Modeling and Interpreting CHAMP Magnetic Anomaly Field over China Continent Using Spherical Cap Harmonic Analysis

Based on the CHAMP Magsat data set, spherical cap harmonic analysis was used to model the magnetic fields over China continent. The data set used in the analysis includes the 15′×15′ gridded values of the CHAMP anomaly fields (latitude φ=25°N to 50°N and longitude λ=78°E to 135°E). The pole of the cap is located at φ=35°N and λ=110°E with half-angle of 30°. The maximum index (Kmax) of the model is 30 and the total number of model coefficients is 961, which corresponds to the minimum wavelength at the earth's surface about 400 km. The root mean square (RMS) deviations between the calculated and observed values are ～ 4 nT for ΔX, ～ 3 nT for ΔY and ～ 3.5 nT for ΔZ, respectively. Results show that positive anomalies are found mainly at the Tarim basin with ～6- 8 nT, the Yangtze platform and North China platform with ～4 nT, and the Songliao basin with ～4-6 nT. In contrast, negative anomaly is mainly located in the Tibet orogenic belt with the amplitude ～ (-6)-(-8) nT. Upward continuation of magnetic anomalies was used to semi-quantitatively separate the magnetic anomalies in different depths of crust. The magnetic anomalies at the earth's surface are from -6 to 10 nT for upper crust, middle crust -27 to 42 nT and lower crust -12 to 18 nT, respectively. The strikes of the magnetic anomalies for the upper crust are consistent with those for the middle crust, but not for the lower crust. The high positive magnetic anomalies mainly result from the old continental nucleus and diastrophic block (e.g. middle Sichuan continental nucleus, middle Tarim basin continental nucleus, Junggar diastrophic block and Qaidam diastrophic block). The amplitudes of the magnetic anomalies of the old continental nucleus and diastrophic block are related to evolution of deep crust. These results improve our understanding of the crustal structure over China continent.     

Geological Features, Mineralization Types and Metallogenic Setting of the Phlaythong Large Iron Deposit, Southern Laos

<正>The Phlaythong large iron deposit in Shampasak of southern Laos,is located in the Kon Tum microblock(Fig.1A),central-southern part of the Indo-China block,and the geographic coordinate of the central mining area is 14°43′04″N and 106°07′02″E.Intensive tectonic and magmatic activities of multiple periods developed in this region,especially in Mesozoic and Cenozoic,which are closely     

Beiya Gold Deposit,Heqing County,Yunnan——One of China's Ten Biggest Gold Deposits

<正>The Beiya gold polymetallic ore district covers an area of 22.06 km2 and is located 47.5 km away in the direction 172°from Heqing county seat of northwestern Yunnan.Its geographical coordinates are 100°11′15″–100°13′00″E and6°07′30″–26°10′30″N.Since its discovery in 1999 until November 31st 2013,it has had accumulative proven(111b+122b+331+332+333)gold metal amounts of 258.475t at an average grade of 2.61 g/t.This deposit contains 88.98million tons of paragenetic and associated iron ores,with TFe grade varying from 9%to 36%;metal amounts are:gold     

THE OROGENIC MOVEMENTS IN CHINA

INTRODUCTION The western Islands (Hsisatao) or the Paracel Reefs form the south-ern-most Chinese territory in the China sea. They are situated between latitudes 15°30′ N., and 17°30′ N. and longitudes E 111-113°. Accordingly     

THE GUANO DEPOSIT OF THE WESTERN ISLANDS (HSISATAO) OR PARACEL REEFS

INTRODUCTION The western Islands (Hsisatao) or the Paracel Reefs form the south-ern-most Chinese territory in the China sea. They are situated between latitudes 15°30′ N., and 17°30′ N. and longitudes E 111-113°. Accordingly     

Distribution and Forming Model of Fluvial Terrace in the Huangshui Catchment and its Tectonic Indication

