鄂尔多斯盆地东部太原组碎屑岩中自生伊利石形成机制及其对储层形成的影响

鄂尔多斯盆地东部太原组砂岩骨架颗粒中几乎没有碎屑长石,残余的微量长石(在岩石中的平均含量为0.4%.低于X射线衍射检测限)主要为钾长石,同时具有较低的自生高岭石含量(1.02%)、很低的自生石英含量和同期火山物质含量,以及较高的自生伊利石含量(1.22%),这表明太原组的自生伊利石主要是在相对高温的深埋藏封闭条件下,通过钾长石溶解反应:钾长石+H~++H_2O→高岭石+硅质+K~+和高岭石伊利石化反应:高岭石+K~+→伊利石+H~++H_2O或其加和反应:钾长石+高岭石→硅质+伊利石+H_2O形成,后者通过消耗钾离子而克服钾长石溶解的动力学屏障,是前者的重要驱动反应,并向流体输出氢离子,因此对次生孔隙的形成、尤其是在相对深埋藏的成岩过程中与钾长石溶解有关的次生孔隙的形成具有显著的积极作用.     

Kinetic Modeling of Diagenesis of Eogene Lacustrine Sandstone Reservoirs in the Jianghan Basin,Southeastern China

In the Tuoshi oilfield,located in the Cenozoic Jianghan Basin of southeastern China ,there have been found hydrocarbon reservoirs hosted in lacustrine sandstones of the Eogene Xingouzui Formation.The main diagenetic features identified in these sandstones include the dissolution of detrital K-feldspar and albite grains,the precipitation of quartz as overgrowths and /or cements ,and the precipitation and /or transformation of clay minerals.These diagenetic features were interpreted to have occurred in early,intermediate and late stages,based on the burial depth.The kinetics of fluid-mineral reactions and the concentrations of aqueous species au each stage of diagenesis were simulated numerically for these lacustrine sandstones,using a quasi-sta-tionary state approximation that incorporates simultaneous chemical reactions in a time-space continuum.During the early diagenetic stage,pore fluid was weakly acidic,which resulted in dissolution of K-feldspar and albite and,therefore,led to the release of K^ ,Na^ ,Al^3 and SiO2(aq) into the diagenetic fluid.The increased K^ ,Na^ ,Al^3 and SiO2(aq) concentrations in the diagenetic fluid caused the precipitation of quartz,kaolinite and illite.At the beginning of the intermediate diagenetic stage the concentration of H^ was built up due to the decomposition of organic matter,which was responsible for further dissolution of K-feldspar and albite and pre-cipitation of quartz,kaolinite,and illite.During the late diagenetic stage,the pore fluid was weakly alkaline,K-feldspar became stable and was precipitated with quartz and clay minerals.When the burial depth was greater than 3000 m,the pore fluids became supersaturated with respect to allbite,but undersaturated with respect to quartz,resulting in the precipitation of albite and the dissolution of quartz.The diagenetic reactions forecasted in the numerical modeling closely matched the diagenet-ic features identified by petrographic examination, and therefore,can help us to gain a better understanding of the diagenetic processes and associated porosity evolution in sandstone reservoirs.     

蒙脱石伊利石化的控制因素、转化机制及其转化模型的研究综述

蒙脱石伊利石化是近几十年来粘土矿物学研究的核心之一。本文综述了近年来蒙脱石伊利石化的研究进展，内容涉及影响控制蒙脱石伊利石化的主要因素，包括温度、时间、压力、孔隙流体的化学成分等；蒙脱石向伊利石转化的机制及动力学模拟；当前流行的几种蒙脱石伊利石化的转化模型。     

