Nutrient-chlorophyll trajectories across trophic gradients

We estimate the response of chl-a (mg · m^–3) to changes in concentrations of total phosphorus (TP) by calculating the slopeS = chl-a/TP in chl-a =f(TP) graphs. Results show that in years where algae are P-limited oligotrophic lakes respond less (median slope 0.21) to changes in nutrient concentrations than eutrophic lakes, (median slope 0.31) and these again less than hypereutrophic lakes, (median slope 1.02). We find no saturation value for the slope within the TP range considered (6–480 mg · m^–3). Chl-a in eutrophic lakes responds more frequently to non-nutrient factors than oligotrophic and hypereutrophic lakes. Results obtained by replacing TP with a new nutrient parameter, TP = 0.056 · TP · IN^0.226, in which inorganic nitrogen, IN, is factored in, suggest that nitrogen has an influence on chl-a in oligotrophic lakes. Blue-green algae respond less to changes in TP than other algal species, e.g., diatoms.     

Background aspects of lake restoration: water balance,heavy metal content,phosphorus homeostasis

Perturbations of the lake water balance, inputs of heavy metals to lakes, and intensifying fertilization of lakes through input and accumulation of phosphorus—these three classes of phenomena are among the more important background processes in lake restoration. Lake restoration consists of a series of measures animed at producing a homeostatic response of a lake system to external perturbations. The success of its implementation is affected by the morphometric and edaphic parameters of different types of lakes. The relationship between the volume (V) and mean-depth of fresh-water lakes indicates a trend of . Glacial lakes occuring on or near crystalline shields have relatively shallow depths, whereas volcanic lakes, rift valley and deep valley lakes have relatively greater depths for the same volume. For saline lakes (21 lakes, V>1 km³) that undergo cycles of expansion and shrinkage, the V to relationship is closer to power 1. Water residence times (τ) of small and big fresh-water lakes show a trend of τ approximately linear in or τ∝V^0.3. Volcanic lakes and Maare have longer residence times in comparison to other lakes of similar volumes. For the major inorganic chemical species and heavy metals, the regulatory upper-limit concentrations in drinking water in the USA and EEC are from several times to more than 100 times higher than their concentrations in a global mean river water. Only three elements (Fe, P, and Al) occur in river water at concentrations approaching such upper-limit recommendations. Rates of accumulation of phosphorus in lake water and sediments, computed as the difference between input and ouflow removal rates for 23 fresh-water lakes, are generally lower for lakes of longer water residence time. The rate of accumulation is a measure of homeostatic response of the lake system to input load: it is equivalent to the rate of all the removal processes needed to maintain phosphorus concentration in lake water at a steady state.     

Sensitivity to acidification of subalpine ponds and lakes in north‐western Colorado

Although acidifying deposition in western North America is lower than in many parts of the world, many high‐elevation ecosystems there are extremely sensitive to acidification. Previous studies determined that the Mount Zirkel Wilderness Area (MZWA) has the most acidic snowpack and aquatic ecosystems that are among the most sensitive in the region. In this study, spatial and temporal variability of ponds and lakes in and near the MZWA were examined to determine their sensitivity to acidification and the effects of acidic deposition during and after snowmelt. Within the areas identified as sensitive to acidification based on bedrock types, there was substantial variability in acid‐neutralizing capacity (ANC), which was related to differences in hydrological flowpaths that control delivery of weathering products to surface waters. Geological and topographic maps were of limited use in predicting acid sensitivity because their spatial resolution was not fine enough to capture the variability of these attributes for lakes and ponds with small catchment areas. Many of the lakes are sensitive to acidification (summer and autumn ANC < 100 µeq L^?1), but none of them appeared to be threatened immediately by episodic or chronic acidification. In contrast, 22 ponds had minimum ANC < 30 µeq L^?1, indicating that they are extremely sensitive to acidic deposition and could be damaged by episodic acidification, although net acidity (ANC < 0) was not measured in any of the ponds during the study. The lowest measured pH value was 5·4, and pH generally remained less than 6·0 throughout early summer in the most sensitive ponds, indicating that biological effects of acidification are possible at levels of atmospheric deposition that occurred during the study. The aquatic chemistry of lakes was dominated by atmospheric deposition and biogeochemical processes in soils and shallow ground water, whereas the aquatic chemistry of ponds was also affected by organic acids and biogeochemical processes in the water column and at the sediment–water interface. These results indicate that conceptual and mechanistic acidification models that have been developed for lakes and streams may be inadequate for predicting acidification in less‐understood systems such as ponds. Copyright © 2004 John Wiley & Sons, Ltd.     