<正>The Huang Shui River,a main tributary of the Yellow River,crosses a series of tectonically subsided and uplifted areas that show different patterns of terrace formation.The distribution of fluvial terrace of the Huang Shui River is studied through topographic and sedimentologic terrace mapping.Three terraces in the Haiyan Basin,four terraces in the Huangyuan Basin,19 terraces in the Xi'ning Basin(the four high terraces may belong to another river),nine terraces in the Ping'an Basin, five terraces in the Ledu Basin and 12 terraces in the Minhe Basin are recognized.Sedimentology research shows that the geomorphologic and sedimentological pattern of the Huang Shui River,which is located at the margin of Tibet,are different from that of the rivers at other regions.The formation process of the terrace is more complicated at the Huang Shui catchment:both accumulation terrace and erosion terrace were formed in each basin and accumulation terraces were developed in some basins when erosion terraces were formed in other basins,indicating fluvial aggradation may occur in some basins simultaneously with river incision in other basins.A conceptual model of the formation process of these two kinds of fluvial terraces at Huang Shui catchment is brought forward in this paper.First,the equilibrium state of the river is broken because of climatic change and/or tectonic movement,and the river incises in all basins in the whole catchment until reaching a new equilibrium state.Then,the downstream basin subsides quickly and the equilibrium state is broken again,and the river incises at upstream basins while the river accumulates at the subsidence basin quickly until approaching a new equilibrium state again.Finally,the river incises in the whole catchment because of climatic change and/or tectonic movement and the accumulation terrace is formed at the subsidence basin while the erosion terrace is formed at other basins.The existence of the accumulation terrace implied the tectonic subsidence in the sub-basins in Huang Shui catchment.These tectonic subsidence movements gradually developed from the downstream Minhe Basin to the upstream Huangyuan Basin.Dating the terrace sequence has potential to uncover the relationship between the subsidence in the catchment and the regional tectonic at the northeastern Tibetan Plateau.     

Features and Formation Mechanism of Faults and Potash-forming Effect in the Lop Nur Salt Lake, Xinjiang, China

1 Introduction The Lop Nur Salt Lake, located in the eastern part of the Tarim Basin, Xinjiang, China, has become a playa in the Quaternary. It is under the jurisdiction of Ruoqiang County, Xinjiang, being ~450 km east of Korla City, the capital of the Bayingolin Mongolian Autonomous Prefecture (Fig. 1), and 300 km south of the seat of Shanshan County. The geographic coordinates are 90o00'–91o30' E and 39o40'– 41o20' N. Field survey and drilling since 1995 have revealed an occurren…     

Geologic Characteristics of Volcanic Hydrocarbon Reservoirs and Exploration Directions in China

Abstract: Volcanic rocks are distributed widely in China, which are important exploration targets. By analyzing many discovered volcanic hydrocarbon reservoirs all over the world, the authors summarized the geologic characteristics of the formation of volcanic hydrocarbon reservoirs in China, and gave further exploration directions and advices. (1) There are mainly Carboniferous-Permian, Jurassic-Cretaceous, Paleogene-Neogene volcanic rocks in oil- and gas-bearing basins in China, which are mainly distributed in the Junggar Basin, Songliao Basin, Bohai Bay Basin, etc. There are mainly intermediate rocks and acidic rocks in east China, and intermediate rocks and basic rocks in west China. They primarily develop in intracontinental rift settings and island arc environments. (2) Pore-fissure reservoirs are distributed widely in basins, which are volcanic rocks mainly in explosive and effusive facies. (3) Volcanic hydrocarbon reservoirs are chiefly near-source lithostratigraphic hydrocarbon reservoirs, and the oil and gas accumulation is predominantly controlled by lithotypes, faults and structural positions. (4) Deep-seated oil and gas reservoirs in the Songliao Basin and Carboniferous volcanic hydrocarbon reservoirs in the Junggar Basin are potential giant volcanic gas provinces, the volcanic hydrocarbon reservoirs in the Bohai Bay Basin and Santanghu Basin are favorable for oil and gas reserves increase, and volcanic rocks in the Turpan Basin, Sichuan Basin, Tarim Basin have exploration potentiality. (5) The technology series of oil and gas exploration in volcanic rocks have been preliminarily formed.     

