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1.
《International Geology Review》2012,54(6):754-777
ABSTRACTThe Pliocene–Quaternary volcanics in NE Turkey are mainly hornblende–phyric trachyandesites having a narrow range of SiO2 from 61.88 to 63.00 wt.% and exhibiting adakitic signatures with their Na2O (3.67–4.27 wt.%), Al2O3 (16.19–16.80 wt.%), Y (14.1–16.5 ppm) contents and K2O/Na2O (0.87–1.12), Sr/Y (44.24–54.90), and La/Yb (36.80–43.88) ratios. Plagioclases as the main mineral phases show a wide range of compositions, and weak normal and reverse zoning. Hornblendes are generally edenite and pargasite (Mg#: 0.39–0.74). Clinopyroxenes are augite (Mg#: 0.58–0.76). Biotites have Mg# ranging from 0.45 to 0.66. The textural and compositional variations indicate disequilibrium crystallization possibly arising from magma mixing. The U–Pb zircon dating of the adakitic volcanics yielded 3.4–1.9 Ma. The studied rocks display moderate light rare earth element /heavy rare earth element ratios and enrichment in the lithophile element and depletion in high field strength element, implying that the parental magmas were derived from mantle sources previously enriched by slab-derived fluids and/or subducted sediments. The crystallization temperature and pressure estimations based on the clinopyroxene thermobarometry range from 1144 to 1186°C and from 3.92 to 7.97 kbar, respectively. Hornblende thermobarometry, oxygen fugacity, and hygrometer calculations yielded results as 908–993°C at a pressure of 2.87–5.22 kbar, water content of 4.4–8.4 wt.%, and relative oxygen fugacity (ΔNNO log units) of ?0.6 to 0.9, respectively. Biotite thermobarometry suggests relatively higher oxygen fugacity conditions (10–13.33 to 10–17.60) at temperatures of 676–819°C and at pressures from 1.15 to 1.76 kbar. In the light of the obtained data and modelling, it can be concluded that the magmas of the adakitic volcanics were derived from enriched mantle source through relatively higher partial melting and experienced magma mixing with melts at the crustal level. Additionally, the fractional crystallization and assimilation-fractional crystallization processes may have played an important role during the evolution of the studied volcanics. 相似文献
2.
《International Geology Review》2012,54(10):1226-1245
Monzogabbro stocks including felsic enclaves (monzosyenite) around the Bafra (Samsun) area at the western edge of the Eastern Pontides cut Eocene-aged volcanic and sedimentary units. The monzogabbros contain plagioclase, alkali feldspar, clinopyroxene, olivine, hornblende, biotite, apatite, and iron-titanium oxides, whereas the felsic enclaves contain alkali feldspar, plagioclase, hornblende, biotite, clinopyroxene, and iron-titanium oxides. Mineral chemistry data suggest that magmas experienced hydrous and anhydrous crystallization in deep and shallow crustal magma chambers. Several thermobarometers were used to estimate temperatures of crystallization and emplacement for the mafic and felsic magmas. Clinopyroxene thermobarometry yielded 1100–1232 C and 5.9–8.1 kbar for monzogabbros, and 931–1109 C and 1.8–6.9 kbar for felsic enclaves. Hornblende thermobarometry and oxygen fugacity estimates reveal 739–971°C, 7.0–9.2 kbar and 10?9.71 for monzogabbros and 681–928°C, 3.0–6.1 kbar and 10?11.34 for felsic enclaves. Biotite thermobarometry shows elevated oxygen fugacity varying from 10?18.9–10?11.07 at 632–904°C and 1.29–1.89 kbar for monzogabbros, to 10?15.99 –10?11.82 at 719–873°C and 1.41–1.77 kbar for felsic enclaves. The estimated zircon and apatite saturation temperatures are 504–590°C and 693–730°C for monzogabbros and 765–775°C and 641–690°C for felsic enclaves, respectively. These data imply that several phases in the gabbroic and syenitic magmas did not necessarily crystallize simultaneously and further indicate that the mineral compositions may register intervals of disequilibrium crystallization. Besides, thermobarometry contrasts between monzogabbro and felsic enclave may be partly a consequence of extended interactions between the mafic and felsic magmas by mixing/mingling and diffusion. Additionally, the hot felsic magma was close to liquidus conditions (crystallinity < 30%) when injected into cooler mafic magma (crystallinity > 50%), and thus, the monzogabbro stocks reflect hybrid products from the mingling and incomplete mixing of these two magmas. 相似文献
3.
