AN EXAMPLE OF A THERMALLY METAMORPHOSED AGGLUTINATE

A single fragment from an Apollo 16 soil appears to be a soil agglutinate that has experienced thermal metamorphism. Its texture is similar to that observed in many of the samples of recrystallized polymict breccias collected in the lunar highlands. Debris blankets, consisting largely of mineral and lithic clasts and derived from highland bedrock by major impacts, are less likely than agglutinate-rich soil from the highland megaregolith to be the progenitor of this class of recrystallized rocks.     

Lithologic distribution and geologic history of the Apollo 17 site: The record in soils and small rock particles from the highland massifs

Abstract— Through analysis by instrumental neutron activation (INAA) of 789 individual lithic fragments from the 2 mm–4 mm grain-size fractions of five Apollo 17 soil samples (72443, 72503, 73243, 76283, and 76503) and petrographic examination of a subset, we have determined the diversity and proportions of rock types recorded within soils from the highland massifs. The distribution of rock types at the site, as recorded by lithic fragments in the soils, is an alternative to the distribution inferred from the limited number of large rock samples. The compositions and proportions of 2 mm–4 mm fragments provide a bridge between compositions of <1 mm fines, and types and proportions of rocks observed in large collected breccias and their clasts. The 2 mm–4 mm fraction of soil from South Massif, represented by an unbiased set of lithic fragments from station-2 samples 72443 and 72503, consists of 71% noritic impact-melt breccia, 7% incompatible-trace-element-(ITE)-poor highland rock types (mainly granulitic breccias), 19% agglutinates and regolith breccias, 1% high-Ti mare basalt, and 2% others (very-low-Ti (VLT) basalt, monzogabbro breccia, and metal). In contrast, the 2 mm–4 mm fraction of a soil from the North Massif, represented by an unbiased set of lithic fragments from station-6 sample 76503, has a greater proportion of ITE-poor highland rock types and mare-basalt fragments: it consists of 29% ITE-poor highland rock types (mainly granulitic breccias and troctolitic anorthosite), 25% impact-melt breccia, 13% high-Ti mare basalt, 31% agglutinates and regolith breccias, 1% orange glass and related breccia, and 1% others. Based on a comparison of mass-weighted mean compositions of the lithic fragments with compositions of soil fines from all Apollo 17 highland stations, differences between the station-2 and station-6 samples are representative of differences between available samples from the two massifs. From the distribution of different rock types and their compositions, we conclude the following: (1) North-Massif and South-Massif soil samples differ significantly in types and proportions of ITE-poor highland components and ITE-rich impact-melt-breccia components. These differences reflect crudely layered massifs and known local geology. The greater percentage of impact-melt breccia in the South-Massif light-mantle soil stems from derivation of the light mantle from the top of the massif, which apparently is richer in noritic impact-melt breccia than are lower parts of the massifs. (2) At station 2, the 2 mm–4 mm grain-size fraction is enriched in impact-melt breccias compared to the <1 mm fraction, suggesting that the <1 mm fraction within the light mantle has a greater proportion of lithologies such as granulitic breccias which are more prevalent lower in the massifs and which we infer to be older (pre-basin) highland components. (3) Soil from station 6, North Massif, contains magnesian troctolitic anorthosite, which is a component that is rare in station-2 South-Massif soils. (4) Compositional differences between poikilitic impact-melt breccias from the two massifs suggest broad-scale heterogeneity in impact-melt breccia interpreted by most investigators to be ejecta from the Serenitatis basin. We have found rock types not previously recognized or uncommon at the Apollo 17 site. These include (1) ITE-rich impact-melt breccias that are compositionally distinct from previously recognized “aphanitic” and “poikilitic” groups at Apollo 17; (2) regolith breccias that are free of mare components and poor in impact melt of the types associated with the main melt-breccia groups, and that, if those groups derive from the Serenitatis impact, may represent the pre-Serenitatis surface; (3) several VLT basalts, including an unusual very-high-K basaltic breccia; (4) orange-glass regolith breccias; (5) aphanitic-matrix melt breccias at station 6; (6) fragments of alkali-rich composition, including alkali anorthosite, and monzogabbro; (7) one fragment of 72275-type KREEP basalt from station 3; (8) seven lithic fragments of ferroan-anorthositic-suite rocks; and (9) a fragment of metal, possibly from an L chondrite. Some of these lithologies have been found only as lithic fragments in the soils and not among the large rock samples. In contrast, we have not found among the 2 mm–4 mm lithic fragments individual samples of certain lithologies that have been recognized as clasts in breccias (e.g., dunite and spinel troctolite). The diversity of lithologic information contained in the lithic fragments of these soils nearly equals that found among large rock samples, and most information bearing on petrographic relationships is maintained, even in such small samples. Given a small number of large samples for “petrologic ground truth,” small lithic fragments contained in soil “scoop” samples can provide the basis for interpreting the diversity of rock types and their proportions in remotely sensed geologic units. They should be considered essential targets for future automated sample-analysis and sample-return missions.     

