Anthropogenic influences on hydrocarbon contents of sediments deposited in eastern Lake Ontario since 1800

 The amounts and types of extractable hydrocarbon components in sediment cores from the Rochester Basin of eastern Lake Ontario provide a record of environmental changes that have accompanied the settlement and population growth of the surrounding land areas. Sediments deposited prior to the mid-1800s contain low concentrations of hydrocarbons that are dominated by land-plant wax components. Concentrations begin to rise in the late 1800s as erosion of soil and nutrients from watershed areas accelerated. This pattern continues into modern times. Episodes of enhanced aquatic productivity are sometimes recorded in twentieth-century sediments by the dominance of algal hydrocarbons, but land-plant components typically predominate. Petroleum residues begin to appear in sediments deposited in the late 1800's but remain minor constituents of the hydrocarbon contents of modern sediments in the Rochester Basin. Received: 21 March 1995 · Accepted: 11 August 1995     

Environmental changes in Saginaw Bay,Lake Huron recorded by geolipid contents of sediments deposited since 1800

Changes in organic materials preserved within sediments of Saginaw Bay deposited over the past two centuries record corresponding periods in the environmental history of this part of Lake Huron and its watershed. Sediments deposited since 1940 show an increasingly greater input of aquatic organic matter in response to accelerating cultural eutrophication of Saginaw Bay. Concentrations of fatty acids, sterols, fatty alcohols, and aliphatic hydrocarbons are higher in these modern sediments than in deeper ones. Molecular distributions of these geolipids reflect less aquatic material deeper in the sediments. Prior to 1875, sediment organic matter appears to be diluted by mineral matter from enhanced erosion caused by clearing of the watershed for farming and settlement. During this period there is better preservation of carbonate minerals due to quicker burial. Since 1875, petroleum components comprise over 90% of the total aliphatic hydrocarbon content of these sediments, reflecting the advent and continued existence of chronic, low-level petroleum contamination of this part of the Great Lakes.     

赣北元古代变质沉积岩的铅钕同位素特征

赣北地区元古代变质沉积岩的铅、钕同位素研究结果表明,它们与扬子古陆南缘其他元古代地层非常相似,表明它们具有相似的成岩物质来源及构造演化历史。研究结果还显示,双桥山群变质泥质岩的PbPb等时线年龄为（1490±68）Ma,而障公山群、双桥山群、程浪群和修水群的钕模式年龄分别为1.57Ga、1.89Ga、1.77Ga和1.60Ga,均分布在1.5～1.9Ga之间,表明这些地层的形成年龄应小于1.9Ga,是中—晚元古代的产物,同时表明扬子古陆南缘存在古元古代的基底。     

The Correlation of Inorganic C,O Isotopic Values for Lake Chenghai Sediments and Its Environmental Implications

As one of the lakes on the Yunnan-Guizhou plateau, Lake Chenghai, which is a typical closed lake with the precipitation accounting for one-third or more of the annual water input, has a high total salinity (almost like a saline lake). The inorganic C, O isotopic composition of lake sediments bears much sensitive information about environmental change in the catchment, while their correlations revealed the hydrological conditions under which the lake was closed. Their compositional variations are controlled by temperature, precipitation, photosynthesis, dissolving equilibrium of the carbonate system and hydrological condition. According to our research on inorganic C, O isotopic composition of Lake Chenghai sediments, we investigated the environmental change of this catchment several decades ago. The results showed that Lake Chenghai has kept good hydrological closing conditions in the past several decades, as indicated by the good correlation of inorganic C, O isotopic composition of sediments; and that the environmental change in this catchment shows a tendency of periodical evolution on a 10⁻¹¹-years scale, although the signal noise is relatively high at the bottom of the sediment core. And we also can extend C, O isotopes, a sensitive environmental indicator, to nearly saline lake environments with a high degree of mineralization.     

The stability of the relative content ratios of Cu,Pb and Zn in soils and sediments

The study indicates that the relative content ratios of Cu, Pb and Zn in soils and sediments tend to have stability compared to those in meteorites, rocks and organisms. This stability is considered to be associated with their geochemical properties and has no relationship to the existing environments if it is not disturbed by an anthropogenic factor. In addition, it can serve as a background reference in determining the changes in environmental quality due to human activities.     

