The Planetary Fourier Spectrometer (PFS) onboard the European Mars Express mission

The Planetary Fourier Spectrometer (PFS) for the Mars Express mission is an infrared spectrometer optimised for atmospheric studies. This instrument has a short wave (SW) channel that covers the spectral range from 1700 to (1.2-) and a long-wave (LW) channel that covers 250- (5.5-). Both channels have a uniform spectral resolution of . The instrument field of view FOV is about 1.6^° (FWHM) for the Short Wavelength channel (SW) and 2.8^° (FWHM) for the Long Wavelength channel (LW) which corresponds to a spatial resolution of 7 and 12 km when Mars is observed from an height of 250  km. PFS can provide unique data necessary to improve our knowledge not only of the atmosphere properties but also about mineralogical composition of the surface and the surface-atmosphere interaction.The SW channel uses a PbSe detector cooled to 200-220 K while the LW channel is based on a pyroelectric (L_iT_aO₃) detector working at room temperature. The intensity of the interferogram is measured every 150 nm of physical mirrors displacement, corresponding to 600 nm optical path difference, by using a laser diode monochromatic light interferogram (a sine wave), whose zero crossings control the double pendulum motion. PFS works primarily around the pericentre of the orbit, only occasionally observing Mars from large distances. Each measurements take 4 s, with a repetition time of 8.5 s. By working roughly 0.6 h around pericentre, a total of 330 measurements per orbit will be acquired 270 looking at Mars and 60 for calibrations. PFS is able to take measurements at all local times, facilitating the retrieval of surface temperatures and atmospheric vertical temperature profiles on both the day and the night side.     

Calibration of the Planetary Fourier Spectrometer long wavelength channel

The Planetary Fourier Spectrometer (PFS) experiment on board the Mars Express mission has two channels covering the 1.2-5 μm (SWC) and the 5-50 μm (LWC). The Long Wavelength Channel (LWC) measures the thermal emission spectrum of Mars between 200 and 2000 cm⁻¹ with a spectral resolution of 1.4 cm⁻¹, in absence of apodisation. We present here the calibration of this channel and its performance. The instrument calibration has been performed on ground, before launch, in space during Near Earth Verification (NEV) measurements, and at Mars. Special attention has been given to the problem of microvibrations on board the spacecraft.In order to obtain correct results, the source-instrument-detector interaction is studied very accurately. The instrument variations during a pericentre pass impose a complex procedure for the LW channel calibration, but fortunately the procedure adopted seems to work well. Samples of the calibrated data are given (as single spectrum and as an average over a few spectra) to show the performance of the experiment and its scientific potentialities.     

Calibration of the Planetary Fourier Spectrometer short wavelength channel

The Planetary Fourier Spectrometer (PFS) experiment on board the Mars Express mission has two channels covering the 1.2-5.5 μm short wavelength channel (SWC) and the 5.5-45 μm (LWC). The SWC measures part of the thermal emission spectrum and the solar reflected spectrum of Mars between 1700 and 8200 cm⁻¹ with a spectral resolution of 1.3 cm⁻¹, in absence of apodisation. We present here the calibration of this channel and its performance. The instrument calibration has been performed on ground, before launch, in space during near earth verification (NEV) measurements, and at Mars. Special attention has been given to the problem of microvibrations on board the spacecraft.In order to obtain correct results, the source-instrument-detector interaction for the thermal part is studied very accurately. The instrument shows a nonlinear behaviour with source intensity. The SNR increases with amplification, hence high gain factors are usually used. The detector is, in space, cooled by a passive radiator, and works around 210-215 K. The calibration source (an internal lamp) shows variations during a pericentre pass and therefore impose a complex procedure for the SW channel calibration. Mechanical microvibrations strongly affect part of the spectrum. We discuss the validity of the present calibration, and indicate possible future developments. Samples of the calibrated data are given to show the performance of the experiment and its scientific potentialities.     