The spatial and temporal distribution of lunar mare basalts as deduced from analysis of data for lunar meteorites

In this work we analyze data for lunar meteorites with emphasis on the spatial and temporal distribution of lunar mare basalts. The data are mostly from the Lunar Meteorite Compendium (http://www-curator.jsc.nasa.gov/antmet/lmc/contents.cfm cited hereafter as Compendium) compiled by Kevin Righter, NASA Johnson Space Center, and from the associated literature. Analysis of the data showed that (i) a significant part of the lunar meteorite source craters are not larger than hundreds of meters in diameter; (ii) cryptomaria seem to be rather abundant in lunar highlands; (iii) the ratios of lunar meteorites belonging to three broad petrologic groups (mare basalt/gabbro, feldspatic highland breccias, and mingled breccias which are a mixture of mare and highland components) seem to be roughly proportional to the areal distribution of these rocks on the lunar surface; and (iv) the meteorite mare basalt ages show a range from ～2.5 to 4.3 Ga and fill the gaps in the Apollo/Luna basalt age distribution. The ages of mare basalt clasts from mingled breccias seem to be systematically higher than those of “normal” mare basalts, which supports the suggestion that mingled breccias originated mostly from cryptomaria.     

Lunar meteorite Queen Alexandra Range 93069: A lunar highland regolith breccia with very low abundances of mafic components

Abstract— Lunar meteorite QUE 93069 found in Antarctica is a mature, anorthitic regolith breccia with highland affinities that was ejected from the Moon <0.3 Ma ago. The frequency distribution of mineral and lithic clasts gives information about the nature of the regolith and subregolith basement near the ejection site as well as about the abundances of rock types shocked to different degrees prior to the breccia formation. Thin section QUE 93069,37 consists of 67.5 vol% fine-grained (<～130 μm) constituents and 32.5 vol% mineral and lithic clasts and an impact melt vein. The most abundant types of these clasts are intragranularly recrystallized anorthosites and plagioclases (together 26.3 vol%) and feldspathic fine-grained to microporphyritic crystalline melt breccias (21.9 vol%). Mafic crystalline melt breccias are extremely rare (1.3 vol%). Granulitic lithologies are 10.4 vol%, recrystallized feldspathic melt breccias are 15.0 vol%, and glasses are 3.5 vol%. The impact melt vein cutting across the entire thin section was probably formed subsequent to the lithification process of the bulk rock at pressures below 20 GPa, because the bulk rock never experienced a higher peak shock pressure. Lunar meteorite QUE 93069 has a higher abundance of clear glass, occurring within melt spherules, glassy fragments, and an impact melt vein than lunar meteorites ALHA81005, Y-791197, Y-82192/3, Y-86032, or MAC 88104/5. The high abundance of melt spherules indicates that this lunar meteorite contains the highest content of typical regolith components. Mafic crystalline melt breccias are much rarer in QUE 93069 than in all other lunar highland regolith breccias. The extremely low abundance of mafic components may constrain possible areas of the Moon, from which the breccia was derived. The source area of QUE 93069 must be a highland terrain lacking significant mafic impact melts or mare components.     

