Rare earth, major and trace elements in Jurassic manganese shales of the Northern Calcareous Alps: hydrothermal versus hydrogenous origin of stratiform manganese deposits

Summary ?The rare earth, major and trace element geochemistry of Jurassic deep marine manganese shales allow insight into their environment of deposition. We present data of 24 samples from the Northern Calcareous Alps (Eastern Alps), collected from Late Jurassic strata of the Tennengebirge and from Early Jurassic strata of the Karwendel Mts. Whereas major and trace element geochemistry is controlled by the detrital input, rare earth element data and the relationship between total organic carbon and (pyritic) sulfur can be used to constrain the origin of the manganese accumulation. The data of this study are compatible with a hydrogenous precipitation of manganese by strongly varying redox-conditions at the sediment–water interface of a slope basin. Received December 21, 2001; revised version accepted February 18, 2002     

Late Jurassic tectonics and sedimentation: breccias in the Unken syncline,central Northern Calcareous Alps

This study analyses and discusses well preserved examples of Late Jurassic structures in the Northern Calcareous Alps, located at the Loferer Alm, about 35 km southwest of Salzburg. A detailed sedimentary and structural study of the area was carried out for a better understanding of the local Late Jurassic evolution. The Grubhörndl and Schwarzenbergklamm breccias are chaotic, coarse-grained and locally sourced breccias with mountain-sized and hotel-sized clasts, respectively. Both breccias belong to one single body of breccias, the Grubhörndl breccia representing its more proximal and the Schwarzenbergklamm breccia its more distal part, respectively. Breccia deposition occurred during the time of deposition of the Ruhpolding Radiolarite since the Schwarzenbergklamm breccia is underlain and overlain by these radiolarites. Formation of the breccias was related to a major, presumably north-south trending normal fault scarp. It was accompanied and post-dated by west-directed gravitational sliding of the Upper Triassic limestone (“Oberrhätkalk”), which was extended by about 6% on top of a glide plane in underlying marls. The breccia and slide-related structures are sealed and blanketed by Upper Jurassic and Lower Cretaceous sediments. The normal fault scarp, along which the breccia formed, was probably part of a pull-apart basin associated with strike slip movements. On a regional scale, however, we consider this Late Jurassic strike-slip activity in the western part of the Northern Calcareous Alps to be synchronous with gravitational emplacement of “exotic” slides and breccias (Hallstatt mélange), triggered by Late Jurassic shortening in the eastern part of the Northern Calcareous Alps. Hence, two competing processes affected one and the same continental margin.     

Evidence for Jurassic subduction from the Northern Calcareous Alps (Berchtesgaden; Austroalpine,Germany)

The closure of the western part of the Neotethys Ocean started in late Early Jurassic. The Middle to early Late Jurassic contraction is documented in the Berchtesgaden Alps by the migration of trench-like basins formed in front of a propagating thrust belt. Due to ophiolite obduction these basins propagated from the outer shelf area (=Hallstatt realm) to the interior continent (=Hauptdolomit/Dachstein platform realm). The basins were separated by nappe fronts forming structural highs. This scenario mirrors syn-orogenic erosion and deposition in an evolving thrust belt. Active basin formation and nappe thrusting ended around the Oxfordian/Kimmeridgian boundary, followed by the onset of carbonate platforms on structural highs. Starved basins remained between the platforms. Rapid deepening around the Early/Late Tithonian boundary was induced by extension due to mountain uplift and resulted in the reconfiguration of the platforms and basins. Erosion of the uplifted nappe stack including obducted ophiolites resulted in increased sediment supply into the basins and final drowning and demise of the platforms in the Berriasian. The remaining Early Cretaceous foreland basins were filled up by sediments including siliciclastics. The described Jurassic to Early Cretaceous history of the Northern Calcareous Alps accords with the history of the Western Carpathians, the Dinarides, and the Albanides, where (1) age dating of the metamorphic soles prove late Early to Middle Jurassic inneroceanic thrusting followed by late Middle to early Late Jurassic ophiolite obduction, (2) Kimmeridgian to Tithonian shallow-water platforms formed on top of the obducted ophiolites, and (3) latest Jurassic to Early Cretaceous sediments show postorogenic character.     

