Pressure Buildup and Brine Migration During CO2 Storage in Multilayered Aquifers

Carbon dioxide injection into deep saline formations may induce large‐scale pressure increases and migration of native fluid. Local high‐conductivity features, such as improperly abandoned wells or conductive faults, could act as conduits for focused leakage of brine into shallow groundwater resources. Pressurized brine can also be pushed into overlying/underlying formations because of diffuse leakage through low‐permeability aquitards, which occur over large areas and may allow for effective pressure bleed‐off in the storage reservoirs. This study presents the application of a recently developed analytical solution for pressure buildup and leakage rates in a multilayered aquifer‐aquitard system with focused and diffuse brine leakage. The accuracy of this single‐phase analytical solution for estimating far‐field flow processes is verified by comparison with a numerical simulation study that considers the details of two‐phase flow. We then present several example applications for a hypothetical CO₂ injection scenario (without consideration of two‐phase flow) to demonstrate that the new solution is an efficient tool for analyzing regional pressure buildup in a multilayered system, as well as for gaining insights into the leakage processes of flow through aquitards, leaky wells, and/or leaky faults. This solution may be particularly useful when a large number of calculations needs to be performed, that is, for uncertainty quantification, for parameter estimation, or for the optimization of pressure‐management schemes.     

Origin and Evolution of Aquitard Porewater in the Western Coastal Plain of Bohai Bay,China

High‐salinity paleowater from low‐permeability aquitards in coastal areas can be a major threat to groundwater resources; however, such water has rarely been studied. The chemical and isotopic compositions of porewater extracted from a 200‐m‐thick Quaternary sedimentary sequence in the western coastal plain of Bohai Bay, China, were analyzed to investigate the salinity origin and chemical evolution of porewater in aquitards. Porewater samples derived at depths shallower than 32 m are characterized by Cl‐Na type saline water (total dissolved solids [TDS], 10.9–84.3 g/L), whereas those at depths greater than 32 m comprise Cl·SO₄‐Na type brackish water (TDS, 2.2–6.3 g/L). Saline porewater is interpreted as evaporated seawater prior to halite saturation, as evidenced by Cl‐Br relationships. Although substantial dilution of saline porewater with meteoric water is supported by a wider Cl^? range and δ²H‐δ¹⁸O covariance, the original marine waters were not completely flushed out. The deeper brackish porewater is determined to be a mixture of fresher porewater and brine groundwater and had a component of old brine of less than 10%, as indicated by a mixing model defined using δ²H and Cl^? tracers. Porewater δ²H‐δ¹⁸O relationships and negative deuterium excess ranging from ?25.9‰ to ?2.9‰ indicate the existence of an arid climate since Late Pleistocene in Tianjin Plain. The aquitard porewaters were chemically modified through water‐rock interactions due to the long residence time.     

Modelling biofilm growth in the presence of carbon dioxide and water flow in the subsurface

The concentration of greenhouse gases – particularly carbon dioxide (CO₂) – in the atmosphere has been on the rise in the past decades. One of the methods which have been proposed to help reduce anthropogenic CO₂ emissions is the capture of CO₂from large, stationary point sources and storage in deep geological formations. The caprock is an impermeable geological layer which prevents the leakage of stored CO₂, and its integrity is of utmost importance for storage security. Due to the high pressure build-up during injection, the caprock in the vicinity of the well is particularly at risk of fracturing. Biofilms could be used as biobarriers which help prevent the leakage of CO₂ through the caprock in injection well vicinity by blocking leakage pathways. The biofilm could also protect well cement from corrosion by CO₂-rich brine.     

