Properties of original impactors estimated from three‐dimensional analysis of whole Stardust tracks

Abstract– The Stardust mission captured comet Wild 2 particles in aerogel at 6.1 km s^?1. We performed high‐resolution three‐dimensional imaging and X‐ray fluorescence mapping of whole cometary tracks in aerogel. We present the results of a survey of track structures using laser scanning confocal microscopy, including measurements of track volumes, entry hole size, and cross‐sectional profiles. We compare various methods for measuring track parameters. We demonstrate a methodology for discerning hypervelocity particle ablation rates using synchrotron‐based X‐ray fluorescence, combined with mass and volume estimates of original impactors derived from measured track properties. Finally, we present a rough framework for reconstruction of original impactor size, and volume of volatilized material, using our measured parameters. The bulk of this work is in direct support of nondestructive analysis and identification of cometary grains in whole tracks, and its eventual application to the reconstruction of the size, shape, porosity, and chemical composition of whole Stardust impactors.     

X‐ray fluorescence measurements of the surface elemental composition of asteroid 433 Eros

Abstract— We report major element ratios determined for the S‐class asteroid 433 Eros using remote‐sensing x‐ray fluorescence spectroscopy with the near‐Earth asteroid rendezvous Shoemaker x‐ray spectrometer (XRS). Data analysis techniques and systematic errors are described in detail. Data acquired during five solar flares and during two extended “quiet Sun” periods are presented; these results sample a representative portion of the asteroid's surface. Although systematic uncertainties are potentially large, the most internally consistent and plausible interpretation of the data is that Eros has primitive Mg/Si, Al/Si, Ca/Si and Fe/Si ratios, closely similar to H or R chondrites. Global differentiation of the asteroid is ruled out. The S/Si ratio is much lower than that of chondrites, probably reflecting impact‐induced volatilization and/or photo‐ or ion‐induced sputtering of sulfur at the surface of the asteroid. An alternative explanation for the low S/Si ratio is that it reflects a limited degree of melting with loss of an FeS‐rich partial melt. Size‐sorting processes could lead to segregation of Fe‐Ni metal from silicates within the regolith of Eros; this could indicate that the Fe/Si ratios determined by the x‐ray spectrometer are not representative of the bulk Eros composition.     

Effect of a synchrotron X‐ray microtomography imaging experiment on the amino acid content of a CM chondrite

X‐ray microcomputed tomography and synchrotron X‐ray microcomputed tomography (μCT) are becoming popular tools for the reconnaissance imaging of chondrites. However, there are occasional concerns that the use of μCT may be detrimental to organic components of a chondrite. Soluble organic compounds represent ~2–10% of the total solvent extractable carbon in CI and CM carbonaceous chondrites and amino acids are among the most abundant compounds in the soluble organic fraction. We irradiated two samples of the Murchison CM2 carbonaceous chondrite under conditions slightly harsher (increased beam exposure time) than those typically used for x‐ray μCT imaging experiments to determine if detectable changes in the amino acid abundance and distribution relative to a nonexposed control sample occurred. After subjecting two meteorite portions to ionizing radiation dosages of 1.1 kiloGray (kGy) and 1.2 kGy with 48.6 and 46.6 keV monochromatic X‐rays, respectively, we analyzed the amino acid content of each sample. Within analytical errors, we found no differences in the amino acid abundances or enantiomeric ratios when comparing the control samples (nonexposed Murchison) and the irradiated samples. We show with calculations that any sample heating due to x‐ray exposure is negligible. We conclude that a monochromatic synchrotron X‐ray μCT experiment at beamline 13‐BM‐D of the Advanced Photon Source, which imparts ~1 kGy doses, has no detectable effect on the amino acid content of a carbonaceous chondrite. These results are important for the initial reconnaissance of returned samples from the OSIRIS‐REx and Hayabusa 2 asteroid sample return missions.     