Diagenesis of the Lower Cretaceous Kanmon Group sandstones, SW Japan

The Kanmon Group (Lower Cretaceous) is a non-marine sequence in the Inner Zone of southwest Japan and is divided into the lower Wakino (lacustrine) and the upper Shimonoseki (fluvial) subgroups. Major diagenetic changes in this group are compaction, iron-oxide cementation, calcite cementation and grain replacement, quartz overgrowth and pore-fill cementation, illite authigenesis, chlorite pore-fill cementation and grain replacement, albitization of feldspar, and grain replacement by pyrite. Two subgroups of the Kanmon Group present no significant differences in general diagenetic features, paragenetic sequence, or the degree of diagenetic changes despite differences in depositional environments (lacustrine vs. fluvial) and stratigraphic positions. However, some differences are recognized in the content and chemistry of authigenic minerals caused by different sandstone framework compositions. The content of authigenic clay minerals is higher in sandstones of the Shimonoseki Subgroup containing abundant volcanic rock fragments. In addition, the composition of chlorite, the most abundant authigenic clay mineral in Kanmon sandstones, is Mg-rich in the volcanoclastic Shimonoseki sandstones, compared to an Fe-rich variety in Wakino sandstones. The original sandstone composition played a significant role in pore-water composition and diagenetic reactions.The Wakino sandstones lost most of its porosity by compaction, whereas Shimonoseki sandstones are only compacted in the vicinity of the basin-bounding fault. The weakly compacted Shimonoseki sandstones, instead, were largely cemented by pore-filling calcite during early diagenesis; cementation prevented compaction during further burial. The Kanmon Group sediments were heated to about 300 °C based on illite crystallinity values.     

Analysis of geological effects on methane adsorption capacity of continental shale: a case study of the Jurassic shale in the Tarim Basin,northwestern China

The Jurassic shale is an important source rock for the found gas reservoirs in the Tarim Basin, northwestern China, but has never been researched for shale gas potential. The geological effects on methane adsorption capacity for the gas shale have been investigated in this paper through the geochemical, mineralogical and adsorption analyses on samples from wells and sections. The methane adsorption capacity ranges from 0.58 to 16.57 cm³/g, and the total organic carbon (TOC) content is between 0.5 and 13.5 wt%. The organic maturity measured by T_max is between 410 °C (immature) and 499 °C (overmature). The methane adsorption capacity of the Jurassic continental shale in the Tarim Basin is affected by many geological factors, including the TOC content, organic matter maturity, mineral composition, surface area and pore size distribution. The TOC content is the most significant factor with a positive effect on the adsorption capacity of the Jurassic shale, and the influence varies piecewise according to the TOC content. The TOC content contributes much more to the methane adsorption capacity of organic‐rich shale samples (TOC content > 0.7 wt%) than to the organic‐lean samples (TOC content < 0.7 wt%). The mineral composition is a secondary factor, and the abundance of clay content has a positive effect on the methane adsorption capacity despite its relatively weaker adsorption ability compared to TOC. The pore size distribution has different effects on surface area and pore volume. Mesopores and micropores provide the major surface area and are mainly derived from TOC and illite, which has a positive influence on the adsorption capacity. Mesopores and macropores offer the major pore volume and are mainly formed by illite, which is the major contributor for pore volume rather than surface area. In addition, the TOC and illite contents of the Jurassic shale in the Tarim Basin are closely related to the origin, maturity and diagenesis evolution of the shale: (1) both TOC and illite content variations are related to the different provenances and depositional environments of shale; (2) the decrease of TOC content with increasing maturity is also partly attributed to hydrocarbon generation; and (3) the increase of illite content with increasing maturity is due to illitization in the diagenesis of shale. Copyright © 2015 John Wiley & Sons, Ltd.     

塔里木盆地西北地区震旦系苏盖特布拉克组潮坪相碎屑岩成岩作用与成岩演化研究

塔里木盆地西北地区苏盖特布拉克组发育一套潮坪相沉积,是该层系油气勘探的主要目标。基于什艾日克剖面、奇格布拉克剖面、肖尔布拉克剖面的地质测量,采用薄片鉴定、阴极发光、扫描电镜、流体包裹体测温及黏土矿物X衍射等分析手段开展海相碎屑岩成岩作用和成岩演化研究,为塔里木盆地苏盖特布拉克组进一步开展油气勘探部署和甜点储层预测提供地质依据。结果表明：（1）研究区苏盖特布拉克组发育潮坪沉积环境的砂体,砂岩类型以岩屑石英砂岩、岩屑砂岩为主,偶见长石岩屑砂岩,成分成熟度和结构成熟度中等;（2）苏盖特布拉克组砂岩经历了压实（溶）作用、胶结作用、溶蚀作用及交代作用等成岩作用,压实作用是造成储层致密的直接原因,钙质胶结和硅质胶结是储层致密化的根本因素;（3）苏盖特布拉克组砂岩的成岩演化阶段已达到中成岩B期,成岩演化序列为：压实作用/自生黏土矿物（绿泥石）环边—第一期长石、岩屑溶蚀作用—第一期硅质胶结—第一期泥微晶方解石胶结/压溶作用/黏土矿物的伊利化—第二次硅质胶结/第二期铁方解石胶结—钙质胶结物溶蚀。据此建立的成岩演化模式为塔里木盆地超深层致密砂岩中甜点储层预测提供可靠的地质依据。     

