新疆东昆仑白干湖钨锡矿田矿化体模型

白干湖钨锡矿田矿床类型属构造导控的高温热液型,矿化体几何形状取决于导控构造及容矿岩石的性质.该矿床容矿岩石有绢云石英片岩、石英透闪石岩、变质辉长岩、蚀变花岗岩等区内所有岩石类型.矿化是以均匀的微细脉浸染为主,矿化岩石与同类型未矿化岩石特征差别无几,矿化期交代作用十分微弱.矿石类型属于微细脉浸染及富细脉型.矿化体模型是在基本了解矿床地质特征,成控规律以及地表主要矿体形态数据基础上拟建的.理论上,矿化体是以导矿构造为骨架的简化板状矿化体,与易矿化岩层贯通所形成的似层状矿化体构成的复合体.这种复合体即使在高精度矿产勘查过程中也不能保证取得相对准确的数据.因此,准确识别矿化体性质十分重要.     

Gold-Related Sulfide Mineralization and Ore Genesis of the Penjom Gold Deposit, Pahang, Malaysia

The Penjom gold deposit lies on the eastern side of the Raub‐Bentong Suture line within the Central Belt of Permo‐Triassic rocks, near Kuala Lipis, Pahang, Malaysia. The geology of the deposit is dominated by a sequence of fine‐ to coarse‐grained rhyolitic to rhyodacitic tuff, tuff‐breccia and a minor rhyolitic–rhyodacitic volcanic series, associated with argillaceous marine sedimentary rocks consisting of shale with subordinate shalely limestone of Padang Tungku Formation and Pahang Volcanic Series. Fine‐ to coarse‐grained tonalite and quartz porphyry intruded this unit. The main structural features of the area are north–south‐trending left‐lateral strike‐slip faults and their subsidiaries, which generally strike north–south and dip moderately to the east (350°–360°/40°–60°). Mineralization at the Penjom gold deposit is structurally controlled and also erratic laterally and vertically. The gold mineralization can be categorized as (i) gold associated with carbonate‐rich zones hosted within dilated quartz veins carrying significant amount of sulfides; (ii) gold disseminated within stockwork of quartz–carbonate veins affiliated with tonalite; and (iii) gold often associated with arsenopyrite and pyrite in quartz–carbonate veins and stringers hosted within shear zones of brittle–ductile nature in all rock types and in brittle fractured rhyodacitic volcanic rocks. Sphalerite, chalcopyrite, tetrahedrite and pyrrhotite are the minerals accompanying the early stage of gold mineralization. These minerals also suffered from local brittle deformation. However, most of the gold mineralization took place after the deposition of these sulfides. Galena appears somewhat towards the end of gold mineralization, whereas tellurium and bismuth accompanied gold contemporaneously. The gold mineralization occurred most probably due to the metamorphogenic deformational origin concentrated mostly in the shear zone. The mineralization is strongly controlled by the wall rock (e.g. graphitic shale), the sulfide minerals and fluid–rock interaction.     

栗木矿田三个黄牛花岗岩型钨锡矿床地质特征

三个黄牛花岗岩型钨锡矿床与栗木复式岩体的第二阶段花岗岩有关,研究表明,三个黄牛隐伏花岗岩属超酸性过铝富碱一类岩石。矿体赋存于隐伏岩体浅部。矿石矿物黑钨矿、白钨矿、锡石主要以浸染状、细脉状及团块状产出,与钨锡成矿有关的交代作用有钠长石化、云英岩化以及晚期中低温热液蚀变作用,显示钨锡具有多阶段成矿,矿化延续时间长的特点。研究指出,在隐伏岩体岩沟凹陷内相对突起的部位继续寻找花岗岩型钨锡矿床具有一定的前景。     

湘东桐木山云英岩型锡矿床锡石及共生石英中流体包裹体研究

桐木山云英岩型锡矿床是湘东锡田锡多金属矿田中一个典型矿床,在详尽的野外考察、矿石结构观察以及流体包裹体岩相学研究的基础上,采用流体包裹体组合的研究方法,利用冷热台、激光拉曼等测试手段,对矿床中锡石中流体包裹体进行直接测定,同时开展与锡石共生的石英及切割矿体的后期石英脉石英中流体包裹体对比研究。结果显示,锡石中流体包裹体的组分、均一温度、盐度与共生的石英存在明显差异,表明锡石与石英形成的P-T-X条件不同。切割矿体的石英脉为成岩成矿后流体作用的产物。与锡石形成相关的流体为中高温、中低盐度的NaCl-H₂O流体体系,与石英形成相关的流体为复杂的含碳流体。流体体系的冷却作用及流体与围岩的反应可能是导致锡石沉淀的主要因素,与石英形成相关的流体在演化过程中则经历了明显的流体不混溶作用。

