Geochemical and biological consequences of groundwater augmentation in lakes of west-central Florida (USA)

We studied sediment cores from four Florida (USA) lakes that have received groundwater hydrologic supplements (augmentation) for >30 years to maintain lake stage. Top samples (0–4 cm) from sediment cores taken in Lakes Charles, Saddleback, Little Hobbs, and Crystal had ²²⁶Ra activities of 44.9, 17.5, 7.6, and 8.5 dpm g⁻¹, respectively, about an order of magnitude greater than values in deeper, older deposits. The surface sample from Lake Charles yielded the highest ²²⁶Ra activity yet reported from a Florida lake core. Several lines of evidence suggest that groundwater augmentation is responsible for the high ²²⁶Ra activities in recent sediments: (1) ²²⁶Ra activity in cores increased recently, (2) the Charles, Crystal, and Saddleback cores display ²²⁶Ra/²¹⁰Pb disequilibrium at several shallow depths, suggesting ²²⁶Ra entered the lakes in dissolved form, (3) cores show recent increases in Ca, which, like ²²⁶Ra, is abundant in augmentation groundwater, and (4) greater Sr concentrations are associated with higher ²²⁶Ra activities in recent Charles and Saddleback sediments. Sr concentrations in Eocene limestones of the deep Floridan Aquifer are high relative to Sr concentrations in surficial quartz sands around the lakes. Historical water quality inferences for the lakes were based on diatom assemblages in sediments. Recent alkalization in Lakes Charles, Saddleback, Little Hobbs, and Crystal was inferred from weighted-averaging calibration (WACALIB). The lakes also show recent trophic state increases based on WACALIB-derived estimates for limnetic total P. Although residential and agricultural sources might contribute to increased P loading, P in augmentation waters probably has had significant influence on eutrophication. Dystrophic diatoms were abundant in the early history of Lakes Saddleback, Little Hobbs, and Crystal, which suggests that these lakes contained more tannic waters during the past than at present, perhaps as a consequence of greater inflows from surrounding wetlands. Ionic content of lake waters increased, as indicated by diatom autecological analysis. Recent geochemical and biological changes detected in cores from these lakes probably are a result of deliberate groundwater augmentation, although inputs of groundwater pumped for agricultural and residential development in the watersheds also might have contributed to limnological changes.     

Low-background gamma counting: applications for210Pb dating of sediments

Sediment cores from three lakes were dated with²¹⁰Pb using a constant rate of supply (CRS) model. We used low-background gamma counting to measure naturally occurring levels of²¹⁰Pb,²²⁶Ra, and¹³⁷Cs in sediment samples because sample preparation is simple and non-destructive,²²⁶Ra activity provides a direct measure of supported²¹⁰Pb activity for each sample analyzed, and¹³⁷Cs activity may provide an independent age marker for the 1962–1963 peak in atmospheric fallout of this radionuclide. In one core supported²¹⁰Pb activity was estimated equally well from²²⁶Ra activity of each sampling interval or from the mean total²¹⁰Pb activity of constant activity samples at depth. Supported²¹⁰Pb activity was constant with depth in this core. In a short freeze core, determining²²⁶Ra activity of every sample proved advantageous in estimating supported²¹⁰Pb activity because supported²¹⁰Pb activity could be estimated from²¹⁰Pb measurements only at the deepest sampling interval. Supported²¹⁰Pb activity estimated from²²⁶Ra activity also yielded more precise estimates of highly variable sedimentation rates. In the third core²²⁶Ra activity exceeded²¹⁰Pb activity at the top of the core and varied 20 fold with depth. This high input of²²⁶Ra in disequilibrium with²¹⁰Pb is attributed to recent erosion of radium-bearing materials in the drainage basin. These data invalidate the assumption that supported²¹⁰Pb activity is constant in sediment cores and can be estimated from the mean total²¹⁰Pb activity at depths where²¹⁰Pb activity is constant. We recommend using gamma counting or another independent assay of²²⁶Ra to validate the assumption of constant supported²¹⁰Pb activity in sediment cores if there is reason to expect that²²⁶Ra activity varies with depth.This is the fourth of a series of papers to be published by this journal following the 20 ^th anniversary of the first application of²¹⁰Pb dating of lake sediments. Dr. P.G. Appleby is guest editing this series.     

