Holocene climate variability in the Southern Ocean recorded in a deep-sea sediment core off South Australia

To understand Holocene climatic development and to determine drivers of climatic changes and climate variability, high-resolution marine proxy records are required from key oceanic locations. However, information on the Holocene climate development from the Southern Hemisphere is still rare and mainly based on terrestrial archives. Here, we present data with a high-resolution of circa 35 years from sediment cores taken east of the Great Australian Bight, where it is possible to determine Southern Ocean Holocene climate and the longer-term trends of the El Niño–Southern Oscillation (ENSO) conditions. For this purpose, we used the oxygen-isotope records of two planktonic foraminifer species Globigerinoides ruber and Globigerina bulloides which inhabit different water masses as well as faunal counts of planktonic foraminifers. After the ocean frontal systems off southern Australia were pushed northward by orbitally-forced insolation changes during the early Holocene, the data indicate increasing ENSO variability during the mid to late Holocene when the fronts shifted polewards again. A strong circa 1550 year cycle is found in the Globigerina bulloides record which reflects the wider Southern Ocean signal with prominent cold phases centred at circa 9.2, 7.3, 5.8, 4.3, 2.7, 1.4 ka BP and, possibly the Little Ice Age, which have global counterparts.     

Late Quaternary sediment dating and quantification of lateral sediment redistribution applying230Thex: a study from the eastern Atlantic sector of the Southern Ocean

High-resolution records of the natural radionuclide²³⁰Th were measured in sediments from the eastern Atlantic sector of the Antarctic circumpolar current to obtain a detailed reconstruction of the sedimentation history of this key area for global climate change during the late Quaternary. High-resolution dating rests on the assumption that the²³⁰Th_ex flux to the sediments is constant. Short periods of drastically increased sediment accumulation rates (up to a factor of 8) were determined in the sediments of the Antarctic zone during the climate optima at the beginning of the Holocene and the isotope stage 5e. By comparing expected and measured accumulation rate of²³⁰Th_ex, lateral sediment redistribution was quantified and vertical particle rain rates originating from the surface water above were calculated. We show that lateral contributions locally were up to 6.5 times higher than the vertical particle rain rates. At other locations only 15% of the expected vertical particle rain rate were deposited.     

Research Progress of Long-term Ocean Temperature Changes in the Southern Ocean

In the recent decades， a large amount of anthropogenic heat has been absorbed and stored in the Southern Ocean. Results from observations and climate models' simulations both show that the Southern Ocean displays large warming in the upper and subsurface ocean that maximizes at 45°~40°S. However， the underlying mechanisms and evolution processes of the Southern Ocean temperature changes remain unclear， leaving the Southern Ocean to be a hotspot of climate change studies in the recent years. The present study summarized the current progress in the observations and numerical modeling of long-term temperature changes in the Southern Ocean. The effects of changes in wind， surface heat flux， sea-ice and other factors on the ocean temperature changes were presented， along with the introduction to the role of oceanic mean circulation and eddies. The present study further proposed that a deepening of the understanding in the Southern Ocean temperature change may be achieved by investigating the fast and slow responses of the Southern Ocean to external radiative forcing， which are respectively associated with the fast adjustments of the ocean mixed-layer and the slow evolution of the deep ocean. Specifically， the striking and fast mixed-layer ocean warming north of 50°S is tightly related to the surface heat absorption over upwelling regions and wind-driven meridional heat transport， resulting in enhanced warming around 45°S. While in the slow response of the Southern Ocean temperature， the enhanced ocean warming shifts southward and downward， mainly associating with the heat transfer from oceanic eddies. The Southern Ocean temperature has pronounced climatic effects on many aspects， such as global energy balance， sea-level rise， ocean stratification changes， regional surface warming and atmospheric circulation changes. However， large model biases/deficiencies in simulating the present-day climatology and essential ocean dynamic processes last in generations of climate models， which are the main challenge in advancing our understanding in the mechanisms for the Southern Ocean climate changes. Therefore， to achieve reliable future projections of the Southern Ocean climate， substantial efforts will be needed to improve the model performances and physical understanding in the relative role of various processes in ocean temperature changes at different time scales.     