Stratigraphy,paleontology, and age of Lake Algonquin sediments in southwestern Ontario,Canada

Molluscs, ostracodes, diatoms, pollen, plant macrofossils, peat, and wood have been found in glacial Lake Algonquin sediments, and estuarine-alluvial sediments of the same age, in southern Ontario. Molluscs and ostracodes are particularly abundant and widespread. Pollen analysis of Lake Algonquin sediments, bogs on the Algonquin terrace, and upland bogs above the Algonquin terrace, indicate that Lake Algonquin was still in existence at the time of the spruce-pine pollen transition, previously dated at an average of 10,600 yr BP at a number of sites in Michigan, Ohio, and southern Ontario. Wood in estuarine-alluvial sediments graded to the Algonquin level is of similar radiocarbon age. Evidence from several sites in the eastern Great Lakes area suggests the presence of a preceding low-water stage (Kirkfield outlet stage); drowned and alluviated valleys and fining-upward sediment sequences have been identified in this study as further supporting evidence. Lake Algonquin drained from the southern sites by isostatic tilting and eventual opening of the “North Bay outlet” some time shortly after 10,400 yr BP.Our radiocarbon dates suggest the low-water stage has an age of about 11,000 yr BP, and that Lake Algonquin drained 10,000–15,000 y. a. Dates previously published for the Lake Michigan basin are generally too young in comparison with ours, and dates on the Champlain Sea are generally too old. More critical evaluation of all dating results is desirable.From fossil remains we suggest a rapidly expanding fauna in the waters of Lake Algonquin. The spruce pollen period was a time of rapid faunal and floral migration, when the ice front was retreating from Kirkfield to North Bay, Ontario. Diversity of some species and fossil numbers increased substantially at the transition from spruce to pine just before Lake Algonquin drained.     

The drainage of Lake Ojibway in glaciolacustrine sediments of northern Ontario and Quebec,Canada

Physical evidence for the drainage of glacial lakes remains relatively rare in depositional records, giving rise to much debate on the location of outlets and discharge pathways, as well as on the climate impact of the attendant meltwater forcing. Lake Ojibway developed following the withdrawal of the Laurentide Ice Sheet in northern Ontario and Quebec, Canada. The late‐stage evolution of this large ice‐dammed lake was influenced by the complex dynamics of the retreating ice margin, which highly complicates the identification of the termination of Lake Ojibway in glaciolacustrine sediment records. Here, we document the composition of sections of rhythmites that contain in their upper part an anomalously thick and whitish bed (10–15 cm) that is in turn overlain by ～1 m of faintly bedded rhythmites. Grain‐size analyses showed that the thick whitish bed consists primarily of fine to coarse silt (2–63 μm), contrasting with the lower and upper rhythmites that are largely dominated by clay (<2 μm). The detrital carbonate content of the thick silt bed is characterized by consistently high values (2.5 to 2.8%), whereas the bounding rhythmites show lower and highly variable values. Oxygen isotope measurements further show a marked change going from typical glacial meltwater values (～ ?29.6 to ?27.7‰; VSMOW) for the lower rhythmites and the silt bed to modern‐like meteoric values (?18.4 to ?14.6‰) for the uppermost rhythmites. These data suggest that this marker bed may be associated with a major drawdown event that possibly corresponds to the final drainage of Lake Ojibway. AMS radiocarbon dating of ostracods extracted from the drainage bed also documents an important hardwater effect within the Ojibway basin.     

Natural and anthropogenic budgets of a small watershed in the massif central (France): Chemical and strontium isotopic characterization of water and sediments

