus, the shear zones record temperatures that are ∼200°C higher than the surrounding country rocks. Simple calculations show that the combination of relatively high shear stresses (∼100 MPa) and high strain rates (∼10⁻¹¹ s⁻¹) for short durations (<1 Ma) can account for the observed apparent temperature variations. The evidence indicates that shear heating is the dominant mechanism for localised temperature increases in the shear zones, while the country rock remained at relatively lower temperatures.     

Evaluation of potential landslide damming: Case study of Urni landslide,Kinnaur, Satluj valley,India

This work aims to understand the process of potential landslide damming using slope failure mechanism,dam dimension and dam stability evaluation. The Urni landslide, situated on the right bank of the Satluj River, Himachal Pradesh(India) is taken as the case study. The Urni landslide has evolved into a complex landslide in the last two decade(2000-2016) and has dammed the Satluj River partially since year 2013,damaging ～200 m stretch of the National Highway(NH-05). The crown of the landslide exists at an altitude of ～2180-2190 m above msl, close to the Urni village that has a human population of about 500.The high resolution imagery shows ～50 m long landslide scarp and ～100 m long transverse cracks in the detached mass that implies potential for further slope failure movement. Further analysis shows that the landslide has attained an areal increase of 103,900 ± 1142 m^2 during year 2004-2016. About 86% of this areal increase occurred since year 2013. Abrupt increase in the annual mean rainfall is also observed since the year 2013. The extreme rainfall in the June, 2013; 11 June(～100 mm) and 16 June(～115 mm),are considered to be responsible for the slope failure in the Urni landslide that has partially dammed the river. The finite element modelling(FEM) based slope stability analysis revealed the shear strain in the order of 0.0-0.16 with 0.0-0.6 m total displacement in the detachment zone. Further, kinematic analysis indicated planar and wedge failure condition in the jointed rockmass. The debris flow runout simulation of the detached mass in the landslide showed a velocity of ～25 m/s with a flow height of ～15 m while it(debris flow) reaches the valley floor. Finally, it is also estimated that further slope failure may detach as much as 0.80 ±0.32 million m^3 mass that will completely dam the river to a height of 76±30 m above the river bed.     

Late Holocene moisture balance variability in the southwest Yukon Territory,Canada

Analyses of sediment cores from Marcella Lake, a small, hydrologically closed lake in the semi-arid southwest Yukon, provides effective moisture information for the last ∼4500 years at century-scale resolution. Water chemistry and oxygen isotope analyses from lakes and precipitation in the region indicate that Marcella Lake is currently enriched in ¹⁸O by summer evaporation. Past lake water values are inferred from oxygen isotope analyses of sedimentary endogenic carbonate in the form of algal Charophyte stem encrustations. A record of the δ¹⁸O composition of mean annual precipitation at Jellybean Lake, a nearby evaporation-insensitive system, provides data of simultaneous δ¹⁸O variations related to decade-to-century scale shifts in Aleutian Low intensity/position. The difference between the two isotope records, Δδ, represents ¹⁸O-enrichment in Marcella Lake water caused by summer effective moisture conditions. Results indicate increased effective moisture between ∼3000 and 1200 cal BP and two marked shifts toward increased aridity at ∼1200 and between 300 and 200 cal BP. These prominent late Holocene changes in effective moisture occurred simultaneously with changes in Aleutian Low circulation patterns over the Gulf of Alaska indicated by Jellybean Lake. The reconstructed climate patterns are consistent with the topographically controlled climatic heterogeneity observed in the coastal mountains and interior valleys of the region today.     

U–Pb isotopic dating of titanite microstructures: potential implications for the chronology and identification of large impact structures

