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1.
http://dx.doi.org/10.1016/j.gsf.2016.11.007 总被引:1,自引:1,他引:0
Lunar anorthosite is a major rock of the lunar highlands,which formed as a result of plagioclasefloatation in the lunar magma ocean(LMO).Constraints on the sufficient conditions that resulted in the formation of a thick pure anorthosite(mode of plagioclase 95 vol.%) is a key to reveal the early magmatic evolution of the terrestrial planets.To form the pure lunar anorthosite,plagioclase should have separated from the magma ocean with low crystal fraction.Crystal networks of plagioclase and mafic minerals develop when the crystal fraction in the magma(φ) is higher than ca.40-60 vol.%,which inhibit the formation of pure anorthosite.In contrast,when φ is small,the magma ocean is highly turbulent,and plagioclase is likely to become entrained in the turbulent magma rather than separated from the melt.To determine the necessary conditions in which anorthosite forms from the LMO,this study adopted the energy criterion formulated by Solomatov.The composition of melt,temperature,and pressure when plagioclase crystallizes are constrained by using MELTS/pMELTS to calculate the density and viscosity of the melt.When plagioclase starts to crystallize,the Mg~# of melt becomes 0.59 at 1291 C.The density of the melt is smaller than that of plagioclase for P 2.1 kbar(ca.50 km deep),and the critical diameter of plagioclase to separate from the melt becomes larger than the typical crystal diameter of plagioclase(1.8-3 cm).This suggests that plagioclase is likely entrained in the LMO just after the plagioclase starts to crystallize.When the Mg~# of melt becomes 0.54 at 1263 C,the density of melt becomes larger than that of plagioclase even for 0 kbar.When the Mg~# of melt decreases down to 0.46 at 1218 C,the critical diameter of plagioclase to separate from the melt becomes 1.5-2.5 cm,which is nearly equal to the typical plagioclase of the lunar anorthosite.This suggests that plagioclase could separate from the melt.One of the differences between the Earth and the Moon is the presence of water.If the terrestrial magma ocean was saturated with H_2O,plagioclase could not crystallize,and anorthosite could not form. 相似文献
2.
Mohamed W. Ali-Bik Said H. Abd El Rahim Wael Abdel Wahab 《Arabian Journal of Geosciences》2014,7(10):4009-4027
A small intrusive fresh gabbroic mass intrudes the Neoproterozoic metasediments and Dokhan volcanics of Wadi Az Zarib area, Central Eastern Desert. It is composed of hornblende gabbros and leuco-hornblende gabbros. Their petrography, opaque mineralogy, and geochemistry are addressed to elucidate their tectonic setting and petrogenesis. They represent a subduction-related calc–alkaline magma that evolved in an island arc setting. In terms of maturity, the supposed arc represents an intermediate stage between continental arc and active continental margin. Thermobarometry and physical–chemical data of the parent magma as deduced from compositions of amphiboles, biotite, and plagioclase indicate crystallization temperatures of 931–825 °C at pressures of 6.16–4.01 kbar and H2Omelt of 6.4–5.2 wt%. Data, as presented, argue in favor of fractional crystallization mechanism to be accounted to the present suite to interpret the observed variations. The evolution of the suite from hornblende gabbros to leuco-hornblende gabbros was accompanied by decreasing of MgO, CaO, Cr, and Ni with simultaneous increasing of Al2O3, TiO2, Na2O, K2O, Ba, Rb, Sr, La, and Ce. Residuals calculated during mass balance fractional crystallization modeling suggest that brown and green hornblendes are the main fractionated phases which derived the melt composition towards the leuco-hornblende gabbros. 相似文献
3.