     

江西崇义老庵里破碎带蚀变岩型锡钨多金属矿床地质特征

江西崇义老庵里锡多金属矿床产于南岭成矿带赣南段天门山岩体西缘外接触带,矿化地质体受破碎带与灰岩层控制,沿破碎带发育矽卡岩化、绿泥石化、碳酸盐化和与之相伴的锡石—硫化物—白钨矿化,矿与矿化界线靠样品圈定,矿体呈似层状、扁透镜状,金属矿物主要是锡石、黄锡矿、方铅矿、闪锌矿、锡黝铜矿及白钨矿,往深部白钨矿增多.矿床成因应属与...     

南岭东段大金山钨锡多金属矿床大坳矿段垂向分带规律浅析

南岭东段大金山钨锡多金属矿大坳矿段是典型的石英脉型矿床,含矿石英脉具有近地表以钨锡矿化为主,而深部以钼矿化为主的垂向分带规律,且在岩体与地层接触界面附近发育一组与接触面近平行的含钼石英脉。大坳矿段钨锡钼的矿化呈现出上钨锡下钼的分带规律。理论上黑钨矿、锡石通常为相对高温的矿物,一般应发育于相对靠近岩体的高温环境,而辉钼矿为相对低温的矿物,似乎应发育于相对远离岩体的低温环境,初步分析后认为,该矿段的逆向分带特征主要由钨、锡与钼之间不同的地球化学亲和性造成的。     

Geology and Mineral Chemistry of Gold Mineralization in Mirge‐Naqshineh Occurrence (Saqez,NW Iran): Implications for Transportation and Precipitation of Gold

The Mirge-Naqshineh gold district is situated at northwest of Iran with a NW-trending brittleductile shear zone. It is hosted by Precambrian meta-sedimentary and meta-volcanic units traversed by mineralized quartz veins. In terms of cross-cutting relationships and sulfide content three types of quartz veins are identified in the region. Among those, parallel to bedding quartz vein(type Ⅰ) is the main host for gold mineralization. Gold is found in three different forms: 1) submicrometer-size inclusions of gold in arsenian pyrite, 2) as electrum and 3) in the crystal lattice of sulfides(pyrite, galena and chalcopyrite). Six types of pyrite(Py1-Py6) were identified in this ore reserve. Py3 coexists with arsenopyrite and contains the greatest As-Au concentrations. There is a negative correlation between the As and S contents in Py2 and Py3, implying the substitution of sulfur by arsenic. Pyrites and mineralized quartz veins were formed via metamorphic-hydrothermal fluid and reflect the gold-transportation as Au(HS)_2~- under reducing and acidic conditions. The gold precipitation mainly controlled by crystallization of arsenian pyrite during fluid/rock interactions and variation of fO_2. The volcanic host rock has played an important role in gold concentration, as Py3 in this rock contains inclusion of gold particles, but gold is within the lattice of pyrite in phyllite or other units.     

内蒙古维拉斯托锡多金属矿流体包裹体特征

大兴安岭锡矿带是中国北方唯一成型的锡多金属成矿带。新近发现的内蒙古维拉斯托锡多金属矿床位于大兴安岭南段,隶属中亚造山带东段的兴蒙造山带。该矿床为一典型的大型斑岩型热液脉型锡多金属矿床,矿区内锡矿化主要赋存于石英斑岩体顶部及其上部的石英脉中。矿床成矿阶段包括石英斑岩体内的滴状锡锌矿化阶段、石英斑岩体上部石英脉中的辉钼矿矿化阶段、石英锡石黑钨矿阶段和石英多金属硫化物阶段。流体包裹体研究结果显示：流体包裹体类型主要为气液两相包裹体,尤其是富液相包裹体,其次为含子矿物的三相包裹体。斑岩体内矿化阶段流体包裹体均一温度为324~333 ℃,盐度为6.5%~7.5% NaCleqv,密度为0.73~0.74 g/cm3;石英脉型矿化阶段包裹体均一温度为201~324 ℃,盐度为3.4%~9.9% NaCleqv,密度为0.73~0.92 g/cm3。包裹体显微测温分析结果显示该矿区成矿流体具有中高温、低盐度、中密度的特征。激光拉曼光谱分析表明,气液两相包裹体液相成分主要为H2O,气相成分主要有H2O、CO2和CH4。氢氧同位素研究结果表明该矿床石英斑岩体上部石英脉矿化阶段的成矿流体为岩浆水和大气降水混合来源,以岩浆水为主。岩浆流体与大气降水的混合以及流体演化中的降温过程是该矿床矿石沉淀的主要机制。     