Factors affecting water chemistry of alpine lakes

During a four-year study (1988–1991), 413 lakes in the Central Alps (Italy, Switzerland and Austria) were investigated to quantify their acidification. The ionic content of the lakes was generally low: 68% of them had alkalinity values of less than 200 µeq 1^–1 and were regarded as sensitive to acidification. Moreover, 36% of the lakes showed alkalinity values of less than 50 µeq 1^–1. Redundancy Analysis was used to relate the hydrochemistry of 187 lakes to their catchment characteristics. Calcite weathering was the main factor influencing lake chemistry. The same analysis, applied to a subset of 101 lakes lying in watersheds exclusively composed of silicic rocks, showed that lake chemistry was influenced by silicate weathering and nitrogen uptake. These processes were found to be mainly related to lake altitude and the fraction of the watershed not covered by vegetation, i.e. controlled by temperature. The importance of these relations to explain the pH shift produced by climatic variation is also discussed.     

Geochemical characterization of the organic matter, pore water constituents and shallow methane gas in the eastern part of the Ulleung Basin, East Sea (Japan Sea)

Abstract Geochemical analyses of sediments, pore water and headspace gas of the piston cores taken from the eastern part of Ulleung Basin of the East Sea (Japan Sea) were carried out to assess the origin of the sedimentary organic matter and interstitial fluid. Several tephra layers within the core are identified as the Ulleung‐Oki (10.1 ka), the Aira‐Tanzawa (23 ka) and the Ulleung‐Yamato (30.9 ka) tephras. With the exception of these volcanic layers, the cores consist predominantly of muddy sediments that contain >0.5% total organic carbon. Atomic C/N ratios and δ¹³C_org values suggest that the organic matter originated from marine algae rather than from land vascular plants, whereas Rock‐Eval pyrolysis suggests that the organic matter is thermally immature and comes from a land vascular plant (Type III). These conflicting results seem to be caused by the heavy oxidization of the marine organic matter. Sulphate concentration profiles of pore waters show strongly linear depletion (r² > 0.97) with sediment depth. The estimated sulphate–methane interface (SMI) depth using the sulphate concentration gradient was nearly 3.5 m below seafloor (mbsf) in the southern part of the study area, and deeper than 6 mbsf in the northern part of the area. The difference in SMI depths is likely associated with the amount of the methane flux. The methane concentration below the SMI in the two southern cores increases rapidly, implying the occurrence of methanogenesis and anaerobic methane oxidation (AMO). In contrast, the two northern cores have a low methane concentration below the SMI. values measured from all cores were in the range of −83.5 to −69.5‰, which suggests that the methane derives from a methanogenic microbe. values become decreased toward SMI, but increased below SMI; therefore, has eventually the minimum value near the SMI. The values are also decreased when the methane concentration is increased. These phenomena support the typical occurrence of AMO in the study area.     

