Rare earth element studies of surficial sediments from the southwestern Carlsberg Ridge,Indian Ocean

The rare earth element (REE) contents of sixteen surficial calcareous sediments from the southwestern Carlsberg Ridge, Indian Ocean, have been determined. The total REE vary from 35 ppm to 126 ppm and are inversely related to the calcium carbonate content. REEs show a strong positive correlation with Al + Fe + K + Mg + Na (r ²= 0.98) and Mn + Fe + Cu + Ni (r ²= 0.86) suggesting that the REE is associated with a combined phase of clays (mainly illite) and Mn-Fe oxyhydroxides. The aeolian input into these sediments is suggested from the weak positive Eu/Eu* anomaly. Shale-normalized (NASC) pattern along with La_(n)/Yb_(n) ratio suggest enrichment of heavy REE (HREE) relative to the light REE (LREE) with a negative Ce/Ce* anomaly implying retention of a bottom water REE pattern. An erratum to this article is available at .     

Fractal analysis of bathymetry and gravity profiles across the Chagos-Laccadive Ridge and the Carlsberg Ridge in the Indian Ocean

Gravity and bathymetry data have been extensively used to infer the thermo-mechanical evolution of different segments of the oceanic lithosphere. It is now understood that magmatic fluid processes involved in the accretion of oceanic crust are spatially complex and episodic. The nature of these processes which are in general nonlinear, can be described using fractal analysis of marine geophysical data. Fractal analysis has been carried out for gravity and bathymetry profiles over the aseismic Chagos-Laccadive Ridge and the spreading Carlsberg Ridge. The Iterated Function Systems (IFS) have been used to generate synthetic profiles of known dimension (D) and these are compared with the observed profiles. The D for the data sets are in the range of 1–1.5. The D for gravity profiles is less than those of bathymetry and the D for gravity and bathymetry over spreading ridge is higher than the aseismic ridge. The low fractal dimension indicates that the processes generating them are of low dimensional dynamical systems.     

Mineralogy and trace element geochemistry of sulfide minerals from the Wocan Hydrothermal Field on the slow-spreading Carlsberg Ridge,Indian Ocean

The basalt-hosted Wocan Hydrothermal Field (WHF), located on the NW slope of an axial volcanic ridge at a depth of ∼3000 m at 6°22′N on the slow-spreading Carlsberg Ridge, northwest Indian Ocean, was discovered in 2013 during Chinese DY28th cruise. Preliminary investigations show that the field consists of two hydrothermal sites: Wocan-1, which shows indications for recent high-temperature hydrothermal activity, is located near the peak of the axial volcanic ridge at a water depth of 2970–2990 m, and Wocan-2 site, located at a water depth of 3100 m, ∼1.7 km to the northwest of Wocan-1. The recovered hydrothermal precipitates can be classified into four groups: (i) Cu-rich chimneys; (ii) Cu-rich massive sulfides; (iii) Fe-rich massive sulfides; and (iv) silicified massive sulfides. We conducted mineral texture and assemblage observation and Laser-ablation ICP-MS analyses of the hydrothermal precipitates to study the mineralization processes. Our results show that there are distinct systematic trace element distributions throughout the different minerals in the four sample groups. In general, chalcopyrite from the group (i) is enriched in Pb, As, Mo, Ga, Ge, V, and Sb, metals that are commonly referred to as medium- to low-temperature elements. In contrast these elements are present in low contents in the chalcopyrite grains from other sample groups. Selenium, a typical high-temperature metal, is enriched in chalcopyrite from groups (ii) and (iv), whereas Ag and Sn are enriched only in some silicified massive sulfides. As with chalcopyrite, pyrite also shows distinct trace element associations in grains with different habitus. The low-temperature association of elements (Pb, Mo, Mn, U, Mg, Ag, and Tl) is typically present in colloform/framboidal pyrite, whereas the high-temperature association (Se, Co, and Bi) is enriched in euhedral pyrite. Sphalerite in the groups (i) and (iii) at Wocan-1 is characterized by high concentrations of Ga, Ge, Pb, Cd, As, and Sb, indicating that sphalerite in these sample groups likely precipitated at intermediate temperatures. Early bornite, which mainly occurs in the central part of the Cu-rich chimney, is typically enriched in Sn and In compared to the other minerals. In contrast, late bornite that likely formed during increasing interaction of hydrothermal fluids with cold, oxygenated seawater has low Sn and In, but significantly higher concentrations of Ag, Au, Mo and U. Digenite, also forming in the exterior parts of the samples during the late stages of hydrothermal fluid venting, is poor in most trace elements, except Ag and U. The notable Ag enrichment in the late-stage mineral assemblages at both Wocan-1 and Wocan-2 may therefore be related to lower temperatures and elevated pH. Our results indicate that Wocan-1 has experienced a cycle of heating with Cu-rich chimney growth and subsequent cooling, followed by late seafloor weathering, while Wocan-2 has seen intermediate- to high-temperature mineralization followed by intense silicification of sulfides. Seafloor weathering processes or mixing of hydrothermal fluids with seawater during the waning stages of hydrothermal fluid flow result in significant redistributions of trace elements in sulfide minerals.     

