Anatomy of individual agglutinates from a lunar highland soil

Abstract— We report results of our investigation of the relationship between values of I_s/FeO (relative concentration of nanophase Fe⁰ divided by total FeO content), glass abundance, total Fe content, and degree of digestion of <20 μm clasts for 22 individual agglutinates (250–1000 μm) from the mature Apollo 16 soil 61181 (I_s/FeO = 82 units in the <250 μm fraction). Agglutinates are important products of space weathering on the Moon, and they influence spectral observations at visible and near-IR wavelengths. Values of I_s/FeO for individual agglutinates (250–1000 μm) within this single soil span a range from 3 to 262 units which is larger than the range observed for all Apollo 16 bulk soils (～0 to 110 units). No correlation was observed between I_s/FeO and glass abundance and FeO concentrations for either agglutinitic glass or whole agglutinate particles under investigation. Our results suggest that the variation in I_s/FeO for agglutinates from a single soil may be in part a consequence of natural mixing processes on the Moon that produce highly-variable environments (with respect to surface exposure) for agglutinate formation and in part to variable kinetics of reactions in an agglutinate melt, which are influenced by a variety of factors including melt composition, temperature, impactor velocity, and quench rate. We cannot exclude but do not see evidence for other processes including addition of exotic agglutinates, micrometeoritic bombardment into compositionally-diverse microtargets, recycling of agglutinates, preferential melting of very fine soil particles, and production of nanophase Fe⁰ in amorphous rims of very fine irradiated lunar grains contributing to the observed variation of I_s/FeO.     

Some properties of dust outside the galactic disk

The joint use of accurate near- and mid-infrared photometry from the 2MASS and WISE catalogues has allowed the variations of the extinction law and the dust grain size distribution in high Galactic latitudes (|b| > 50°) at distances up to 3 kpc from the Galactic midplane to be analyzed. The modified method of extrapolation of the extinction law applied to clump giants has turned out to be efficient for separating the spatial variations of the sample composition, metallicity, reddening, and properties of the medium. The detected spatial variations of the coefficientsE(H ? W1)/E(H ? Ks), E(H ? W2)/E(H ? Ks), and E(H ? W3)/E(H ? Ks) are similar for all high latitudes and depend only on the distance from the Galactic midplane. The ratio of short-wavelength extinction to long-wavelength one everywhere outside the Galactic disk has been found to be smaller than that in the disk and, accordingly, the mean dust grain size is larger, while the grain size distribution in the range 0.5–11 µm is shifted toward coarse dust. Specifically, the mean grain size initially increases sharply with distance from the Galactic midplane, then decreases gradually, approaching a value typical of the disk at |Z| ≈ 2.4 kpc, and, further out, stabilizes or may increase again. The coefficients under consideration change with coordinate Z with a period of about 1312 ± 40 pc, coinciding every 656 ± 20 pc to the south and the north and showing a significant anticorrelation between their values in the southern and northern hemispheres at intermediate Z. Thus, there exists a unified large-scale periodic structure of the interstellar medium at high latitudes within at least 5 kpc. The same periodic variations have also been found for the extinction coefficient R _V within 600 pc of the Galactic midplane through the reduction of different photometric data for stars of different classes.     

Lyman-alpha observations of venera-9 and 10 I. The non-thermal hydrogen population in the exosphere of venus

The dayside hydrogen exosphere was observed in October–November 1975 with a Lymanalpha photometer carried on board Venera-9 and 10. In addition to intensity measurements, the use of a hydrogen cell allowed for the first time linewidth measurements. Both intensity and linewidth measurements below 1500 km of altitude are well fitted by a single exospheric component (T_c = 500 ± 100 K, n_c = 1.5 × 10⁴ atom cm^?3at 250 km). Above 3000 km, the measured linewidth increased sharply, to decrease again above 4500 km. This feature is interpreted as the signature of an additional population of “hot” atoms circulating on satellite orbits, created just behind the bow-shock by charge-exchange collisions (with an efficiency of 4%) between the neutral atoms and the solar wind protons, which became turbulent after bow-shock crossing. The density ratio of “hot” to standard population is of the order of 10% around 3500 km of altitude.     