Review on Researches of Aragonite Saturation State in the Southern Ocean:A Key Parameter of Southern Ocean Acidification

The Southern Ocean is a strong sink for atmospheric CO₂, making it especially vulnerable to ocean acidification (OA). The aragonite saturation state (Ω_arg) of seawater has been used as an index for the estimation of OA, which plays a critical role in evaluating the living environment of marine calcified organisms. However, it is very difficult to perform the studies of OA and Ω_arg in the Southern Ocean due to its harsh climate. Therefore, in order to better understand the OA and its further influences, the advances of Ω_arg studies were summarized in the oceans surrounding the Antarctica. Significant spatial and temporal variations of surface seawater Ω_arg are demonstrated in the Southern Ocean. In general, the surface seawater Ω_arg shows a lower value in the off-shore areas than in the open oceans. And, Ω_arg also exhibits a strong seasonal cycle with a higher value in summer than in winter. The distributions of Ω_arg in vertical water column generally present a declining tendency from surface to bottom. In addition, the shoaling of Ω_arg horizon at high latitude could be attributed to the ventilation and upwelling of deep waters in the Southern Ocean. There are many factors that could impact the Ω_arg in the Southern Ocean, including sea ice melting, sea-air CO₂ exchange, biological activities and hydrological processes, etc. Finally, the future changes and key scientific problems of OA in the Southern Ocean are proposed.     

Amino acids in a surface sediment core of the Atlantic abyssal plain

The amino acids in a 56 cm sphincter core (K-19-4-9, Woods Hole Oceanographie Institution) from 30°N latitude, 60°W longitude—approximately 300 miles southeast of Bermuda—at a water depth of 5454m were analyzed by gas and liquid chromatography. Amino acids decreased rapidly with depth with β-alanine and γ-aminobutyric acid predominating in deeper sections. Most of the amino acids are tightly bound in the sediment and are released only upon hydrolysis with 6N HC1. Amino acids accounted for only 0.40% of total nitrogen in the non-carbonate minerals in the top 0–8 cm and 7.9 × 10^?4 percent in the bottom 48–56 cm. The remaining nitrogen is removed from the sediment by amino acid extraction.     

Structural identification of the C25 highly branched isoprenoid pentaene in the marine diatom Rhizosolenia setigera

2,6,10,14-tetramethyl-7-(3-methylpent-4-enyl)-pentadeca-2,5E,9E,13-tetraene I possessing a C₂₅ highly branched isoprenoid skeleton has been isolated from the marine diatom Rhizosolenia setigera and identified by ¹H and ¹³C NMR spectroscopy.     

Iron in a post-glacial lake sediment core; a Mössbauer effect study

The distribution of iron in a 6-m core of post-glacial sediment from an oligotrophic lake (Connistonwater, England) was determined, principally by Mossbauer spectroscopy on dried samples. The immediate post-glacial deposits contain 4.8 wt. % of iron, with a Fe²⁺; Fe³⁺ ratio ～- 4. The iron there is predominantly in the form of chlorite, but there are small amounts in hematite and illite. The distribution of iron is different, and very variable in the recent sediments (~ < 13,000 BP), which contain 25–35 per cent organic matter and 5.2 wt. % of iron relative to the inorganic fraction. Typically half the iron is present there as chlorite, and the rest is ferric, mostly in the form of an amorphous gel which is also present in undried samples. To explain the observed ferrous:ferric profile, it is proposed that the latter includes iron which was once mobile, having been leached from the Fe²⁺-bearing clays under reducing conditions in the soils of the drainage basin, or in the sediment itself. It was subsequently precipitated as ferric hydroxide on contact with the oxic lake water. In contrast, the ferrous iron in the sediments is immobile iron, which remained locked in the chlorite phase of the clay particles as they were carried from soil to sediment intact.All the sediments are rather inhomogeneous. Chlorite, and especially hematite, are mechanically concentrated in pink varves in the immediate post-glacial deposits. In the partly inorganic sediments, the concentration of ferrous iron (chlorite) is approximately uniform, but the ferric content may differ by a factor of five between regions only a few millimeters apart.     