Petrology,chemistry, and isotopic compositions of the lunar highland regolith breccia Dar al Gani 262

Abstract— Lunar meteorite Dar al Gani 262 (DG 262)—found in the Libyan part of the Sahara—is a mature, anorthositic regolith breccia with highland affinities. The origin from the Moon is undoubtedly indicated by its bulk chemical composition; radionuclide concentrations; noble gas, N, and O isotopic compositions; and petrographic features. Dar al Gani 262 is a typical anorthositic highland breccia similar in mineralogy and chemical composition to Queen Alexandra Range (QUE) 93069. About 52 vol% of the studied thin sections of Dar al Gani 262 consist of fine-grained(100 μm) constituents, and 48 vol% is mineral and lithic clasts and impact-melt veins. The most abundant clast types are feldspathic fine-grained to microporphyritic crystalline melt breccias (50.2 vol%; includes recrystallized melt breccias), whereas mafic crystalline melt breccias are extremely rare (1.4 vol%). Granulitic lithologies are 12.8 vol%, intragranularly recrystallized anorthosites and cataclastic anorthosites are 8.8 and 8.2 vol%, respectively, and (devitrified) glasses are 2.7 vol%. Impact-melt veins (5.5 vol% of the whole thin sections) cutting across the entire thin section were probably formed subsequent to the lithification process of the bulk rock at pressures below 20 GPa, because the bulk rock never experienced a higher peak shock pressure. Mafic crystalline melt breccias are very rare in Dar al Gani 262 and are similar in abundance to those in QUE 93069. The extremely low abundance of mafic components and the bulk composition may constrain possible areas of the Moon from which the breccia was derived. The source area of Dar al Gani 262 must be a highland terrain lacking significant mafic impact melts or mare components. On the basis of radionuclide activities, an irradiation position of DG 262 on the Moon at a depth of 55–85 g/cm³and a maximum transit time to Earth <0.15 Ma is suggested. Dar al Gani 262 contains high concentrations of solar-wind-implanted noble gases. The isotopic abundance ratio ⁴⁰Ar/³⁶Ar < 3 is characteristic of lunar soils. The terrestrial weathering of DG 262 is reflected by the occurrence of fractures filled with calcite and by high concentrations of Ca, Ba, Cs, Br, and As. There is also a large amount of terrestrial C and some N in the sample, which was released at low temperatures during stepped heating. High concentrations of Ni, Co, and Ir indicate a significant meteoritic component in the lunar surface regolith from which DG 262 was derived.     

Meteoritic material on the moon

Three types of meteoritic material are found on the Moon: micrometeorites, ancien planetesimal debris from the ‘early intense bombardment’, and debris of recent, crater-forming projectiles. Their amounts and compositions have been determined from trace element studies. The micrometeorite component is uniformly distributed over the entire lunar surface, but is seen most clearly in mare soils. It has a primitive, C1-chondrite-like composition, and comprises 1-1.5% of mature soils. Apparently it represents cometary debris. The mean annual influx rate is 2.4 × 10^?9 g cm^?2 yr^?1. It shows no detectable time variation or dependence on selenographic position. The ancient component is seen in highland breccias and soils more than 3.9 AE old. It has a fractionated composition, with volatiles depleted relative to siderophiles. The abundance pattern does not match that of any known meteorite class. At least two varieties exist (LN and DN, with Ir/Au, Re/Au 0.25-0.5 and > 0.5 the C1 value). Both seem to represent the debris of planetesimals that produced the mare basins and highland craters during the first 700 Myr of the Moon's history. It appears that the LN and DN objects impacted at less then 10 km s^?1, had diameters less than 100 km, contained more than 15% Fe, and were not internally differentiated. Both were depleted in volatiles; the LN objects also in refractories (Ir, Re). This makes it unlikely that the LN bodies served as important building blocks of the Moon. The crater-forming component has remained elusive. Only a possible hint of this component has been seen, in ejecta from Dune Crater and Apollo 12 KREEP glasses of Copernican (?) origin.     

