Nanometer‐scale anatomy of entire Stardust tracks

Abstract– We have developed new sample preparation and analytical techniques tailored for entire aerogel tracks of Wild 2 sample analyses both on “carrot” and “bulbous” tracks. We have successfully ultramicrotomed an entire track along its axis while preserving its original shape. This innovation allowed us to examine the distribution of fragments along the entire track from the entrance hole all the way to the terminal particle. The crystalline silicates we measured have Mg‐rich compositions and O isotopic compositions in the range of meteoritic materials, implying that they originated in the inner solar system. The terminal particle of the carrot track is a ¹⁶O‐rich forsteritic grain that may have formed in a similar environment as Ca‐, Al‐rich inclusions and amoeboid olivine aggregates in primitive carbonaceous chondrites. The track also contains submicron‐sized diamond grains likely formed in the solar system. Complex aromatic hydrocarbons distributed along aerogel tracks and in terminal particles. These organics are likely cometary but affected by shock heating.     

Three‐dimensional shapes and Fe contents of Stardust impact tracks: A track formation model and estimation of comet Wild 2 coma dust particle densities

Abstract– We investigated three‐dimensional structures of comet Wild 2 coma particle impact tracks using synchrotron radiation (SR) X‐ray microtomography at SPring‐8 to elucidate the nature of comet Wild 2 coma dust particles captured in aerogel by understanding the capture process. All tracks have a similar entrance morphology, indicating a common track formation process near the entrance by impact shock propagation irrespective of impactor materials. Distributions of elements along the tracks were simultaneously measured using SR‐XRF. Iron is distributed throughout the tracks, but it tends to concentrate in the terminal grains and at the bottoms of bulbs. Based on these results, we propose an impact track formation process. We estimate the densities of cometary dust particles based on the hypothesis that the kinetic energy of impacting dust particles is proportional to the track volume. The density of 148 cometary dust particles we investigated ranges from 0.80 to 5.96 g cm^?3 with an average of 1.01 (±0.25) g cm^?3. Moreover, we suggest that less fragile crystalline particles account for approximately 5 vol% (20 wt%) of impacting particles. This value of crystalline particles corresponds to that of chondrules and CAIs, which were transported from the inner region of the solar system to the outer comet‐forming region. Our results also suggest the presence of volatile components, such as organic material and perhaps ice, in some bulbous tracks (type‐C).     

Aerogel tracks made by impacts of glycine: Implications for formation of bulbous tracks in aerogel and the Stardust mission

Abstract– Impacts of small particles of soda‐lime glass and glycine onto low density aerogel are reported. The aerogel had a quality similar to the flight aerogels carried by the NASA Stardust mission that collected cometary dust during a flyby of comet 81P/Wild 2 in 2004. The types of track formed in the aerogel by the impacts of the soda‐lime glass and glycine are shown to be different, both qualitatively and quantitatively. For example, the soda‐lime glass tracks have a carrot‐like appearance and are relatively long and slender (width to length ratio <0.11), whereas the glycine tracks consist of bulbous cavities (width to length ratio >0.26). In consequence, the glycine particles would be underestimated in diameter by a factor of 1.7–3.2, if the glycine tracks were analyzed using the soda‐lime glass calibration and density. This implies that a single calibration for impacting particle size based on track properties, as previously used by Stardust to obtain cometary dust particle size, is inappropriate.     

Properties of original impactors estimated from three‐dimensional analysis of whole Stardust tracks

Abstract– The Stardust mission captured comet Wild 2 particles in aerogel at 6.1 km s^?1. We performed high‐resolution three‐dimensional imaging and X‐ray fluorescence mapping of whole cometary tracks in aerogel. We present the results of a survey of track structures using laser scanning confocal microscopy, including measurements of track volumes, entry hole size, and cross‐sectional profiles. We compare various methods for measuring track parameters. We demonstrate a methodology for discerning hypervelocity particle ablation rates using synchrotron‐based X‐ray fluorescence, combined with mass and volume estimates of original impactors derived from measured track properties. Finally, we present a rough framework for reconstruction of original impactor size, and volume of volatilized material, using our measured parameters. The bulk of this work is in direct support of nondestructive analysis and identification of cometary grains in whole tracks, and its eventual application to the reconstruction of the size, shape, porosity, and chemical composition of whole Stardust impactors.     

