Geochemical evidence for consecutive accretion of oceanic fragments: The example of the Samarka Terrane,Sikhote-Alin

The data of geochemical study of Late Triassic cherts from tectonic–sedimentary complexes from different structural levels of the Samarka Terrane are reported. It is shown that the concentration and character of distribution of the major petrogenic oxides and minor and rare-earth elements in cherts of the upper and lower structural levels differ significantly, which results from differences in the facies environments of chert deposition. All the geochemical characteristics of cherts show that their deposition proceeded in the pelagic area of sedimentation, but in different parts. The Katen Complex composing the lower structural level is the most distant from the continental margin. The closest is the Amba-Matay Complex composing the upper structural level. Based on the geochemical and biostratigraphic data and the age of accretion of paleooceanic fragments, the length of the subducted oceanic plate (>6000 km) is calculated.     

The nature of the Palaeozoic oceanic basin at the southwestern margin of Gondwana and implications for the origin of the Chilenia terrane (Pichilemu region,central Chile)

The Coastal Accretionary Complex of central Chile constitutes the product of early Carboniferous to Late Triassic subduction at the rear of Chilenia, a continental terrane likely derived from Laurentia and accreted to southwestern margin of Gondwana during the Mid to Late Devonian. The complex contains basaltic metavolcanic sequences of the subducted oceanic lithosphere accreted to the active margin. In this paper, we address the tectonic setting of these rocks by means of a geochemical study in the coastal area of Pichilemu region, central Chile. The accreted fragments of oceanic crust occupy different structural levels, exhibit variable metamorphic grade, and have geochemical fingerprints that reveal a compositional heterogeneity of the subducted oceanic crust. The amphibolites have N to E-MORB compositions. Greenschist units include N-MORB and E-MORB transitional to OIB, and blueschists and greenschists interleaved within a single metavolcanosedimentary sequence have OIB signatures. Neodymium isotopic systematics indicate depleted and enriched mantle sources, whereas strontium isotopic systematics indicate seawater/rock interaction. The variety of rocks suggests formation in an oceanic setting characterized by shallow and deep mantle sources, such as plume-influenced ridge. Based on the geological, petrological, geochemical, and isotopic characteristics, we propose that the metavolcanic protoliths of the Pichilemu region formed relatively close to the western margin of the Chilenia terrane during the initial stage (late Cambrian–Early Devonian) of seafloor development and drifting of this continental block. Geochemical similarities with oceanic units accreted to the active margin south of the Pichilemu region indicate a regional pattern of the oceanic crust subducted under the Palaeozoic Chilean margin between, at least, 34°S and 39°S latitude, strongly supporting the activity of a mantle plume. This, in turn, can be correlated with the location of the Pacific plume generation zone in early Palaeozoic era, corroborating a Laurentian origin for the Chilenia terrane.     

Early Carboniferous High Ba‐Sr Granitoid in Southern Langshan of Northeastern Alxa: Implications for Accretionary Tectonics along the Southern Central Asian Orogenic Belt

Voluminous granitoids are widely distributed in the Langshan region, northeast of the Alxa block, and record the evolutionary processes of the southern Central Asian Orogenic Belt. The Dabashan pluton was emplaced into the Paleoproterozoic Diebusige complex. Early Carboniferous zircon LA-ICP MS U-Pb ages were from 327 Ma to 346 Ma. The Dabashan pluton can be classified as monzogranite and syenogranite, and exhibits high K2O contents and K2O/Na2O ratios, which reveal a high-K calc-alkaline nature. The samples display strongly fractionated REE patterns, and are enriched in large ion lithophile elements (LILE) relative to high field strength elements (HFSE). The Dabashan plutons display unusually high Ba (823–2817 ppm) and Sr (166–520 ppm) contents and K/Rb ratios (315–627), but low Rb/Ba ratios (0.02–0.14), and exhibit fertile zircon Hf isotopic compositions [εHf(t)=?14 to ?20], which are comparable to those of typical high Ba–Sr granitoids. Based on the geochemical compositions of the samples, we suggest that subducted sediments and ancient crustal materials both played important roles in their generation. Basaltic melts were derived from partial melting of subcontinental lithophile mantle metasomatized by subducted sediment-related melts with residual garnet in the source, which caused partial melting of ancient lower crust. Magmas derived from underplating ascended and emplaced in the middle–upper crust at different depths. The resultant magmas experienced some degree of fractional crystallization during their ascent. Given these geochemical characteristics, together with regional tectonic, magmatic, and structure analysis data, an active continental margin environment is proposed for the generation of these rocks.     

