Formation of U-depleted rhyolite from a basanite at El Hierro, Canary Islands

Phonolite and trachyte are the felsic magmas of the alkaline magma suites, which characterize the Canary Islands. The October 2011 submarine eruption off El Hierro, the westernmost island, nevertheless, produced a small volume of rhyolitic magma. The rhyolite occurred as highly vesicular, white coloured pumices enveloped in and mingled with darker coloured basanitic pumice. The basanitic pumice is relatively crystal poor with a few euhedral olivines (mostly Fo_77–79), clinopyroxenes and Fe-rich spinels, whereas very rare olivine of same composition is found together with equally rare Fe-sulphide and FeTi-rich oxides in the rhyolite. The Fe–Mg exchange equilibrium in the oxides permits to calculate an equilibrium temperature of 970–890 °C for the rhyolite, in agreement with quartz-melt equilibrium at ca. 930 °C. A striking mineralogical feature of the rhyolite is the presence of rounded to contorted grains of milky quartz, which are xenocrysts incorporated and partly dissolved into the magma. Analyses of residual volatile concentrations in the glasses show that the rhyolite melt was highly degassed, whereas the basanitic glass still has important halogen concentrations. Trace element patterns of the mafic glasses and their elevated incompatible element concentrations are typical of the western Canary Island basanites. In contrast, the trace element composition of the rhyolite shows surprisingly low concentrations for all elements except the most incompatible ones (e.g. Rb, Ba, K and Th). All other measured LILE, HFSE and REE have significantly lower concentration than the basanitic counterpart that can be explained by fractionation of accessory phases (1 % apatite, 1 % sphene and 0.1 % zircon). Surprisingly, low U concentration is presumably related to elevated oxygen fugacity in the rhyolite, causing U to be in a hexavalent state, and fluxing of F-rich gas leading to volatilization of UF₆, known to emanate at low temperature. The results suggest that a gas-rich basanitic melt remobilized a small volume of stagnant rhyolitic melt formed by incorporation of approximately 10 % quartz-rich sediment into a late differentiate of trachytic composition. Sediments at the interface of an old oceanic crust adjacent to a continental shield and younger volcanic island are likely to act as magma traps were sediment assimilation may alter the mantle-derived magma composition. Quartz assimilation thus explains the production of rhyolite magma in a volcanic island characterized by an alkaline magma series from primitive basanites to trachytes.     

Arc dacite genesis pathways: Evidence from mafic enclaves and their hosts in Aegean lavas

Mafic enclaves are commonly found in intermediate arc magmas, and their occurrence has been linked to eruption triggering by pre-eruptive magma mixing processes. New major, trace, Sr–Nd and U–Th isotope data of rocks from Nisyros in the Aegean volcanic arc are presented here. Pre-caldera samples display major and trace element trends that are consistent with fractionation of magnetite and apatite within intermediate compositions, and zircon within felsic compositions, and preclude extensive hybridization between mafic and felsic magmas. In contrast, post-caldera dacites form a mixing trend towards their mafic enclaves. In terms of U-series isotopes, most samples show small ²³⁸U excesses of up to  10%. Mafic enclaves have significantly higher U/Th ratios than their dacitic host lavas, precluding simple models that relate the mafic and felsic magmas by fractionation or aging alone. A more complicated petrogenetic scenario is required. The post-caldera dacites are interpreted to represent material remobilized from a young igneous protolith following influx of fresh mafic magma, consistent with the U–Th data and with Sr–Nd isotope constraints that point to very limited (< 10%) assimilation of old crust at Nisyros. When these results are compared to data from Santorini in the same arc, there are many geochemical similarities between the two volcanic centers during the petrogenesis of the pre-caldera samples. However, striking differences are apparent for the post-caldera lavas: in Nisyros, dacites show geochemical and textural evidence for magma mixing and remobilization by influx of mafic melts, and they erupt as viscous lava domes; in Santorini, evidence for geochemical hybridization of dacites and mafic enclaves is weak, dacite petrogenesis does not involve protolith remobilization, and lavas erupt as less viscous flows. Despite these differences, it appears that mafic enclaves in intermediate Aegean arc magmas consistently yield timescales of at least 100 kyrs between U enrichment of the mantle wedge and eruption, on the upper end of those estimated for the eruptive products of mafic arc volcanoes. Finally, the data presented here provide constraints on the rates of differentiation from primitive arc basalts to dacites (less than  140 kyrs), and on the crustal residence time of evolved igneous protoliths prior to their remobilization by mafic arc magmas (greater than  350 kyrs).     