Lunar surface agglutinates: Mapping composition anomalies

From the Clementine UVVIS imagery of the lunar surface, the abundance of agglutinates in the lunar regolith and their composition in terms of FeO and Al₂O₃ oxides have been predicted. Data on the spectral, chemical, and mineralogic measurements of about 30 lunar soil samples from the Lunar Samples Characterization Consortium (LSCC) collection were used. The fulfilled prognosis confirms that the mare agglutinates are enriched in Al₂O₃ and depleted of FeO, while the highland agglutinates are depleted of Al₂O₃ and enriched in FeO. This behavior can be caused by the global transport of the lunar surface material induced by cosmogenic factors.     

Physical parameters of the Orion Bar photodissociation region from radio recombination line observations at 8 mm

Observations of carbon (C), hydrogen and helium (H, He) radio recombination lines (RRLs) at four positions in the Orion Bar photodissociation region (PDR) and toward the center of Orion A have been performed with the RT-22 radio telescope (Pushchino) at 8 mm. The physical parameters of the PDR at these points have been estimated by comparing the carbon RRLs and infrared CII and OI lines. A hydrogen number density in the range 1.2–3.1 × 10⁵ cm^?3 and a mean size of the region along the line of sight (L) in the range 0.006–0.04 pc have been derived. The PDR temperature decreases with increasing distance from the exciting star (θ ¹ C Ori) from 210–230 to 140–150 K (a distance of ≈5′). The data obtained confirm the increase in the PDR size along the line of sight toward the Orion Bar, where, however, L has turned out to be less than the available values in the literature, which can be explained by the presence of clumps in the PDR. A density jump is evident in the Orion Bar region. The PDR zone encompasses the core of the HII region by a thin layer and extends farther, delineating the boundary and the ionization front of the core of the HII region in the Orion Bar and further out the boundary between the halo of the HII region and the molecular cloud. The derived emission measure (EM) toward the Orion Bar has been compared with other C RRL observations. The EM measured from carbon RRLs is EM ≈ 100(±50%) pc cm^?6, imposing constraints on the possible two-component PDR structure. Estimates show that the star θ ¹ C Ori is quite sufficient as a carbon ionization source in the Orion Bar PDR. Some of the data on the ionized hot gas (HII) in this direction have been obtained from H and He RRLs. In particular, the radial velocities (V _lsr) of the HII region are blueshifted with respect to V _lsr of the PDR by 10–17 km s^?1, while the relative ionized helium abundance decreases with increasing distance from the star, indicating that the helium ionization zone is smaller than the ionized hydrogen one.     

Structure of the bulge of the galaxy NGC 4258

The superfine structure of the bulge of the galaxy NGC 4258 has been investigated in H₂O maser emission at the epochs on February 4, 2013, and November 29, 2013. The peak intensities of the spectral components reached F ≈ 5 Jy. The emission of the component at v = 476 km s^-1 dominated at the beginning of this period; the second component at v = 487 km s^-1 was observed at the end of the period. The structure is a chain of compact components up to 200 µas or 7mpc in extent. The velocity of the local standard of rest is v _LSR = 482 km s^-1. Two bright compact components with a separation between them Δρ ≈ 35 µas or 1.3 mpc and a pair of components spaced 13 µas apart, whose brightness reaches 30% of the peak value corresponding to a brightness temperature T _b ≈ 1018 K, are located at the center. The sizes of the components are ~2–3 µas. A splitting and a shift of the two pairs of components relative to each other by 8 µas or 0.3 mpc in the 45° direction are observed at the end of the period. The velocity gradient of the structure is dV/dρ = 224 km s^-1 mas^-1, suggesting a solid-body rotation with a period T ≈ 760 years. The compact components correspond to the tangential directions of the arm. Two parallel chains of components corresponding to the tangential directions of the walls of the bipolar outflow carrying away an excess angular momentum are ejected from the central part of the bulge, two sources. The outflow is oriented at an angle X ≈ 15° relative to the disk axis. The brightness of the outflow fragments does not exceed 1.5% of the peak value. The ejection of material from the central part in the northward direction at a level up to 0.2%, T _b ≈ 10¹⁵ K, is observed at the epoch on February 4, 2013, at v = 478 km s^-1. The core structure suggests a double system: parallel disks–vortices spaced 0.25 mpc apart.     