Interpretation of210Pb profiles and verification of the CRS dating model in PIRLA project lake sediment cores

This paper reports results and analysis of²¹⁰Pb-activity measurements in 51 lake-sediment cores from 32 lakes in the four PIRLA (Paleoecological Investigations of Recent Lake Acidification) project regions (Adirondack Mountains [New York], Northern New England, Northern Florida, and the Northern Great Lakes States). General application of the Constant Rate of Supply (Constant Flux) model for²¹⁰Pb dating is valid for lakes in the PIRLA study, although application of the model is equivocal in a few lakes.²¹⁰Pb inventories and profiles are replicable among closely spaced cores within a lake. Specific²¹⁰Pb activity in surface sediments is negatively correlated with bulk sediment accumulation rate in seepage lakes, but not in drainage lakes. Drainage lakes with lower pH have lower unsupported²¹⁰Pb inventories in sediments, but the relationship does not occur in seepage lakes.²¹⁰Pb profiles in only seven of the cores, all from either the Adirondacks or the northern Great Lakes states, exhibit exponential decay curves. Deviations from an exponential profile include a flattening of the profile in the top few cm or excursions of one or a few measurements away from an exponential curve.²¹⁰Pb dates typically agree with other chronostratigraphic markers, most of which are subject to greater uncertainty. Several hypotheses, including sediment mixing, hydrologic regime, sediment focusing, and acidification, are proposed to explain variation of²¹⁰Pb distribution among lakes and regions. Hydrologic factors exert control on unsupported²¹⁰Pb inventories in PIRLA lakes, and there is a strong focusing effect in drainage lakes but a weak focusing effect in seepage lakes.This is the third of a series of papers to be published by this journal following the 20^th anniversary of the first application of²¹⁰Pb dating of lake sediments. Dr P. G. Appleby is guest editing this series.     

Highly variable sediment distribution in shallow, wind-stressed lakes: a case for sediment-mapping surveys in paleolimnological studies

We examine sediment distribution patterns in seven Florida lakes and discuss implications for paleolimnological studies of shallow, subtropical lakes. The study lakes are highly productive and should exhibit thick organic sediment deposits, but organic sediments are often grossly lacking because basins are shallow, and frequent mixing, lack of stratification, and warm temperatures lead to breakdown of organic material.Organic sediment distribution patterns are highly variable. We observe three types of distribution patterns. When organic sediments are abundant, there may be (1) uniform sediment distribution. In lakes lacking organic sediments, there are (2) distribution to deeper areas if present, or (3) distribution to peripheral areas and embayments when deep waters are absent. We advocate the use of systematic mapping surveys to locate optimal coring sites for paleolimnological studies of shallow, wind-stressed lakes. Because numerous factors affect diagenesis and sediment redistribution, sediment abundance and location are not predictable. Sediment chronologies may be discontinuous and disturbed even in accumulation zones. The extent to which sedimentary records are discontinuous or disturbed is not quantifiable in any practical manner. ²¹⁰Pb and ¹³⁷Cs radioisotopic profiles provide qualitative evidence of the degree of stratigraphic disturbance. Total excess ²¹⁰Pb inventories show that sediments are focused into depositional zones when sediment distribution is uneven. Excess ²¹⁰Pb inventories are not informative about the completeness of sedimentary profiles unless small inventories suggest discontinuous sedimentation or erosional events. We present examples of disturbed and undisturbed profiles, and discuss how we use radioisotopic and geochemical evidence, and multiple cores to assess stratigraphic continuity.Journal Series No. R-04815 of the Florida Agricultural Experiment Station.     