Late Ordovician island‐arc volcanic rocks,northern Capertee Zone,Lachlan Fold Belt,New South Wales

The Cape Hoskins volcanoes form part of the Quaternary volcanic island arc that extends from Rabaul in the east to the Schouten Islands in the west, and they overlie the northerly dipping New Britain Benioff Zone. The products of the volcanoes range in composition from basalt to rhyolite, and are normative in quartz and hypersthene. They contain phenocrysts of plagioclase and subordinate augite, hypersthene, and in most samples iron‐titanium oxides; some samples also contain olivine or quartz or both, and some pumice contains hornblende and, rarely, biotite.

Chemical analyses of 29 volcanic rocks are presented; 22 were also analysed for 17 minor elements — Rb, Ba, Sr, Pb, Zn, Cu, Zr, Y, Ni, Co, Sc, Cr, V, Ga, B, U, and Th.

Chemically the rocks have many of the characteristics of the ‘island arc tholeiitic series’, but do not show a pronounced relative enrichment in iron and appear to be relatively enriched in Sr. Compared with volcanic rocks from the northern part of the Willaumez Peninsula, they are lower in K (but not Na), Ti, Rb, Ba, Zr, Pb, Th, Ni, and probably also V, Cu, and Zn: these differences are attributed to the greater depth of the Benioff Zone beneath the Willaumez Peninsula. The more basic of the Cape Hoskins rocks are similar in most respects to lavas of comparable composition from Ulawun volcano to the east.     

松辽盆地北部升平气田营城组火山岩储层特征与成岩演化

对升平气田白垩系营城组火山岩岩石学与物性特征、储集空间类型及其形成和演化等研究结果表明,火山岩岩石类型主要有火山碎屑岩、火山熔岩和沉火山岩,以流纹岩为主,少量英安岩、安山岩。火山岩气藏储集空间以次生溶孔(洞)为主,其次为原生孔隙和裂缝。火山岩的演化过程可划分为前期和后期两个阶段。前期阶段以火山自身活动为主,主要形成气孔和火山角砾间孔为主的原生孔隙;后期阶段包括火山熔岩的冷凝作用与火山岩的后生成岩作用,是火山岩储集空间形成的主要时期。研究区风化剥蚀面、断层与裂缝是天然气成藏的主要运移通道,也是有利的储集空间。     

Magmatic inclusions in rhyolites,contaminated basalts,and compositional zonation beneath the Coso volcanic field,California

