The magnetic characteristics of returned lunar samples and 5heir implications for regolith processes

Magnetic observations yield information about the amount and nature of the magnetic phases present in a sample. They reveal that the predominant magnetic phase in the lunar samples is metallic iron which is sometimes alloyed with nickel and cobalt. In the mare basalts less than 0.1% of metallic iron is present, whereas in the non-mare crystalline rocks several percent of iron has been found in some samples. The soils have approximately 0.5% of iron, which is fine grain, rather pure iron occurring in impact glass. In the recrystallized breccias and the igneous rocks the iron is coarser. Systematic minor variations in metallic iron content in the soils reveal soil maturity trends. Mixing between highland and mare soils can be traced with the Fe²⁺ content. Mare soils differ from highland soils in having a higher value of reduced remanence. The magnetic characteristics of the Apollo 14 breccias are not consistent with the progressive metamorphism of a common starting material. Shock welding in the range of tens of kbs can account for the characteristics of some of the ‘unmetamorphosed’ breccias. Greater shock accompanied by recovery can account for the magnetic characteristics of the ‘recrystallized’ breccias.     

Constraints on the depth and variability of the lunar regolith

Abstract— Knowledge of regolith depth structure is important for a variety of studies of the Moon and other bodies such as Mercury and asteroids. Lunar regolith depths have been estimated using morphological techniques (i.e., Quaide and Oberbeck 1968; Shoemaker and Morris 1969), crater counting techniques (Shoemaker et al. 1969), and seismic studies (i.e., Watkins and Kovach 1973; Cooper et al. 1974). These diverse methods provide good first order estimates of regolith depths across large distances (tens to hundreds of kilometers), but may not clearly elucidate the variability of regolith depth locally (100 m to km scale). In order to better constrain the regional average depth and local variability of the regolith, we investigate several techniques. First, we find that the apparent equilibrium diameter of a crater population increases with an increasing solar incidence angle, and this affects the inferred regolith depth by increasing the range of predicted depths (from ～7–15 m depth at 100 m equilibrium diameter to ～8–40 m at 300 m equilibrium diameter). Second, we examine the frequency and distribution of blocky craters in selected lunar mare areas and find a range of regolith depths (8–31 m) that compares favorably with results from the equilibrium diameter method (8–33 m) for areas of similar age (～2.5 billion years). Finally, we examine the utility of using Clementine optical maturity parameter images (Lucey et al. 2000) to determine regolith depth. The resolution of Clementine images (100 m/pixel) prohibits determination of absolute depths, but this method has the potential to give relative depths, and if higher resolution spectral data were available could yield absolute depths.     

On the depth of the lunar regolith

The aim of this paper is to point out that if the sinuous rilles on the Moon represent trenches in the mare ground in which they meander, the existence of a great number of individual boulders on their slopes - as discovered on the high-resolution photographs taken by US Lunar Orbiters 4 and 5 in 1967 - suggests that the solid substrate of the lunar globe is covered by broken-up debris produced by cosmic abrasion - and hereafter referred to as lunar regolith - of thickness comparable with the depth of the respective rilles - at least of those lacking flat floors; which is generally in the order of 200–300 m. This depth is much greater than that indicated previously by other methods possessing more limited depth in range; and need not apply uniformly all over the Moon. In point of fact, marial regions abounding in sinuous rilles may represent loci where the lunar regolith has developed its maximum depth.     

Distribution, ,movement,and evolution of the volatile elements in the lunar regolith

The abundances and distributions of carbon, nitrogen, and sulfur in lunar soils are reviewed. Carbon and nitrogen have a predominantly extra-lunar origin in lunar soils and breccias, while sulfur is mostly indigeneous to the Moon. The lunar processes which effect the movement, distribution, and evolution of carbon, nitrogen, and sulfur, along with the volatile alkali elements sodium, potassium, and rubidium during regolith processes are discussed. Possible mechanisms which may result in the addition to or loss from the Moon of these volatile elements are considered.     