Lunar rock magnetism

The relationship between the magnetization and temperature in a high constant magnetic field for a temperature range between 5 K and 1100 K was examined for Apollo 11, 12 and 14 lunar materials. The average value of Curie point temperature is (768.2 ± 3.5)°C for the lunar igneous rocks and (762.5 ± 3.4)°C for the lunar fines and breccias. A tentative conclusion about the ferromagnetic substance in the lunar materials would be that Fe is absolutely dominant with a slight association of Ni and Co, and probably Si also, in the lunar native irons.The antiferromagnetic phase of ilmenite and the paramagnetic phase of pyroxenes are considerably abundant in all lunar materials. However, a discrepancy of observed magnetization from a simulated value based on known magnetic elements for the temperature range between 10 and 40 K suggests that pyroxene phase represented by (M _x Fe_1-x ) SiO₃ (whereM = Ca²⁺, Mg²⁺, etc and 0 x 1/4) also may behave antiferromagnetically.Magnetic hysteresis curves are obtained at 5 K and 300 K, and the viscous magnetic properties also are examined for a number of lunar materials. The superparamagnetically viscous magnetization has been experimentally proven as due to fine grains of metallic iron less than 200 Å in mean diameter. The viscous magnetization is dominant in the lunar fines and breccias which is classified into Type II, while it is much smaller than the stable magnetic component in lunar igneous rocks (Type I). The superparamagnetically fine particles of metallic iron are mostly blocked at 5 K in temperature; thus coercive force (H _c ) and saturation remanent magnetization (I _R ) become much large at 5 K as compared with the corresponding values at 300 K.Strongly impact-metamorphosed parts of lunar breccias have an extremely stable NRM which could be attributed to TRM. NRM of the lunar igneous rocks and majority of breccias (or clastic rocks) are intermediately stable, but their stability is considerably higher than that of IRM of the same intensity. This result may imply that some mechanism which causes an appreciable magnitude of NRM and the higher stability, such as the shock effect, may take place on the lunar surface in addition to TRM mechanism for special cases.A particular igneous rock (Sample 14053) is found to have an unusually strong magnetism owing to a high content of metallic iron (about 1 weight percent), and its NRM amounts to 2 × 10^–3 emu/g. The abundance of such highly magnetic rocks is not known as yet but it seems that the observed magnetic anomalies on the lunar surface could be related to such highly magnetized rock masses.     

Report of the Working Party on the classification of the lunar igneous rocks

Abstract— A report is presented for a possible revised classification of lunar igneous rocks that still uses the division of Moon rocks into mare and highland types. It subdivides the mare rocks into basalts depending on TiO₂ content and glasses depending on colour, and subdivides the highland rocks principally into KREEP basalts and into coarse‐grained igneous rocks comparable to and using terrestrial igneous rock terminology.     

Comparison of the analytical results from the surveyor,Apollo, and Luna missions

The principal chemical element composition and inferred mineralogy of the powdered lunar surface material at seven mare and one terra sites on the Moon are compared. The mare compositions are all similar to one another and comparable to those of terrestrial ocean ridge basalts except in having higher titanium and much lower sodium contents than the latter. These analyses suggest that most, if not all, lunar maria have this chemical composition and are derived from rocks with an average density of 3.19 g cm^–3. Mare Tranquillitatis differs from the other maria in having twice the titanium content of the others.The chemical composition of the single highland site studied (Surveyor 7) is distinctly different from that of any of the maria in having much lower amounts of titanium and iron and larger amounts of aluminium and calcium. Confirmation of these general characteristics of lunar highland material has come from recent observations by the Apollo 15 Orbiter. The inferred mineralogy is 45 mole percent high anorthite plagioclase and the parent rocks have an estimated density of 2.94 g cm^–3. The Surveyor 7 chemical composition is the principal contributor to present estimates of the overall chemical composition of the lunar surface.Presented at the NATO Advanced Study Institute on Lunar Studies, Patras, Greece, September 14–25, 1971. This paper is an expanded and updated version of a paper presented at the Apollo 12 Lunar Science Conference, Houston, Texas, January 11–14, 1971, and published in the Proceedings of this Conference (Turkevich, 1971).     

Procrustean science: Indigenous siderophiles in the lunar highlands,according to Delano and Ringwood

The best estimate of indigenous lunar siderophiles comes from 29 pristine lunar rocks, characterized by low siderophile abundances, plutonic textures, and high age. Delano and Ringwood's blanket rejection of these rocks, on the contention that they are impact melts, is not justified by the petrologic evidence. Contrary to their claims, gold in highland breccias is largely meteoritic and is unaffected by fumarolic volcanism, as shown by its correlation with Ir and noncorrelation with fumarolic T1 (r=0.896 and 0.272). Delano and Ringwood's approach, involving subtraction of an H-chondrite meteoritic component from highland breccias, ignores the variation of Ir/Au ratios in modern and ancient meteorites, and hence leads to spurious excesses of Au, Ni, and volatiles, and in some cases to physically meaningless, negative residuals. Their excess volatiles in highland crust relative to mare basalts disappear when the highland composition is based on pristine lunar rocks rather than under-corrected breccias. Contrary to claims by Delano and Ringwood, the Ni/Co trend in Apollo 16 samples cannot be explained by an indigenous component rich in Ni (150–200 ppm) and Co (30–45ppm); mixing lines show that much lower Ni and Co contents are required (e.g., 7 ppm each).Chondrites and lunar highland breccias show essentially parallel fractionation trends for the siderophile-element ratios Re/Ir, Au/Ir, Ni/Ir, Ni/Pd, and Os/Ir. Because the chondritic ratios were established in the solar nebula, it appears that the lunar ratios also reflect nebular processes, and have not been modified by planetary processes.Properly derived abundances for the lunar highlands show large, systematic depletions relative to terrestrial oceanic tholeiites, by the following factors: Ge 270, Re 230, Sb170, Zn150, Au60, Tl 50, Ag 48, Ni 42, Se 12. It would seem that the resemblance to the Earth's mantle is not quite as striking as claimed by Delano and Ringwood.     