How reliable is the210Pb dating method? Old and new results from Switzerland

We present a historical overview of applications of²¹⁰Pb dating in Switzerland with a special emphasis on the work performed at the University of Bern. It is demonstrated that the average specific activity of²¹⁰Pb in the lower atmosphere is very constant and does not show seasonal variations. We then concentrate on new results from Lobsigensee, a very small lake, and on published and new data from Lake Zurich. Several²¹⁰Pb profiles from these lakes show obvious disturbances and a disagreement of the resulting sedimentation rate when compared to that for the 23 years defined by¹³⁷Cs peaks of 1986 (Chernobyl) and 1963 (bomb fallout).A mean sedimentation rate of about 0.14 g cm^–2 y^–1 is found in the oxic and suboxic center part of Lake Zurich. In the oxic locations, the²¹⁰Pb flux to the sediments was close to the atmospheric input of about 1/60 Bq cm^–2 y^–1. In other parts of the lake a significant deficit in the inventory of²¹⁰Pb was found in the sediments. This could be due to a chemical redissolution of²¹⁰Pb together with Mn under reducing conditions. In contrast, in the suboxic part of the lake (135 m depth) the flux of²¹⁰Pb was about twice the atmospheric input. This excess is not caused by allochthonous contributions and is tentatively explained by the transport of sediment material resulting from small slides at the very steep lake shores or more probably by reprecipitation of²¹⁰Pb together with Mn when the conditions in the lake water become locally and seasonally more oxidizing. Dissolved²¹⁰Pb may migrate from locations with reducing conditions and reprecipitate under more oxic conditions. Indeed, a correlation of Mn and²¹⁰Pb in sediments of Lake Zurich was found.This is the first of a series of papers to be published by this journal following the 20^th anniversary of the first application of²¹⁰Pb dating of lake sediments. Dr P. G. Appleby is guest editing this series.     

Sediment focusing in six small lakes inferred from radionuclide profiles

Sediment focusing in six small lake basins is inferred from sedimentary radionuclide profiles. The activities of¹³⁷Cs and⁹⁺²⁴⁰Pu do not decrease to zero above the sub-surface maximum but tail off gradually. Similar behavior is observed in the sediments of three lakes for¹³⁴Cs and⁶⁰Co, which were added only to the lake. This upward tailing is not caused by bioturbation or erosion from the watershed. Sediment focusing is the likely cause, further substantiated by inventories in deep sediments of⁹⁺²⁴⁰Pu and²¹⁰Pb that are twice as high as expected from atmospheric fallout. Inventories in deep sediments of¹³⁷Cs are in several cases lower than expected from atmospheric fallout, and cannot be explained by hydraulic flushing from the lakes, as this would require unreasonable flushing rates. The low¹³⁷Cs inventories and the sedimentary profiles of the¹³⁷Cs/⁹⁺²⁴⁰Pu ratio are consistent with¹³⁷Cs removal from the water column by boundary scavenging to shallow sediments. The profiles and inventories of all three nuclides could be reproduced with a simple three box model, assuming focusing of shallow sediments (50–60% of total sediment area) to deep sediments with a rate constant of 5–10% yr^–1.This is the seventh of a series of papers to be published by this journal following the 20 ^th anniversary of the first application of²¹⁰Pb dating of lake sediment. Dr P. G. Appleby is guest editing this series.     

Historical rates of sediment and nutrient accumulation in marshes of the Upper St. Johns River Basin, Florida, U.S.A.