Clay gouge

Clays are a common component of fault gouge, but their genesis and importance in fault evolution is poorly understood. We present preliminary evidence that clays participate in extensive mineral reactions and microfabric changes during faulting. Rather than thinking of clay reactions as a consequence of mechanical processes or fault localization following diagenetically altered horizons, we see the interplay between clay mineral reactions and mechanical processes as a single, integrated process. Furthermore, faulting may lower kinetic barriers to low-temperature (∼100°C) mineral reactions that are common in sedimentary rocks.Our most striking example of fault diagenesis-deformation is a profile of %illite in mixed-layer illite/smectite in shales beneath the Lewis Thrust, Canada. Whereas burial diagenesis caused minimal smectite-to-illite reaction, shales within meters of the thrust are almost completely converted to illite. The consequences of these changes are manifested in geochemical, geochronologic and microfabric characteristics of clay gouge. In this example, faulting has helped overcome a kinetic barrier in the smectite-to-illite reaction without appreciable addition of heat. In another example we infer that dissolution–precipitation reactions continue during faulting even when smectite has already been completely transformed to illite.If mineral reactions intimately interact with mechanical processes in shallow-crustal faults, then our current understanding of the mechanical and hydraulic properties of fault zones may be incomplete. Syndeformational mineral reactions and associated fabric changes could make faults much weaker than would be expected from evaluation of the static mineral assemblage of gouge and single crystal properties. Syndeformational mineral reactions may promote fault slip (affecting earthquake activity) in gouge-bearing faults under stress conditions considerably lower than predicted from static mineral properties. In addition, fault-induced dissolution-precipitation reactions may contribute to fault localization.     

华池油田华152区长3油层组砂岩的成岩作用与孔隙演化

华池油田华152区长3油层组储层以粉细粒长石砂岩、岩屑长石砂岩为主,发育多种孔隙类型,主要有粒间溶孔、粒内溶孔、剩余粒间孔、晶间微孔隙和构造缝,其中粒间溶孔是长3油层组储层的主要孔隙类型。主要成岩矿物为伊利石、绿泥石、伊／蒙混层、高岭石、方解石、白云石、石英等。根据成岩作用的矿物岩石学标志,将研究区成岩阶段界定为中成岩A期。压实和胶结作用破坏了砂岩的原生孔隙结构,而溶蚀作用形成次生孔隙,有效地改善了砂岩的孔隙结构。     

The roles of pedogenesis and diagenesis in clay mineral assemblages: Lower Cretaceous fluvial mudrocks,Nova Scotia,Canada

Clay mineral assemblages in alluvial mudrocks are important for paleoclimatic interpretation and for understanding burial diagenetic cementation in sandstones, but it is commonly difficult to unravel the relative importance of source weathering, pedogenesis and diagenesis in their origin. The clay mineral assemblages in fluvial overbank mudrocks from the Lower Cretaceous Chaswood Formation in central Nova Scotia, investigated by X-ray diffraction analysis of the < 2 µm fraction of 45 samples, include kaolinite, illite, vermiculite, and mixed layer kaolinite/expandable clay and mica/vermiculite. The assemblages vary with depositional facies. Wetland organic-rich mudrocks have large amounts of amorphous material and kaolinite is the dominant clay mineral. In the eastern part of the basin, where overbank mudrocks were episodically uplifted by syn-sedimentary strike-slip faulting, cumulate ultisol and alfisol paleosols are common. In the ultisols, hematite is enriched and kaolinite increases at the expense of illite in the B horizon. Alfisols contain more illite and vermiculite and the B horizon is enriched in goethite. In the western part of the basin, where thin sandstones with abundant diagenetic kaolinite cement are interbedded with the mudrocks, the distinctive clay mineral assemblage of mica/vermiculite mixed layer, vermiculite with 15.5 Å peak, and kaolinite/expandable mixed layer clay with a 17.7 Å peak is interpreted to result from bacterially-mediated oxidation of organic matter below the paleo-water table during early burial diagenesis. Deeper burial diagenesis may lead to slightly higher kaolinite crystallinity. Volcanic ash appears to alter to kaolinite/expandable mixed layer clay with a 7.9 Å peak. Comparison with the continuously subsiding and rapidly accumulated Wessex Formation of southern England, formed at a similar paleolatitude, shows the strong role of pedogenic processes and early diagenesis by meteoric water in development of clay mineral assemblages in the locally tectonically uplifted Chaswood Formation.     

