The Anarak, Jandaq and Posht-e-Badam metamorphic complexes in central Iran: New geological data, relationships and tectonic implications

The Anarak, Jandaq and Posht-e-Badam metamorphic complexes occupy the NW part of the Central-East Iranian Microcontinent and are juxtaposed with the Great Kavir block and Sanandaj-Sirjan zone. Our recent findings redefine the origin of these complexes, so far attributed to the Precambrian–Early Paleozoic orogenic episodes, and now directly related to the tectonic evolution of the Paleo-Tethys Ocean. This tectonic evolution was initiated by Late Ordovician–Early Devonian rifting events and terminated in the Triassic by the Eocimmerian collision event due to the docking of the Cimmerian blocks with the Asiatic Turan block.

The “Variscan accretionary complex” is a new name we proposed for the most widely distributed metamorphic rocks connected to the Anarak and Jandaq complexes. This accretionary complex exposed from SW of Jandaq to the Anarak and Kabudan areas is a thick and fine grain siliciclastic sequence accompanied by marginal-sea ophiolitic remnants, including gabbro-basalts with a supra-subduction-geochemical signature. New ⁴⁰Ar/³⁹Ar ages are obtained as 333–320 Ma for the metamorphism of this sequence under greenschist to amphibolite facies. Moreover, the limy intercalations in the volcano-sedimentary part of this complex in Godar-e-Siah yielded Upper Devonian–Tournaisian conodonts. The northeastern part of this complex in the Jandaq area was intruded by 215 ± 15 Ma arc to collisional granite and pegmatites dated by ID-TIMS and its metamorphic rocks are characterized by some ⁴⁰Ar/³⁹Ar radiometric ages of 163–156 Ma.

The “Variscan” accretionary complex was northwardly accreted to the Airekan granitic terrane dated at 549 ± 15 Ma. Later, from the Late Carboniferous to Triassic, huge amounts of oceanic material were accreted to its southern side and penetrated by several seamounts such as the Anarak and Kabudan. This new period of accretion is supported by the 280–230 Ma ⁴⁰Ar/³⁹Ar ages for the Anarak mild high-pressure metamorphic rocks and a 262 Ma U–Pb age for the trondhjemite–rhyolite association of that area. The Triassic Bayazeh flysch filled the foreland basin during the final closure of the Paleo-Tethys Ocean and was partly deposited and/or thrusted onto the Cimmerian Yazd block.

The Paleo-Tethys magmatic arc products have been well-preserved in the Late Devonian–Carboniferous Godar-e-Siah intra-arc deposits and the Triassic Nakhlak fore-arc succession. On the passive margin of the Cimmerian block, in the Yazd region, the nearly continuous Upper Paleozoic platform-type deposition was totally interrupted during the Middle to Late Triassic. Local erosion, down to Lower Paleozoic levels, may be related to flexural bulge erosion. The platform was finally unconformably covered by Liassic continental molassic deposits of the Shemshak.

One of the extensional periods related to Neo-Tethyan back-arc rifting in Late Cretaceous time finally separated parts of the Eocimmerian collisional domain from the Eurasian Turan domain. The opening and closing of this new ocean, characterized by the Nain and Sabzevar ophiolitic mélanges, finally transported the Anarak–Jandaq composite terrane to Central Iran, accompanied by large scale rotation of the Central-East Iranian Microcontinent (CEIM). Due to many similarities between the Posht-e-Badam metamorphic complex and the Anarak–Jandaq composite terrane, the former could be part of the latter, if it was transported further south during Tertiary time.     

Post-collisional granitoids from the Dabie orogen in China: Zircon U–Pb age, element and O isotope evidence for recycling of subducted continental crust

While recycling of subducted oceanic crust is widely proposed to be associated with oceanic island, island arc, and subduction-related adakite magmatism, it is less clear whether recycling of subducted continental crust takes place in continental collision belts. A combined study of zircon U–Pb dating, major and minor element geochemistry, and O isotopes in Early Cretaceous post-collisional granitoids from the Dabie orogen in China demonstrates that they may have been generated by partial melting of subducted continental crust. The post-collisional granitoids from the Dabie orogen comprise hornblende-bearing intermediate rocks and hornblende-free granitic rocks. These granitoids are characterized by fractionated REE patterns with low HREE contents and negative HFSE anomalies (Nb, Ta and Ti). Although zircon U–Pb dating gives consistent ages of 120 to 130 Ma for magma crystallization, occurrence of inherited cores is identified by CL imaging and SHRIMP U–Pb dating; some zircon grains yield ages of 739 to 749 Ma and 214 to 249 Ma, in agreement with Neoproterozoic protolith ages of UHP metaigneous rocks and a Triassic tectono-metamorphic event in the Dabie–Sulu orogenic belt, respectively. The granitoids have relatively homogeneous zircon δ¹⁸O values from 4.14‰ to 6.11‰ with an average of 5.10‰ ± 0.42‰ (n = 28) similar to normal mantle zircon. Systematically low zircon δ¹⁸O values for most of the coeval mafic–ultramafic rocks and intruded country rocks preclude an AFC process of mafic magma or mixing between mafic and felsic magma as potential mechanisms for the petrogenesis of the granitoids. Along with zircon U–Pb ages and element results, it is inferred that the granitic rocks were probably derived from partial melting of intermediate lower crust and the intermediate rocks were generated by amphibole-dehydration melting of mafic rocks in the thickened lower crust, coupled with fractional crystallization during magma emplacement. The post-collisional granitoids in the Dabie orogen are interpreted to originate from recycling of the subducted Yangtze continental crust that was thickened by the Triassic continent–continent collision. Partial melting of orogenic lithospheric keel is suggested to have generated the bimodal igneous rocks with the similar crustal heritage. Crustal thinning by post-collisional detachment postdated the onset of bimodal magmatism that was initiated by a thermal pulse related to mantle superwelling in Early Cretaceous.     