Regulating Environmental Factors of Nutrients Release from Wheat Straw Biochar for Sustainable Agriculture

One mechanism by which biochar application enhances soil nutrient availability is through direct nutrients release from biochar. However, factors controlling the release processes are poorly understood. In this study, the effects of pH, biochar to water ratio, temperature, ionic strength, and equilibration time on the release of PO, NO, NH, K⁺, Na⁺, Ca²⁺, and Mg²⁺ from biochar were evaluated in simulated experiments. The release of PO, K⁺, Ca²⁺, and Mg²⁺ was significantly affected by extraction pH, suggesting that their release from biochar was pH dependent or an H⁺‐consuming process. Correlation analysis indicated that PO and Ca²⁺, PO and Mg²⁺, and Ca²⁺ and Mg²⁺ were co‐solubilized with increasing soil acidity. To a lesser extent, the recovery of the nutrients was also affected by the ratio of biochar to water: more nutrients were soluble with more water supply. In contrast, the release of Na was not affected by pH while the concentration increased with decreasing biochar to water ratio. Meanwhile, other factors (temperature, ionic strength, and equilibration time) had less effect on nutrient release from biochar. Under the influence of pH, the patterns of NO and PO release from biochar were different: extractable NO concentration was not affected by the pH but more PO was released in strongly acidic conditions. Our data suggested that P was mainly retained in inorganic forms while N was in organic forms in biochar. We conclude that environmental factors have marked influences on nutrients release from biochar.     

Environmental impacts on the distribution of microbial tetraether lipids in Chinese lakes with contrasting pH: Implications for lacustrine paleoenvironmental reconstructions

Glycerol dialkyl glycerol tetraethers(GDGTs) in lake sediments are useful biomarkers for the continental paleoclimatic reconstruction. However, the environmental controls on the distribution of these compounds, in particular the 6-methyl isomers of bacterial branched GDGTs(bGDGTs), in the lakes with contrasting pH, are still unknown, hindering their application for paleo-reconstructions. Here, we investigated the environmental impacts on the distribution of GDGTs in 17 alkaline lakes and 1 acid lake in China. It was found that the dissolved oxygen content in water column may have an impact on the distribution of archaeal isoprenoid GDGTs(iGDGTs) by causing the change in archaeal communities. The ratio of GDGT-0/crenarchaeol increases with decreasing oxygen content, indicating that the relative abundance of anaerobic methanogenic archaea or Miscellaneous Crenarchaeotic Group(MCG) vs. aerobic Thaumarchaeota is controlled by the oxygen content dissolved in water of these lakes. Thaumarchaeota are likely to contribute only a small proportion of iGDGTs in the relatively oxygen-depleted lakes, and thus TEX_(86) is not suitable for the reconstruction of the surface temperature of these lakes. The abundance ratio of iGDGTs to bGDGTs(R_(i/b)) appears to show no relationship with water pH in all the lakes, but exhibits a significant positive correlation with the water depth of the acid Lake Qinghai in Tengchong. As expected, the methylation degree of bGDGTs(MBT′) was found to correlate with both mean annual air temperature(MAT) and water pH, and the cyclization degree of bGDGTs(CBT) correlates only with water pH in these lakes. However, the MBT′_(5ME), an index to measure the methylation degree of 5-methyl bGDGTs, exhibits no relationship with MAT, whereas MBT′_(6ME), the methylation degree of 6-methyl bGDGTs, was found to correlate significantly with MAT. This is opposite to the situation observed in the global soils, pointing to a different adaptation of b GDGT-producing bacteria to environmental variables or different microbial sources of bGDGTs in these lakes. The relative abundance of 6- vs. 5-methyl bGDGTs is controlled by pH in these lakes, similar to that observed in worldwide soils. Hence, the isomer ratio(IR) of 6-methyl bGDGTs or CBT′ can be used as a proxy for water pH, although they might be influenced by other environmental factors including temperature in the lakes with a narrow range of pH.     

