Methane, ethane, and mixed clouds in Titan's atmosphere: Properties derived from microphysical modeling

Theoretical arguments point to and recent observations confirm the existence of clouds in Titan's atmosphere, yet we possess very little data on their particle size, composition and formation mechanism. A time-dependent microphysical model is used to study the evolution of ice clouds in Titan's atmosphere. The model simulates nucleation, condensational growth, evaporation, coagulation, and transport of particles in a column of atmosphere. A variety of cloud compositions are studied, including pure ethane clouds, pure methane clouds, and mixed methane-ethane clouds (all with tholin cores). The abundance of methane cloud particles may be limited by the number of ethane coated tholin nuclei rather than the number of tholins with hydrocarbon coatings. However, even the condensation of methane onto these relatively sparse ethane/tholin cloud particles is sufficient to keep the methane close to saturation. Typical methane supersaturations are of order 0.06 on the average. For simulations which take into account recent lab measurements indicating it is relatively easy for methane to nucleate onto tholin particles without an ethane-layer present, the three types of clouds (methane, ethane, and mixed) exist simultaneously. Pure methane clouds are the most abundant cloud type and serve to lower the supersaturation to about 0.04. Cloud production does not require a continuous surface source of methane. However, clouds produced by mean motions are not the visible methane clouds seen in recent Cassini and ground-based observations. Ethane clouds in the troposphere almost instantaneously nucleate methane to form mixed clouds. However, a thin ethane ‘haze’ remains just above the tropopause for some scenarios and the mixed clouds at the tropopause remain ?50% ethane by mass. Also, evaporation of methane from the mixed cloud particles near the surface leaves a thicker layer of ethane cloud particles at ∼10 km. Nevertheless, the precipitation rate of methane to Titan's surface is between 0.001 and 0.5 cm/terrestrial-year, depending on various initial conditions such as critical saturation, size and abundance of cloud condensation nuclei, surface sources and eddy diffusion.     

Seasonal cycle of water vapor in the atmosphere of mars as revealed from the MAWD/<Emphasis Type="Italic">Viking 1</Emphasis> and <Emphasis Type="Italic">2</Emphasis> experiment

The most detailed information on the seasonal evolution of water vapor distribution in the Martian atmosphere was obtained by the Mars Atmospheric Water Detector (MAWD), which was a five-channel spectrometer operating aboard the Viking 1 and 2 spacecraft in 1977–1980, and from the very recent observations by the Thermal Emission Spectrometer (TES) on the Mars Global Surveyor spacecraft. The TES results show a considerably larger amount of water vapor near the perihelion of Mars (summer in the southern hemisphere) than the estimates based on the MAWD data for this season, which is characterized by the development of global dust storms. The TES and MAWD instruments operated in different spectral regions (20–50 m and 1.38 m, respectively), and this could result in the aforementioned difference because of the effect of aerosol scattering on the intensity of the H₂O bands, which becomes significant at short wavelengths. We considered the effect of aerosol scattering on the water vapor content measured in the 1.38-m band, taking into account the different geometries of observations, and restored the H₂O content from the MAWD data with allowance for multiple scattering. We obtained a seasonal and spatial distribution of water vapor that showed better agreement with the TES data and, thus, indicated the stability of the hydrological cycle on Mars. Periodic structures, which could possibly be associated with the influence of the stationary planetary waves, are reliably revealed in the zonal distribution of the atmospheric water vapor. The seasonal variability of the wave structures correlates with variations of the latitude gradient of water vapor. This could indicate that wave processes contribute considerably to the meridional water transport in the Martian atmosphere.Translated from Astronomicheskii Vestnik, Vol. 38, No. 6, 2004, pp. 483–496.Original Russian Text Copyright © 2004 by Fedorova, Rodin, Baklanova.     

