Archaean quartz arenites in the Canadian Shield: examples from the Superior and Churchill Provinces

Units of remarkably pure Archaean quartz arenite occur in the northwestern part of the Superior Province and in the northern terrane of the Western Churchill Province (Rae Province) of the Canadian Shield. In the Superior Province, silica-cemented quartz arenites of Archaean age are well preserved in several greenstone belts. The example from the Keeyask Lake sedimentary assemblage displays tabular–planar and trough cross-beds, ripple marks, reactivation surfaces and pebble lag deposits. In spite of penetrative deformation and greenschist-grade metamorphism, primary textures are extremely well preserved, showing framework grains to be very well rounded and sorted. The succession of Keeyask Lake quartz-arenite beds is overlain by siltstones containing small-scale stratiform, domal and columnar stromatolites. A shallow-marine environment of deposition is inferred. Detrital heavy minerals include pyrite, magnetite, zircon, tourmaline, apatite, sphene and topaz. In the northern part of the Western Churchill Province (Rae Province), Archaean quartz arenites occur in northeasterly trending belts where intense structural deformation has in most places obscured or obliterated primary textures and structures. This has led to speculation that some of these units are metachert or recrystallized vein quartz, but local preservation of primary textures and structures provides clear evidence of epiclastic origin. In the example described herein, quartz arenites of the Woodburn Lake Group display sparse occurrences of trough and tabular–planar cross-beds, channels, ripple marks and pebble lag deposits. Probable environments of deposition for these quartz arenites include fluvial systems and shallow-marine shelf settings. The occurrence of unequivocal quartz-arenite clasts in beds of intercalated conglomerate provides direct evidence of at least two episodes of accumulation of almost pure quartz sand. Thin sections and polished slabs reveal frameworks of clastic quartz grains with little to no matrix (now mainly muscovite), and rare detrital grains of accessory heavy minerals, predominantly zircon and opaque iron oxides. Pyrite and other sulphides have been introduced along fractures, but some intergranular sulphide grains may be of detrital origin. The principal source for the quartz arenites in both areas must have been quartz-rich granitoid rocks. Conditions of intense chemical weathering are indicated. The widespread occurrence of extremely mature quartz arenites throughout Archaean terranes of the Canadian Shield, and in other shields of the world, are suggestive of crustal stability during early Earth history. The association of quartz arenites and ultramafic rocks, uncharacteristic of younger terranes, is now recognized in many Archaean greenstone belts of the Canadian Shield.     

Climatic and tectonic influences on fan deltas and wave- to tide-controlled shoreface deposits: evidence from the Archaean Keskarrah Formation, Slave Province, Canada

The 2.6 Ga Keskarrah Formation, located in the central Slave Province, Northwest Territories, Canada, is a late-orogenic, tectonically controlled sedimentary sequence that developed under unusual climatic and depositional conditions. The formation is adjacent to the crustal-scale, north-trending Beniah Lake Fault and overlies the 3.15 Ga Augustus Granite, the 2.69–2.7 Ga mafic volcanic Peltier Formation and the turbiditic Contwoyto Formation unconformably. Principal lithofacies in the Keskarrah Formation include conglomerate, sandstone and siltstone–sandstone. The conglomerate lithofacies represents coalescing gravelly streamflow-dominated fan deltas adjacent to topographic highs. Up-section quartz-rich arenites and quartz arenites of the sandstone lithofacies are interpreted to be shallow-water shoreface deposits influenced by wave action and tides. The overlying feldspathic litharenites of the siltstone–sandstone lithofacies are consistent with a lower shoreface to proximal offshore environment dominated by wave and tide interaction. Tidal influence in both sandstone-dominated lithofacies is inferred from the presence of mudstone laminae between bedforms and on foresets of cross-beds, as well as from abundant reactivation surfaces with local mudstone drapes. Intense chemical weathering during the Archaean, resulting from elevated atmospheric levels, higher temperatures and moist climatic conditions, played an important role in the development of quartz-rich arenites that appear to be first-cycle deposits. Few lithic fragments and feldspar grains are preserved due to in-situ host rock weathering, chemical weathering during transport and wave and tide action. Hydraulic sorting and abrasion in the shoreface environment contributed to the continued breakdown and transport of labile minerals. Increased proportions of lithic fragments in sandstone beds of the conglomerate lithofacies are the result of shorter transport distances from source areas to the depositional environment. Abundant conglomerate with up to 4-m large granitic boulders derived from the adjacent Augustus Granite and mafic clasts from the Peltier Formation indicate high relief and fault-related uplift and subsidence. The intimate association of fan deltas and wave- and tide-influenced shallow-marine deposits in association with quartz-rich sandstones forming in a high-relief area make the Keskarrah Formation remarkable in the rock record.     