Identifying and dating large impact structures is challenging, as many of the traditional shock indicator phases can be modified by post-impact processes. Refractory accessory phases, such as zircon, while faithful recorders of shock wave passage, commonly respond with partial U–Pb age resetting during impact events. Titanite is an accessory phase with lower Pb closure temperature than many other robust chronometers, but its potential as indicator and chronometer of impact-related processes remains poorly constrained. In this study, we examined titanite grains from the Sudbury (Ontario, Canada) and Vredefort (South Africa) impact structures, combining quantitative microstructural and U–Pb dating techniques. Titanite grains from both craters host planar microstructures and microtwins that show a common twin–host disorientation relationship of 74° about <102>. In the Vredefort impact structure, the microtwins deformed internally and developed high- and low-angle grain boundaries that resulted in the growth of neoblastic crystallites. U–Pb isotopic dating of magmatic titanite grains with deformation microtwins from the Sudbury impact structure yielded a ²⁰⁷Pb/²⁰⁶Pb age of 1851?±?12 Ma that records either the shock heating or the crater modification stage of the impact event. The titanite grains from the Vredefort impact structure yielded primarily pre-impact ages recording the cooling of the ultra-high-temperature Ventersdorp event, but domains with microtwins or planar microstructures show evidence of U–Pb isotopic disturbance. Despite that the identified microtwins are not diagnostic of shock-metamorphic processes, our contribution demonstrates that titanite has great potential to inform studies of the terrestrial impact crater record.     

Extensive impact melting on the H-chondrite parent asteroid during the cataclysmic bombardment of the early solar system: Evidence from the achondritic meteorite Dar al Gani 896

DaG 896 is an olivine-rich microporphyritic rock of komatiitic composition. Both the olivine composition (Fa_17.5±2.1, [Mn/Mg] = 0.0061) and the bulk oxygen isotopic composition (δ17O = +2.55, δ18O = +3.50) indicate that DaG 896 is a sample of the H-chondrite parent body. The bulk chemistry shows an H-chondritic distribution of lithophile elements, whereas chalcophile and siderophile elements are strongly depleted, indicating formation through whole-rock melting (or nearly so) of H-chondrite material, nearly complete loss of the metal plus sulfide component, and crystallization without significant igneous fractionation. Superheated, severely shocked chondritic relics (∼10 vol%), typically in the form of corroded lithic fragments <100 μm in size intimately distributed within the igneous lithology, indicate that melting was triggered by a highly energetic impact, which possibly induced shock pressures of ∼80-100 GPa. The relatively young 3.704 ± 0.035 Ga 40Ar-39Ar crystallization age is consistent with the impact melting origin, as magmatism in the asteroid belt was active only in the first hundred million years of solar system history.Based on textural data and thermodynamic crystallization modelling, we infer that DaG 896 crystallized from a liquidus temperature of ∼1630°C under relatively slow cooling rates (∼10°C h⁻¹) to ∼1300°C, before quenching. The two-stage cooling history indicates that a reasonable formation environment might be a dike intruding cooler basement below a crater floor. Metal-silicate fractionation may have been accomplished, at least at the centimeter-scale of the studied meteorite sample, through differential acceleration of immiscible liquids of different density during the intense flow regimes associated with the excavation and modification stages of the cratering mechanism. Alternatively, DaG 896 may represent a surface sample of a differentiated melt body at the floor of an impact crater, as gravitational settling appears to be an effective process at the surface of a chondritic parent asteroid: for metal particles 1 to 10 mm in size, typically observed in partially differentiated impact melt rocks, Stokes’ Law indicates a settling velocity >1 m h ⁻¹ during the first few hours of crystallization on asteroidal bodies of >25 km radius.The ∼3.7 Ga age of DaG 896 nearly overlaps with the slightly older resetting ages of H-chondrites (all impact melts) available from the literature, indicating that the H-chondrite parent asteroid underwent extensive impact melting at the enduring of the cataclysmic bombardment of the early solar system. Such an age overlap may also indicate early disruption of the initial H-chondrite parent asteroid.The close similarity between the bulk composition and degassing age of DaG 896 and silicate inclusions in IIE iron meteorites is further evidence in support of a common origin by impact melting and metal-silicate segregation on the H-chondrite parent asteroid. Our new high-precision oxygen isotopic measurements of H-chondrites (Δ17O = 0.77 ± 0.04) should be extended to IIEs to verify this possible petrogenetic link.     