A 1D microphysical cloud model for Earth,and Earth-like exoplanets: Liquid water and water ice clouds in the convective troposphere

One significant difference between the atmospheres of stars and exoplanets is the presence of condensed particles (clouds or hazes) in the atmosphere of the latter. In current 1D models clouds and hazes are treated in an approximate way by raising the surface albedo, or adopting measured Earth cloud properties. The former method introduces errors to the modeled spectra of the exoplanet, as clouds shield the lower atmosphere and thus modify the spectral features. The latter method works only for an exact Earth-analog, but it is challenging to extend to other planets.The main goal of this paper is to develop a self-consistent microphysical cloud model for 1D atmospheric codes, which can reproduce some observed properties of Earth, such as the average albedo, surface temperature, and global energy budget. The cloud model is designed to be computationally efficient, simple to implement, and applicable for a wide range of atmospheric parameters for planets in the habitable zone.We use a 1D, cloud-free, radiative–convective, and photochemical equilibrium code originally developed by Kasting, Pavlov, Segura, and collaborators as basis for our cloudy atmosphere model. The cloud model is based on models used by the meteorology community for Earth’s clouds. The free parameters of the model are the relative humidity and number density of condensation nuclei, and the precipitation efficiency. In a 1D model, the cloud coverage cannot be self-consistently determined, thus we treat it as a free parameter.We apply this model to Earth (aerosol number density 100 cm^?3, relative humidity 77%, liquid cloud fraction 40%, and ice cloud fraction 25%) and find that a precipitation efficiency of 0.8 is needed to reproduce the albedo, average surface temperature and global energy budget of Earth. We perform simulations to determine how the albedo and the climate of a planet is influenced by the free parameters of the cloud model. We find that the planetary climate is most sensitive to changes in the liquid water cloud fraction and precipitation efficiency.The advantage of our cloud model is that the cloud height and the droplet sizes are self-consistently calculated, both of which influence the climate and albedo of exoplanets.     

Optical and chemical properties of atmospheric organic aerosols

In the light of recent field and laboratory measurements we developed a structural and chemical model for organic atmospheric aerosols. The model organic aerosol consists of an aqueous core surrounded by a hydrophobic organic layer of biological origin. The role of organic aerosols is to concentrate organic materials at the surface and transport these organic molecules in the atmosphere. The nascent hydrophobic organic aerosol is not expected to nucleate clouds efficiently. Processing by atmospheric radicals creates hydrophilic sites on the surface. The processed, aged organic aerosol is expected to accommodate water and form cloud condensation nuclei. Processing of organic atmospheric aerosols implicates them in atmospheric radiative transfer.     

Salten Skov I: A Martian magnetic dust analogue

A fine grained magnetic iron oxide precipitate found in Denmark has been studied with regard to grain size, magnetic properties, aerosol transport, grain electrification, aggregation and optical reflectance. It has shown itself to be a good Martian dust analogue. The fraction of the Salten Skov I soil sample <63 μm was separated from the natural sample by dry sieving. This fraction could be dispersed by ultrasonic treatment into grains of diameter ～1 μm, in reasonable agreement with suspended dust grains in the Martian atmosphere estimated from the Viking, Pathfinder and Mars Exploration Rover missions. Though mineralogical and chemical differences exist between this analogue and Martian dust material, in wind tunnel experiments many of the physical properties of the atmospheric dust aerosol are reproduced.     

Microphysical modeling of ethane ice clouds in titan’s atmosphere

A time-dependent microphysical model is used to study the evolution of ethane ice clouds in Titan’s atmosphere. The model simulates nucleation, condensational growth, evaporation, coagulation, and transport of particles. For a critical saturation of 1.15 (a lower limit, determined by laboratory experiments), we find that ethane clouds can be sustained between altitudes of 8 and 50 km. Growth due to coalescence is inefficient, limiting the peak in the size distribution (by number) to 10 μm. These clouds vary with a period of about 20 days. This periodicity disappears for higher critical saturation values where clouds remain subvisible. Rainout of ethane due to methane cloud formation raises the altitude of the ethane cloud bottom to near the tropopause and may eliminate ethane clouds entirely if methane cloud formation occurs up to 30 km. However, clouds formed above the troposphere from other gases in Titan’s atmosphere could be sustained even with rainout up to 30 km. Although the optical depth of ethane clouds above 20 km is typically low, short-lived clouds with optical depths of order 0.1-1 can be created sporadically by dynamically driven atmospheric cooling. Ethane cloud particles larger than 25 μm can fall to the surface before total evaporation. However, ethane clouds remain only a small sink for tholin particles. At the peak of their cycle, the optical depth of ethane clouds could be comparable to that of tholin in the near-infrared, resulting in a 5% increase in Titan’s albedo for wavelengths between 1 and 2 μm. A number of factors limit our ablility to predict the ethane cloud properties. These factors include the mixing time in the troposphere, the critical saturation ratio for ethane ice, the existence of a surface reservoir of ethane, the magnitude and timing of dynamically driven temperature perturbations, and the abundance and life cycle of methane clouds.     