A lunar soil evolution model

Comminution, agglutination, and replenishment processes in a lunar soil are modeled by a system of time dependent, linear differential equations. In the model a soil is subdivided into coarse particle, fine particle, and agglutinate fractions. The relative mass abundance of each component in a mature soil is found to be proportional to rates for the reworking processes. Evolution of the grain size distribution from a fresh ejecta blanket to a mature soil is described quantitatively in terms of the changing proportions of the three soil constituents. If size data is available for an immature soil and a mature soil of the same system, rates for the various processes can be calculated under certain simplifying assumptions.     

The detrital zone in the shorty crater cores

The lower part of lunar cores 74002/1 contains pure fine-grained black soil grading upward to orange soil. The section, however, between 10 cm and the lunar surface contains a mixture of orange and dark soil with a clast-in-matrix texture and some agglutinates. Therefore, this upper section is interpreted as a detrital zone. Although Shorty Crater was formed approximately 30 m.y. ago, all indicators of soil age give a much shorter time for residence of the detrital zone. Both absolute agglutinate content and authigenic agglutinate content indicate a surface residence of less than 8 m.y. for the detrital portion of the core. Most calculated ages of the detrital zone cluster are around 3 m.y. Grain size distribution is characteristic of an immature soil and there is little evidence, indicated by lack of upward fining and decrease in coarsest grain sizes, ofin situ maturation of the section. Mixing with adjacent soils is very low, even though such soils lie only 0.5 M from the sampling site. Four of the five sub-strata in the upper 10 cm could have been produced by the impact event that produced the 20 M wide boulder field near the sampling site on the Shorty Crater rim. This event would distribute perched clasts over the sampling site. Thickness of the detrital part of the section is in keeping with its being ejecta from the boulder bed crater. The thickness of the agglutinate-rich zone, 1.5 cm, is reasonable for a less-than 4 m.y. residence time.     

Spatial variations of the extinction law in the galactic disk from infrared observations

Infrared photometry in the J (1.2 µm), H (1.7 µm), Ks (2.2 µm) bands from the 2MASS catalogue and in the W1 (3.4 µm), W2 (4.6 µm), W3 (12 µm), W4 (22 µm) bands from the WISE catalogue is used to reveal the spatial variations of the interstellar extinction law in the infrared near the midplane of the Galaxy by the method of extrapolation of the extinction law applied to clump giants. The variations of the coefficients E(H ? W1)/E(H ? Ks), E(H ? W2)/E(H ? Ks), E(H ? W3)/E(H ? Ks), and E(H ? W4)/E(H ? Ks) along the line of sight in 2° × 2° squares of the sky centered at b = 0° and l = 20°, 30°, ..., 330°, 340° as well as in several 4° × 4° squares with |b| = 10° are considered. The results obtained here agree with those obtained by Zasowski et al. in 2009 using 2MASS and Spitzer-IRAC photometry for the same longitudes and similar photometric bands, confirming their main result: in the inner (relative to the Sun) Galactic disk, the fraction of fine dust increases with Galactocentric distance (or the mean dust grain size decreases). However, in the outer Galactic disk that was not considered by Zasowski et al., this trend is reversed: at the disk edge, the fraction of coarse dust is larger than that in the solar neighborhood. This general Galactic trend seems to be explained by the influence of the spiral pattern: its processes sort the dust by size and fragment it so that coarse and fine dust tend to accumulate, respectively, at the outer and inner (relative to the Galactic center) edges of the spiral arms. As a result, fine dust may exist only in the part of the Galactic disk far from both the Galactic center and the edge, while coarse dust dominates at the Galactic center, at the disk edge, and outside the disk.     

Altitude profile of H in the atmosphere of Venus from Lyman α observations of Venera 11 and Venera 12 and origin of the hot exospheric component