Kazem Kazemi Ali Kananian Yilin Xiao Fatemeh Sarjoughian 《Arabian Journal of Geosciences》2018,11(22):717
The Haji Abad intrusion is a well-exposed Middle Eocene I-type granodioritc pluton in the Urumieh–Dokhtar magmatic assemblage (UDMA). The major constituents of the investigated rocks are K-feldspar, quartz, plagioclase, pyroxene, and minor Fe–Ti oxide and hornblende. The plagioclase compositions fall in the labradorite, andesine, and oligoclase fields. The amphiboles range in composition from magnesio-hornblende to tremolite–hornblende of the calcic-amphibole group. Most pyroxenes principally plot in the field of diopside. The calculated average pressure of emplacement is 1.9 kbar for the granodioritic rocks, crystallizing at depths of about 6.7 km. The highest pressure estimated from clinopyroxene geobarometry (5 kbar) reflects initial pyroxene crystallization pressure, indicating initial crystallization depth (17.5 km) in the Haji Abad granodiorite. The estimated temperatures using two-feldspar thermometry give an average 724 °C. The calculated average temperature for clinopyroxene crystallization is 1090 °C. The pyroxene temperatures are higher than the estimated temperature by feldspar thermometry, indicating that the pyroxene and feldspar temperatures represent the first and late stages of magmatic crystallization of Haji Abad granodiorite, respectively. Most pyroxenes plot above the line of Fe3+?=?0, indicating they crystallized under relatively high oxygen fugacity or oxidized conditions. Furthermore, the results show that the Middle Eocene granitoids crystallized from magmas with H2O content about 3.2 wt%. The relatively high water content is consistent with the generation environment of HAG rocks in an active continental margin and has allowed the magma to reach shallower crustal levels. The MMEs with ellipsoidal and spherical shapes show igneous microgranular textures and chilled margins, probably indicating the presence of magma mixing. Besides, core to rim compositional oscillations (An and FeO) for the plagioclase crystals serve as robust evidence to support magma mixing. The studied amphiboles and pyroxenes are grouped in the subalkaline fields that are consistent with crystallization from I-type calc-alkaine magma in the subduction environment related to active continental margin. Mineral chemistry data indicate that Haji Abad granodiorites were generated in an orogenic belt related to the volcanic arc setting consistent with the subduction of Neo-Tethyan oceanic crust beneath the central Iranian microcontinent. 相似文献
4.
Mohamed M. Abu Anbar 《Mineralogy and Petrology》2009,95(1-2):87-103
The Wadi Nesryin gabbroic intrusion is part of the Neoproterozoic Pan-African basement cropping out in southern Western Sinai of Egypt. The intrusion comprises hornblende gabbro, pyroxene–hornblende gabbro, diorite and appinitic varieties. It exhibits chilled margins against the older rocks represented by fine-grained gabbro and dolerite and belongs to what is known throughout Egypt as the “younger gabbro suite”. Mineralogy, mineral chemistry and whole rock geochemistry indicate that these rocks were derived from tholeiitic magmas with minor calc-alkaline affinity. They have chemical signatures of subduction related arc rocks formed at an active convergent plate margin. They were formed by 15–30% of partial melting of a garnet lherzolite and to a minor extent of spinel-garnet lherzolite sources, modified by fluids related to a subducting slab. Pressure estimates using the amphibole geobarometer indicate that the gabbroic rocks crystallized at pressures between 2.8 and 5.6 kbar (average?=?4.3 kbar). Diorites record lower formation pressures between 1.8 and 3.7 kbar (average?=?3.0 kbar). The temperature estimates calculated by several geothermometers yielded crystallization temperatures ranging from 674°C to 961°C, with an average of about 817°C. The whole rock Rb–Sr isochron age of the Nesryin gabbroic intrusion is 617?±?19 Ma with initial 87Sr/86Sr?=?0.70322?±?0.00004. This age indicates that the mafic–ultramafic plutons in the Pan-African belt in southern Sinai belong to the Egyptian younger gabbros and not to the older metagabbro–diorite complexes or ophiolitic suites. The rocks have low 87Sr/86Sr initial ratios ranging from 0.703141 to 0.703338 and negative ? Sr ranging from ?6.34 to ?9.14. The initial 143Nd/144Nd ratios range from 0.511944 to 0.512145 with positive and high ? Nd values (1.93 to 5.86) reflecting a mantle contribution in their petrogenesis. 相似文献
5.
《International Geology Review》2012,54(1):104-132
We conducted geochemical and isotopic studies on the Oligocene–Miocene Niyasar plutonic suite in the central Urumieh–Dokhtar magmatic belt, in order better to understand the magma sources and tectonic implications. The Niyasar plutonic suite comprises early Eocene microdiorite, early Oligocene dioritic sills, and middle Miocene tonalite + quartzdiorite and minor diorite assemblages. All samples show a medium-K calc-alkaline, metaluminous affinity and have similar geochemical features, including strong enrichment of large-ion lithophile elements (LILEs, e.g. Rb, Ba, Sr), enrichment of light rare earth elements (LREEs), and depletion in high field strength elements (HFSEs, e.g. Nb, Ta, Ti, P). The chondrite-normalized rare earth element (REE) patterns of microdiorite and dioritic sills are slightly fractionated [(La/Yb)n = 1.1–4] and display weak Eu anomalies (Eu/Eu* = 0.72–1.1). Isotopic data for these mafic mantle-derived rocks display ISr = 0.70604–0.70813, ?Nd (microdiorite: 50 Ma and dioritic sills: 35 Ma, respectively) = +1.6 and ?0.4, TDM = 1.3 Ga, and lead isotopic ratios are (206Pb/204Pb) = 18.62–18.57, (207Pb/204Pb) = 15.61–15.66, and (208Pb/204Pb) = 38.65–38.69. The middle Miocene granitoids (18 Ma) are also characterized by relatively high REE and minor Eu anomalies (Eu/Eu* = 0.77–0.98) and have uniform initial 87Sr/86Sr (0.7065–0.7082), a range of initial Nd isotopic ratios [?Nd(T)] varying from ?2.3 to ?3.7, and Pb isotopic composition (206Pb/204Pb) = 18.67–18.94, (207Pb/204Pb) = 15.63–15.71, and (208Pb/204Pb) = 38.73–39.01. Geochemical and isotopic evidence for these Eocene–Ologocene mafic rocks suggests that the magmas originated from lithospheric mantle with a large involvement of EMII component during subduction of the Neotethyan ocean slab beneath the Central Iranian plate, and were significantly affected by crustal contamination. Geochemical and isotopic data of the middle Miocene granitoids rule out a purely crustal-derived magma genesis, and suggest a mixed mantle–crustal [MASH (melting, assimilation, storage, and homogenization)] origin in a post-collision extensional setting. Sr–Nd isotope modelling shows that the generation of these magmas involved ~60% to 70% of a lower crustal-derived melt and ~30% to 40% of subcontinental lithospheric mantle. All Niyasar plutons exhibit transitional geochemical features, indicating that involvement of an EMII component in the subcontinental mantle and also continental crust beneath the Urumieh–Dokhtar magmatic belt increased from early Eocene to middle Miocene time. 相似文献
6.