Proterozoic fluvial styles: response to changes in accommodation space (Rivieradal sandstones, eastern North Greenland)

Fluvial styles recorded by the uppermost part of the Neoproterozoic ‘Rivieradal sandstones' succession of eastern North Greenland reflect variations in rate of generated accommodation space and possibly climatic changes. Three facies associations, arranged in two genetic sequences, are recognised within the succession. The lower sequence initially records little available accommodation space. A high degree of reworking results in sheet-like, high-energy, bed-load-dominated, braided river deposits lacking recurrent facies patterns. As accommodation space increases upwards through the sequence, reduction in reworking is recorded by the development of fining- and thickening-upward muddy fluvial cycles. Evidence of desiccation or prolonged periods of drought are absent within the deposits and climate was probably relatively humid. Channel deposits in the lower sequence reflect mixed-load, braided fluvial systems with stable channel banks and floodplains, and the gradient appears to have been low to moderate. These features are generally considered favourable for the establishment of meandering river systems, but channels, nevertheless, retained an overall braided character and their deposits show no evidence of meandering. Despite indications of a climatic setting without significant periods of drought sediments indicate that large fluctuations in discharge occurred within the mixed-load streams and this is suggested to be the main cause for the absence of meandering. The swift and rather dramatic response of the fluvial systems to changes in precipitation, probably resulted from rapid runoff rates caused by the absence of vegetation. The upper sequence shows an initial return to shallow, sandy braided river deposition recording little available accommodation space. A subsequent increase in the rate of generated accommodation space is indicated by the presence of alternating sheet sandstones and sand-streaked mudstones with abundant desiccation cracks. The sheet sandstones show evidence of high-energy, unconfined ephemeral fluvial flash-flood deposition, while the mudstones are interpreted to represent muddy floodplain deposits. The change in fluvial style, combined with the widespread evidence of desiccation, suggest an evolution towards a more semi-arid climate in the upper sequence. This climatic change could account for the reduced clastic input seen in the overlying marine succession which culminated in carbonate platform deposition. The present study suggests that even under conditions considered favourable for the formation of meandering streams, these will rarely occur in Proterozoic deposits due to the lacking influence of vegetation. Although meandering deposits cannot be ruled out as having formed in pre-vegetational times, the conditions for their formation appear to have been even more restricted than previously realised.     

Preservation of pre-vegetational mixed fluvio–aeolian deposits in a humid climatic setting: an example from the Middle Proterozoic Eriksfjord Formation, Southwest Greenland

Sedimentological studies of a 30 m thick coastal cliff section within the Middle Proterozoic Eriksfjord Formation in western South Greenland reveals three distinct types of fluvial sand sheet deposits that reflect perennial streams (Type I), semi-perennial streams (Type II), and ephemeral flash floods (Type III). Perennial river sand sheets are characterised by co-sets of medium-scale trough cross-beds, interbedded with isolated medium- and large-scale, high-angle, tabular cross-beds. Indications of desiccation or subaerial exposure are absent. Semi-perennial fluvial sand sheets consist predominantly of low-angle cross-beds, interbedded with isolated sets of high-angle tabular cross-beds with common reactivation surfaces. Horizontal lamination and climbing ripple lamination form subordinate structures. Associated with the sand sheets are adhesion structures and 0.05–0.4 m thick sets of wind ripple-lamination indicating periods of subaerial exposure and aeolian reworking. High-energy ephemeral flash flood sand sheets consist almost exclusively of planar-parallel lamination and climbing ripple lamination with some isolated sets of low-angle cross-bedding. Scouring and internal truncation surfaces are common. The three types of sand sheets are considered to reflect deposition under changing climatic conditions, varying from humid to arid or semi-arid. Aeolian deposits are preserved within the sand sheets showing characteristics of dominantly perennial flow punctuated by shorter periods of desiccation (Type II), while sand sheets showing features typical of arid and or semi-arid flow conditions (Type III) contain no preserved aeolian deposits. This selective preservation is interpreted to be a result of the combined effect of groundwater table level and fluvial style which in turn are inferred to have been controlled by the climatic regime. The deposits show that during pre-vegetational times the preservation of aeolian deposits, under certain conditions, may be more optimal in fluvial systems formed in a humid climate than in fluvial systems formed under semi-arid or arid circumstances. The occurrence of aeolian deposits within a Precambrian succession of fluvial deposits therefore, need not be an indication of the most arid environmental conditions.     