Recrystallisation,phase mixing and strain localisation in peridotite during rapid extrusion of sub-arc mantle lithosphere

The Anita Peridotite, in southwestern New Zealand, is a ∼1 × 20 km ultramafic massif that was rapidly extruded from beneath a Cretaceous arc within the 4 km wide mylonitic Anita Shear Zone. The peridotitic body contains a spectacular array of textures that preserve evidence for changing temperature, stress, and deformation mechanisms during the exhumation process. Olivine and orthopyroxene microstructures and lattice-preferred orientations (LPO) record a three-phase deformation history. Dislocation glide on the C- and E-type slip systems is recorded by coarse pre-mylonitised olivine grains, and occurred under hydrous conditions at T ∼650 °C, stress ∼200–700 MPa and strain rate ∼10⁻¹⁵ s⁻¹, probably within hydrated sub-arc mantle lithosphere. Rare protomylonite pods record deformation by dislocation creep in porphyroclasts and dislocation-accommodated grain boundary sliding in the matrix on {0kl}[100] in olivine and (100)[001] in orthopyroxene, under conditions of T ∼730–770 °C, stress ∼52–700 MPa and strain rate ∼10⁻¹⁵ s⁻¹. The massif, however, is dominated by mylonite and ultramylonite that wrap the protomylonite pods, comprising mostly fine-grained olivine neoblasts that lack internal distortions and have uniform LPOs. These textures indicate deformation occurred by grain-size sensitive (GSS) creep at T ∼650 °C, stress ∼69–137 MPa and strain rate ∼10⁻¹⁵ s⁻¹, and thus during conditions of cooling and decreasing stress. GSS creep became more dominant with time, as the proportion of randomly-oriented neoblasts increased and formed interlinked networks that accommodated much of the strain. Grain boundary pinning allowed GSS creep to be maintained in polyphase regions, following mixing of olivine and orthopyroxene, which may have occurred by grain boundary transport in a fluid phase during a “creep cavitation” process. The results indicate that the Anita Peridotite recrystallised and underwent rheological weakening at a constant strain rate, with strain distributed across the entire section. This widespread deformation caused rapid exhumation of the peridotite from the lithospheric mantle into the overlying arc crust. The massif therefore records multiple overprinting phases of deformation under mantle and crustal conditions associated with the rapid exhumation of a large orogenic peridotite.     

Recycled oceanic crust as a source for tonalite intrusions in the mantle section of the Khor Fakkan block,Semail ophiolite (UAE)

Several types of felsic granitoid rocks have been recognized, intrusive in both the mantle and the crustal sequence of the Semail ophiolite. Several models have been proposed for the source of this suite of tonalites, granodiorites, trondhjemites intrusions, however their genesis is still not clearly understood. The sampled Dadnah tonalites that intruded in the mantle section of the Semail ophiolite display arc-type geochemical characteristics, are high siliceous, low-potassic, metaluminous to weakly peraluminous, enriched in LILE, show positive peaks for Ba, Pb, Eu, negative troughs for U, Ti and occur with low δ¹⁸O_H2O, moderate ε_Sr and negative ε_Nd values. They have crystallized at temperatures that range from ∼550 °C to ∼720 °C and pressure ranging from 4.4 kbar to 6.5 kbar. The isotopic ages from our tonalite samples range between 98.6 Ma and 94.9 Ma, slightly older and overlapping with the age of the metamorphic sole. Our field observations, mineralogical, petrological, geochemical, isotopic and melt inclusion data suggest that the Dadnah tonalites formed by partial melting (∼10%–15% continuous or ∼12% batch partial melting), accumulation of plagioclase, fractional crystallization (∼55%–57%), and interaction with their host harzburgites. These tonalites were the end result of partial melting and subsequent contamination and mixing of ∼4% oceanic sediments with ∼96% oceanic lithosphere from the subducted slab. This MORB-type slab melt composed from ∼97% recycled oceanic crust and ∼3% of the overlying mantle.We suggest that a possible protolith for these tonalites was the basaltic lavas from the subducted oceanic slab that melted during the initial stages of the supra-subduction zone (SSZ), which was forming synchronously to the spreading ridge axis. The tonalite melts mildly modified due to low degree of mixing and interaction with the overlying lithospheric mantle. Subsequently, the Dadnah tonalites emplaced at the upper part of the mantle sequence of the Semail ophiolite and are geochemically distinct from the other mantle intrusive felsic granitoids to the south.     