Imprints of ancient recycled oceanic lithosphere in heterogeneous Indian Ocean mantle: Evidence from petrogenesis of Carlsberg ridge basalts from Northwest Indian Ocean

This paper reports new petrological, geochemical and isotopic data for Carlsberg Ridge Basalts (CRB) of northwest Indian Ocean and evaluates their petrogenetic aspects in the context of the geochemical and tectonic evolution of the Indian Ocean mantle. The CRB samples exhibit tholeiitic to transitional composition of precursor melts derived by high degree, shallow level partial melting of a spinel peridotite mantle source. CRB reflects distinct E-MORB affinity with selective enrichment in incompatible trace elements. Higher values of Zr/Hf (33.8–47.3) and Zr/Sm (24.9–36.4) in conjunction with lower Nb/Ta (1.7–7.3) ratio corroborate their origin from an enriched mantle source. Negative Nb anomalies with lower Nb/Y (0.04–0.11) and Zr/Y (2.5–3.5) conform to a non-plume origin of these basalts. Higher Zr/Nb (25.5–71.5) and Th/Nb (0.6–0.42) compared to OIB substantiate contributions from recycled subduction-processed components in the source mantle. Lower Nb/U (6.2–37.9) values with higher Ba/Nb (6.1–21.9), Ba/Th (27.7–147.5), Zr/Nb (25.5–71.5) and Th/Nb (0.6–0.42) compared to OIB and N-MORB attest to role of a metasomatized oceanic lithosphere that recycled into the depleted upper mantle attributing to the source heterogeneity. Sr-Nd isotopic signatures (⁸⁷Sr/⁸⁶Sr: 0.702668 to 0.702841 and ¹⁴³Nd/¹⁴⁴Nd: 0.512972 to 0.513068) of CRB suggest a HIMU source component preserved in the northwest Indian Ocean Ridge mantle. The compositional diversity of the Indian Ocean mantle can be translated in terms of periodic refertilization of depleted N-MORB type mantle through delamination and recycling of oceanic (HIMU component) and continental lithosphere (EM I component) concurrent with Neoproterozoic-Palaeozoic amalgamation and Jurassic dispersal of Gondwana Supercontinent respectively. This study complies with the derivation of CRB from a geochemically heterogeneous Indian Ocean mantle that experienced a protracted residence beneath the Gondwana Supercontinent prior to the opening of Indian Ocean and trapped recycled metasomatized oceanic lithosphere genetically linked with multiple stages of paleo-ocean closure and continental convergence during Gondwana assembly.     

Rare earth abundances and Rb-Sr systematics of basalts,gabbro, anorthosite and minor granitic rocks from the Indian Ocean Ridge System,Western Indian Ocean

Basalts dredged from the Mid-Indian Ocean Ridge System have rare earth, Rb, and Sr concentrations like those from other mid-ocean ridges, but have slightly higher Sr⁸⁷/Sr⁸⁶ ratios. Underlying gabbroic complexes are similar to the basalts in Sr⁸⁷/Sr⁸⁶, but are poorer K, Rb, and in rare earths. The chemical and isotopic data, as well as the geologic relations suggest a cumulate origin for the bulk of the gabbroic complexes.     