U-Pb ages and tectonomagmatic relationships of early Ordovician low-Ti tholeiites, boninites and related plutonic rocks in central Newfoundland, Canada

The Wild Bight Group (WBG) and South Lake Igneous Complex (SLIC) together comprise one of the Ordovician accreted oceanic terranes of the central mobile belt of the Newfoundland Appalachians. Combined detailed mapping, geochemistry, Sm-Nd isotopic studies and U-Pb geochronology have shown that sheeted dykes and hornblende diorite and tonalite plutons of the SLIC are genetically related to a discrete package of volcanic rocks in the WBG. These igneous rocks are geochemically, isotopically and temporally distinct from volcanic rocks in the rest of the WBG. Plutonic rocks of the SLIC range in age from 486 ± 3 Ma to 489 ± 3 Ma, and a cross-cutting gabbro dyke gives a minimum age of 486 ± 4 Ma for the related volcanic sequence. Volcanic rocks in the rest of the WBG sequence are predominantly younger than 472 ± 3 Ma. The older volcanic sequence of the WBG and the SLIC occur as fault-bounded packages interleaved within the younger WBG sequence. A conformable stratigraphic relationship between the older and younger sequences of the WBG has not been demonstrated. The mafic rocks of the older package include boninites and low-Ti, high-Mg tholeiitic island arc basalts which are interpreted to be genetically related, and normal island arc tholeiites (IAT). The high-Mg mafic rocks are interpreted to have formed in an extensional setting during subduction zone initiation, and the normal IAT are thought to represent stabilisation of the volcanic front. The associated high-Si, low-K rhyolite and tonalite are interpreted to be the products of secondary melting at the base of thickened early arc crust. Sm-Nd isotopic compositions indicate that the characteristic trace element signature of the boninites developed at or near their time of generation and was not a long lived characteristic of the source region. The boninites and low-Ti tholeiites are interpreted to have originated from a similar source, which was metasomatized by different subduction-related components. Apparent decoupling of Sm-Nd geochemical and isotopic compositions suggests that these very depleted rocks may be recording the effect of subduction zone processes not yet fully understood. Received: 31 October 1997 / Accepted: 6 May 1998     

Petrology, geochemistry and geodynamic implications of Jurassic island arc magmatism as revealed by mafic volcanic rocks in the Mesozoic low-grade sequence, eastern Rhodope, Bulgaria

In the eastern Bulgarian Rhodope, mafic extrusive rocks and underlying greenschists are found in the Mesozoic low-grade unit, which represents the northern extension of similar sequences including the Evros ophiolites in Thrace (Greece). Both rock types define a suite of low-Ti tholeiitic basalts to transitional boninitic basaltic andesites and andesites and associated metapyroclastites (greenschists), intruded at its base by diorite dikes of a boninitic affinity. Mafic lavas and greenschists display large ion lithophile element (LILE) enrichment relative to high-field strength elements (HFSE), flat REE patterns of a slight light REE depletion, a strong island arc tholeiite (IAT) and weak MORB-like signature. All these rocks are characterized by negative Nb anomalies ascribed to arc lavas. They have positive Nd_i values in the range of + 4.87 to + 6.09, approaching the lower limit of MORB-like source, and relatively high (²⁰⁷Pb/²⁰⁴Pb)_i (15.57–15.663) at low (²⁰⁶Pb/²⁰⁴Pb)_i (18.13–18.54) ratios. The Nd isotopic compositions coupled with trace element data imply a dominantly depleted MORB-like mantle source and a contribution of subduction modified LILE-enriched component derived from the mantle wedge. The diorite dike has a low Nd_i value of − 2.61 and is slightly more Pb radiogenic (²⁰⁷Pb/²⁰⁴Pb)_i (15.64) and (²⁰⁶Pb/²⁰⁴Pb)_i (18.56), respectively, reflecting crustal contamination. Petrologic and geochemical data indicate that the greenschists and mafic extrusive rocks represent a magmatic assemblage formed in an island arc setting. The magmatic suite is interpreted as representing an island arc–accretionary complex related to the southward subduction of the Meliata–Maliac ocean under the supra-subduction back-arc Vardar ocean/island arc system. Magmatic activity appears to have initiated in the north during the inception of the island arc system by the Early–Middle Jurassic time in the eastern Rhodope that most likely graded to back-arc spreading southwards as represented by the Late Jurassic MORB-type Samothraki Island ophiolites. This tectonic scenario is further constrained by paleotectonic reconstructions. The arc–trench system collided with the Rhodope in the Late Jurassic times.     

Age Constraints on the Tectonic Evolution and Provenance of the Pie de Palo Complex, Cuyania Composite Terrane, and the Famatinian Orogeny in the Sierra de Pie de Palo, San Juan, Argentina

New U-Pb age determinations confirm earlier interpretations that the strongly deformed and metamorphosed mafic and intermediate igneous rocks of the Pie de Palo Complex represent a Mesoproterozoic fragment of suprasubduction zone oceanic crust.