The change from rifting to thrusting in the Northern Calcareous Alps as recorded in Jurassic sediments

Facies analysis, fossil dating, and the study of the metamorphism in the Late Triassic to Early Cretaceous sedimentary successions in the central part of the Northern Calcareous Alps allow to reconstruct the tectonic evolution in the area between the South Penninic Ocean in the northwest and the Tethys Ocean with the Hallstatt Zone in the southeast. The Triassic as well as the Early and Middle Jurassic sediments were deposited in a rifted, transtensive continental margin setting. Around the Middle/Late Jurassic boundary two trenches in front of advancing nappes formed in sequence in the central part of the Northern Calcareous Alps. The southern trench (Late Callovian to Early Oxfordian) accumulated a thick succession of gravitatively redeposited sediments derived from the sedimentary sequences of the accreted Triassic–Liassic Hallstatt Zone deposited on the outer shelf and the margin of the Late Triassic carbonate platform. During a previous stage these sediments derived from sequences deposited on the more distal shelf (Salzberg facies zone of Hallstatt unit, Meliaticum), and in a later stage from more proximal parts (Zlambach facies zone of Hallstatt unit, Late Triassic reef belt). Low temperature–high pressure metamorphism of some Hallstatt limestones before redeposition is explained by the closure of parts of the Tethys Ocean in Middle to Late Jurassic times and associated subduction. In the northern trench (Late Oxfordian to Kimmeridgian) several hundred meters of sediment accumulated including redeposited material from a nearby topographic rise. This rise is interpreted as an advancing nappe front as a result of the subduction process. The sedimentary sealing by Tithonian sediments, documented by uniform deep-water sedimentation (Oberalm Formation), gives an upper time constraint for the tectonic events. In contrast to current models, which propose an extensional regime for the central and eastern Northern Calcareous Alps in the Late Jurassic, we propose a geodynamic model with a compressional regime related to the Kimmerian orogeny.     

Facies distribution of the Lower Cambrian cryptic microbial and epibenthic archaeocyathan-microbial communities, western Anti-Atlas, Morocco

Marine microbial communities recorded in the Moroccan Anti‐Atlas were unaffected across the Neoproterozoic–Cambrian transition. A stromatolite‐dominated consortium was replaced at the beginning of the Atdabanian (ca 20 Myr after the Neoproterozoic–Cambrian boundary) by shelly metazoan and thromboid consortia, which contain the oldest biostratigraphically significant fossils of the Moroccan Cambrian. The associated collapse of microbial mat (stromatolitic) growth appears to coincide with a change from pre‐Atdabanian shallow‐water restricted conditions into Atdabanian deeper, open‐sea conditions. It is postulated that this environmental change led to an episode of improved water circulation over carbonate platform interiors, promoting shelly metazoan immigration into the region. The Tiout/Amouslek lithostratigraphic contact in the early Atdabanian marks the end of an episodically unstable seafloor as suggested by the abundance of slumping and sliding structures, and synsedimentary microfaults and cracks recorded in the underlying Tiout Member. Concurrent with the transition is the occurrence of a network of cryptic fissures and cavities that provided habitats for a coelobiontic chemosynthetic–heterotrophic microbial community composed of stromatolitic crusts, Renalcis–Epiphyton–Girvanella intergrowths, and Kundatia thalli. In the overlying Amouslek Formation, archaeocyathan–thromboid reefs were constrained by substrate stability, water depth and subsidence rate. Four reef geometries are distinguished: (i) patch reefs surrounded by shales, (ii) bioherms in which flank beds intercalate laterally with carbonate and shale inter‐reef sediments, (iii) biostromes or low‐relief structures formed as a result of lateral accretion of patch reefs, and (iv) kalyptrate complexes that nucleated because of a marked tendency for aggregation, and in which patch reefs and bioherms occur stacked together bounded by clay–marl–silt seams.     

