Residence and redistribution of REE, Y, Zr, Th and U during granulite-facies metamorphism: behaviour of accessory and major phases in peraluminous granulites of central Spain

Accessory minerals are thought to play a key role in controlling the behaviour of certain trace elements such as REE, Y, Zr, Th and U during crustal melting processes under high-grade metamorphic conditions. Although this is probably the case at middle crustal levels, when a comparison is made with granulite-facies lower crustal levels, differences are seen in trace element behaviour between accessory minerals and some major phases. Such a comparison can be made in Central Spain where two granulite-facies terranes have equilibrated under slightly different metamorphic conditions and where lower crustal xenoliths are also found. Differences in texture and chemical composition between accessory phases found in leucosomes and leucogranites and those of melanosomes and protholiths indicate that most of the accessory minerals in melt-rich migmatites are newly crystallized. This implies that an important redistribution of trace elements occurs during the early stages of granulite-facies metamorphism. In addition, the textural position of the accessory minerals with respect to the major phases is crucial in the redistribution of trace elements when melting proceeds via biotite dehydration melting reactions. In granulitic xenoliths from lower crustal levels, the situation seems to be different, as major minerals show high concentration of certain trace elements, the distribution of which is thus controlled by reactions involving final consumption of Al-Ti-phlogopite. A marked redistribution of HREE–Y–Zr between garnet and xenotime (where present) and zircon, but also of LREE between feldspars (K-feldspar and plagioclase) and monazite, is suggested.     

HTLP metamorphism and fluid-fluxed melting during multistage anatexis of continental crust (N Sardinia,Italy)

The Variscan high-grade metamorphic basement of northern Sardinia and southern Corsica record lower Carboniferous anatexis related to post-collisional decompression of the orogen. Migmatites exposed in the Punta Bianca locality (Italy) consist of quartz + biotite + plagioclase + K-feldspar orthogneisses, garnet and cordierite-bearing diatexite and metatexites, derived from metasediments. Field evidence, petrographic observations, ELA-ICP-MS zircon and monazite dating and pseudosection modelling suggest that anatexis was apparently episodic involving two main stages of partial melting. Using pseudosection modelling, we infer that the first stage of partial melting is in the upper amphibolite facies (~0.45 GPa at ~740°C). Cordierite overgrowths replacing sillimanite, combined with the composition of plagioclase and K-feldspar, suggest decompression followed cooling below the solidus at low pressures of ~0.3 GPa. The age of the first anatectic event is not precisely constrained because of extensive resetting of the isotopic systems during the second melting stage, yet few zircons preserve a lower Carboniferous age which is consistent with the regional dataset. This lower Carboniferous migmatitic fabric is offset by a network of pseudotachylyte-bearing faults suggestive of cooling to greenschist facies conditions. Garnet/cordierite-bearing diatexites incorporate fragments of pseudotachylite-bearing orthogneiss and metatexites. Pseudosection modelling indicates nearly isobaric re-heating up to ~750°C, followed by further cooling below the solidus. The inferred P–T path is consistent with decompression and cooling of the Variscan crust through post-collisional extension and collapse of the thickened orogenic crust, followed by nearly isobaric re-heating at low pressures (~0.3 GPa) yielding to a second melting stage under LP-HT conditions. U/Th-Pb monazite ages for diatexite migmatites indicate an upper bound of 310–316 Ma for the second melting stage, suggesting that the second melting stage is coincident with the regional phase of crustal shearing. The cause of the high geothermal gradient required for re-heating during the second melting stage is unknown but likely requires some heat source that was probably related to dissipation of mechanical work within crustal-scale shear zones. According to this interpretation, some upper Carboniferous peraluminous granite precursors of the Corsica–Sardinia Batholith could be the outcome rather than the cause of the late-Variscan high-T metamorphism.     

Phase relations in the partial melting of the Baldissero spinel-lherzolite (Ivrea-Verbano zone,Western Alps,Italy)

The occurrence of various types of mobilizates in the Baldissero spinel lherzolite is due to partial melting of the same body. The study of the relationships between the peridotite and its mobilizates demonstrates that olivine did not take an active part in the fusion. Estimates of the degree of partial melting vary from 10% for the average composition, to 20% for the most depleted samples. These values refer to an initial pyrolitic composition, and thus are relative, as they can vary depending on the actual primary composition.The calculated composition of the liquid generated by partial melting is quite similar to that of a picritic basalt, and is practically the same irrespective of the 10% and 20% fusion. This fact provides strong evidence that melting took place at a unique invariant point of the natural system, producing a liquid with a remarkably constant composition.Projection of the liquid in the fo-an-di-si diagram is fairly well aligned with the modal compositions of the solid residua, but does not coincide with the minimum of the simplified system. The proposed solution is based on the enlargement of the spinel field (at constant pressure), due to the Cr content in this phase. Therefore, the position of the invariant minimum is not fixed, but rather controlled by the Cr content of the spinel. Is is suggested that, by an increase in the Cr content, spinel might at a given moment become refractory. Thus, saturated or over-saturated magmas are produced depending on the phase relations between olivine, orthopyroxene and clinopyroxene. This would happen in the case of very advanced fusions or in the case of fusion of already depleted peridotites.The relationships between mobilizates of different generations suggest a non adiabatic mantle upwelling.     