Meteoroid ablation models

The fate of entering meteoroids in atmosphere is determined by their size, velocity and substance properties. Material from ablation of small-sized meteors (roughly R≤0.01–1 cm) is mostly deposited between 120 and 80 km altitudes. Larger bodies (up to meter sizes) penetrate deeper into the atmosphere (down to 20 km altitude). Meteoroids of cometary origin typically have higher termination altitude due to substance properties and higher entry velocity. Fast meteoroids (V>30–40 km/s) may lose a part of their material at higher altitudes due to sputtering. Local flow regime realized around the falling body determines the heat transfer and mass loss processes. Classic approach to meteor interaction with atmosphere allows describing two limiting cases: – large meteoroid at relatively low altitude, where shock wave is formed (hydrodynamical models); – small meteoroid/or high altitudes – free molecule regime of interaction, which assumes no collisions between evaporated meteoroid particles. These evaporated particles form initial train, which then spreads into an ambient air due to diffusion. Ablation models should make it possible to describe physical conditions that occur around meteor body. Several self-consistent hydrodynamical models are developed, but similar models for transition and free molecule regimes are still under study. This paper reviews existing ablation models and discusses model boundaries.     

Infrared Spectroscopy of Micro-Organisms near 3.4 μm in Relation to Geology and Astronomy

Microorganisms sealed in KBr discs have an absorption spectrum over the 2.5–15 μm waveband that shows thermal stability as they are heated in an inert atmosphere to temperatures of about400 ^°C. Microfossils tightly sealed within cavities in rocks could be endowed with similar properties of thermal stability. The observed absorption of interstellar material along the line of sight from the solar system to the galactic centre is remarkably similar to the spectrum of dry micro-organisms over the 3.15–3.7 μm waveband. This revised version was published online in July 2006 with corrections to the Cover Date.     

TITAN’S GROUND REFLECTANCE RETRIEVAL FROM CASSINI-VIMS DATA TAKEN DURING THE JULY 2ND, 2004 FLY-BY AT 2 AM UT

An attempt to evaluate the preliminary values of the Titan's surface albedo at 2 μm from the first Cassini-VIMS observations of the moon is presented. The methodology is based on the application of radiative transfer calculations and a microphysical model of the Titan atmosphere based on fractal aerosol. As a first guess, the surface has been considered flat and lambertian. The results are presented as a function of the geographical coordinates associated to the image pixels. The libRadtran package, using the radiative transfer equation solver DISORT 2.0, has been applied for the calculations. A test run to evaluate the model performances, using ground based observations of Titan as reference in the range of wavelengths 0.3-1.0 μm, has been carried out.The retrieved values of the surface albedo range between 0.03 and 0.22.     

Noctilucent clouds: Simulation studies of their genesis,properties and global influences