Sublacustrine hydrothermal seeps and silicification of microbial bioherms in the Ediacaran Oued Dar'a caldera,Anti‐Atlas,Morocco

This paper presents a case study of the sublacustrine precipitation of hydrothermal silica ± TiO₂ in the Ediacaran Mançour Group of the Saghro inlier, Anti‐Atlas, Morocco. Lacustrine carbonates containing stromatolitic mats and bioherms occur in ephemeral ponds developed within the Oued Da'ra caldera. Its syn‐eruptive infill consists of pyroclastites, ashflow tuffs, and subsidiary lava flows and sills, whereas inter‐eruptive deposition is mainly represented by slope‐related debris‐flow breccias and landslides, alluvial fans and fluvial channels. Carbonate production took place in a mosaic of differentially subsiding, fault‐bounded intra‐caldera blocks controlled by episodic collapse‐induced drowning, pyroclastic blanketing and migration of alluvial/fluvial environments. After microbial carbonate production, the carbonates recorded several early‐diagenetic processes, punctuated by polyphase fissuring (controlling secondary permeability) locally linked to hydrothermal influx. Three generations of carbonate cements are recognisable: (i) fibrous, botryoidal and blocky/drusy mosaics of calcite; (ii) idiotopic mosaics of dolomite caused by flushing of hypersaline Mg‐rich brines; and (iii) euhedral to drusy calcite via dedolomitization. The δ¹³C and δ¹⁸O values from carbonate cements broadly become successively isotopically lighter, as a result of meteoric and hydrothermal influence, and were probably overprinted by the Panafrican‐3 phase that affected the top of the Mançour Group. Two mechanisms of silicification are involved: (i) early‐diagenetic occlusion of interparticle pores at the sediment/water interface of pyroclastic substrates and reefal core and flanks; and (ii) hydrothermal precipitation of silica ± TiO₂ lining fissures and vuggy porosity encased in the host rock. Silica conduits cross‐cutting lacustrine mats and bioherms exhibit high potential of preservation in collapsed volcanic calderas. Primary fluid inclusions of hydrothermal silica contain brine relics with NaCl/CaCl₂ ratios of 2·1 to 4·4, representing minimum entrapment temperatures of about 142 to 204°C, and abiotic hydrocarbons (heavy alkanes) related to serpentinization of the volcanic and volcanosedimentary basement of the Oued Dar'a caldera.     

Faulting and fracturing in the Jurassic carbonate ramp folds of southern Rif ridges (Northern Morocco)

In the South Rifian ridges (SRR), the dominated structures correspond to the faulted anticline characteristic of a foreland orogeny context, front of the Rif Alpine belt. These anticlines correspond to thrust propagation folds. Geometric model of these structures shows that the normal faults have controlled the Mesozoic sedimentation during extensive episodes and participated in determining areas of thrusting during Miocene compressional phases. However, the normal fault strike which is relative to the direction of the shortening determined the geometry of diverse folds whether into the frontal ramps, lateral, or oblique. In the meantime, the systematic fracturing study in the Jurassic limestone beds, in different parts of the folds with axes oriented E-W, NW-SE, and NE-SW, permits to propose a relative fracturing chronology and tries investigating the relationship between folding and fracturing. The three main fracture families, oblique, transversal, and axial, appear simultaneously during the amplification of the fold. The simple shear in the limb contributes the latest to the folding reactivation and the density of the intensification of these microfractures. Likewise, given the important downslope fold limb dip of the ramp propagation folds, theoretically the shear intensity is more important, and micro-fractures are more important in the downslope fold limb, thus the uphill one.     