Diagenetic mineral development within the Upper Jurassic Haynesville-Bossier Shale,USA

Despite recent advances, diagenetic processes in fine-grained sediments are still relatively poorly understood. Key questions still to be resolved include the types of diagenetic minerals present in mudstones and the extent of element mobility in these low permeability systems. This study utilizes data from the Haynesville-Bossier Shale, USA, to analyze lithologies, discriminate authigenic phases and identify mobile elements during diagenesis. It has implications for understanding how authigenic minerals develop and the sources of those authigenic minerals in fine-grained sediments. On the basis of grain-size and mineralogy five lithologies are designated: (i) silica-rich argillaceous mudstones; (ii) argillaceous siliceous mudstones; (iii) mixed siliceous mudstones; (iv) mixed mudstones; and (v) authigenically-dominated mudstones. The diagenetic development of the Haynesville-Bossier Shale can be divided into early and late diagenesis. Ferroan and non-ferroan dolomite, framboidal pyrite and bioclast pore-filling kaolinite and calcite grain replacements and cements all formed during early diagenesis. Late diagenetic mineral phases include illite formed by the illitization of smectite, replacive and displacive chlorite, calcite-replacive albite, quartz-replacive calcite and replacive and/or displacive quartz. The presence of extensive late diagenetic mineral precipitates indicates that there was a degree of element mobility on at least the local scale. Aluminium present in albite is most likely to have resulted from the illitization of smectite. Quartz overgrowths probably resulted from illitization and the pressure dissolution at quartz silt grain boundaries. Externally, hydrothermal fluids resulting from regional-scale igneous activity appear to have played a role in the formation of chlorite and possibly albite. The work indicates that extensive mineral development and element mobility occurred during late diagenesis.     

Diagenesis of Tertiary marlstones in the Vienna Basin

Summary To investigate the diagenetic changes of Tertiary pelitic sediments in the Vienna Basin a suite of drill core samples from the OeMV-bore-hole Aderklaa 78 has been studied using mineralogical and chemical methods.The sediments generally correspond to shales and cover a section from 780–2812 m depth. Their mineralogical composition is complex and variable and mainly due to the initial variation in detrital constituents at the time of sedimentation and the local sedimentary environments. Quartz, feldspars (sodic-plagioclase, K-feldspar), carbonates (calcite, dolomite, siderite), phyllosilicates (mica, chlorite, kaolinite, illite-smectite mixed-layers), and pyrite to a minor extent are the essential components of the shales.The analytical data of bulk samples and the less than 0.2 micron fractions point out that mechanical compaction of the sediments was accom inied by isochemical changes within the shale sequence. The diagenetic overprint of the mineral constituents is revealed by a decrease with depth of K-feldspar and an increase of quartz respectively, but especially by the gradual illitization of smectite via mixed-layer intermediates. Burial diagenesis in this Vienna Basin profile therefore can be expressed by the mineral reaction: K-feldspar+smectiteillite+quartz.A local reversal in all these trends in the basal Tertiary section can be explained by unusually high magnesium contents of the pore waters which inhibited illitization by promoting the stability of smectite relative to illite.