Geodynamics of the Amirante Ridge and Trench Complex,Western Indian Ocean

The formation and evolution of the ～600 km long arcuate Amirante Ridge and Trench Complex (ARTC) is a significant geomorphic–structural feature in the Western Indian Ocean (WIO). The WIO contains evidence of at least two major magmatic episodes followed by continental rifting within the span of a little more than 20 million years. This involved the splitting of Madagascar from India at around 85 Ma and then separation between India and the Seychelles at 64–63 Ma as a possible consequence of two powerful volcanic eruptions from the Marion and Reunion hot spots, respectively. Formation and evolution of the ARTC represents this tumultuous period in the Indian Ocean, approximately between 85 and 60 Ma (Late Cretaceous–Early Tertiary).

We integrated geophysical, palaeomagnetical, and petrological data to examine three existing models that attempt to explain the formation of ARTC. In contrast, our study hints at several stages of extension and compression responsible for its formation. Our integrated data also suggest that the Carlsberg Ridge may have played a prominent role in the evolution of the ARTC that seems to have formed through a ridge-jump process after the conjugate spreading centres – Mascarene and Palitana ridges formed earlier during the India–Madagascar separation – ceased spreading because of violent eruption of the Reunion hot spot at around 65 Ma. The eruption disturbed the plumbing system of magma ascent, resulting in cessation of spreading along the conjugate spreading centres, forcing a ridge jump.

A collage of seismic refraction and reflection, free-air gravity, magnetic anomaly data, and Ar dating of rocks indicates that as the Carlsberg Ridge swept the Seychelles towards south, the crust between Madagascar and the Seychelles was increasingly compressed, with the abandoned northern Mascarene spreading centre absorbing the maximum stress. With continued compression, the western limb of the abandoned spreading ridge was thrust below the eastern limb to a limited degree. This partial subduction agrees with the gravity and seismic results. Our new study also accounts for the anomalous presence of 14 km-thick oceanic crust beneath the ARTC and its characteristic difference in petrology with other established subduction zones in the world.     

西南印度洋脊原位辉长岩元素地球化学特征及意义

通过对位于西南印度洋脊超慢速扩张脊东段的大洋钻探计划(ODP)ODP 735B钻孔上部岩心不同位置、不同岩性的样品进行全岩主、微量元素分析,并结合前人研究成果,对旋回内部及旋回之间的全岩地球化学特征差异进行了探讨,对其成因进行了约束.ODP 735B岩心全岩主量元素特征主要受控于分离结晶生成的矿物组合及比例.全岩主量元素之间的协变关系对反映玄武质熔体结晶演化过程中矿物生成及化学成分演化具有一定的指示意义.稀土元素的分析表明,除较明显的正Eu异常外,旋回1、2均表现出明显的LREE分馏,而HREE则未出现明显分馏.微量元素的分析表明,西南印度洋超低速洋脊的旋回1和旋回2中均表现出明显的Nb、Ta负异常和Sr、K正异常,但不能依靠其全岩微量元素Nb、Ta负异常特征对其源区地球化学特征成因和地质意义进行判断.      

Seismic moment release along selected major transforms on the Central Indian Ridge,Western Indian Ocean,and its tectonic implications