Geochronological Constraints on Evolution of Singhbhum Mobile Belt and Associated Basic Volcanics of Eastern Indian Shield 总被引:1,自引:1,他引:1
The Singhbhum Mobile Belt (SMB) of the eastern Indian shield represents a roughly east-west-trending arcuate belt of folded supracrustals overlying the granite-greenstone basement of the Singhbhum-Orissa Craton along its northern, eastern and western margins and is bounded by the Chotanagpur Gneissic Complex to further north. The radiometric ages of the basement Singhbhum and equivalent granites and the intrusive anorogenic Mayurbhanj granite pluton constrain the time of evolution of this mobile belt between 3.12 and 3.09 Ga. Hence, the SMB supracrustals also known as Singhbhum Group, is late Mesoarchaean in age and not Proterozoic as thought earlier. The evolution of the SMB was followed by emplacement of some major basic igneous rocks within or adjacent to the supracrustals. These include Simlipal volcanics at >3.09 Ga on the SMB, Mayurbhanj gabbro along with Mayurbhanj granite at 3.09 Ga along the marginal part of the craton near the SMB, and the Dalma volcanics on the SMB along with the Dhanjori volcanics adjacent to SMB at 2.80 Ga. The 2.80 Ga old basic volcanics is also associated with emplacement of some small granite plutons occurring along the marginal part of the craton, one of them, the Tamperkola granite intrudes the SMB. The >3.09 Ga onward igneous activities along the marginal part of Singhbhum-Orissa Craton took place essentially under anorogenic tectonic setting before being affected by a major metamorphism at 2.50 Ga, which is recorded on the Dalma volcanics and on some small granite pluton occurs along the marginal part of the craton. The Jagannathpur and stratigraphically equivalent Malangtoli volcanics, occurring within the Singhbhum-Orissa Craton at the west, were erupted at 2.25 Ga. The boundary between the SMB supracrustals and the Singhbhum-Orissa Craton is demarked by a prominent shear zone known as the Singhbhum Shear Zone, which shows multiple reactivation, the oldest being at 3.09 Ga, followed by subsequent reactivation during Palaeo- and Mesoproterozoic periods at 2.2, 1.8, 1.6-1.5, 1.4 and 1.0 Ga respectively. The Singhbhum Group and the adjacent Chotanagpur Gneissic Complex appear to have evolved from a near shore syn-rift and a distal post-rift stable shelf sedimentary assemblages respectively, which were deposited without any stratigraphic break in a marine basin existed in the present north of the Singhbhum-Orissa Craton. Both of these assemblages were deformed and metamorphosed together during Proterozoic at 2.5 to >2.3 Ga, 1.6 Ga and 1.0 Ga. 相似文献
4.
Determining the mechanisms involved in generating large-volume eruptions (>100 km3) of silicic magma with crystallinities approaching rheological lock-up (~50 vol% crystals) remains a challenge for volcanologists. The Cenozoic Southern Rocky Mountain volcanic field, in Colorado and northernmost New Mexico, USA, produced ten such crystal-rich ignimbrites within 3 m.y. This work focuses on the 28.7 Ma Masonic Park Tuff, a dacitic (~62–65 wt% SiO2) ignimbrite with an estimated erupted volume of ~500 km3 and an average of ~45 vol% crystals. Near-absence of quartz, titanite, and sanidine, pronounced An-rich spikes near the rims of plagioclase, and reverse zoning in clinopyroxene record the reheating (from ~750 to >800?°C) of an upper crustal mush in response to hotter recharge from below. Zircon U–Pb ages suggest prolonged magmatic residence, while Yb/Dy vs temperature trends indicate co-crystallization with titanite which was later resorbed. High Sr, Ba, and Ti concentrations in plagioclase microlites and phenocryst rims require in-situ feldspar melting and concurrent, but limited, mass addition provided by the recharge, likely in the form of a melt-gas mixture. The larger Fish Canyon Tuff, which erupted from the same location ~0.7 m.y. later, also underwent pre-eruptive reheating and partial melting of quartz, titanite, and feldspars in a long-lived upper crustal mush following the underplating of hotter magma. The Fish Canyon Tuff, however, records cooler pre-eruptive temperatures (~710–760?°C) and a mineral assemblage indicative of higher magmatic water contents (abundant resorbed sanidine and quartz, euhedral amphibole and titanite, and absence of pyroxene). These similar pre-eruptive mush-reactivation histories, despite differing mineral assemblages and pre-eruptive temperatures, indicate that thermal rejuvenation is a key step in the eruption of crystal-rich silicic volcanics over a wide range of conditions. 相似文献
5.
Mixtures of synthetic crystalline enstatite and diopside were reacted with small water contents in sealed capsules in piston-cylinder apparatus at 30 kb between 1000° C and 1700° C. The compositions of coexisting enstatite and diopside solid solutions were measured with an ARL-EMX electron microprobe between 1000° C and 1500° C. Between 1100° C and 1500° C the pyroxenes coexisted with H2O-undersaturated liquid which quenched to inhomogeneous pyroxene crystals. The presence of liquid facilitated growth of pyroxene crystals suitable for microprobe determinations. The solvus of Davis and Boyd (1966) is generally used in geothermometry; our enstatite solvus limb is a few mol-% richer in Mg2Si2O6 in the temperature range 1000–1400° C; our diopside solvus limb is a few mol-% richer in Mg2Si2O6 below 1100°C, in close agreement between 1100° C and 1200° C, but richer in CaMgSi2O6 between 1200° C and 1500° C. Estimated equilibration temperatures for a diopside with composition 78.7% Di is 1300° C according to our results compared with 1210° C for the Davis and Boyd solvus. 相似文献
6.