Properties of the Hermean regolith: V. New optical reflectance spectra, comparison with lunar anorthosites, and mineralogical modelling

We present new optical (0.4-0.65 μm) spectra of Mercury and lunar pure anorthosite locations, obtained quasi-simultaneously with the Nordic Optical Telescope (NOT) in 2002. A comparative study is performed with the model of Lucey et al. (2000, J. Geophys. Res. 105, 20297-20305, and references therein) between iron-poor, mature, pure anorthosite (>90% plagioclase feldspar) Clementine spectra from the lunar farside and a combined 0.4-1.0 μm mercurian spectrum, obtained with the NOT, calculated for standard photometric geometry. Mercury is located at more extreme locations in the Lucey ratio-reflectance diagrams than any known lunar soil, specifically with respect to the extremely iron-poor mature anorthosites. Though quantitative prediction of FeO and TiO₂ abundances cannot be made without a more generally applicable model, we find qualitatively that the abundances of both these oxides must be near zero for Mercury. We utilize the theory of Hapke (2002, Icarus 157, 523-534, and references therein), with realistic photometric parameters, to model laboratory spectra of matured mineral powders and lunar soils, and remotely sensed spectra of lunar anorthosites and Mercury. An important difference between fabricated and natural powders is the high value for the internal scattering parameter necessary to interpret the spectra for the former, and the requirement of rough and non-isotropically scattering surfaces in the modelling of the latter. The mature lunar anorthosite spectra were well modelled with binary mixtures of calcic feldspars and olivines, grain sizes of 25-30 μm and a concentration of submicroscopic metallic iron (SMFe) of 0.12-0.15% in grain coatings. The mercurian spectrum is not possible to interpret from terrestrial mineral powder spectra without introducing an average particle scattering function for the bulk soil that increases in backscattering efficiency with wavelength. The observed spectrum is somewhat better predicted with binary mixture models of feldspars and pyroxenes, than with single-component regoliths consisting of either albite or diopside. Correct spectral reflectance values were predicted with a concentration of 0.1 wt% SMFe in coatings of 15-30 μm sized grains. Since reasonable cosmogonical formation scenarios for Mercury, or meteoritic infall, predict iron concentrations at least this high, we draw the conclusion that the average grain size of Mercury is about a factor of two smaller than for average returned lunar soil samples. The 0.6-2.5 μm spectrum of McCord and Clark (1979, J. Geophys. Res. 178, 745-747) is used to further limit the possible range of mineralogical composition of Mercury. It is found that an intimately mixed and matured 3:1 labradorite-to-enstatite regolith composition best matches both the optical and near-infrared spectra, yielding an abundance of ∼1.2 wt% FeO and ∼0 wt% TiO₂.     

Implications for asteroidal regolith properties from comparisons with the lunar phase relation and theoretical considerations

The phase relations of several asteroids. Mercury, and the Moon display the same basic characteristics, but differ slightly in detail. An improved treatment of the photometric function for open-work particulate layers shows that for phase angles greater than about 7°, the shape of the curves is diagnostic of the presence of such layers, and that both the shape and slope of the curves is dependent primarily upon the bulk density of these layers. This treatment also strongly indicates that the “opposition effect” is not due to shadow hiding in a regolith of very low bulk density. Other data support the idea that this effect is unrelated to shadow-hiding phenomena, and that it may thus be a diffraction/scattering effect with or without internal reflection phenomena also.     

Horizontal transport of the regolith,modification of features,and erosion rates on the lunar surface

New lunar soils, freshly deposited as impact ejecta, evolve into more mature soils by a complex set of processes involving both near-surface effects and mixing. Poor vertical mixing statistics and interregional exchange by impact ejection complicate the interpretation of soil maturization. Impact ejecta systematics are developed for the smaller cratering events which, with cumulative crater populations observed in young mare regions and on Copernicus ejecta fields, yield rates and a range distribution for the horizontal transport of material by impact processes. The deposition rate for material originating more than 1 m away is found to be about 8 mm m.y.^?1 Material from 10 km away accumulates at a rate of about 0.08 mm m.y.^?1, providing a steady influx of foreign material. From the degradation of boulder tracks, a rate of 5±3 cm m.y.^?1 is computed for the filling of shallow lunar depressions on slopes. Mass wastage and downslope movement of bedrock outcroppings on Hadley Rille seems to be proceeding at a rate of about 8 mm m.y.^?1 The Camelot profile is suggestive of a secondary impact feature.     

Effects of maturation on the reflectance of the lunar regolith: Apollo 16 — A case study

Soils at the Apollo 16 site become progressively darker as the percentage of glassy agglutinates increases. Magnetic separates of the agglutinate fraction of a soil always are darker than the bulk soil, and darker than the non-agglutinate fraction that consists of rock and mineral fragments. Darkening of a soil with maturity is due mainly to the increasing proportion of agglutinates. Coating of rock and mineral fragments with thin deposits of glass aids darkening in a minor way, but most of these particles eventually are destroyed by melting as the soils mature.Present address: Dept. of Geological Sciences, University of Washington, Seattle, Wash., U.S.A.     