A gabbroic pegmatite, interpreted to have formed during arc rifting or subsequent back-arc spreading, yielded a U-Pb age of 1204 ^+5.3/_–4.7 Ma. Highly tectonized ultramafic-mafic cumulates, occurring at the structural base of the Pie de Palo Complex and previously interpreted to represent remnants of a primitive arc phase, prior to rifting and back-arc spreading, could not be dated, but should be older than 1204 Ma if these inferences are correct. Tabular, sill-like bodies of leucogabbro/diorite and calc-alkaline tonalite/granodiorite sills yielded ages of 1174±43 and 1169 ⁺⁸/_–7 Ma respectively. They may represent a younger, more evolved arc phase established after arc rifting or a younger, tectonically unrelated Mesoproterozoic arc. SHRIMP-analysis of metamorphic zircon rims with low Th/U ratios in VVL 110 gave a ²⁰⁶Pb/²³⁸U age of 455±10 Ma, similar to lower intercept dates determined by discordia lines. Combined, these data indicate that the bulk of the amphibolite facies metamorphism present in the Pie de Palo Complex was generated during the Famatinian Orogeny.

Analysis of six single detrital zircon grains in a metasedimentary, quartzofeldspathic garnet-mica schist, tectonically interleaved with the igneous rocks of the Pie de Palo Complex, and tentatively correlated with the Difunta Correa metasedimentary sequence of other workers, yielded three age populations: 1150–1160 Ma; 1050–1080 Ma and 665 Ma, indicating that these sedimentary rocks were deposited during the late Neoproterozoic or Early Paleozoic. In addition, they confirm structural evidence that intercalation of rocks of the Pie de Palo Complex with isolated slivers of these sedimentary rocks is due to tectonic imbrications. These ages are also consistent with a Laurentian provenance, and earlier interpretations that these rocks once represented a sedimentary cover to the Pie de Palo Complex. The zircon population of 1050–1080 Ma could be derived from Grenville-age felsic plutons identified elsewhere in the Pie de Palo Complex by other workers. However, no evidence has been found in our samples for a Grenville-age orogenic event, invoked previously to explain accretion of the oceanic Pie de Palo Complex to Laurentia prior to the late Neoproterozoic/Early Cambrian rifting and drift of Cuyania.     

Geochemical and isotopic constraints on the age and origin of the Nidar Ophiolitic Complex, Ladakh, India: Implications for the Neo-Tethyan subduction along the Indus suture zone

The Nidar ophiolite complex is exposed within the Indus suture zone in eastern Ladakh, India. The suture zone is considered to represent remnant Neo-Tethyan Ocean that closed via subduction as the Indian plate moved northward with respect to the Asian plate. The two plates ultimately collided during the Middle Eocene. The Nidar ophiolite complex comprises a sequence of ultra-mafic rocks at the base, gabbroic rocks in the middle and volcano-sedimentary assemblage on the top. Earlier studies considered the Nidar ophiolite complex to represent an oceanic floor sequence based on lithological assemblage. However, present study, based on new mineral and whole rock geochemical and isotopic data (on bulk rocks and mineral separates) indicate their generation and emplacement in an intra-oceanic subduction environment. The plutonic and volcanic rocks have nearly flat to slightly depleted rare earth element (REE) patterns. The gabbroic rocks, in particular, show strong positive Sr and Eu anomalies in their REE and spidergram patterns, probably indicating plagioclase accumulation. Depletion in high field strength elements (HFSE) in the spidergram patterns may be related to stabilization of phases retaining the HFSE in the subducting slab and / or fractional crystallization of titano-magnetite phases. The high radiogenic Nd- and low radiogenic Sr-isotopic ratios for these rocks exclude any influence of continental material in their genesis, implying an intra-oceanic environment.

Nine point mineral–whole rock Sm–Nd isochron corresponds to an age of 140 ± 32 Ma with an initial ¹⁴³Nd/¹⁴⁴Nd of 0.513835 ± 0.000053 (E_Nd t = + 7.4). This age is consistent with the precise Early Cretaceous age of Hauterivian (132 ± 2 to 127 ± 1.6 Ma) to Aptian (121 ± 1.4 to 112 ±1.1 Ma) for the overlying volcano-sedimentary (radiolarian bearing chert) sequences based on well-preserved radiolarian fossils (Kojima, S., Ahmad, T., Tanaka, T., Bagati, T.N., Mishra, M., Kumar, R. Islam, R., Khanna, P.P., 2001. Early Cretaceous radiolarians from the Indus suture zone, Ladakh, northern India. In: News of Osaka Micropaleontologists (NOM), Spec. Vol., 12, 257–270.) and cooling ages of 110–130 Ma based on ³⁹Ar/⁴⁰Ar for Nidar–Spontang ophiolitic rocks (Mahéo, G., Berttrand, H., Guillot, S., Villa, I. M., Keller, F., Capiez, P., 2004. The South Ladakh Ophiolites (NW Himalaya, India): an intra-oceanic tholeiitic arc origin with implications for the closure of the Neo-Tethys. Chem. Geol., 203, 273–303.). As these gabbroic and volcanic rocks are interpreted to be arc related, the new Sm–Nd age data may indicate that intra-ocean subduction in the Neo-Tethyan ocean may have started much before  140 ± 32 Ma as this date is interpreted as the age of crystallization of the arc magma. Present and published age data on the arc magmatic rocks from the Indus suture zone may collectively indicate episodic magmatism with increasing maturity of the arc from more basic (during ~ 140 ± 32 Ma) when the arc was immature through intermediate (andesitic/granodioritic) at ~ 100 Ma to more felsic (rhyolitic/dioritic) magmatism at ~ 50–45 Ma, when the Indian and the Asian plates collided.     