Thermodynamic models are vital tools to evaluate magma crystallization and storage conditions. Before their results can be used independently, however, they must be verified with controlled experimental data. Here, we use a set of hydrothermal experiments on the Late-erupted Bishop Tuff (LBT) magma to evaluate the rhyolite-MELTS thermodynamic model, a modified calibration of the original MELTS model optimized for crystallization of silicic magmas. Experimental results that are well captured by rhyolite-MELTS include a relatively narrow temperature range separating the crystallization of the first felsic mineral and the onset of the ternary minimum (quartz plus two feldspars), and extensive crystallization over a narrow temperature range once the ternary minimum is reached. The model overestimates temperatures by ~40 °C, a known limitation of rhyolite-MELTS. At pressures below 110 MPa, model and experiments differ in the first felsic phase, suggesting that caution should be exercised when applying the model to very low pressures. Our results indicate that for quartz, sanidine, plagioclase, magnetite, and ilmenite to crystallize in equilibrium from LBT magma, magma must have been stored at ≤740 °C, even when a substantial amount of CO2 occurs in the coexisting fluid. Such temperatures are in conflict with the hotter temperatures retrieved from magnetite–ilmenite compositions (~785 °C for the sample used in the experiments). Consistent with other recent studies, we suggest that the Fe–Ti oxide phases in the Late Bishop Tuff magma body are not in equilibrium with the other minerals and thus the retrieved temperature and oxygen fugacity do not reflect pre-eruptive storage conditions. 相似文献
7.
Takeshi Kuritani Takeyoshi Yoshida Jun-Ichi Kimura Yuka Hirahara Toshiro Takahashi 《Mineralogy and Petrology》2014,108(1):1-11
The water content of low-K tholeiitic basalt magma from Iwate volcano, which is located on the volcanic front of the NE Japan arc, was estimated using multi-component thermodynamic models. The Iwate lavas are moderately porphyritic, consisting of ~8 vol.% olivine and ~20 vol.% plagioclase phenocrysts. The olivine and plagioclase phenocrysts show significant compositional variations, and the Mg# of olivine phenocrysts (Mg#78–85) correlates positively with the An content of coexisting plagioclase phenocrysts (An85–92). The olivine phenocrysts with Mg# > ~82 do not form crystal aggregates with plagioclase phenocrysts. It is inferred from these observations that the phenocrysts with variable compositions were primarily derived from mushy boundary layers along the walls of a magma chamber. By using thermodynamic calculations with the observed petrological features of the lavas, the water content of the Iwate magma was estimated to be 4–5 wt.%. The high water content of the magma supports the recent consensus that frontal-arc magmas are remarkably hydrous. Using the estimated water content of the Iwate magma, the water content and temperature of the source mantle were estimated. Given that the Iwate magma was derived from a primary magma solely by olivine fractionation, the water content and temperature were estimated to be ~0.7 wt.% and ~1,310 °C, respectively. Differentiation mechanisms of low-K frontal-arc basalt magmas were also examined by application of a thermodynamics-based mass balance model to the Iwate magma. It is suggested that magmatic differentiation proceeds primarily through fractionation of crystals from the main molten part of a magma chamber when it is located at <~200 MPa, whereas magma evolves through a convective melt exchange between the main magma and mushy boundary layers when the magma body is located at >~200 MPa. 相似文献
8.
Antar Abdel Wahab Mohamed Fouad Ghoneim Tamer Abu-Alam 《Arabian Journal of Geosciences》2017,10(2):30
The Cenozoic volcanism of western Saudi Arabia extends from southern Yemen to Jordan northward. They cover an area of nearly 180,000 km2. The rocks are dominated by alkali olivine basalts and olivine basalts. Al-Wahbah crater, a part of Harrat Kishb, represents a model occurrence to study the gneisses of these rocks. New mineral chemistry and isotopic data are presented. It aims to follow the isotopic, mineralogical, and thermobarometry variations among these volcanics. Amphiboles of the studied volcanics belong to the monoclinic calcic group. The chemistry of the amphibole crystals shows two ranges of pressure. They are 3.6–5.6 and 0.38–0.78 kbar. The Aliv values of the amphiboles are in the range of 1.202 and 1.407, indicating corresponding temperature condition of 820–920 and 620–720 °C, respectively. The feldspar of the studied samples has the composition of plagioclase, though some grains have sanidine composition. They are formed in temperature range of 975 and 400 °C. The coexisting amphiboles and plagioclases indicate two sets of pressure and temperature. They are 540–575 °C (3.5–4 kbar) and 510–525 °C (~2 kbar), respectively. Rb–Sr isochron of the whole rock yields an age of 0.867 ± 0.160 Ma with initial Sr87/Sr86 of 0.702 ± 0.00086. The low initial ratio of Sr87/Sr86 together with positive values of εNd today implies that the studied volcanics have mantle source. Meanwhile, the present isotopic data suggest extraction of juvenile magma from asthenosphere source. The present study shows that the Al-Wahbah crater rocks belong to Cenozoic basalts and indicate EM-I-like signature. 相似文献
9.