The Chemical Composition of Global Subducting Sediments and Its Geological Significance

Subducted sediments play an important role in crust-mantle interaction and deep mantle processes, especially for subduction zone magmatism and mantle geochemistry. The current rate of Global Subducting Sediments (GLOSS) is 0.5~0.7 km³/a. The GLOSS are composed of terrigenous material(76 wt.%), calcium carbonate(7 wt.%), opal(10 wt.%) and mineral-bound H₂O⁺(7 wt.%). The chemical compositions of GLOSS are similar to those of upper continental crust which is mainly controlled by the terrigenous materials, and yet the materials formed by marine processes will dilute the terrigenous materials. The components of subducted sediments are different among trenches. In the accretionary margin, the components of subducted sediments are similar to those of the upper crust, while in the non-accretionary margin the components are terrigenous materials plus those produced by marine processes. During subduction, subducted sediments will released fluids, melt or supercritical fluid to affect island arc/back-arc basin magmatism by means of aqueous fluid or sediment melt. In addition, a part of subducted sediments, together with underlying altered oceanic crust/lithosphere, recycle into the mantle and contribute to the mantle heterogeneity. Geochemical tracers indicate that subducted sediments play variable contributions to the magmatic processes in different tectonic setting. Thus, subducted sediments play an important role in two relatively independent dynamics systems (plate tectonics and mantle plume), as well as related mantle evolution models. As a result, by accurately calculating the compositions of subduction sediments and using various geochemical indicators, we can further limit the input and output fluxes of various elements or isotopes, and then obtain more accurately residual subducted components, which can provide us some important clues for geodynamic process.     

Geochemical modelling of early Eocene adakitic magmatism in the Eastern Pontides,NE Anatolia: continental crust or subducted oceanic slab origin?

Early Eocene adakitic volcanic and granitoid rocks are widespread in the Eastern Pontides of NE Turkey, providing significant constraints for the early Cenozoic tectonomagmatic evolution of the region. These adakitic rock units exhibit relatively high Sr/Y and La/Yb ratios, but low Y and Yb values, similar to modern adakites generated by partial fusion of a subducted oceanic slab. They also have high K₂O and low MgO contents, and show moderately enriched I_Sr and low ?_Nd(t) isotopic signatures. Our trace element modelling suggests that these adakitic magmas were generated from partial melting at low pressures of a garnet-bearing amphibolitic source in the continental lower crust. This lower crustal melting resulted from slab break off-induced asthenospheric upwelling and related magmatic underplating beneath the Eastern Pontides. We interpret this melting event and the adakitic magmatic activity as a syn- to post-collisional process involving early Cenozoic collision of the Pontide and Anatolide–Tauride continental blocks. The geochemical and tectonic constraints presented here indicate that early Eocene adakitic magmatism in the Eastern Pontides did not result from partial fusion of a subducted oceanic slab, but instead represent continental-type adakite formation.     