Differential Thermal Regimes of the Tarim and Sichuan Basins in China: Implications for Hydrocarbon Generation and Conservation

The uncertainty surrounding the thermal regimes of the ultra-deep strata in the Tarim and Sichuan basins, China, is unfavorable for further hydrocarbon exploration. This study summarizes and contrasts the present-day and paleo heat flow, geothermal gradient and deep formation temperatures of the Tarim and Sichuan basins. The average heat flow of the Tarim and Sichuan basins are 42.5 ± 7.6 mW/m2 and 53.8 ± 7.6 mW/m2, respectively, reflecting the characteristics of ‘cold’ and ‘warm’ basins. The geothermal gradient with unified depths of 0–5,000 m, 0–6,000 m and 0–7,000 m in the Tarim Basin are 21.6 ± 2.9 °C/km, 20.5 ± 2.8 °C/km and 19.6 ± 2.8 °C/km, respectively, while the geothermal gradient with unified depths of 0–5,000 m, 0–6,000m and 0–7,000 m in the Sichuan Basin are 21.9 ± 2.3 °C/km, 22.1 ± 2.5 °C/km and 23.3 ± 2.4 °C/km, respectively. The differential change of the geothermal gradient between the Tarim and Sichuan basins with depth probably results from the rock thermal conductivity and heat production rate. The formation temperatures at depths of 6,000 m, 7,000 m, 8,000 m, 9,000 m and 10,000 m in the Tarim Basin are 80°C–190°C, 90°C–220°C, 100°C–230°C, 110°C–240°C and 120°C–250°C, respectively, while the formation temperatures at depths of 6,000 m, 7,000 m, 8,000 m and 9,000 m in the Sichuan Basin are 120°C–200°C, 140°C–210°C, 160°C–260°C and 180°C–280°C, respectively. The horizontal distribution pattern of the ultra-deep formation temperatures in the Tarim and Sichuan basins is mainly affected by the basement relief, fault activity and hydrothermal upwelling. The thermal modeling revealed that the paleo-heat flow in the interior of the Tarim Basin decreased since the early Cambrian with an early Permian abrupt peak, while that in the Sichuan Basin experienced three stages of steady state from Cambrian to early Permian, rapidly rising at the end of the early Permian and declining since the late Permian. The thermal regime of the Sichuan Basin was always higher than that of the Tarim Basin, which results in differential oil and gas generation and conservation in the ultra-deep ancient strata. This study not only promotes theoretical development in the exploration of ultra-deep geothermal fields, but also plays an important role in determining the maturation phase of the ultra-deep source rocks and the occurrence state of hydrocarbons in the Tarim and Sichuan basins.     

Origin and Distribution of Hydrogen Sulfide in Oil-Bearing Basins,China

Abstract: The concentration of hydrogen sulfide gas (H2S) varies greatly in the oil-bearing basins of China, from zero to 90%. At present, oil and gas reservoirs with high H2S concentration have been discovered in three basins, viz. the Bohai Bay Basin, Sichuan Basin and the Tarim Basin, whereas natural gas with low H2S concentration has been found in the Ordos Basin, the Songliao Basin and the Junggar Basin. Studies suggest that in China H2S origin types are very complex. In the carbonate reservoir of the Sichuan Basin, the Ordos Basin and the Tarim Basin, as well as the carbonate-dominated reservoir in the Luojia area of the Jiyang depression in the Bohai Bay Basin, Wumaying areas of the Huanghua depression, and Zhaolanzhuang areas of the Jizhong depression, the H2S is of Thermochemical Sulfate Reduction (TSR) origin. The H2S is of Bacterial Sulphate Reduction (BSR) origin deduced from the waterflooding operation in the Changheng Oilfield (placanticline oil fields) in the Songliao Basin. H2S originates from thermal decomposition of sulfur-bearing crude oil in the heavy oil area in the Junggar Basin and in the Liaohe heavy oil steam pilot area in the western depression of the Bohai Bay Basin. The origin types are most complex, including TSR and thermal decomposition of sulfcompounds among other combinations of causes. Various methods have been tried to identify the origin mechanism and to predict the distribution of H2S. The origin identification methods for H2S mainly comprise sulfur and carbon isotopes, reservoir petrology, particular biomarkers, and petroleum geology integrated technologies; using a combination of these applications can allow the accurate identification of the origins of H2S. The prediction technologies for primary and secondary origin of H2S have been set up separately.     