Structural synthesis of the Northern Calcareous Alps, TRANSALP segment

The Northern Calcareous Alps (NCA) are the site of very large top-to-north convergent movements during Cretaceous–Tertiary Alpine mountain building. To determine the amount of shortening, the depth of detachment and the style of deformation, we retro-deformed an approximately 40 × 40 km area comprising the Lechtal and Allgäu Nappes. On the basis of all available geological data and processed sections of the TRANSALP reflection seismic experiment, coherent 3D models were constructed by splining lines from N–S cross-sections. Integration of 3D kinematic modeling and field data shows the following. The structure of the Lechtal Nappe is controlled by the Triassic Hauptdolomit. Four main thrusts link to a detachment at 2–6 km depth below sea level. Shortening estimates vary, from 25% (east) to 42% (west). Additional contraction is accommodated by folding. In the east the subjacent Allgäu Nappe can be traced about 10 km down-plunge, and is shortened by about one third. In the western part the downplunge width is at least 15–20 km, with restorable shortening of one third. The triple (Inntal, Lechtal, Allgäu Nappes) NCA nappe system was moved uniformly N–S to produce laterally heterogeneus shortening of 40–90 km or 50–67%. We suggest that the NCA are underlain by substantial amounts of buried Molasse sediments and/or overthrust units of Helvetic and Rheno-Danubian Flysch, indicating post-Eocene N–S shortening of at least 55 km. Restored to an initial configuration, the basin topography of the NCA reveals strong E–W thickness variations of the Triassic Wettersteinkalk and Hauptdolomit platform carbonates. Such variations may pertain to N–S trending growth faults, which were important precursors to later Jurassic extension of the Austroalpine passive margin. Such structures are unlikely to be seen in the conventional N–S cross-sections, but form an essential geometrical and mechanical element in later, convergent mountain building.     

Carbonates in Upper Permian evaporites of the Northern Calcareous Alps,Austria

Thin black dolomites occur within the evaporitic Alpine Haselgebirge Formation (Late Permian) of the central and eastern Northern Calcareous Alps, Austria. They have been compared with the southalpine Bellerophon Formation byTollmann (1964). Samples obtained from the gypsum-anhydrite deposit of Wienern am Grundlsee, Styria, are mostly unfossiliferous mudstones (dolomicrite and dolomicrospar) devoid of sedimentary structures. Only few samples contain a low-diversity ostracode fauna. Electron microprobe and X-ray diffraction analysis indicate well-ordered and near-stoichiometric dolomite (49.9±0.2 mol% CaCO₃). The oxygen isotopic composition varies between –3.0 and –5.7 PDB. The ¹³C ratios fall into two distinct groups: –0.9 to +1.9, and –3.5 to –6.8 PDB. The carbon isotope data of the first group indicate a predominantly marine origin of the carbonates. The significantly depleted ¹³C ratios of the second group are probably due to freshwater influx into the basin and/or sulfate reduction. Sulfur and strontium isotope data from intercalated anhydrite and gypsum preclude an entirely non-marine origin of the brines. The light ¹⁸O ratios are probably due to early diagenetic sulfate reduction and/or dolomite recrystallization during moderate burial. A detailed interpretation of the depositional environment is rendered impossible because of the pervasive alpine tectonics. However, northalpine Bellerophon carbonates appear to be restricted to areas of major anhydrite deposition, and are absent in the halitedominated facies.

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Zusammenfassung Im zentralen und östlichen Abschnitt der Nördlichen Kalkalpen Österreichs treten geringmächtige, bituminöse Dolomite im Verband der salinaren Alpinen Haselgebirge Formation (Oberperm) auf. Sie wurden vonTollmann (1964) mit der südalpinen Bellerophon Formation verglichen. Bei den untersuchten Proben von der Gips- und Anhydritlagerstätte Wienern am Grundlsee (Steiermark) handelt es sich fast durchwegs um fossilleere Mikrite und Mikrosparite, die keinerlei Sedimentstrukturen aufweisen. Nur sehr wenige Proben führen Ostrakoden. Nach Mikrosonden-Analysen und röntgendiffraktometrischen Untersuchungen bestehen diese mikrokristallinen Dolomite aus fast stöchiometrischen, gut geordneten Dolomit (49.9±0.2 Mol% CaCO₃). Die Sauerstoffisotopenwerte schwanken von –3.0 bis –5.7 PDB und die ¹³C Verhältnisse fallen in zwei Gruppen: –0.9 bis +1.9, und –3.5 bis –6.8 PDB. Die Werte der ersten Gruppe indizieren eine im wesentlichen marine Bildung der Karbonate. Die deutlich leichteren ¹³C-Werte der zweiten Gruppe können durch Süßwassereinfluß während der Sedimentation und/oder durch Sulfatreduktion erklärt werden. Schwefel- und Strontium-Isotopenwerte, gemessen an Anhydriten und Gipsen im Verband mit den Dolomiten, schließen eine rein nicht-marine Herkunft der Salzlösungen aus. Die negativen ¹⁸O-Verhältnisse der Dolomite sind wahrscheinlich auf diagenetische Prozesse (Sulfatreduktion und/oder Umkristallisation) zurückzuführen. Die enorme alpidische Deformation dieser Evaporitserien gestattet es nicht, das ursprüngliche Ablagerungsmilieu der Karbonate zu rekonstruieren. Die nordalpinen Bellerophon Karbonate scheinen jedoch an Ablagerungsbereiche mit mächtiger Anhydritbildung gebunden zu sein, und fehlen primär in der Halit-dominierten Fazies.