We used 210Pb-dated sediment cores from wetlands and Blue Cypress Lake, in the Upper St. Johns River Basin (USJRB), Florida, USA, to measure historical accumulation rates of bulk sediment, total carbon (C), total nitrogen (N), and total phosphorus (P). Marsh cores displayed similar stratigraphies with respect to physical properties and nutrient content. Wetland sediments typically contained > 900 mg organic matter (OM) g^–1 dry mass, > 500 mg C g^–1, and 30–40 mg N g^–1. OM, C, and N concentrations were slightly lower in uppermost sediments of most cores, but displayed no strong stratigraphic trends. Total P concentrations were relatively low in bottommost deposits (0.01–0.11 mg g^–1), but ranged from 0.38–2.67 mg g^–1 in surface sediments. The mean sediment accretion rate in the marsh since ~ 1900, 0.33 ± 0.05 cm yr^–1, was calculated from ten ²¹⁰Pb-dated cores. All sites displayed increases in accumulation rates of bulk sediment, C, N, and P since the early part of the 20th century. These trends are attributed to recent hydrologic modifications in the basin combined with high nutrient loading from agricultural, residential, and urban sources.     

210Pb and 137Cs dating methods in lakes: A retrospective study

²¹⁰Pb has been used for more than two decades to provide the geochronology of annually deposited sediments and to construct pollution histories. Evidence from some lakes suggests that this radionuclide may be adequately mobile to compromise dating reliability. This study provides one test of that possibility by comparing recent measurements of ²¹⁰Pb and trace metals to ones carried out more than 20 yrs in the past. ¹³⁷Cs dating is used to confirm sediment accumulation rates in the recent cores. In the three Connecticut, USA, lakes studied, sediment accumulation rates changed abruptly to higher values between 40-50 yrs ago (increasing by factors of 2.2, 2.9, and 3.0). In all three lakes, rates calculated from ²¹⁰Pb distributions both above and below this horizon agreed, within measurement uncertainty, in recent and older cores. Furthermore, when the older data were corrected for 20 yrs of burial, the changes in slope in ²¹⁰Pb distributions occurred at the same depth in each pair of cores. The depth of sharp peaks in concentrations of trace metals also matched. In general, this evidence supports the idea that sediments in these lakes have simply been buried, without significant diagenetic remobilization of ²¹⁰Pb and trace metals . Nevertheless, some important differences were also observed. For two of the three lakes, there was a significant difference in average sediment accumulation rate during the past 33 yrs as calculated from ¹³⁷Cs and ²¹⁰Pb in the recent cores. Most potential causes for this difference can be ruled out, and it appears that one of the two nuclides is remobilized compared to the other. There were also significant differences in the total inventories of both ²¹⁰Pb and trace metals (both up to 2 ×) between recent and older cores in some cases. This may be due to dissimilar sediment focusing, since it is not known for certain whether the new cores were collected at exactly the same sites as in the past.     

南极普里兹湾海域铀系同位素的分布

本文报道了南极普里兹湾海域U、2 2 6Ra、2 1 0 Pb、2 1 0 Po的分布以及2 34U/2 38U和2 1 0 Po/2 1 0 Pb放射性比值。研究结果表明 ,该海域表层水中的铀同位素分布基本均匀 ,铀含量范围为1 3 2 8- 1 4 2 0 μmol·m- 3,平均值为 ( 1 3.82± 0 .2 9) μmol·m- 3,2 34U/2 38U平均放射性比值为1 1 4± 0 0 3。铀含量与盐度之间存在良好的相关性 ,其相关系数达 0 895。该海域溶解态2 2 6Ra比活度范围为 1 37- 1 78Bq·m- 3,平均值为 1 5 5Bq·m- 3;颗粒态 2 2 6Ra比活度范围为0 0 0 6- 0 0 35Bq·m- 3,平均值为 0 0 1 5Bq·m- 3;2 1 0 Po比活度 0 80- 1 5 2Bq·m- 3,平均 1 1 4Bq·m- 3;2 1 0 Pb比活度 1 34- 2 1 5Bq·m- 3,平均 1 66Bq·m- 3;2 1 0 Po/2 1 0 Pb的放射性比值0 5 5- 0 84,平均 0 69。并对2 1 0 Po和2 1 0 Pb的不平衡作了讨论。还研究了 1个站位溶解态和颗粒态2 2 6Ra、2 1 0 Pb的深度分布及2 1 0 Pb在两相中的分配     

Distribution coefficients of210Pb and210Po in laboratory and natural aquatic systems