The metapelitic garnet–biotite–muscovite–aluminosilicate–quartz (GBMAQ) geobarometer

In this contribution we have empirically calibrated the garnet–biotite–muscovite–aluminosilicate–quartz (GBMAQ) barometer using low- to medium–high-pressure, mid-grade metapelites. Application of the barometer suggests that the GBMAQ and GASP barometers show quite similar pressure estimates. Furthermore, metapelites within thermal contact aureole or very limited geographic area show no meaningful pressure diversity determined by the GBMAQ and GASP barometers which is the geological reality. The random error of the GBMAQ barometer is expected to be around ± 0.8 kbar, and this barometer shows no systematic bias with respect to either pressure, or temperature, or Al^VI in muscovite, or Fe in biotite, or Fe in garnet. The GBMAQ barometer is thermodynamically consistent with the garnet–biotite geothermometer because they share the same activity models of both garnet and biotite. This barometer is especially useful for assemblages with Ca-poor garnet or Ca-poor plagioclase or plagioclase-absent metapelites. Application of this barometer beyond the calibration ranges, i.e., P–T range and chemical ranges of the minerals, is not encouraged.     

An enlarged and updated internally consistent thermodynamic dataset with uncertainties and correlations: the system K2O–Na2O–CaO–MgO–MnO–FeO–Fe2O3–Al2O3–TiO2–SiO2–C–H2–O2

We present, as a progress report, a revised and much enlarged version of the thermodynamic dataset given earlier (Holland & Powell, 1985). This new set includes data for 123 mineral and fluid end-members made consistent with over 200 P–T–X_CO2–f_O2 phase equilibrium experiments. Several improvements and advances have been made, in addition to the increased coverage of mineral phases: the data are now presented in three groups ranked according to reliability; a large number of iron-bearing phases has been included through experimental and, in some cases, natural Fe:Mg partitioning data; H₂O and CO₂ contents of cordierites are accounted for with the solution model of Kurepin (1985); simple Landau theory is used to model lambda anomalies in heat capacity and the Al/Si order–disorder behaviour in some silicates, and Tschermak-substituted end-members have been derived for iron and magnesium end-members of chlorite, talc, muscovite, biotite, pyroxene and amphibole. For the subset of data which overlap those of Berman (1988), it is encouraging to find both (1) very substantial agreement between the two sets of thermodynamic data and (2) that the two sets reproduce the phase equilibrium experimental brackets to a very similar degree of accuracy. The main differences in the two datasets involve size (123 as compared to 67 end-members), the methods used in data reduction (least squares as compared to linear programming), and the provision for estimation of uncertainties with this dataset. For calculations on mineral assemblages in rocks, we aim to maximize the information available from the dataset, by combining the equilibria from all the reactions which can be written between the end-members in the minerals. For phase diagram calculations, we calculate the compositions of complex solid solutions (together with P and T) involved in invariant, univariant and divariant assemblages. Moreover we strongly believe in attempting to assess the probable uncertainties in calculated equilibria and hence provide a framework for performing simple error propagation in all calculations in thermocalc, the computer program we offer for an effective use of the dataset and the calculation methods we advocate.     

Study on the Cu–As–Sb–Ag–Bi–Pb–Te Sulfosalt Minerals from the Hydrothermal System of Southwestern Hokkaido,Japan

Shin‐Otoyo, Suttsu, Teine, Date, Chitose, and Koryu are sites rich in precious and base metal Miocene–Pleistocene epithermal deposits, and located in southwestern Hokkaido, Japan. The deposits are predominantly hosted by the Green Tuff Formation of Middle Miocene age. Ore petrographic study of these deposits shows the occurrence of variable quantities of Cu–As–Sb–Ag–Bi–Pb–Te sulfosalt minerals. Determination of mineralogical and chemical compositions of the sulfosalt minerals was undertaken to elucidate the time and spatial changes of the sulfide‐sulfosalt minerals. Various types of sulfosalt minerals identified from gold–silver and base metal quartz–sulfide veins represented some sulfosalt mineralization phases, such as the Cu–Fe–Sn–S phase of mawsonite and stannite; Cu–(As,Sb)–S phase of tetrahedrite–tennantite and luzonite–famatinite series minerals; (Cu,Ag)–Bi–Pb–S phase of emplectite, pavonite, friedrichite, aikinite, and lillianite–gustavite series minerals; (Ag,Cu)–(As,Sb)–S phase of proustite–pyrargyrite and pearceite–polybasite series minerals; and Bi–Te–S phase of tetradymite and kawazulite minerals. There are some trends in the paragenetic sequence of sulfosalt mineralization in southwestern Hokkaido (in complete or partial) as follows: sulfide → Cu–Fe–Sn–S → (Cu,Ag)–Bi–Pb–S → (Bi–Te–S) → Cu–(As,Sb)–S → ([Ag,Cu]–[As,Sb]–S). The formation of sulfosalt minerals is characterized by the introduction of some elements such as Sn, Bi, and Te at an earlier stage and an increase or decrease of some elements such as As and Sb, followed by the introduction of Ag at the later stage of ore mineral paragenesis sequence. Mineral composition of the Chitose and Koryu deposits are slightly different from those of Shin‐Otoyo, Suttsu, Teine, and Date due to their lack of Sn (tin) and Bi (bismuth) mineralization. The variable concentrations and relationships are not simply with redistributed trace elements from the original sulfide minerals of chalcopyrite, pyrite, galena, and sphalerite. Some heavier elements were also introduced during the replacement reaction, which is consistent with the occurrence of their associated minerals.     