Basaltic lava flows and high-silica rhyolite domes form the Pleistocene part of the Coso volcanic field in southeastern California. The distribution of vents maps the areal zonation inferred for the upper parts of the Coso magmatic system. Subalkalic basalts (<50% SiO₂) were erupted well away from the rhyolite field at any given time. Compositional variation among these basalts can be ascribed to crystal fractionation. Erupted volumes of these basalts decrease with increasing differentiation. Mafic lavas containing up to 58% SiO₂, erupted adjacent to the rhyolite field, formed by mixing of basaltic and silicic magma. Basaltic magma interacted with crustal rocks to form other SiO₂-rich mafic lavas erupted near the Sierra Nevada fault zone.Several rhyolite domes in the Coso volcanic field contain sparse andesitic inclusions (55–61% SiO₂). Pillow-like forms, intricate commingling and local diffusive mixing of andesite and rhyolite at contacts, concentric vesicle distribution, and crystal morphologies indicative of undercooling show that inclusions were incorporated in their rhyolitic hosts as blobs of magma. Inclusions were probably dispersed throughout small volumes of rhyolitic magma by convective (mechanical) mixing. Inclusion magma was formed by mixing (hybridization) at the interface between basaltic and rhyolitic magmas that coexisted in vertically zoned igneous systems. Relict phenocrysts and the bulk compositions of inclusions suggest that silicic endmembers were less differentiated than erupted high-silica rhyolite. Changes in inferred endmembers of magma mixtures with time suggest that the steepness of chemical gradients near the silicic/mafic interface in the zoned reservoir may have decreased as the system matured, although a high-silica rhyolitic cap persisted.The Coso example is an extreme case of large thermal and compositional contrast between inclusion and host magmas; lesser differences between intermediate composition magmas and inclusions lead to undercooling phenomena that suggest smaller T. Vertical compositional zonation in magma chambers has been documented through study of products of voluminous pyroclastic eruptions. Magmatic inclusions in volcanic rocks provide evidence for compositional zonation and mixing processes in igneous systems when only lava is erupted.     

Geochemistry of coastal sands of Eastern Mediterranean: The case of Nisyros volcanic materials

Coastal sand samples collected from the northern part of Nisyros volcanic island (Dodecanese, Greece) were investigated for first time for their potential in strategic metals and compared with parental rocks of the island which are Quaternary volcanics with alternating lava flows, pyroclastic layers and lava domes and relevant materials located near granitoids of Northern Greece. The PXRD and SEM-EDS study of the sands revealed enhanced content of feldspars, Fe-Mn oxides, magnetite, tourmaline, pyroxenes, ilmenites, along with zircons, apatite and sulfide inclusions. The fresh hydrothermally deposited clayely material collected from the Nisyros caldera crater had a rather different mineralogical composition from the coastal one (alunite, anhydrite, opal-CT, quartz, kaolinite). UCC-normalized spidergrams indicated that the weathering processes contributed to accumulation of heavy minerals (mainly ilmenite), and strategic metals including V (1920 mg/kg) and Nb (245 mg/kg), in the coastal sand. The low REE concentration (ΣREE + Y = 240 mg/kg) could be attributed to the absence of REE-rich minerals. Moreover, the sands exhibit different geochemical patterns compared to the volcanic source rocks of the island, which are especially enriched in Large-Ion Lithophile Elements (LILE) and depleted in High Field Strength Elements (HFSE), such as Nb and Ta. On the other hand, the caldera material is enriched in volatile components, sulfur, chalcophile elements (Se, Bi, Hg, As, Pb) and Ba. Micro-XRF analyses of representative crystals showed that the high Nb content of the sands was associated with the Ti/Fe-rich phases (e.g. ilmenites). The geochemical composition of N Greece sands showed, because of their origin, enrichment not only in HFSE but also in REE.The study of the coastal heavy mineral sands originating from different geological environments of Greece provides information about the association of their mineral components with REE, other elements of economic interest (e.g. Co, Nb, Ta) and natural actinides. In addition, the study of the black sands of Nisyros island could be considered as a characteristic example of those from other parts of Hellenic Volcanic Arc (HVA) and other relevant Mediterranean regions.     

Petrology and geochemistry of the island of Sarigan in the Mariana arc; calc-alkaline volcanism in an oceanic setting