The formation, evolution and properties of noctilucent clouds are studied using a timedependent one-dimensional model of ice particles at mesospheric altitudes. The model treats ice crystals, meteoric dust, water vapor and air ionization as fully interactive cloud elements. For ice particles, the microphysical processes of nucleation, condensation, coagulation and sedimentation are included; the crystal habits of ice are also accounted for. Meteoric dust is analyzed in the manner of Hunten et al. (1980). The simulated particle sizes range from 10 Å to 2.6μm. The chemistry of water vapor and the charge balance of the mesosphere are also analyzed in detail.Based on model calculations, including numerous sensitivity tests, several conclusions are reached. Extremely cold mesopause temperatures (<140K) are necessary to form noctilucent clouds; such temperatures only exist at high latitudes in summer. A water vapor concentration of 4–5 ppmv is sufficient to form a visible cloud. However, a subvisible cloud can exist in the presence of only 1 ppmv of H₂O. Ample cloud condensation nuclei are always present in the mesosphere; at very low temperatures, either meteoric dust or hydrated ions can act as cloud nuclei. To be effective, meteoric dust particles must be larger than 10–15 Å in radius. When dust is present, water vapor supersaturations may be held to such low values that ion nucleation is not possible. Ion nucleation can occur, however, in the absence of dust or at extremely low temperatures (<130K). While dust nucleation leads to a small number (<10cm^?3) of large ice particles (>0.05 μm radius) and cloud optical depths (at 550 nm) ～10^?4, ion nucleation generally leads to a large number (～10³cm^?3) of smaller particles and optical depths ～10^?5). However, because calculated nucleation rates in noctilucent clouds are highly uncertain, the predominant nucleus for the clouds (i.e., dust or ions) cannot be unambiguously established. Noctilucent clouds require several hours-up to a day-to materialize. Once formed, they may persist for several days, depending on local meteorological conditions. However, the clouds can disappear suddenly if the air warms by 10–20 K. The environmental conditions which exist at the high-latitude summer mesopause, together with the microphysics of small ice crystals, dictate that particle sizes will be ? 0.1 μm radius. The ice crystals are probably cubic in structure. It is demonstrated that particles of this size and shape can explain the manifestations of noctilucent clouds. Denser clouds are favored by higher water vapor concentrations, more rapid vertical diffusion and persistent upward convection (which can occur at the summer pole). Noctilucent clouds may also condense in the cold “troughs” of gravity wave trains. Such clouds are bright when the particles remain in the troughs for several hours or more; otherwise they are weak or subvisible.Model simulations are compared with a wide variety of noctilucent cloud data. It is shown that the present physical model is consistent with most of the measurements, as well as many previous theoretical results. Ambient noctilucent clouds are found to have a negligible influence on the climate of Earth. Anthropogenic perturbations of the clouds that are forecast for the next few decades are also shown to have insignificant climatological implications.     

Spectral imaging of martian water ice clouds and their diurnal behavior during the 1999 aphelion season (Ls = 130°)

We report high-spectral-resolution (λ/δλ = 800-2300) near-infrared mapping observations of Mars at L_s = 130° (April 1999), which were obtained by drift-scanning the cryogenic long-slit spectrometer at the KPNO 2.2-m telescope across the disk. Data were reformatted into calibrated spectral image cubes (x,y,λ) spanning 2.19 to 4.12 μm, which distinguish atmospheric CO₂ features, solar lines, and surface and aerosol features. Maps of relative band depth between 3.0 and 3.5 μm trace water ice clouds and show the diurnal evolution of features in the persistent northern summer aphelion cloud belt, which was mapped contemporaneously but at fixed local time by the Mars Global Surveyor Thermal Emission Spectrometer (MGS/TES). Cloud optical depth, particle sizes, and ice aerosol content were estimated using a two-stream, single-layer scattering model, with Mie coefficients derived from recently published ice optical constants, followed by a linear spectral deconvolution process. A comparison of data and model spectra shows evaporating nighttime clouds in the morning followed by afternoon growth of a prominent orographic cloud feature on the west flank of Elysium Mons. Cloud optical depth at 3.2 μm evolved to 0.28 ± 0.13 and ice aerosol column abundance to 0.9 ± 0.3 pr μm in the afternoon. Column abundances as large as 0.17 pr μm were retrieved in nonorographic clouds within the aphelion cloud band around midday. These clouds exhibit a modest decline in optical depth during the afternoon. Results show that ice particle radii from <2 μm to >4 μm exist in both cloud types. However, large particles dominate the spectra, consistent with recent MGS/TES emission phase function measurements of aphelion cloud aerosol properties.     

Polarimetry of Mars in High-Transparency Periods: How Reliable Are the Estimates of Aerosol Optical Properties?

The influence of various factors on the interpretation of polarimetric observations of Mars performed under high-transparency atmospheric conditions was investigated. It was demonstrated that the technique proposed by Morozhenko (1974) for the data interpretation does not allow the optical characteristics of cloud particles to be estimated unambiguously. In particular, it turns out that both the model of a thin layer composed of very small silicate particles and the model of very small ice particles in a thin layer fit the data of measurements at a phase angle of 25°. Numerical simulations showed that reliable information on the reflectance characteristics of the Martian surface in a wide spectral range, including blue and ultraviolet wavelengths, is necessary to obtain reliable estimates of aerosol optical properties. Our calculations confirmed that the scattering on ice-cloud particles could introduce a significant ambiguity in the interpretation of the available polarimetric data. Besides, small particles, both ice and silicate, existing in the upper atmospheric layer can substantially mask the layer of larger particles below, which becomes invisible for remote sensing.     