Analysis of disturbances in the Planetary Fourier Spectrometer through numerical modeling

Fourier transform spectrometers are instruments with high sensitivity to many kinds of disturbances. This study started from the analysis of the disturbances related to mechanical vibrations on the PFS FTIR spectrometer to show how the measured spectra can differ from the actual ones. The complete study, more in general, accounts for the characteristics of a real instrument and its operating environment to show, which can be the effects of many sources of disturbances on realistic measurements. The analysis is especially relevant when the spectra are used for the determination of parameters through “best fitting techniques” by matching with synthetic ones because it shows how spectral features used in these studies can be modified by disturbances. A previous work addressed the theoretical treatment of vibrations borne effects on FTIR spectrometers and is the ground work for the present; however, that study, being based on an analytical approach could only show examples of single effects on simplified input signals such as emission lines. This study conversely is based on a numerical model, developed in order to include altogether the effects addressed in the theoretical work to show combined effects on complex spectra like those expected from Mars. This allows not only to evaluate the linked effects of many kinds of disturbances but also to account for the real spectrometer characteristics. The use of synthetic spectra as input allows the comparison between expected spectra and measured ones. The simulation is tailored on the Planetary Fourier Spectrometer (PFS), onboard the ESA Mars Express spacecraft, from 2003 orbiting around Mars and in particular on its short wavelength (SW) channel, where many disturbances are more evident.     

Dust deposition at the Mars Pathfinder landing site: observations and modeling of visible/near-infrared spectra

Temporal variations in the visible/near-infrared reflectance spectra of the radiometric calibration targets on the Mars Pathfinder (MPF) lander obtained by the Imager for Mars Pathfinder (IMP) camera reveal the effects of aeolian dust deposition at the MPF site throughout the mission. Sky brightness models in combination with two-layer radiative transfer models were used with these data to track changes in dust opacity on the radiometric calibration targets (RCTs) to constrain the dust deposition rate and the spectral properties of the deposited dust. Two-layer models were run assuming both linear and nonlinear dust accumulation rates, and suggest that RCT dust optical depth at the end of the 83-sol mission was 0.08 to 0.16, or on the order of 5- to 10-μm thickness for plausible values for dust porosity and grain size. These values correspond to dust fall rates of about 20-45 μm per Earth year, consistent with previous studies of dust deposition on Mars. The single scattering albedos of the dust derived from the models fall between those previously determined for atmospheric dust and bright soils. Comparisons of relative reflectance spectra calibrated using observed RCT radiances from late in the mission versus using radiances from modeled (dust-free) RCTs also reveal distinct spectral differences consistent with dust on the RCTs. Temporal variations in RCT dust opacity are not clearly linked to known passages of vortices at the MPF site, but overall suggest that deposition of dust onto the targets by local dust devils may be favored over erosion. Analyses of temporal changes in visible/near-infrared spectra will provide valuable information for future missions by constraining how dust deposition affects landed spacecraft operability (e.g., solar power availability), instrument calibration, and interpretations of surface mineralogy and composition.     

Investigation of water vapor on Mars with PFS/SW of Mars Express

New insight into the seasonal, diurnal and spatial distribution of water vapor on Mars has been obtained from analyzing the spectra of the short-wavelength channel (SW) of the Planetary Fourier Spectrometer (PFS) onboard Mars Express. The processed dataset, recorded between January 2004 and April 2005, covers the seasons from LS=331° of Mars Year 26 to LS=196° of the following year. In this period the mean column density around vernal equinox was 8.2 pr. μm. The maximum values during northern summer were about 65 pr. μm, located around 75° N latitude with a longitudinally inhomogeneous distribution. Regarding the atmospheric transport, the majority of polar water vapor remains in the north polar region while only about a quarter is transported southward. Geographically there are two water vapor maxima visible, over Arabia Terra and the Tharsis plateau, that are most likely caused both by atmosphere-ground interaction and by atmospheric circulation. A comparison with other instruments generally shows a good agreement, only the SPICAM results are systematically lower. Compared to the results from the PFS long-wavelength channel the results of this work are slightly higher. A strong discrepancy is visible northward of about 50° N during the northern summer that is possibly explained by a non-uniform vertical H₂O mixing. In particular, a confinement of the water to the lower few kilometers yields a much better agreement between the retrieved column densities of the two PFS channels.     