Revised empirical garnet–biotite–muscovite–plagioclase geobarometer in metapelites

The garnet–biotite–muscovite–plagioclase (GBMP) barometer was empirically revised for P–T conditions of 1–14 kbar and 450–840 °C, using 263 metapelitic rock samples from all over the world. This barometer is based on activity models for garnet, biotite and plagioclase identical to those of the well‐calibrated garnet–biotite thermometer and the garnet–aluminosilicate–plagioclase–quartz (GASP) barometer. The GBMP barometer is less temperature dependent than the GASP barometer and can be applied to either Al₂SiO₅‐absent or Al₂SiO₅‐bearing metapelites. The total error of the GBMP barometer is estimated to be about ±1.2 kbar on considering input temperature error and analytical errors of chemical compositions of the phases involved. The random error of the GBMP barometer is evenly distributed with respect to pressure, temperature and mineral composition. Simultaneous application of the GBMP barometer and the garnet–biotite thermometer identifies the correct stability field for Al₂SiO₅‐bearing metapelites. Application of the GBMP barometer to metapelitic rocks within the same geological terranes or thermal contact aureoles yielded similar pressures within error. A spreadsheet for implementing the proposed GBMP geobarometer is supplied on the journal's website.     

Internally consistent data for sulphur‐bearing phases and application to the construction of pseudosections for mafic greenschist facies rocks in Na2O–CaO–K2O–FeO–MgO–Al2O3–SiO2–CO2–O–S–H2O

The Holland and Powell internally consistent data set version 5.5 has been augmented to include pyrite, troilite, trov (Fe_0.875S), anhydrite, H₂S, elemental S and S₂ gas. Phase changes in troilite and pyrrhotite are modelled with a combination of multiple end‐members and a Landau tricritical model. Pyrrhotite is modelled as a solid solution between hypothetical end‐member troilite (trot) and Fe_0.875S (trov); observed activity–composition relationships fit well to a symmetric formalism model with a value for w_trot?trov of ?3.19 kJ mol^?1. The hypothetical end‐member approach is required to compensate for iron distribution irregularities in compositions close to troilite. Mixing in fluids is described with the van Laar asymmetric formalism model with a_ij values for H₂O–H₂S, H₂S–CH₄ and H₂S–CO₂ of 6.5, 4.15 and 0.045 kJ mol^?1 respectively. The derived data set is statistically acceptable and replicates the input data and data from experiments that were not included in the initial regression. The new data set is applied to the construction of pseudosections for the bulk composition of mafic greenschist facies rocks from the Golden Mile, Kalgoorlie, Western Australia. The sequence of mineral assemblages is replicated successfully, with observed assemblages predicted to be stable at X(CO₂) increasing with increasing degree of hydrothermal alteration. Results are compatible with those of previous work. Assemblages are insensitive to the S bulk content at S contents of less than 1 wt%, which means that volatilization of S‐bearing fluids and sulphidation are unlikely to have had major effects on the stable mineral assemblage in less metasomatized rocks. The sequence of sulphide and oxide phases is predicted successfully and there is potential to use these phases qualitatively for geobarometry. Increases in X(CO₂) stabilized, in turn, pyrite–magnetite, pyrite–hematite and anhydrite–pyrite. Magnetite–pyrrhotite is predicted at temperatures greater than 410 °C. The prediction of a variety of sulphide and oxide phases in a rock of fixed bulk composition as a function of changes in fluid composition and temperature is of particular interest because it has been proposed that such a variation in phase assemblage is produced by the infiltration of multiple fluids with contrasting redox state. The work presented here shows that this need not be the case.     