On the applicability of lunar breccias for paleomagnetic interpretations

Many of the breccias returned by the Apollo missions are capable of acquiring a substantial viscous remanent magnetization (VRM) which is of two forms. The first one has an upper limit to the relaxation times of about 100 to 1000min which corresponds to a grain diameter of about 145 Å. This suggests that the maximum relaxation time is determined by the transition from superparamagnetic to stable single domain particles. The second form of VRM follows the classical logt dependence typical for multidomain grains with a wide distribution of relaxation times. Hysteresis loop measurements yield the same kind of grain size distributions. In addition the analysis shows a fivefold enrichment of native iron in the breccias and soils as compared to the igneous rocks. In spite of a large VRM some breccias contain a stable remanent magnetization. Its intensity is typically 10^–6emu/gm, the same value found for igneous rocks. It is possible, therefore, to use some of the breccias to reconstruct the history of the lunar magnetic field.     

Some characteristic magnetic properties of lunar materials

One of the typical magnetic characteristics of lunar materials is the composition of their ferromagnetic constituent. Lunar breccias often contain kamacite (less than 7 weight per cent of Ni content) as well as almost pure metallic iron. Metallic ferromagnetics in most igneous rocks are almost pure iron, but the kamacite phase also has been found in some Apollo 15 igneous rocks. It seems likely therefore the metallic ferromagnetics in the lunar crust are more or less similar to those in chondrites.Another typical magnetic characteristic of lunar materials is the presence of a considerable amount of superparamagnetically fine particles of metallic iron. A higher relative content of such fine iron particles results in a higher value of the ratio of magnetic susceptibility (o) to saturation magnetization (I _s), a smaller ratio of the coercive force (H _c) to remanence coercive force (H _RC), and an extremely higher ratio of the viscous component (I _v) to the stable one (I _s) of the remanent magnetization.Communication presented at the Lunar Science Institute Conference on Geophysical and Geochemical Exploration of the Moon and Planets, January 10–12, 1973.     

Compositional evidence regarding the influx of interplanetary materials onto the lunar surface

Siderophilic element/Ir ratios are higher in mature lunar soils from highlands sites than in those from mare sites. We infer that the population of materials responsible for the early intense bombardment of the Moon had high ratios, and that the population responsible for the essentially constant flux has low ratios. No group of chondrites has siderophile/Ir ratios identical to those in the mare or highlands soils; CM chondrites are the most similar, and CM-like materials may account for a major fraction of Earth-crossing materials during the past 3.7 b.y.Siderophile/Ir ratios may be used to determine the amount of highlands regolith in soils or breccias from the mare-highlands interface areas (Apollo 15 and 17), and to infer the time of formation of highlands breccias whose sideropbiles originated in mature soils. Arguments are summarized against the viewpoint that the siderophiles in most highlands breccias originated in basin-forming projectiles. Differences in mature soil siderophile concentrations at Apollo 14 and 16 indicate a substantially greater concentration at the latter site immediately following the Imbrium event.Siderophile concentrations are used to estimate mean regolith depths at the landing sites; as relative values these are more precise than estimates based on seismic or crater observations. The longlived flux is calculated to be 2.9 g cm^–2 b.y.^–1 averaged over the past 3.7 b.y. A consideration of the relationship between mass fluence and time indicates that the mass flux decreased with a half-life of about 40 m.y. immediately following the Imbrium event.     