Early Proterozoic supracrustal and plutonic rocks from the Gold Hill-Wheeler Peak area in northern New Mexico define three populations: amphibolite—diorite—tonalite, hornblendite—cumulus amphibolite and felsic volcanics and porphyries. Also present are mid-Proterozoic granites. Amphibolites are similar in Ti, Zr, Cr, Ni and REE contents to young calc-alkaline and arc basalts and diorites and tonalites are similar in composition to young andesites and to high-Al2O3 tonalites, respectively. Felsic volcanics resemble young felsic volcanics from mature arc systems in their immobile-element contents. Geochemical model studies suggest that the amphibolites, hornblendites, diorites and tonalites are related by progressive fractional crystallization of a hydrous parent tholeiite magma produced from partial melting of undepleted lherzolite. Amphibolites represent parent tholeiites modified by olivine removal. Hornblendite is an early solid residue comprised chiefly of hornblende, clinopyroxene, and olivine; diorite and cumulus amphibolite represent respectively residual solid (clinopyroxene, plagioclase, hornblende) and liquid, after 50% crystallization. Tonalite represents a residual liquid after 80% crystallization. Felsic volcanic rocks are produced by partial melting of a tonalite or diorite source with granulite-facies mineralogy in the lower crust. Granites have a similar origin to felsic volcanics although requiring an inhomogeneous source with the presence of residual hornblende or garnet.The calc-alkaline igneous rocks in the Gold Hill-Wheeler Peak area suggest the presence of an arc system in northern New Mexico during the Early Proterozoic. The fact that these rocks interfinger with and are overlain by mature clastic sediments favors a model in which a continental arc system is uplited, eroded and buried by cratonic sediments from the north. 相似文献
10.
Fractional crystallization of primitive,hydrous arc magmas: an experimental study at 0.7 GPa 总被引:4,自引:2,他引:2
Rohit H. Nandedkar Peter Ulmer Othmar Müntener 《Contributions to Mineralogy and Petrology》2014,167(6):1-27
Differentiation of mantle-derived, hydrous, basaltic magmas is a fundamental process to produce evolved intermediate to SiO2-rich magmas that form the bulk of the middle to shallow continental and island arc crust. This study reports the results of fractional crystallization experiments conducted in a piston cylinder apparatus at 0.7 GPa for hydrous, calc-alkaline to arc tholeiitic magmas. Fractional crystallization was approached by synthesis of starting materials representing the liquid composition of the previous, higher temperature experiment. Temperatures ranged from near-liquidus at 1,170 °C to near-solidus conditions at 700 °C. H2O contents varied from 3.0 to more than 10 wt%. The liquid line of descent covers the entire compositional range from olivine–tholeiite (1,170 °C) to high-silica rhyolite (700 °C) and evolves from metaluminous to peraluminous compositions. The following crystallization sequence has been established: olivine → clinopyroxene → plagioclase, spinel → orthopyroxene, amphibole, titanomagnetite → apatite → quartz, biotite. Anorthite-rich plagioclase and spinel are responsible for a marked increase in SiO2-content (from 51 to 53 wt%) at 1,040 °C. At lower temperatures, fractionation of amphibole, plagioclase and Fe–Ti oxide over a temperature interval of 280 °C drives the SiO2 content continuously from 53 to 78 wt%. Largest crystallization steps were recorded around 1,040 °C and at 700 °C. About 40 % of ultramafic plutonic rocks have to crystallize to generate basaltic–andesitic liquids, and an additional 40 % of amphibole–gabbroic cumulate to produce granitic melts. Andesitic liquids with a liquidus temperature of 1,010 °C only crystallize 50 % over an 280 °C wide range to 730 °C implying that such liquids form mobile crystal mushes (<50 % crystals) in long-lived magmatic systems in the middle crust, allowing for extensive fractionation, assimilation and hybridization with periodic replenishment of more mafic magmas from deeper magma reservoirs. 相似文献
11.
Plagioclase zoning as an indicator of magma processes at Bezymianny Volcano,Kamchatka 总被引:6,自引:1,他引:5
Vasily D. Shcherbakov Pavel Yu. Plechov Pavel E. Izbekov Jill S. Shipman 《Contributions to Mineralogy and Petrology》2011,162(1):83-99
Back-scattered electron (BSE)-derived zoning patterns of plagioclase phenocrysts are used to identify magma processes at Bezymianny
Volcano, Kamchatka, based on the 2000–2007 sequence of eruptive products. The erupted magmas are two-pyroxene andesites, which
last equilibrated at ~915°C temperature, 77–87 MPa pressure, and a water content of ~1.4 wt%. Textural and compositional zoning
of individual plagioclase phenocrysts typically includes a repeated core-to-rim sequence of oscillatory zoning (An50–60) truncated by a dissolution surface followed by an abrupt increase in An content (up to An85), which then gradually decreases rimward. This zoning pattern is interpreted to be the result of frequent replenishments
of the magma chamber which cause both thermal and chemical interaction between resident and recharge magmas. The outermost
70- to 150-μm-wide zoning patterns of plagioclase phenocrysts are composed of dissolution surface with a subsequent increase
in An and Fe contents. Zoning patterns of the rims exhibit correlation among plagioclase phenocrysts within one eruption.