西藏谢通门县邦弄含铁电英岩脉的地质特征及成因分析

文章介绍了西藏谢通门县邦弄地区含铁电英岩脉的地质特征.电英岩脉的延伸方向大致与区内的断层平行,围岩为中粒斑状角闪黑云二长花岗岩.电英岩脉中见有不同程度的铁矿化,共有23条矿化较好的含铁电英岩脉.含铁电英岩脉中矿石矿物为赤铁矿(镜铁矿),脉石矿物为石英、电气石及少量的白云母和长石.矿石具叶片状、鳞片状结构,块状构造,矿石...     

中国锡矿成矿规律概要

我国锡矿资源丰富,矿床类型比较齐全。在锡矿资源储量中占有较大比重的主要是锡石—硫化物型、矽卡岩型和石英脉型;从开采和利用角度来说,最为重要的是锡石—硫化物型和石英脉型。锡石—硫化物型主要集中在桂北、滇东等地,矽卡岩型集中分布在南岭中段湘南等矿集区、石英脉型则主要集中在华南地区的闽西、赣中、粤北、湘南等地;成矿时代以中生代最为重要;成矿大地构造背景以造山运动之后的大陆环境为主,构造变动剧烈,深大断裂纵横交错,岩浆活动频繁,特别是与锡成矿作用关系密切的中生代花岗岩类非常发育,最具特色。本次在对全国873处锡矿矿产地资料进行系统梳理的基础上,深入总结了全国锡矿的成矿规律,厘定出20个以锡为主或锡较为重要的矿床成矿系列,认为锡石—硫化物型、矽卡岩(—云英岩型)、石英脉型和岩体型4类锡矿类型,应该作为重点预测类型,并划分出44个成锡带,提出了19个重要工作部署区,并编制了中国成锡带图、中国锡矿成矿规律图等系列图件,为潜力评价预测工作提供了理论依据。     

Characteristic Features of Tin–iron–copper Mineralization in the Anle-Huanggangliang Mining Area, Inner Mongolia, China

Abstract: The Anle Sn‐Cu and Huanggangliang Fe‐Sn deposits have been exploited in the Linxi district, which is located 165 km northwest of Chifeng City in northern China. In this study the formation mechanisms of the tin deposits in the Anle and Huanggangliang mining area were investigated to understand the mechanisms of tin mineralization in northern China. The veins of the Anle deposit are divided into cassiterite–quartz–chlorite veins, chalcopyrite‐bearing quartz veins, cassi–terite–chalcopyrite–bearing quartz veins and sphalerite‐quartz veins. The sequence of mineralization is tin mineralization (stage I), copper mineralization (stage II), and lead‐zinc mineralization (stage III). The Huanggangliang tin deposit consists of magnetite skarn orebodies and many cassiterite‐bearing feldspar–fluorite veins and veinlets cutting the magnetite orebodies. The fluid inclusions in quartz and fluorite in ores from the Anle and Huanggangliang tin deposits are divided into two‐phase fluid inclusions, vapor‐rich fluid inclusions and poly‐phase fluid inclusions. The final homogenization temperatures of fluid inclusions of quartz in the ores of the Anle deposit and fluorite of tin‐bearing feldspar veins in the Huanggangliang tin deposit range from 195 to 425C and from 215 to 450C, respectively. The fluids responsible for the Anle and Huanggangliang tin deposits were of very high temperature and NaCl‐rich ones containing K, Ca, Al, Si, Ti, Fe and Cl in addition to ore metals such as Sn and Cu. The temperature and chemical composition of fluid in fluid inclusions of igneous rocks in the mining area are very similar to those of fluid in fluid inclusions in the ores of these deposits. The fluid for these ore deposits had a close relation with the fluid coexisting with melt of Late Jurassic granitic rocks in this mining area. Salinities of fluid inclusions from these ore deposits and granitic rocks in the mining area were estimated to range from 35 to 50 wt % NaCl equivalent. Based on arsenopy‐rite geothermometry and fluid inclusion studies, a fluid containing 40 wt% NaCl (eq.) could be formed by phase separation of fluid having 6 wt% NaCl (eq.) at a temperature of 420 to 500C and a pressure of 0.3 to 0.4 kb. The temperatures and pressures presented above indicate an NaCl‐rich magmatic fluid derived from granitic melt that had intruded into a shallow level of crust caused the Sn–Fe–Cu mineralization of the mining area. The geological relationship between these ore deposits and granitic bodies around the ore deposits, and the similarity of fluids forming these ore deposits and coexisting with granitic melt, suggest that these ore deposits were formed by the activity of fluid derived from granitic melt in Late Jurassic age.     