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Résumé En Autriche, dans les secteurs central et oriental des Alpes calcaires du nord, existent des dolomies bitumineuses de faible puissance en relation avec la formation évaporitique alpine de l'Haselgebirge (Permien supérieur).Tollmann (1964) les a comparées à la formation sud-alpine de Bellérophon. Des échantillons provenant des gisements de gypse et d'anhydrite de Wienern sur le Grundlsee (Styrie) montrent des mudstones (dolomicrites à dolomicrosparites) dépourvus de fossiles et de structures sédimentaires. Seuls quelques échantillons contiennent une faune à ostracodes peu diversifiée. Les examens à la microsonde et aux rayons X montrent une dolomite bien ordonnée et quasi-stoechiométrique (49,9±0,2% moléculaire de CaCo₃). La composition isotopique de l'oxygène varie entre –3,0 et –5,7 PDB. Les rapports ¹³C se répartissent en deux groupes: –0,9 à +1,9 et –3,5 à –6,8 PDB. Ces données indiquent pour le premier groupe une origine surtout marine des carbonates. Les valeurs moins élevées des rapports du second groupe sont dues probablement à l'arrivée d'eau douce dans le bassin et/ou à une réduction des sulfates. Les valeurs isotopiques du soufre et du strontium, mesurées sur les gypses et anhydrites associés aux dolomies, excluent une origine entièrement continentale pour les saumures. Les faibles rapports ¹⁸O sont dûs probablement à une réduction diagénétique précoce des sulfates et/ou à la recristallisation de la dolomite pendant l'enfouissement. Une interprétation détaillée des conditions de dépôt est rendue impossible par l'ampleur de la déformation tectonique alpine. Il semble toutefois que des carbonates nord-alpins de type «Bellérophon» soient liés aux aires de forte sédimentation d'anhydrite et soient absents dans les faciès à halite dominante.

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Haselgebirge ( ) . Tollmann (1964) . , Grundlsee, , , - . . - , - , (49.9–0,2 % ₃). –3,0 –5,7% PDB, ¹³C : –0,9 –1,9% –3,5 –6,8% PDB. . / . , , , . ¹⁸ , , : / . . , , » « .

     

The Mantos Blancos copper deposit: an upper Jurassic breccia-style hydrothermal system in the Coastal Range of Northern Chile