A Multiscale Assessment of Shallow Groundwater Salinization in Michigan

Managing nonpoint-source (NPS) pollution of groundwater systems is a significant challenge because of the heterogeneous nature of the subsurface, high costs of data collection, and the multitude of scales involved. In this study, we assessed a particularly complex NPS groundwater pollution problem in Michigan, namely, the salinization of shallow aquifer systems due to natural upwelling of deep brines. We applied a system-based approach to characterize, across multiple scales, the integrated groundwater quantity–quality dynamics associated with the brine upwelling process, assimilating a variety of modeling tools and data—including statewide water well datasets scarcely used for larger scientific analysis. Specifically, we combined (1) data-driven modeling of massive amounts of groundwater/geologic information across multiple spatial scales with (2) detailed analysis of groundwater salinity dynamics and process-based flow modeling at local scales. Statewide “hotspots” were delineated and county-level severity rankings were developed based on dissolved chloride (Cl⁻) concentration percentiles. Within local hotspots, the relative impact of upwelling was determined to be controlled by: (1) streams—which act as “natural pumps” that bring deeper (more mineralized) groundwater to the surface; (2) the occurrence of nearly impervious geologic material at the surface—which restricts fresh water dilution of deeper, saline groundwater; and (3) the space–time evolution of water well withdrawals—which induces slow migration of saline groundwater from its natural course. This multiscale, data-intensive approach significantly improved our understanding of the brine upwelling processes in Michigan, and has applicability elsewhere given the growing availability of statewide water well databases.     

基于改进SWAT模型的灌溉—施肥—耕作对乌梁素海流域营养物负荷及作物产量的影响

不合理的灌溉、施肥和耕作是导致乌梁素海流域农业面源污染的主要根源,乌梁素海作为我国北方地区重要的生态安全屏障,多年来面临着湖泊水环境污染、水生态退化等问题,科学开展湖泊水环境综合治理首先要解决流域内农业面源污染问题.研究通过修改土壤水平衡、溶质平衡、地下水平衡和作物生长等模块对SWAT 2012原始版本进行改进,并采用改进的SWAT模型构建了乌梁素海流域分布式水文模型,利用实测径流、硝态氮与总磷排放量、地下水埋深以及作物产量校正和验证模型.基于现状情景,以玉米、葵花和小麦3种主要作物为研究对象,设置了削减灌水量、施肥量及调整耕作方式3种农田管理情景.基于改进SWAT模型不同情景的模拟结果,计算分析各管理情景下的硝态氮与总磷负荷及对各作物产量的影响.结果表明,改进SWAT模型具有良好的模拟效果.不同作物削减5%夏灌水量增产最多达8.41%～10.32%,削减10%秋浇水量均明显减少硝态氮和总磷负荷.不同作物营养物负荷均随着氮磷施肥削减比例的增大呈现逐渐降低的趋势,但下降曲线逐渐趋于平缓;各作物产量随氮磷施肥削减比例的增加呈先增加后减少的趋势,其中玉米、小麦氮磷施肥削减比例达20%时产量开...     

Using chlorofluorocarbons (CFCs) and tritium to improve conceptual model of groundwater flow in the South Coast Aquifers of Laizhou Bay,China

The southern coastal plain of Laizhou Bay, which is the area most seriously affected by salt water intrusion in north China, is a large alluvial depression, which represents one of the most important hydrogeological units in the coastal region of northern China. Chlorofluorocarbons (CFCs, including CFC‐11, CFC‐12 and CFC‐113) and tritium were used together for dating groundwater up to 50 years old in the study area. There are two cones of depression, caused by intensive over‐exploitation of fresh groundwater in the south and brine water in the north. The assigned CFC apparent ages for shallow groundwater range from 8 a to >50 a. A binary mixing model based on CFC‐113 and CFC‐12 concentrations in groundwater was used to estimate fractions of young and pre‐modern water in shallow aquifers and to identify groundwater mixing processes during saltwater intrusion. Discordance between concentrations of different CFC compounds indicate that shallow groundwater around the Changyi cone of depression is vulnerable to contamination. Pumping activities, CFC contamination, mixing and/or a large unsaturated zone thickness (e.g. >20 m) may be reasons for some groundwater containing CFCs without tritium. Saline intrusion mainly occurs because of large head gradients between fresh groundwater in the south and saline water bodies in the north, forming a wedge of saline water below/within fresh aquifer layers. Both CFC and tritium dates indicate that the majority of the saline water is from >50 a, with little or no modern seawater component. Based on the distribution of CFC apparent ages, tritium contents plus chemical and physical data, a conceptual model of groundwater flow along the investigated Changyi‐Xiaying transect has been developed to describe the hydrogeological processes. Three regimes are identified from south to north: (i) fresh groundwater zone, with a mixing fraction of 0.80–0.65 ‘young’ water calculated with the CFC binary mixing model (groundwater ages <34 a) and 1.9–7.8TU of tritium; (ii) mixing zone characterized by a mixing fraction of 0.05–0.65 young groundwater (ages of 23–44 a), accompanied by local vertical recharge and upward leakage of older groundwater; and (iii) salt water zone, mostly comprising waters with ages beyond the dating range of both CFCs and tritium. Some shallow groundwater in the north of the Changyi groundwater depression belongs to the >50a water group (iii), indicating slow velocity of groundwater circulation and possible drawing in of saline or deep groundwater that is tracer‐free. Copyright © 2012 John Wiley & Sons, Ltd.     