Three‐dimensional shapes and Fe contents of Stardust impact tracks: A track formation model and estimation of comet Wild 2 coma dust particle densities

Abstract– We investigated three‐dimensional structures of comet Wild 2 coma particle impact tracks using synchrotron radiation (SR) X‐ray microtomography at SPring‐8 to elucidate the nature of comet Wild 2 coma dust particles captured in aerogel by understanding the capture process. All tracks have a similar entrance morphology, indicating a common track formation process near the entrance by impact shock propagation irrespective of impactor materials. Distributions of elements along the tracks were simultaneously measured using SR‐XRF. Iron is distributed throughout the tracks, but it tends to concentrate in the terminal grains and at the bottoms of bulbs. Based on these results, we propose an impact track formation process. We estimate the densities of cometary dust particles based on the hypothesis that the kinetic energy of impacting dust particles is proportional to the track volume. The density of 148 cometary dust particles we investigated ranges from 0.80 to 5.96 g cm^?3 with an average of 1.01 (±0.25) g cm^?3. Moreover, we suggest that less fragile crystalline particles account for approximately 5 vol% (20 wt%) of impacting particles. This value of crystalline particles corresponds to that of chondrules and CAIs, which were transported from the inner region of the solar system to the outer comet‐forming region. Our results also suggest the presence of volatile components, such as organic material and perhaps ice, in some bulbous tracks (type‐C).     

Three‐dimensional textural and compositional analysis of particle tracks and fragmentation history in aerogel

Abstract— We report analyses of aerogel tracks using (1) synchrotron X‐ray computed microtomography (XRCMT), (2) laser confocal scanning microscopy (LCSM), and (3) synchrotron radiation X‐ray fluorescence (SRXRF) of particles and their paths resulting from simulated hypervelocity impacts (1–2), and a single ～1 mm aerogel track from the Stardust cometary sample collector (1–3). Large aerogel pieces can be imaged sequentially, resulting in high spatial resolution images spanning many tomographic fields of view (‘lambda‐tomography’). We report calculations of energy deposited, and tests on aromatic hydrocarbons showing no alteration in tomography experiments. Imaging at resolutions from ～17 to ～1 micron/pixel edge (XRCMT) and to <100 nm/pixel edge (LCSM) illustrates track geometry and interaction of particles with aerogel, including rifling, particle fragmentation, and final particle location. We present a 3‐D deconvolution method using an estimated point‐spread function for aerogel, allowing basic corrections of LCSM data for axial distortion. LCSM allows rapid, comprehensive, non‐destructive, high information return analysis of tracks in aerogel keystones, prior to destructive grain extraction. SRXRF with LCSM allows spatial correlation of grain size, chemical, and mineralogical data. If optical methods are precluded in future aerogel capture missions, XRCMT is a viable 3D imaging technique. Combinations of these methods allow for complete, nondestructive, quantitative 3‐D analysis of captured materials at high spatial resolution. This data is fundamental to understanding the hypervelocity particle‐aerogel interaction histories of Stardust grains.     

Internal structure of type I deep‐sea spherules by X‐ray computed microtomography

Abstract— The internal structures of type I spherules (melted micrometeorites rich in iron) have been investigated using synchrotron‐based computed microtomography. Variations from sphericity are small—the average ratio of the largest to the smallest semimajor axis is 1.07 ± 0.06. The X‐ray tomographs reveal interior cavities, four spherules with metal cores with diameters ranging from 57 to 143 μm and, in two spherules, high attenuation features thought to be nuggets rich in platinumgroup elements. Bulk densities range from 4.2 to 5.9 g/cm³ and average grain densities from 4.5 to 6.5 (g/cm³) with uncertainties of 10–15%. The average grain densities are those expected for materials containing mostly oxides of iron and nickel. The tomographic density measurements indicate an average void space of 5⁺⁸_‐5%. The void spaces may be contraction features or the skeletons of bubbles that formed in the molten precursors during atmospheric passage.     

Nanometer‐scale anatomy of entire Stardust tracks

Abstract– We have developed new sample preparation and analytical techniques tailored for entire aerogel tracks of Wild 2 sample analyses both on “carrot” and “bulbous” tracks. We have successfully ultramicrotomed an entire track along its axis while preserving its original shape. This innovation allowed us to examine the distribution of fragments along the entire track from the entrance hole all the way to the terminal particle. The crystalline silicates we measured have Mg‐rich compositions and O isotopic compositions in the range of meteoritic materials, implying that they originated in the inner solar system. The terminal particle of the carrot track is a ¹⁶O‐rich forsteritic grain that may have formed in a similar environment as Ca‐, Al‐rich inclusions and amoeboid olivine aggregates in primitive carbonaceous chondrites. The track also contains submicron‐sized diamond grains likely formed in the solar system. Complex aromatic hydrocarbons distributed along aerogel tracks and in terminal particles. These organics are likely cometary but affected by shock heating.     