On the application of magnetic methods for the characterisation of space weathering products

Space weathering is now commonly accepted to modify the optical and magnetic properties of airless body regoliths throughout the Solar System. Although the precise formation processes are not well understood, the presence of ubiquitous sub-microscopic metallic iron (SMFe) grains in lunar soils and corresponding spectral analyses have explained both the unique optical and magnetic properties of such soils. More recently, a variety of ion irradiation, laser melting and vaporisation and impact experiments have been shown to reproduce these effects in the laboratory. Such experiments are crucial to the study of the formation of SMFe under controlled conditions. To date, more emphasis has been placed on optical analyses of laboratory samples, as these address directly the mineralogical interpretation of remote sensing data. However, the magnetic analyses performed on the Apollo and Luna samples have provided useful qualitative and quantitative evaluation of regolith metallic iron content. These techniques are reviewed here, demonstrated on pulsed laser irradiated olivine powder, and their utility for determining the quantity and size distribution of this metallic iron discussed. Ferromagnetic resonance, multi-frequency magnetic susceptibility, vibrating sample magnetometry and thermomagnetic measurements were carried out. Each showed trends expected for the conversion of paramagnetic Fe²⁺ in olivine to fine-grained Fe⁰, with some grains in the superparamagnetic size range. Although evidence for superparamagnetic iron was found, the quantity of sub-microscopic metallic iron produced in these experiments proved insufficient to make conclusive measurements of either the quantity or size distribution of this iron. Improvements to both the experimental and analytical procedures are discussed to better enable such measurements in the future.     

Reflectance Spectral Characteristics of Lunar Surface Materials

Based on a comprehensive analysis of the mineral composition of major lunar rocks (highland anorthosite, lunar mare basalt and KREEP rock), we investigate the reflectance spectral characteristics of the lunar rock-forming minerals, including feldspar, pyroxene and olivine. The affecting factors, the variation of the intensity of solar radiation with wavelength and the reflectance spectra of the lunar rocks are studied. We also calculate the reflectivity of lunar mare basalt and highland anorthosite at 300 nm, 415 nm, 750 nm, 900 nm, 950 nm and 1000 nm. It is considered that the difference in composition between lunar mare basalt and highland anorthosite is so large that separate analyses are needed in the study of the reflectivity of lunar surface materials in the two regions covered by mare basalt and highland anorthosite, and especially in the region with high Th contents, which may be the KREEP-distributed region.     

Ages of Globally Distributed Lunar Paleoregoliths and Soils from 3.9 Ga to the Present

This study determines the ages of 191 discrete lunar regolith samples from the Apollo, Luna, and meteorite collections. Model closure ages (for lithified breccias) and appearance ages (for unconsolidated soils) are calculated using the trapped ⁴⁰Ar and ³⁶Ar abundances of each sample, determined from published Ar data. Model closure ages of regolith breccias span ~3.9 to 0.01 Ga and appearance ages of soils range from ~3.6 to 0.03 Ga; 169 of these ages are published here for the first time, while 22 are recalculated ages. The regolith breccias with the oldest closure ages originate from the ancient highlands and oldest mare surfaces sampled by the Apollo missions. Soils generally have similar ages to each other, regardless of location and collection depth, with most model ages <2.0 Ga. Together, the soils and regolith breccias represent a record of regolith processes over the past 3.9 Ga. The data illustrate that individual landing sites can provide a diversity of ages, which has implications for planning future missions. Differences in maturity between older and younger regolith samples may reflect a change in collisional regimes over time. We note, too, that the closure ages published here are critical data needed for selecting temporally appropriate regolith samples used to decipher the diversity of impactors hitting the lunar surface over time and how the Sun has changed in time.     

Thermophysical properties of lunar material returned by Apollo missions

Data on thermophysical properties measured on lunar material returned by Apollo missions are reviewed. In particular, the effects of temperature and interstitial gaseous pressure on thermal conductivity and diffusivity have been studied. For crystalline rocks, breccias and fines, the thermal conductivity and diffusivity decrease as the interstitial gaseous pressure decreases from 1 atm to 10^–4T. Below 10^–4T, these properties become insensitive to the pressure. At a pressure of 10^–4T or below, the thermal conductivity of fines is more temperature dependent than that of crystalline rocks and breccias. The bulk density also affects the thermal conductivity of the fines. An empirical relationship between thermal conductivity, bulk density and temperature derived from the study of terrestrial material is shown to be consistent with the data on lunar samples. Measurement of specific heat shows that, regardless of the differences in mineral composition, crystalline rocks and fines have almost identical specific heat in the temperature range between 100 and 340K. The thermal parameter calculated from thermal conductivity, density and specific heat shows that the thermal properties estimated by earth-based observations are those characteristic only of lunar fines and not of crystalline rocks and breccias. The rate of radioactive heat generation calculated from the content of K, Th and U in lunar samples indicates that the surface layer of the lunar highland is more heat-producing than the lunar maria. This may suggest fundamental differences between the two regions.Now at Lamont-Doherty Geological Observatory, Columbia University, Palisades, New York, U.S.A.     