新疆库布苏金矿石英标型特征研究

重点研究了库布苏矿化带中石英脉与金矿化关系，对不同成矿阶段石英的化学成分，晶胞参，红外光谱，热发光，包裹体等进行了研究，总结了找矿矿物学标志。     

新疆干梁子锡矿田成岩成矿作用同位素年代学研究及矿床成因探讨

干梁子锡矿田位于准噶尔盆地东北缘,构造上处于西伯利亚和哈萨克斯坦－准噶尔板块的交汇部位,是贝勒库都克锡矿带的重要组成部分。地质地球化学和同位素年代学研究表明,干梁子锡矿田的形成与碰撞造山期花岗岩体的侵位有关,属岩浆热液型锡矿,成矿时代为中石炭世。     

微细浸染型金矿的硅质阴极发光与成矿物源分析——以黔西南和桂西北金矿为例

应用阴极发光技术研究了微细浸染型金矿中赋矿围岩和矿石中硅质以及成矿期和表生期石英脉的阴极发光特征。结果表明 :围岩(包括石英斑岩和辉绿岩墙)中的硅质和石英及次生硅化石英均表现不同的发光特征 ,而与原生矿化有关的原生硅化石英不发光 ;其中 ,氧化矿石中的硅化石英和表生梳状石英脉在阴极发光下呈棕色 ,与赋矿围岩中碎屑石英的次生溶解加大边表现的发光特征一致。这表明氧化和表生石英的硅质来源与溶解围岩和改造原生矿石有关 ,而原生硅化石英的硅质来源与围岩(包括岩浆岩)无关 ,进而表明成矿物质并非围岩提供。结合其它方面的系列研究 ,为该类型金矿属深源流体成矿作用产物的新观点 ,即成矿物质和流体可能直接来源于深部或上地幔提供了进一步的证据。这表明 ,阴极发光技术是一种简便、可靠和实用的矿床成因研究手段。     

芙蓉矿田白腊水锡矿矿化特征及找矿意义

白腊水锡矿床是在新一轮地质大调查中发现,并进行了初步评价的大型矿床.该区断裂构造发育,构造线以NNE-NE向为主,并控制着锡矿带的分布.通过该矿床矿化特征的研究认为:①白腊水矿区到处发育的石英脉可能是锡矿化作用的同期产物;②矿脉内的锡矿化可能极不均匀,高品位的地段一般在构造破碎强烈地方;③该区不同岩体的成矿元素含量明显高于地壳花岗岩类岩石的平均值,有些高出数十倍,具良好的含矿性;④该地区的岩浆岩的稀土元素组成特征极为相似,岩(矿)石稀土元素球粒陨石标准化曲线具有相同的变化特点,显示出岩(矿)石可能为同一岩浆房演化的产物;同时反映出矿化可能与细粒花岗岩关系更密切.     

湘南芙蓉矿田白腊水锡矿床包裹体特征

白腊水锡矿床位于骑田岭复式岩体的南部,矿体受断裂构造带控制;矿脉(体)的分布及其形态、产状等受低序次断裂控制。矿物中V-L包裹体、V-L-Lco2包裹体发育,包裹体均一温度显示有三个区间,可划分为三个成矿阶段,反映出成矿多期次叠加的特征。根据石英流体包裹体Rb-Sr等时线年龄值(177Ma)和锡矿化强蚀变岩石Rb Sr同位素年龄(136Ma),表明成矿时代应为燕山早期,并且该矿床形成可能是二次成矿作用的产物。     

Polymetallic Mineralization at the Nakakoshi Copper Deposits, Central Hokkaido, Japan

Abstract: Polymetallic mineralization at the Nakakoshi deposits, Kamikawa town, central Hokkaido, occur as fracture-filling veins in Cretaceous slate of the Hidaka Supergroup. Ten veins have been recognized in NE-SW and E-W directions. Sericite in altered slate which is the host of the deposits, was dated at 31. 1 Ma, Oligocene in age.
No. 9 vein consists of massive chalcopyrite ore with various kinds of minerals such as pyrite, pyrrhotite, arsenopyrite, sphalerite, tetrahedrite, Ag-minerals and Cu–Zn–Fe–In–Sn–S minerals, quartz and sericite. Chalcopyrite and pyrite contain sphalerite star and sphalerite with chalcopyrite emulsions. Maximum indium contents of sphalerite and the Cu–Zn–Fe–In–Sn–S minerals are 1. 8 and 16. 3 wt%, respectively. The sulfur isotopic ratios, δ³⁴S of ore minerals, range from –12. 9 to –9. 6%. Formation temperatures of the sulfide minerals are estimated as 300–500°C, based on the paragenesis and chemical compositions of the minerals.     