Contourites associated with pelagic mudrocks and distal delta-fed turbidites in the Lower Proterozoic Timeball Hill Formation epeiric basin (Transvaal Supergroup), South Africa

Five genetic facies associations/architectural elements are recognised for the epeiric sea deposits preserved in the Early Proterozoic Timeball Hill Formation, South Africa. Basal carbonaceous mudrocks, interpreted as anoxic suspension deposits, grade up into sheet-like, laminated, graded mudrocks and succeeding sheets of laminated and cross-laminated siltstones and fine-grained sandstones. The latter two architectural elements are compatible with the Te, Td and Tc subdivisions of low-density turbidity current systems. Thin interbeds of stromatolitic carbonate within these first three facies associations support photic water depths up to about 100 m. Laterally extensive sheets of mature, cross-bedded sandstone disconformably overlie the turbidite deposits, and are ascribed to lower tidal flat processes. Interbedded lenticular, immature sandstones and mudrocks comprise the fifth architectural element, and are interpreted as medial to upper tidal flat sediments. Small lenses of coarse siltstone–very fine-grained sandstone, analogous to modern continental rise contourite deposits, occur within the suspension and distal turbidite sediments, and also form local wedges of inferred contourites at the transition from suspension to lowermost turbidite deposits. Blanketing and progressive shallowing of the floor of the Timeball Hill basin by basal suspension deposits greatly reduced wave action, thereby promoting preservation of low-density turbidity current deposits across the basin under stillstand or highstand conditions. A lowstand tidal flat facies tract laid down widespread sandy deposits of the medial Klapperkop Member within the formation. Salinity gradients and contemporaneous cold periglacial water masses were probably responsible for formation of the inferred contourites. The combination of the depositional systems interpreted for the Timeball Hill Formation may provide a provisional model for Early Proterozoic epeiric basin settings.     

The importance of air escape processes in the formation of dish-and-pillar and teepee structures within modern and Precambrian fluvial deposits

Attributed to escape of water from unconsolidated deposits, teepee and dish-and-pillar structures are common features in the Late Proterozoic Torridonian red bed succession of NW Scotland. Study of the first annual flood on a modern depositional analogue, in Wadi Baysh, Saudi Arabia, revealed that a layer of mud, initially deposited across the alluvium, restricted the escape of air being displaced through the normally unconfined aquifer by waters entering the aquifer from the river channels. As air bubbled through high level pool-floor muds, it generated dish-and-pillar structures. The formation of teepee structures by similarly combined air and water escapes nearer to the channel later in the annual cycle of flooding is foreseen. It is suggested that the two sediment structures are generated in response to different parts of the aquifer recharge spectrum. The role of air displacement by influent waters is important in the initial phases of structure formation, and combined air and water escape creates greater disturbance to the sediments. The sedimentary structures formed are not, therefore, solely due to water escape, as has been previously suggested. Ephemeral seasonal flooding appears to have characterized the deposition of at least the Stoer Group and Diabaig Formation sediments in the Torridonian.     

Precambrian tidal and glacial clastic deposits: implications for Precambrian Earth–Moon dynamics and palaeoclimate

Over the past decade the study of Precambrian clastic tidal rhythmites — stacked laminae of sandstone, siltstone and mudstone that display periodic variations in thickness reflecting a strong tidal influence on sedimentation — has provided accurate palaeotidal and palaeorotational data. Palaeotidal records obtained from tidal rhythmites may be systematically abbreviated, however, and derived periods and frequencies can be misleading. The validity of such values, including past length of day, can be assessed by testing for internal self-consistency through application of the laws of celestial mechanics. Such a test supports the estimated length of day of h derived from the late Neoproterozoic (620 Ma) Elatina–Reynella rhythmites in South Australia, and the indicated mean rate of lunar retreat of cm/year since 620 Ma. The validity of estimated lengths of day obtained from other Precambrian tidal rhythmites remain unverified because the data sets contain only one primary value directly determined from the rhythmites. The Elatina–Reynella data militate against significant Earth expansion at least since 620 Ma, and suggest that the free nutation or ‘tipping' of the Earth's fluid core has undergone a resonance with the Earth's annual forced nutation since the Neoproterozoic. Glaciogenic deposits are readily distinguishable from ejecta resulting from impacts with Earth-crossing bodies. Palaeomagnetic data, based on the geocentric axial dipole model for the geomagnetic field, indicate that Neoproterozoic and Palaeoproterozoic glaciation and cold climate near sea level occurred in low palaeolatitudes. This enigmatic finding may imply global glaciation or an increased obliquity of the ecliptic, and is relevant to modelling the effect of ice sheet formation on the Earth's obliquity history by obliquity–oblateness feedback mechanisms. Through multidisciplinary studies, clastic sedimentology and geophysics together can make substantial contributions to understanding Precambrian Earth–Moon dynamics and global palaeoenvironments.     