Generation of new continental crust by sublithospheric silicic-magma relamination in arcs: A test of Taylor's andesite model

The paradox of the Earth's continental crust is that although this reservoir is generally regarded as having differentiated from the mantle, it has an andesitic bulk composition that contrasts with the intrinsic basaltic composition of mantle-derived melts. Classical models for new crust generation from the mantle in two-stage processes fail to account for two fundamental facts: the absence of ultramafic residues in the lower crust and the hot temperature of batholith magma generation. Other models based on the arrival of already-fractionated silicic magmas to the crust have not received the necessary attention. Addition of new crust by relamination from below of subducted materials has been formulated as a process complementary to delamination of mafic residues. Here we show important support to relamination from below the lithosphere as an important mechanism for new crust generation in magmatic arcs of active continental margins and mature intraoceanic arcs. The new support is based on three independent lines: (1) thermo-mechanical modeling of subduction zones, (2) experimental phase relations and melt compositions of subducted materials and (3) geochemical relations between mafic granulites (lower crust) and batholiths (upper crust). The mineral assemblage and bulk geochemistry of lower crust rocks are compared with solid residues left after granite melt segregation. The implication is that an andesite magma precursor is responsible for the generation of new continental crust at active continental margins and mature oceanic arcs. According to our numerical and laboratory experiments, melting and eventual reaction with the mantle of subducted oceanic crust and sediments produce the andesite magmas. These ascend in the form of mantle wedge diapirs and are finally attached (relaminated) to the continental crust, where they crystallize partially and produce the separation of the solid fraction to form mafic granulites (lower crust) and granitic (sl) liquids to form the batholiths (upper crust).     

Geochemistry of basal Cambrian black shales and cherts from the Northern Tarim Basin,Northwest China: Implications for depositional setting and tectonic history

Black shales and thin-bedded cherts in the basal Cambrian are widespread worldwide and they carry important information on the formation of sedimentary basins and on the tectonic history. We studied the geochemical signatures of the early Cambrian black shales and bedded cherts from the Northern Tarim Basin, China, with the objectives of understanding the depositional setting of these rocks and inferring the tectonic history in the region. Twenty two black shales, ten cherts, and two nodular phosphorites were collected from two outcrops at Xiaoerbulake and Sugaitebulake in the Northern Tarim Basin, spanning vertical sections of 8.8 and 7.5 m, respectively. A suite of techniques, including field investigations, X-ray diffraction, electron microscopy, trace element, rare earth element (REE), and isotope geochemistry, were employed to characterize the geochemical signatures of these rocks. Field evidence indicates that the black shales and bedded cherts are over- and underlain by dolomites, suggesting a shallow marine depositional environment. Mineralogical and trace element data suggest that the Tarim black shales and cherts were deposited in a suboxic continental shelf environment, and hydrothermal activity may have extracted certain trace elements from mafic continental crust and concentrated them in the sedimentary basin. REE characteristics for the cherts are very similar to those that are known to be deposited in pelagic ocean floor settings, suggesting that the hydrothermal fluids may be derived from the infant southern Tianshan Ocean in the north of the Tarim Basin. Os isotope signatures at the time of deposition (¹⁸⁷Os/¹⁸⁸Os_i = 1.1–2.7) are typical of crustal signatures, and the radiogenic Os isotope signatures rule out the mantle as a possible source of Os and other metals. A positive correlation between ¹⁸⁷Os/¹⁸⁸Os and ε_Nd is consistent with upper crust-derived basin sediments that contain a variable contribution of hydrothermal fluids possibly derived from ancient mafic continental crust. These trace element, REE, and isotope systematics collectively suggest that incorporation of hydrothermal fluids derived from ancient, mafic continental crust combined with deposition in relatively reducing conditions may have controlled the chemical and isotopic compositions of these rocks. We infer that the hydrothermal fluid was carried to the continental shelf by upwelling during the initial stages of formation of the southern Tianshan Ocean, where the fluid interacted with thinned, mafic crustal basement lithologies and was subsequently incorporated into the black shales and bedded cherts in the Northern Tarim Basin. This study provides important geochemical evidence for the creation of the Tianshan Ocean, which is a result of break-up of the Rodinia Supercontinent during the early Cambrian.     