Excess Ar-free phengite in ultrahigh-pressure metamorphic rocks from the Lago di Cignana area, Western Alps

Ar/Ar analyses of phengites and paragonites from the ultrahigh-pressure metamorphic rocks (zoisite–clinozoisite schist, garnet–phengite schist and piemontite schist) in the Lago di Cignana area, Western Alps were carried out with a laser probe step-heating method using single crystals and a spot dating method on thin sections. Eight phengite and two paragonite crystals give the plateau ages of 37–42 Ma with 96–100% of ³⁹Ar released. Each rock type also contains mica crystals showing discordant age spectra with age fractions (20–35 Ma) significantly younger than the plateau ages. Phengite inclusions in garnet give ages of 43.2 ± 1.1 Ma and 44.4 ± 1.5 Ma, which are significantly older than the spot age (36.4 ± 1.4 Ma) from the matrix phengites, and the plateau ages from the step-heating analyses. Inclusion ages (43 and 44 Ma) are consistent with a zircon SHRIMP age (44 ± 1 Ma) in this area. These results suggest that the oceanic materials that underwent a simple subduction related UHPM, form excess ⁴⁰Ar-free phengite and that the peak metamorphism is ca. 44 Ma or little older. We suggest that matrix phengites experienced a retrogression reaction changing their chemistry contemporaneously with deformation related to the exhumation of rocks releasing significant radiogenic ⁴⁰Ar from the crystals. This has lead to the apparent ages of the matrix phengites that are significantly younger than the inclusion age.     

Strain partitioning and preservation of Ar/Ar ages during Variscan exhumation of a subducted crust (Malpica–Tui complex, NW Spain)

The Malpica–Tui complex (NW Iberian Massif) consists of a Lower Continental Unit of variably deformed and recrystallized granitoids, metasediments and sparse metabasites, overridden by an upper unit with rocks of oceanic affinities. Metamorphic minerals dated by the ⁴⁰Ar/³⁹Ar method record a coherent temporal history of progressive deformation during Variscan metamorphism and exhumation. The earliest stages of deformation (D1) under high-pressure conditions are recorded in phengitic white micas from eclogite-facies rocks at 365–370 Ma. Following this eclogite-facies peak-metamorphism, the continental slab became attached to the overriding plate at deep-crustal levels at ca. 340–350 Ma (D2). Exhumation was accompanied by pervasive deformation (D3) within the continental slab at ca. 330 Ma and major deformation (D4) in the underlying para-autochthon at 315–325 Ma. Final tectonothermal evolution included late folding, localized shearing and granitic intrusions at 280–310 Ma.

Dating of high-pressure rocks by the ⁴⁰Ar/³⁹Ar method yields ages that are synchronous with published Rb–Sr and Sm–Nd ages obtained for both the Malpica–Tui complex and its correlative, the Champtoceaux complex in the French Armorican Massif. The results indicate that phengitic white mica retains its radiogenic argon despite been subjected to relatively high temperatures (500–600 °C) for a period of 20–30 My corresponding to the time-span from the static, eclogite-facies M1 peak-metamorphism through D1-M2 eclogite-facies deformation to amphibolite-facies D2-M3. Our study provides additional evidence that under certain geological conditions (i.e., strain partitioning, fluid deficiency) argon isotope mobility is limited at high temperatures, and that ⁴⁰Ar/³⁹Ar geochronology can be a reliable method for dating high pressure metamorphism.     

Age and emplacement of late-Variscan granites of the western Bohemian Massif with main focus on the Hauzenberg granitoids (European Variscides, Germany)

The Variscan Hauzenberg pluton consists of granite and granodiorite that intruded late- to postkinematically into HT-metamorphic rocks of the Moldanubian unit at the southwestern margin of the Bohemian Massif (Passauer Wald). U–Pb dating of zircon single-grains and monazite fractions, separated from medium- to coarse-grained biotite-muscovite granite (Hauzenberg granite II), yielded concordant ages of 320 ± 3 and 329 ± 7 Ma, interpreted as emplacement age. Zircons extracted from the younger Hauzenberg granodiorite yielded a ²⁰⁷Pb–²⁰⁶Pb mean age of 318.6 ± 4.1 Ma. The Hauzenberg granite I has not been dated. The pressure during solidification of the Hauzenberg granite II was estimated at 4.6 ± 0.6 kbar using phengite barometry on magmatic muscovite, corresponding to an emplacement depth of 16-18 km. The new data are compatible with pre-existing cooling ages of biotite and muscovite which indicate the Hauzenberg pluton to have cooled below T = 250–400 °C in Upper Carboniferous times. A compilation of age data from magmatic and metamorphic rocks of the western margin of the Bohemian Massif suggests a west- to northwestward shift of magmatism and HT/LP metamorphism with time. Both processes started at > 325 Ma within the South Bohemian Pluton and magmatism ceased at ca. 310 Ma in the Bavarian Oberpfalz. The slight different timing of HT metamorphism in northern Austria and the Bavarian Forest is interpreted as being the result of partial delamination of mantle lithosphere or removal of the thermal boundary layer.     