Rims are interpreted as a result of crystallization of a batch of magma in the conduit after recharge event. 相似文献
12.
《Precambrian Research》1986,34(1):69-104
This investigation is based on detailed geological mapping of the western part of the Bolangir anorthosite massif of Orissa, India and its granulite borders, detailed petrography, whole-rock chemistry, mineralogy and an equilibrium thermodynamic analysis of the mineral phase relations. Structural analysis of the foliations of the granulites and the primary flow layers and the joint system of the anorthositic rocks strongly indicates that the pluton was forcefully intruded into the granulitic cover with considerable stretching and extension and approached the form and structure of a schlieren dome. The anorthositic suite of rocks includes anorthositic norites (median plagioclase composition An75), noritic anorthosites (median plagioclase composition An70) and anorthosites (median plagioclase composition An52), while the bordering granulites include leptynites (K-feldspar + plagioclase + quartz + orthopyroxene + biotite + garnet + ilmenite), khondalites (K-feldspar + quartz + sillimanite + garnet + graphite + ilmenite ± biotite), basic granulites (plagioclase + diopsidic clinopyroxene + orthopyroxene + garnet + hornblende + ilmenite ± K-feldspar ± quartz ± magnetite) and calc-granulites (diopside + scapolite + calcite + garnet + microline + quartz + sphene ± magnetite ± apatite). The anorthositic rocks have a relatively high K2O/SiO2 ratio with the MgO/FeO ratio mainly between 1 and 2. The MgO/FeO vs. plagioclase/mafics relations of the anorthositic suite indicate the fractionation trend: anorthositic norite → noritic anorthosite → anorthosite.The calculated P−T curves for nine different mineral equilibria in the anorthosites and the granulites converge to a broad cluster within the region, 3–7 kbar and 600–740°C. The orthopyroxene—garnet thermometer (Harley) and orthopyroxene—plagioclase—garnet—quartz barometer (Newton and Perkins) restrict the convergence to a slightly narrower P−T region: 4.7–7 kbar and 620–740°C. The two-pyroxene equilibria were possibly quenched at a somewhat higher temperature region and the temperature spread of the order of 200°C at pressures between 4.7 and 7 kbar may represent the P−T path over which the pluton cooled in the final stage of its evolution. The parent magma of the anorthosites, believed to be coeval with the 1312 Ma old Chilka Lake massif anorthosites of Orissa, may have formed under a Proterozoic continental crust of well over 20 km thickness. 相似文献
13.
《Journal of African Earth Sciences》1999,28(3):721-741
Gabbroic intrusions of the El-Aradiya area are a part of the Neoproterozoic basement cropping out in the central Eastern Desert of Egypt. They are composed mainly of gabbroic cumulates (diopside-plagioclase cumulate and plagioclase-augite cumulate) and fine-grained noncumulate gabbro. Mineral chemistry data indicate that the plagioclase core compositions of the gabbroic cumulates range between An90 and An60, whereas fine-grained noncumulate gabbro plagioclase core compositions are An61−56 and rim compositions are An54−42. The clinopyroxenes are diopside and augite in the gabbroic cumulate, and augite in the fine-grained noncumulate gabbro. Chemical re-equilibration between pyroxenes of gabbroic cumulates vary from 1150-900°C and for fine-grained noncumulate gabbro range from 1200-1100°C. The amphiboles are calcic, varying from tschermakite and tschermakitic hornblende, and Mg-hornblende in the gabbroic cumulate and only Mg-hornblende in the fine-grained noncumulate gabbro. They indicate an island-arc tholeiitic setting for gabbroic intrusions of the El-Aradiya area. Major and trace element data suggest arc tholeiite characters, a comagmatic suite and subduction-related magma with enrichment of LILE and depletion in HFSE relative to MORB. The estimated parent magma is similar to tholeiitic Aleutian arc primary magma. The gabbroic intrusions are analogous to intrusions emplaced in an immature island-arc setting in which the oceanic crust was thin. 相似文献
14.