Geochemical features of the Matomb alluvial rutile from the Neoproterozoic Pan-African belt,Southern Cameroon

The Matomb region constitutes an important deposit of detrital rutile. The rutile grains are essentially coarse (> 3 mm), tabular and elongated, due to the short sorting of highly weathered detritus. This study reports the major, trace, and rare-earth element distribution in the bulk and rutile concentrated fractions. The bulk sediments contain minor TiO₂ concentrations (1–2 wt%), high SiO₂ contents (∼77–95 wt%) and variable contents in Al₂O₃, Fe₂O₃, Zr, Y, Ba, Nb, Cr, V, and Zn. The total REE content is low to moderate (86–372 ppm) marked by high LREE-enrichment (LREE/HREE ∼5–25.72) and negative Eu anomalies (Eu/Eu^* ∼0.51–0.69). The chemical index of alteration (CIA) shows that the source rocks are highly weathered, characteristic of humid tropical zone with the development of ferrallitic soils. In the concentrated fractions, TiO₂ abundances exceed 94 wt%. Trace elements with high contents include V, Nb, Cr, Sn, and W. These data associated with several binary diagrams show that rutile is the main carrier of Ti, V, Nb, Cr, Sn, and W in the alluvia. The REE content is very low (1–9 ppm) in spite of the LREE-abundance (LREE/HREE ∼4–40). The rutile concentrated fractions exhibit anomalies in Ce (Ce/Ce^* ∼0.58 to 0.83; ∼1.41–2.50) and Eu (Eu/Eu^* ∼0.42; 1.20–1.64). The high (La/Sm)_N, (La/Yb)_N and (Gd/Yb)_N ratios indicate high REE fractionation.     

Microstructural evolution during strain localization in dolomite aggregates

Dolomite aggregates deformed by dislocation creep over a wide range of conditions (T = 700–1000 °C, effective pressure of 900 MPa, strain rates of 10⁻⁷ – 10⁻⁴/s) strain weaken by up to 75% of the peak differential stress. Microstructural study of samples shortened to different finite strains beyond the peak differential stress shows that strain becomes highly localized within shear zones by high-temperature creep processes, with no contribution of brittle cracking. At low strains (8%), dolomite deforms homogeneously by recrystallization-accommodated dislocation creep. At progressively higher sample strains, deformation is localized into narrow shear zones made up of very fine (∼3 μm) recrystallized grains and relict porphyroclasts (20–100 μm). Finely-recrystallized dolomite grains in the shear zones are largely dislocation free and localized shear is facilitated by diffusion creep. In contrast, original dolomite grains and porphyroclasts in shear zones have high dislocation densities and do not deform after shear zone formation. Calculated strain rates in the shear zones are two to three orders of magnitude faster than the imposed bulk strain rate of the samples and these strain rates are consistent with predictions of the diffusion creep flow law for fine-grained dolomite.     

A new fragment of the early earth crust: the Aasivik terrane of West Greenland

The Aasivik terrane is a ∼1500 km² complex of gneisses dominated by ∼3600 Ma components, which has been discovered in the Archaean craton of West Greenland, ∼20–50 km south of the Paleoproterozoic Nagssugtoqidian orogen. The Aasivik terrain comprises granulite facies tonalitic to granitic gneisses with bands of mafic granulite, which include disrupted mafic dykes. Four gneiss samples of the Aasivik terrain have given imprecise SHRIMP U–Pb zircon ages of 3550–3780 Ma with strong loss of radiogenic lead and new growth of zircon probably associated with a granulite facies metamorphic event(s) at ∼2800–2700 Ma. To the Southeast, the Aasivik terrane is in tectonic contact with a late Archaean complex of granitic and metapelitic gneisses with apparently randomly distributed mafic and ultramafic units, here named the Ukaleq gneiss complex. Two granitic samples from the Ukaleq gneiss complex have U–Pb zircon ages of 2817 ± 10 and 2820 ± 12 Ma and t_zircon ε_Nd values of 2.3–5.4. Given their composition and positive ε_Nd values, they probably represent melts of only slightly older juvenile crust. A reconnaissance SHRIMP U–Pb study of a sample of metasedimentary rock from the Ukaleq gneiss complex found ∼2750–2900 Ma zircons of probable detrital origin and that two or more generations of 2700–2500 Ma metamorphic zircons are present. This gneiss complex is provisionally interpreted as a late Archaean accretionary wedge. A sample of banded granulite facies gneiss from a complex of banded gneisses south of the Aasivik terrain here named the Tasersiaq gneiss complex has yielded two zircon populations of 3212 ± 11 and 3127 ± 12 Ma. Contacts between the three gneiss complexes are mylonites which are locally cut by late-post-kinematic granite veins with SHRIMP U–Pb zircon ages of ∼2700 Ma. The isotopic character and the relationships between the lithologies from the different gneiss complexes suggest the assembly of unrelated rocks along shear zones between 2800 and 2700 Ma. The collage of Archaean gneiss complexes were intruded by A-type granites, here named the Umiatsiaasat granites, at ∼2700 Ma, later than the tectonic intercalation of the gneiss complexes.     