Vertical profile of polycyclic aromatic hydrocarbons in a sediment core from a reservoir in Osaka City

Concentrations of polycyclic aromatic hydrocarbons (PAHs) were measured in a dated sediment core from a reservoir at Osaka City, Southwest Japan. The sediment core consisted of deposits collected over a period of almost 70 years whose PAH content would serve as a historical record of atmospheric environment at Osaka City. Total PAH concentrations varied from 4.2 to 26 mg kg⁻¹ dry wt, and peaked in the 1940s, reflecting the occurrence of a large fire due to air attacks during World War II. The results indicated that warfare had the largest impact on atmospheric environment in Osaka City. Total PAH concentrations decreased in the post-war period except for a small peak. In the 1950s, there was a downward trend from the 1970s to the present. These trends can be ascribed to the growth of industrial activities and the regulation of atmospheric pollutant emissions, respectively.     

Cenozoic glaciation of Antarctica and sedimentation in the Southern Ocean

Literature pertaining to history of the Cenozoic glaciation in Antarctica and its influence on sedimentation in marginal areas of the continent and deep-water domains of the Southern Ocean are reviewed. Original data obtained by G.L. Leichenkov on seismostratigraphy of the East Antarctica margin are also used. Particular attention is paid to the history of silica accumulation, ice-rafted material deposition, and formation of contourites. The results make it possible to define the following main stages of Antarctic glaciation in the Cenozoic: (1) middle-late Eocene; (2) Oligocene; (3) early Miocene; (4) middle Miocene; (5) late Miocene-early Pliocene; and (6) late Pliocene-Holocene.     

Surface metal enrichment and partitioning of metals in a dated sediment core from a Norwegian fjord

A 24-cm long sediment core from an oxic fjord basin in Ranafjord, Northern Norway, was sliced in 2 cm sections and analysed for As, Co, Cu, Ni, Hg, Pb, Zn, Mn, Fe, ignition loss and Pb-210. Partitioning of metals between silicate, non-silicate and non-detrital phases was assessed by leaching experiments, in an attempt to understand the mechanisms of surface metal enrichment in sediments. Relative to metal concentrations in sediments deposited in the 19th century, metals in near surface sediments were enriched in the following order: Pb > Mn > Hg > Zn > Cu > As > Fe. Cobalt and Ni showed no enrichment. The non-detrital fraction of Cu, Pb, Mn and Zn was significantly higher in the upper 10 cm than at greater depth in the core. This corresponds to sediments deposited since 1900, when mining activities started in the area. The enrichment of Cu, Pb and Zn is assumed to be mainly a result of mining, while Mn is apparently enriched in the surface due to migration of dissolved Mn and precipitation in the oxic surface layer. Elevated concentrations of As and Fe in the upper 4 cm are presumably due to discharges from a coke plant and an iron works respectively. The excess Hg present in the near surface sediments is tightly bound, either in coal particles or ore dust introduced by local industry, or via long distance transport of atmospheric particles. Calculations of metal flux to the sediments indicate an anthropogenic flux of Zn equal to its natural flux, while the flux of Pb shows a threefold increase above natural input.     

Widespread distribution and molecular diversity of diatom frustule bound aliphatic long chain polyamines (LCPAs) in marine sediments