We have measured the distribution coefficient (Kd) of²¹⁰Po and²¹⁰Pb in laboratory systems and in natural freshwater systems. In the laboratory systems, an inverse relationship was observed between the particle concentration of sand or lake sediment, and the distribution coefficients of²¹⁰Po and²¹⁰Pb. The slope of the log-linearK _d vs particle concentration relation is consistent with existingK _d-particle concentration theories. These laboratory observations are consistent with similar measurements in two lakes. TheK _d values of Po and Pb for the bottom sediment-pore water system with a high particle concentration were 10 to 100 times lower than those for dilute concentrations of particles suspended in the lake water. TheK _d of²¹⁰Pb in the sediments was >10⁴ so that the diffusive transport of²¹⁰Pb has only a small influence on the interpretation of²¹⁰Pb concentration-depth profiles and the²¹⁰Pb dating of these sediments.This is the second of a series of papers to be published by this journal following the 20^th anniversary of the first application of²¹⁰Pb dating of lake sediments. Dr P. G. Appleby is guest editing.     

Radiometric dating of lake sediments from Signy Island (maritime Antarctic): evidence of recent climatic change

Sediment cores from three lakes (Moss, Sombre and Heywood) in the maritime Antarctic (Signy Island, South Orkney Islands) have been successfully dated radiometrically by²¹⁰Pb and¹³⁷Cs. The core inventories of both fallout radionuclides are an order of magnitude higher than that which can be supported by the direct atmospheric flux at this latitude. The elevated values may be explained by fallout onto the catchment during the winter being delivered directly to the lakes during the annual thaw. Two of the lakes (Sombre and Heywood) show marked increases in sediment accumulation afterc. 1950. This appears to be associated with a documented rise in temperature in the South Orkney Islands, which has caused extensive deglaciation at Signy Island.This is the tenth of a series of papers to be published by this journal following the 20 ^th anniversary of the first application of²¹⁰Pb dating of lake sediments. Dr P.G. Appleby is guest editing this series.     

Sediment heavy metal record in Lake Baikal: natural and antrhopogenic sources

Geochemical analysis of six radiometrically dated short cores of recent sediment from Lake Baikal shows clear evidence of enhanced Pb supply. However, the sediment concentration increases are very small; the average Pb concentration rises from a baseline value of 10.9 g g^-1 to a peak value of only 14.8 g g^-1. In contrast to the more polluted lakes commonly studied in Europe and North America, variation in Pb concentration is far more strongly influenced by natural variation than by pollution. In sediment deposited over the last 150–200 years 73% of the variance in the sediment Pb concentration can be accounted for by variation in bulk composition of the sediment, and by atmospheric pollution. Factors influencing Pb concentrations over this time period are, in order of decreasing average importance (fraction of total variance explained), catchment supply (indicated by ²²⁶Ra activity variation) (43%), anthropogenic Pb emissions (24%), and dilution by ferromanganese hydroxides (6%). On longer (1000s of years) time scales dilution by biogenic silica is probably more important.The recent enhanced supply of catchment Pb correlates with accelerating accumulation rates, indicating a link with enhanced erosion. Anthropogenic sources dominate only in the southern basin, where local fossil-fuel burning industry is situated. The evidence for a local industrial source for the Pb pollution is strengthened by the high correlation between the inventories for Pb and for spheroidal carbonaceous particles. The absence of detectable anthropogenic Pb enrichment in the northern part of the lake suggests that long-distance Pb pollution is small compared with the local natural supply.     