Some characteristic magnetic properties of lunar materials

One of the typical magnetic characteristics of lunar materials is the composition of their ferromagnetic constituent. Lunar breccias often contain kamacite (less than 7 weight per cent of Ni content) as well as almost pure metallic iron. Metallic ferromagnetics in most igneous rocks are almost pure iron, but the kamacite phase also has been found in some Apollo 15 igneous rocks. It seems likely therefore the metallic ferromagnetics in the lunar crust are more or less similar to those in chondrites.Another typical magnetic characteristic of lunar materials is the presence of a considerable amount of superparamagnetically fine particles of metallic iron. A higher relative content of such fine iron particles results in a higher value of the ratio of magnetic susceptibility (o) to saturation magnetization (I _s), a smaller ratio of the coercive force (H _c) to remanence coercive force (H _RC), and an extremely higher ratio of the viscous component (I _v) to the stable one (I _s) of the remanent magnetization.Communication presented at the Lunar Science Institute Conference on Geophysical and Geochemical Exploration of the Moon and Planets, January 10–12, 1973.     

Spectral properties, magnetic fields, and dust transport at lunar swirls

Lunar swirls are albedo anomalies associated with strong crustal magnetic fields. Swirls exhibit distinctive spectral properties at both highland and mare locations that are plausibly explained by fine-grained dust sorting. The sorting may result from two processes that are fairly well established on the Moon, but have not been previously considered together. The first process is the vertical electrostatic lofting of charged fine dust. The second process is the development of electrostatic potentials at magnetic anomalies as solar wind protons penetrate more deeply into the magnetic field than electrons. The electrostatic potential can attract or repel charged fine-grained dust that has been lofted. Since the finest fraction of the lunar soil is bright and contributes significantly to the spectral properties of the lunar regolith, the horizontal accumulation or removal of fine dust can change a surface’s spectral properties. This mechanism can explain some of the spectral properties of swirls, accommodates their association with magnetic fields, and permits aspects of weathering by micrometeoroids and the solar wind.     

A Monte Carlo model for the gardening of the lunar regolith

The processes of movement and turnover of the lunar regolith are described by a Monte Carlo model, which includes the effects of collisions by particles from 10^?7 g to 10¹⁰ g. The movement of material by the direct cratering process is the dominant mode, but slumping is also included for angles exceeding the static angle of repose. Using a group of interrelated computer programs a large number of properties are calculated, including topography, formation of layers, depth of the disturbed layer, nuclear track distributions, cosmogenic nuclides and others. In the most complex program, the history of a 36 point square array is followed for times up to 4 × 10⁸ yr. As expected the histories generated are complex and exhibit great variety. Because a crater covers much less area than its ejecta blanket, there is a tendency for the height change at a test point to exhibit the ‘gambler's ruin’ phenomenon: periods of slow accumulation followed by sudden excavation. In general the agreement with experiment and observation seems good. Two areas of disagreement stand out. First, the calculated surface is rougher than that observed. This problem is understood, and will not occur in a newer version of the model. Second, the observed bombardment ages, of the order of 4 × 10⁸ yr, are shorter than expected (by perhaps a factor of 5). We cannot accept Fireman's (1974) explanation; this remains an important puzzle.     

The regolith portion of the lunar meteorite Sayh al Uhaymir 169

Abstract— –Sayh al Uhaymir (SaU) 169 is a composite lunar meteorite from Oman that consists of polymict regolith breccia (8.44 ppm Th), adhering to impact‐melt breccia (IMB; 32.7 ppm Th). In this contribution we consider the regolith breccia portion of SaU 169, and demonstrate that it is composed of two generations representing two formation stages, labeled II and III. The regolith breccia also contains the following clasts: Ti‐poor to Ti‐rich basalts, gabbros to granulites, and incorporated regolith breccias. The average SaU 169 regolith breccia bulk composition lies within the range of Apollo 12 and 14 soil and regolith breccias, with the closest correspondence being with that of Apollo 14, but Sc contents indicate a higher portion of mare basalts. This is supported by relations between Sm‐Al₂O₃, FeO‐Cr₂O₃‐TiO₂, Sm/Eu and Th‐K₂O. The composition can best be modeled as a mixture of high‐K KREEP, mare basalt and norite/troctolite, consistent with the rareness of anorthositic rocks. The largest KREEP breccia clast in the regolith is identical in its chemical composition and total REE content to the incompatible trace‐element (ITE)‐ rich high‐K KREEP rocks of the Apollo 14 landing site, pointing to a similar source. In contrast to Apollo 14 soil, SaU 169 IMB and SaU 169 KREEP breccia clast, the SaU 169 regolith is not depleted in K/Th, indicating a low contribution of high‐Th IMB such as the SaU 169 main lithology in the regolith. The data presented here indicate the SaU 169 regolith breccia is from the lunar front side, and has a strong Procellarum KREEP Terrane signature.     