Isotopic studies of rocks from oceanic island arcs such as the Marianas indicate that little, if any, recycling of continental material (e.g. oceanic sediments) occurs in these arcs. Because oceanic arcs are on the average more mafic than the dominantly andesitic continental arcs, an important question is whether the andesites of continental arcs are produced by a fundamentally different (more complex?) mechanism than the lavas of oceanic arcs. An excellent opportunity for study of this question is provided by the island of Sarigan, in the Mariana active arc, on which calc-alkaline andesites (including hornblende-bearing types) are exposed along with more mafic lavas. Available isotope data suggest the Sarigan lavas (including the andesites) were derived from mantle material with little or no involvement of continental components. Ratios of incompatible elements suggest that most of the Sarigan lavas were derived from similar source materials. Absolute abundances of incompatible elements vary irregularly within the eruptive sequence and indicate at least 5 distinct magma batches are represented on Sarigan. Major element data obtained on the lavas and mineral phases in them, combined with modal mineral abundances, suggest that the calc-alkaline nature of the volcanic rocks on Sarigan results from the fractional crystallization of titanomagnetite in combination with other anhydrous phases. Amphibole, although present in some samples, is mainly a late-crystallizing phase and did not produce the calc-alkline characteristics of these lavas. Gabbroic samples found in the volcanic sequence have mineralogc and geochemical characteristics that would be expected of residual solids produced during fractional crystallization of the Sarigan lavas. When combined, data on the lavas and the gabbros suggest the following crystallization sequence: olivine — plagioclase — clinopyroxene — titanomagnetite — orthopyroxene±hornblende, biotite and accessory phases. These results lead to the conclusion that calc-alkaline magmas can be generated directly from mantle sources.     

冲绳海槽火山岩岩石系列的厘定及构造环境意义

冲绳海槽是一个处于弧后扩张作用早期的年轻的弧后盆地,是研究弧后扩张作用早期盆地演化和壳幔过程的天然实验室.随着调查研究工作的逐步展开和深入,也发现了一些新的、重要的、亟待解决的科学问题,而火山岩岩石系列归属的厘定又是其他研究工作的基础.在系统收集和整理迄今已有冲绳海槽火山岩资料的基础上,结合近期分析测试数据, 对冲绳海槽火山岩的岩石系列归属进行了重新厘定,探讨了火山岩的构造环境指示意义和浮岩与玄武岩之间的成因联系.研究结果表明:冲绳海槽火山岩分布具有以基性玄武岩和酸性(流纹)英安岩为主的双峰式特征,中性火山岩稀少,基性的玄武岩属于亚碱性系列的橄榄拉斑玄武岩,酸性浮岩可归属为亚碱性岩系的流纹英安岩或流纹岩;在构造环境判别上,冲绳海槽玄武岩表现出大洋中脊和岛弧构造环境的特点,既有别于大洋中脊扩张中心,也有别于成熟型弧后盆地,呈现出弧后早期扩张阶段盆地独特的构造环境特征;广泛分布于冲绳海槽的酸性浮岩表现出一定的岛弧环境的特点;酸性浮岩与玄武岩具有同源性,酸性岩是基性的玄武质岩浆经不同程度结晶分异和同化混染作用的产物.      

Origin of felsic volcanism in the Izu arc intra-arc rift

An intra-arc rift (IAR) is developed behind the volcanic front in the Izu arc, Japan. Bimodal volcanism, represented by basalt and rhyolite lavas and hydrothermal activity, is active in the IAR. The constituent minerals in the rhyolite lavas are mainly plagioclase and quartz, whereas mafic minerals are rare and are mainly orthopyroxene without any hydrous minerals such as amphibole and biotite. Both the phenocryst and groundmass minerals have felsic affinities with a narrow compositional range. The petrological and bulk chemical characteristics are similar to those of melts from some partial melting experiments that also yield dry rhyolite melts. The hydrous mineral-free narrow mineral compositions and low-Al₂O₃ affinities of the IAR rhyolites are produced from basaltic middle crust under anhydrous low-temperature melting conditions. The IAR basalt lavas display prominent across-arc variation, with depleted elemental compositions in the volcanic front side and enriched compositions in the rear-arc side. The across-arc variation reflects gradual change in the slab-derived components, as demonstrated by decreasing Ba/Zr and Th/Zr values to the rear-arc side. Rhyolite lavas exhibit different across-arc variations in either the fluid-mobile elements or the immobile elements, such as Nb/Zr, La/Yb, and chondrite-normalized rare earth element patterns, reflecting that the felsic magmas had different source. The preexisting arc crust formed during an earlier stage of arc evolution, most probably during the Oligocene prior to spreading of the Shikoku back-arc basin. The lack of systematic across-arc variation in the IAR rhyolites and their dry/shallow crustal melting origin combines to suggest re-melting of preexisting Oligocene middle crust by heat from the young basaltic magmatism.     