The sedimentary record of spheroidal carbonaceous fly-ash particles in shallow Danish lakes

Spheroidal carbonaceous particles (SCP) from combustion of oil and coal have been quantified in cores from top sediments of Danish shallow lakes. Chronologies were provided by ²¹⁰Pb-dating supplemented by measurements of other radionuclides (¹³⁷Cs, ¹³⁴Cs, ²⁴¹Am). All cores show indications of sediment mixing but most still retain a characteristic SCP record. Deposition rates of SCP were low until the 1920s, increased strongly after World War II, reached maximum levels around 1970 and decreased thereafter. These results were used to infer a new chronology for a sediment core from a shallow lake, from which a ²¹⁰Pb chronology had previously been published.SCP inventories are positively correlated with ²¹⁰Pb inventories and dry matter accumulated since 1900, suggesting that absolute SCP accumulation rates may be more influenced by sedimentary processes than by atmospheric fluxes. The concentrations of SCP in surface sediments of the six lakes do, however, correlate with regional SO₂ emissions.     

Environmental Change and Atmospheric Contamination on Svalbard: Sediment Chronology

Sediment cores collected from eight lakes along the western coast of Svalbard as part of a project investigating atmospheric pollution and environmental change in Arctic regions were dated radiometrically using natural (²¹⁰Pb) and artificial (¹³⁷Cs and ²⁴¹Am) fallout radionuclides. At four sites the sedimentation rates were relatively uniform, and in consequence the ²¹⁰Pb dates were relatively unambiguous. At the remaining sites there were irregularities in the ²¹⁰Pb activity versus depth profiles, indicating significant variations in the net sediment accumulation rate during the past 120 years. At these sites, there were significant differences between ²¹⁰Pb dates calculated using the two standard simple dating models, constant rate of supply (CRS) and constant initial concentration (CIC). In most cases, stratigraphic dates based on the ¹³⁷Cs and ²⁴¹Am records supported use of the CRS model, though at one site (Ossian Sarsfjellet) the CIC model appeared more appropriate. The irregularities in the ²¹⁰Pb records were mainly caused by episodes of accelerated sedimentation due, for example, to inwash or slump events, though at some sites there appears to have been a systematic increase in sediment accumulation rates in recent decades. Sediment accumulation rates were generally lower at the northern sites, and higher at the more southerly locations. Mean sediment accumulation rates varied by an order of magnitude, ranging from 0.002 to 0.050 g cm⁻² y⁻¹ (0.02–0.10 cm y⁻¹). ²¹⁰Pb fluxes measured from the core inventories were mostly in the range 34–80 Bq m⁻² y⁻¹ typical of Arctic sites. Much higher values, recorded at two sites (Birgervatnet and Daltjørna), may be due to significant inputs from the catchments during spring thaw.     

Baptiste Lake,Alberta — A late Holocene history of changes in a lake and its catchment in the southern Boreal forest

Lead-210 assay and dating are subject to several sources of error, including natural variation, the statistical nature of measuring radioactivity, and estimation of the supported fraction. These measurable errors are considered in calculating confidence intervals for ²¹⁰Pb dates. Several sources of error, including the effect of blunders or misapplication of the mathematical model, are not included in the quantitative analysis. First-order error analysis and Monte Carlo simulation (of cores from Florida PIRLA lakes) are used as independent estimates of dating uncertainty. CRS-model dates average less than 1% older than Monte Carlo median dates, but the difference increases non-linearly with age to a maximum of 11% at 160 years. First-order errors increase exponentially with calculated CRS-model dates, with the largest 95% confidence interval in the bottommost datable section being 155±90 years, and the smallest being 128±8 years. Monte Carlo intervals also increase exponentially with age, but the largest 95% occurrence interval is 152±44 years. Confidence intervals calculated by first-order methods and ranges of Monte Carlo dates agree fairly well until the ²¹⁰Pb date is about 130 years old. Older dates are unreliable because of this divergence. Ninety-five per cent confidence intervals range from about 1–2 years at 10 years of age, 10–20 at 100 years, and 8–90 at 150 years old.This is the third of a series of papers to be published by this journal which is a contribution of the Paleoecological Investigation of Recent Lake Acidification (PIRLA) project. Drs. D.F. Charles and D.R. Whitehead are guest editors for this series.     