Tectono-thermal evolution of the Reed Bank Basin,Southern South China Sea

The Reed Bank Basin in the southern margin of the South China Sea is considered to be a Cenozoic rifted basin. Tectono-thermal history is widely thought to be important to understand tectonics as well as oil and gas potential of basin. In order to investigate the Cenozoic tectono-thermal history of the Reed Bank Basin, we carried out thermal modeling on one drill well and 22 pseudo-wells using the multi-stage finite stretching model. Two stages of rifting during the time periods of ∼65.5–40.4 Ma and ∼40.4–28.4 Ma can be recognized from the tectonic subsidence rates, and there are two phases of heating corresponding to the rifting. The reconstructed average basal paleo-heat flow values at the end of the rifting events are ∼60 and ∼66.3 mW/m², respectively. Following the heating periods, this basin has undergone a persistent thermal attenuation phase since ∼28.4 Ma and the basal heat flow cooled down to ∼57.8–63.5 mW/m² at present. In combination with the radiogenic heat production of the sedimentary sequences, the surface heat flow of the Reed Bank Basin ranges from ∼60.4 to ∼69.9 mW/m².     

The strength and fractal dimension characteristics of alum–kaolin flocs

Flocs generated by various shear forces exhibit different characteristics of size, strength and structure. These properties were investigated by employing a continuous optical monitoring and a microscope with CCD camera to directly monitor aggregation under six different shear intensities. The floc structure was characterized by the fractal dimension. The results showed that the flocculation index (FI) decreased from 1.16 at 20 rpm to 0.25 at 250 rpm and the floc size decreased from 550 μm to 150 μm, meantime, the FI value showed a good correlation with floc size. In order to determine the floc strength, two methods were used. One was the strength factor, ranging from 18.3% to 62.5%, calculated from FI curve, and the other was a theoretical value between 0.005 N/m² and 0.240 N/m², estimated by calculation. The floc strength increased with the G value in both cases. Furthermore, the fractal dimension increased with G and its value was between 1.30 and 1.63. The relation between fractal dimension and strength was also obtained.     

Ferric iron in sediments as a novel CO2 mineral trap: CO2–SO2 reaction with hematite

Thermodynamic simulations of reactions among SO₂-bearing CO₂-dominated gas, water and mineral phases predict that Fe^III in sediments should be converted almost entirely to dissolved Fe^II and siderite (FeCO₃), and that SO₂ should simultaneously be oxidized to dissolved sulfate. The reactions are however, subject to kinetic constraints which may result in deviation from equilibrium and the precipitation of other metastable mineral phases. To test the prediction, a laboratory experiment was carried out in a well stirred hydrothermal reactor at 150 °C and 300 bar with hematite, 1.0 m NaCl, 0.5 m NaOH, SO₂ in quantity sufficient to reduce much of the iron, and excess CO₂. The experiment produced stable siderite and metastable pyrite and elemental S. Changes in total dissolved Fe are consistent with nucleation of pyrite at ∼17 h, and nucleation of siderite at ∼600 h. Dissolution features present on elemental S at the conclusion of the experiment suggest nucleation early in the experiment. The experiment did not reach equilibrium after ∼1400 h, as indicated by coexistence of hematite with metastable pyrite and elemental sulfur. However, the results confirm that Fe^III can be used to trap CO₂ in siderite if partly oxidized S, as SO₂, is present to reduce the Fe with CO₂ in the gas phase.     