Outokumpu revisited: New mineral deposit model for the mantle peridotite-associated Cu–Co–Zn–Ni–Ag–Au sulphide deposits

The metaturbidites of the Palaeoproterozoic Jormua–Outokumpu thrust belt in eastern Finland enclose m- to km-scale ultramafic massifs that are distributed over an area of more than 5000 km². These bodies, which almost entirely consist of highly depleted mantle peridotites (now metaserpentinites and metaperidotites), are intimately associated with massive to semimassive, polymetallic Cu–Co–Zn–Ni–Ag–Au sulphide deposits that sustained mining in the region between 1913 and 1988. Currently, one deposit (Kylylahti) is proceeding into a definitive feasibility study emphasising the renewed economic interest for Outokumpu-type deposits.The origin of these Outokumpu-type Cu–Co–Zn–Ni–Ag–Au deposits is now re-interpreted to be polygenetic. First, their formation requires deposition of a Cu-rich proto-ore within peridotitic sea floor at  1950 Ma. Close modern analogues to the proto-ore setting include, for example, the Logatchev and Rainbow fields at the Mid-Atlantic Ridge, where venting of high-T–low-pH hydrothermal fluid resulted in accumulations of Cu–Zn–Co–Ag–Au sulphides on serpentinised ultramafic seafloor. Second, the Ni-rich composition of Outokumpu sulphide ores calls for a separate source for nickel: Some 40 Ma after the deposition of the Cu-rich proto-ore – concomitant with the obduction of the ultramafic massifs – disseminated Ni sulphides formed through chemical interaction between obducting peridotite massifs and adjacent black schists. This process was related to listwaenite–birbirite type carbonate–silica alteration at margins of the ultramafic massifs. Due to this alteration, silicate nickel was released from the primary Fe–Mg silicates and redeposited as Ni sulphides in the alteration fringes of the massifs.We propose that syntectonic mixing of these two “end-member” sulphides, i.e., the primary Cu-rich proto-ore and the secondary Ni-sulphide disseminations, resulted in the uncommon metal combination of the Outokumpu-type sulphides. Late tectonic solid-state re-mobilisation, related to the duplexing of the ore by isoclinal folding, upgraded the sulphides into economic deposits.     

Calculation of partial melting equilibria in the system Na2O–CaO–K2O–FeO–MgO–Al2O3–SiO2–H2O (NCKFMASH)

A thermodynamic model for haplogranitic melts in the system Na₂O–CaO–K₂O–Al₂O₃–SiO₂–H₂O (NCKASH) is extended by the addition of FeO and MgO, with the data for the additional end‐members of the liquid incorporated in the Holland & Powell (1998) internally consistent thermodynamic dataset. The resulting dataset, with the software thermocalc , is then used to calculate melting relationships for metapelitic rock compositions. The main forms for this are P–T and T–X pseudosections calculated for particular rock compositions and composition ranges. The relationships in these full‐system pseudosections are controlled by the low‐variance equilibria in subsystems of NCKFMASH. In particular, the solidus relationships are controlled by the solidus relationships in NKASH, and the ferromagnesian mineral relationships are controlled by those in KFMASH. However, calculations in NCKFMASH allow the relationships between the common metapelitic minerals and silicate melt to be determined. In particular, the production of silicate melt and melt loss from such rocks allow observations to be made about the processes involved in producing granulite facies rocks, particularly relating to open‐system behaviour of rocks under high‐grade conditions.     

Genesis of the Weiquan Ag–Polymetallic Deposit in East Tianshan, China: Evidence from Zircon U–Pb Geochronology and C–H–O–S–Pb Isotope Systematics