On the spectral reflectance and maturation darkening of lunar soils

Optical absorption and diffuse reflectance spectra were obtained for simulated lunar glasses of four different compositions, both in their as-quenched (reduced) states and following mild subsolidus oxidation. The transmission spectra, when normalized by the FeO content of the glasses, differed from one another only in the relative intensity of an unresolved band in the UV. For fixed melting conditions the strength of this band in the as-quenched glasses increased with increasing FeO, or with increasing TiO₂ for a fixed FeO content. Electron spin resonance (ESR) experiments have demonstrated the absence of Fe³⁺ or Ti³⁺ and the presence of metallic iron in these materials; all other transition-group elements were excluded in preparation. The unresolved UV absorption edge in the as-quenched reduced glasses is therefore tentatively ascribed to Fe²⁺Ti⁴⁺ intervalency charge transfer transitions. A similar UV edge was also produced by oxidation, leading to the conclusion that the assignment of this band would be ambiguous in the absence of an independent determination of the valence states of Fe and Ti. The relationship between the transmission spectra of polished samples and the reflectance spectra of sieved powders of the same materials is shown to be well described by the Kubelka-Munk approximation. Using this insight, it is possible to understand the spectral characteristics both of oxidation darkening of synthetic glass powders and of maturation darkening of lunar soils in terms of (1) the growth of the aforementioned charge transfer band(s) and (2) the development of opaque surface phases. It is shown that mechanism (1) is of primary importance in lunar highland materials and that mechanism (2) dominates in mare materials. The present results, coupled with previous findings, suggest that lunar soil maturation darkening may result from vitrification only if accompanied by (a) enrichment in the elements Fe and Ti, (b) changes in valence states of these elements, (c) partial crystallization of opaque phases such as iron, ilmenite or magnetite, or (d) a combination of (a), (b), and (c).     

Particle track measurements in lunar regolith breccias

Particle track measurements have been reported for 25 (5%) of the regolith breccias in the collection; they have been reported for 16 breccias (30%) in the reference suite. The most frequently reported measurement for these 25 breccias is the maximum surface exposure age of the compacted rock (48% of the published breccia measurements). Information on the nature of the precompaction regolith is given for 9 rocks (36%) and on the nature of the compaction event for 6 rocks (24%). Most of the breccias appear to have simple post-compaction surface exposure histories (89%). From the few track density frequency distributions (7) that are available and inferring from the low exposure ages of these rocks (75% < 10⁶ yr), it appears that most of these breccias are amenable to studies which separate the contemporary surface exposure age from information about the precompaction regolith. If the number of immature-submature precompaction soils (6 out of 10 of the breccias for which appropriate data are available) represents many regolith breccias, then we can infer that regolith breccias may sample the deeper, less reworked materials in the lunar soil and compliment the samples available from the returned cores.     

Petrography and geochemistry of lunar meteorites Dhofar 1673, 1983, and 1984

The Dhofar 1673, Dhofar 1983, and Dhofar 1984 meteorites are three lunar regolith breccias classified based on their petrography, mineralogy, oxygen isotopes, and bulk chemistry. All three meteorites are dominated by feldspathic lithic clasts; however, impact melt rock clasts and spherules are also found in each meteorite. The bulk chemistry of these samples is similar to other feldspathic highland meteorites with the Al₂O₃ content only slightly lower than average. Within the lithic clasts, the Mg # of mafic phases versus the anorthite content of feldspars is similar to other highland meteorites and is found to plot intermediate of the ferroan‐anorthositic suite and magnesian suite. The samples lack any KREEPy signature and have only minor indications of a mare basalt component, suggesting that the source region of all three meteorites would have been distal from the Procellarum KREEP Terrane and could have possibly been the Feldspathic Highland Terrane. All three meteorites were found within 500 m of each other in the Dhofar region of Oman. This, together with their similar petrography, stable isotope chemistry, and geochemistry indicates the possibility of a pairing.