X‐ray luminosity functions of different morphological and X‐ray type AGN populations

Luminosity functions are one of the most important observational clues when studying galaxy evolution over cosmic time. In this paper we present the X‐ray luminosity functions for X‐ray detected AGN in the SXDS and GWS fields. The limiting fluxes of our samples are 9.0 ×10^–15 and 4.8 ×10^–16 erg cm^–2 s^–1 in the 0.5–7.0 keV band in the two fields, respectively. We carried out analysis in three X‐ray bands and in two redshift intervals up to z ≤ 1.4. Moreover, we derive the luminosity functions for different optical morphologies and X‐ray types. We confirm strong luminosity evolution in all three bands, finding the most luminous objects at higher redshift. However, no signs of density evolution are found in any tested X‐ray band. We obtain similar results for compact and early‐type objects. Finally, we observe the “Steffen effect”, where X‐ray type‐1 sources are more numerous at higher luminosities in comparison with type‐2 sources. (© 2013 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Space shuttle observations of terrestrial impact structures using SIR‐C and X‐SAR radars

Abstract— Ten terrestrial impact structures were imaged during two flights of the 1994 space radar laboratory (SRL) experiment. These craters include Wolf Creek, Australia; Roter Kamm, Namibia; Zhamanshin, Kazakhstan; BP and Oasis, Libya; Aorounga, Chad; Amguid, Algeria; and Spider, Connolly Basin and Henbury, Australia. SRL contained two co‐registered instruments; the United States shuttle imaging radar‐C (SIR‐C) polarimetric radar system operating in L‐band (λ = 24 cm) and C‐band (λ = 5.6 cm), and the joint German/Italian synthetic aperture radar (X‐SAR) operating in vertically‐polarized X‐band (λ = 3 cm). Comparisons show SRL images to be complementary to, or in some cases superior to, corresponding optical images for evaluating size, location, and relative age of impact features. Regardless of wavelength or polarization, craters with significant relief appear prominently on radar as a result of slope and roughness effects. In desert regions, longer wavelengths penetrate dry sand mantles to reveal hidden crater dimensions or associated buried landforms. Radar polarities and wavelengths are particularly sensitive to vegetation, surface roughness, and soil moisture or electrical properties. In the more temperate environments of Kazakhstan and Australia, SRL images show detailed stream patterns that reveal the location and structure of otherwise obscured impact features.     

Combining IR and X‐ray microtomography data sets: Application to Itokawa particles and to Paris meteorite

In the near future, a new generation of sample return missions (Hayabusa2, OSIRIS‐REx, MMX, etc.) will collect samples from small solar system bodies. To maximize the scientific outcome of laboratory studies and minimize the loss of precious extraterrestrial samples, an analytical sequence from less destructive to more destructive techniques needs to be established. In this work, we present a combined X‐ray and IR microtomography applied to five Itokawa particles and one fragment of the primitive carbonaceous chondrite Paris. We show that this analytical approach is able to provide a 3‐D physical and chemical characterization of individual extraterrestrial particles, using the measurement of their 3‐D structure and porosity, and the detection of mineral and organic phases, and their spatial co‐localization in 3‐D. We propose these techniques as an efficient first step in a multitechnique analytical sequence on microscopic samples collected by space missions.     

Effect of polychromatic X‐ray microtomography imaging on the amino acid content of the Murchison CM chondrite

X‐ray microcomputed tomography (μCT) is a useful means of characterizing cosmochemical samples such as meteorites or robotically returned samples. However, there are occasional concerns that the use of μCT may be detrimental to the organic components of a chondrite. Small organic compounds such as amino acids comprise up to ~10% of the total solvent extractable carbon in CM carbonaceous chondrites. We irradiated three samples of the Murchison CM carbonaceous chondrite under conditions akin to and harsher than those typically used during typical benchtop X‐ray μCT imaging experiments to determine if detectable changes in the amino acid abundance and distribution relative to a nonexposed Murchison control sample occurred. After subjecting three meteorite samples to ionizing radiation dosages between ~300 Gray (Gy) and 3 kGy with bremstrahlung X‐rays, we analyzed the amino acid content of each sample. Within sampling and analytical errors, we cannot discern differences in the amino acid abundances and amino acid enantiomeric ratios when comparing the control samples (nonexposed Murchison) and the irradiated samples. We conclude that a polychromatic X‐ray μCT experiment does not alter the abundances of amino acids to a degree greater than how well those abundances are measured with our techniques and therefore any damage to amino acids is minimal.     