Geochemical constraints on the evolution of mafic and felsic rocks in the Bathani volcanic and volcano-sedimentary sequence of Chotanagpur Granite Gneiss Complex

The Bathani volcanic and volcano-sedimentary (BVS) sequence is a volcanic and volcano-sedimentary sequence, best exposed near Bathani village in Gaya district of Bihar. It is located in the northern fringe of the Chotanagpur Granite Gneiss Complex (CGGC). The volcano-sedimentary unit comprises of garnet-mica schist, rhyolite, tuff, banded iron formation (BIF) and chert bands with carbonate rocks as enclaves within the rhyolite and the differentiated volcanic sequence comprises of rhyolite, andesite, pillow basalt, massive basalt, tuff and mafic pyroclasts. Emplacement of diverse felsic and mafic rocks together testifies for a multi-stage and multi-source magmatism for the area. The presence of pillow basalt marks the eruption of these rocks in a subaqueous environment. Intermittent eruption of mafic and felsic magmas resulted in the formation of rhyolite, mafic pyroclasts, and tuff. Mixing and mingling of the felsic and mafic magmas resulted in the hybrid rock andesite. Granites are emplaced later, cross-cutting the volcanic sequence and are probably products of fractional crystallization of basaltic magma. The present work characterizes the geochemical characteristics of the magmatic rocks comprising of basalt, andesite, rhyolite, tuff, and granite of the area. Tholeiitic trend for basalt and calc-alkaline affinities of andesite, rhyolite and granite is consistent with their generation in an island arc, subduction related setting. The rocks of the BVS sequence probably mark the collision of the northern and southern Indian blocks during Proterozoic period. The explosive submarine volcanism may be related to culmination of the collision of the aforementioned blocks during the Neoproterozoic (1.0 Ga) as the Grenvillian metamorphism is well established in various parts of CGGC.     

Time-scales of Differentiation from Mafic Parents to Rhyolite in North American Continental Arcs

Young rhyolites and associated lavas and magmatic enclaves fromthe Katmai–Novarupta volcanic system (Alaskan Peninsula),and the Crater Lake and Medicine Lake volcanic system (Cascades)were analyzed for U and Th isotope abundances, as well as majorand trace element concentrations, to investigate the time-scalesof the processes that lead to rhyolite generation in continentalarcs. Basalts and basaltic andesites typically migrate fromthe mantle to the surface within several thousand years. Variationsin (²³⁰Th)/(²³²Th) and (²³⁸U)/(²³²Th) ratios with SiO₂ concentrationsin intermediate lavas appear to result from crystal fractionationcombined with assimilation of recently crystallized magmas.These data also suggest that     

Formation of Subaqueous Felsic Domes and Accompanying Pyroclastic Deposits on the Foça Peninsula (Izmir,Turkey)

In western Anatolia, a thick volcanic succession of andesitic to rhyolitic lavas and volcaniclastic rocks crops out extensively. On Foça Peninsula, the westernmost part of the region, a dominantly rhyolitic sequence is exposed where massive rhyolites occur as dome or domelike stubby lava flows. These rhyolite domes vertically and laterally pass into blanketing volcaniclastic sequences. The gradational boundary relations and the facies characteristics of the surrounding volcaniclastic sequences indicate that the silicic domes directly intruded a subaqueous environment and were shattered upon sudden contact with water to form hyaloclastic blankets.

In and around these rhyolite domes, we have defined six different volcanic and volcaniclastic facies, consisting of: (1) massive rhyolite; (2) massive perlite; (3) hyaloclastic breccias; (4) rhyolite pumice and lithic fragment-bearing volcaniclastic rocks; (5) subaqueous welded ignimbrites; and (6) brecciated perlite. The massive rhyolite facies have distinct structures from the centers to the peripheries of the domes and stubby lava flows. Massive lava facies gradually pass into hyaloclastic breccias and massive perlite facies, indicating water-magma interaction during the emplacement. Phreatomagmatic explosive activity and doming caused the subaqueous pyroclastic flows on the flanks of the volcanic center. Welding in the upper parts of these pyroclastic flow deposits indicates the high-temperature emplacement of the pyroclastic material and relatively slow cooling caused by the cushioning effect of the gas-vapor mixture and rapid deposition of younger pyroclastic units.     