The siliceous skeletal remains of diatoms are a primary component of sediments, covering vast areas of the sea floor. We used high performance liquid chromatography–electrospray ionization–tandem mass spectrometry (HPLC–ESI–MSⁿ) under high resolution time-of-flight MS (TOF-MS) conditions, as well as nuclear magnetic resonance spectroscopy (NMR) and Fourier transform infrared spectroscopy (FTIR), to investigate the distribution and molecular diversity of long chain polyamines (LCPAs) entrapped in sedimentary diatom biosilica in sediments from the Indian sector of the Southern Ocean, the Bering Sea and the Northeast Pacific. This revealed the existence of complex polyamine populations with both known and unknown structural features, including the presence of ketone and carboxylic acid groups in the LCPA backbone, functional groups that likely modulate the silica precipitating properties of LCPAs in the environment and which may constitute points of initial silica deposition (Wallace, A.F., De Yoreso, J.J., Dove, P.M., 2009. Kinetics of silica nucleation on carboxy- and amine-terminated surfaces: insights for biomineralization. Journal of the American Chemical Society 131, 5244–5250). Although various LCPA species overlapped between samples (putrescine-based LCPAs with various degrees of methylation and N-methyl propylamine repeat units were ubiquitous in all samples), clear regional differences were shown in composition and structural characteristics, likely reflecting the various diatom species contributing to the total LCPA pool for each sedimentary environment. We further show, using scanning electron microscopy and energy dispersive X-ray analysis (SEM–EDX) that LCPAs purified from diatom skeletal remains rapidly re-direct the formation of silica nanospheres in vitro, and become embedded in the precipitated silicified matrix, forming an LCPA–silica composite material. The results show that aliphatic polyamines produced by diatoms for morphogenesis of their cell walls are widespread in sediments where the fossil frustules are preserved. These newly assigned components constitute useful biological markers of diatom input to sediments.     

Environmental risks associated with aeration of a freshwater sediment exposed to mine drainage water

The study examined freshwater sediments from a pond receiving waters from an open-pit lignite quarry located in Europe's Black Triangle in the northern part of the Czech Republic. Sediments were studied with respect to chemical changes upon aeration to assess the risks associated with their acidification and release of toxic metals. Three types of sediments were sampled: orange precipitates of ferric oxides, underlying black anoxic material and brown clayey material from the original bottom of the pond. The experiment revealed that only black anoxic sediment presents environmental concerns upon aeration. Its redox potential rose steeply from -124 up to +412 mV within the first 50 h of aeration, afterwards, it increased only slowly and reached a finale value of +663 mV after 362 h of aeration. The redox changes were accompanied by sulphate production. Up to 97,037.8 mg of sulphate was released into the solution from 1 kg of the sediment. Consequently, the pH values dropped from 6.7 down to 3.3 within the first 50 h of aeration and reached a value of 2.7 at the end of the experiment. The decrease of pH values was followed by increased zinc and manganese mobility. Iron solubilisation was not continuous. An initial drop in iron mobility was followed by an increase, after which the mobility decreased again. This fluctuation reflected the changes in iron solubility depending on the oxidation state and pH changes in the sediment suspension.     

晚更新世以来内蒙古哈素海钻孔地层记录及其年龄

“河套古大湖”对于研究区域环境及气候演化具有重要的意义,然而,其形成与消亡的时代仍存在争议。依托于哈素海西南岸边获取的HSH钻孔,采用AMS14C、OSL测年方法确定了沉积物年代,结合岩心的岩性、沉积结构等特征,分析了哈素海的演化历史,并探讨了河套古大湖存亡的时期。结果表明,哈素海地区晚更新世以来的沉积环境主要经历了以下转变过程：150~70 ka为较稳定的湖泊,70~55 ka湖泊水位下降,为滨湖相沉积,55~27 ka为湖沼沉积,27~0 ka为滨湖相沉积。根据哈素海的沉积演化历史,结合河套盆地相关研究成果,认为河套古大湖早在150~110 ka就已形成,其后水位下降,直至55 ka之后,萎缩消亡,河套盆地局部地区形成湖沼沉积,但已不再是统一的大湖。研究结果对于深入探讨河套盆地演化历史乃至黄河的变迁具有重要意义。     

Distribution and enrichment of heavy metals in a sediment core from the Pearl River Estuary