Mafic dykes of Almora region intrude the Precambrian crystalline rocks of Kumaun Lesser Himalaya. Mafic dykes exhibit fine grained margin and medium to coarse grained core, melanocratic, low to highly ferromagnetic (MS=0.85?38.58×10?3SI) in nature commonly showing subophitic to ophitic textures with ol-pl-cpx-hbl-bt-mt-ap-sp assemblage, and modally correspond to leucogabbro and olivinegabbro (sensu stricto). Olivine (Fo61-Fo33), clinopyroxene (Wo46-En42-Fs22 to Wo40-En36-Fs15) and plagioclase (An58-An12) have crystallized in the temperature range of ca1400–980°C at pressure <2 kbar in an olivine tholeiitic basalt parent. Low acmite (Napfu=0.033?0.025), (Mg#=0.64–0.82), Ti-Al contents of clinopyroxenes and their evolution along enstatite-ferrosilite join (i.e. Mg?Fe substitution) strongly suggest tholeiitic nature of mafic dyke melt with changing activities of alumina and silica. Clinopyroxene compositions of mafic dykes differ markedly as compared to those observed for adjoining Bhimtal volcanics but closely resemble to that crystallized in tholeiitic melts of Deccan province. Observed Cr vs Mg# variation, enriched LILE (Sr, Ba)-LREE and positive Eu-anomaly of the studied mafic dykes are indicative of fractional crystallization of olivine-clinopyroxene -plagioclase from a crustally-contaminated tholeiitic basalt magma derived from enriched mantle source. The mafic dykes of Almora are geochemically identical to mafic dykes of Nainital, but are unrelated to Precambrian mafic volcanic flow and dykes of NW Himalaya and dykes of Salma and Rajmahal regions. 相似文献
15.
The conditions under which rear-arc magmas are generated were estimated using primary basalts from the Sannome-gata volcano, located in the rear of the NE Japan arc. Scoriae from the volcano occur with abundant crustal and mantle xenoliths, suggesting that the magma ascended rapidly from the upper mantle. The scoriae show significant variations in their whole-rock compositions (7.9–11.1 wt% MgO). High-MgO scoriae (MgO > ~9.5 wt%) have mostly homogeneous 87Sr/86Sr ratios (0.70318–0.70320), whereas low-MgO scoriae (MgO < ~9 wt%) have higher 87Sr/86Sr ratios (>0.70327); ratios tend to increase with decreasing MgO content. The high-MgO scoriae are aphyric, containing ~5 vol% olivine microphenocrysts with Mg# [100 × Mg/(Mg + Fe2+)] of up to 90. In contrast, the low-MgO scoriae have crustal xenocrysts of plagioclase, alkali feldspar, and quartz, and the mineralogic modes correlate negatively with whole-rock MgO content. On the basis of these observations, it is inferred that the high-MgO scoriae represent primary or near-primary melts, while the low-MgO scoriae underwent considerable interaction with the crust. Using thermodynamic analysis of the observed petrological features of the high-MgO scoriae, the eruption temperature of the magmas was constrained to 1,160–1,220 °C. Given that the source mantle was depleted MORB-source mantle, the primary magma was plausibly generated by ~7 % melting of a garnet-bearing spinel peridotite; taking this into consideration, and considering the constraints of multi-component thermodynamics, we estimated that the primary Sannome-gata magma was generated in the source mantle with 0.5–0.6 wt% H2O at 1,220–1,230 °C and at ~1.8 GPa, and that the H2O content of the primary magma was 6–7 wt%. The rear-arc Sannome-gata magma was generated by a lower degree of melting of the mantle at greater depths and lower temperatures than the frontal-arc magma from the Iwate volcano, which was also estimated to be generated by ~15 % melting of the source mantle with 0.6–0.7 wt% H2O at ~1,250 °C and at ~1.3 GPa. 相似文献
16.
The evolution of a carbonated nephelinitic magma can be followed by the study of a statistically significant number of melt inclusions, entrapped in co-precipitated perovskite, nepheline and magnetite in a clinopyroxene- and nepheline-rich rock (afrikandite) from Kerimasi volcano (Tanzania). Temperatures are estimated to be 1,100°C for the early stage of the melt evolution of the magma, which formed the rock. During evolution, the magma became enriched in CaO, depleted in SiO2 and Al2O3, resulting in immiscibility at ~1,050°C and crustal pressures (0.5–1 GPa) with the formation of three fluid-saturated melts: an alkali- and MgO-bearing, CaO- and FeO-rich silicate melt; an alkali- and F-bearing, CaO- and P2O5-rich carbonate melt; and a Cu–Fe sulfide melt. The sulfide and the carbonate melt could be physically separated from their silicate parent and form a Cu–Fe–S ore and a carbonatite rock. The separated carbonate melt could initially crystallize calciocarbonatite and ultimately become alkali rich in composition and similar to natrocarbonatite, demonstrating an evolution from nephelinite to natrocarbonatite through Ca-rich carbonatite magma. The distribution of major elements between perovskite-hosted coexisting immiscible silicate and carbonate melts shows strong partitioning of Ca, P and F relative to FeT, Si, Al, Mn, Ti and Mg in the carbonate melt, suggesting that immiscibility occurred at crustal pressures and plays a significant role in explaining the dominance of calciocarbonatites (sövites) relative to dolomitic or sideritic carbonatites. Our data suggest that Cu–Fe–S compositions are characteristic of immiscible sulfide melts originating from the parental silicate melts of alkaline silicate–carbonatite complexes. 相似文献
17.