Doppler Tomography of X‐ray binaries

The Space Telescope Imaging Spectrograph (STIS) on HST provides the first ultraviolet data that are of sufficient spectral and temporal resolution to generate Doppler tomograms of X‐ray binaries.We show both optical and ultraviolet maps constructed for the intermediate mass system Hercules X‐1/HZ Her and the massive wind‐fed system SMC X‐1/SK160. We have used the maps and corresponding lightcurves as diagnostics with which to test the validity of published models for Hercules X‐1. We find that although the models are mostly able to explain the light curves they are not consistent with the full phase maps. We present simulations of Doppler maps of X‐ray lines that will be possible with the spectral and temporal resolution and substantial effective area of the next major X‐ray mission, Con‐X. (© 2004 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Meteorite 3‐D synchrotron microtomography: Methods and applications

Abstract— Methods of synchrotron X‐ray computed microtomography (XRCMT) are described, which allow nondestructive, high spatial and contrast resolution imaging of the density structures of meteorites and their components in three dimensions. Images of bulk chondrites (to one cubic centimeter in size) reveal compound chondrules, chondrule/matrix volumetric ratios, metal and sulfide distribution, petrofabrics, and 3‐D chondrule and calcium‐aluminum inclusion (CAI) sizes and shapes. Images of separated chondrules and CAIs reveal void spaces, mineral intergrowth textures, and the true locations of crystal rims and cores, at resolutions to <8 cubic micron/volume element. Images of achondrites reveal mineral fabrics and crystal zoning. Lunar glass spherules can be searched for phenocrysts bearing deeply sourced melt inclusions. A companion DVD and URL contain images for classroom and research use. Numerical techniques for quantification of X‐ray computed microtomography (XRCMT) data and its potential applications are discussed. Three‐dimensional X‐ray images of meteorites provide a way to discover components of interest and to precisely slice samples to expose these components with minimal damage and loss of material. Three‐dimensional studies of petrographic features (size, shape, texture, and modal abundance) of chondrites and their components, as well as other meteorites, have definite advantages over standard 2‐D studies using randomly sliced thin sections.     

A 3‐D study of mineral inclusions in chromite from ordinary chondrites using synchrotron radiation X‐ray tomographic microscopy—Method and applications

Abstract– A method is described for imaging in 3‐D the interiors of meteoritic chromite grains and their inclusions using synchrotron radiation X‐ray tomographic microscopy. In ordinary chondrites, chromite is the only common mineral that survives long‐term weathering on Earth. Information about the silicate matrix of the original meteorite, however, can be derived from mineral inclusions preserved in the protecting chromite. The inclusions are crucial in the classification of fossil meteorites as well as sediment‐dispersed chromite grains from decomposed meteorites and larger impacts, as these are used for characterizing the past influx of material to Earth, but have previously been difficult to locate. The method is non‐destructive and time efficient for locating inclusions. The method allowed quantitative and morphological studies of both host chromite grains and inclusions in three dimensions. The study of 385 chromite grains from eight chondrites (H4–6, L4–6, LL4, LL6) reveals that inclusions are abundant and equally common in all samples. Almost two‐thirds of all chromite grains contain inclusions, regardless of group and type. The study also shows that the size of the inclusions and the host chromite grains, as well as the number of inclusions, within the host chromite grains vary with petrographic type. Thus, the petrographic type of the host of a suite of chromite grains can be determined based solely on inclusion content. The study also revealed that the amount of fractures in the host chromite can be correlated to previously assigned shock stages for the various chondrites. The study has thus shown that the features and inclusions of fossil chromite grains can give similar information about a former host meteorite as do studies of an unweathered whole meteorite, meaning that this technique is essential in the studies of ancient meteorite flux to Earth.     