Late-orogenic basins in the Archaean Superior Province, Canada: characteristics and inferences

The late-orogenic Archaean Duparquet, Kirkland and Stormy basins of the Canadian Superior Province are characterized by bounding crustal-scale faults and abundant porphyry stock emplacement. Lava flows and pyroclastic deposits are restricted to the Kirkland and Stormy basins, and coarse clastic detritus characterizes the Duparquet basin. Seven distinct lithofacies are identified: (1) mafic volcanic, (2) felsic volcanic, (3) pyroclastic, (4) volcaniclastic, (5) conglomerate-sandstone, (6) sandstone-argillite  conglomerate), and (7) argillite-sandstone  tuffaceous sandstone). The mafic and felsic volcanic lithofacies represent effusive lava flows, the pyroclastic lithofacies is formed of subaerial surge and airfall deposits and the volcaniclastic lithofacies is composed of reworked volcanic debris. The conglomerate-sandstone lithofacies is interpreted as alluvial fan, fan delta or proximal braided stream deposits, whereas the sandstone-argillite lithofacies is consistent with sandy-dominated flood- or braidplain deposits. A dominantly shallow-water lacustrine setting is inferred for the argillite-sandstone lithofacies. These different lithofacies record the basin history and can be used to identify basin-forming processes. Lithofacies stacking and rapid lateral changes of lithological units in conjunction with interformational unconformities and basin margin faults suggest tectonically induced sedimentation. Volcanism can also influence basin evolution and the delicate balance between erosion, sedimentation, and prevalent transport processes is affected by volcanic input. Catastrophic influx of pyroclastic material facilitated mass-wasting processes and formation of non-confined hyperconcentrated flood flow deposits account for local congestion of alluvial or fluvial dispersal patterns. Confined stream flow processes govern sedimentation during intravolcanic phases or prominent tectonic uplift. In addition, climate which controls the weathering processes, and vegetation which stabilizes unconsolidated material, affects the transport and depositional process. A CO₂-rich aggressive weathering, humid Archaean atmosphere favours traction current deposits and an absence of vegetation promotes rapid denudation. Although tectonism is the prevalent long-term controlling factor in restricted basins, the effects of volcanism, climate and lack of vegetation can also be detected.     

Controls on spatial and temporal distribution of Precambrian eolianites

Inversely graded stratification, generated by the migration of wind ripples, and adhesion structures permit unequivocal identification of Precambrian eolianites. These criteria, in combination with scale of cross-beds, angle of inclination of foresets, geometry of depositional units, and associated non-eolian facies, are used to discriminate between Precambrian dune/draa, dune-plinth, sand-sheet, and interdune deposits that formed in inland and coastal settings. Based on an analysis of published literature, fundamental conclusions can be drawn on the spatial and temporal distribution of Precambrian eolianites. The oldest reported eolianites are from the ca. 2.1 Ga Deweras Group in Zimbabwe and Hurwitz Group in Canada and numerous examples of eolianites are reported from the 1.8 Ga and younger rock record. Lack of Archean and early Paleoproterozoic eolianites and their widespread development after 1.8 Ga are examined with respect to: absence of vegetation, crustal growth and tectonic setting, relative sea-level fluctuations, unfavorable atmospheric and/or climatic change, and non-recognition. The lack of pre-2.2 Ga eolianites may be related to reworking by braided rivers combing across non-vegetated floodplains, reworking of coastal eolianites during transgression or their non-recognition in the Early Precambrian record. The temporal concentration of eolianites at 1.8 Ga may best be related to the early stages of breakup and the assembly phases of supercontinents.     

Impressions of algal mats from the Middle Proterozoic Belt Supergroup, northwestern Montana, U.S.A.

Irregular, low relief bedding-plane markings which probably represent impressions of thin, wrinkled algal mats have recently been detected in mudstones from the 1100 m.y. old Snowslip Formation, Belt Supergroup, Glacier National Park, Montana. Algal-mat impressions are rarely reported from ancient strata, yet algal mats are common in certain modern environments. Originating primarily in moist settings and in relatively quiescent shallow-water settings, such structures may be of some value in interpreting ancient depositional environments.     