贵州独山地区二叠纪—三叠纪凝灰岩地球化学特征及其地质意义

本文对右江盆地北缘晚二叠世大隆组、早三叠世罗楼组中的凝灰岩夹层开展地质分析研究。镜下岩石学鉴定显示其为一套玻屑、晶屑凝灰岩;而其主量元素特征分析表明属流纹质、安山质凝灰岩,具高硅、高铝、高钾特征。结合稀土元素球粒陨石标准化分布型式图及微量元素原始地幔标准化蛛网图形态特征,Y、Nb、Rb、La、Pb及Ce等稀土、微量元素的比值特征,认为凝灰岩的岩浆来源与该时期发生在凭祥一带的中—酸性火山弧活动密切相关。构造背景属于古特提斯洋向北往华南陆块之下俯冲时,形成活动大陆边缘岛弧,弧后陆壳发生伸展活动形成右江盆地。岩浆来源于洋壳俯冲发生部分熔融,且尚未与地幔发生作用,在上升过程中与陆壳物质发生混染,由火山弧的活动喷发而来。     

Two-dimensional numerical modeling of tectonic and metamorphic histories at active continental margins

The evolution of an active continental margin is simulated in two dimensions, using a finite difference thermomechanical code with half-staggered grid and marker-in-cell technique. The effect of mechanical properties, changing as a function of P and T, assigned to different crustal layers and mantle materials in the simple starting structure is discussed for a set of numerical models. For each model, representative P–T paths are displayed for selected markers. Both the intensity of subduction erosion and the size of the frontal accretionary wedge are strongly dependent on the rheology chosen for the overriding continental crust. Tectonically eroded upper and lower continental crust is carried down to form a broad orogenic wedge, intermingling with detached oceanic crust and sediments from the subducted plate and hydrated mantle material from the overriding plate. A small portion of the continental crust and trench sediments is carried further down into a narrow subduction channel, intermingling with oceanic crust and hydrated mantle material, and to some extent extruded to the rear of the orogenic wedge underplating the overriding continental crust. The exhumation rates for (ultra)high pressure rocks can exceed subduction and burial rates by a factor of 1.5–3, when forced return flow in the hanging wall portion of the self-organizing subduction channel is focused. The simulations suggest that a minimum rate of subduction is required for the formation of a subduction channel, because buoyancy forces may outweigh drag forces for slow subduction. For a weak upper continental crust, simulated by a high pore pressure coefficient in the brittle regime, the orogenic wedge and megascale melange reach a mid- to upper-crustal position within 10–20 Myr (after 400–600 km of subduction). For a strong upper crust, a continental lid persists over the entire time span covered by the simulation. The structural pattern is similar in all cases, with four zones from trench toward arc: (a) an accretionary complex of low-grade metamorphic sedimentary material; (b) a wedge of mainly continental crust, with medium-grade HP metamorphic overprint, wound up and stretched in a marble cake fashion to appear as nappes with alternating upper and lower crustal provenance, and minor oceanic or hydrated mantle interleaved material; (c) a megascale melange composed of high-pressure and ultrahigh-pressure metamorphic oceanic and continental crust, and hydrated mantle, all extruded from the subduction channel; (d) zone represents the upward tilted frontal part of the remaining upper plate lid in the case of a weak upper crust. The shape of the P–T paths and the time scales correspond to those typically recorded in orogenic belts. Comparison of the numerical results with the European Alps reveals some similarities in their gross structural and metamorphic pattern exposed after collision. A similar structure may be developed at depth beneath the forearc of the Andes, where the importance of subduction erosion is well documented, and where a strong upper crust forms a stable lid.     