New data (U–Pb, K–Ar) on the geochronology of the alkaline-carbonatitic association of Fuerteventura, Canary Islands, Spain

Zircons from a nepheline-syenite of the Fuerteventura Basal Complex were dated by Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS). The age obtained from a total of 21 U–Th–Pb analyses is 25.4 ± 0.3 Ma (2σ) indicating a late Oligocene–early Miocene crystallization. This age is consistent with new K–Ar ages on nepheline-syenites and pyroxenites, and contradicts previously published ³⁹Ar–⁴⁰Ar (feldspar) ages that were interpreted to represent a late Cretaceous–early Paleocene, pyroxenitic–syenitic magmatic episode. These new geochronological data are consistent with both field observations and most of the previously published ages on alkaline silicate rocks and associated carbonatites of Fuerteventura. Therefore, they strongly support the existence of a single, late Oligocene–early Miocene event of alkaline–carbonatitic magmatism in the Basal Complex of Fuerteventura, taking place at approximately 25 Ma and comprising: alkaline-pyroxenites, melteigites-ijolites, nepheline-syenites and carbonatites, as well as their volcanic equivalents and associated dykes.

These new data provide an estimate for the length of time that it took the island to grow, thus eliminating one of the major problems in explaining its development by a hot-spot model.     

Mixing of asthenospheric and lithospheric mantle-derived basalt magmas as shown by along-arc variation in Sr and Nd isotopic compositions of Early Miocene basalts from back-arc margin of the NE Japan arc

We report trace element and Sr–Nd isotopic compositions of Early Miocene (22–18 Ma) basaltic rocks distributed along the back-arc margin of the NE Japan arc over 500 km. These rocks are divided into higher TiO₂ (> 1.5 wt.%; referred to as HT) and lower TiO₂ (< 1.5 wt.%; LT) basalts. HT basalt has higher Na₂O + K₂O, HFSE and LREE, Zr/Y, and La/Yb compared to LT basalt. Both suite rocks show a wide range in Sr and Nd isotopic compositions (initial ⁸⁷Sr/⁸⁶Sr (SrI) = 0.70389 to 0.70631, initial ¹⁴³Nd/¹⁴⁴Nd(NdI) = 0.51248 to 0.51285). There is no any systematic variation amongst the studied Early Miocene basaltic rocks in terms of Sr–Nd isotope or Na₂O + K₂O and K₂O abundances, across three volcanic zones from the eastern through transitional to western volcanic zone, but we can identify gradual increases in SrI and decreases in NdI from north to south along the back-arc margin of the NE Japan arc. Based on high field strength element, REE, and Sr–Nd isotope data, Early Miocene basaltic rocks of the NE Japan back-arc margin represent mixing of the asthenospheric mantle-derived basalt magma with two types of basaltic magmas, HT and LT basaltic magmas, derived by different degrees of partial melting of the subcontinental lithospheric mantle composed of garnet-absent lherzolite, with a gradual decrease in the proportion of asthenospheric mantle-derived magma from north to south. These mantle events might have occurred in association with rifting of the Eurasian continental arc during the pre-opening stage of the Japan Sea.     

U–Pb and Sm–Nd geochronology of amphibolites from the Curaçá Belt, São Francisco Craton, Brazil: Tectonic implications

The Curaçá terrane is part of the Itabuna–Salvador–Curaçá (I–S–C) Paleoproterozoic orogen in the São Francisco craton, northeastern Brazil, and comprises supracrustal rocks, gneisses of their probable basement, amphibolites, and mafic-ultramafic Cu-bearing bodies (including the Caraíba Cu-Mine), all affected by D₁-D₃ deformation events associated to M₁-M₃ metamorphism under high-T granulite and amphibolite facies, and assisted by G₁-G₃ tonalitic-granodioritic-granitic intrusions. U–Pb and Sm–Nd Thermal Ionization Mass Spectrometry (TIMS) isotopic data from amphibolite, tonalite, and granite, sampled in a well-known outcrop, indicate partial reset and heterogeneous modification of the original isotopic systems, attributable to deformation and metamorphism. The ages obtained from these systems agree with each other, and also with other previously published U–Pb data, and imply that 2.6 Ga is the crystallization age of the protolith of the amphibolite. Together with key structural relationships, they also indicate a 2.08–2.05 Ga interval for M₃ metamorphism, and make even a less precise age (2.2–2.3 Ga) acceptable, as it suggests contamination in the amphibolite with material in a syn-D₂ tonalite crystallized 2248 ± 36 Ma ago. The new data demonstrate the existence of Neoarchean fragments of both oceanic and continental crusts and constrain the Archean-Paleoproterozoic development of the Curaçá belt, the I–S–C orogen, and the São Francisco craton.     