Neoproterozoic trace fossils vs. microbial mat structures: Examples from the Tandilia Belt of Argentina

The Tandilia Belt in northeast Argentina includes a Neoproterozoic sequence of sediments (Sierras Bayas Group), in which the Cerro Largo Formation, ca. 750 Ma in age, forms a siliciclastic, shallowing upward succession of subtidal nearshore to tidal flat deposits. Trace fossils Palaeophycus isp. and Didymaulichnus isp. have been described from the upper part of this succession. Specific sedimentary structures consisting of round-crested bulges, arranged in a reticulate pattern, and networks of curved cracks are associated with the trace fossils. These structures are considered to be related to epibenthic microbial mats that once colonized the sediment surface. They reflect stages of mat growth and mat destruction, if compared to analogous structures in modern cyanobacterial mats of peritidal, siliciclastic depositional systems. Also the trace fossils are interpreted as mat-related structures, partly forming components of networks of shrinkage cracks, partly representing the upturned and involute margins of shrinkage cracks or circular openings in desiccating and shrinking, thin microbial mats.

The definition of Didymaulichnus miettensis Young as a Terminal Proterozoic trace fossil is questioned, and it may be considered to interpret the ‘bilobate’ structure as the upturned, opposite margins of microbial shrinkage cracks which have been brought back into contact by compaction after burial.     

Large-scale distribution of metal contamination in the fine-grained sediments of the Clark Fork River,Montana, U.S.A.

Historic discharges from the mining and smelting complex at the head-waters of the Clark Fork River have resulted in elevated Ag, Cd, Cu, Pb and Zn concentrations in the <60 μm fraction of both bed and flood-plain sediments of the river. Processes affecting the trends in longitudinal distributions of these metals were investigated by repeated sampling over a 380 km river reach between August 1986 and July 1989. At the most upstream site, bed-sediment metal concentrations were enriched 18–115 times above least enriched tributaries, depending on the metal. All metals decreased exponentially with distance downstream away from mining. The exponential model predicts that elevated metal concentrations should occur over 550 km downstream, in Lake Pend Oreille. Longitudinal trends, obvious on a scale of hundreds of kilometers, were obscured by small-scale spatial variability when shorter stretches of the river were considered. Longitudinal dispersion appeared to be controlled largely by physical dilution with less-contaminated sediments.Evidence suggests that erosion of contaminated flood-plains contributes to metal contamination in the bed sediments. Tributary input appeared to have little influence on the large-scale, downstream distribution of metals; however, it did contribute to local variability in bed-sediment metal concentrations. Association of metals with specific mineral grains, as well as variability in total organic C and Fe concentration, appeared also to contribute to variability.Some year-to-year variability in bed-sediment metal concentrations was observed, however, trends in longitudinal dispersion were not significantly different between at least two of the years sampled.     

Grain size partitioning of metals in contaminated,coarse-grained river floodplain sediment: Clark Fork River,Montana, U.S.A.

The traditional concept of the relationship between metal content and grain size assumes that the fine fraction carries most of the metals in natural sediments. This concept is supported in many cases by strong, significant linear relationships between total-sediment metal concentrations and percentages of various fine-size fractions. Such observations have led to development of methods to correct for the effects of grain size in order to accurately document geographical and temporal variations and identify trends in metal concentrations away from a particular source. Samples from the floodplain sediment of a large, coarse-grained river system indicates that these concepts do not hold for sediments contaminated by mining and milling wastes. In this particular system, the application of methods to correct for grain-size effects would lead to erroneous conclusions about trends of metals in the drainage. This indicates that the a priori application of grain-size correction factors limits interpretation of actual metal distributions and should not be used unless data indicate that correlations exist between metals and particular size fractions.     

Gahnite in the metamorphosed stratiform massive sulfide deposits of the Mineral District,Virginia, U.S.A.

Summary Ferroan-gahnite, (Zn,Fe)Al₂O₄, is a common accessory mineral found in association with the metamorphosed volcanogenic massive sulfide ore bodies of the Mineral District, Virginia. Gahnite is present throughout the mineralized zones that contain pyrite, sphalerite, chalcopyrite, and sulfosalts. Although constituting only 1–2 modal percent of most samples and displaying not well-defined distribution pattern, gahnite is especially abundant at the margins of the mineralized zones and locally constitutes as much as 35 modal percent. The compositions vary slightly from one deposit to another but all lie within the range of 68 to 88 mol.% gahnite (ZnAl₂O₄), 8 to 25 mol.% hercynite (FeAl₂O₄), and 1–17 mol.% spinel (MgAl₂O₄). Gahnite occurs within a wide variety of mineral assemblages, with or without coexisting sphalerite.The reflectance and unit cell dimension are sensitive to composition and decrease with increasing gahnite component. The approximate 8% reflectance at 540 nm is intermediate between most silicates and ore minerals such as sphalerite and magnetite and thus provides a ready method for recognition in reflected light. The gahnite is believed to have formed during amphibolite grade regional metamorphism as a result of either sphalerite desulfidation or the reaction of original zinc oxide phases.