The Eocene and Miocene volcanic rocks between the cities of Trabzon and Giresun in the Eastern Pontides (NE Turkey) erupted as mildly and moderately alkaline magmas ranging from silica-saturated to silica-undersaturated types. 40Ar-39Ar dating and petrochemical data reveal that the studied volcanic rocks are discriminated in two: Lutetian (Middle Eocene) mildly alkaline, (basaltic rocks: 45.31 ± 0.18 to 43.86 ± 0.19 Ma; trachytic rocks: 44.87 ± 0.22 to 41.32 ± 0.12 Ma), and Messinian (Late Miocene) moderately alkaline volcanic rocks (tephrytic rocks: 6.05 ± 0.06 and 5.65 ± 0.06 Ma). The trace and the rare earth element systematic, characterised by moderate light earth element (LREE)/heavy rare earth element (HREE) ratios in the Eocene basaltic and trachytic rocks, high LREE/HREE ratios in the Miocene tephrytic rocks, and different degrees of depletion in Nb, Ta, Ti coupled with high Th/Yb ratios, show that the parental magmas of the volcanic rocks were derived from mantle sources previously enriched by slab-derived fluids and subducted sediments. The Sr, Nd and Pb isotopic composition of the Eocene and Miocene volcanic rocks support the presence of subduction-modified subcontinental lithospheric mantle. During the magma ascent in the crust, parental magmas of both the Eocene and Miocene volcanic rocks were mostly affected by fractional crystallisation rather than assimilation coupled with fractional crystallisation and mixing. The silica-undersaturated character of the Miocene tephrytic rocks could be attributed to assimilation of carbonate rocks within shallow-level magma chambers. The parental magmas of the Eocene volcanic rocks resulted from a relatively high melting degree of a net veined mantle and surrounding peridotites in the spinel stability field due to an increase in temperature, resulting from asthenospheric upwelling related to the extension of lithosphere subsequent to delamination. The parental magmas for the Miocene volcanic rocks resulted from a relatively low melting degree of a net veined mantle domain previously modified by metasomatic melts derived from a garnet peridotite source after decompression due to extensional tectonics, combined with strike-slip movement at a regional scale related to ongoing delamination. 相似文献
7.
Mousumi Banerjee Jyotisankar Ray Nupur Adhikary Sandip Nandy C. Manikyamba Madhuparna Paul Dola Chakraborty Alireza Eslami 《Journal of the Geological Society of India》2016,88(2):245-255
Malangtoli volcanics of the Singhbhum craton of the eastern Indian shield is one of the important Proterozoic lava suites. Experimental studies on 1 atmosphere pressure constrain the parental magma type and temperature range of crystallization of the parent magma (deduced to be in the range of 1500°C to 1200°C). The experimental studies show that at 1500°C, plagioclase is the first phase to crystallize, followed by few opaques which join along with plagioclase at 1450°C. At subsequent lower temperature (1400°C-1300°C), plagioclase and opaque continue to crystallize. At 1250°C plagioclase and opaque still persist while pyroxene appears first and liquid (glass) still remains. Appearance of opaque minerals (magnetite and illmenite) at both ~1400°C and ~1300°C indicate oscillation of oxygen fugacity in the parent magma, petrographically documented by coarser phenocrysts as well as finer or peripheral tiny grains. Use of tectonic discrimination diagrams (based on discrimination factors F1-F2 and FeOt/MgO vs. TiO2) shows an island arc tholeiitic affinity for Malangtoli volcanic, suggests that the role of proto-plate convergence in Singhbhum architecture played an important role to build up Malangtoli volcanics during Proterozoic. 相似文献
8.