Possibilities and limitations of lake restoration: Conclusions for Lake Lugano

In most lakes eutrophication is linked to an excessive input of phosphorus. Lake restoration by reduction of P-input (external measure) has led to a considerable drop of the P-concentration in all major Swiss lakes as well as in many other lakes. Internal restoration measures such as artificial mixing, drainage of hypolimnetic water, flushing, aeration, biomanipulation and others serve to improve and accelerate the response of a lake to external measures. For the case of Lago di Lugano, a simple two-box model is employed to demonstrate that a reduction of the P-input to about 25% of the present values is necessary to reach the P-criterion (P-concentration below 30 µg/l). Internal measures could possibly accelerate the extremely slow response of the northern basin.     

Spatial Variation of the Precipitation Chemistry in the Thrace Region of Turkey

Pollutants affect not only the environment in which they originate since they are also transported by air currents to other locations. For this reason, air pollution is a global problem for all countries and the air and water quality need to be monitored carefully. More information on precipitation chemistry is required to determine the source of pollution as well as its effects on the ecosystems. In this study, precipitation chemistry has been analyzed for the first time by using simple bulk collectors located at four different sites in Northwest Turkey for a period of two years. About 650 sequential rainwater samples were collected and analyzed for pH, electrical conductivity, anions such as , , Cl^?, and cations such as Na⁺, K⁺, Mg²⁺, Ca²⁺, and . The selected sites were under the effect of different environmental factors. Our results showed that the highest and concentrations were measured in the Northwest of the research area. Additionally, it has been found that Ca²⁺ ions are abundant within all rainwater samples.     

Lengths and hazards from channel-fed lava flows on Mauna Loa, Hawai‘i, determined from thermal and downslope modeling with FLOWGO

Using the FLOWGO thermo-rheological model we have determined cooling-limited lengths of channel-fed (i.e. a) lava flows from Mauna Loa. We set up the program to run autonomously, starting lava flows from every 4th line and sample in a 30-m spatial-resolution SRTM DEM within regions corresponding to the NE and SW rift zones and the N flank of the volcano. We consider that each model run represents an effective effusion rate, which for an actual flow coincides with it reaching 90% of its total length. We ran the model at effective effusion rates ranging from 1 to 1,000 m³ s^–1, and determined the cooling-limited channel length for each. Keeping in mind that most flows extend 1–2 km beyond the end of their well-developed channels and that our results are non-probabilistic in that they give all potential vent sites an equal likelihood to erupt, lava coverage results include the following: SW rift zone flows threaten almost all of Mauna Loas SW flanks, even at effective effusion rates as low as 50 m³ s^–1 (the average effective effusion rate for SW rift zone eruptions since 1843 is close to 400 m³ s^–1). N flank eruptions, although rare in the recent geologic record, have the potential to threaten much of the coastline S of Keauhou with effective effusion rates of 50–100 m³ s^–1, and the coast near Anaehoomalu if effective effusion rates are 400–500 m³ s^–1 (the 1859 a flow reached this coast with an effective effusion rate of 400 m³ s^–1). If the NE rift zone continues to be active only at elevations >2,500 m, in order for a channel-fed flow to reach Hilo the effective effusion rate needs to be 400 m³ s^–1 (the 1984 flow by comparison, had an effective effusion rate of 200 m³ s^–1). Hilo could be threatened by NE rift zone channel-fed flows with lower effective effusion rates but only if they issue from vents at 2,000 m or lower. Populated areas on Mauna Loas SE flanks (e.g. Phala), could be threatened by SW rift zone eruptions with effective effusion rates of 100 m³ s^–1.Editorial responsibility: J Donnelly-Nolan     

Anisotropy of Cs137 gamma-ray absorption in rocks

Summary The anisotropy of the Cs¹³⁷ gamma-ray absorption coefficient has been investigated in layered models and several rock samples. It was found that in contrast to other petrophysical parameters the gamma-ray absorption coefficient is characterized by a relatively small coefficient of anisotropy (3–5%). Therefore, the possible effect of the anisotropy can be neglected in the measurements of for rocks as it is usually below current observational errors.     