Zircon U–Pb geochronology of gneissic rocks in the Yunkai massif and its implications on the Caledonian event in the South China Block

This paper presents new zircon U–Pb data and interpretations for the gneissic rocks in the Yunkai massif in order to constrain the timing and evolution of the Caledonian tectonothermal event in the South China Block (SCB). Magmatic and inherited zircons from the orthogneiss in the region, previously thought to be of Precambrian origin, yielded ²⁰⁶Pb/²³⁸U apparent ages of 421–441 Ma and 513–1343 Ma, respectively. Also a weighted mean ²⁰⁶Pb/²³⁸U age of 236.0 ± 3.1 Ma was obtained, interpreted as the metamorphic resetting age during the Indosinian tectonic event. Our analyses show that the paragneiss in the region, previously regarded as Proterozoic sedimentary rocks, contains detrital zircons of the Archaean to Paleozoic origin, of which the youngest zircons yielded the U–Pb age of  423 Ma. These data indicate that (1) the Proterozoic and Archaean components may exist beneath the Yunkai massif; (2) most of the metaigneous rocks are actually the Caledonian anatectic granites possibly overprinted by Indosinian ( 236 Ma) reactivation; (3) some paragneiss might have originally deposited during the Devonian time; and (4) a subsequently rapid uplifting took place after the emplacement of the Caledonian granites, revealed by the observation that the Devonian clastic strata uncomfortably overlie the Caledonian granites. In combination with other geochronological data and geological observations throughout the SCB, we propose that the Caledonian tectonothermal event around Silurian ( 450–400 Ma) might be a result from an intracontinental collision between the Yangtze and Cathaysian blocks in response to the subduction/collision between the North China block and SCB.     

Cretaceous isochron ages from K–Ar and Ar / Ar dating of eclogitic rocks in the Tso Morari Complex, western Himalaya, India

The Tso Morari Complex, which is thought to be originally the margin of the Indian continent, is composed of pelitic gneisses and schists including mafic rock lenses (eclogites and basic schists). Eclogites studied here have the mineral assemblage Grt + Omp + Ca-Amp + Zo + Phn + Pg + Qtz + Rt. They also have coesite pseudomorph in garnet and quartz rods in omphacite, suggesting a record of ultrahigh-pressure metamorphism. They occur only in the cores of meter-scale mafic rock lenses intercalated with the pelitic schists. Small mafic lenses and the rim parts of large lenses have been strongly deformed to form the foliation parallel to that of the pelitic schists and show the mineral assemblages of upper greenschist to amphibolite facies metamorphism. The garnet–omphacite thermometry and the univariant reaction relations for jadeite formation give 13–21 kbar at 600 °C and 16–18 kbar at 750 °C for the eclogite formation using the jadeite content of clinopyroxene (X_Jd = 0.48).

Phengites in pelitic schists show variable Si / Al and Na / K ratios among grains as well as within single grains, and give K–Ar ages of 50–87 Ma. The pelitic schist with paragonite and phengite yielded K–Ar ages of 83.5 Ma (K = 4.9 wt.%) for paragonite–phengite mixture and 85.3 Ma (K = 7.8 wt.%) for phengite and an isochron age of 91 ± 13 Ma from the two dataset. The eclogite gives a plateau age of 132 Ma in Ar/Ar step-heating analyses using single phengite grain and an inverse isochron age of 130 ± 39 Ma with an initial ⁴⁰Ar / ³⁶Ar ratio of 434 ± 90 in Ar/Ar spot analyses of phengites and paragonites. The Cretaceous isochron ages are interpreted to represent the timing of early stage of exhumation of the eclogitic rocks assuming revised high closure temperature (500 °C) for phengite K–Ar system. The phengites in pelitic schists have experienced retrograde reaction which modified their chemistry during intense deformation associated with the exhumation of these rocks with the release of significant radiogenic ⁴⁰Ar from the crystals. The argon release took place in the schists that experienced the retrogression to upper greenschist facies metamorphisms from the eclogite facies conditions.     

Rise and fall of the Eastern Great Indonesian arc recorded by the assembly, dispersion and accretion of the Banda Terrane, Timor

New age, petrochemical and structural data indicate that the Banda Terrane is a remnant of a Jurassic to Eocene arc–trench system that formed the eastern part of the Great Indonesian arc. The arc system rifted apart during Eocene to Miocene supra-subduction zone sea floor spreading, which dispersed ridges of Banda Terrane embedded in young oceanic crust as far south as Sumba and Timor. In Timor the Banda Terrane is well exposed as high-level thrust sheets that were detached from the edge of the Banda Sea upper plate and uplifted by collision with the passive margin of NW Australia. The thrust sheets contain a distinctive assemblage of medium grade metamorphic rocks overlain by Cretaceous to Miocene forearc basin deposits. New U/Pb age data presented here indicate igneous zircons are less than 162 Ma with a cluster of ages at 83 Ma and 35 Ma. ⁴⁰Ar/³⁹Ar plateau ages of various mineral phases from metamorphic units all cluster at between 32–38 Ma. These data yield a cooling curve that shows exhumation from around 550 °C to the surface between 36–28 Ma. After this time there is no evidence of metamorphism of the Banda Terrane, including its accretion to the edge of the Australian continental margin during the Pliocene. These data link the Banda Terrane to similar rocks and events documented throughout the eastern edge of the Sunda Shelf and the Banda Sea floor.     

Very fast exhumation of high-pressure metamorphic rocks with excess Ar and inherited Sr, Betic Cordilleras, southern Spain

In order to attempt to further constrain the age of the early Alpine tectonic evolution of the Mulhacén Complex and to explore the influence of inherited isotopes, micas from a small number of well-characterised rocks from the Sierra de los Filábres, with a penetrative tectonic fabric related to the exhumation of eclogite-facies metamorphic rocks, were selected for ⁴⁰Ar/³⁹Ar and Rb–Sr dating.