阿拉善宗乃山岩体东南缘花岗岩LA-ICP-MS锆石U-Pb年龄与地球化学特征

阿拉善宗乃山岩体东南缘分布多种类型的花岗岩,本文主要采用岩相学、激光剥蚀电感耦合等离子体质谱(LA-ICP-MS)锆石U-Pb定年、岩石地球化学等技术手段,对宗乃山岩体东南缘岩石类型、年代学、源岩特征以及构造背景进行了研究。结果表明:岩石类型主要为碱性-钙碱性准铝质花岗岩和闪长岩;单颗粒锆石分析获得黑云母斜长花岗岩年龄为236.8±1.9 Ma~249.7±2.6 Ma,片麻状花岗岩年龄为268.1±1.1 Ma,岩体成岩时期主要为华力西晚期和印支期早期,具有多期侵入的特征。该岩体岩石源岩为I型花岗岩,源于地壳火山弧区和同碰撞区,表明由于洋壳俯冲作用,在宗乃山东南缘形成了岛弧花岗岩侵入体。LA-ICP-MS锆石U-Pb定年技术为洋壳俯冲提供了年代学约束,确定了研究区碰撞时间为早于236.8±1.9 Ma。     

俯冲循环组分对大洋地幔不均一性的定量约束

大洋地幔内部存在广泛的不均一性,其成因可有多种模式,其中俯冲循环作用对地幔组成的变化具有重要影响. 为明确各循环组分对亏损地幔的改造作用及其在富集源区中的相对贡献,系统总结了不同循环组分（远洋沉积物、俯冲洋壳、陆壳）的平均微量元素特征,计算了各循环组分在俯冲过程中经历的化学变化. 基于改造后的循环组分,开展与亏损地幔源区的混合和熔融模拟. 结果表明,HIMU型玄武岩可以由纯俯冲洋壳（≤10%）与亏损地幔（≥90%）混合形成的源区,经较低程度熔融（0.5%~1.5%）形成;而EMI型玄武岩可以由俯冲洋壳（≤10%）、俯冲剥蚀的下陆壳物质（≤3%）、亏损地幔（≥90%）混合形成的源区,经较低程度熔融（1%~2%）形成;EMII型玄武岩可以由俯冲洋壳（≤10%）、GLOSS-II（全球俯冲沉积物）或上陆壳物质（≤0.8%）与亏损地幔（≥90%）混合形成的源区,经较低程度熔融（1%~1.5%）形成.      

Crustal xenoliths from Calbuco Volcano,Andean Southern Volcanic Zone: implications for crustal composition and magma-crust interaction

Crustal xenoliths in the 1961 andesite flow of Calbuco Volcano, in the southern Southern Volcanic Zone (SSVZ) of the Andes, consist predominantly of pyroxene granulites and hornblende gabbronorites. The granulites contain plagioclase+pyroxene+magnetite±amphibole, and have pronounced granoblastic textures. Small amounts of relict amphibole surrounded by pyroxene-plagioclase-magnetite-glass symplectites are found in some specimens. These and similar textures in the gabbronorites are interpreted as evidence of dehydration melting. Mineral and bulk rock geochemical data indicate that the granulites are derived from an incompatible trace element depleted basaltic protolith that underwent two stages of metamorphism: a moderate pressure, high temperature stage accompanied by melting and melt extraction from some samples, followed by thermal metamorphism after entrainment in the Calbuco andesite lavas. High _Nd ^T values (+4.0 to +8.6), Nd-isotope model ages of 1.7–2.0 Ga, and trace element characteristics like chondrite normalized La/Yb< and La/Nb1 indicate that the protoliths were oceanic basalts. Similar oceanic metabasalts of greenschist to amphibolite facies are found in the Paleozoic metamorphic belt that underlies the Chilean coastal ranges. Mineral and bulk rock compositions of the gabbronorite xenoliths indicate that they are cognate, crystallizing from the basaltic andesite magma at Calbuco. Crystallization pressures for the gabbros based on total Al contents in amphibole are 6–8 kbar. These pressures point to middle to lower crustal storage of the Calbuco magma. Neither granulite nor gabbro xenoliths have the appropriate geochemical characteristics to be contaminants of Calbuco andesites, although an ancient sedimentary contaminant is indicated by the lava compositions. The presence of oceanic metabasaltic xenoliths, together with the sedimentary isotopic imprint, suggests that the lower crust beneath the volcano is analogous to the coastal metamorphic belt, which is an accretionary complex of intercalated basalts and sediments that formed along the Paleozoic Gondwanan margin. If this is the case, the geochemical composition of the lower and middle crust beneath the SSVZ is significantly different from that of most recent SSVZ volcanic rocks.     