The Weiquan Ag-polymetallic deposit is located on the southern margin of the Central Asian Orogenic Belt and in the western segment of the Aqishan-Yamansu arc belt in East Tianshan,northwestern China. Its orebodies, controlled by faults, occur in the lower Carboniferous volcanosedimentary rocks of the Yamansu Formation as irregular veins and lenses. Four stages of mineralization have been recognized on the basis of mineral assemblages, ore fabrics, and crosscutting relationships among the ore veins. Stage I is the skarn stage(garnet + pyroxene), Stage Ⅱ is the retrograde alteration stage(epidote + chlorite + magnetite ± hematite 士 actinolite ± quartz),Stage Ⅲ is the sulfide stage(Ag and Bi minerals + pyrite + chalcopyrite + galena + sphalerite + quartz ± calcite ± tetrahedrite),and Stage IV is the carbonate stage(quartz + calcite ± pyrite). Skarnization,silicification, carbonatization,epidotization,chloritization, sericitization, and actinolitization are the principal types of hydrothermal alteration. LAICP-MS U-Pb dating yielded ages of 326.5±4.5 and 298.5±1.5 Ma for zircons from the tuff and diorite porphyry, respectively. Given that the tuff is wall rock and that the orebodies are cut by a late diorite porphyry dike, the ages of the tuff and the diorite porphyry provide lower and upper time limits on the age of ore formation. The δ~(13)C values of the calcite samples range from-2.5‰ to 2.3‰, the δ~(18)O_(H2 O) and δD_(VSMOW) values of the sulfide stage(Stage Ⅲ) vary from 1.1‰ to 5.2‰ and-111.7‰ to-66.1‰, respectively,and the δ~(13)C, δ~(18)O_(H2 O) and δD_(V-SMOW) values of calcite in one Stage IV sample are 1.5‰,-0.3‰, and-115.6‰, respectively. Carbon, hydrogen, and oxygen isotopic compositions indicate that the ore-forming fluids evolved gradually from magmatic to meteoric sources. The δ~(34)S_(V-CDT) values of the sulfides have a large range from-6.9‰ to 1.4‰, with an average of-2.2‰, indicating a magmatic source, possibly with sedimentary contributions. The ~(206)Pb/~(204)Pb, ~(207)Pb/~(204)Pb, and ~(208)Pb/~(204)Pb ratios of the sulfides are 17.9848-18.2785,15.5188-15.6536, and 37.8125-38.4650, respectively, and one whole-rock sample at Weiquan yields~(206)Pb/~(204)Pb,~(207)Pb/~(204)Pb, and ~(208)Pb/~(204)Pb ratios of 18.2060, 15.5674, and 38.0511,respectively. Lead isotopic systems suggest that the ore-forming materials of the Weiquan deposit were derived from a mixed source involving mantle and crustal components. Based on geological features, zircon U-Pb dating, and C-H-OS-Pb isotopic data, it can be concluded that the Weiquan polymetallic deposit is a skarn type that formed in a tectonic setting spanning a period from subduction to post-collision. The ore materials were sourced from magmatic ore-forming fluids that mixed with components derived from host rocks during their ascent, and a gradual mixing with meteoric water took place in the later stages.     

A new thermodynamic model for sapphirine: calculated phase equilibria in K2O–FeO–MgO–Al2O3–SiO2–H2O–TiO2–Fe2O3

The activity–composition (a–x) relations of sapphirine are re‐evaluated in the light of a recent new internally‐consistent data set of phase end‐members for use in phase equilibria modelling, particularly of ultra‐high‐temperature (UHT) rocks. This is achieved with the aid of relatively oxidized sapphirine+quartz‐bearing granulites from Wilson Lake, Canada. Calculated P–T projections and compatibility diagrams in the K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O–TiO₂–Fe₂O₃ (KFMASHTO) system are used to illustrate sapphirine+quartz‐bearing phase equilibria in the context of UHT metamorphism. These new a–x relations for sapphirine should allow pseudosection thermobarometry in NCKFMASHTO for estimating peak P–T conditions of sapphirine‐bearing rocks.     

Thermodynamic modelling of C–O–H fluids

H₂O, CO₂, CH₄, CO, H₂ and O₂ are the most important species in crustal fluids. The composition of these C–O–H fluids can be calculated if the pressure, temperature, carbon activity, and either the oxygen fugacity or the atomic H/O ratio of the fluid is known. The calculation methods are discussed and calculation results are illustrated with isobaric T–X_i, P–T, and isobaric–isothermal ternary C–O–H diagrams. Fluid inclusion compositions, in particular, the X_CO2/(X_CO2+X_CH4) ratio, can be used for C–O–H model calculations. However, care should be taken about possible post-entrapment changes, which may have modified the chemical composition of the fluid inclusion.