A detailed seismicity map of the Central Indian Ridge for the period 1912–1993 is presented, and the earthquakes pertaining to four major transforms offsetting the ridge are utilized to study the moment release pattern. The scalar moment release for the period 1912–1993, and the summed moment rate tensors for both short period (1977–1993) and long period (1912–1993) bring out a unified picture of moment release pattern. The fraction of seismic slip calculated based on depths of 100°C and 400°C limiting temperatures suggests that the Marie-Celeste transform requires a slip almost to a depth of 400°C isotherm to account for the observed moment, and the Argo transform requires depth of faulting much above the 400°C isotherm. A very small fraction of slip is accounted seismically for Vema (53%) and 12° 12′S (23%) even to depths of 100°C isotherm, suggesting a very low order of moment release along these transforms. The horizontal plate velocities and the corresponding strain rates obtained from moment tensor summation of long period data (82 years) give rise to (V _y ^y ; V _y ^x mm. yr⁻¹) of 6.0 and 6.1 along Marie-Celeste, 1.3 and 0.50 along Argo, 0.06 and 0.06 along 12° 12′S, 1.6 and 0.25 along Vema transforms. The corresponding strain rates (ε _y ^y ;ε _y ^x × 10⁻¹⁵ S⁻¹) are 12.7 and 6.8 along MarieCeleste, 6.9 and 1.4 along Argo, 0.27 and 0.14 along 12° 12′S, 7.3 and 0.58 along Vema transforms. These results suggest that the strain rates were highest and almost all predicted motion is taken up seismically along the Marie-Celeste transform. The strain rates are lower along Argo transform and the observed moment release require shallower depth of faulting in order to slip to be accounted seismically. The Vema and 12° 12′S transforms are characterized by low strain rates and less than 15 per cent of motion is accommodated seismically within the seismogenic layer. It is proposed that the deficiency of moment release along the Vema and 12° 12′S multiple transform system may be due to most of the plate motion occurring aseismically.     

The offshore east African rift system: new insights from the Sakalaves seamounts (Davie Ridge,SW Indian Ocean)

The offshore branch of the East African Rift System (EARS) has developed during Late Cenozoic time along the eastern Africa continental margin. While Neogene–Pleistocene extensional tectonic deformation has been evidenced along the northern segment of the Davie Ridge, the spatial extent of deformation further south remains poorly documented. Based on recent and various oceanographic datasets (bathymetric surveys, dredge samples and seismic profiles), our study highlights active normal faulting, modern east–west extensional tectonic deformation and Late Cenozoic alkaline volcanism at the Sakalaves Seamounts (18°S, Davie Ridge) that seem tightly linked to the offshore EARS development. In parallel, rift‐related tectonic subsidence appears responsible for the drowning of the Sakalaves Miocene shallow‐water carbonate platform. Our findings bring new insights regarding the development of the EARS offshore branch and support recent kinematic models proposing the existence of a plate boundary across the Mozambique Channel.     

Petrology of the Ninety East Ridge (Indian Ocean) compared to other aseismic ridges

The volcanics from the Ninety East Ridge in the Indian Ocean consist of basalts and oceanic andesites. The basalts from the Ninety East Ridge differ from the Mid-Indian Oceanic Ridge basalts in their higher pyroxene content, their higher Fe₂O₃ + FeO content (>11%), higher TiO₂ content (2–3%), and variable K₂O content (0.2–1.5%). Volcanics from other aseismic ridges, i.e. the Cocos, the Iceland-Faeroe and the Walvis ridges, show a trend of differentiation which has progressed further than is commonly encountered on mid-oceanic ridge rocks. The Ninety East and the Iceland-Faeroe ridges contain mildly tholeiitic basalts and oceanic andesites while the Walvis and the Cocos Ridges consist of plagioclase-alkali basalts, trachybasalts and trachytes. The majority of basalts found on aseismic ridges have a higher total iron oxide content (>11%) and a more variable K₂O (2–3%) and TiO₂ (1.5–4%) content than mid-oceanic ridge basalts. The type of volcanism encountered on aseismic ridges is similar to that of the islands which are near or associated with the ridges.     

Geochemical characteristics of lavas from Broken Ridge, the Naturaliste Plateau and southernmost Kerguelen Plateau: Cretaceous plateau volcanism in the southeast Indian Ocean