The planetary fourier spectrometer (PFS) onboard the European Venus Express mission

The planetary fourier spectrometer (PFS) for the Venus Express mission is an infrared spectrometer optimized for atmospheric studies. This instrument has a short wavelength (SW) channel that covers the spectral range from 1700 to 11400 cm⁻¹ (0.9–5.5 μm) and a long wavelength (LW) channel that covers 250–1700 cm⁻¹ (5.5–45 μm). Both channels have a uniform spectral resolution of 1.3 cm⁻¹. The instrument field of view FOV is about 1.6 ° (FWHM) for the short wavelength channel and 2.8 ° for the LW channel which corresponds to a spatial resolution of 7 and 12 km when Venus is observed from an altitude of 250 km. PFS can provide unique data necessary to improve our knowledge not only of the atmospheric properties but also surface properties (temperature) and the surface-atmosphere interaction (volcanic activity).PFS works primarily around the pericentre of the orbit, only occasionally observing Venus from larger distances. Each measurements takes 4.5 s, with a repetition time of 11.5 s. By working roughly 1.5 h around pericentre, a total of 460 measurements per orbit will be acquired plus 60 for calibrations. PFS is able to take measurements at all local times, enabling the retrieval of atmospheric vertical temperature profiles on both the day and the night side.The PFS measures a host of atmospheric and surface phenomena on Venus. These include the:(1) thermal surface flux at several wavelengths near 1 μm, with concurrent constraints on surface temperature and emissivity (indicative of composition); (2) the abundances of several highly-diagnostic trace molecular species; (3) atmospheric temperatures from 55 to 100 km altitude; (4) cloud opacities and cloud-tracked winds in the lower-level cloud layers near 50-km altitudes; (5) cloud top pressures of the uppermost haze/cloud region near 70–80 km altitude; and (6) oxygen airglow near the 100 km level. All of these will be observed repeatedly during the 500-day nominal mission of Venus Express to yield an increased understanding of meteorological, dynamical, photochemical, and thermo-chemical processes in the Venus atmosphere. Additionally, PFS will search for and characterize current volcanic activity through spatial and temporal anomalies in both the surface thermal flux and the abundances of volcanic trace species in the lower atmosphere.Measurement of the 15 μm CO₂ band is very important. Its profile gives, by means of a complex temperature profile retrieval technique, the vertical pressure-temperature relation, basis of the global atmospheric study.PFS is made of four modules called O, E, P and S being, respectively, the interferometer and proximity electronics, the digital control unit, the power supply and the pointing device.     

Methods for the analysis of data from the Planetary Fourier Spectrometer on the Mars Express Mission

This work presents an algorithm for the scientific analysis of individual calibrated measurements from the Planetary Fourier spectrometer (PFS).The instrument, included in the scientific payload of the ESA Mars Express mission to Mars, acquires spectra in the range between 250 and 8200 cm⁻¹, with a sampling step of ∼1 cm⁻¹ and an effective resolution of ∼2 cm⁻¹. The observed radiance depends on several parameters of the atmosphere and surface of Mars as described by the radiative transfer equation. Adopting the very general formalism of Bayesian analysis, we determined which quantities are actually retrievable from individual measurements. Namely, they are: the surface temperature, the column density of dust and water ice aerosols in the atmosphere, the air temperature as a function of altitude (in the indicative range 5-45 km above the surface), the surface pressure, and the column density of water vapor and carbon monoxide. These evaluations are carried out taking into account the noise equivalent radiance (NER) of the instrument and the natural variabilities of the investigated parameters in the Martian environment, as estimated from the expectations of the European Martian Climate Dataset v3.1 (EMCD). Other parameters included in the radiative transfer equation shall be assumed as known, because they are not retrievable from individual measurements due to the instrumental NER or an underconstrained inverse problem: the surface emissivity in the thermal infrared, the optical properties of suspended dust and the analytical shape of dust concentration vs. altitude.During the development of the algorithm devoted to these studies, different approaches were evaluated on the basis of formal, computational and scientific considerations, with the aim to develop the general design of an integrated software package.The resulting code was extensively tested on a wide set of simulated PFS spectra. These spectra were computed from the atmospheric and surface conditions extracted from the EMCD, assumed to be representative of the Martian environment for different values of latitude, local time and season. Their comparison with the retrievals from simulated observations allowed us to evaluate the systematic and random errors affecting the procedures with respect to the different quantities involved. The code evaluates the surface temperature with an error in the order of 1 K, while the vertical air temperature profile is computed with an uncertainty less than 2 K from in the region between 5 and 20 km above the surface, increasing up to 7 K at 50 km. The column opacity of dust, measured in terms of integrated optical thickness at 1100 cm⁻¹, is computed with an error of around 0.13. The surface pressure determination is carried out with a typical uncertainty of 0.2-0.3 millibar. Several auxiliary tests allowed us to study the correlations between the different retrieval errors and the possible causes of incorrect PFS data interpretation. The choice of a suitable model for the dust optical properties is demonstrated to be particularly critical.This paper also presents the first discussion about application of the procedure to actual PFS Martian data. Despite the calibration issues still affecting the determination of absolute radiance in the near-infrared, the algorithm is able to achieve a satisfactory modeling of observations in a wide range of situations.     