Conceptualizing leakage and storage contributions from long open interval wells in regional deep basin flow models

Deep basin aquifers are increasingly used in water‐stressed areas, though their potential for sustainable development is inhibited by overlying aquitards and limited recharge rates. Long open interval wells (LOIWs)—wells uncased through multiple hydrostratigraphic units—are present in many confined aquifer systems and can be an important mechanism for deep basin aquifers to receive flow across aquitards. LOIWs are a major control on flow in the deep Cambrian–Ordovician sandstone aquifers of the upper Midwest, USA, providing a source of artificial leakage from shallow bedrock aquifers and equilibrating head within the sandstone aquifers despite differential pumpage. Conceptualizing and quantifying this anthropogenic flow has long been a challenge for groundwater flow modellers, particularly on a regional scale. Synoptic measurements of active production wells and well completion data for northeast Illinois form the basis for a transient, head‐specified MODFLOW model that determines mass balance contributions to the region and estimates LOIW leakage to the aquifers. Using this insight, transient LOIW leakage was simulated using transiently changing K_V zones in a traditional, Q‐specified MODFLOW‐USG model, a novel approach that allows the K_V in a cell containing a LOIW to change transiently by use of the time‐variant materials (TVM) package. With this modification, we achieved a consistent calibration through time, averaging 19.9 m root mean squared error. This model indicates that artificial leakage via LOIWs contributed a minimum of 10–13% of total flow to the sandstone aquifers through the entire history of pumping, up to 50% of flow around 1930. Removal from storage exceeds 40% of flow during peak withdrawals, much of this flow sourced from units other than the primary sandstone aquifers via LOIWs. As such, understanding the timing and magnitude of LOIW leakage is essential for predicting future water availability in deep basin aquifers.     

Effect of Sea‐Level Rise on Salt Water Intrusion near a Coastal Well Field in Southeastern Florida

A variable‐density groundwater flow and dispersive solute transport model was developed for the shallow coastal aquifer system near a municipal supply well field in southeastern Florida. The model was calibrated for a 105‐year period (1900 to 2005). An analysis with the model suggests that well‐field withdrawals were the dominant cause of salt water intrusion near the well field, and that historical sea‐level rise, which is similar to lower‐bound projections of future sea‐level rise, exacerbated the extent of salt water intrusion. Average 2005 hydrologic conditions were used for 100‐year sensitivity simulations aimed at quantifying the effect of projected rises in sea level on fresh coastal groundwater resources near the well field. Use of average 2005 hydrologic conditions and a constant sea level result in total dissolved solids (TDS) concentration of the well field exceeding drinking water standards after 70 years. When sea‐level rise is included in the simulations, drinking water standards are exceeded 10 to 21 years earlier, depending on the specified rate of sea‐level rise.     