Mafic enclaves in the 1991–1995 dacite of Unzen volcano show chemical and textural variability, such as bulk SiO2 contents ranging from 52 to 62 wt% and fine- to coarse-grained microlite textures. In this paper, we investigated the mineral chemistry of plagioclase and hornblende microlites and distinguished three enclave types. Type-I mafic enclaves contain high-Mg plagioclase and low-Cl hornblende as microlites, whereas type-III enclaves include low-Mg plagioclase and high-Cl hornblende. Type-II enclaves have an intermediate mineral chemistry. Type-I mafic enclaves tend to show a finer-grained matrix, have slightly higher bulk rock SiO2 contents (56–60 wt%) when compared with the type-III mafic enclaves (SiO2?=?53–59 wt%), but the overall bulk enclave compositions are within the trend of the basalt–dacite eruptive products of Quaternary monogenetic volcanoes around Unzen volcano. The origin of the variation of mineral chemistry in mafic enclaves is interpreted to reflect different degree of diffusion-controlled re-equilibration of minerals in a low-temperature mushy dacitic magma reservoir. Mafic enclaves with a long residence time in the dacitic magma reservoir, whose constituent minerals were annealed at low-temperature to be in equililbrium with the rhyolitic melt, represent type-III enclaves. In contrast, type-I mafic enclaves result from recent mafic injections with a mineral assemblage that still retains the high-temperature mineral chemistry. Taking temperature, Ca/(Ca?+?Na) ratio of plagioclase, and water activity of the hydrous Unzen magma into account, the Mg contents of plagioclase indicate that plagioclase microlites in type-III enclaves initially crystallized at high temperature and were subsequently re-equilibrated at low-temperature conditions. Compositional profiles of Mg in plagioclase suggest that older mafic enclaves (Type-III) had a residence time of ~100 years at 800 °C in a stagnant magma reservoir before their incorporation into the mixed dacite of the 1991–1995 Unzen eruption. Presence of different types of mafic enclaves suggests that the 1991–1995 dacite of Unzen volcano tapped mushy magma reservoir intermittently replenished by high-temperature mafic magmas. 相似文献
18.
A. K. Dwivedi U. K. Pandey C. Murugan A. K. Bhatt P. V. Ramesh Babu Mallikarjun Joshi 《Journal of the Geological Society of India》2011,77(6):527-538
The Barabazar granite, exposed at the northern margin of Singhbhum craton, Eastern India, occurs along the South Purulia Shear
Zone (SPSZ) and is emplaced into the Palaeoproterozoic metapelites and felsic volcanics of Singhbhum Group. Geochemical, petrographical
and geochronological studies on the Barabazar granite addressed in the work have wide implications on understanding the geodynamics
of SPSZ during Palaeoproterozoic to Mesoproterozoic. Geochemically, Barabazar granite displays limited range of major oxides,
alkali enrichment and highly fractionated features (SiO2 > 75%; Eu/Eu* = 0.16–0.33; enrichment of K, Rb, Th, U and Nb; depletion of Ba, Sr, P and Ti). It is predominantly peraluminous
(molar Al2O3/CaO+Na2O+K2O (A/CNK) =1.14–144) and contains abundant alkali feldspar, perthite, and minor plagioclase, biotite and accessory minerals.
Geochemical and petrological data indicates that it is A-type granite, which formed in ‘Within plate granite’ tectonic set
up. The Barabazar granite was emplaced at ca. 1771 Ma (Pb-Pb) in rift related environs and evolved by partial melting of stabilized
lower/middle crust (initial 87Sr/86Sr = 0.7302 ± 0.0066 and μ1 = 8.5 ± 0.5). Subsequently, the shear zone (SPSZ) developed during the closure of the riftogenic basin and was reactivated
during the Grenvillian orogeny (Ca. 900–1300 Ma), resulting in rehomogenisation of the strontium isotopes and thereby yielding
younger whole-rock Rb-Sr isotope age of c. 971 Ma for the Barabazar granite. Probably during this tectonic event, the Singhbhum
craton (Southern India Shield) would have finally juxtaposed with Northern Indian Shield along Central Indian Tectonic Zone
(CITZ) during the global Grenvillian orogeny. 相似文献
19.