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Gahnit in metamorphen schichtgebundenen Sulfid-Lagerstätten des Mineral-Distriktes, Virginia, U.S.A.

Zusammenfassung Eisenhaltiger Gahnite (Zn,Fe)Al₂O₄ ist in den metamorphen vulkanogenen massiven Sulfiderzkörpern Virginias als akzessorisches Mineral weit verbreitet. Er kommt durchwegs in den Pyrit, Zinkblende, Kupferkies und Sulfosalze enthaltenden mineralisierten Zonen vor. Obwohl die meisten Proben nur 1–2 Modal % Gahnit enthalten, und keine klar definierte Verteilung zu erkennen ist, tritt er besonders häufig an den Rändern der mineralisierten Zonen auf und erreicht lokal 35 Modal %. Die Zusammensetzung schwankt leicht von Vorkommen zu Vorkommen, liegt aber stets zwischen 68 und 88 Mol.% Gahnit (ZnAl₂O₄) 8 und 25 Mol.% Hercynit (FeAl₂O₄) und 1 und 17 Mol.% Spinell (MgAl₂O₄) Gahnit ist Bestandteil sehr verschiedener Mineralparagenesen mit und ohne Zinkblende.

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With 7 Figures     

Geochemical signature of provenance in sand-size material in soils and stream sediments near the Tobacco Root batholith, Montana, U.S.A.

Trace-element geochemistry of sandstones are being used to determine provenance. We have conducted preliminary and limited experiments to determine to what extent daughter sands retain the geochemical signature of parent rocks. Six sets of first-order stream sediments, soils from adjacent slopes, and a variety of parent rocks were collected from southwestern Montana, U.S.A. Sampling in a low-relief area ensured that climate and residence time of soils on slopes could be eliminated as variables. Sand-size fractions of stream sediments and soils, and the corresponding parent rocks (granodiorite, quartz monzonite, granite gneiss, biotite-tonalite gneiss and amphibolite) were analyzed for most major elements and selected trace elements. Petrologic modal analysis of the parent rocks and the 0.25–0.50-mm fraction of each sand was done to monitor major mineralogic control, if any, on chemical compositions of the samples.

Our data show that the abundances of the Si and Al in sediments do not discriminate provenance. Abundances of Ca, Mg, Fe and Ti may broadly distinguish between sands derived from metamorphic and igneous source rocks, at least in the area studied. Differences in abundances of the Ba and Th, and the ratio of La/Lu between granitic, tonalitic and amphibolitic parent rocks are preserved in the daughter sediments that we studied. However, the size of the Eu anomaly in the REE patterns of different daughter sediments is not diagnostic of parent rocks. Abundances of Co and Sc distinguish between sediments derived from felsic and mafic rocks. A better provenance discrimination is obtained if the ratios La/Sc, Th/Sc, La/Co, Ba/Sc and Ba/Co are used.

Petrologic modal data show that mineral contents and chemical compositions of parent rocks are compatible with each other. The chemical composition of the sands may be roughly correlated to the petrological modal data but the abundances of some minor and trace elements of sediments cannot be inferred from modal mineralogy. This is expected because these elements may concentrate in accessory minerals and/or may weather out into aqueous or clay mineral fractions; it is also compatible with conclusions of previous studies that some of these elements do not reside in sand-size fractions of siliciclastic sediments.     

Use of tourmaline in stream sediments to detect submarine exhalative sulfide deposits: example from central Virginia,U.S.A.

The detection of several unmined submarine exhalative sulfide deposits, most of which are concealed with no surface expression, was investigated using the distribution grain counts of tourmaline in stream sediment concentrates. The number of sulfide zones located using this method is comparable to that achieved using trace metal nalyses of fine-grained stream sediment andMnz.sbnd;Fe oxide coatings on stream pebbles. Because both dravite, associated with a sulfide zone, and schorl, from a pegmatite, are known to occur in the field area, it is likely that both will occur in stream sediment and will be included in tourmaline-grain-counts of sediment concentrates. Attempts to differentiate dravite and schorl in the sediment concentrates, based on microscopically observable physical properties, were unsuccessful, but semi-quantitative chemical analyses should readily accomplish this because of large differences in Mg and Fe concentrations.     