Crustal shear-wave velocity structure beneath northeast India from teleseismic receiver function analysis

We investigated the seismic shear-wave velocity structure of the crust beneath nine broadband seismological stations of the Shillong–Mikir plateau and its adjoining region using teleseismic P-wave receiver function analysis. The inverted shear wave velocity models show ∼34–38 km thick crust beneath the Shillong Plateau which increases to ∼37–38 km beneath the Brahmaputra valley and ∼46–48 km beneath the Himalayan foredeep region. The gradual increase of crustal thickness from the Shillong Plateau to Himalayan foredeep region is consistent with the underthrusting of Indian Plate beyond the surface collision boundary. A strong azimuthal variation is observed beneath SHL station. The modeling of receiver functions of teleseismic earthquakes arriving the SHL station from NE backazimuth (BAZ) shows a high velocity zone within depth range 2–8 km along with a low velocity zone within ∼8–13 km. In contrast, inversion of receiver functions from SE BAZ shows high velocity zone in the upper crust within depth range ∼10–18 km and low velocity zone within ∼18–36 km. The critical examination of ray piercing points at the depth of Moho shows that the rays from SE BAZ pierce mostly the southeast part of the plateau near Dauki fault zone. This observation suggests the effect of underthrusting Bengal sediments and the underlying oceanic crust in the south of the plateau facilitated by the EW-NE striking Dauki fault dipping 30⁰ toward northwest.     

The role of shear strain in the graphitization of a high-volatile bituminous and an anthracitic coal

A ‘soft’ carbon-based high-volatile bituminous (R_{o max}=0.68%) coal and a ‘hard’ carbon-based Pennsylvania anthracite (R_{o max}=5.27%) were deformed in the steady state at high temperatures and pressures in a series of coaxial and simple shear deformation experiments designed to constrain the role of shear strain and strain energy in the graphitization process. Tests were carried out in a Griggs-t type solid (NaCl) medium apparatus at T=400–900°C, constant displacement rates of 10^-5−10^-6 s⁻¹, at confining pressures of 0.6 GPa (coaxial) or 0.8 and 1.0 GPa (simple shear). Coaxial samples were shortened up to 50%, whereas shear strains up to 4.9 were attained in simple shear tests. Experiments lasted up to 118 h. Deformed, high-volatile bituminous coal was extensively coked and no correlation between strain and R_{o max}, bireflectance or coal texture was observed in any samples. With increasing temperature, R_{o max} and bireflectance increase in highly anisotropic, coarse mosaic units, but remain essentially constant in the fine granular mosaic, which becomes more abundant at higher temperatures. Graphite-like reflectances are observed locally only in highly reactive macerals and in pyrolytic carbon veins. The degree of molecular ordering attained in deformed bituminous coal samples appears to be determined by the heating-pressurization path rather than by subsequent deformation.Graphitization did not occur in coaxially deformed anthracite. Nonetheless, dramatic molecular ordering occurs at T>700°C, with average bireflectance values increasing from 1.68% at 700°C to 6.36% at 900°C. Anisotropy is greatest in zones of high strain at all temperatures. In anthracite samples deformed in simple shear over the 600–900°C range at 1.0 GPa, the average R_{o max} values increase up to 11.9%, whereas average bireflectance values increase up to 10.7%. Bireflectance increases with progressive bedding rotation and, thus, with increasing shear strain. Graphitization occurs in several anthracite samples deformed in simple shear at 900°C. X-ray diffraction and transmission electron microscopy of highly anisotropic material in one sample confirms the presence of graphite with d₀₀₂=0.3363 nm. These data strongly suggest that shear strain, through its tendency to align basic structural units, is the factor responsible for the natural transformation of anthracite to graphite at temperatures far below the 2200°C required in hydrostatic heating experiments at ambient pressure.     