Along‐track compositional and textural variation in extensively melted grains returned from comet 81P/Wild 2 by the Stardust mission: Implications for capture‐melting process

Abstract— Five amorphous (extensively melted) grains from Stardust aerogel capture Track 35 were examined by transmission electron microscopy (TEM); two from the bulb, two from near the bulb‐stylus transition, and one from near the terminal particle. Melted grains consist largely of a texturally and compositionally heterogeneous emulsion of immiscible metal/sulfide beads nanometers to tens of nanometers in diameter in a silica‐rich vesicular glass. Most metal/sulfide beads are spherical, but textures of non‐spherical beads indicate that some solidified as large drops during stretching and breaking while in translational and rotational motion, and others solidified from lenses of immiscible liquid at the silicate‐melt/vesicle (vapor) interface. Melted grains appear to become richer in Fe relative to Mg, and depleted in S relative to Fe and Ni with increasing penetration distance along the aerogel capture track. Fe/S ratios are near unity in grains from the bulb of Track 35, consistent with the dominance of Fe‐monosulfide minerals inferred by previous research on Stardust materials. Near‐stoichiometric Fe/S in melted grains from the bulb suggests that Fe‐sulfides in the bulb were dispersed and melted during formation of the bulb but did not lose S. Along‐track increases in Fe/S in melted grains from the bulb through the bulb‐stylus transition and continuing into the stylus indicate that S initially present as iron monosulfide may have been progressively partially volatilized and lost from the melted grains with greater penetration of the grains deeper into the aerogel during capture‐melting of comet dust. Extensively melted grains from the bulbs of aerogel capture tracks may preserve better primary compositional information with less capture‐related modification than grains from farther along the same capture tracks.     

Fine‐grained material of 81P/Wild 2 in interaction with the Stardust aerogel

Abstract– The deceleration tracks in the Stardust aerogel display a wide range of morphologies, which reveal a large diversity of incoming particles from comet 81P/Wild 2. If the large and dense mineral grains survived the extreme conditions of hypervelocity capture, this was not the case for the fine‐grained material that is found strongly damaged within the aerogel. Due to their low mechanical strength, these assemblages were disaggregated, dispersed, and flash melted in the aerogel in walls of bulbous deceleration tracks. Their petrologic and mineralogical properties are found significantly modified by the flash heating of the capture. Originating from a quenched melt mixture of comet material and aerogel, the representative microstructure consists of silica‐rich glassy clumps containing Fe‐Ni‐S inclusions, vesicles and “dust‐rich” patches, the latter being remnants of individual silicate components of the impacting aggregate. The average composition of these melted particle fragments is close to the chondritic CI composition. They might originate from ultrafine‐grained primitive components comparable to those found in chondritic porous IDPs. Capture effects in aerogel and associated sample biases are discussed in terms of size, chemical and mineralogical properties of the grains. These properties are essential for the grain survival in the extremely hot environment of hypervelocity impact capture in aerogel, and thus for inferring the correct properties of Wild 2 material.     

Fine‐grained material encased in microtracks of Stardust samples

Dust from comet 81P/Wild 2 was captured at high speed in silica aerogel collectors during the Stardust mission. Studies of deceleration tracks in aerogel showed that a number of cometary particles were poorly cohesive and fragmented during impact. Fragments are now scattered along the walls of impact cavities. Here, we report a transmission electron microscope study of a piece of aerogel extracted from the wall of track 10. We focused on micron‐sized secondary tracks along which fragments of a fine‐grained material are disseminated. Two populations of fragments were identified. The first is made of polycrystalline silicate assemblages (olivine, pyroxene, and spinel) that appear to be chemically related to each other. The second corresponds to silica‐rich glassy clumps characteristic of a mixture of melted cometary material and aerogel. A significant number of fragments have been found with a composition close to chondritic CI for the major elements Fe‐Mg‐S at a submicron scale. These fragments have thus never been chemically differentiated by high‐temperature processes prior to the accretion on the comet, in contrast to terminal particles, which are dominated by larger, denser, and frequently monomineralic components.     