Middle Miocene near trench volcanism in northern Colombia: A record of slab tearing due to the simultaneous subduction of the Caribbean Plate under South and Central America?

Field, geochemical, geochronological, biostratigraphical and sedimentary provenance results of basaltic and associated sediments northern Colombia reveal the existence of Middle Miocene (13–14 Ma) mafic volcanism within a continental margin setting usually considered as amagmatic. This basaltic volcanism is characterized by relatively high Al₂O₃ and Na₂O values (>15%), a High-K calc-alkaline affinity, large ion lithophile enrichment and associated Nb, Ta and Ti negative anomalies which resemble High Al basalts formed by low degree of asthenospheric melting at shallow depths mixed with some additional slab input. The presence of pre-Cretaceous detrital zircons, tourmaline and rutile as well as biostratigraphic results suggest that the host sedimentary rocks were deposited in a platform setting within the South American margin. New results of P-wave residuals from northern Colombia reinforce the view of a Caribbean slab subducting under the South American margin.The absence of a mantle wedge, the upper plate setting, and proximity of this magmatism to the trench, together with geodynamic constraints suggest that the subducted Caribbean oceanic plate was fractured and a slab tear was formed within the oceanic plate. Oceanic plate fracturing is related to the splitting of the subducting Caribbean Plate due to simultaneous subduction under the Panama-Choco block and northwestern South America, and the fast overthrusting of the later onto the Caribbean oceanic plate.     

Fission track and fault kinematics analyses for new insight into the Late Cenozoic tectonic regime changes in West-Central Sulawesi (Indonesia)

A 3-D density model for the Cretan and Libyan Seas and Crete was developed by gravity modelling constrained by five 2-D seismic lines. Velocity values of these cross-sections were used to obtain the initial densities using the Nafe–Drake and Birch empirical functions for the sediments, the crust and the upper mantle. The crust outside the Cretan Arc is 18 to 24 km thick, including 10 to 14 km thick sediments. The crust below central Crete at its thickest section, has values between 32 and 34 km, consisting of continental crust of the Aegean microplate, which is thickened by the subducted oceanic plate below the Cretan Arc. The oceanic lithosphere is decoupled from the continental along a NW–SE striking front between eastern Crete and the Island of Kythera south of Peloponnese. It plunges steeply below the southern Aegean Sea and is probably associated with the present volcanic activity of the southern Aegean Sea in agreement with published seismological observations of intermediate seismicity. Low density and velocity upper mantle below the Cretan Sea with ρ  3.25 × 10³ kg/m³ and V_p velocity of compressional waves around 7.7 km/s, which are also in agreement with observed high heat flow density values, point out at the mobilization of the upper mantle material here. Outside the Hellenic Arc the upper mantle density and velocity are ρ ≥ 3.32 × 10³ kg/m³ and V_p = 8.0 km/s, respectively. The crust below the Cretan Sea is thin continental of 15 to 20 km thickness, including 3 to 4 km of sediments. Thick accumulations of sediments, located to the SSW and SSE of Crete, are separated by a block of continental crust extended for more than 100 km south of Central Crete. These deep sedimentary basins are located on the oceanic crust backstopped by the continental crust of the Aegean microplate. The stretched continental margin of Africa, north of Cyrenaica, and the abruptly terminated continental Aegean microplate south of Crete are separated by oceanic lithosphere of only 60 to 80 km width at their closest proximity. To the east and west, the areas are floored by oceanic lithosphere, which rapidly widens towards the Herodotus Abyssal plain and the deep Ionian Basin of the central Mediterranean Sea. Crustal shortening between the continental margins of the Aegean microplate and Cyrenaica of North Africa influence the deformation of the sediments of the Mediterranean Ridge that has been divided in an internal and external zone. The continental margin of Cyrenaica extends for more than 80 km to the north of the African coast in form of a huge ramp, while that of the Aegean microplate is abruptly truncated by very steep fractures towards the Mediterranean Ridge. Changes in the deformation style of the sediments express differences of the tectonic processes that control them. That is, subduction to the northeast and crustal subsidence to the south of Crete. Strike-slip movement between Crete and Libya is required by seismological observations.     