长白山天池地区全新世以来火山活动及其特征

新生代以来,强烈而频繁的火山活动铸成了长白山火山的主体——白头山火山锥。近几年来,从火山学和火山灾害学角度在该区进行研究和调查所获得的资料发现,长白山天池地区在全新世至少有六期火山活动在地表留下了记录。除白云峰期和八卦庙期喷发出大量碱流岩质浮岩形成的火山碎屑流造成了严重的火山灾害之外,其他四次喷发的规模均较小、影响面不大。老虎洞期活动发生在浮岩喷发之前,主要产物为玄武质火山渣和熔岩;气象站期喷发可能是该火山近期活动的表现,以碱流岩喷溢为主。这些喷发活动证实,该区近代火山活动不仅从未停止过,相反,活动的频度却逐渐加大。     

Petrology and geochemistry of Camiguin Island, southern Philippines: insights to the source of adakites and other lavas in a complex arc setting

Camiguin is a small volcanic island located 12 km north of Mindanao Island in southern Philippines. The island consists of four volcanic centers which have erupted basaltic to rhyolitic calcalkaline lavas during the last ∼400 ka. Major element, trace element and Sr, Nd and Pb isotopic data indicate that the volcanic centers have produced a single lava series from a common mantle source. Modeling results indicate that Camiguin lavas were produced by periodic injection of a parental magma into shallow magma chambers allowing assimilation and fractional crystallization (AFC) processes to take place. The chemical and isotopic composition of Camiguin lavas bears strong resemblance to the majority of lavas from the central Mindanao volcanic field confirming that Camiguin is an extension of the tectonically complex Central Mindanao Arc (CMA). The most likely source of Camiguin and most CMA magmas is the mantle wedge metasomatized by fluids dehydrated from a subducted slab. Some Camiguin high-silica lavas are similar to high-silica lavas from Mindanao, which have been identified as “adakites” derived from direct melting of a subducted basaltic crust. More detailed comparison of Camiguin and Mindanao adakites with silicic slab-derived melts and magnesian andesites from the western Aleutians, southernmost Chile and Batan Island in northern Philippines indicates that the Mindanao adakites are not pure slab melts. Rather, the CMA adakites are similar to Camiguin high-silica lavas which are products of an AFC process and have negligible connection to melting of subducted basaltic crust. Received: 27 February 1998 / Accepted: 27 August 1998     

Facies architecture of the felsic lava‐dominated host sequence to the Thalanga massive sulfide deposit,Lower Ordovician,northern Queensland