Near Infrared Spectra of two Asteroids with low Tisserand Invariant

We present near infrared reflectance spectra from 0.8 to 2.5 μm of two asteroids with low Tisserand invariant, 1373 Cincinnati and 2906 Caltech. We compare our spectra with cometary nuclei and other asteroids in their class. Asteroids Cincinnati and Caltech have Tisserand invariant values of 2.72 and 2.97, respectively, values less than 3 are considered suggestive of cometary origin. The observed spectral slopes in the near-infrared are consistent with both the spectra of cometary nuclei and of primitive asteroids. However, both asteroids have features in the near-infrared that are not seen in cometary nuclei, but are present in other X-type asteroids. 1373 Cincinnati has a sharp slope change between 0.75 and 1.0 μm and 2906 Caltech has a broad and shallow absorption between 1.35 and 2.2 μm. Our attempts to model the visible and near-infrared spectrum of these two objects, with the components successfully used by Emery and Brown (2004, Icarus 164, 104–121) to fit Trojan asteroids, did not yield acceptable fits.Visiting Astronomer at the Infrared Telescope Facility, which is operated by the University of Hawaii under contract to the National Aeronautics and Space Administration.     

A bulk cloud parameterization in a Venus General Circulation Model

A condensing cloud parameterization is included in a super-rotating Venus General Circulation Model. A parameterization including condensation, evaporation and sedimentation of mono-modal sulfuric acid cloud particles is described. Saturation vapor pressure of sulfuric acid vapor is used to determine cloud formation through instantaneous condensation and destruction through evaporation, while pressure dependent viscosity of a carbon dioxide atmosphere is used to determine sedimentation rates assuming particles fall at their terminal Stokes velocity. Modifications are described to account for the large range of the Reynolds number seen in the Venus atmosphere.Two GCM experiments initialized with 10 ppm-equivalent of sulfuric acid are integrated for 30 Earth years and the results are discussed with reference to “Y” shaped cloud structures observed on Venus. The GCM is able to produce an analog of the “Y” shaped cloud structure through dynamical processes alone, with contributions from the mean westward wind, the equatorial Kelvin wave, and the mid-latitude/polar Mixed Rossby/Gravity waves. The cloud top height in the GCM decreases from equator to pole and latitudinal gradients of cloud top height are comparable to those observed by Pioneer Venus and Venus Express, and those produced in more complex microphysical models of the sulfur cycle on Venus. Differences between the modeled cloud structures and observations are described and dynamical explanations are suggested for the most prominent differences.     

Micrometeorites and Their Implications for Meteors

Micrometeorites (MMs) are extraterrestrial dust particles, in the size range 25–400 μm, recovered from the Earth’s surface. They have experienced a wide range of heating during atmospheric entry from completely molten spherules to particles heated to temperatures <300°C that have retained low temperature minerals. The majority of MMs have mineralogies, textures and compositions that strongly resemble components from chondritic meteorites suggesting these correspond to sporadic, low geocentric velocity meteors. Changes in MMs due to entry heating, however, have implications for meteoric processes in general that may allow the observed behaviour of meteors to be directly related to the material properties of their meteoroids.     

Jupiter's ammonia clouds—localized or ubiquitous?