Antar Abdel Wahab Mohamed Fouad Ghoneim Tamer Abu-Alam 《Arabian Journal of Geosciences》2017,10(2):30
The Cenozoic volcanism of western Saudi Arabia extends from southern Yemen to Jordan northward. They cover an area of nearly 180,000 km2. The rocks are dominated by alkali olivine basalts and olivine basalts. Al-Wahbah crater, a part of Harrat Kishb, represents a model occurrence to study the gneisses of these rocks. New mineral chemistry and isotopic data are presented. It aims to follow the isotopic, mineralogical, and thermobarometry variations among these volcanics. Amphiboles of the studied volcanics belong to the monoclinic calcic group. The chemistry of the amphibole crystals shows two ranges of pressure. They are 3.6–5.6 and 0.38–0.78 kbar. The Aliv values of the amphiboles are in the range of 1.202 and 1.407, indicating corresponding temperature condition of 820–920 and 620–720 °C, respectively. The feldspar of the studied samples has the composition of plagioclase, though some grains have sanidine composition. They are formed in temperature range of 975 and 400 °C. The coexisting amphiboles and plagioclases indicate two sets of pressure and temperature. They are 540–575 °C (3.5–4 kbar) and 510–525 °C (~2 kbar), respectively. Rb–Sr isochron of the whole rock yields an age of 0.867 ± 0.160 Ma with initial Sr87/Sr86 of 0.702 ± 0.00086. The low initial ratio of Sr87/Sr86 together with positive values of εNd today implies that the studied volcanics have mantle source. Meanwhile, the present isotopic data suggest extraction of juvenile magma from asthenosphere source. The present study shows that the Al-Wahbah crater rocks belong to Cenozoic basalts and indicate EM-I-like signature. 相似文献
9.
Mineral chemistry of submarine lavas from Hilo Ridge, Hawaii: implications for magmatic processes within Hawaiian rift zones 总被引:10,自引:0,他引:10
Huai-Jen Yang Frederick A. Frey David A. Clague Michael O. Garcia 《Contributions to Mineralogy and Petrology》1999,135(4):355-372
The crustal history of volcanic rocks can be inferred from the mineralogy and compositions of their phenocrysts which record
episodes of magma mixing as well as the pressures and temperatures when magmas cooled. Submarine lavas erupted on the Hilo
Ridge, a rift zone directly east of Mauna Kea volcano, contain olivine, plagioclase, augite ±orthopyroxene phenocrysts. The
compositions of these phenocryst phases provide constraints on the magmatic processes beneath Hawaiian rift zones. In these
samples, olivine phenocrysts are normally zoned with homogeneous cores ranging from ∼ Fo81 to Fo91. In contrast, plagioclase, augite and orthopyroxene phenocrysts display more than one episode of reverse zoning. Within each
sample, plagioclase, augite and orthopyroxene phenocrysts have similar zoning profiles. However, there are significant differences
between samples. In three samples these phases exhibit large compositional contrasts, e.g., Mg# [100 × Mg/(Mg+Fe+2)] of augite varies from 71 in cores to 82 in rims. Some submarine lavas from the Puna Ridge (Kilauea volcano) contain phenocrysts
with similar reverse zonation.
The compositional variations of these phenocrysts can be explained by mixing of a multiphase (plagioclase, augite and orthopyroxene)
saturated, evolved magma with more mafic magma saturated only with olivine. The differences in the compositional ranges of
plagioclase, augite and orthopyroxene crystals between samples indicate that these samples were derived from isolated magma
chambers which had undergone distinct fractionation and mixing histories. The samples containing plagioclase and pyroxene
with small compositional variations reflect magmas that were buffered near the olivine + melt ⇒Low-Ca pyroxene + augite +
plagioclase reaction point by frequent intrusions of mafic olivine-bearing magmas. Samples containing plagioclase and pyroxene
phenocrysts with large compositional ranges reflect magmas that evolved beyond this reaction point when there was no replenishment
with olivine-saturated magma. Two of these samples contain augite cores with Mg# of ∼71, corresponding to Mg# of 36–40 in
equilibrium melts, and augite in another sample has Mg# of 63–65 which is in equilibrium with a very evolved melt with a Mg#
of ∼30. Such highly evolved magmas also exist beneath the Puna Ridge of Kilauea volcano. They are rarely erupted during the
shield building stage, but may commonly form in ephemeral magma pockets in the rift zones.
The compositions of clinopyroxene phenocryst rims and associated glass rinds indicate that most of the samples were last equilibrated
at 2–3 kbar and 1130–1160 °C. However, in one sample, augite and glass rind compositions reflect crystallization at higher
pressures (4–5 kbar). This sample provides evidence for magma mixing at relatively high pressures and perhaps transport of
magma from the summit conduits to the rift zone along the oceanic crust-mantle boundary.
Received: 8 July 1998 / Accepted: 2 January 1999 相似文献
10.