Experimental impact features in Stardust aerogel: How track morphology reflects particle structure,composition, and density

Abstract– The Stardust collector shows diverse aerogel track shapes created by impacts of cometary dust. Tracks have been classified into three broad types (A, B, and C), based on relative dimensions of the elongate “stylus” (in Type A “carrots”) and broad “bulb” regions (Types B and C), with occurrence of smaller “styli” in Type B. From our experiments, using a diverse suite of projectile particles shot under Stardust cometary encounter conditions onto similar aerogel targets, we describe differences in impactor behavior and aerogel response resulting in the observed range of Stardust track shapes. We compare tracks made by mineral grains, natural and artificial aggregates of differing subgrain sizes, and diverse organic materials. Impacts of glasses and robust mineral grains generate elongate, narrow Type A tracks (as expected), but with differing levels of abrasion and lateral branch creation. Aggregate particles, both natural and artificial, of a wide range of compositions and volatile contents produce diverse Type B or C shapes. Creation of bulbous tracks is dependent upon impactor internal structure, grain size distribution, and strength, rather than overall grain density or content of volatile components. Nevertheless, pure organic particles do create Type C, or squat Type A* tracks, with length to width ratios dependent upon both specific organic composition and impactor grain size. From comparison with the published shape data for Stardust aerogel tracks, we conclude that the abundant larger Type B tracks on the Stardust collector represent impacts by particles similar to our carbonaceous chondrite meteorite powders.     

Comparison of GEMS in interplanetary dust particles and GEMS‐like objects in a Stardust impact track in aerogel

Comet 81P/Wild 2 dust, the first comet sample of known provenance, was widely expected to resemble anhydrous chondritic porous (CP) interplanetary dust particles (IDPs). GEMS, distinctly characteristic of CP IDPs, have yet to be unambiguously identified in the Stardust mission samples despite claims of likely candidates. One such candidate is Stardust impact track 57 “Febo” in aerogel, which contains fine‐grained objects texturally and compositionally similar to GEMS. Their position adjacent the terminal particle suggests that they may be indigenous, fine‐grained, cometary material, like that in CP IDPs, shielded by the terminal particle from damage during deceleration from hypervelocity. Dark‐field imaging and multidetector energy‐dispersive X‐ray mapping were used to compare GEMS‐like‐objects in the Febo terminal particle with GEMS in an anhydrous, chondritic IDP. GEMS in the IDP are within 3× CI (solar) abundances for major and minor elements. In the Febo GEMS‐like objects, Mg and Ca are systematically and strongly depleted relative to CI; S and Fe are somewhat enriched; and Au, a known aerogel contaminant, is present, consistent with ablation, melting, abrasion, and mixing of the SiO_x aerogel with crystalline Fe‐sulfide and minor enstatite, high‐Ni sulfide, and augite identified by elemental mapping in the terminal particle. Thus, GEMS‐like objects in “caches” of fine‐grained debris abutting terminal particles are most likely deceleration debris packed in place during particle transit through the aerogel.     

Penetration into low-density media: In situ observation of penetration process of various projectiles

In order to understand the penetration process of projectiles into lower-density targets, we carry out hypervelocity impact experiments using low-density (60 mg cm^?3) aerogel targets and various types of projectiles, and observe the track formation process in the targets using a high-speed camera. A carrot shaped track, a bulbous, and a “hybrid” one consisting of bulbous and thin parts, are formed. The results of the high-speed camera observations reveal the similarity and differences on the temporal evolution of the penetration depth and maximum diameter of these tracks. At very early stages of an impact, independent of projectile type, the temporal penetration depth is described by hydrodynamic models for the original projectiles. Afterward, when the breakup of projectiles does not occur, intact projectiles continue to penetrate the aerogels. In the case of the breakup of projectiles, the track expands with a velocity of about a sound velocity of the aerogel at final stages. If there are large fragments, they penetrate deeper and the tracks become a hybrid type. The penetration of the large fragments is described by hydrodynamic models. Based on these results, we discuss the excavation near the impact point by shock waves.     