A chronological assessment of Lake Okeechobee (Florida) sediments using multiple dating markers

Reconstructing recent limnological history often relies on lead-210 dating to accurately ascribe a chronology to a sediment profile. In Lake Okeechobee, Florida, a large, shallow subtropical lake that may experience severe mixing, multiple dating methods are required to confirm that conformable sedimentation has been preserved and that the assumptions of the ²¹⁰Pb method are satisfied. This study uses stratigraphic profiles of heavy metals, ¹³⁷Cs, PCBs and pollen as independent dating markers to validate the sediment chronology as determined by ²¹⁰Pb for three cores from the central mud zone of the lake. Unsupported ²¹⁰Pb and most dating markers show distinct concentration/depth profiles, suggesting that the sediments have not been severely mixed for at least the last 75 years. Onset and maximum activity of the radioisotope ¹³⁷Cs in the cores coincides with the ²¹⁰Pb-dated interval of 1945–1970. This agrees well with the known timing of atmospheric deposition of ¹³⁷Cs that resulted from above-ground nuclear testing during late 1940s until 1963. Sediment core profiles of atmospherically deposited metals such as Zn and Pb, which reflect regional increases during industrialization and decreases after regulation in the 1970s, exhibit expected concentration increases and peaks coinciding within 5–15 years of the predicted ²¹⁰Pb dates. Uranium, a contaminant in some phosphate fertilizers, shows large concentration increases at core depths dated to be about 1950 by ²¹⁰Pb, matching the intensification of agriculture after WWII. PCBs, which are expected to peak in the early 1970s, were measured in one core, and the observed peak corresponds to a ²¹⁰Pb date of about 1960. Pollen makers were unable to verify specific events, but increases in disturbance taxa and declines in native types correspond generally with the expected dates assigned by ²¹⁰Pb dating. Conformity between the ²¹⁰Pb defined dates and independent markers of < ±15 years confirm that Lake Okeechobee sediments do preserve a sequential and reliable stratigraphic history of the lake, useful for reconstructing past limnological conditions.     

Evaluation of210Pb dating in lake sediments using stable Pb,Ambrosia pollen,and137Cs

We used sediment chronology data from fourteen published studies of lake cores across much of North America and Scandinavia in order to make a large scale comparison of the different dating techniques. The uncertainty of²¹⁰Pb derived dates was determined using common sediment event markers: the stable Pb rise, the¹³⁷Cs rise, and theAmbrosia pollen rise. For all data combined, the 95% confidence intervals for the stable Pb rise and theAmbrosia rise, were approximately 30 years. These 95% confidence intervals are slightly higher than those derived by First-Order Error analysis performed by others on²¹⁰Pb derived dates. When comparing the concordance of two²¹⁰Pb models (CRS and CIC) against markers of known history, we found that the CRS model dates (constant rate of supply) had consistently better agreement than the CIC model dates (constant initial concentration). Major discrepancies between¹³⁷Cs and²¹⁰Pb were common, but were consistently more severe in sediments of soft water lakes pointing to an inability of sediments with low mineral content to immobilize Cs.This is the ninth of a series of papers to be published by this journal following the 20 ^th anniversary of the first application of²¹⁰Pb dating of lake sediments, Dr. P. G. Appleby is guest editing this series.     

Distribution of <Superscript>137</Superscript>Cs and <Superscript>210</Superscript>Pb in sediments of tidal flats in north Jiangsu Province

Seven cores were collected from different sediment zones of tidal flats at Xinyanggang in north Jiangsu province in August 2007. Sediment grain-size distribution and radioisotopes of ¹³⁷Cs and ²¹⁰Pb analysis were carried out for these cores. Sediment rates of the cores and radioisotopes distribution in surface sediment in different zones of the tidal flat were calculated from the ¹³⁷Cs and ²¹⁰Pb activities in sediments cores. The results indicated that each tidal zone had experienced different evolution phases, hydrological dynamics in the tidal flats made the grain-size of the surface sediment change gradually. ¹³⁷Cs and ²¹⁰Pb activities on the superficial layer of the cores varied spatially and the reason was discussed. On tidal flats, the fluctuation of ¹³⁷Cs and ²¹⁰Pb activities in the cores reflected the special sedimentary characteristics. Vegetation affects the grain-size distribution and the vertical profiles of ¹³⁷Cs and ²¹⁰Pb in the upper depths. ¹³⁷Cs and ²¹⁰Pb chronology got the comparable average sediment rates on the tidal flat. The characteristics of ¹³⁷Cs and ²¹⁰Pb in the cores reflected various depositional dynamical environments in different tidal zones and gave information on the different evolvement phases of the tidal zones. Based on the information of grain-size distribution, texture of the cores, sediment rates and topography, the evolution lines of the tidal flat were reconstructed.     