Lavas from several major bathymetric highs in the eastern Indian Ocean that are likely to have formed as Early to Middle Cretaceous manifestations of the Kerguelen hotspot are predominantly tholeiitic; so too are glass shards from Eocene to Paleocene volcanic ash layers on Broken Ridge, which are believed to have come from eruptions on the Ninetyeast Ridge. The early dominance of tholeiitic compositions contrasts with the more recent intraplate, alkalic volcanism of the Kerguelen Archipelago. Isotopic and incompatible-element ratios of the plateau lavas are distinct from those of Indian mid-ocean ridge basalts; their Nd, Sr, ²⁰⁷Pb/²⁰⁴Pb and isotopic ratios overlap with but cover a much wider range than measured for more recent oceanic products of the Kerguelen hotspot (including the Ninetyeast Ridge) or, indeed, oceanic lavas from any other hotspot in the world. Samples from the Naturaliste Plateau and ODP Site 738 on the southern tip of the Kerguelen Plateau are particularly noteworthy, with ε_Nd(T) = − 13 to −7, (⁸⁷Sr/⁸⁶Sr)_T=0.7090 to 0.7130 and high ²⁰⁷Pb/²⁰⁴Pb relative to ²⁰⁶Pb/²⁰⁴Pb. In addition, the low-ε_Nd(T) Naturaliste Plateau samples are elevated in SiO₂ (> 54 wt%). In contrast to “DUPAL” oceanic islands such as the Kerguelen Archipelago, Pitcairn and Tristan da Cunha, the plateau lavas with extreme isotopic characteristics also have relative depletions in Nb and Ta (e.g., Th/Ta, La Nb > primitive mantle values); the lowest ε_Nd(T) and highest Th/Ta and La Nb values occur at sites located closest to rifted continental margins. Accepting a Kerguelen plume origin for the plateau lavas, these characteristics probably reflect the shallow-level incorporation of continental lithosphere in either the head of the early Kerguelen plume or in plume-derived magmas, and suggest that the influence of such material diminished after the period of plateau construction. Contamination of asthenosphere with the type of material affecting Naturaliste Plateau and Site 738 magmatism appears unlikely to be the cause of low-²⁰⁶Pb/⁰⁴Pb Indian mid-ocean ridge basalts. Finally, because isotopic data for the plateaus do not cluster or form converging arrays in isotope-ratio plots, they provide no evidence for either a quickly evolving, positive ε_Nd, relatively high-²⁰⁶Pb/²⁰⁴Pb plume composition, or a plume source dominated by mantle with ε_Nd of −3 to 0.     

Anatectic Migmatites from the Roof of an Ocean Ridge Magma Chamber

A well-preserved contact aureole at the base of the sheeteddyke complex in the Troodos ophiolite, Cyprus, records the partialmelting of the roof of a mid-ocean ridge magma chamber. Hydrothermallyaltered dykes within the lowermost 10–30 m of the sheeteddyke complex were recrystallized to pyroxene and hornblendehornfels and, closest to the underlying gabbros (<10 m),partially melted (up to >30%) at water-undersaturated conditionsand temperatures     

Composition of macrobenthos from the Central Indian Ocean Basin

The deep sea is well known for its high faunal diversity. But the current interest in its abundant polymetallic nodules, poses a threat to the little known benthic organisms surviving in this unique environment. The present study is the first attempt to document the Indian Ocean abyssal benthic diversity of macroinvertebrates and to investigate its relation to the surface primary production (chl-a), sediment labile organic matter, organic carbon and texture. The present study is based on 87 individuals. Altogether 39 macroinvertebrate genera were obtained from water depths of 4500–5500 m from 23 box cores. Reduction in macrobenthic density was seen towards the southern latitudes. The area was dominated by deposit feeding macrobenthos. Vertically, the fauna was distributed down to 30 cm depth, with the highest faunal density in the top 2–5 cm sediment section. The values for population density were strongly correlated with surface water chl-a and sediment protein, indicating supply of fresh organic matter as a critical factor for maintaining the deep sea benthic diversity and abundance.     