Emre Aydınçakır Cem Yücel Gilles Ruffet Mehmet Ali Gücer Enver Akaryalı Abdullah Kaygusuz 《Chemie der Erde / Geochemistry》2022,82(2):125871
The debate about whether Eocene magmatism is considered to be post-collisional or subduction-related or not still continues. Here we offer new 40Ar-39Ar ad U-Pb zircon geochronology, mineral chemistry, bulk rock and Sr-Nd-Pb isotope geochemistry data obtained from the southern dike (SD) suite, in comparison with the northern dike (ND) suite, from the Eastern Pontides. The geochronological data indicate that the SD suite erupted between 45.89 and 45.10 Ma corresponding to the Lutetian (Middle Eocene). The magmas of the ND suite are characterised by slightly more alkaline affinity compared to the SD suite. The trace and rare earth element (REEs) content of the SD suite is characterised by large ion lithophile element (LILEs; Sr, K2O, Ba, Rb) enrichment and depletion of Nb, Ta, and TiO2 elements to different degree with high Th/Yb ratios, which indicate that the magmas forming the SD and ND suites were derived from lithospheric mantle sources enriched by mostly slab-derived fluids in the spinel stability field. The Sr, Nd and Pb radiogenic isotope ratios of the dikes support the view that the magma for the hydrous group (H-SD) was derived from a relatively more enriched mantle source than the other SD and ND suites. The ND suite and the anhydrous group (A-SD) display similar geochemical features characterised by moderate light earth element (LREE)/heavy rare earth element (HREE) ratios, while the H-SD group has respectively lower LREE/HREE ratios indicating higher melting degree. Detailed considerations of the alkalinity, enrichment and partial melting degree for the source of the studied volcanic rocks indicate that the magmas of the northern dike suite are characterised by slightly more alkaline affinity, whereas the magmas throughout the southern dike suite show increments in the enrichment rate and melting degree. In light of the obtained data and comparative interpretations, the geodynamic evolution and differences in petrogenetic character of the Lutetian magmas from both the northern and southern parts of the Eastern Pontides may be explained by different degrees of melting of a net veined mantle source initially metasomatized by mostly subduction fluids during asthenospheric upwelling due to fragmented asymmetric delamination in a post-collisional extensional tectonic environment. 相似文献
11.
Lavas and pyroclastic products of Nisyros volcano (Aegean arc, Greece) host a wide variety of phenocryst and cumulate assemblages that offer a unique window into the earliest stages of magma differentiation. This study presents a detailed petrographic study of lavas, enclaves and cumulates spanning the entire volcanic history of Nisyros to elucidate at which levels in the crust magmas stall and differentiate. We present a new division for the volcanic products into two suites based on field occurrence and petrographic features: a low-porphyricity andesite and a high-porphyricity (rhyo)dacite (HPRD) suite. Cumulate fragments are exclusively found in the HPRD suite and are predominantly derived from upper crustal reservoirs where they crystallised under hydrous conditions from melts that underwent prior differentiation. Rarer cumulate fragments range from (amphibole-)wehrlites to plagioclase-hornblendites and these appear to be derived from the lower crust (0.5–0.8 GPa). The suppressed stability of plagioclase and early saturation of amphibole in these cumulates are indicative of high-pressure crystallisation from primitive hydrous melts (≥ 3 wt% H2O). Clinopyroxene in these cumulates has Al2O3 contents up to 9 wt% due to the absence of crystallising plagioclase, and is subsequently consumed in a peritectic reaction to form primitive, Al-rich amphibole (Mg# > 73, 12–15 wt% Al2O3). The composition of these peritectic amphiboles is distinct from trace element-enriched interstitial amphibole in shallower cumulates. Phenocryst compositions and assemblages in both suites differ markedly from the cumulates. Phenocrysts, therefore, reflect shallow crystallisation and do not record magma differentiation in the deep arc crust. 相似文献
12.
《International Geology Review》2012,54(2):158-184
Early Miocene igneous rocks associated with the Dalli porphyry ore body are exposed within the Urumieh-Dokhtar Magmatic Arc (UDMA). The Dalli porphyry Cu–Au deposit is hosted by subduction-related subvolcanic plutons with chemical composition from diorite to granodiorite, which intruded andesitic and dacitic volcanic rocks and a variety of sedimentary sequences. 40Ar/39Ar age data indicate a minimum emplacement age of ~21 million years for a potasically altered porphyritic diorite that hosts the porphyry system. The deposit has a proven reserve of 8 million tonnes of rock containing 0.75 g/t Au and 0.5% Cu. Chondrite-normalized rare earth element (REE) patterns for the subvolcanic rocks are characterized by light REE enrichments [(La/Sm) n ?=?2.57–6.40] and flat to gently upward-sloping profiles from middle to heavy REEs [(Dy/Yb) n ?=?0.99–2.78; (Gd/Yb) n ?=?1.37–3.54], with no significant Eu anomalies. These characteristics are generated by the fractionation of amphibole and the suppression of plagioclase crystallization from hydrous calc-alkaline magmas. In normalized multi-element diagrams, all analysed rocks are characterized by enrichments in large ion lithophile elements and depletions in high field strength elements, and display typical features of subduction-related calc-alkaline magmas. We used igneous mineral compositions to constrain the conditions of crystallization and emplacement. Biotite compositions plot above the nickel–nickel oxide (NNO) buffer and close to oxygen fugacity values defined by the hematite–magnetite (HM) buffer, indicating oxidizing conditions during crystallization. Assuming a minimum crystallization temperature of 775°C, the oxygen (fO2) and water (fH2O) fugacities are estimated to be 10?10.3 bars (~ΔNNO+4) and ≤748 bars, respectively, during the crystallization of biotite phenocrysts. The temperature and pressure conditions, estimated from temperature–corrected Al-in-hornblende barometry and amphibole-plagioclase thermometry, suggest that the hornblende phenocrysts in Dalli rocks crystallized at around 780 ± 20°C and 3.8 ± 0.4 kbar. An alternative method using the calcic amphibole thermobarometer indicates that the Dalli magmas were, on average, characterized by an H2O content of 4.3 wt.%, a relatively high oxygen fugacity of 10?11.0 bars (ΔNNO+1.3), and a hornblende phenocryst crystallization temperature of 880 ± 68°C and pressure of 2.6 ± 1.7 kbar. 相似文献
13.