Stardust impact analogs: Resolving pre‐ and postimpact mineralogy in Stardust Al foils

Abstract– The grains returned by NASA’s Stardust mission from comet 81P/Wild 2 represent a valuable sample set that is significantly advancing our understanding of small solar system bodies. However, the grains were captured via impact at ～6.1 km s^?1 and have experienced pressures and temperatures that caused alteration. To ensure correct interpretations of comet 81P/Wild 2 mineralogy, and therefore preaccretional or parent body processes, an understanding of the effects of capture is required. Using a two‐stage light‐gas gun, we recreated Stardust encounter conditions and generated a series of impact analogs for a range of minerals of cometary relevance into flight spare Al foils. Through analyses of both preimpact projectiles and postimpact analogs by transmission electron microscopy, we explore the impact processes occurring during capture and distinguish between those materials inherent to the impactor and those that are the product of capture. We review existing and present additional data on olivine, diopside, pyrrhotite, and pentlandite. We find that surviving crystalline material is observed in most single grain impactor residues. However, none is found in that of a relatively monodisperse aggregate. A variety of impact‐generated components are observed in all samples. Al incorporation into melt‐derived phases allows differentiation between melt and shock‐induced phases. In single grain impactor residues, impact‐generated phases largely retain original (nonvolatile) major element ratios. We conclude that both surviving and impact‐generated phases in residues of single grain impactors provide valuable information regarding the mineralogy of the impacting grain whilst further studies are required to fully understand aggregate impacts and the role of subgrain interactions during impact.     

X‐ray energy spectra of CAL87

We present X‐ray spectral analysis of the super‐soft source CAL87 using ASCA, Chandra, XMM‐Newton observations. Early ASCA CCD spectrum reported a strong oxygen absorption edge, which is considered to originate in the an optically thick white‐dwarf atmosphere. On the other hand, contemporaneous grating observations by Chandra and XMM‐Newton indicate emission line dominated spectra, which obviously indicate the optically thin origin. Fitting all the available CCD (ASCA and XMM‐Newton) and grating spectra (XMM‐Newton and Chandra) simultaneously, we show that the CAL87 X‐ray energy spectrum is in fact composed of both an optically thick component with deep absorption edges and an optically thin component with numerous emission lines. The current result supports the standard SSS model that the primary source of X‐ray emission is nuclear burning in the white dwarf atmosphere, surrounded by a highly photoionised, optically thin corona (© 2010 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

High spectral resolution X‐ray observations of AGN

A brief overview of some highlights of high spectral resolution X‐ray observations of AGN is given, mainly obtained with the RGS of XMM‐Newton. Future prospects for such observations with XMM‐Newton are given. (© 2008 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Extragalactic X‐ray surveys: AGN physics and evolution

We review the most important findings on AGN physics and cosmological evolution as obtained by extragalactic X‐ray surveys and associated multiwavelength observations. We briefly discuss the perspectives for future enterprises and in particular the scientific case for an extremely deep (2–3 Ms) XMM survey. (© 2008 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Cometary charge exchange diagnostics in UV and X‐ray

Since the initial discovery of cometary charge exchange emission, more than 20 comets have been observed with a variety of X‐ray and UV observatories. This observational sample offers a broad variety of comets, solar wind environments and observational conditions. It clearly demonstrates that solar wind charge exchange emission provides a wealth of diagnostics, which are visible as spatial, temporal, and spectral emission features. We review the possibilities and limitations of each of those in this contribution (© 2012 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

On the soft X‐ray emission of M82

We present a spatial analysis of the soft X‐ray and Hα emissions from the outflow of the starburst galaxy M82. We find that the two emissions are tightly correlated on various scales. The O VII triplet of M82, as resolved by X‐ray grating observations of XMM‐Newton, is dominated by the forbidden line, inconsistent with the thermal prediction. The O VII triplet also shows some spatial variations. We discuss three possible explanations for the observed O VII triplet, including the charge exchange at interfaces between the hot outflow and neutral cool gas, a collisional non‐equilibrium‐ionization recombining plasma, and resonance scattering (© 2012 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)