Two extreme ultraviolet (EUV) spectrophotometers flown in December 1978 on Venera 11 and Venera 12 measured the hydrogen Lyman α emission resonantly scattered in the atmosphere of Venus. Measurements were obtained across the dayside of the disk, and in the exosphere up to 50,000 km. They were analyzed with spherically symmetric models for which the radiative transfer equation was solved. The H content of the Venus atmosphere varies from optically thin to moderately thick regions. A shape fit at the bright limb allows one to determine the exospheric temperature T_c and the number density n_c independently of the calibration of the instrument or the exact value of the solar flux. The dayside exospheric temperature was measured for the first time in the polar regions, with T_c = 300 ± 25°K for Venera 11 (79°S) and T_c = 275 ± 25°K (59°S) for Venera 12. At the same place, the density is n_c = 4_?2⁺³ × 10⁴ atom.cm^?3, and the integrated number density N_t from 250 to 110 km (the level of CO₂ absorption) is 2.1 × 10¹² atom.cm^?2, a factor of 3 to 6 lower than that predicted in aeronomical models. This probably indicates that the models should be revised in the content of H-bearing molecules and should include the effect of dynamics. Across the disk the value of N_t decreases smoothly with a total variation of two from the morning side to the afternoon side. Alternately it could be a latitude effect, with less hydrogen in the polar regions. The nonthermal component if clearly seen up to 40,000 km of altitude. It is twice as abundant as at the time of Mariner 10 (solar minimum). Its radial distribution above 4000 km can be simulated by an exospheric distribution with T = 10³⁰K and n = 10³ atom.cm^?3 at the exobase level. However, there are less hot atoms between 2000 and 4000 km than predicted by an ionospheric source. A by-product of the analysis is a determination of a very high solar Lyman α flux of 7.6 × 10¹¹ photons (cm² sec Å)^?1 at line center (1 AU) in December 1978.     

Frost grain size metamorphism: Implications for remote sensing of planetary surfaces

An understanding of the rates of frost grain growth is essential to the goal of relating spectral data on surface mineralogy to the physical history of a planetary surface. Models of grain growth kinetics have been constructed for various frosts based on their individual thermodynamic properties and on the difference in binding energy between molecules on plane vs curved faces. A steady state situation can occur on planetary surfaces in which thermal elimination of small grains competes with their creation, usually by meteorite impact. We utilize predicted grain growth rates to explain telescopic spectral data on condensate surfaces throughout the solar system. On Pluto, predicted CH₄ ice grain growth rates are very high despite the low temperature, resulting in a multicentimeter optical path. This explains the strong CH₄ absorption band depths, which otherwise would require large amounts of CH₄ gas. On the Uranian and Saturnian satellites, extremely slow grain growth rates are predicted because of the low vapor pressure of H₂O at the existing average surface temperatures. This may explain evidence for fine grain size and peculiar microstructure. On Io, ordinary thermal exchange is more effective than sputtering in promoting grain growth because of the properties of SO₂. Over much of Io's disk, submicron size grains of SO₂ could plausibly reconfigure into a surface glaze on a timescale comparable to the resurfacing rate. This may explain the relatively strong SO₂ signature in Io's infrared absorption spectrum as opposed to its weaker manifestation in the visible spectrum. In spite of lower sputtering fluxes, sputtering plays a more important role in grain growth for Europa, Ganymede, and Callisto than on Io. This is a result of high rates of thermally activated grain growth and resurfacing on Io. The sequence of H₂O-ice absorption band depths (related to the mean grain size) is J₂(T) ～ J₃(T) > J₂(L) > J₃(L) ～ J₄(T) ～ J₄(L), where L = leading and T = trailing. This is to be expected if sputtering were dominant. The calculations show, however, that neither thermalized exchange fluxes nor sputtering exchange fluxes can produce the implied grain growth or the ordering by ice absorption band depths of the six satellite hemispheres. Only sputtering control by simple ejection of H₂O from the satellites, as the dominant cause of shorter mean lifetimes for smaller exposed grains, can satisfactorily explain the data. Some observations, which suggest that there are vertical grain size gradients, may result from a steady state balance between intense near surface production of fine frost by comminution, coupled with ongoing ubiquitous grain growth in the vertical column. In certain cases, e.g., Europa and Enceladus, the possibility exists that endogenic activity as well as comminution could affect grain size—at least locally. It is concluded that not only ice identification and mapping, but ice grain size mapping is an important experiment to be conducted on future missions.     