A. A. Gurenko Thor H. Hansteen Hans-Ulrich Schmincke 《Contributions to Mineralogy and Petrology》1996,124(3-4):422-435
Picritic units of the Miocene shield volcanics on Gran Canaria, Canary Islands, contain olivine and clinopyroxene phenocrysts
with abundant primary melt, crystal and fluid inclusions. Composition and crystallization conditions of primary magmas in
equilibrium with olivine Fo90-92 were inferred from high-temperature microthermometric quench experiments, low-temperature microthermometry of fluid inclusions
and simulation of the reverse path of olivine fractional crystallization based on major element composition of melt inclusions.
Primary magmas parental for the Miocene shield basalts range from transitional to alkaline picrites (14.7–19.3 wt% MgO, 43.2–45.7
wt% SiO2). Crystallization of these primary magmas is believed to have occurred over the temperature range 1490–1150° C at pressures
≈5 kbar producing olivine of Fo80.6-90.2, high-Ti chrome spinel [Mg/ (Mg+Fe2+)=0.32–0.56, Cr/(Cr+Al)=0.50–0.78, 2.52–8.58 wt% TiO2], and clinopyroxene [Mg/(Mg+Fe)=0.79–0.88, Wo44.1-45.3, En43.9-48.0, Fs6.8-11.0] which appeared on the liquidus together with olivine≈Fo86. Redox conditions evolved from intermediate between the QFM and WM buffers to late-stage conditions of NNO+1 to NNO+2. The
primary magmas crystallized in the presence of an essentially pure CO2 fluid. The primary magmas originated at pressures >30 kbar and temperatures of 1500–1600° C, assuming equilibrium with mantle
peridotite. This implies melting of the mantle source at a depth of ≈100 km within the garnet stability field followed by
migration of melts into magma reservoirs located at the boundary between the upper mantle and lower crust. The temperatures
and pressures of primary magma generation suggest that the Canarian plume originated in the lower mantle at depth ≈900 km
that supports the plume concept of origin of the Canary Islands.
Received: 23 October 1995/Accepted: 21 February 1996 相似文献
14.
ABSTRACTIn this study, Early Cretaceous skarn deposits and genesis of their host diorite/monzodiorite porphyry in the Xuzhou-Huaibei (Xu-Huai) region, northern Anhui-Jiangsu have been discussed by detailed geochemical work. In-situ zircon U–Pb dating of the diorites related to Fe–Cu–Au deposits shows that they were formed between 131.4 ± 1.5 Ma and 130.8 ± 1.8 Ma. Geochemical data indicate a depletion of high field strength elements (HFSE) in the diorite porphyry with similarity to that of arc-related igneous rocks. The diorite porphyry was probably derived from typical arc magmas related to continental margin subduction characterized by light rare earth elements (LREEs) enrichment and HFSE depletion. REEs compositions of apatite in the diorite porphyry indicate that the dioritic magma was produced from the metasomatized subcontinental mantle by slab-derived fluids. The magma was proven to be a high oxygen fugacity; thus, it was particularly conducive to the precipitation of Fe, Cu, Au and other ore-forming elements. The δ34S values of pyrite and chalcopyrite of Fe–Cu–Au ores range from ?0.2‰ to 2.8‰, indicating that the sulphur in the ore was probably derived from deep-seated magmas. Integrated with geochronological and geochemical analyses, we suggest that the Early Cretaceous igneous suites associated with Fe–Cu–Au deposits in the Xu-Huai region are related to recycling subduction of Pacific oceanic crust. 相似文献
15.
P. le Roux A. le Roex J.-G. Schilling 《Contributions to Mineralogy and Petrology》2002,142(5):582-602
New major and trace element data are reported for a suite of basalts dredge sampled from the southern MAR (40.6-52.5°S) during cruise 9309 of the R/V Maurice Ewing and cruise 32 of the S.A. Agulhas (51-54.5°S). Samples range from aphyric to moderately porphyritic with plagioclase and olivine the dominant phenocryst and microphenocryst phases. Clinopyroxene occurs rarely as a phenocryst phase. Bulk rock and quench glass samples have major element compositions ranging from moderately primitive (Mg#=68.5) to evolved (Mg#=41.1), with a comparable range in incompatible (Zr=54-232 ppm; Nb=0.8-21 ppm) and highly compatible trace element (Ni=51-289 ppm; Cr=39-949 ppm) abundances. Incompatible trace element ratios (e.g., Zr/Nb=5.9-69; Y/Nb=0.88-29; (La/Sm)N=0.48-2.9) indicate both enriched and depleted MORB occurring along this section of the MAR, agreeing with along-ridge radiogenic isotope ratio variations delineating compositional influences of the off-axis Discovery, and a so-called LOMU-component, and ridge-centered Shona mantle plumes (Douglass et al. 1999; Douglass and Schilling 2000). Major- and trace-element variations, particularly decreasing CaO/Al2O3 ratios and relatively constant Sc abundances with decreasing Mg# suggest crystallization of olivine, plagioclase, and clinopyroxene in most of these basalts prior to eruption. Liquid-lines-of-descent, derived from forward modeling of various reasonable parental magma compositions at pressures between 1 atm-8 kbar, confirm clinopyroxene as an early crystallizing phase, along with olivine and plagioclase, and its pivotal role in the compositional evolution of these basalts. Pressures deduced using algorithms of Grove et al. 1992 and Michael and Cornell 1998 indicate crystallization beneath ridge segments unaffected by mantle plumes occurred predominately at depths of 3-6 kbar (10-20 km). Crystallization beneath ridge segments affected by the Discovery and Shona mantle plumes occurred over a larger pressure range (1 atm-~7 kbar), but predominantly at crustal depths (1 atm-3 kbar), possibly due to more constant magma fluxes and higher temperatures in the crust and lithosphere in these regions favoring the existence and longevity of subaxial magma chambers. 相似文献
16.