Aeolian to marine transition in Cambro—Ordovician cratonic sheet sandstones of the northern Mississippi valley, U.S.A.

Cratonic quartz sandstones have presented several intractable problems. Besides their extreme textural and compositional maturity and paucity of shale, their sheet-like geometry is particularly notable. If the sandstones were entirely marine, as long supposed, such geometry is difficult to explain in terms of modern shelf sediments, which are generally held to be either relict or only slightly reworked by the Holocene transgression (palimpsest). Re-study of two quartz sandstones in the northern Mississippi Valley region reveals evidence for significant non-marine deposition followed by varying degrees of marine reworking during transgressions. Facies patterns are similar in the Cambrian Wonewoc and Ordovician St Peter sandstones, both of which overlie unconformities. In both, a large-scale cross-stratified facies believed to represent aeolian ergs passes laterally into a planar-and-channelled facies inferred to represent sand plains composed of braided fluvial and aeolian sand sheet deposits. Criteria of aeolian deposition in both facies include adhesion structures, large ripple index, fine climbing translatent lamination, grainfall and grainflow stratification. Criteria of braided fluvial deposition include shallow channels containing sequences of thinning-upward sets of trough cross-stratification, reactivation surfaces, low-index ripples, and polygonal cracks. Probable aeolian sand sheets contain flat bedding punctuated by small channels, adhesion structures, and coarse-sand ripples with large index. There is a conspicuous absence of trace and body fossils from these inferred non-marine deposits. In contrast is a burrowed and trough cross-stratified facies characterized by medium-scale cross-bedding alternating with bioturbated intervals and rare brachiopod or trilobite-mould coquinas, which is interpreted as shallow marine. In both formations, this last facies replaces laterally and overlaps the other two, reflecting transgression and variable reworking. The main areas of non-marine deposits in both formations are capped by a thin, burrowed subfacies that represents the culmination of each transgression; that is, a stillstand during which sediment influx ceased and both physical winnowing and bioturbation were intense. It is suggested that the sheet-like geometry of many cratonic quartz sandstones is due primarily to initial sand dispersal by aeolian and fluvial processes. That such processes must have been orders-of-magnitude more important on pre-Devonian, vegetation-free landscapes than they have been since, not only helps to explain the sheet-like character but also the exceptional maturity of the older cratonic sandstones.     

Residence of silver in mineral deposits of the Thunder Mountain caldera complex,Central Idaho,U.S.A.

Summary Silver is an accessory element in gold, antimony, and tungsten deposits of the caldera complex. Most of the deposits are economically of low grade and genetically of xenothermal or epithermal character. Their gold- and silver-bearing minerals are usually disseminated, fine grained, and difficult to study. Sparsely disseminated pyrite and arsenoprite are common associates.Identified silver minerals are: native silver and electrum; the sulfides acanthite, argentite (the latter always inverted to acanthite), and members of the Silberkies group; the sulfosalts matildite, miargyrite, pyrargyrite, argentian tetrahedrite, and unnamed Ag-Sb-S and Ag-Fe-Sb-S minerals; the telluride hessite and the selenide naumannite; halides of the cerargyrite group; and the antimonate stetefeldtite. Suspected silver minerals include the sulfide uytenbogaardtite and the sulfosalts andorite, diaphorite, and polybasite. Electrum, acanthite, and argentian tetrahedrite are common, though nowhere abundant. The other silver minerals are rare.Silver is present as a minor element in the structure of some varieties of other minerals. These include arsenopyrite, chalcopyrite, chalcostibite, covelline, digenite, galena, sphalerite, and stibnite. The search for adventitious Ag in most of these minerals has been cursory. The results merely indicate that elemental silver is not confined to discrete silver minerals and is, therefore, an additional complication for the recovery of silver-bearing material from some deposits.Silver occurs cryptically in some plants of the region. At Red Mountain, for example, the ashed sapwood of Douglas-fir (Pseudotsuga menziesii) contains 2 to 300 ppm Ag. Silver in the ashed wood is roughly 100 times as abundant as it is in soil. The phenomenon, useful in biogeochemical exploration, deserves the attention of mineralogists.

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Das Vorkommen von Silber in den Erzlagerstätten des Thunder-Mountain-Caldera-Komplexes, Idaho, U.S.A.