Populations of nanodiamond grains in meteorites from the data on isotopic composition and content of nitrogen

The present study has shown that the dependence of the isotopic composition of nitrogen on the N/C ratio, revealed from the data for bulk samples of meteoritic nanodiamond, can be obtained within the framework of the following model of the composition of populations of nanodiamond grains: (a) initial nanodiamond, i.e., the nanodiamond in the protoplanetary cloud before the accretion of the meteorite parent bodies, was composed mainly of grains of two populations (denoted as C_N and C_F), the ratio of which changed in meteorites depending on the degree of hydrothermal metamorphism; (b) only the grains of one of these populations (C_N) contain volume-bound nitrogen with δ¹⁵N = ?350‰; (c) the grains of both populations contain surface-bound nitrogen (δ¹⁵N ≡ 0). The calculations revealed the following properties of population grains in this model. (1) The grains of the C_N and C_F populations are most likely the same in isotopic composition of carbon and heterogeneous in distribution of its isotopes: the central part of grains is enriched with the δ¹²C isotope relative to the remainder of the grain. While the value of δ¹³C is ?37.3 ± 1.1‰ for carbon in the central part, it is ?32.8 ± 1.5‰ for the whole volume of the grains. (2) The noble gases of the HL component, specifically Xe-HL, are anomalous in isotopic composition and are most likely contained in the third population of nanodiamond grains (denoted as C_HL), the mass fraction of which is negligible relative to that for other grain populations. Only the grains of the C_HL population have an undoubtedly presolar origin, while the grains of the other nanodiamond populations could have formed at the early stages of the evolution of the protoplanetary cloud material before the accretion of the meteoritic parent bodies.     

A fit to the interstellar extinction curve without graphite

It is shown that interstellar extinction between 1 and 10 μm^?1 can be obtained from a grain mixture containing Fe₃O₄, SiO, MgO, and glassy carbon. MgO produces the 220 nm extinction bump and eliminates the need for graphite as a component of interstellar dust.     

Isotopically anomalous neon in meteoritic nanodiamonds: Formation during type II supernova explosions

We hypothesize the formation of neon associated with isotopically anomalous xenon (Xe-HL) in meteoritic nanodiamonds and designated as Ne-X through the mixing of the Ne-HL and Ne-S subcomponents. The Ne-HL subcomponent is neon from the helium (He/C) zone of a type II supernova or a mixture of neon from this zone and its hydrogen zone, while the Ne-S subcomponent is spallation neon formed during a supernova explosion in nuclear spallation reactions induced by high-energy protons. Based on this hypothesis and the presumed abundances of neon isotopes in the zones of a high-mass (25M _⊙) supernova after its explosion, we have calculated the abundances of neon components in nanodiamond separates and its grain-size fractions. Our calculations have shown the following. (1) The main source of Ne-HL is neon from the helium zone of the supernova; as a result, the ²⁰Ne/²²Ne and ²¹Ne/²²Ne ratios for Ne-X are 0.26 ± 0.03 and 0.19 ± 0.04, respectively. The isotopic composition of Ne-X is identical to that for Ne-A2 if Ne-HL is produced by the mixing of neon from the helium and hydrogen zones in proportion 1: 1.06. (2) In meteoritic nanodiamonds, the main neon abundance is determined by neon of the P3 component (Ne-P3). Ne-P3 is retained during thermal metamorphism, because it is sited in traps of the crystal lattice of diamond with a high energy of its activation. (3) The Ne-X/Ne-P3 ratio increases with nanodiamond grain size; as a result, there is no need to invoke an additional neon component (Ne-P6) to interpret the data on neon in meteoritic nanodiamonds.     

Infrared photometry for two RV Tau stars and V1027 Cyg

We present and discuss the results of our long-term JHKLM photometry for two RV Tau stars (R Sge and RV Tau) and the yellow supergiant V1027 Cyg, a candidate for protoplanetary nebulae. The amplitude of the infrared brightness variations in R Sge and RV Tau over fourteen years of observations was 0 _. ^m 9?1 ^m ; the infrared brightness variations in V1027 Cyg over eighteen years did not exceed 0 _. ^m 25. The infrared brightness and color of R Sge fluctuated about their gradually changing mean values; the infrared brightness variations agree with a period of 70.77 days. The periodic J brightness and J-H color variations in R Sge can be explained by temperature pulsations with ΔT ≤ 200 K and radial pulsations with [ΔR/R] ≤ 0.2. From 1995 to 2008, the mean J brightness of RV Tau increased, while its mean J-H color index decreased; the variations in the mean J brightness can be associated mainly with stellar temperature variations; a periodic component with P = 78.73 days is observed in the infrared brightness and color fluctuations. The variations in the mean J brightness and J-H color index of the supergiant V1027 Cyg over eighteen years of observations did not exceed a few hundredths of a magnitude; both temperature and radial pulsations may be present in the observed J brightness variations. The most probable period of the infrared brightness fluctuations in V1027 Cyg is 237 ± 2 days. The dust shell of R Sge may consist of two layers with grain temperatures of ～1000 and ～700 K; the optical depth at 1.25 µm is ～0.02 and ～0.24, respectively. The grain temperatures in the circumstellar dust shells of the supergiants RV Tau and V1027 Cyg are ～600 K (RV Tau) and ～700 K (V1027 Cyg). Their optical depths at 1.25 µm are ～0.24 (RV Tau) and ～0.008 (V1027 Cyg).     