N. S. Gorbachev 《Petrology》2010,18(4):416-431
The paper reports data on the geology and tectono-magmatic reactivation of the Norilsk area and on the stratigraphy and geochemistry
of its volcanic sequence, with the discussion of the sources and genesis of the ore magmas and the scale of the ore-forming
process. According to the geochemistry of the lavas and intrusive rocks (Ti concentration and the La/Sm and Gd/Yb ratios),
two types of the parental magmas are recognized: high-Ti magmas of the OIB type (from bottom to top, suites iv, sv, and gd
of phase 1) and low-Ti magmas (suites hk, tk, and nd of phase 2 and suites mr-mk of phase 3), which were derived from the
lithospheric mantle. The magmatic differentiation of the parental low-Ti magma of the tk type into a magma of the nd type
was associated with the derivation of an evolved magma of the nd type, which was depleted in ore elements, and an ore magma,
which was a mixture of silicate and sulfide melts, protocrysts of silicate minerals, and chromite. Judging from their geochemical
parameters, the intrusions of the lower Norilsk type were comagmatic with the lavas of the upper part of the nd suite, and
the ore-bearing intrusions of the upper Norilsk type were comagmatic with the lavas of the mr-mk suites. When the ore-bearing
intrusions were emplaced, their magmas entrained droplets of sulfide melt and protocrysts of olivine and chromite and brought
them to the modern magmatic chamber. These protocrysts are xenogenic with respect to the magma that formed the intrusions.
In certain instances (Talnakh and Kharaelakh intrusions), the moving magma entrained single portions of sulfide magma, which
were emplaced as individual subphases. The experimental study of the peridotite-basalt-fluid system shows that mantle reservoirs
with protoliths of subducted oceanic crustal material could serve as sources of relatively low-temperature (1250–1350°C) high-Ti
magnesian magmas of the rifting stage from an olivine-free source. 相似文献
17.
Zafer Aslan Dilber Erdem İrfan Temizel Mehmet Arslan 《International Geology Review》2017,59(14):1764-1785
Palaeogene and Neogene volcanic rocks are widespread on the Biga Peninsula of Northwest Turkey. These rocks were formed during the Eocene, Oligocene–Miocene, and late Miocene, and the early Miocene ?apç? volcanic rocks in the Bal?kesir area consist of andesitic lava flows and associated pyroclastics. Temperatures, pressures, and oxygen fugacities calculated for the hornblendes in these andesitic rocks are 903–930°C, 3.3–4.8 kbar, and –9.91 to –11.88, respectively, and for the biotites they are 755–788°C, 1.30–1.74 kbar, and –14.88 to –13.98, respectively. SHRIMP U–Pb dating of zircons from three andesite samples gave ages of 22.72 ± 0.19, 22.97 ± 0.23, and 18.72 ± 0.17 Ma (early Miocene), and these are regarded as crystallization ages. Geochemical analyses show that the volcanic rocks are mainly high-K and calc-alkaline, and have high contents of large-ion lithophile elements and low contents of high-field strength elements, revealing that they evolved from parental magmas that were derived from an enriched subcontinental lithospheric mantle source. The chondrite-normalized rare earth element patterns of the rocks are concave upwards with LaCN/LuCN = 11.9–21.2 and EuCN/Eu* = 0.84–0.92, implying significant fractional crystallization of hornblende during their evolution. According to the petrological data with regional geology, Neogene magmatic activity on the Biga Peninsula has a post-collisional feature, and was closely related to slab break-off geodynamic model after collision of Tauride–Anatolide Block and Sakarya continent. 相似文献
18.