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Diagenetische Veränderungen an neogenen tonigen Sedimenten des Wiener Beckens

Zusammenfassung Zur Feststellung diagenetischer Veränderungen an den neogenen pelitischen Sedimenten des Wiener Beckens wurde eine Serie von Tonmergeln der ÖMV-Tiefbohrung Aderklaa 78 dem Teufenbereich zwischen 780–2812 m entnommen und mineralogisch sowie chemisch untersucht.Der Mineralbestand der Proben ist primär vom Einzugsgebiet und dem Ablagerungsmilieu der Sedimente geprägt. Quarz, Feldspäte (Albit-reicher Plagioklas, Alkalifeldspat), Karbonate (Calcit, Dolomit, Siderit) und Schichtsilikate (Glimmer, Chlorit, Kaolinit, Illit-Smektit Mischphasen) sowie untergeordneter Pyrit sind die wesentlichen Gemengteile der Ablagerungen.Die Untersuchungsergebnisse der Gesamtproben und der Fraktionen kleiner 0,2 Mikron zeigen, daß die mechanische Kompaktion der Sedimente von isochemischen Umwandlungsprozessen begleitet wird. Die diagenetische Überprägung des Mineralbestandes äußert sich mit zunehmender Tiefe in der Abnahme des Alkalifeldspates und der Zunahme des Quarzes, vor allem aber in der fortschreitenden Illitisierung des Smektits, die über Mixed-Layer Zwischenbildungen verschiedenen Ordnungsgrades abläuft.Die Mineralreaktion Alkalifeldspat+SmektitIllit+Quarz entspricht der versenkungsdiagenetischen Entwicklung dieses Bereiches.Eine lokale Trendumkehr der mineralogisch-chemischen Veränderungen im Nahbereich zur mesozoischen Basis des Neogens ist mit einer extremen Zusammensetzung der Porenwässer zu erklären, deren hoher Mg-Gehalt eine kontinuierliche Entwicklung des Illitisierungsprozesses verhindert.

     

鸡西盆地下白垩统城子河组-穆棱组露头砂岩中的黏土矿物成因探讨

对鸡西盆地下白垩统城子河组—穆棱组露头砂岩中的黏土矿物进行了X-衍射分析。研究结果表明,黏土矿物主要由伊利石,高岭石和伊/蒙混层组成,组合可分为高岭石型与伊/蒙混层和伊利石型两种,根据黏土矿物组合判断露头砂岩处于中成岩阶段A期。下白垩统城子河组—穆棱组煤系地层和泥岩成岩过程中析出的有机酸是高岭石型黏土矿物组合发育的重要原因,而沉积相带水动力条件弱导致砂岩渗滤条件的变差则是伊/蒙混层和伊利石型黏土矿物组合形成的原因。     

Significance of the chemistry and morphology of diagenetic siderite in clastic rocks of the Mesozoic Scotian Basin

Siderite (FeCO₃) is a widespread minor diagenetic mineral in clastic sedimentary basins. Although eodiagenetic authigenesis of siderite is well-known, siderite formed during burial diagenesis shows habits and chemical compositions that are poorly understood. This study tests the hypothesis that diagenetic siderite cements in sandstones in the Scotian Basin, offshore eastern Canada, show systematic variability in chemistry and habit that is a response to recrystallization and changing composition of basinal fluids. Mineral textures were determined from backscattered electron images, and chemistry mostly from electron microprobe analyses. Five chemical types of siderite are identified using k-means cluster analysis, based on the amount of substitution of Ca, Mg and Mn for Fe. Eodiagenetic microcrystalline coated grains, concretions and intraclasts in sandstones are principally Fe-rich siderite and locally have recrystallised to blocky equant crystals. Mesodiagenetic Mg-rich siderite partly replaced these equant crystals and also framework mica and K-feldspar grains, showing textural evidence for coupled dissolution–reprecipitation. Slender Mg-rich siderite rhombs (lozenges, bladed or wheat-seed siderite) have precipitated before and after the formation of quartz overgrowths in geochemical microenvironments. Magnesium substitution reflects Mg-rich formation waters resulting from smectite to illite conversion. Equivalent Ca-rich siderite occurs where sandstones overlie a Jurassic carbonate bank. Late Mn-rich siderite has complex textures resembling those of Mississippi-Valley type ores, with spheroidal rims, a honeycomb-like mesh and concentric infill around secondary pores. It also occurs in veins or replacing intraclasts, post-dating late ferroan-calcite cements in sandstones that show strong dissolution by hot basinal brines. The Ca, Mg and Mn content of diagenetic siderite, coupled with textural evidence for recrystallization, can thus be used to track changes in ambient formation fluids. Siderite habits and chemistry described from the Scotian Basin are found in many clastic basins, suggesting that the observed recrystallization textures and variation in chemical type are of broad application.     