The Upper Jurassic Mantos Blancos copper deposit (500 Mt at 1.0% Cu), located in the Coastal Range of northern Chile, displays two superimposed hydrothermal events. An older phyllic alteration probably related to felsic magmatic–hydrothermal brecciation at ∼155 Ma, and younger (141–142 Ma) potassic, propylitic, and sodic alterations, coeval with dioritic and granodioritic stocks and sills, and dioritic dikes. Main ore formation is genetically related to the second hydrothermal event, and consists of hydrothermal breccias, disseminations and stockwork-style mineralization, associated with sodic alteration. Hypogene sulfide assemblages show distinctive vertical and lateral zoning, centered on magmatic and hydrothermal breccia bodies, which constitute the feeders to mineralization. A barren pyrite root zone is overlain by pyrite-chalcopyrite, and followed upwards and laterally by chalcopyrite-digenite or chalcopyrite-bornite. The assemblage digenite–supergene chalcocite characterizes the central portions of high-grade mineralization in the breccia bodies. Fluid inclusions show evidence of boiling during the potassic and sodic alteration events, which occurred at temperatures around 450–460°C and 350–410°C, and salinities between 3–53 and 13–45 wt% NaCl eq., respectively. The hydrothermal events occurred during episodic decompression due to fluid overpressuring, hydrofracturing, and sharp changes from lithostatic to hydrostatic conditions. Sulfur isotope results of hypogene sulfide minerals fall in a narrow range around 0 per mil, suggesting a dominance of magmatic sulfur. Carbon and oxygen isotopic data of calcites from propylitic alteration suggest a mantle-derived carbon and oxygen isotope fractionation due to low-temperature alteration.     

Authigenic aluminium phosphate-sulphates in sandstones of the Mitterberg Formation, Northern Calcareous Alps, Austria

Complex aluminium phosphate-sulphate minerals of the hinsdalite group have been identified as early diagenetic precipitates in Late Permian sandstones of the Northern Calcareous Alps, western Austria. According to their chemical composition they can be regarded as solid solutions between woodhouseite, svanbergite, crandallite and goyazite. The model proposed for their origin involves the dissolution of detrital apatite in a low-pH environment and subsequent precipitation of aluminium phosphate-sulphate minerals, which clearly pre-date syntaxial quartz cementation of the sediment. Their occurrence probably has been overlooked in other sandstones showing diagenetic apatite dissolution. The recognition of such minerals could provide a significant insight into early phosphate diagenesis.     

Origin of manganese carbonates in Jurassic red shale, central Japan

Manganese carbonate deposits in Japanese Jurassic sedimentary rocks were studied petrogeochemically. The deposits are characteristically composed of spheroidal micronodules, up to 1 mm in diameter, and always contain well-preserved radiolarian shells. Chemical elemental composition and mineralogical characteristics indicate that the micronodules contain rhodochrosite in a mixed carbonate phase composition (Mn_86.7?92.2Ca_2.2?2.9Mg_2.6?6.7Fe_2.6?5.6)CO₃ Carbon and oxygen isotope values, which range from ?7.99 to ?4.78‰ and ?4.05 to 0.28‰ relative to PDB, respectively, suggest that the manganese carbonate was precipitated in a suboxic zone. The micronodules closely resemble agglutinated benthic foraminifera in shape. We suggest that agglutinated foraminiferal tests composed of radiolarian shells accumulated selectively on the sediment surface during redeposition of bottom sediments and were replaced by manganese carbonate in suboxic diagenetic conditions of manganese reduction.     

某水库库区侏罗系钙质砾岩对水库渗漏的影响

某拟建水库地层中存在溶孔和溶洞等溶蚀现象,可构成潜在渗漏通道。在对水库库区地质、水文地质条件调查、分析基础上,重点研究了库区钙质砾岩溶蚀的发育机理、特点和空间发育规律。由此,初步认为：库区钙质砾岩条带溶蚀不甚发育,不存在贯通性的渗漏通道,不会引起水库严重渗漏。     

西藏北部双湖地区海相侏罗纪磁性地层研究

西藏北部双湖地区海相侏罗纪磁性地层采样剖面包括菊花山下侏罗统剖面和那底岗日中、上侏罗统剖面,采集样品共1231件。磁性地层采样工作是在实测地层(岩石地层和生物地层)剖面后进行的。采样使用国产手提式气压钻机,钻取的岩心直径为25 mm,长度为20～50 mm,用磁罗盘定向器定向取心。采样间距一般为0.5～5 m,但重要界面附近间距达到 5 cm。分析表明双湖地区海相侏罗系碳酸盐岩的天然剩磁普遍较高,一般达到6.7×10~(-3)～3.8×10~(-2)A/m。大多数样品在热退磁到500～600℃区间时,剩磁衰减了100％,表明岩石中所含磁性载体力磁铁矿。系统研究表明双湖地区晚三叠世与早侏罗世之间缺失一个NAUNESKI反向极性带,界面的时间缺失量约为2 Ma,野外表现为不整合接触关系。中、下侏罗统之间为假整合接触关系,沉积间断时间约为320 ka。     