Triple oxygen isotope constraints on the origin of ocean island basalts

Understanding the origin of ocean island basalts (OIB) has important bearings on Earth’s deep mantle. Although it is widely accepted that subducted oceanic crust, as a consequence of plate tectonics, contributes material to OIB’s formation, its exact fraction in OIB’s mantle source remains ambiguous largely due to uncertainties associated with existing geochemical proxies. Here we show, through theoretical calculation, that unlike many known proxies, triple oxygen isotope compositions (i.e. Δ¹⁷O) in olivine samples are not affected by crystallization and partial melting. This unique feature, therefore, allows olivine Δ¹⁷O values to identify subducted oceanic crusts in OIB’s mantle source. Furthermore, the fractions of subducted ocean sediments and hydrothermally altered oceanic crust in OIB’s mantle source can be quantified using their characteristic Δ¹⁷O values. Based on published Δ¹⁷O data, we estimated the fraction of subducted oceanic crust to be as high as 22.3% in certain OIB, but the affected region in the respective mantle plume is likely to be limited.

     

Slab decarbonation and CO2 recycling in the Southwestern Colombian volcanic arc

The contribution of subducted carbonate sediments to the genesis of the Southwestern Colombian arc magmas was investigated using a comprehensive petrography and geochemical analysis, including determination of major and trace element contents and Sr, Nd, Hf and Pb isotope compositions. These data have been used to constrain the depth of decarbonation in the subducted slab, indicating that the decarbonation process continues into the sub-arc region, and ultimately becomes negligible in the rear arc. We propose on the basis of multi-isotope approach and mass balance calculations, that the most important mechanism to induce the slab decarbonation is the infiltration of chemically reactive aqueous fluids from the altered oceanic crust, which decreasingly metasomatize the mantle wedge, triggering the formation of isotopically different primary magmas from the volcanic front (VF) with relatively high ¹⁷⁶Hf/¹⁷⁷Hf, high ⁸⁷Sr/⁸⁶Sr, negative values of εNd and lower Pb isotopes compared to the rear arc (RA).The presence of more aqueous fluids at the volcanic front may increase the degree of decarbonation into carbonate-bearing lithologies. Moreover, with increasing pressure and temperature in the subduction system, the decrease in dehydration of the slab, leads to cessation of fluid-induced decarbonation reactions at the rear arc. This development allows the remaining carbonate materials to be recycled into the deep mantle.     