A sediment core collected from coastal zone near the Qiao Island in the Pearl River Estuary was analyzed for total metal concentrations, chemical partitioning, and physico-chemical properties. Three vertical distribution patterns of the heavy metals in the sediment core were identified, respectively. The dominant binding phases for Cu, Pb, Cr, and Zn were the residual and Fe/Mn oxides fractions. Cd in all sediments was mainly associated with exchangeable fraction. Influences of total organic carbon content and cation exchange capacity on the total concentrations and fractions of almost all the metals were not evident, whereas sand content might play an important role in the distributions of residual phases of Cr, Cu, Pb, and Zn. In addition, sediment pH had also an important influence on the Fe/Mn oxides, organic/sulfide and residual fractions of Cr, Cu, and Zn. Contamination assessment on the heavy metals in the sediment core adopting Index of Geoaccumulation showed that Cr, V, Be, Se, Sn, and Tl were unpolluted, while Cu, Ni, Pb, Zn, Cd, and Co were polluted in different degrees throughout the core. It was remarkable that the various pollution levels of the metals from moderate (for Cu, Pb, and Zn) to strong (for Cd) were observed in the top 45 cm of the profiles. The relative decrease of the residual fraction in the upper 45 cm of the core is striking, especially for Zn and Cu, and, also for Pb, and Cr. The change in fraction distribution in the upper 45 cm, which is very much contrasting to the one at larger depths, confirms that the residual fraction is related to the natural origin of these metals, whereas in the upper part, the non-residual fractions (mainly the Fe/Mn oxides fraction) are increased due to pollution in the last decade. The possible sources for Cu, Pb, Zn, and Cd contaminations were attributed to the increasing municipal and industrial wastewater discharges, agricultural runoff, atmospheric inputs, and runoff from upstream mining or smelting activities, which may be associated with an accelerating growth of economy in the Pearl River Delta region in the past decade.     

Fractionation of Th, Pa, and Be induced by particle size and composition within an opal-rich sediment of the Atlantic Southern Ocean

This study centers on the question: How sensitive are ²³¹Pa/²³⁰Th and ¹⁰Be/²³⁰Th to sediment composition and redistribution? The natural radionuclides ²³¹Pa, ²³⁰Th and ¹⁰Be recorded in deep sea sediments are tracers for water mass advection and particle fluxes. We investigate the influence of oceanic particle composition on the element adsorption in order to improve our understanding of sedimentary isotope records. We present new data on particle size specific ²³¹Pa and ¹⁰Be concentrations. An additional separation step, based on settling velocities, led to the isolation of a very opal-rich phase. We find that opal-rich particles contain the highest ²³¹Pa and ¹⁰Be concentrations, and higher ²³¹Pa/²³⁰Th and ¹⁰Be/²³⁰Th isotope ratios than opal-poor particles. The fractionation relative to ²³⁰Th induced by the adsorption to opal-rich particles is more pronounced for ²³¹Pa than for ¹⁰Be. We conclude that bulk ²³¹Pa/²³⁰Th in Southern Ocean sediments is most suitable as a proxy for past opal fluxes. The comparison between two neighboring cores with rapid and slow accumulation rates reveals that these isotope ratios are not influenced significantly by the intensity of sediment focusing at these two study sites. However, a simulation shows that particle sorting by selective removal of sediment (winnowing) could change the isotope ratios. Consequently, ²³¹Pa/²³⁰Th should not be used as paleocirculation proxy in cases where a strong loss of opal-rich material due to bottom currents occurred.     

Impact of lateral transport on organic proxies in the Southern Ocean

Lateral transport of fine-grained organic carbon particles can complicate the interpretation of paleoclimate records based on organic proxies. Here we investigated the effect of lateral transport on newly developed temperature and soil organic matter proxies, TEX₈₆ and BIT index, respectively, in core MD88-769 recovered from the South East Indian Ridge. Our results show that TEX₈₆ and BIT records in comparison to diatom and foraminifera records were representative for more local climate changes while alkenones and n-alkanes originated from distant areas by oceanic and atmospheric transport, respectively. This suggests that TEX₈₆ and BIT paleoclimate records are primarily influenced by local conditions and less subjected to long-distance lateral transport than other organic proxies in the Southern Ocean.     