The genesis of Lofer cycles of the Dachstein Limestone,Northern Calcareous Alps,Austria

Peritidal carbonate platform Lofer cycles have been regarded as a record of sea-level oscillations driven by variations in the earth's orbit. Fresh analysis of a newly measured 700 m thick section from the Steinernes Meer is presented here. Estimation of stratigraphic completeness indicates that this sequence is only 0.75–9.5% complete, strongly suggesting that Milankovitch patterns are not preserved. Analysis of cycle thickness-frequency distributions reveals an exponential pattern, strongly suggestive of aperiodic, random deposition rather than periodic deposition in response to orbital forcing. Evidence for the importance of autocyclic processes (e.g. lateral migration of inter- to supratidal mudbanks and subtidal areas) and syn-sedimentary tectonic downfaulting events within this already active Late Triassic extensional zone is presented.     

Growing folds and sedimentation of the Gosau Group, Muttekopf, Northern Calcareous Alps, Austria

Analysis of the three-dimensional geometry of Upper Cretaceous clastics in the Muttekopf area (Northern Calcareous Alps, Austria) indicate fold and fault structures active during deposition. Coniacian continental to neritic sedimentation (Lower Gosau Subgroup) was contemporaneous with displacements on NW-trending faults and minor folding along NE-trending axes. From the Santonian onwards (sedimentation of the deep-marine Upper Gosau Subgroup) the NW-trending faults were sealed and large folds with WSW-trending axes developed. The direction of contraction changed to N-S after the end of Gosau deposition in the Danian (Paleocene). Synorogenic sedimentation patterns indicate continuous contraction from the Coniacian to the Late Maastrichtian/?Danian. Therefore, large-scale extension as observed in the central part of the Eastern Alps cannot be documented in the western parts of the Northern Calcareous Alps. A combination of subduction tectonic erosion for the frontal parts and gravitational adjustment of an unstable orogen after nappe stacking for the internal parts possibly accounts for the different development of Gosau basins in the frontal and trailing regions of the Austroalpine wedge.     

Biosedimentology of the Early Jurassic post-extinction carbonate depositional system, central High Atlas rift basin, Morocco

This study documents a Liassic example of the long‐ranging effects of mass extinction on carbonate systems. Biohistoric constraints inherent in the Liassic carbonate depositional system are deciphered from normal‐marine, sub‐tidal deposits of the central High Atlas rift basin (Morocco) through ?Hettangian/Sinemurian to Early Toarcian times. The integration of results from the analysis of lithofacies, depositional geometries, microfacies, macrobenthos, carbonate build‐ups, carbon and oxygen stable isotopes, and rare earth element + yttrium distribution patterns allows the intrinsic (or biohistoric) control on the central High Atlas deposits to be separated from extrinsic factors, such as basin development and palaeoclimate. The survival interval in the aftermath of the end‐Triassic mass extinction persisted until the Early Sinemurian indicated by a severely depleted carbonate system impoverished in skeletal organisms. A tectonic pulse at the Early to Late Sinemurian boundary interval caused a basin widening with immigration of a marine fauna. However, until the latest Sinemurian (macdonelli Subzone of the raricostatum Zone) the deposits were dominated by filter‐feeding benthic heterotrophs (sponges, brachiopods, polychaetes and crinoids). During this stage, primary production within the enlarged basin must have been largely planktonic and there was a net‐flux of organic matter to the sea floor (oxygen minimum zone). A regional radiation of organic‐walled phytoplankton is inferred to explain the selective success of the filter‐feeding community and the occurrence of sponge mounds. Thus, significant effects of the end‐Triassic mass extinction are still present during the Late Sinemurian. Through almost the entire Pliensbachian a highly productive, shoal‐rimmed carbonate platform existed; it developed subsequent to tectonic reorganization and a marine recirculation event (radiolarian facies, Δδ¹³C ≈ ?1·1, strongly negative Ce‐anomaly). Photosymbiotic sediment producers (mainly large bivalves) now state the success of specialists and environmental equilibrium conditions. In the latest Pliensbachian the climax stage was reached with the development of a coralgal reef‐rimmed carbonate platform. The Liassic carbonate depositional system experienced a terminal, multicausal Early Toarcian drowning event during which most of the large bivalves became extinct.     