Mohamed W. Ali-Bik Said H. Abd El Rahim Wael Abdel Wahab 《Arabian Journal of Geosciences》2014,7(10):4009-4027
A small intrusive fresh gabbroic mass intrudes the Neoproterozoic metasediments and Dokhan volcanics of Wadi Az Zarib area, Central Eastern Desert. It is composed of hornblende gabbros and leuco-hornblende gabbros. Their petrography, opaque mineralogy, and geochemistry are addressed to elucidate their tectonic setting and petrogenesis. They represent a subduction-related calc–alkaline magma that evolved in an island arc setting. In terms of maturity, the supposed arc represents an intermediate stage between continental arc and active continental margin. Thermobarometry and physical–chemical data of the parent magma as deduced from compositions of amphiboles, biotite, and plagioclase indicate crystallization temperatures of 931–825 °C at pressures of 6.16–4.01 kbar and H2Omelt of 6.4–5.2 wt%. Data, as presented, argue in favor of fractional crystallization mechanism to be accounted to the present suite to interpret the observed variations. The evolution of the suite from hornblende gabbros to leuco-hornblende gabbros was accompanied by decreasing of MgO, CaO, Cr, and Ni with simultaneous increasing of Al2O3, TiO2, Na2O, K2O, Ba, Rb, Sr, La, and Ce. Residuals calculated during mass balance fractional crystallization modeling suggest that brown and green hornblendes are the main fractionated phases which derived the melt composition towards the leuco-hornblende gabbros. 相似文献
19.
Amphibole and apatite insights into the evolution and mass balance of Cl and S in magmas associated with porphyry copper deposits 总被引:1,自引:0,他引:1
Chlorine and sulfur are of paramount importance for supporting the transport and deposition of ore metals at magmatic–hydrothermal systems such as the Coroccohuayco Fe–Cu–Au porphyry–skarn deposit, Peru. Here, we used recent partitioning models to determine the Cl and S concentration of the melts from the Coroccohuayco magmatic suite using apatite and amphibole chemical analyses. The pre-mineralization gabbrodiorite complex hosts S-poor apatite, while the syn- and post-ore dacitic porphyries host S-rich apatite. Our apatite data on the Coroccohuayco magmatic suite are consistent with an increasing oxygen fugacity (from the gabbrodiorite complex to the porphyries) causing the dominant sulfur species to shift from S2? to S6+ at upper crustal pressure where the magmas were emplaced. We suggest that this change in sulfur speciation could have favored S degassing, rather than its sequestration in magmatic sulfides. Using available partitioning models for apatite from the porphyries, pre-degassing S melt concentration was 20–200 ppm. Estimates of absolute magmatic Cl concentrations using amphibole and apatite gave highly contrasting results. Cl melt concentrations obtained from apatite (0.60 wt% for the gabbrodiorite complex; 0.2–0.3 wt% for the porphyries) seems much more reasonable than those obtained from amphibole which are very low (0.37 wt% for the gabbrodiorite complex; 0.10 wt% for the porphyries). In turn, relative variations of the Cl melt concentrations obtained from amphibole during magma cooling are compatible with previous petrological constraints on the Coroccohuayco magmatic suite. This confirms that the gabbrodioritic magma was initially fluid undersaturated upon emplacement, and that magmatic fluid exsolution of the gabbrodiorite and the pluton rooting the porphyry stocks and dikes were emplaced and degassed at 100–200 MPa. Finally, mass balance constraints on S, Cu and Cl were used to estimate the minimum volume of magma required to form the Coroccohuayco deposit. These three estimates are remarkably consistent among each other (ca. 100 km3) and suggest that the Cl melt concentration is at least as critical as that of Cu and S to form an economic mineralization. 相似文献
20.
A.
nal 《Geological Journal》2008,43(1):95-116
The Middle Miocene Orduzu volcanic suite, which is a part of the widespread Neogene Yamadağ volcanism of Eastern Anatolia, consists of a rhyolitic lava flow, rhyolitic dykes, a trachyandesitic lava flow and basaltic trachyandesitic dykes. Existence of mafic enclaves and globules in some of the volcanic rocks, and microtextures in phenocrysts indicate that magma mingling and mixing between andesitic and basaltic melts played an important role in the evolution of the volcanic suite. Major and trace element characteristics of the volcanic rocks are similar to those formed in convergent margin settings. In particular, incompatible trace element patterns exhibit large depletions in high field strength elements (Nb and Ta) and strong enrichments in both large ion lithofile elements (Ba, Th and U) and light rare earth elements, indicating a strong subduction signature in the source of the volcanic rocks. Furthermore, petrochemical data obtained suggest that parental magmas of rhyolite lava and dykes, and trachyandesite lava and basaltic trachyandesite dykes were derived from subduction‐related enriched lithospheric mantle and metasomatized mantle (± asthenosphere), respectively. A detailed mineralogical study of the volcanic suite shows that plagioclase is the principal phenocryst phase in all of the rock units from the Orduzu volcano. The plagioclase phenocrysts are accompanied by quartz in the rhyolitic lava flows and by two pyroxenes in the trachyandesitic lava flows and basaltic trachyandesitic dykes. Oxide phases in all rocks are magnetite and ilmenite. Calculated crystallization temperatures range from 650°C to 800°C for plagioclase, 745°C–1054°C for biotite, 888°C–915°C for pyroxene and 736°C–841°C for magnetite–ilmenite pairs. Calculated crystallization pressures of pyroxenes vary between 1.24–5.81 kb, and oxygen fugacity range from −14.47 to −12.39. The estimates of magmatic intensive parameters indicate that the initial magma forming the Orduzu volcanic unit began to crystallize in a high‐level magma chamber and then was stored in a shallow reservoir where it underwent intermediate‐mafic mixing. The rhyolitic lava flow and dykes evolved in relatively shallower crustal magma chambers. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献