鄂尔多斯盆地白垩系粘土矿物的分布特征及其沉积-成岩环境意义

系统地分析了鄂尔多斯盆地白垩系粘土矿物的特征及其沉积、成岩环境意义。研究结果表明:白垩系砂岩、泥质岩的粘土矿物组合以I+C+I/S型、I+C型为主,具有高伊利石含量,较高绿泥石、伊/蒙混层矿物含量的粘土矿物组成特点;其中泥质岩粘土矿物主要为陆源碎屑成因,次为沉积成岩过程中形成的自生粘土矿物,而砂岩粘土矿物兼有陆源碎屑成因和沉积成岩过程自生成因的特征;白垩系沉积时气候总体特征为干旱—半干旱,但局部时段发生干—湿气候波动而处于短暂的湿热气候环境;白垩系沉积物源富含长石等硅酸盐矿物,沉积物质主要自北、南、西向盆地内部搬运沉积;白垩系沉积和埋藏成岩过程中水介质整体上具有盐度较高,偏碱性,富K+、Fe2+、Mg2+的特点,且总体上盆地南部水介质中的这些指标都高于北部。     

珠三坳陷成岩作用与油气聚集

采用岩石学、矿物学、X 射线衍射分析技术、有机包裹体以及地球化学等方法对珠三坳陷成岩作用与油气聚集规律进行研究,认为珠三坳陷的成岩作用阶段处于早成岩期和晚成岩期A、B亚期,坳陷内两个主力成油（气）凹陷具有不同的成岩史,其次生孔隙发育带的形成机理也不同,油气的分布与伊蒙泥层粘土矿物转化带关系密切。珠海组砂岩石英次生加大边的形成对坳陷内油气聚集起控制作用。     

Sandstone diagenesis in the Pattani Basin (Gulf of Thailand): history of water-rock interaction and comparison with the Gulf of Mexico

In the Pattani Basin, a failed-rift basin, extensive water-rock interaction has occurred between subquartzose alluvial sandstones of Miocene age and their pore fluids. Diagenetic rates and pathways have been strongly influenced by high geothermal gradients, high CO₂ fugacities, and low pore water salinities. Depositional pore water was fresh to brackish, depending on the depositional environment of the sediments. Chloride concentrations in modern formation water are believed primarily to reflect the proportions of river and sea water in the depositional environment. However, the concentration of other important solutes and the isotopic composition of the formation waters can not be explained by roportional mixing of these two end-member waters. Dissolution of detrital plagioclase (An = 3) and K- feldspar are reactions of major significance that are reflected chemically in the Na/Cl and K/Cl ratios of the formation water. Despite the high temperature of the sandstones (120–200°C), diagenetic albite does not occur. Geochemical calculations indicate the formation water is undersaturated with respect to both orthoclase and albite. This style of feldspar diagenesis differs significantly from that of sandstones of similar composition in other basins, and has probably influenced other aspects of silicate diagenesis.Important authigenic minerals are: 1. locally abundant calcite cement (δ¹³C= −12.8, δ¹⁸O= −17.3 PDB), an early diagenetic phase that formed at about 60°C; 2. pore-filling kaolinite (δ¹⁸O= 9.9, δD= −83.5SMOW) that was closely associated with feldspar dissolution and formed over a range of temperatures; and 3. fibrous pore-lining and pore-bridging illite (δ¹⁸O = 9.8, δD = − 86.7 SMOW, the last significant cement, formed at temperatures of 120 to 150°C. Potassium/argon dates on illite indicate that sandstone diagenesis took place during a period of rapid sedimentation in the first two-thirds of the burial history.Comparison of Pattani Basin diagenesis with diagenesis of sandstones of similar age in other sedimentary basins demonstrates that chemical diagenesis, relative to mechanical compaction, has been especially rapid in the Pattani Basin. This reflects the effect of high temperatures on reaction rates. The net effect is a high average rate of porosity loss with burial (11% km).     