Martian atmospheric particulate spectral end-members recovery from PFS and IRIS data

We present an application of a multivariate analyses technique on data returned by the Planetary Fourier Spectrometer (PFS) instrument on board the ESA’s Mars Express (MEX) spacecraft in order to separate the atmospheric contribution from the observed radiation. We observe that Thermal/Far Infrared spectra returned from Mars, covering almost a whole martian year, can be represented by a linear model using a limited set of end-member spectra. We identify the end-members as the suspended mineral dust and water ice clouds, but no surface signature was found. We improve previous studies performed with data from the Thermal Emission Spectrometer (TES) thanks to the higher spectral resolution of PFS. This allows for distinguishing narrow gaseous bands present in the martian atmosphere. Furthermore, the comparison of results from PFS and TES with data collected in 1971 by the Mariner 9 Infrared Interferometer Spectrometer (IRIS) shows an atmospheric dust component with similar spectral behavior. This might indicate homogeneity of the dust source regions over a time period of more than 30 years.     

The Isocam Responsivity in Orbit. Standard star photometry

An overview is given of the absolute flux calibration of the ISOCAMdetectors. The flux calibration is based on observations of standard stars selected from the Ground Based Preparatory Programme, for which Kurucz stellar models are available. No dependencies of the responsivity on different configurations of thecamera were found. No trend of changing responsivity is found throughout the mission for the SW and LW detectors. There exists a decreasing responsivity of about 5% for LW during the orbit.     

PFS-MEX observation of ices in the residual south polar cap of Mars

The Mars Express spacecraft has a highly inclined orbit around Mars and so has been able to observe the south pole of Mars in illuminated conditions at the end of the southern summer (L_s=330). Spectra from the planetary Fourier spectrometer (PFS) short wavelength (SW) channel were recorded over the permanent ice cap to study its composition in terms of CO₂ ice and H₂O ice. Models are fitted to the observed data, which include a spatial mixture of soil (not covered by ice) and CO₂ frost (with a specific grain size and a small amount of included dust and H₂O ice). Two different kinds of spectra were observed: those over the permanent polar cap with almost pure CO₂ ice, negligible water ice, no soil fraction required, and bright; and those over mixed terrain (at the edge of the cap or near troughs) containing a significant soil spatial fraction, more water ice and smaller CO₂ grain size. The amount of water ice given by fits to scaled albedo models is less than 10 ppm by weight. When using multi-stream reflectance models with the appropriate lighting geometry, the water amount must be 2-5 times greater than the albedo fit (less than 50 ppm). At the periphery of the residual polar cap, we found a region almost completely covered by water frost, modeled as a mixture of micron-sized and sub-mm sized grains. Our result using a granular mixture of micron-sized grains of water ice and dust with the CO₂ grains is different from the modeling of OMEGA polar cap observations using molecular mixtures.     

The miniaturized Möessbauer spectrometer MIMOS II for the Phobos-Grunt mission

Möessbauer spectroscopy is a powerful tool for the mineralogical analysis of Fe-bearing materials. The miniaturized Möessbauer spectrometer MIMOS II has already been working on the surface of Mars for 6 years as part of the NASA Mars Exploration Rovers mission. The improved version of the instrument is a component of the scientific payload of the Phobos-Grunt mission. The scientific objectives of the instrument are the following: to identify the iron-bearing phases, to determine the quantitative distribution of iron among these phases, and to determine the distribution of iron among its oxidation states.     

Laser-induced breakdown spectroscopy with artificial neural network processing for material identification

Laser-induced breakdown spectroscopy (LIBS) has demonstrated its high potential in measurement of material composition in many areas including space exploration. LIBS instruments will be parts of payloads for the 2011 Mars Science Laboratory NASA-led mission and the ExoMars mission planned by ESA. This paper considers application of artificial neural networks (ANN) for material identification based on LIBS spectra that may be obtained with a portable instrument in ambient conditions. The several classes of materials used in this study included those selected to represent the sites analogues to Mars. In addition, metals and aluminum alloys were used to demonstrate ANN capabilities. Excellent material classification is achieved with single-shot measurements in real time.     