Organic compound alteration during hypervelocity collection of carbonaceous materials in aerogel

Abstract— The NASA Stardust mission brought to Earth micron‐size particles from the coma of comet 81P/Wild 2 using aerogel, a porous silica material, as the capture medium. A major challenge in understanding the organic inventory of the returned comet dust is identifying, unambiguously, which organic molecules are indigenous to the cometary particles, which are produced from carbon contamination in the Stardust aerogel, and which are cometary organics that have been modified by heating during the particle capture process. Here it is shown that 1) alteration of cometary organic molecules along impact tracks in aerogel is highly dependent on the original particle morphology, and 2) organic molecules on test‐shot terminal particles are mostly preserved. These conclusions are based on two‐step laser mass spectrometry (L²MS) examinations of test shots with organic‐laden particles (both tracks in aerogel and the terminal particles themselves).     

Comprehensive examination of large mineral and rock fragments in Stardust tracks: Mineralogy,analogous extraterrestrial materials,and source regions

Abstract– Transmission electron microscopy examination of 87 large fragments from 16 carrot‐shaped and bulbous Stardust (SD) tracks was performed to study the range and diversity of materials present in comet Wild 2. Olivines and low‐Ca pyroxenes represent the largest proportions of fragments observed; however, a wide range of minerals and rocks were found including probable ferromagnesian, Al‐rich and Si‐rich chondrule fragments, a refractory inclusion, possible matrix mineral/lithic clasts, and probable condensate minerals. These materials, combined with fine‐grained components in the tracks, are analogous to components in unequilibrated chondrite meteorites and cluster interplanetary dust particles (IDPs). Two unusual lithologies in the bulbous tracks are only observed in chondritic porous IDPs and may have direct links to IDPs. The absence of phyllosilicates indicates that comet Wild 2 may be a “dry” comet that did not accrete or form significant amounts of hydrated phases. Some large mineral fragments in the SD tracks are analogous to large mineral IDPs. The large variations of the coarse‐grained components within and between all 16 tracks show that comet Wild 2 is mineralogically diverse and unequilibrated on nearly all scales and must have accreted materials from diverse source regions that were widely dispersed throughout the solar nebula.     

An igneous fragment from cluster IDP L2011#21: An analog for the source of pyrrhotite and taenite in comet 81P/Wild 2 captured in Stardust aerogel

The silica glass extracted from the bulbous parts of Stardust tracks is riddled by electron‐opaque nanograins with compositions that are mostly between pyrrhotite and metallic iron with many fewer nanograins having a Fe‐Ni‐S composition. Pure taenite nanograins are extremely rare, but exist among the terminal particles. Assuming that these Fe‐Ni‐S compositions are due to mixing of pyrrhotite and taenite melt droplets, it is remarkable that the taenite melt grains had discrete Fe/Ni ratios. This paper presents the data from an igneous pyrrhotite/taenite fragment of cluster IDP L2011#21, wherein the taenite compositions have the same discrete Fe/Ni clusters as those inferred for the Stardust nanograins. These Fe/Ni clusters are a subsolidus feature with compositions that are constrained by the Fe‐Ni phase diagram. They formed during cooling of the parent body of this cluster IDP fragment. These specific Fe/Ni ratios, 12.5, 24, 40, and 53 atom% Ni, were preserved in asteroidal taenite that survived radially outward transport to the Kuiper Belt where it accreted into the (future) comet Wild 2 nucleus.     

Microscopic impactor debris in the soil around Kamil crater (Egypt): Inventory,distribution, total mass,and implications for the impact scenario

We report on the microscopic impactor debris around Kamil crater (45 m in diameter, Egypt) collected during our 2010 geophysical expedition. The hypervelocity impact of Gebel Kamil (Ni‐rich ataxite) on a sandstone target produced a downrange ejecta curtain of microscopic impactor debris due SE–SW of the crater (extending ~300,000 m², up to ~400 m from the crater), in agreement with previous determination of the impactor trajectory. The microscopic impactor debris include vesicular masses, spherules, and coatings of dark impact melt glass which is a mixture of impactor and target materials (Si‐, Fe‐, and Al‐rich glass), plus Fe‐Ni oxide spherules and mini shrapnel, documenting that these products can be found in craters as small as few tens of meters in diameter. The estimated mass of the microscopic impactor debris (<290 kg) derived from Ni concentrations in the soil is a small fraction of the total impactor mass (~10 t) in the form of macroscopic shrapnel. That Kamil crater was generated by a relatively small impactor is consistent with literature estimates of its pre‐atmospheric mass (>20 t, likely 50–60 t).     