安塞油田长2油层成岩作用及其对储层物性的影响

安塞地区长2油层储层以中细粒长石砂岩为主，主要成岩矿物为绿泥石环边、方解石胶结物、石英和长石加大生长、伊利石、伊一蒙混层、钠长石和高岭石等。绿泥石环边的发育对原生粒间孔的保存起到有利的作用。石英加大级别达Ⅲ级，加大边含有丰富的有机包体，均一温度范围48．1～76．5℃，烃类进入储层的时间为早白垩世中期至晚白垩世。储层发育多种孔隙类型，面孔率平均为11．60％．主要类型有粒间孔、骨架颗粒溶孔和微裂缝等。残余粒间孔和骨架颗粒溶孔是本区长2储层的主要孔隙类型。根据成岩作用的矿物岩石学标志、有机质成熟度及古温度，将长2油层砂岩的成岩作用划分为3个成岩阶段：早成岩阶段、晚成岩阶段和表生成岩阶段。储层性质明显地受到沉积微相和成岩作用的影响，沉积物粒度较粗、厚度较大的分流河道储集物性明显优于各种粒度较细、厚度较薄的分流间席状砂体。     

国内难溶性钾矿资源及其开发利用

国内难溶性钾矿资源较丰富,可分为含钾岩石和含钾矿物两大类及若干亚类。含钾沉积岩有:富钾火山沉积凝灰岩(绿豆岩),含钾砂、页岩,含钾泥灰岩,含钾石膏泥,含钾磷块岩等;含钾岩浆岩有:霞石正长岩、霓辉石石英正长岩、流纹斑岩、正长斑岩、花岗伟晶岩、钾长粗面凝灰熔岩等;含钾变质岩有:钾长浅粒岩、云母片岩、钾长混合片麻岩等;可作钾矿资源的含钾矿物有:钾长石、明矾石、伊利石、白榴石、海绿石等。目前,绿豆岩,含钾砂、页岩,流纹岩,海绿石,白榴石等已可单独开采利用,制作钾肥;霞石正长岩、伊利石、钾长石、明矾石等可被综合回收利用;粗面岩、响岩、粗玄岩,含钾泥灰岩、钾长浅粒岩等尚待开发利用。     

海拉尔盆地乌尔逊-贝尔凹陷下白垩统火山碎屑岩成岩作用类型及序列

海拉尔盆地乌尔逊-贝尔凹陷下白垩统发育火山熔岩-正常碎屑沉积岩之间的过渡岩石类型,其成岩作用类型与正常沉积岩相比具有特殊性.采用显微镜下描述与扫描电镜分析相结合的方法对研究区成岩作用类型进行了研究,并总结出成岩作用序列.结果显示火山碎屑岩的成岩作用类型包括熔结作用、机械渗滤作用、压实作用、脱玻化作用、重结晶作用、胶结作用、自生矿物转化和溶蚀溶解作用.其中,熔结作用、脱玻化作用以及凝灰质的溶蚀溶解作用是火山碎屑岩所特有的成岩作用类型.研究区具有成因联系的成岩共生组合主要有4类,分别是:(1)微晶石英和微晶方解石;(2)石英的溶解与结晶;(3)自生白云母、蒙皂石、伊利石和绿泥石;(4)沸石与自生长石.成岩序列可以分为熔结作用阶段、机械渗滤作用阶段、脱玻化作用阶段、凝灰质溶蚀溶解作用阶段、粘土矿物混层阶段、自生白云母阶段、沸石胶结阶段、颗粒强烈胶结阶段以及铁白云发育阶段.研究区下白垩统处于早成岩B期至晚成岩B期,主要为晚成岩A期.      

塔中地区志留系沥青砂岩成岩作用及其对储层性质的影响

运用沉积学原理对塔中地区志留系经历复杂成岩演化的沥青砂岩进行研究分析,了解到该岩石主要经过压实作用、胶结作用和溶蚀作用等成岩作用。其胶结物的主要类型有绿泥石、伊利石、高岭石、伊-蒙混层等粘土矿物以及碳酸盐矿物、石英、长石、黄铁矿等。孔隙类型以粒间孔隙、粒内孔、铸模孔、特大孔、裂缝孔隙等为主,其中以粒间孔隙最为发育,低地温梯度有利于在深层形成次生孔隙。志留系沥青砂岩储层物性受沉积和成岩双重因素的影响,成岩演化阶段处于晚成岩A期。根据影响储层物性的储层成岩作用,可将成岩相类型划分为不稳定碎屑溶蚀成岩相、压实-弱溶蚀成岩相、压实充填成岩相、压实压溶成岩相、碳酸盐胶结成岩相等几种主要类型,成岩相类型决定了储层性质,不稳定碎屑溶蚀成岩相和压实-弱溶蚀成岩相是本区较好的油气储层。