A single phengite grain from an amphibolite yielded an ⁴⁰Ar/³⁹Ar laser step heating plateau age of 86.9±1.2 Ma (2σ; 70% ³⁹Ar released) and an inverse isochron age of 86.2±2.4 Ma with an ³⁶Ar/⁴⁰Ar intercept within error of the atmospheric value. Induction furnace step heating of a biotite separate from a gabbro relic in an eclogite yielded a weighted mean age of 173.2±6.3 Ma (2σ; 95% ³⁹Ar released). These ages are diagnostic of excess argon (⁴⁰Ar_XS) incorporation, as they are older than independent age estimates for the timing of eclogite-facies metamorphism and intrusion of the gabbros. ⁴⁰Ar_XS incorporation probably resulted from restricted fluid mobility in the magmatic rocks during their metamorphic recrystallisation.

Rb–Sr whole-rock–phengite ages of graphite-bearing mica schists from Paleozoic rocks (Secano unit) show a dramatic variation (66.1±3.2, 40.6±2.6 and 14.1±2.2 Ma). An albite chlorite mica schist from the Mesozoic series of the Nevado–Lubrín unit has a whole-rock–mica–albite age of 17.2±1.9 Ma, which is within error of an ⁴⁰Ar/³⁹Ar plateau age published previously and of the youngest Rb–Sr age of the Paleozoic series obtained in this study. The significant spread in Rb–Sr ages implies that progressive partial resetting of an older isotopic system has occurred. The microstructure of the samples with pre-Miocene Rb–Sr ages reveals incomplete recrystallisation of white mica and inhibited grain growth due to the presence of graphite particles. This interpretation agrees with previously published, disturbed and slightly dome-shaped ⁴⁰Ar/³⁹Ar age spectra that may point similarly to the presence of an older isotope component. The progressively reset Rb–Sr system is a relic of Variscan metamorphism of the Paleozoic series of the Mulhacén Complex. In contrast, the origin of the ca. 17.2 Ma old sample from the Mesozoic series precludes any isotopic inheritance, in agreement with its pervasive tectono-metamorphic recrystallisation during the Miocene.

Exhumation of the eclogite-facies Mulhacén Complex occurred in two stages with contrasting rates of about 22.5 mm/year during the early phase and 9–10 mm/year during the late phase; the latter with a cooling rate in the order of 330 °C/Ma.     

Geochronological, geochemical and geothermal constraints on petrogenesis of the Indosinian peraluminous granites in the South China Block: A case study in the Hunan Province

The Indosinian granites in the South China Block (SCB) have important tectonic significance for the evolution of East Asia. Samples collected from Hunan Province can be geochemically classified into two groups. Group 1 is strongly peraluminous (A/CNK > 1.1), similar to S-type granites, and Group 2 has A/CNK = 1.0–1.1, with an affinity to I-type granites. Group 1 has lower FeOt, Al₂O₃, MgO, CaO, TiO₂ and ε_Nd(t) values but higher K₂O + Na₂O, Rb/Sr, Rb/Ba and ⁸⁷Sr/⁸⁶Sr(t) than those of Group 2. Samples of both groups have similar LREE enriched pattern, with (Eu/Eu) = 0.19–0.69, and strongly negative Ba, Sr, Nb, P and Ti anomalies. Geothermobarometry study indicates that the precursor magmas were emplaced at high-level depth with relatively low temperature (734–827 °C). Geochemical data suggest that Group 1 was originated from a source dominated by pelitic composition and Group 2 was from a mixing source of pelitic and basaltic rocks with insignificant addition of newly mantle-derived magma. Eight granitic samples in Hunan Province are dated at the cluster of 243–235 and 218–210 Ma by zircon U–Pb geochronology. Together with recent zircon U–Pb ages for other areas in the SCB, two age-clusters, including 243–228 Ma just after peak-metamorphism ( 246–252 Ma) and 220–206 Ma shortly after magma underplating event (224 Ma), are observed. It is proposed that in-situ radiogenic heating from the over-thickened crust induced dehydrated reaction of muscovite and epidote/zoisite to form the early Indosinian granites in response to the isostatic readjustments of tectonically thickened crust. Conductive heating from the underplating magma in the postcollisional setting triggered the formation of late Indosinian granites. Such a consideration is supported by the results from FLAC numerical simulation.     

Evolution of the REE mineralogy in HP–LT metapelites of the Sebtide complex, Rif, Morocco: Monazite stability and geochronology