From an analysis of the Galileo Near Infrared Imaging Spectrometer (NIMS) data, Baines et al. (Icarus 159 (2002) 74) have reported that spectrally identifiable ammonia clouds (SIACs) cover less than 1% of Jupiter. Localized ammonia clouds have been identified also in the Cassini Composite Infrared Spectrometer (CIRS) observations (Planet. Space Sci. 52 (2004a) 385). Yet, ground-based, satellite and spacecraft observations show that clouds exist everywhere on Jupiter. Thermochemical models also predict that Jupiter must be covered with clouds, with the top layer made up of ammonia ice. For a solar composition atmosphere, models predict the base of the ammonia clouds to be at 720 mb, at 1000 mb if N/H were 4×solar, and at 0.5 bar for depleted ammonia of 10⁻²×solar (Planet. Space Sci. 47 (1999) 1243). Thus, the above NIMS and CIRS findings are seemingly at odds with other observations and cloud physics models. We suggest that the clouds of ammonia ice are ubiquitous on Jupiter, but that spectral identification of all but the freshest of the ammonia clouds and high altitude ammonia haze is inhibited by a combination of (i) dusting, starting with hydrocarbon haze particles falling from Jupiter's stratosphere and combining with an even much larger source—the hydrazine haze; (ii) cloud properties, including ammonia aerosol particle size effects. In this paper, we investigate the role of photochemical haze and find that a substantial amount of haze material can deposit on the upper cloud layer of Jupiter, possibly enough to mask its spectral signature. The stratospheric haze particles result from condensation of polycyclic aromatic hydrocarbons (PAHs), whereas hydrazine ice is formed from ammonia photochemistry. We anticipate similar conditions to prevail on Saturn.     

Thermal Emission From The Dust Coma Of Comet Hale-Bopp And The Composition Of The Silicate Grains

The dust coma of comet Hale-Bopp was observed in the thermal infrared over a wide range in solar heating (R = 4.9–0.9 AU) and over the full wavelength range from 3 μm to 160 μm. Unusual early activity produced an extensive coma containing small warm refractory grains; already at 4.9 AU, the 10 μm silicate emission feature was strong and the color temperature was 30% above the equilibrium blackbody temperature. Near perihelion the high color temperature, strong silicate feature, and high albedo indicated a smaller mean grain size than in other comets. The 8–13 μm spectra revealed a silicate emission feature similar in shape to that seen in P/Halley and several new and long period comets. Detailed spectral structure in the feature was consistent over time and with different instruments; the main peaks occur at 9.3, 10.0 and 11.2 μm. These peaks can be identified with olivine and pyroxene minerals, linking the comet dust to the anhydrous chondritic aggregate interplanetary dust particles. Spectra at 16–40 μm taken with the ISO SWS displayed pronounced emission peaks due to Mg-rich crystalline olivine, consistent with the 11.2 μm peak. This revised version was published online in July 2006 with corrections to the Cover Date.     

The retrieval of altitude profiles of the Martian aerosol microphysical characteristics from the limb measurements of the <Emphasis Type="Italic">Mars Express</Emphasis> OMEGA spectrometer

Parameterization of the spectral dependence of the optical characteristics of Martian aerosols has been proposed for processing the results of measurements of outgoing radiation. A method for retrieving the altitude profiles of the microphysical characteristics of Martian aerosols from the limb spectrometry of the OMEGA instrument of the Mars Express mission have been developed. For one of the observational sessions, the altitude profiles of the concentration and the modal radius of the size distribution function of aerosol particles retrieved with the proposed parameterization are presented. For the purpose of the interpretation of the data acquired from the optical remote sensing of planetary atmospheres, we consider how the spectral dependence of aerosol optical characteristics, in particular the volume coefficients of aerosol scattering and absorption and the phase function, can be parameterized in a specified, probably wide, spectral range. The method of such a parameterization has been proposed for the cases of a fixed chemical composition of the aerosol materials dominating in the atmosphere. It has been shown that these cases allow the required spectral dependences to be presented as a function of a small number of parameters, for which the parameters of the size distribution function of aerosol particles can be successfully used. However, since such direct calculations of the aerosol characteristics require an inadmissibly long period of time for the tasks of interpretation of the remote sensing data, an algorithm for organizing the parameterization function as a special, preliminary generated computer database has been suggested. This database provides the continuity in the dependence on the parameters, the specified computation accuracy, and the required output speed of the results. As a specific application, the parameterization of the spectral dependence of the optical characteristics of the Martian aerosols has been proposed for the tasks of processing the results of measurements of outgoing radiation. As a result, the method for retrieving the altitude profiles of the microphysical characteristics of Martian aerosols from the limb spectrometric measurements of the OMEGA instrument of the Mars Express mission has been developed. For one of the observational sessions, the altitude profiles of the concentration and the modal radius of the size distribution function of aerosol particles retrieved with the proposed parameterization are presented.