A small watershed (160 km²) located in the Massif Central (France) has been chemically, isotopically and hydrologically studied through its dissolved load, bed sediments and soils. This watershed is underlain by basaltic bedrock and associated soils in which the vegetation is dominated mainly by meadows.Dissolved concentrations of major ions (Cl, SO₄, NO₃, HCO₃, Ca, Na, Mg, K, Al and Si), trace elements (Rb and Sr) and strontium isotopes have been determined for two different hydrologic periods on the main stream of the Allanche river and its tributaries.The major objectives of this study were to characterize the chemical and isotopic signatures of each reservoir occurring in the watershed. Changes in chemical and isotopic signatures are interpreted in terms of fluctuations of the different components inputs: rainwater, weathering products, anthropogenic addition.Water quality may be influenced by natural inputs (rainwater, weathering processes) and anthropogenic additions (fertilizers, road salts, etc.). Precipitation serves as a major vehicle for dissolved chemical species in addition to the hydrosystem and, in order to constrain rain inputs, a systematic study of rainwaters is carried out over a one year period using an automatic collector. Corrections of rainwater addition using chloride as an atmospheric input reference were computed for selected elements and the Sr/Sr ratio. After such corrections, the geochemical budget of the watershed was determined and the role of anthropogenic additions evaluated through the relationship between strontium isotopes and major and trace element ratios. Thus, 10% of Ca and Na originate in rainwater input, 40 to 80% in fertilizer additions and 15 to 50% in rock weatheringThe cationic denudation rates for this watershed are around 0.3 g s^–1 km² during low water discharge and 0.6 g s^–1 km² in high water stage. This led to a chemical denudation rate of 5.3 mm/1000 years.For solid matter, the normalization of chemical species relative to parent rocks shows the depletion or enrichment in soils and sediments. The use of K and Ca as mobile reference illustrates the weathering state of soils and sediments relative to parent rocks. This weathering state for bed sediments range from 15 to 45% for the K normalization and from 2 to 50% for the Ca normalization. For the soils, the weathering state ranges from 15 to 57% for the K normalization and from 17 to 90% for the Ca normalization.     

东秦岭北部富碱侵入岩钕、锶、铅同位素特征及构造意义

东秦岭北部富碱侵入岩主要分布在陕西省洛南与河南省卢氏－确山一带,岩石有碱性岩、碱性花岗岩和石英正长岩三大类。岩石Ｎｄ、Ｓｒ和Ｐｂ同位素地球化学的研究表明,该区富碱侵入体的源区应是以下地壳为主,并通过碰撞造山作用带入少量地幔和上地壳物质。源区同位素组成横向与垂向的不均一性说明华北块体存在成熟的下地壳层,而北秦岭块体是造山带环境。古大陆边缘经历了多次裂解作用和多期碱性岩浆活动;碱性岩浆是在减压扩容环境     

Geochemical and isotopic evolution of groundwater in the Wadi Watir watershed,Sinai Peninsula,Egypt

The Wadi Watir delta in the Wadi Watir watershed is a tourist area in the arid southeastern part of the Sinai Peninsula, Egypt, where development and growth of the community on the delta are constrained by the amount of groundwater that can be withdrawn sustainably. To effectively manage groundwater resources in the Wadi Watir delta, the origin of groundwater recharge, groundwater age, and changes in groundwater chemistry in the watershed needs to be understood. Mineral identification, rock chemistry, water chemistry, and the isotopes of hydrogen, oxygen, and carbon in groundwater were used to identify the sources, mixing, and ages of groundwater in the watershed and the chemical evolution of groundwater as it flows from the upland areas in the watershed to the developed areas at the Wadi Watir delta. Groundwater in the Wadi Watir watershed is primarily from recent recharge while groundwater salinity is controlled by mixing of chemically different waters and dissolution of minerals and salts in the aquifers. The El Shiekh Attia and Wadi El Ain areas in the upper Wadi Watir watershed have different recharge sources, either from recharge from other areas or from different storm events. The downgradient Main Channel area receives groundwater flow primarily from the El Shiekh Attia area. Groundwater in the Main Channel area is the primary source of groundwater supplying the aquifers of the Wadi Watir delta.     

Research on the carbon isotopic composition of organic matter from Lake Chenghai and Caohai Lake sediments

The carbon isotopic composition of organic matter from lake sediments has been extensively used to infer variations in productivity. In this paper, based on the study of the contents and δ13C values of organic matter in different types of lakes, it has been found that δ13C values of organic matter have different responses to lake productivity in different lakes. As to the lakes dominated by aqutic macrophytes such as Lake Caohai, organic matter becomes enriched in 13C with increasing productivity. As to the lakes dominated by aquatic algae such as Lake Chenghai, δ13C values of organic matter decrease with increasing productivity, and the degradation of aquatic algae is the main factor leading to the decrease of δ13C values of organic matter with increasing productivity. Therefore, we should be cautious to use the carbon isotopic composition of organic matter to deduce lake productivity.     

