Historical polycyclic aromatic and petrogenic hydrocarbon loading in Northern Central Gulf of Mexico shelf sediments

The distribution of selected hydrocarbons within ten dated sediment cores taken from the Mississippi River Bight off coastal Louisiana suggests a chronic contaminant loading from several sources including the river itself, oil and gas exploration in the central Gulf of Mexico (GOM) shelf area, and natural geologic hydrocarbon seeps. Data were grouped as either total polycyclic aromatic hydrocarbons (PAH's), which were indicative of pyrogenic PAH's; or estimated total hopanes (indicative of petrogenic hydrocarbons). The total PAH concentrations and estimated total hopanes begin increasing above background levels (approximately 200 ng g(-1)) after the 1950s. The distribution of these hydrocarbons and hopanes within the dated sediment cores suggests that the Mississippi River is a regional source of pyrogenic PAH's, and that the hopanes are from natural geologic hydrocarbon seeps, oil and gas exploration in the GOM, or both.     

Natural gas seepage in the Gulf of Mexico

Hydrocarbon compositions and δ¹³C values for methane of fourteen natural seep gases and four underwater vents in the northwestern Gulf of Mexico are reported. The C₁/(C₂ + C₃) ratios of the seep gas samples ranged from 68 to greater than 1000, whereas δ_PDB¹³C values varied from ?39.9 to ?65.5‰. Compositions suggest that eleven of the natural gas seeps are produced by microbial degradation whereas the remaining three have a significant thermocatalytically produced component. Contradictions in the inferences drawn from molecular and isotopic compositions make strict interpretation of the origins of a few of the samples impossible.     

Marine geophysics along the Gulf of Mexico and the Yucatan peninsula coastal area in Mexico

Marine geophysical studies were carried out along the coastal zone of Mexico in the Atlantic Ocean as part of CICAR and IDOE projects. An area of 200,000 km² was covered by two reconnaissance cruises and a more limited area by tracks for more detailed research. The 15,000 km of track lines include a collection of continuous seismic profiling, bathymetry, gravity and magnetic data.The analyses and correlation of results indicate some local structure features and their relationship to the Neo-volcanic zone and the salt dome belt in the Gulf of Mexico. On the Yucatan area the results show the interaction of continental and oceanic crust at the NW border of the Caribbean Plate.     

Authigenic carbonates in sediments from the Gulf of Mexico

The carbon isotopic composition of diagenetic dolomite and calcite in some sediments of the Gulf of Mexico varies between “normal-marine” (δ¹³C ca. 0‰) and −14.6‰ which suggests that biogenic CO₂ contributed to the carbonate formation. The δ¹³O values of dolomite and coexisting calcite are very similar but variable down-core.Dolomite and calcite precipitated early from pore water where SO₄²⁻ was not reduced. However, during (and after?) SO₄²⁻ reduction dolomite and calcite still formed and there are at least two generations of carbonate minerals present.     

Energetics during eddy shedding in the Gulf of Mexico

Ocean Dynamics - Using the Estimating Circulation and Climate of the Ocean (ECCO) Phase II product, this study investigates the energetic characteristics during eddy shedding in the Gulf of Mexico....     

Zooplankton and Karenia brevis in the Gulf of Mexico

Blooms of the toxic dinoflagellate Karenia brevis are common in the Gulf of Mexico, yet no in situ studies of zooplankton and K. brevis have been conducted there. Zooplankton abundance and taxonomic composition at non-bloom and K. brevis bloom stations within the Ecology of Harmful Algal Blooms (ECOHAB) study area were compared. At non-bloom stations, the most abundant species of zooplankton were Parvocalanus crassirostris, Oithona colcarva, and Paracalanus quasimodo at the 5-m isobath and P. quasimodo, O. colcarva, and Oikopleura dioica at the 25-m isobath. There was considerable overlap in dominance of zooplankton species between the 5 and 25-m isobaths, with nine species contributing to 90% of abundance at both isobaths. At stations within K. brevis blooms however, Acartia tonsa, Centropages velificatus, Temora turbinata, Evadne tergestina, O. colcarva, O. dioica, and P. crassirostris were dominant. Variations in abundance between non-bloom and bloom assemblages were evident, including the reduction in abundance of three key species within K. brevis blooms.     

Anthropogenic metal contamination and sapropel imprints in deep Mediterranean sediments

Sediment cores from the deep Balearic basin and the Cretan Sea provide evidence for the accumulation of Cd, Pd and Zn in the top few centimeters of the abyssal Mediterranean sea-bottom. In both cores, 206Pb/207Pb profiles confirm this anthropogenic impact with less radiogenic imprints toward surface sediments. The similarity between excess 210Pb accumulated in the top core and the 210Pb flux suggests that top core metal inventories reasonably reflect long-term atmospheric deposition to the open Mediterranean. Pb inventory in the western core for the past 100 years represents 20-30% of sediment coastal inventories, suggesting that long-term atmospheric deposition determined from coastal areas has to be used cautiously for mass balance calculations in the open Mediterranean. In the deeper section of both cores, Al normalized trace metal profiles suggest diagenetic remobilization of Fe, Mn, Cu and, to a lesser extent, Pb that likely corresponds to sapropel event S1.     

The late Wisconsin flood into the Gulf of Mexico

¹⁸O/¹⁶O and¹⁴C analysis of deep-sea cores from the Gulf of Mexico revealed a 2.4% isotopic anomaly between 12,000 and 11,000 years ago. This value, together with estimates of the oxygen isotopic composition of ice meltwater and rates of mixing within the Gulf of Mexico indicates that the average yearly discharge of the Mississippi River was between 100,000 and 230,000 m³/s (as compared to 57,000 m³/s for the peak flood of February 17, 1937), with probable yearly peak floods twice as large. Corresponding sea-level rise was between 1 and 2 m per century.     