The geological and metallogenic history of the Singhbhum Craton of eastern India is marked by several episodes of volcanism, plutonism, sedimentation and mineralization spanning from Paleoarchean to Mesoproterozoic in a dynamic tectonic milieu. Distinct signatures of this Archean-Proterozoic geodynamic process are preserved in discrete crustal provinces that constitute the Singhbhum Craton. Here we report new major, trace and PGE geochemical data from the ~ 3.4 Ga Iron Ore Group (IOG) volcanic rocks of the Jamda-Koira basin, a part of the BIF-bearing volcano-sedimentary sequences of the Noamundi-Jamda-Koira iron ore basin in the western part of Singhbhum Granite (SBG), and ~ 2.25 Ga metavolcanic rocks of Malangtoli. The IOG and Malangtoli volcanic rocks are porphyritic basalts and despite belonging to different ages, they exhibit similar mineralogical composition marked by clinopyroxene, plagioclase (present as both phenocryst and groundmass), opaques and volcanic glass (restricted to groundmass). The igneous mineralogy of these rocks has been overprinted by greenschist to lower amphibolite grade of metamorphism. The Malangtoli samples show low and high MgO compositional varieties. Immobile trace element compositions classify the IOG samples as andesite having a calc-alkaline composition, whereas the Malangtoli rocks correspond to basalt and andesite displaying a tholeiitic to calc-alkaline trend. The IOG basalts show low to moderate PGE contents marked by 26.23–68.35 ppb of ΣPGE, whereas the Malangtoli basalts display a moderate to high concentration of PGE (ΣPGE = 43.01–190.43 ppb). The studied samples have relatively enriched ΣPPGE ranging from 24.1–63.3 ppb (IOG) and 34–227.3 ppb (Malangtoli) against 2.2–4.1 ppb and 1.9–8.9 ppb ΣIPGE contents respectively. PPGE/IPGE ratios for IOG and Malangtoli samples range from 7.7–17.6 and 4.8–59.9. HFSE, REE and PGE compositions suggest a low degree (< 1 to 1%) of partial melting in the garnet lherzolite domain for the generation of IOG volcanic rocks. The parental magma of the Malangtoli basalts were generated by lower to higher degrees (3–< 10%) of mantle melting at depths corresponding to spinel to garnet lherzolite regime. Trace element (Zr/Nb, Th/Ta, Th/Nb, Ni/Cu) and PGE (Pd/Ir, Pd/Pt, Cu/Pd, Ni/Pd, Cu/Ir) ratios corroborate a sulphide saturated and PGE depleted character of IOG volcanic rocks that underwent crustal assimilation. In contrast, the high MgO Malangtoli basalts exhibit sulphide undersaturated, PGE undepleted nature devoid of crustal contamination whereas the low MgO Malangtoli basalts are sulphide saturated, PGE depleted and crustally contaminated. The IOG volcanic rocks correspond to intraoceanic arc with polygenetic crustal signatures, and show affinity towards arc-generated calc-alkaline basalts. The low- and high MgO basalts of Malangtoli are affiliated to transitional arc to rift-controlled back arc tectonic setting in a basinal environment that developed proximal to an active convergent margin. 相似文献
20.
Storage conditions of Bezymianny Volcano parental magmas: results of phase equilibria experiments at 100 and 700 MPa 总被引:1,自引:1,他引:0
Renat R. Almeev Francois Holtz Alexei A. Ariskin Jun-Ichi Kimura 《Contributions to Mineralogy and Petrology》2013,166(5):1389-1414
The crystallization sequence of a basaltic andesite from Bezymianny Volcano, Kamchatka, Russia, was simulated experimentally at 100 and 700 MPa at various water activities (aH2O) to investigate the compositional evolution of residual liquids. The temperature (T) range of the experiments was 950–1,150 °C, aH2O varied between 0.1 and 1, and the log of oxygen fugacity (fO2) varied between quartz–fayalite–magnetite (QFM) and QFM + 4.1. The comparison of the experimentally produced liquids and natural samples was used to constrain the pressure (P)–T–aH2O–fO2 conditions of the Bezymianny parental magma in the intra-crustal magma plumbing system. The phase equilibria constraints suggest that parental basaltic andesite magmas should contain ~2–2.5 wt% H2O; they can be stored in upper crustal levels at a depth of ~15 km, and at this depth they start to crystallize at ~1,110 °C. The subsequent chemical evolution of this parental magma most probably proceeded as decompressional crystallization occurred during magma ascent. The final depths at which crystallization products accumulated prior to eruption are not well constrained experimentally but should not be shallower than 3–4 km because amphibole is present in natural magmas (>150 MPa). Thus, the major volume of Bezymianny andesites was produced in a mid-crustal magma chamber as a result of decompressional crystallization of parental basaltic andesites, accompanied by mixing with silicic products from the earlier stages of magma fractionation. In addition, these processes are complicated by the release of volatiles due to magma degassing, which occurs at various stages during magma ascent. 相似文献