The ecohydrological imprint of deforestation in the semiarid Chaco: insights from the last forest remnants of a highly cultivated landscape

The semiarid Chaco plains present one of the highest rates of forest clearing and agricultural expansion of the world. In other semiarid plains, such massive vegetation replacements initiated a groundwater recharge and salt mobilization process that, after decades, raised regional water tables and salts to the surface, degrading agricultural and natural ecosystems. Indirect evidence suggests that this process (known as dryland salinity) began in the Chaco plains. Multiple approaches (deep soil profiles, geoelectric surveys and monitoring of groundwater salinity, level and isotopic composition) were combined to assess the dryland salinity status in one of the oldest and most active agricultural hotspots of the region, where isolated forest remnants occupy an extremely flat cultivated matrix. Full vadose moisture and chloride profiles from paired agriculture‐forest stands (17 profiles, six sites) revealed the following: a generalized onset of deep drainage with cultivation (32 to >87 mm year^?1), full leaching of native chloride pools (13.7 ± 2.5 kg m^?2) down to the water table after >40 years following clearing and differential groundwater table rises (0.7 to 2 m shallower water tables under agriculture than under neighbouring forests). Continuous level monitoring showed abrupt water table rises under annual crops (up to 2.6 m in 15 days) not seen under forests or pastures. Varying deep drainage rates and groundwater isotopic composition under agricultural plots suggest that these pulses are strongly modulated by crop choices and sequences. In contrast to other dryland salinity‐affected areas of the world, forest remnants in the study area (10–20% of the area) are not only surviving the observed hydrological shifts but also sustaining active salty groundwater transpirative discharge, as evidenced by continuous water table records. The overall impact of these forest remnants on lowering neighbouring water tables would be limited by the low hydraulic conductivity of the sediments. As highly cultivated areas of the Chaco evolve to new hydrological conditions of shallower saline water tables, innovative crop rotations that minimize recharge, enhance transpirative discharge and tolerate salinity will be needed. Copyright © 2016 John Wiley & Sons, Ltd.     

Geophysical Investigation of Fresh‐Saline Water Interface: A Case Study from South Punjab,Pakistan

The importance of the study of fresh‐saline water incursion cannot be over‐emphasized. Borehole techniques have been widely used, but they are quite expensive, intrusive, and time consuming. The electrical resistivity method has proved very successful in groundwater assessment. This advanced technique uses the calculation of Dar‐Zarrouk (D‐Z) parameters, namely longitudinal unit conductance, transverse unit resistance, and longitudinal resistivity has been employed by using 50 vertical electrical sounding points to assess the groundwater and delineate the fresh‐saline water interface over 1045 km² area of Khanewal in Southern Punjab of Pakistan. The x‐y plots and maps of D‐Z parameters were produced to establish a decipherable vision for the occurrence and distribution of different water‐bearing formations of fresh‐saline water aquifers through a complicated situation of intermixing of different resistivity ranges for fresh‐saline water bodies. This technique is useful to reduce the ambiguity produced by the process of equivalence and suppression which cause intermixing in differentiating fresh, brackish, and saline aquifers during interpretation. The fresh‐saline water interface is correlated very well with the previous studies of water quality analysis carried out in Khanewal area. The results suggest that the D‐Z parameters are useful for demarcating different aquifer zones. The behavior and pattern of D‐Z parameters with respect to occurrence and distribution of different water‐bearing formations were effectively identified and delineated in the study area.     

Impacts of Methane on Carbon Dioxide Storage in Brine Formations

In the context of geological carbon sequestration (GCS), carbon dioxide (CO₂) is often injected into deep formations saturated with a brine that may contain dissolved light hydrocarbons, such as methane (CH₄). In this multicomponent multiphase displacement process, CO₂ competes with CH₄ in terms of dissolution, and CH₄ tends to exsolve from the aqueous into a gaseous phase. Because CH₄ has a lower viscosity than injected CO₂, CH₄ is swept up into a ‘bank’ of CH₄‐rich gas ahead of the CO₂ displacement front. On the one hand, this may provide a useful tracer signal of an approaching CO₂ front. On the other hand, the emergence of gaseous CH₄ is undesirable because it poses a leakage risk of a far more potent greenhouse gas than CO₂ if the cap rock is compromised. Open fractures or faults and wells could result in CH₄ contamination of overlying groundwater aquifers as well as surface emissions. We investigate this process through detailed numerical simulations for a large‐scale GCS pilot project (near Cranfield, Mississippi) for which a rich set of field data is available. An accurate cubic‐plus‐association equation‐of‐state is used to describe the non‐linear phase behavior of multiphase brine‐CH₄‐CO₂ mixtures, and breakthrough curves in two observation wells are used to constrain transport processes. Both field data and simulations indeed show the development of an extensive plume of CH₄‐rich (up to 90 mol%) gas as a consequence of CO₂ injection, with important implications for the risk assessment of future GCS projects.     