Ground water discharge and nitrate flux to the Gulf of Mexico

Ground water samples (37 to 186 m depth) from Baldwin County, Alabama, are used to define the hydrogeology of Gulf coastal aquifers and calculate the subsurface discharge of nutrients to the Gulf of Mexico. The ground water flow and nitrate flux have been determined by linking ground water concentrations to 3H/3He and 4He age dates. The middle aquifer (A2) is an active flow system characterized by postnuclear tritium levels, moderate vertical velocities, and high nitrate concentrations. Ground water discharge could be an unaccounted source for nutrients in the coastal oceans. The aquifers annually discharge 1.1 +/- 0.01 x 10(8) moles of nitrate to the Gulf of Mexico, or 50% and 0.8% of the annual contributions from the Mobile-Alabama River System and the Mississippi River System, respectively. In southern Baldwin County, south of Loxley, increasing reliance on ground water in the deeper A3 aquifer requires accurate estimates of safe ground water withdrawal. This aquifer, partially confined by Pliocene clay above and Pensacola Clay below, is tritium dead and contains elevated 4He concentrations with no nitrate and estimated ground water ages from 100 to 7000 years. The isotopic composition and concentration of natural gas diffusing from the Pensacola Clay into the A3 aquifer aids in defining the deep ground water discharge. The highest 4He and CH4 concentrations are found only in the deepest sample (Gulf State Park), indicating that ground water flow into the Gulf of Mexico suppresses the natural gas plume. Using the shape of the CH4-He plume and the accumulation of 4He rate (2.2 +/- 0.8 microcc/kg/1000 years), we estimate the natural submarine discharge and the replenishment rate for the A3 aquifer.     

Predicting summer hypoxia in the northern Gulf of Mexico: redux

We report on the evolution and accuracy of a model used to predict the mid-summer area of hypoxia (oxygen ≤2 mg l(-1)) in the northern Gulf of Mexico, use it to test for impacts from the Deepwater Horizon oil spill (2010), and estimate the N loading that would meet a management goal. The prediction since 2000 were 100%±6% (μ±1 SE) of the actual value. The predicted in 2010 was 99% of that actual value, suggesting that the net effect of the 2010 oil spill on the hypoxic zone size was negligible. A tropical storm, however, may have reduced the potential size of the hypoxic zone. Lowering the May nitrogen load to about 70,000 mton N nitrate+nitrite would bring the model's predicted hypoxic zone size down to the management goal of 5000 km(2) and restore hypoxic waters to normoxic conditions.     

Linking hypoxia to shrimp catch in the northern Gulf of Mexico

Wide spread and reoccurring hypoxia has been observed in the northern Gulf of Mexico since routine monitoring began in the 1980s. Although the potential ecological effects of hypoxia (habitat loss, mortalities) are well known, there is relatively little information linking hypoxia in the northern Gulf of Mexico to fisheries decline. Previous analyses have shown a negative relationship between hypoxic area and brown shrimp (Farfantepenaeus aztecus) catch for the Texas and Louisiana coasts combined from 1985 to 1997. Extending these analyses with data through 2004, we found that the correlation between hypoxic area and landings holds (r=-0.52), plus there was a significant negative relationship (r=-0.59) between hypoxia and shrimp landings for the Texas coast alone. We hypothesize that this pattern is not seen in the Louisiana fishery alone because of differences in fisheries practices (inshore vs. offshore) between Louisiana and Texas.     

Distribution and abundance of large floating plastic in the north-central Gulf of Mexico

Aerial surveys were conducted in the north-central Gulf of Mexico from June 1988 to May 1989. Sightings of marine debris and specifically large floating plastics were recorded during these surveys. Five study areas off the Louisiana coast were monitored and seasonal distribution and densities were estimated. Each study area contained plastic throughout the year. The estimated densities of plastic were largest in the offshore areas (4 & 5) and smallest in the inshore areas (1 & 3). Seasonally, density of plastic was smallest in the summer and largest in the fall. The reasons for the differences in seasons and study areas are not apparent but the amount of plastic in each area and season could be affected by variations in currents, winds, discharge from rivers, and human activity.     

High-resolution ensemble forecasting for the Gulf of Mexico eddies and fronts

High-resolution models and realistic boundary conditions are necessary to reproduce the mesoscale dynamics of the Gulf of Mexico (GOM). In order to achieve this, we use a nested configuration of the Hybrid Coordinate Ocean Model (HYCOM), where the Atlantic TOPAZ system provides lateral boundary conditions to a high-resolution (5 km) model of the GOM . However, such models cannot provide accurate forecasts of mesoscale variability, such as eddy shedding event, without data assimilation. Eddy shedding events involve the rapid growth of nonlinear instabilities that are difficult to forecast. The known sources of error are the initial state, the atmospheric condition, and the lateral boundary condition. We present here the benefit of using a small ensemble forecast (10 members) for providing confidence indices for the prediction, while using a data assimilation scheme based on optimal interpolation. Our set of initial states is provided by using different values of a data assimilation parameter, while the atmospheric and lateral boundary conditions are perturbed randomly. Changes in the data assimilation parameter appear to control the main position of the large features of the GOM in the initial state, whereas changes in the boundary conditions (lateral and atmospheric) appears to control the propagation of cyclonic eddies at their boundary. The ensemble forecast is tested for the shedding of Eddy Yankee (2006). The Loop Current and eddy fronts observed from ocean color and altimetry are almost always within the estimated positions from the ensemble forecast. The ensemble spread is correlated both in space and time to the forecast error, which implies that confidence indices can be provided in addition to the forecast. Finally, the ensemble forecast permits the optimization of a data assimilation parameter for best performance at a given forecast horizon.