太湖平原碟形洼地沉积物记录的距今8 000年以来植被、气候与地貌演变

利用DGY孔沉积物的岩性、粒度及孢粉分析资料,探讨了太湖平原碟形洼地沉积物记录的8 000年以来植被演化、气候波动,流域地貌环境的演变及其对海平面波动的响应。孢粉记录表明：本区距今8 000～5 000年木本植被由以落叶阔叶乔木和针叶乔木为主变为落叶阔叶乔木和常绿阔叶乔木为主,气候由温和略干转为暖热湿润;距今5 000～4 000年森林退缩,气候温和偏干;距今4 000年左右出现低温事件;距今4000～3000年木本植被以常绿阔叶乔木为主,气候温暖湿润;距今3 000年以来木本植被主要为常绿阔叶乔木、落叶阔叶乔木和针叶乔木,气候总体温暖湿润,有波动变凉干趋势。岩性、粒度及孢粉记录综合显示本区距今8 000～5 000年发育潟湖相泥质粉砂,反映流域环境开放、与海连通;距今5 000～4 000年发育淡水沼泽,未受海水作用,反映水域缩小、流域环境封闭;距今4 000～3 000年水域扩大,并出现海水倒灌,反映内低外高的碟形洼地已经形成;距今3 000年以来,发育湖沼平原,发生数次海水倒灌,反映碟形洼地地貌的进一步发育。     

太湖平原碟形洼地沉积物记录的距今8000年以来植被、气候与地貌演变

利用DGY孔沉积物的岩性、粒度及孢粉分析资料,探讨了太湖平原碟形洼地沉积物记录的8000年以来植被演化、气候波动,流域地貌环境的演变及其对海平面波动的响应。孢粉记录表明:本区距今8000~5000年木本植被由以落叶阔叶乔木和针叶乔木为主变为落叶阔叶乔木和常绿阔叶乔木为主,气候由温和略干转为暖热湿润;距今5000~4000年森林退缩,气候温和偏干;距今4000年左右出现低温事件;距今4000~3,000年木本植被以常绿阔叶乔木为主,气候温暖湿润;距今3000年以来木本植被主要为常绿阔叶乔木、落叶阔叶乔木和针叶乔木,气候总体温暖湿润,有波动变凉干趋势。岩性、粒度及孢粉记录综合显示本区距今8000~5000年发育潟湖相泥质粉砂,反映流域环境开放、与海连通;距今5000~4000年发育淡水沼泽,未受海水作用,反映水域缩小、流域环境封闭;距今4000~3000年水域扩大,并出现海水倒灌,反映内低外高的碟形洼地已经形成;距今3000年以来,发育湖沼平原,发生数次海水倒灌,反映碟形洼地地貌的进一步发育。     

Geochemical characterization of soils, sediments and waters around active and abandoned dumpsites in Lagos

In developing countries, large amounts of wastes are dumped daily in open dumping sites without proper management. This practice usually causes enhanced concentration of metallic ions in environmental media within and beyond the vicinity of such dumps with attendant adverse environmental and health risks. Hence the aim of this study is to assess and elucidate the physico- and metallic ions concentrations in three environmental media （soils, sediments and waters） around active （Ojota） and abandoned （Isolo） dumpsites in Lagos and also to do a comparative study with reference to possible environmental and health impacts. A total of eighty samples comprising water, sediments and topsoils were collected around the two dumpsites. The soil and sediment were dried, disaggregated and sieved to 〈75 μm fraction for analysis of the metallic ions using aqua-regia digestion technique and Inductively Coupled Plasma Mass Spectrometry （ICP-MS）. The analysis of metallic ions and cations in water was carried out using Inductively Coupled Plasma-Optical Emission Spectrometry （ICP-OES） while unacidified water samples were analyzed for anions concentrations using the DIONEX DX-120 Ion Chromatography techniques. Analytical results show that pH, NO3, Fe, Mn and Na in most of the water samples are above WHO and EPA standards. Also there are relatively strong correlations between NO3 and Cl, SO4, Coliform, TDS and EC which are an indicator of water contamination especially in the direction of groundwater flow. The mean values of the significant metallic ions present in the water samples include Cu （16.29 and 38.0）, Zn （535.71 and 667.0）, A1 （0.27 and 0.19）, Ba （42.86 and 55.0）, Sr （80.0 and 136.0） and B （118.7 and 160.2） for active （Ojota） and abandoned （Isolo） dnmpsites respectively. Soil samples revealed varied concentrations with the estimated average contamination factors of 3.86 and 5.71 （As）, 1.60 and 1.93 （Mo）, 3.41 and 4.24 （Zn）, 0.93 and 2.23 （Cu）, 7.71 and 12.64 （Pb）, 8.71 and 9.21（Cd） for both active and abandoned sites respectively. All these metals with Ag are also significant and follow the same trend in the sediments. Ag, Bi, Sb, Ga, Sc, Mn, Ga and La in soil samples are only significant for samples close to the dnmpsites while Bi, Be, Sb, Co, Cu, La and Cr are significant for sediments taken downstream. Most of the metallic ions show significant enrichment in both soil and sediments while A1, B, Ba and Sr are only significant in water.     