On sea-salt nuclei in the atmosphere

Summary The residues of cloud droplets collected at the summit of a mountain were examined with an electron microscope and their materials were identified with the aid of micro-electron-diffraction method. About 30% of nuclei of cloud droplets larger than 5 in radius were mainly composed of sodium chloride and their masses were 10^–1210^–13 gr. We also found salt particles in snow crystals. Some discussions are made about the process of the capture of these particles by snow crystals.     

Hydrochemistry of Three Dystrophic Lakes in Northeastern Poland

A hydrochemical investigation was carried out in spring, summer, and autumn, in the years 1991–1994, in three dystrophic lakes of the Wigry National Park (NE Poland). In spite of the fertile catchment basin, the developing ombrofile peat bogs of lake environment results in the acidification of lakes, the presence of small concentrations of dissolved mineral substances (below 50 mg L^–1), and exceptionally high DOC concentrations, exceeding 10 mg L^–1 C. During summer, a strong thermic stratification develops in the lakes, with constant conditions of oxygen deficiency prevailing below 3 m. In the course of the spring and autumn mixing of dystrophic lakes, the deterioration of oxygen conditions occurs in the epilimnion. In spite of high TP and NH₄⁺ concentrations, which increase from spring to autumn, the conditions developing in the lakes are unfavourable, for the functioning of aquatic organisms, on account of the strong shading. The increased direct irradiation of water bodies caused by deforestation or favourable atmospheric conditions results in an increased trophy of lakes.     

EISCAT measurements of the solar wind

EISCAT observations of interplanetary scintillation have been used to measure the velocity of the solar wind at distances between 15 and 130R (solar radii) from the Sun. The results show that the solar wind consists of two distinct components, a fast stream with a velocity of 800 km s^–1 and a slow stream at 400 kms^–1. The fast stream appears to reach its final velocity much closer to the Sun than expected. The results presented here suggest that this is also true for the slow solar wind. Away from interaction regions the flow vector of the solar wind is purely radial to the Sun. Observations have been made of fast wind/slow wind interactions which show enhanced levels of scintillation in compression regions.     

Progressive cooling of the hyaloclastite ridge at Gjálp, Iceland, 1996–2005

In the subglacial eruption at Gjálp in October 1996 a 6 km long and 500 m high subglacial hyaloclastite ridge was formed while large volumes of ice were melted by extremely fast heat transfer from magma to ice. Repeated surveying of ice surface geometry, measurement of inflow of ice, and a full Stokes 2-D ice flow model have been combined to estimate the heat output from Gjálp for the period 1996–2005. The very high heat output of order 10⁶ MW during the eruption was followed by rapid decline, dropping to  2500 MW by mid 1997. It remained similar until mid 1999 but declined to 700 MW in 1999–2001. Since 2001 heat output has been insignificant, probably of order 10 MW. The total heat carried with the 1.2 × 10¹² kg of basaltic andesite erupted (0.45 km³ DRE) is estimated to have been 1.5 × 10¹⁸ J. About two thirds of the thermal energy released from the 0.7 km³ edifice in Gjálp occurred during the 13-day long eruption, 20% was released from end of eruption until mid 1997, a further 10% in 1997–2001, and from mid 2001 to present, only a small fraction remained. The post-eruption heat output history can be reconciled with the gradual release of 5 × 10¹⁷ J thermal energy remaining in the Gjálp ridge after the eruption, assuming single phase liquid convection in the cooling edifice. The average temperature of the edifice is found to have been approximately 240 °C at the end of the eruption, dropping to  110 °C after 9 months and reaching  40 °C in 2001. Although an initial period of several months of very high permeability is possible, the most probable value of the permeability from 1997 onwards is of order 10^− 12 m². This is consistent with consolidated/palagonitized hyaloclastite but incompatible with unconsolidated tephra. This may indicate that palagonitization had advanced sufficiently in the first 1–2 years to form a consolidated hyaloclastite ridge, resistant to erosion. No ice flow traversing the Gjálp ridge has been observed, suggesting that it has effectively been shielded from glacial erosion in its first 10 years of existence.