Symbiotic halo star LT Del: Phase variations of the emission spectrum and parameters of the cool component

Long-term photometric and spectroscopic observations of the yellow symbiotic star LT Del are analyzed. UBV light curves are presented. Based on the observations of 20 cycles, we have refined the orbital period of the star, P = 476 _· ^d 0 ± 1 _· ^d 0. The brightness has been found to be unstable at some orbital phases with an amplitude up to 0 _· ^m 3. We have measured the fluxes in hydrogen and helium emission lines and in continuum and investigated their relationship to the orbital period. The fluxes in hydrogen and HeI lines follow the UBV light curves in phase; the He II 4686 Å flux does not depend on the phase and is constant within the accuracy of our measurements. The intensity ratio of the 4686 Å andHβ lines changes from 0.2 to 0.9 over the period. We interpret the spectroscopic observations based on the hypothesis of heating and ionization of the stellar wind from a cool component by high-frequency radiation from a hot star with a temperature of 105 K. We have estimated the spectral type of the cool star from our photometry and its continuum energy distribution as a bright K2–4 red giant branch halo star. The bolometric luminosity and mass loss rate have been estimated for the K component to be L _bol ～ 700L _⊙ and \(\dot{M}\) ～ 10^?8 M _⊙ yr^?1, respectively.     

Mariner 10 observations of hydrogen Lyman alpha emission from the venus exosphere: Evidence of complex structure

The Ultraviolet Spectrometer Experiment on the MARINER 10 spacecraft measured the hydrogen Lyman α emmission resonantly scattered in the Venus exosphere at several viewing aspects during the encounter period. Venus encounter occurred at 17:01 GMT on 5 February 1974. Exospheric emissions above the planet's limb were measured and were analyzed with a spherically symmetric, single scattering, two-temperature model. On the sunlit hemisphere the emission profile was represented by an exospheric hydrogen atmosphere with T_c = 275±50 K and n_c = 1.5 × 10⁵ cm^?3 and a non-thermal contribution represented by T_H = 1250±100 K with n_H = 500±100 cm^?3. The observations of the dark limb showed that the spherically symmetric model used for the sunlit hemisphere was inappropriate for the analysis of the antisolar hemisphere. The density of the non-thermal component had increased at low altitudes, < 12,000 km, and decreased at high altitudes, > 20,000 km, by comparison. We conclude that the non-thermal source is on the sunward side of the planet. Analysis of the dark limb crossing suggests that the exospheric temperature on the dark side is <125 K if the exospheric density remains constant over the planet; upper limits are discussed. An additional source of Lyman α emission, 70 ± 15 R, was detected on the dark side of the planet and is believed to be a planetary albedo in contrast to multiple scattering from the sunlit side. Our analysis of the MARINER 10 data is consistent when applied to the MARINER 5 data.     