Strontium isotopic evidence on the chemical evolution of pore waters in the Milk River Aquifer,Alberta, Canada

Strontium isotope ratios were measured on 13 rock, 18 leachate and 28 pore-water samples from the Milk River aquifer, the confining argillaceous formations, and the glacial till mantling the recharge area. Strontium isotope ratios (⁸⁷Sr/⁸⁶Sr) of pore waters from the aquifer, confining units, and the glacial till ranged from 0.7069 to 0.7082. The ⁸⁷Sr/⁸⁶Sr ratios in aquifer pore waters decrease with increasing distance from the aquifer recharge area, and this is interpreted to be the result of mixing and water–rock interaction within the aquifer.The solute composition of the recharging groundwater is modified by the local lithology, causing distinct geochemical patterns along different flow paths within the aquifer. Whole-rock ⁸⁷Sr/⁸⁶Sr ratios indicate that the shales and till are generally more radiogenic than the aquifer sandstone. The authigenic carbonate cements and rock-forming minerals comprising the major lithologic units had little apparent influence on the pore-water Sr chemistry. Carbonate cement leachates from the till and the aquifer sandstone are more radiogenic than those from the confining shale formations. Feldspar separates from the aquifer sandstone have relatively radiogenic Sr isotope ratios, whereas bentonites from the Milk River and Colorado Shale Formations have whole-rock and leachate Sr isotope ratios that are relatively unradiogenic. Ratios of most Milk River aquifer pore waters are lower than those of any leachates or whole rocks analyzed, except the bentonites.The ⁸⁷Sr/⁸⁶Sr ratios of exchangeable Sr in the bentonites are similar to ratios found in the more evolved pore waters. Simple rock–water interaction models calculated for the whole-rock, leachate, and exchangeable-ion/pore-water pairs indicate that ion exchange with bentonite clays within the Milk River and Colorado Shale Formations appears to influence the isotopic evolution of the pore-water Sr in each of these units.     

Weathering and climate change since l820 AD in Hoh Xil, Qinghai-Xizang Plateau, China——Evidence from element geochemistry of lake sediments of Gulug Co Lake

Element geochemistry of lake sediments has been widely used to detect climate change because element composition and ratios can reflect the weathering degree in the source area. Given the dement composition of lake sediments from Gulug Co Lake, Hoh Xil, Qing- hai-Xizang Plateau, chemical index of alteration （CIA）, index of composition variability （ICV） and other element ratios have been used to establish the weathering sequence of this area since 1820 AD. The weathering is so weak that the element composition change is more sensitive to climate change and autochthonous processes. From 1820 to 1984 AD, there were two drier periods with a wetter interval from 1870 to 1945 AD. After 1984 the weather showed a tendency of becoming wet.     

Weathering and climate change since 1820 AD in Hoh Xil, Qinghai-Xizang Plateau, China Evidence from element geochemistry of lake sediments of Gulug Co Lake

Element geochemistry of lake sediments has been widely used to detect climate change because element composition and ratios can reflect the weathering degree in the source area. Given the element composition of lake sediments from Gulug Co Lake, Hoh Xil, Qinghai-Xizang Plateau, chemical index of alteration (CIA), index of composition variability (ICV) and other element ratios have been used to establish the weathering sequence of this area since 1820 AD. The weathering is so weak that the element composition change is more sensitive to climate change and autochthonous processes. From 1820 to 1984 AD, there were two drier periods with a wetter interval from 1870 to 1945 AD. After 1984 the weather showed a tendency of becoming wet.     