Experimental investigation of injectivity alteration due to salt precipitation during CO2 sequestration in saline aquifers

Injection of CO₂ into saline aquifers causes the geochemical reaction of rock-fluid and salt precipitation due to the evaporation of water as a physical process. Well injectivity is an important issue in carbon capture and storage (CCS) projects because large volumes of CO₂ must be stored for a long time and salt precipitation can significantly reduce injectivity by reducing the permeability. The impact of salt precipitation on the injectivity must therefore be specified in order to maintain the security of CCS projects and enable them to perform at a high level of practicality. The objective of this work is to investigate the influence of the injection rate and brine salinity on injectivity reduction due to evaporation and salt precipitation. In this study, we injected supercritical CO₂ into a sandstone rock sample fully saturated with NaCl brine to characterize the salt precipitation induced by the evaporation process.Evaporation is investigated by mass measurement of the water and vapor produced. The extension in time of salt precipitation and the precipitation profile are analyzed by drying rate measurement, Capillary number and Peclet number. The consequences of salt precipitation on injectivity are specified by permeability and relative permeability analysis. The results show that a high drying rate in the early stage of injection induces rapid salt precipitation. The level of salt precipitation increases with salinity, within a permeability reduction range of 21–66%, and decreases with the injection rate, within a permeability reduction range of 43–62%. The relative permeability of CO₂ is affected by both the injection rate and salinity.     

Groundwater recharge and discharge in a hyperarid alluvial plain (Akesu,Taklimakan Desert,China)

Groundwater recharge and discharge in the Akesu alluvial plain were estimated using a water balance method. The Akesu alluvial plain (4842 km²) is an oasis located in the hyperarid Tarim River basin of central Asia. The land along the Akesu River has a long history of agricultural development and the irrigation area is highly dependent on water withdrawals from the river. We present a water balance methodology to describe (a) surface water and groundwater interaction and (b) groundwater interaction between irrigated and non‐irrigated areas. Groundwater is recharged from the irrigation system and discharged in the non‐irrigated area. Uncultivated vegetation and wetlands are supplied from groundwater in the hyperarid environment. Results show that about 90% of groundwater recharge came from canal loss and field infiltration. The groundwater flow from irrigated to non‐irrigated areas was about 70% of non‐irrigated area recharge and acted as subsurface drainage for the irrigation area. This desalinated the irrigation area and supplied water to the non‐irrigated area. Salt moved to the non‐irrigation area following subsurface drainage. We conclude that the flooding of the Akesu River is a supplemental groundwater replenishment mechanism: the river desalinates the alluvial plain by recharging fresh water in summer and draining saline regeneration water in winter. Copyright © 2007 John Wiley & Sons, Ltd.     

Early detection of brine and CO2 leakage through abandoned wells using pressure and surface-deformation monitoring data: Concept and demonstration

In this paper, we develop a methodology for early detection of potential CO₂ leakage from geological storage formations using pressure and surface-deformation anomalies. The basic idea is based on the fact that leakage-induced pressure signals travel much faster than the migrating CO₂; thus such anomalies may be detected early enough for risk management measures taking effect in avoiding substantial CO₂ leaks. The early detection methodology involves automatic inversion of anomalous brine leakage signals with efficient forward pressure and surface-deformation modeling tools to estimate the location and permeability of leaky features in the caprock. We conduct a global sensitivity analysis to better understand under which conditions pressure anomalies can be clearly identified as leakage signals, and evaluate signal detectability for a broad parameter range considering different detection limits and levels of data noise. The inverse methodology is then applied to two synthetic examples of idealized two-aquifer-and-one aquitard storage systems, with an injection well and a leaky well, for different monitoring scenarios. In Example 1, only pressure data at the monitoring and injection wells are used for leakage detection. Our results show that the accuracy of leakage detection greatly depends on the level of pressure data noise. In Example 2, joint inversion of pressure and surface-deformation measurements significantly improves the speed of convergence toward the true solution of the leakage parameters and enables early leakage detection. In both examples, successful detection is achieved when two monitoring wells are appropriately placed within up to 4 km from the leaky well.     