Continuous supply of recycled Pacific oceanic materials in the source of Cenozoic basalts in SE China: the Zhejiang case

Various enriched recycled oceanic components in the source of Cenozoic intra-plate alkaline basalts from eastern China were identified by previous studies. Due to the existence of a stagnant subducted Pacific slab in the mantle transition zone beneath eastern China, it is logical to connect the stagnant slab to the recycled oceanic materials. However, the recycled oceanic materials could also result from ancient subduction events (e.g., Paleo-Tethyan, Paleo-Asian or Izanagi plate subduction) because enriched geochemical signatures of a recycled slab can be preserved in the mantle for longer than 1 Gyr. Investigating the temporal variations of the recycled oceanic materials in the mantle source is a useful way to trace the origin of the basalts. In this article, we have conducted a detailed geochemical study, including major and trace elements and Sr–Nd–Pb isotopes, on two alkaline basalt groups from Zhejiang, SE China, which erupted 26–17 Ma and after 11 Ma, respectively. In particular, we recovered the H₂O content of the initial magmas based on the H₂O content of the clinopyroxene (cpx) phenocrysts and the partition coefficients of H₂O between cpx and basaltic melts. The H₂O contents of the Zhejiang basalts range from 1.3 to 2.6 (wt.%), which fall within the range of back-arc basin or island arc basalts. The older basalts are more alkaline and have lower Si and Al contents; higher trace element concentrations; higher La/Yb, Ce/Pb and Nb/La ratios; lower H₂O/Ce and Ba/Th ratios; and stronger negative K, Pb, Hf and Ti anomalies than the younger ones. The co-relationships between Ba/La, H₂O/Ce, Nb/La, Ce/Pb and Ba/Th in the two groups of the Zhejiang basalts indicate that a recycled dehydrated oceanic alkaline basalt component is needed in the source of the older rocks, along with a depleted mantle component. Meanwhile, an additional recycled dehydrated sediment component was required in the source of the younger rocks. The temporal change in the recycled oceanic materials in the mantle sources of Zhejiang Cenozoic basalts demonstrates that the recycled components can only originate in the stagnant Pacific slab that is the only plate subducted since 100 Ma in this area.     

华北克拉通北缘晚志留世末-早泥盆世钾质碱性岩的成因及对区域构造演化的限定

华北克拉通北缘晚志留世末-早泥盆世碱性岩的成因研究可以为古生代古亚洲洋与华北克拉通的相互作用过程提供重要信息.本文以内蒙古达茂旗黄合少正长岩为研究对象,开展了锆石U-Pb年代学、矿物化学、地球化学和Sr-Nd同位素的研究,并综合同带其他代表性岩体的岩石矿物及元素特征,探讨了华北克拉通北缘钾质碱性岩的岩浆体系性质、源区特...     

Rare earth element geochemistry of the Betts Cove ophiolite,Newfoundland: complexities in ophiolite formation

The Betts Cove ophiolite includes the components of typical ocean crust: pillow lavas, sheeted dikes, gabbros and ultramafics. However, the trace element geochemistry of basaltic rocks is unusual. Three geochemical units are recognized within the lava and dike members. Within the pillow lavas, the geochemical units correspond to stratigraphic units. Upper lavas have ‘normal’ (i.e., typical for ocean floor basalts) TiO₂ contents (0.75 to 2.0 wt%), heavy rare earth elements (HREE) values in the range 6–20× chondrites and chondrite-normalized REE patterns with relative LREE depletion. Intermediate lavas have TiO₂ contents between 0.30 and 0.50 wt%, HREE contents from 4–7× chondrites and extreme relative LREE depletion. Lower lavas have anomalously low TiO₂ contents (<0.30 wt%) and unusual convex-downwards REE patterns with REE abundances around 2–5 × chondrite. These geochemical differences can be explained if the three groups were derived from different mantle sources. Independent mantle sources for the three units are consistent with their different ${}^{143}\text{Nd}{}^{144}\text{Nd}$ ratios varying at 480 m.y.B.P. from 0.51222 in a lower lava to 0.51238 in an upper lava. The upper lavas may be partial melts of a source similar in composition to that of modern MORB, the intermediate lavas may be from a very depleted oceanic mantle (second stage melt), and the lower lavas may have formed by melting an extremely depleted mantle that had been invaded by a LREE-enriched fluid. A possible tectonic environment where these different sources could be juxtaposed is a back-arc or inter-arc basin.