Determining the groundwater basin and surface watershed boundary of Dalinuoer Lake in the middle of Inner Mongolian Plateau,China and its impacts on the ecological environment

The surface watershed and groundwater basin have fixed recharge scale, which are not only the basic unit for hydrologic cycle research but also control the water resources formation and evolution and its corresponding eco-geological environment pattern. To accurately identify the boundary of the surface watershed and groundwater basin is the basis for properly understanding hydrologic cycle and conducting the water balance analysis at watershed scale in complicated geologic structure area, especially when the boundary are inconsistent. In this study, the Dalinuoer Lake located in the middle of the Inner Mongolian Plateau which has complicated geologic structure was selected as the representative case. Based on the multidisciplinary comprehensive analysis of topography, tectonics, hydrogeology, groundwater dynamics and stable isotopes, the results suggest the following: (1) The surface watershed ridge and groundwater basin divide of Dalinuoer Lake are inconsistent. The surface watershed was divided into two separate groundwater systems almost having no groundwater exchange by the SW-NE Haoluku Anticlinorium Fault which has obvious water-blocking effect. The surface drainage area of Dalinuoer Lake is 6139 km². The northern regional A is the Dalinuoer Lake groundwater system with an area of 4838 km², and the southern regional B is the Xilamulun Riverhead groundwater system with an area of 1301 km². (2) The groundwater in the southern of regional A and the spring-feeding river are the important recharge sources for the Dalinuoer Lake, and it has greater recharge effects than the northern Gonggeer River system. (3) It is speculated that the trend of Haoluku Anticlinorium Fault is the boundary of the westerlies and the East Asian summer Monsoon (EASM) climate systems, which further pinpoints the predecessor’s understanding of this boundary line. At present, the Dalinuoer Lake watershed is proved to have gone through a prominent warming-drying trend periods, which leads to the precipitation reduction, temperature rise, human activities water usage increasement. So the hydrological cycle and lake eco-environment at watershed scale will still bound to be change, which may pose the potential deterioration risk on the suitability of fish habitat. The results can provide basic support for better understanding water balance evolution and lake area shrinkage cause as well as the ecological protection and restoration implementation of Dalinuoer Lake watershed.© 2021 China Geology Editorial Office.     

安徽巢湖湖泊沉积物孢粉-炭屑组合记录的全新世以来植被与气候演变

利用湖泊钻孔的孢粉及炭屑分析资料,探讨了安徽巢湖湖泊沉积物孢粉-炭屑组合记录的全新世以来植被与气候演变。孢粉-炭屑记录表明：本区9870-6040 cal.{a BP},植被是以壳斗科的落叶、常绿属种为主的落叶阔叶、常绿阔叶混交林,气候呈现温和略干的特点;6040-4860 cal.{a BP},植被是以落叶栎类、栗属、青冈属和栲/石栎属为主的落叶阔叶、常绿阔叶混交林,气候由前一阶段的温和略干变为温暖湿润,进入全新世最适宜气候期;4860-2170 cal.{a BP},植被是以落叶栎类占绝对优势的落叶阔叶、常绿阔叶混交林,气温逐渐降低、湿度下降,气候温和干燥,环境整体向着干旱趋势转化,2170 cal.{a BP}左右出现一次明显的干旱事件;2170-1040 cal.{a BP},森林退缩,落叶阔叶、常绿阔叶混交林迅速被破坏,演替成以禾本科为主的草地,气候处于转型时期,总体上温和湿润;1040-200 cal.{a BP},木本植物仅零星分布,可能存在针叶阔叶混交林植被,植被类型逐渐演替成以禾本科、蒿属和蓼属等为主的草丛,其中包括较多的农作物,气候温凉稍湿;200 cal.{a BP}以来,湖区周围零星分布有阔叶乔木,松林在远处可能有分布,植被仍是以禾本科、蒿属和蓼属等为主的草丛,气候相对温暖湿润,但也有若干变凉干的波动,湖泊富营养化水平逐渐增加,人类活动已经对环境变化产生了较大的影响。