Calcareous nannoplankton in the Jurassic deposits of the Dobrudja foredeep (Ukraine and Moldova)

The paper is concerned with Jurassic calcareous nannoplankton from the Dobrudja foredeep. The regional Jurassic stratigraphy based on nannoplankton is considered. The NJ10/Stephanolithion speciosum, NJ11/Pseudoconus enigma, NJ14/Stephanolithion bigotii maximum, and NJ15/Cyclagelosphaera margerelii Zones, consistent with the International Nannoplankton Zonation Scheme, have been recognized in the deposits of the Dobrudja foredeep.     

Calcareous nannofossil biostratigraphy and paleoecology of the Cenomanian – Turonian transition in the Tarfaya Basin, southern Morocco

An abundant and diverse nannoflora occurs across the Cenomanian/Turonian (C/T) boundary at Tazra in the Tarfaya Basin of southern Morocco. The nannoflora of this sequence permits recognition of three biozones (CC10-CC12), three subzones (CC10a, CC10b and CC10c), and thirteen important nannolith bioevents previously reported from this interval elsewhere. The floral record shows erratic species abundance fluctuations that clearly vary with lithology and reflect at least in part preservational bias and diagenetic processes. In general, four dissolution resistant taxa are dominant: Watznaueria barnesae, Eiffellithus turriseiffelii, Eprolithus floralis, and Zeugrhabdotus spp. The late Cenomanian Zone CC10 marks a rapid excursion in ∂¹³C and is characterized by the successive extinction of four taxa, which are widely recognized as reliable biomarkers: Corollithion kennedyi, Axopodorhabdus albianus, Lithraphidites acutus, and Helenea chiastia. This interval is also marked by high species richness and high abundance of the tropical species Watznaueria barnesae, suggesting warm tropical waters. The subsequent ∂¹³C plateau and organic carbon-rich black shale deposition of the oceanic anoxic event (OAE2) is characterized by low species richness, but high nannofossil abundance, and peak abundance of the cool water and high productivity indicator Zeugrhabdotus spp., followed by the first peak abundance of cool water Eprolithus floralis. This interval correlates with the planktic foraminiferal diversity minimum and the Heterohelix shift, which marks the expansion of the oxygen minimum zone (OMZ). The C/T boundary is identified based on the FO of Quadrum gartneri, which is <1 m below the FO of the planktic foraminifer C/T marker Helvetoglobotruncana helvetica. In the early and middle Turonian, the two dominant species, tropical W. barnesae and cool water E. floralis, alternate in abundance and suggest fluctuating climatic conditions.     

Advances in the microbial mineralization of seafloor hydrothermal systems

Research on the biomineralization in modern seafloor hydrothermal systems is conducive to unveiling the mysteries of the early Earth’s history, life evolution, subsurface biosphere and microbes in outer space. The hydrothermal biomineralization has become a focus of geo-biological research in the last decade, since the introduction of the microelectronic technology and molecular biology technology. Microorganisms play a critical role in the formations of oxide/hydroxides (e.g. Fe, Mn, S and Si oxide/hydroxides) and silicates on the seafloor hydrothermal systems globally. Furthermore, the biomineralization of modern chemolithoautotrophic microorganisms is regarded as a nexus between the geosphere and the biosphere, and as an essential complement of bioscience and geology. In this paper, we summarize the research progress of hydrothermal biomineralization, including the biogenic minerals, the microbial biodiversity, and also the interactions between minerals and microorganisms. In the foreseeable future, the research on hydrothermal biomineralization will inspire the development of geosciences and biosciences and thus enrich our knowledge of the Earth’s history, life evolution and even astrobiology.© 2019 China Geology Editorial Office.