KRb ratios in some volcanic rocks from Mauritius,Indian Ocean

$\text{K}\text{Rb}$ ratios in Mauritian Older Series basalts range from 200 to 350. A fall to around 175 in trachytes probably relates to kaersutite fractionation. Highly variable ratios in Intermediate     

Petrogenesis of the Back-arc East Scotia Ridge, South Atlantic Ocean

The East Scotia Ridge is an active back-arc spreading centrelocated to the west of the South Sandwich island arc in theSouth Atlantic Ocean, consisting of nine main segments, E1 (north)to E9 (south). Major and trace element and Sr–Nd–Pbisotope compositions are presented, together with water contents,for lavas sampled along the active ridge axis. Magmatism alongthe East Scotia Ridge is chemically heterogeneous, but thereis a common mid-ocean ridge basalt (MORB)-type source componentfor all the magmas. An almost unmodified MORB-source mantleappears to underlie the central part of the back-arc. Subductioncomponents are found at the northern and southern ends of theridge, and there is a marked sediment melt input of up to 2%in segment E4. Enriched (plume) mantle is present beneath segmentE2 at the northern end of the ridge, suggesting that plume mantleis flowing westward around the edges of the subducting slab.The southern part of segment E8 is unique in that its magmasource is similar to sub-arc depleted mantle. KEY WORDS: geochemistry; petrogenesis; volcanism; back-arc; subduction     

热点作用背景下的洋中脊跃迁和扩展作用:印度洋盆地张开过程探讨

在《印度洋底大地构造图》的基础上,分析了印度洋盆构造格局和洋盆演化重大事件序列,并从印度洋盆初始裂解机制、扩张中心跃迁与热点作用、洋中脊扩展作用等方面讨论了印度洋盆的张开过程,提出以下几点认识:(1)现今印度洋洋中脊可分为两个系统:东南印度洋中脊-中印度洋中脊-卡斯伯格洋脊系统(东支)和西南印度洋中脊系统(西支),前者是太平洋洋中脊扩展作用的产物,后者是太平洋-东南印度洋中脊与大西洋中脊之间构造调节的产物;(2)印度洋盆最初裂解受地幔柱垂向挤压-水平伸展作用控制,沿前寒武造山带等地壳薄弱带发育;(3)印度洋盆经历两次扩张中心的跃迁,其趋向性跃迁方向与热点相对板块的运动方向具有一致性,显示两者存在内在联系。(4)大西洋和太平洋洋中脊在印度洋交汇,于古近纪连通,末端伴随陆块持续发生碎裂化、裂解化,可称为鱼尾构造模式,表明印度洋盆衔接和调节了三大洋盆的发育和演化过程,具有全球洋盆枢纽的关键意义。     

Platinum-group element systematics in Mid-Oceanic Ridge basaltic glasses from the Pacific, Atlantic, and Indian Oceans

The concentrations of Ir, Ru, Pt and Pd have been determined in 29 Mid-Oceanic Ridge basaltic (MORB) glasses from the Pacific (N = 7), the Atlantic (N = 10) and the Indian (N = 11) oceanic ridges and the Red Sea (N = 1) spreading centers. The effect of sulfide segregation during magmatic differentiation has been discussed with sample suites deriving from parental melts produced by high (16%) and low (6%) degrees of partial melting, respectively. Both sample suites define positive and distinct covariation trends in platinum-group elements (PGE) vs. Ni binary plots. The high-degree melting suite displays, for a given Ni content, systematically higher PGE contents relative to the low-degree melting suite. The mass fraction of sulfide segregated during crystallization (X_sulf), the achievement of equilibrium between sulfide melt and silicate melts (R_eff), and the respective proportions between fractional and batch crystallization processes (S_b) are key parameters for modeling the PGE partitioning behavior during S-saturated MORB differentiation. Regardless of the model chosen, similar sulfide melt/silicate melt partition coefficients for Ir, Ru, Pt and Pd are needed to model the sulfide segregation process, in agreement with experimental data. When corrected for the effect of magmatic differentiation, the PGE data display coherent variations with partial melting degrees. Iridium, Ru and Pt are found to be compatible in nonsulfide minerals whereas the Pd behaves as a purely chalcophile element. The calculated partition coefficients between mantle sulfides and silicate melts (assuming a PGE concentration in the oceanic mantle at ∼0.007 × CI-chondritic abundances) increase from Pd (∼10³) to Ir (∼10⁵). This contrasting behavior of PGE during S-saturated magmatic differentiation and mantle melting processes can be accounted for by assuming that Monosufide Solid Solution (Mss) controls the PGE budget in MORB melting residues whereas MORB differentiation processes involve Cu-Ni-rich sulfide melt segregation.