A Martian PFS average spectrum: Comparison with ISO SWS

The evaluation of the planetary Fourier spectrometer performance at Mars is presented by comparing an average spectrum with the ISO spectrum published by Lellouch et al. [2000. Planet. Space Sci. 48, 1393.]. First, the average conditions of Mars atmosphere are compared, then the mixing ratios of the major gases are evaluated. Major and minor bands of CO₂ are compared, from the point of view of features characteristics and bands depth. The spectral resolution is also compared using several solar lines. The result indicates that PFS radiance is valid to better than 1% in the wavenumber range 1800-4200 cm⁻¹ for the average spectrum considered (1680 measurements). The PFS monochromatic transfer function generates an overshooting on the left-hand side of strong narrow lines (solar or atmospheric). The spectral resolution of PFS is of the order of 1.3 cm⁻¹ or better. A large number of narrow features to be identified are discovered.     

Mapping methane in Martian atmosphere with PFS-MEX data

In this study we map the methane gas in the Martian atmosphere. The main goal of this work is to show the methane behaviour across the planet seasonally. To this aim, we analyze the strongest methane band in the short wavelength channel of the Planetary Fourier Spectrometer (PFS) on board ESA Mars Express (MeX) spacecraft. The optical line depth is used to derive the column density of methane. The maps thus obtained show the spatial variability of this non-condensable gas and how the gas is transported in the atmosphere due to the cycle of carbon dioxide. Moreover, the increase of methane over the north polar cap during local summer, which cannot be explained by global circulation, strongly suggests that there could be methane reservoir associated with the polar cap.     

Simulation of the Martian spectral radiance in the presence of atmospheric dust

The interest towards Mars is nowadays renewed as various satellites, already launched or foreseen for the future, will visit this planet, providing a new wealth of data. In particular, infrared spectroscopic observations need a parallel modelling effort for a proper interpretation of observations. The goal of our modelling is to evaluate the influence of a non negligible fraction of dust particles on intensity and profile of atmospheric Martian spectra. The joint effects of the atmosphere and the surface materials have been also accounted for. For the modelling, a version of the MODTRAN code, expressly modified for application to the Mars environment, has been used. As an example of the materials forming dust dispersed in the atmosphere and on the surface, we have considered andesite. Indices of refraction (n and k) of this material have been derived from laboratory measurements. The obtained results can have an important impact on the interpretation of infrared spectra that instruments such as TES (Thermal Emission Spectrometer), on board the Mars Global Surveyor, and PFS, in the Mars Express mission, will provide.     

Ulysses observations of cosmic gamma-ray bursts

We review the current status of the Ulysses mission and summarize the results to date of the GRB experiment. This instrument detects bursts at the rate of about one every 3.5 days, and the localization data are being disseminated rapidly via the BACO-DINE and NMSU networks. The mission should operate through 2001, and future missions to Mars starting in 1996 will complete the 3rd Interplanetary Network.     

The global martian volcanic evolutionary history

Viking mission image data revealed the total spatial extent of preserved volcanic surface on Mars. One of the dominating surface expressions is Olympus Mons and the surrounding volcanic province Tharsis. Earlier studies of the global volcanic sequence of events based on stratigraphic relationships and crater count statistics were limited to the image resolution of the Viking orbiter camera. Here, a global investigation based on high-resolution image data gathered by the High-Resolution Stereo Camera (HRSC) during the first years of Mars Express orbiting around Mars is presented. Additionally, Mars Orbiter Camera (MOC) and Thermal Emission Imaging System (THEMIS) images were used for more detailed and complementary information. The results reveal global volcanism during the Noachian period (>3.7 Ga) followed by more focused vent volcanism in three (Tharsis, Elysium, and Circum-Hellas) and later two (Tharsis and Elysium) volcanic provinces. Finally, the volcanic activity became localized to the Tharsis region (about 1.6 Ga ago), where volcanism was active until very recently (200-100 Ma). These age results were expected from radiometric dating of martian meteorites but now verified for extended geological units, mainly found in the Tharsis Montes surroundings, showing prolonged volcanism for more than 3.5 billions years. The volcanic activity on Mars appears episodic, but decaying in intensity and localizing in space. The spatial and temporal extent of martian volcanism based on crater count statistics now provides a much better database for modelling the thermodynamic evolution of Mars.