Petrology,chemistry, and isotopic compositions of the lunar highland regolith breccia Dar al Gani 262

Abstract— Lunar meteorite Dar al Gani 262 (DG 262)—found in the Libyan part of the Sahara—is a mature, anorthositic regolith breccia with highland affinities. The origin from the Moon is undoubtedly indicated by its bulk chemical composition; radionuclide concentrations; noble gas, N, and O isotopic compositions; and petrographic features. Dar al Gani 262 is a typical anorthositic highland breccia similar in mineralogy and chemical composition to Queen Alexandra Range (QUE) 93069. About 52 vol% of the studied thin sections of Dar al Gani 262 consist of fine-grained(100 μm) constituents, and 48 vol% is mineral and lithic clasts and impact-melt veins. The most abundant clast types are feldspathic fine-grained to microporphyritic crystalline melt breccias (50.2 vol%; includes recrystallized melt breccias), whereas mafic crystalline melt breccias are extremely rare (1.4 vol%). Granulitic lithologies are 12.8 vol%, intragranularly recrystallized anorthosites and cataclastic anorthosites are 8.8 and 8.2 vol%, respectively, and (devitrified) glasses are 2.7 vol%. Impact-melt veins (5.5 vol% of the whole thin sections) cutting across the entire thin section were probably formed subsequent to the lithification process of the bulk rock at pressures below 20 GPa, because the bulk rock never experienced a higher peak shock pressure. Mafic crystalline melt breccias are very rare in Dar al Gani 262 and are similar in abundance to those in QUE 93069. The extremely low abundance of mafic components and the bulk composition may constrain possible areas of the Moon from which the breccia was derived. The source area of Dar al Gani 262 must be a highland terrain lacking significant mafic impact melts or mare components. On the basis of radionuclide activities, an irradiation position of DG 262 on the Moon at a depth of 55–85 g/cm³and a maximum transit time to Earth <0.15 Ma is suggested. Dar al Gani 262 contains high concentrations of solar-wind-implanted noble gases. The isotopic abundance ratio ⁴⁰Ar/³⁶Ar < 3 is characteristic of lunar soils. The terrestrial weathering of DG 262 is reflected by the occurrence of fractures filled with calcite and by high concentrations of Ca, Ba, Cs, Br, and As. There is also a large amount of terrestrial C and some N in the sample, which was released at low temperatures during stepped heating. High concentrations of Ni, Co, and Ir indicate a significant meteoritic component in the lunar surface regolith from which DG 262 was derived.     

Echo simulation of lunar penetrating radar: based on a model of inhomogeneous multilayer lunar regolith structure

Lunar Penetrating Radar(LPR) based on the time domain Ultra-Wideband(UWB) technique onboard China's Chang'e-3(CE-3) rover, has the goal of investigating the lunar subsurface structure and detecting the depth of lunar regolith. An inhomogeneous multi-layer microwave transfer inverse-model is established. The dielectric constant of the lunar regolith, the velocity of propagation, the reflection, refraction and transmission at interfaces, and the resolution are discussed. The model is further used to numerically simulate and analyze temporal variations in the echo obtained from the LPR attached on CE-3's rover, to reveal the location and structure of lunar regolith. The thickness of the lunar regolith is calculated by a comparison between the simulated radar B-scan images based on the model and the detected result taken from the CE-3 lunar mission. The potential scientific return from LPR echoes taken from the landing region is also discussed.     

Identification of magnetite in lunar regolith breccia 60016: Evidence for oxidized conditions at the lunar surface

Lunar regolith breccias are temporal archives of magmatic and impact bombardment processes on the Moon. Apollo 16 sample 60016 is an “ancient” feldspathic regolith breccia that was converted from a soil to a rock at ~3.8 Ga. The breccia contains a small (70 × 50 μm) rock fragment composed dominantly of an Fe‐oxide phase with disseminated domains of troilite. Fragments of plagioclase (An_95‐97), pyroxene (En_74‐75, Fs_21‐22,Wo_3‐4), and olivine (Fo_66‐67) are distributed in and adjacent to the Fe‐oxide. The silicate minerals have lunar compositions that are similar to anorthosites. Mineral chemistry, synchrotron X‐ray absorption near edge spectroscopy (XANES) and X‐ray diffraction (XRD) studies demonstrate that the oxide phase is magnetite with an estimated Fe³⁺/ΣFe ratio of ~0.45. The presence of magnetite in 60016 indicates that oxygen fugacity during formation was equilibrated at, or above, the Fe‐magnetite or wüstite–magnetite oxygen buffer. This discovery provides direct evidence for oxidized conditions on the Moon. Thermodynamic modeling shows that magnetite could have been formed from oxidization‐driven mineral replacement of Fe‐metal or desulphurisation from Fe‐sulfides (troilite) at low temperatures (<570 °C) in equilibrium with H₂O steam/liquid or CO₂ gas. Oxidizing conditions may have arisen from vapor transport during degassing of a magmatic source region, or from a hybrid endogenic–exogenic process when gases were released during an impacting asteroid or comet impact.     