Formation of the Treysa quintet and the main‐group pallasites by impact‐generated processes in the IIIAB asteroid

Treysa and Delegate have compositions closely similar to those of IIIAB irons but plot above the IIIAB field on Ir‐Au diagrams; for this reason they are designated anomalous members of IIIAB. All refractory siderophiles share this anomaly. Wasson ( 1999 ) interpreted the large spread on IIIAB Ir‐Au diagrams to result from melt‐trapping and generated solid and liquid fractional crystallization tracks; almost all IIIAB irons fall between the tracks. In contrast, Treysa, Delegate, and three other irons (the Treysa quintet) plot beyond the liquid track. Ideal fractional crystallization cannot account for compositions that plot outside the region between the tracks. Possible explanations for the anomalous compositions of the Treysa quintet are that (1) these meteorites did not form in the IIIAB magma or (2) they formed by the mixing of early crystallized solids with a late liquid. The weight of the evidence including cosmic‐ray ages favor the second explanation. Although this explanation can account for positions plotting above the liquid track, it requires special circumstances. The infalling blocks must be assimilated and the resulting melt must crystallize quickly into pockets small enough (<1 m) to allow igneous gradients to be leveled by subsequent diffusion. The Treysa quintet shares the region beyond the liquid track with most main‐group pallasites (PMG), which may have also originated in the IIIAB body. It appears that Treysa, its relatives, and the PMG were formed in one or more impact events that mixed olivine and solid metal formed near the core‐mantle boundary with nearby magma. It is then necessary to cool the melt rapidly; the best way to achieve rapid cooling is by heat exchange with cooler solids. That the Treysa quintet and the PMG can be explained by the same processes operating on late IIIAB magma supports the conclusion that PMG formed on the IIIAB parent asteroid.     

TOF‐SIMS analysis of Allende projectiles shot into silica aerogel

Abstract— Powdered Allende projectiles were fired into silica aerogel at 6.1 km/sec in order to evaluate particle retrieval and analysis techniques for samples from the Stardust mission. Since particles may disintegrate and ablate along the penetration paths in a high‐porosity aerogel, TOF‐SIMS analysis may be a suitable method to determine the distribution of such materials along the tracks as well as potential compositional modifications. Therefore, two ?350 μm‐sized tracks, residing at the surface of a keystone specimen that was flattened between two silicon chips, were analyzed. TOF‐SIMS allows for a detailed study of the chemical composition of particles that survived the impact mostly intact and of fine‐grained material from disintegrated projectiles. In the investigated keystone, material from light gas gun debris dominated. Besides the two tracks, a continuous, 40‐μm‐thick surface layer of implanted material—probably gun residue—was found. One of the two analyzed tracks is compositionally distinct from this surface layer and is likely to contain residual material of an Allende projectile. The analyses clearly demonstrate that tracks, resulting from impactors in the 5–10 μm size range, can be successfully analyzed with TOF‐SIMS.     

Three‐dimensional textural and compositional analysis of particle tracks and fragmentation history in aerogel

Abstract— We report analyses of aerogel tracks using (1) synchrotron X‐ray computed microtomography (XRCMT), (2) laser confocal scanning microscopy (LCSM), and (3) synchrotron radiation X‐ray fluorescence (SRXRF) of particles and their paths resulting from simulated hypervelocity impacts (1–2), and a single ～1 mm aerogel track from the Stardust cometary sample collector (1–3). Large aerogel pieces can be imaged sequentially, resulting in high spatial resolution images spanning many tomographic fields of view (‘lambda‐tomography’). We report calculations of energy deposited, and tests on aromatic hydrocarbons showing no alteration in tomography experiments. Imaging at resolutions from ～17 to ～1 micron/pixel edge (XRCMT) and to <100 nm/pixel edge (LCSM) illustrates track geometry and interaction of particles with aerogel, including rifling, particle fragmentation, and final particle location. We present a 3‐D deconvolution method using an estimated point‐spread function for aerogel, allowing basic corrections of LCSM data for axial distortion. LCSM allows rapid, comprehensive, non‐destructive, high information return analysis of tracks in aerogel keystones, prior to destructive grain extraction. SRXRF with LCSM allows spatial correlation of grain size, chemical, and mineralogical data. If optical methods are precluded in future aerogel capture missions, XRCMT is a viable 3D imaging technique. Combinations of these methods allow for complete, nondestructive, quantitative 3‐D analysis of captured materials at high spatial resolution. This data is fundamental to understanding the hypervelocity particle‐aerogel interaction histories of Stardust grains.     