Production and pelagic dissolution of biogenic silica in the Southern Ocean

Vertical distributions of particulate silica, and of production and dissolution rates of biogenic silica, were determined on two N-S transects across the Pacific sector of the Antarctic Circumpolar Current during the austral spring of 1978. Particulate silica profiles showed elevated levels in surface water and near the bottom, with low (35–110 nmol Si · 1^?1) and vertically uniform values through the intervening water column. Both the particulate silica content of the upper 200 m and the production rate of biogenic silica in the photic zone increased from north to south, reaching their highest values near the edge of the receding pack ice. A significant, but variable, fraction (18–58%) of the biogenic silica produced in the surface layer was redissolving in the upper 90–98 m. Net production of biogenic silica in the surface layer (production minus dissolution) was proceeding at a mean rate of ca. 2 mmol Si · m^?2 · day^?1. This is ca. 4 times greater than the most recent estimate of the mean accumulation rate of siliceous sediments beneath the ACC. We estimate, based on mass balance, that the mean dissolution rate of biogenic silica in subsurface water column in the Southern Ocean is 1.2–2.9 mmol Si · m^?2 · day^?1.     

Structural control of El Sela granites and associated uranium deposits, Southern Eastern Desert, Egypt

The El Sela area is a part of the basement complex of the Eastern Desert of Egypt and the Pan-African Shield. The area comprises outcrops of dismembered ophiolites thrust over arc volcano-sedimentary sequence and intruded by different syn- to post-tectonic granitoids. Structural analysis of the area enabled the separation and definition of four structural episodes: (E1) folding–thrusting episode associated with the cratonization of the arc/inter-arc rock association and the intrusion of the syntectonic (Older) granites. (E2) Upright folding episode associated with the compression and shortening to the ENE–WSW direction which is different from the NNW–SSE shortening direction during E1; at the end of E2, late tectonic granites were intruded. (E3) Post-tectonic granitic intrusion episode: two mica granite and granitic dikes were intruded during this episode. (E4) Fracturing, faulting, and post-granitic dike extrusion episodes caused different faults that took place after cratonization until the present. There are three generations of folds during ductile deformation (E1 and E2). The F2 folds are nearly coaxial (along ENE–WSW trend) with the F1 folds. The F3 folding is displayed by folds generally trending NNW–SSE. Therefore, the ENE–WSW and NNW–SSE trends can considered as preexisting discontinuities and mechanical anisotropy of the crust in the following structure episodes. Brittle deformation (E3 and E4) reveals the importance of those trends which control the multi-injections and many alteration features in the study area. During reactivation, a simple shear parallel to the inherited ductile fabrics was responsible for the development of mineralized structures along the ENE–WSW and NNW–SSE trends. So they can be considered as paleochannel trends for deep-seated structures and can act as a good trap for uranium and/or other mineral resources. Most of the uranium anomalies are delineated along ENE–WSW and NNW–SSE shear zones where quartz-bearing veins bounded the lamprophyre dike and microgranites and dissected them in relation to the successive fracturation and brecciation corresponding to the repeated rejuvenation of the structures. Therefore, the structural controls of the uranium mineralizations in the El Sela area appear to be related to the interaction between inherited ductile fabrics and overprinting brittle structures.     

Use of biomarkers indices in a sediment core to evaluate potential pollution sources in a subtropical reservoir in Brazil

The presence of PAHs, n-alkanes, pristane, and phytanes in core sediment from the Vossoroca reservoir (Parana, southern Brazil) was investigated. The total concentration of the 16 PAHs varied from 15.5 to 1646 μg kg⁻¹. Naphthalene was present in all layers (3.34–74.0 μg kg⁻¹). The most abundant and dominant n-alkanes were n-C₁₅ and n-C₃₆, with average concentrations of 198.1 ± 46.8 and 522.9 ± 167.7 μg kg⁻¹, respectively. Lighter n-alkanes were distributed more evenly through the layers and showed less variation, specially n-C₉, n-C₁₂, and n-C₁₈, with average concentrations of 14.6 ± 3.0, 31.6 ± 1.9, and 95.0 ± 5.2 μg kg⁻¹, respectively; heavier n-alkanes were more unevenly distributed.