The Thalanga volcanic‐hosted massive sulfide deposit occurs in the Cambro‐Ordovician Mt Windsor Subprovince in northern Queensland. The orebody comprises steeply dipping, stratiform, sheet‐like, polymetallic massive sulfide lenses. Overall, the volcanic facies architecture at Thalanga is dominated by quartz‐ and/or feldspar‐phyric lavas and synvolcanic intrusions that comprise coherent facies and in situ and resedimented autoclastic facies. Systematic phenocryst logging (mineralogy, abundance, size) has been used to discriminate separate emplacement units of rhyolite in the footwall and dacite in the hangingwall. Some of the petrographically different rhyolite and dacite types can also be distinguished using immobile‐element geochemistry. Rhyolitic lavas and intrusions in the footwall are weakly to strongly altered. Apparent clastic textures resulting from hydrothermal alteration and metamorphism are widely developed in the coherent facies. Genuine clastic textures are characterised by clasts with randomly oriented internal laminar or banded fabric (e.g. rotated, flow‐laminated clasts), marked and consistent differences in quartz phenocryst abundance and/or size range between clasts and matrix, and normal grading. Mass‐flow‐emplaced, rhyolitic breccia units delineate palaeo‐sea‐floor positions in the footwall that are potentially prospective for exhalative massive sulfide mineralisation. A comparison of the distribution of clastic and coherent facies with the geometry of strongly altered zones in the footwall indicates that intense hydrothermal fluid flow was independent of the facies arrangement. The massive sulfide lenses conformably overly altered footwall rhyolite and occur in a distinctive facies association which includes coarse quartz‐phenocryst‐rich rhyolitic sills with peperitic contacts and crystal‐rich polymictic breccia. The hangingwall to the orebody consists of largely unaltered dacitic lavas and synvolcanic intrusions and minor dacitic pumice breccia, dacitic breccia and polymictic volcanic breccia. The facies architecture shows that the Thalanga massive sulfide deposit formed in a below‐storm‐wave‐base depositional environment on top of an elevated, lava‐dominated, rhyolitic volcanic centre. A modern analogue for the setting of the Thalanga massive sulfide is the PACMANUS hydrothermal field on the crest of the dacite lava‐dominated Pual Ridge in the eastern Manus backarc basin (Papua New Guinea).     

The Stonyford Volcanic Complex: a Forearc Seamount in the Northern California Coast Ranges

Jurassic age volcanic rocks of the Stonyford volcanic complex(SFVC) comprise three distinct petrological groups based ontheir whole-rock geochemistry: (1) oceanic tholeiites; (2) transitionalalkali basalts and glasses; (3) high-Al, low-Ti tholeiites.Major and trace element, and Sr–Nd–Pb isotopic dataindicate that the oceanic tholeiites formed as low-degree partialmelts of normal mid-ocean ridge basalt (N-MORB)-source asthenospheresimilar in isotope composition to the East Pacific Rise today;the alkalic lavas were derived from an enriched source similarto that of E-MORB. The high-Al, low-Ti lavas resemble second-stagemelts of a depleted MORB-source asthenosphere that formed bymelting spinel lherzolite at low pressures. Trace element systematicsof the high-Al, low-Ti basalts show the influence of an enrichedcomponent, which overprints generally depleted trace elementcharacteristics. Tectonic discrimination diagrams show thatthe oceanic tholeiite and alkali suites are similar to present-daybasalts generated at mid-oceanic ridges. The high-Al, low-Tisuite resembles primitive arc basalts with an enriched, alkalibasalt-like overprint. Isotopic data show the influence of recycledcomponents in all three suites. The SFVC was constructed ona substrate of normal Coast Range ophiolite in an extensionalforearc setting. The close juxtaposition of the MORB-like olivinetholeiites with alkali and high-Al, low-Ti basalts suggestsderivation from a hybrid mantle source region that includedMORB-source asthenosphere, enriched oceanic asthenosphere, andthe depleted supra-subduction zone mantle wedge. We proposethat the SFVC formed in response to collision of a mid-oceanridge spreading center with the Coast Range ophiolite subductionzone. Formation of a slab window beneath the forearc duringcollision allowed the influx of ridge-derived magmas or themantle source of these magmas. Continued melting of the previouslydepleted mantle wedge above the now defunct subduction zoneproduced strongly depleted high-Al, low-Ti basalts that werepartially fertilized with enriched, alkali basalt-type meltsand slab-derived fluids. KEY WORDS: CRO; oceanic basalts; California     