Penetration tracks in aerogel produced by Al2O3 spheres

Abstract— We conducted impact experiments into SiO₂‐based aerogel of uniform density (0.02 g cm^?3) with spherical corundum projectiles. The highly refractory nature and mechanical strength of corundum minimizes projectile deformation and continuous mass loss by ablation that might have affected earlier experiments with soda‐lime glass (SLG) impactors into aerogel targets. We find that corundum is a vastly superior penetrator producing tracks a factor of 2.5 longer, yet similar in diameter to those made by SLG. At velocities <4 km s^?1 a cylindrical “cavity” forms, largely by melting of aerogel. The diameter and length of this cavity increase with velocity and impactor size, and its volume dominates total track volume. A continuously tapering, exceptionally long and slender “stylus” emerges from this cavity and makes up some 80–90% of the total track length; this stylus is characterized by solid‐state deformations. Tracks formed below 4 km s^?1 lack the molten cavity and consist only of a stylus. Projectile residues recovered from a track's terminus substantially resemble the initial impactors at V > 4 km s^?1, yet they display two distinct surfaces at higher velocities, such as a blunt, forward face and a well‐preserved, hemispherical trailing side; a pronounced, circumferential ridge of compressed and molten aerogel separates these two surfaces. Stringers and patches of melt flow towards the impactor's rear where they accumulate in a characteristic melt tip. SEM‐EDS analyses indicate the presence of Al in these melts at velocities as low as 5.2 km s^?1, indicating that the melting point of corundum (2054 °C) was exceeded. The thermal model of aerogel impact by Anderson and Cherne (2008) suggests actual aerogel temperatures <5000 K at comparable conditions. We therefore propose that projectile melting occurs predominantly at those surfaces that are in contact with this very hot aerogel, at the expense of viscous heating and associated ablation. Exposure to superheated aerogel may be viewed as extreme form of “flash heating.” This seems consistent with observations from the Stardust mission to comet Wild 2, such as relatively pristine interiors of rather large, terminal particles, yet total melting of most fine‐grained dust components.     

Micron‐scale hypervelocity impact craters: Dependence of crater ellipticity and rim morphology on impact trajectory,projectile size,velocity, and shape

The interstellar collector on NASA's Stardust mission captured many particles from sources other than the interstellar dust stream. Impact trajectory may provide a means of discriminating between these different sources, and thus identifying/eliminating candidate interstellar particles. The collector's aerogel preserved a clear record of particle impact trajectory from the inclination and direction of the resultant tracks. However, the collector also contained aluminum foils and, although impact crater studies to date suggest only the most inclined impacts (>45° from normal) produce crater morphologies that indicate trajectory (i.e., distinctly elliptical), these studies have been restricted to much larger (mm and above) scales than are relevant for Stardust (μm). It is unknown how oblique impact crater morphology varies as a function of length scale, and therefore how well Stardust craters preserve details of impactor trajectory. Here, we present data from a series of impact experiments, together with complementary hydrocode modeling, that examine how crater morphology changes with impact angles for different‐sized projectiles. We find that, for our smallest spherical projectiles (2 μm diameter), the ellipticity and rim morphology provide evidence of their inclined trajectory from as little as 15° from normal incidence. This is most likely a result of strain rate hardening in the target metal. Further experiments and models find that variation in velocity and impactor shape complicate these trends, but that rim morphology remains useful in determining impact direction (where the angle of impact is >20° from normal) and may help identify candidate interstellar particle craters on the Stardust collector.