Quantitative estimation of helium-3 spatial distribution in the lunar regolith layer

³He (helium-3) in the lunar regolith implanted by the solar wind is one of the most valuable resources because of its potential as a fusion fuel. The abundance of ³He in the lunar regolith is related to solar wind flux, lunar surface maturity and TiO₂ content, etc. A model of solar wind flux, which takes account of variations due to shielding of the nearside when the Moon is in the Earth's magnetotail, is used to present a global distribution of relative solar wind flux over the lunar surface. Using Clementine UV/VIS multispectral data, the global distribution of lunar surface optical maturity (OMAT) and the TiO₂ content in the lunar regolith are calculated. Based on Apollo regolith samples, a linear relation between ³He abundance and normalized solar wind flux, optical maturity, and TiO₂ content is presented. To simulate the brightness temperature of the lunar surface, which is the mission of the Chinese Chang-E project's multichannel radiometers, a global distribution of regolith layer thickness is first empirically constructed from lunar digital elevation mapping (DEM). Then an inversion approach is presented to retrieve the global regolith layer thickness. It finally yields the total amount of ³He per unit area in the lunar regolith layer, which is related to the regolith layer thickness, solar wind flux, optical maturity and TiO₂ content, etc. The global inventory of ³He is estimated as 6.50×¹⁰⁸ kg, where 3.72×¹⁰⁸ kg is for the lunar nearside and 2.78×¹⁰⁸ kg is for the lunar farside.     

Vertical-structure effects on planetary microwave brightness temperature measurements: Applications to the lunar regolith

The effects of vertical variations in density and dielectric constant on nadir-viewing microwave brightness temperatures are examined. Stratification models as well as models of a continuous increase in density with depth are analyzed. Specific applications address the vertical structure of the lunar frontside regolith, utilizing combined constraints from Apollo data, bistatic radar signatures, and Earth-based measurements of the lunar microwave brightness temperature.Results have been analyzed in terms of the effects on the zeroth and first harmonic of the lunar disk-center brightness temperature variation over a lunation, and their wavelength dependence. Lunation-mean brightness temperatures, which are diagnostic of emissivity and steady-state sub-surface temperatures, are sensitive to both near-surface soil density gradients and single high-impedance dielectric contrasts. Models of the rapid density increase in the upper 5–10 cm of the lunar regolith predict brightness temperature decreases of 2–10°K between λ₀ = 3 and 30 cm. The magnitude of this spectral variation depends upon the thickness of a postulated low-density surface coating layer, and the magnitude of the density gradient in the transition soil layer. Comparable decreases in brightness temperature can be produced by a stratified two-layer model of soil overlaying bedrock if the high-density substrate lies within 1–2 m of the surface. Multiple soil layering on a centimeter scale, such as is observed in the Apollo core samples, is not likely to induce spectral variations in mean brightness temperature due to rapid regional variations in layer depths and thicknesses.The fractional variation in disk-center brightness temperature over a lunation (first harmonic) can be altered by vertical-structure effects only for the case in which a larger and abrupt dielectric contrast exists within the upper surface layer where the significant diurnal variations in physical temperature occur. Soil density variations do not cause scattering effects sufficient to significantly alter the microwave emission weighting function within the diurnal layer. For the Moon, this layer consists of the upper 10 cm. Since no widespread rock substrate as shallow as 10 cm exists in the lunar frontside, only volume scattering effects, due to buried shallow rock fragments, can explain the apparent high electrical loss inferred from Earth-based measurements of the amplitude of lunation brightness temperature variations.Representative models of the lunar frontside vertical structure have also been examined for their effects of radar cross-section measurements and resultant inferences of bulk dielectric constant. Models of the near-surface density gradient predict a significant increase in the remotely inferred dielectric constant value from centimeter to meter wavelengths. Such a model is in general agreement with the dielectric constant spectrum inferred from Earth-based brightness temperature polarization measurements, but is difficult to reconcile with the Apollo bistatic radar results at λ₀ = 13 and 116 cm.