Estimating agricultural deep drainage lag times to groundwater: application to Antelope Valley,California, USA

Estimates of groundwater volumes available in semiarid regions that rely on water balance calculations require the determination of both surface to groundwater lag times and volumes from irrigation or rainfall initiated recharge. Subsurface geologic material hydraulic properties (e.g. hydraulic conductivities, water retention functions) necessary for unsaturated flow modelling are rarely available as are the instrumented field tests that might determine such lag times. Here we develop a simple two‐parameter (specific yield, S_y, and pore‐size distribution index, λ), one‐dimensional unsaturated flow model from simplifications of the Richards equation (using the Brooks‐Corey relationships) to determine lag times from agricultural deep drainage associated with the irrigation of alfalfa hay and various row crops in the Antelope Valley of California, USA. Model‐predicted lag times to depths of 85 m bgs (below ground surface) were similar to that measured in a 2‐year ponded recharge field trial, slightly overestimating that measured by approximately 15% (0.51 vs 0.44 years). Lag time estimates were most sensitive to estimated deep percolation rates and roughly equally sensitive to the model hydraulic parameters. Generally, as subsurface material textures coarsen towards larger S_y and λ values for all S_y >10%, lag times progressively increase; however, at S_y <10%, lag times decrease substantially suggesting that particular combinations of S_y and λ values that may be associated with similarly textured materials can result in the prediction of different lag times for S_y approximately 10%. Overall, lag times of 1–3 years to a depth of 69 m bgs were estimated from deep drainage of agricultural irrigation across a variety of irrigation schedules and subsurface materials. Copyright © 2012 John Wiley & Sons, Ltd.     

Interpretation of Water Level Changes in the High Plains Aquifer in Western Kansas

Water level changes in wells provide a direct measure of the impact of groundwater development at a scale of relevance for management activities. Important information about aquifer dynamics and an aquifer's future is thus often embedded in hydrographs from continuously monitored wells. Interpretation of those hydrographs using methods developed for pumping‐test analyses can provide insights that are difficult to obtain via other means. These insights are demonstrated at two sites in the High Plains aquifer in western Kansas. One site has thin unconfined and confined intervals separated by a thick aquitard. Pumping‐induced responses in the unconfined interval indicate a closed (surrounded by units of relatively low permeability) system that is vulnerable to rapid depletion with continued development. Responses in the confined interval indicate that withdrawals are largely supported by leakage. Given the potential for rapid depletion of the unconfined interval, the probable source of that leakage, it is likely that large‐scale irrigation withdrawals will not be sustainable in the confined interval beyond a decade. A second site has a relatively thick unconfined aquifer with responses that again indicate a closed system. However, unlike the first site, previously unrecognized vertical inflow can be discerned in data from the recovery periods. In years of relatively low withdrawals, this inflow can produce year‐on‐year increases in water levels, an unexpected occurrence in western Kansas. The prevalence of bounded‐aquifer responses at both sites has important ramifications for modeling studies; transmissivity values from pumping tests, for example, must be used cautiously in regional models of such systems.     