广西姑婆山锡矿田矿床地质特征及矿床成因

姑婆山锡矿田锡矿床类型丰富，其中以矽卡岩型、矽卡岩-蚀变断裂破碎带复合型锡矿床为主，矿床主要产于燕山早期姑婆山花岗岩西南接触带2km范围内，且具一定的分带性，从接触带往外，依次为矽卡岩型→矽卡岩与蚀变断裂破碎带复合型→锡石硫化物型→石英脉型。矿床受成矿花岗岩、有利赋矿层位及构造复合等因素的控制，与成矿花岗岩关系尤为密切，成岩、成矿时间接近，成矿物质主要来自岩浆，矿床为与花岗岩有关的岩浆期后热液矿床。     

Genetic aspects of gold mineralization in the Southern Granulite Terrain,India

Gold mineralization in Southern Granulite Terrain (SGT) of India has close spatial relationship with the shear zones (Moyar–Bhavani) present in Cauvery Suture Zone. Gold is found to be associated with primary quartz veins, placers and laterites. The gold prospects in SGT can be broadly grouped into three provinces i) Wynad-Nilgiri, ii) Malappuram and iii) Attappadi. The auriferous quartz veins are within the deformed biotite/hornblende bearing gneisses and amphibolite. Wall rock alteration is conspicuous around the mineralized veins and gives an assemblage of muscovite–calcite–ankerite–chlorite–biotite–pyrite related to fluid–rock interaction at the time of vein formation. Fluid inclusion studies of vein quartz gives an idea of the nature of the ore forming fluids, the fluid involved in gold mineralization is of low saline and aqueous-carbonic in composition and quite similar to the orogenic lode gold deposits reported world-wide. Micro-thermometric data indicates fluid immiscibility (phase separation) during trapping of fluid inclusions and this must have played an important role in gold deposition. Geochronological studies of mineral separates from Wynad-Nilgiri province using Rb–Sr and Sm–Nd isochron methods of the auriferous quartz veins gave an age of approximately 450 Ma for the vein formation. The present studies on SGT gold mineralization indicate 1. During the Pan-African orogeny, extensive fluid influx from mantle and metamorphism extracted gold from a mafic source and were focused along major structural discontinuities of Moyar–Bhavani Shear Zone, 2. The aqueous–carbonic ore fluid interacted with rocks of the upper crust and triggered a set of metasomatic changes responsible for the dissolved components such as Ca, Si and Fe and finally precipitating in the veins and 3. The mineralizing fluid with dissolved gold in sulphide complex got destabilized due to fluid immiscibility and wall rock alteration leading to the deposition of gold with associated sulphide minerals in the vein system.     

Mineralogy, Geochemistry, and Age Constraints on the Beni Bou Ifrour Skarn Type Magnetite Deposit, Northeastern Morocco

Abstract: The Beni Bou Ifrour deposit of northeastern Morocco is a skarn type magnetite deposit. K-Ar age determination suggests that the mineralization occurred at 7.040.47 Ma. The spatial relationship between skarn and dikes of microgran-odiorite derived from the batholith of Wiksane Granodiorite, and the similarity of age (8.020.22 Ma), confirms that the Wiksane Granodiorite is the igneous rock most probably related to mineralization. The skarn is distributed asymmetrically in the limestone, and magnetite ore was developed just below the calc-silicate skarn as two parallel beds separated by 100 m of barren limestone and schist.
The mineralization can be divided into three stages. The early stage is characterized by the formation of calc-silicate minerals, mainly clinopyroxene (80–70 % diopside) and garnet (early almost pure andradite to the late 60 % andradite). The main stage is characterized by the formation of a large amount of magnetite. Epidote and quartz formed simultaneously with magnetite. Fluid temperatures exceeded 500 C during the early to main stages. Fluid with very high salinity (50–75 wt% NaCl equiv.) was responsible for the formation of the magnetite ore. The oxygen isotope composition, together with the fluid inclusion data, suggests that magmatic fluid was significant for the formation of calc-silicate skarn minerals and magnetite. Low temperature (-230C) and low salinity (-10 % NaCl equiv.) hydrothermal fluids dominated by meteoric water were responsible for the late stage quartz and calcite formation.