The Dir-Utror metavolcanic sequence,Kohistan arc terrane,northern Pakistan

The Dir-Utror volcanic series forms a NE–SW trending belt within the northwestern portion of the Kohistan island arc terrane in the western Himalayas of northern Pakistan. The Kohistan arc terrane comprises a diverse suite of volcanic, plutonic, and subordinate sedimentary rocks of late Mesozoic to Tertiary age, developed prior to and after suturing of the Indo-Pakistan and Asiatic continental blocks. The Dir-Utror volcanic series near Dir is dominated by basaltic-andesite and andesite, with subordinate basalt, high-MgO basalt, dacite, and rhyolite. Porphyritic textures are dominant, with less common aphyric and seriate textures. Plagioclase is the dominant phenocryst in mafic to intermediate rocks, K-feldspar and quartz phenocrysts predominate in the dacites and rhyolites. Chlorite, epidote, albite, and actinolite are the most common metamorphic phases; blue-green amphibole, andesine, muscovite, biotite, kaolinite, sericite, carbonate, and opaques are widespread but less abundant. Phase assemblages and chemistry suggest predominant greenschist facies metamorphism with epidote-amphibolite facies conditions attained locally.Whole rock major element compositions define a calc-alkaline trend: CaO, FeO, MgO, TiO₂, Al₂O₃, V, Cr, Ni, and Sc all decrease with increasing silica, whereas alkalis, Rb, Ba, and Y increase. MORB-normalized trace element concentrations show enrichment of the low-field strength incompatible elements (Ce, La, Ba, Rb, K) and deep negative Nb, P, and Ti anomalies—patterns typical of subduction related magmas. Mafic volcanic rocks plot in fields for calc-alkaline volcanics on trace element discrimination diagrams, showing that pre-existing oceanic crust is not preserved here. All rocks are LREE-enriched, with La=16–112×chondrite, La/Lu=2.6–9.8×chondrite, and Eu/Eu*=0.5–0.9. Dacites and rhyolites have the lowest La/Lu and Eu/Eu* ratios, reflecting the dominant role of plagioclase fractionation in their formation. Some andesites have La/Lu ratios which are too high to result from fractionation of the more mafic lavas; chondrite-normalized REE patterns for these andesites cross those of the basaltic andesites, indicating that these lavas cannot be related to a common parent.The high proportion of mafic lavas rules out older continental crust as the main source of the volcanic rocks. The scarcity of more evolved felsic volcanics (dacite, rhyolite) can be explained by the nature of the underlying crust, which consists of accreted intra-oceanic arc volcanic and plutonic rocks, and is mafic relative to normal continental margins. Andesites with high La, La/Lu, K₂O, and Rb may be crustal melts; we suggest that garnet-rich high-pressure granulites similar to those exposed in the Jijal complex may be restites formed during partial melting of the crust.     

相山流纹英安斑岩锆石SHRIMP U-Pb年龄及地质意义

相山火山杂岩位于北东向深断裂(永丰-抚州断裂带)和近南北向断裂带(宜黄-宁都断裂带)的交汇处。前人对其年代学已有过较为详尽的报道,但其定年方法多数精度不高。本文在前人的基础上利用SHRIMP测定了相山火山杂岩第一亚旋回中的流纹英安斑岩的锆石U-Pb年龄,并获得了一组很好的206Pb/238U加权平均年龄为136.6±2.7Ma(MSWD=1.8)。结合前人报道的相山火山杂岩年龄、野外岩石组合以及对定年方法精度的对比,我们确认:相山火山杂岩中的流纹英安斑岩的形成时间应该为早白垩世。     

Phosinaite,a new rare-earth mineral

Using geophysical data, we studied the mechanism of deep-seated magmatic and volcanic activity in the region of the island arcs and associated structures. Data on magmatic activity below the volcanic belt of East Kamchatka, obtained during geophysical investigations, mainly during detailed seismological investigations and deep seismic sounding, provide evidence for an association between the volcanoes and the processes in the Pacific Ocean focal layer of earthquakes, and for the accumulation of magmas below the volcanic belt at depths less than 60 km. We found anomalous columnar bodies more than 5 to 7 km across, linking the volcanoes with the focal layer, and a very large concentration of convective heat flow and volatiles in the magma columns feeding the volcanoes. As to the role of different forces in the uprise of magmas into the volcanoes, hydrostatic forces probably predominate in the asthenosphere, supplemented by tectonic pressure in the lithosphere and forces associated with boiling of magmas during release of volatiles in the crust, especially in its upper layers.—Author.