Verteilung,Eigenschaften und Entstehung der Auswurfsmassen des Impaktkraters Nördlinger Ries

Regarding the importance of the Ries impact structure in the field of planetary geology an attempt is made to synthesize the presently known results of geologic mapping in the Ries area and of general field and laboratory observations. The ballistic bulk ejecta of the crater (diameter about 23 km) form a continuous blanket of mixed breccia (“Bunte Trümmermassen”). Outside the crater more than 90% of its constituents are derived from unshocked fragments of the 750 m thick pre-Ries sedimentary rock strata. This blanket is overlain with a sharp discontinuity by suevite breccia which forms a continuous layer inside the crater and patch-like isolated occurrences outside the crater. Their pattern of distribution is believed to be primary. Suevite is mainly composed of fragments of all stages of shock metamorphism derived from the crystalline basement. The present asymmetrical distribution of éjecta outside the crater rim results from relatively young erosion during the Pliocene and Pleistocene periods. The erosional history indicates that the primary distribution of ejecta was symmetrical with respect to the center of the crater extending up to a distance of at least some 40 km from the impact center. A number of characteristics of the structure and composition of the Ries ejecta formations are discussed and verified quantitatively by new field data. It is shown that the structure and composition of the ejecta formations can be explained qualitatively by the physics of impact cratering and be duplicated by hypervelocity cratering experiments.     

Cold climate during the closest Stage 11 analog to recent Millennia

The early part of marine isotopic Stage 11 near 400,000 years ago provides the closest analog to Holocene insolation levels of any interglaciation during the era of strong 100,000-year climatic cycles. The CH₄ concentration measured in Vostok ice fell to ∼450 ppb, and CO₂ values to ∼250 ppm. These natural decreases contrast with the increases in recent millennia and support the early anthropogenic hypothesis of major gas emissions from late-Holocene farming. During the same interval, δD values fell from typical interglacial to nearly glacial values, indicating a major cooling in Antarctica early in Stage 11. Other evidence suggests that new ice was accumulating during the closest insolation analog to the present day: a major increase in δ¹⁸O_atm at Vostok, a similar increase in marine δ¹⁸O values, and re-initiation of ice rafting in the Nordic Sea. The evidence permits extended (>20,000 year) intervals of Stage 11 interglacial warmth in the Antarctic and North Atlantic, yet it also requires that this warmth ended and a new glacial era began when insolation was most similar to recent millennia. The Holocene CO₂ anomaly was produced only in part by direct anthropogenic emissions; over half of the anomaly resulted from the failure of CO₂ values to fall as they had during previous interglaciations because of natural responses, including a sea-ice advance in the Antarctic and ice-sheet growth in the northern hemisphere.     

Effects of shock pressure on 40Ar -39Ar radiometric age determinations

The relation of shock to the drop in the ⁴⁰¹Ar/³⁹¹Ar ratio seen at high release temperatures in some neutron-irradiated lunar samples is investigated through measurements of the ⁴⁰¹Ar/³⁹¹Ar ratio in gas samples released by stepwise heating of rock samples previously subjected to shock, either in the laboratory or in nature.Explosives were used to shock solid pieces and powder of a basalt from a diabase dike in Liberia to calculated pressures of 65, 150 and 270 kbar. These, an unshocked sample of the powder, two naturally shocked samples from the Brent impact crater in Canada, one unshocked sample from near the crater, and appropriate monitors were irradiated. Ar from stepwise heating was analyzed.The unshocked basalt shows a good ⁴⁰¹Ar/³⁹¹Ar plateau at age 198 ± 9 m.y. in agreement with a previous result of 186 ± 2 m.y. The shocked samples contain varying amounts of implanted atmospheric Ar, the isotopes of which have experienced mass fractionation. This effect is small enough in four samples so that the linearity of their graphs of ³⁹¹Ar/⁴⁰Ar vs ³⁶Ar/⁴⁰Ar is evidence of a plateau. The ages of these samples are then 201 ± 10, 205 ± 11, 205 ± 12 and 201 ± 9 m.y. It appears that the shock has had little effect on the ⁴⁰Ar-³⁹Ar age spectrum, although the release patterns of the ³⁹¹Ar are shifted downward by the order of 200°C. Shock implantation of Ar was at lower shock pressure, in the presence of less Ar, and into a less porous material than previously demonstrated.The Brent Crater samples do not all show good plateaus, but do indicate an age of ~420 m.y. for the crater event and 795 ± 24 m.y. for the rock formation, in agreement with previous results.None of the ⁴⁰¹Ar/³⁹¹Ar profiles shows a drop at high temperature, but a possible role of shock implantation of Ar is indicated in the production of this effect. Further experiments are suggested.