Infrared variability of the nucleus of the Seyfert galaxy NGC 1068 in 1998–2004

Our 8-year-long JHKLM photometry of the Seyfert galaxy NGC 1068 has confirmed its IR variability. The amplitudes of the brightness variations in the J (1.25 μm) and K (2.2 μm) bands are within 0 _. ^m 15 and 0 _. ^m 3, respectively, and exceed the observational errors by more than a factor of 5. The nucleus of NGC 1068 is a variable source and can be at different phases of activity. The brightness of the galaxy in all bands except J decreased from 1998 until 2004. In this period, there was a tendency for the J brightness to increase. The variable source in NGC 1068 is a complex structured object. At least two sources radiate in the wavelength range 1.25–5 μm: a hot source whose radiation shows up in the range 1.25–1.65 μm and a cold source radiating at long wavelengths (2.2–5 μm). The color temperature of the hot source increased from 2300 K (the beginning of our observations) to ∼2700 K (the end of our observations). In contrast, the temperature of the cold source decreased by several tens of degrees (in the temperature range 800–900 K). The IR brightness and color variations observed in 1998–2004 are attributable to the dispersal of the dust envelope that formed around the galactic nucleus some 30 years ago and reached its maximum density in 1994–1995. Our analysis of the spectral energy distributions for the galaxy has shown that the observed radiation in the range 1.25–5 μm can be represented as the sum of radiations from two blackbody sources. For the first period of our observations (JD 2451400), the temperatures of the hot and cold sources are ∼3100 and 760 K, respectively. For the second period (JD 2453230), they are ∼3200 and 720 K, respectively. The hot source is relatively compact; it is smaller in size than the cold source by several tens of times. The mean sizes of the hot and cold sources are ∼2.35 × 10¹⁶ and ∼7.8 × 10¹⁷ cm, respectively. The total mean luminosity of the two sources did not change between the beginning and the end of our observations. The optical depth of the dust envelope averaged over the spectrum of the hot source is τ ∼ 1.5. In 2004, the state of the dust envelope almost returned to its 1974 level, i.e., the dust envelope formation and dispersal cycle was ∼11 000 days (∼30 yr). Original Russian Text ? O.G. Taranova, V.I. Shenavrin, 2006, published in Pis’ma v Astronomicheskiĭ Zhurnal, 2006, Vol. 32, No. 7, pp. 489–496.     

Physical adsorption of hydrogen on interstellar graphite grain surfaces

We review existingsingle-particle theories concerning parameters of importance which determine the kinetics of hydrogen molecule formation and ejection from cold (T _gr?20K) graphite grain surfaces. The nature of thesingle-particle quantum states of low mass gas atoms and molecules in a periodic surface lattice potential is considered. Contributions to the physical adsorption potential due to dynamic polarizability effects arising from thelong-range collective valence-electron charge-density oscillations (plasmons) of the substrate are discussed.Short-range electron correlation effects at the surface may lead to the formation of a ‘quasimolecular state’ of adsorbed H₂ with a bond length ～3.5 Å and a reduced bond energy ～0.075 eV. It is proposed, that one consequence of this dynamical screening of the adsorbed molecules is that they are ejected normal to the grain surface with velocities ?20 km s^?1 and not necessarily in a high vibrational state. Similar dynamical effects could be important in determining activation processes and long-range ordering in monolayer films of adsorbed H₂. The astrophysical consequences of thesemany-body effects are discussed in the light of recent experimental and observational results.     

Peculiarities in the formation of complex organic compounds in a nitrogen–methane atmosphere during hypervelocity impacts

Results of the experiments on model impact vaporization of peridotite, a mineral analogue of stony asteroids, in a nitrogen–methane atmosphere are presented. Nd-glass laser (γ = 1.06 µm) was used for simulation. Pulse energy was ~600–700 J, pulse duration ~10^–3 s, vaporization tempereature ~4000–5000 K. The gaseous medium (96% vol. of N₂ and 4% vol. of CH₄, P = 1 atm) was a possible analogue of early atmospheres of terrestrial planets and corresponded to the present-day atmosphere composition of Titan, a satellite of Saturn. By means of pyrolytic gas chromatography/mass spectrometry, it is shown that solid condensates obtained in laser experiments contain relatively complex lowand high-molecular weight (kerogen-like) organic compounds. The main products of condensate pyrolysis were benzene and alkyl benzenes (including long-chain ones), unbranched aliphatic hydrocarbons, and various nitrogen-containing compounds (aliphatic and aromatic nitriles and pyrrol). It is shown that the nitrogen–methane atmosphere favors the formation of complex organic compounds upon hypervelocity impacts with the participation of stony bodies even with a small methane content in it. In this process, falling bodies may not contain carbon, hydrogen, and other chemical elements necessary for the formation of the organic matter. In such conditions, a noticeable contribution to the impact-induced synthesis of complex organic substances is probably made by heterogeneous catalytic reactions, in particular, Fischer–Tropsch type reactions.