Deep Injection of Waste Water in the Western Canada Sedimentary Basin

Injection of wastes into the deep subsurface has become a contentious issue, particularly in emerging regions of oil and gas production. Experience in other regions suggests that injection is an effective waste management practice and that widespread environmental damage is unlikely. Over the past several decades, 23 km³ of water has been injected into the Western Canada Sedimentary Basin (WCSB). The oil and gas industry has injected most of this water but large amounts of injection are associated with mining activities. The amount of water injected into this basin during the past century is 2 to 3 orders magnitude greater than natural recharge to deep formations in the WCSB. Despite this large‐scale disturbance to the hydrogeological system, there have been few documented cases of environmental problems related to injection wells. Deep injection of waste appears to be a low risk activity based on this experience but monitoring efforts are insufficient to make definitive statements. Serious uncharacterized legacy issues could be present. Initiating more comprehensive monitoring and research programs on the effects of injection in the WCSB could provide insight into the risks associated with injection in less developed sedimentary basins.     

Convective stability analysis of the long-term storage of carbon dioxide in deep saline aquifers

Deep saline aquifers are one of the most suitable geologic formations for carbon sequestration. The linear and global stability analysis of the time-dependent density-driven convection in deep saline aquifers is presented for long-term storage of carbon dioxide (CO₂). The convective mixing that can greatly accelerate the CO₂ dissolution into saline aquifers arises because the density of brine increases upon the dissolution of CO₂ and such a density difference may induce instability. The effects of anisotropic permeability on the stability criteria, such as the critical time for the appearance of convective phenomena and the critical wavelength of the most unstable perturbation, are investigated with linear and global stability analysis. The linear stability analysis provides a sufficient condition for instability while the global stability analysis yields a sufficient condition for stability. The results obtained from these two approaches are not exactly the same but show a consistent trend, both indicating that the anisotropic system becomes more unstable when either the vertical or horizontal permeability increases.     

Small‐Scale ASR Between Flow Barriers in a Saline Aquifer

Regular aquifer storage recovery, ASR, is often not feasible for small‐scale storage in brackish or saline aquifers because fresh water floats to the top of the aquifer where it is unrecoverable. Flow barriers that partially penetrate a brackish or saline aquifer prevent a stored volume of fresh water from expanding sideways, thus increasing the recovery efficiency. In this paper, the groundwater flow and mixing is studied during injection, storage, and recovery of fresh water in a brackish or saline aquifer in a flow‐tank experiment and by numerical modeling to investigate the effect of density difference, hydraulic conductivity, pumping rate, cyclic operation, and flow barrier settings. Two injection and recovery methods are investigated: constant flux and constant head. Fresh water recovery rates on the order of 65% in the first cycle climbing to as much as 90% in the following cycles were achievable for the studied configurations with constant flux whereas the recovery efficiency was somewhat lower for constant head. The spatial variation in flow velocity over the width of the storage zone influences the recovery efficiency, because it induces leakage of fresh water underneath the barriers during injection and upconing of salt water during recovery.     

Study of Current Underground Injection Control Regulations and Practices in Illinois

In 1984, the Illinois Department of Energy and Natural Resources was required to assess the regulations and practices of the Illinois Underground Injection Control (UIC) program as it relates to Class I hazardous waste disposal wells. Nine injection wells, including two standbys (one inactive), are currently in operation at seven sites in the state. These wells range in depth from 1540 to 5524 feet (470 to 1683m; most inject wastes into porous carbonate formations (two wells inject into a thick sandstone). In 1984, approximately 300 million gallons (1.1 billion liters) of industrial wastes were disposed of in these wells. Acids were the most common waste disposed of, although water made up 70 to 95 percent of the wastes by volume. Illinois has been granted primacy in operating this program.
The geologic environment, consisting of the unit accepting the waste and confining units lying above and below, has the capacity to accept the waste, to retain it, and to protect all underground sources of drinking water (USDW) from contamination by its injection. The geology of Illinois is relatively simple and includes disposal zones and associated confining units suitable for deep-well injection across the central two-thirds of the state.
The regulatory structure for Class I injection wells is generally adequate in concept and scope to ensure containment of injected wastes and to safeguard underground sources of drinking water in Illinois. There is a need to update and strengthen selected portions of the regulatory practices in the areas of waste sampling protocol, chemical analysis of collected waste samples, and evaluation of injection well testing and monitoring data.
A number of technologies exist that can treat and dispose of most hazardous and non-hazardous waste streams. Each of these technologies has associated with it economic, environmental and societal impacts.