REE mineralogy was characterized at the micrometer scale (using scanning electron microscopy) in the four tectono-metamorphic units of the Beni Mzala window, Sebtide Complex, Internal Rif, Morocco, which sample a HP-LT metamorphic gradient from subgreenschist to blueschist/eclogite facies. These tectonic units are composed of garnet-free metapelites (and associated synmetamorphic veins) from the same homogeneous aluminium-rich and calcium-poor protolith. In that context, mineralogical differences between units are assumed to result from contrasted pressure and temperature histories. Light REE-bearing Al-phosphates of the crandallite group with florencite-rich composition and variable goyazite content are the dominant LREE minerals in the lowest-grade units, Tizgarine (300 °C, 3 kbar as peak conditions) and Boquete de Anjera (350 °C, 10 kbar). In the latter unit, metamorphic florencite is associated with MREE-rich monazite. In the schist of the highest-grade units, Beni Mzala 2 (420–450 °C, 12 kbar) and Beni Mzala 1 (550 °C, 16 kbar), associations of allanite-rich epidote and synchisite (a LREE-fluorocarbonate) are found whereas florencite and monazite are no longer observed. At the wall of the quartz–kyanite veins, retrograde monazite-(Ce) with grain size of 20 to 50 μm is the only LREE-bearing mineral. Th–Pb and U–Pb SIMS data on some of these grains yield ages of 21.3 ± 1.7 Ma and 20.9 ± 2.1 Ma, respectively, consistent with previous K–Ar ages obtained on retrograde clay–mica mixtures in rocks from the same locality. The identification of a stability field for monazite in high-pressure aluminous metapelites with an upper thermal-limit below 450 °C as well as the derivation of meaningful U–Pb and Th–Pb SIMS ages demonstrates the monazite potential for dating HP-LT metapelites. However, since, under these conditions, monazite growth occurs below its admitted closure-temperature, these ages must be interpreted on the basis of monazite textural relationships.     

Sveconorwegian crustal underplating in southwestern Fennoscandia: LAM-ICPMS U–Pb and Lu–Hf isotope evidence from granites and gneisses in Telemark, southern Norway

Laser ablation ICPMS U–Pb and Lu–Hf isotope data on granitic-granodioritic gneisses of the Precambrian Vråvatn complex in central Telemark, southern Norway, indicate that the magmatic protoliths crystallized at 1201 ± 9 Ma to 1219 ± 8 Ma, from magmas with juvenile or near-juvenile Hf isotopic composition (¹⁷⁶Hf/¹⁷⁷Hf = 0.2823 ± 11, epsilon-Hf > + 6). These data provide supporting evidence for the depleted mantle Hf-isotope evolution curve in a time period where juvenile igneous rocks are scarce on a global scale. They also identify a hitherto unknown event of mafic underplating in the region, and provide new and important limits on the crustal evolution of the SW part of the Fennoscandian Shield. This juvenile geochemical component in the deep crust may have contributed to the 1.0–0.92 Ga anorogenic magmatism in the region, which includes both A-type granite and a large anorthosite–mangerite–charnockite–granite intrusive complex. The gneisses of the Vråvatn complex were intruded by a granitic pluton with mafic enclaves and hybrid facies (the Vrådal granite) in that period. LAM-ICPMS U–Pb data from zircons from granitic and hybrid facies of the pluton indicates an intrusive age of 966 ± 4 Ma, and give a hint of ca. 1.46 Ga inheritance. The initial Hf isotopic composition of this granite (¹⁷⁶Hf/¹⁷⁷Hf = 0.28219 ± 13, epsilon-Hf = − 5 to + 6) overlaps with mixtures of pre-1.7 Ga crustal rocks and juvenile Sveconorwegian crust, lithospheric mantle and/or global depleted mantle. Contributions from ca. 1.2 Ga crustal underplate must be considered when modelling the petrogenesis of late Sveconorwegian anorogenic magmatism in the region.     

Retention of Precambrian Rb/Sr phlogopite ages through Caledonian eclogite facies metamorphism, Bergen Arc Complex, W-Norway

The Lindås Nappe, Caledonides W-Norway was affected by two major tectonometamorphic events. A Precambrian granulite facies event at T=800–900°C, P<10 kbar was followed by localized Caledonian eclogite facies (T=650–700°C and P>15 kbar) and localized amphibolite facies reworking. During the granulite–eclogite facies transition, anorthositic rocks were converted from garnet granulites to kyanite eclogites, while phlogopite-bearing spinel lherzolite reacted to garnet lherzolite. The eclogite and amphibolite facies reequilibration took place along shear zones and fluid pathways. In the unhydrated and undeformed parts, the minerals preserved their granulite facies composition with constant Fe/Mg ratios from core to rim, suggesting diffusional reequilibration. Rb/Sr age dating was carried out on relict granulite facies minerals from three lenses of ultramafites (Alvfjellet, Hundskjeften and Kvamsfjellet). Phlogopite from phlogopite lherzolite at Alvfjellet give 857±9 Ma, while clinopyroxene, amphibole, phlogopite and whole rock from a lherzolite at Hundskjeften yield an age of 842±12 Ma (MSWD=1.9). Clinopyroxene, feldspar, orthopyroxene phlogopite and whole rock from websterite, Kvamsfjellet, yield an age of 835±7 Ma (MSWD<1), while clinopyroxene, phlogopite and whole rock from a lherzolite from the same lens gives a result of 882±9 Ma. These results are interpreted as minimum ages for the granulite facies event and only slightly younger than, or overlap with previous U–Pb zircon ages (929±1 Ma) and Sm–Nd garnet–pyroxene ages (890–923 Ma) interpreted to date the end of the granulite facies event. By contrast, ages obtained for the eclogite and amphibolite facies range from 460 (U–Pb, sphene), 440 (Ar–Ar), 419 (U–Pb, zircon) to 410 Ma (Rb/Sr mineral ages).

These results demonstrate that the reopening temperature for the Rb/Sr system in phlogopite–biotite under dry and static high-pressure conditions is, in the given mineral assemblages, at least 650°C, considerably higher than the 300–400°C assumed as the closure temperature of this system. We ascribe this elevated reopening temperature to fluid absent conditions that prevented element transport and rehomogenization.