Zusammenfassung Silber ist in den Gold-, Antimon- und Wolframlagerstätten des Caldera-Komplexes ein akzessorisches Element. Die Lagerstätten sind wirtschaftlich geringhaltig und genetisch als xeno- oder epithermal zu deuten. Gold- und silberführende Minerale sind meist feinkörnig und treten akzessorisch auf. Im einzelnen wurden folgende Minerale beobachtet: Gediegen Silber und Elektrum; die Sulfide Akanthit und Argentit (immer zu Akanthit umgewandelt) sowie Silberkiese; die Sulfosalze Matildit, Miargyrit, Pyrargyrit, silberhaltiger Tetraedrit und nicht näher identifizierte Ag-Sb-S- und Ag-FeSb-S-Verbindungen; das Tellurid Hessit und das Selenid Naumannit; Halogenide der Kerargyritgruppe; und das Antimonat Stetefeldit. Mögliche weitere Ag-Minerale schließen das Sulfid Uytenbogaardtit und die Sulfosalze Andorit, Diaphorit und Polybasit ein. Von diesen Mineralen kommen Elektrum, Akanthit und silberhaltiger Tetraedrit am häufigsten vor, während alle anderen selten sind. Die gewöhnlichen Nebengemengteile sind Pyrit und Arsenkies.Darüber hinaus wird vermutet, daß Spuren von Silber im Kristallgitter anderer Minerale eingebaut vorliegen; insbesondere in den Gittern von Arsenkies, Kupferkies, Chalcostibit, Covellin, Digenit, Bleiglanz, Zinkblende und Antimonit. Hierzu liegen noch keine umfassenden Untersuchungen vor, jedoch kann vermutet werden, daß Silber nicht ausschließlich auf Ag-Minerale sensu stricto beschränkt ist.Einige Pflanzen des Lagerstättenbezirkes enthalten beachtliche Mengen an Silber, so zum Beispiel die Asche der Douglas-FichtePseudotsuga menziesii. Der Silbergehalt beträgt 2 bis 300 g/t und ist damit gegenüber dem Boden etwa 100fach erhöht. Dieses Phänomen ist von Nutzen in der biogeochemischen Exploration und verdient das Interesse der Mineralogen.

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With 10 Figures

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Contribution to the Ore Mineralogy Symposium (IMA/COM) at the 14th General Meeting of the International Mineralogical Association, at Stanford, California, in July, 1986.     

Soil geochemistry of Mother Lode-type gold deposits in the Hodson mining district, central California, U.S.A.

The Hodson mining district is in the westernmost foothills of the Sierra Nevada in California, about 17 km west of the town of Angels Camp. This district is part of the West Gold Belt, which lies about 12–16 km west of, and generally parallel to, the better known Mother Lode Gold Belt in central California. The district produced several million dollars worth of Au between about 1890 and 1940.     

Evaluation of biogeochemical prospecting methods in the search for sulfide deposits in the Appalachian piedmont, Virginia, U.S.A.

Soil and stream sediment sampling have been the primary geochemical exploration tools in the Appalachian piedmont to date. However, the great thicknesses of soil and saprolite found in the region coupled with the dense vegetation frequently encountered favor biogeochemistry as an alternative or supplemental method since deep-rooted plants sample closer to bedrock. To evaluate this method, an orientation survey was performed in which soils and vegetation at 17 sites north of Mineral, Virginia, were sampled and analyzed for Ag, Cd, Cu, Pb and Zn. The traverse included stations over the host rocks of massive sulfide mineralization, as well as over apparent “barren” country rock. Samples were analyzed by atomic absorption spectrophotometry using standard digestion and analytical techniques.Both A- and B-horizon soil metals generally appear to be reliable indicators of mineralization, with soils developed over sulfides showing up to three-fold enrichment in metal content relative to the average soils developed on the country rock. Correlation of metal concentrations in vegetation to soil metal concentrations reveal plant concentrations expressed on a dry-weight basis correlate stronger and more frequently to soil metals than do ash-weight concentrations. Copper shows some promise in selected organs and species, Ag appears fair but data are limited to one organ of one species, and plant Pb seems totally unresponsive to soil metal concentrations perhaps because foliar absorption is an important plant uptake mechanism here. However, Zn and Cd in organs of the oak group, especially mature leaves and twigs of the current year's growth show the greatest promise as prospecting tools. They correlate well with soil metals and when compared directly to the geology they reliably reflect mineralization. Although results using White oak were slightly less profound than those obtained from the Black-Red oak group, White oak may be preferred as it is a single, more widespread, easily-identifiable species. Copper and especially Zn although essential elements to plants, do not appear to be “difficult” elements for biogeochemical prospecting in the Appalachian piedmont.