Sources and chronology of fifteen elements in the sediments of lakes affected by metal deposition in a mining area

Sources and chronologies of metal contamination were studied in sediment cores of three lakes of the Rouyn-Noranda mining area (Québec, Canada) affected by atmospheric deposition of anthropogenic contaminants. One of the three lakes also received acid mine drainage. The sediments were dated using ²¹⁰Pb and ¹³⁷Cs and analysed for stable Pb isotope ratios and for total concentrations of 15 elements (Ag, Al, Au, Ca, Cu, Cd, Fe, Hg, Mn, Ni, P, Pb, S, Ti, Zn). Stable lead isotopic signatures helped to determine the quantitative contributions of different industrial Pb sources to our sampling sites. This source apportionment showed the dominant influence of the Rouyn-Noranda copper smelter in airborne Pb emissions for the decades following 1926, when industrialization began in the region. The smelter source had a low ratio of ²⁰⁶Pb/²⁰⁷Pb ranging between 0.90 and 1.05, as typical of the Abitibi Archean sulphides. The relationships between element (metal) sedimentary fluxes and anthropogenic Pb fluxes allowed us to infer the origin of the anthropogenic source. These relationships strongly suggest that the copper smelter was (and may still be) an atmospheric source of Cd, Cu, Pb, Zn, Ag and Hg to the surrounding lakes. Our study indicates that the efforts made by the Rouyn-Noranda copper smelter to reduce airborne emissions of metals have been translated in reduced atmospheric metal loadings to the surrounding lakes.     

Difficulties in interpreting fast mixing in the radiometric dating of sediments using 210Pb and 137Cs

²¹⁰Pb geochronologies should be validated with independent tracers such as ¹³⁷Cs. In the cases with constant ²¹⁰Pb activity in the topmost sediments, the presence of a distinct ¹³⁷Cs peak within the ²¹⁰Pb plateau has been used as a definitive demonstration of acceleration (increase in the sedimentation rate in recent years) versus fast mixing. Nevertheless, some limitations can be identified in the use of semiquantitative arguments, and a global understanding of the whole ¹³⁷Cs activity profile is then required. Particularly, the incomplete mixing within the top sediment zone (described through the Incomplete Mixing Zone model) can explain quantitatively and simultaneously the ¹³⁷Cs peak and the flattening in the ²¹⁰Pb activity profile. This is demonstrated using selected examples from literature data. Thus, measured constant ²¹⁰Pb activities in the top 6 cm of a sediment core from Lake Zürich. Nevertheless, they found ⁷Be only in the uppermost layer, the distinct ¹³⁷Cs maximum at 6 cm depth, and undisturbed varves. The fast mixing seemed then opposed to common sense. The constant rate of supply model shows acceleration and it adequately matches the position of the 1963 ¹³⁷Cs peak. Nevertheless it fails to explain the whole ¹³⁷Cs profile when handling time series of ¹³⁷Cs atmospheric deposition. Finally, it is shown how the incomplete mixing of the activity (through the pore water) over a certain mass depth at the top sediment, with a finite value of the mixing coefficient, can quantitatively explain the whole activity versus mass depth profiles of ¹³⁷Cs and ²¹⁰Pb, and the presence of ⁷Be only in the uppermost sediment layer. A further validation of these ideas is presented from other literature data.