The robustness of the Zr-in-rutile and Ti-in-zircon thermometers during high-temperature metamorphism (Ivrea-Verbano Zone, northern Italy)

This study investigates the behaviour of the Zr-in-rutile and Ti-in-zircon thermometers in granulite facies metapelites from the Ivrea-Verbano Zone lower crustal section. U–Pb ages of zircon constrain the timing of regional amphibolite–granulite facies metamorphism to 316 ± 3 Ma and record zircon recrystallisation and resetting of U–Pb ages at 276 ± 4 Ma and 258 ± 3 Ma. Zr-in-rutile thermometry records peak contact metamorphic temperatures related to intrusion of mafic magmatic rocks and gives peak temperatures between 900–930 °C and 1,000–1,020 °C that are consistent with the geological settings of the samples. Ti-in-zircon temperatures of 700–800 °C and 810–870 °C record growth or re-equilibration of zircon after cooling from peak temperatures. Ti-in-quartz thermometry for one sample records both peak and retrograde temperatures. Some rutiles in all samples record resetting of Zr-in-rutile temperatures at ~750–800 °C. Electron microprobe profiles across individual rutiles demonstrate that Zr expulsion occurred by recrystallisation rather than by diffusive exchange. Exsolution of small needles of baddelyite or zircon from rutile is an important method of Zr redistribution, but results in no net Zr loss from the grain. The demonstration that Zr-in-rutile thermometry can robustly record peak temperatures that are not recorded by any other thermometer emphasises the relevance of this technique to investigating the evolution of high-grade metamorphic terranes, such as those that characterise the lower crust.     

Fluid inclusions in granulite-facies metapelites of the Hercynian ancient lower crust of the Serre,Calabria, Southern Italy

Investigations of fluid inclusions in granulitefacies metapelites of southern Calabria enable characterization of the fluid composition of these lower crustal rocks, and constrain the petrologically deduced retrograde P-T path characterized by isothermal uplift prior to isobaric cooling in middle crustal levels. Fluid inclusions in cordierite, garnet and sillimanite have a CO₂-rich composition. Inclusions in cordierite rarely contain minor amounts of N₂ and H₂O, and in garnets some CO₂–CH₄–N₂ inclusions have been analyzed by Raman microprobe. Quartz reveals the most complex fluid melusion compositions (1) CO₂-rich, (2) CO₂–CH₄–N₂, (3) CH₄–N₂, (4) H₂O–MgCl₂–CaCl₂–NaCl, (5) H₂O–NaCl and (6) H₂O–CO₂. The earliest fluid inclusions after peak metamorphism are rich in CO₂ with minor amounts of N₂ and H₂O. An early CO₂–(H₂O–N₂) fluid composition has been confirmed by detection of CO₂, H₂O and N₂ in the channels of the cordierite structure. Most of the early CO₂-rich fluid inclusions were modified during the uplift from the lower to the middle crustal level, resulting in a density decrease with CO₂ still dominant. The subsequent isobaric cooling led to further modifications of the fluid inclusions. High-density inclusions around implosion textures or scattered amongst lower-density ones must have formed during this cooling episode. Aqueous inclusions in quartz are mostly formed late and are consistent with trapping during retrograde rehydration.This project has been supported by the DFG as contribution to the special program Continental Lower Crust     

Local partial melting of the lower crust triggered by hydration through melt–rock interaction: an example from Fiordland,New Zealand

We investigate a low‐strain outcrop of the lower crust, the Pembroke Granulite, exposed in northern Fiordland, New Zealand, which exhibits localized partial melting. Migmatite and associated tschermakite–clinozoisite (TC) gneiss form irregular, elongate bodies that cut a two‐pyroxene–pargasite (PP) gneiss. Gradational boundaries between rock types, and the progressive nature of changes in mineral assemblage, microstructure and chemistry are consistent with the TC gneiss and migmatite representing modified versions of the PP gneiss. Modification is essentially isochemical, where partial modification involves hydration of the assemblage and mineral chemistry changes, and complete modification involves additional recrystallization and in situ partial melt production. Microstructures of quartz and plagioclase, including small dihedral angles, string of beads textures and films surrounding amphibole and garnet grains are consistent with the former presence of melt in modified rock types. The documented rock modification is attributed to melt–rock interaction occurring during porous melt flow of a dominantly externally derived, hydrous silicate melt. Microstructures indicate melt flow occurred along grain boundaries and field relationships show it was focused into channels tens of metres wide, with preference for following the pre‐existing foliation. Melt–rock interaction at the grain scale resulted in hydration and modification of the host PP gneiss, which resulted in localized partial melting. These relationships indicate prograde hydration during localized melt–rock interaction drove migmatization of the lower crust.     

On the structure of the Ivrea-Verbano Zone (northern Italy) and its implications for present-day lower continental crust geometry

The Ivrea-Verbano Zone in northern Italy represents a section through the lower continental crust which has been tilted and emplaced into its present position during the Alpine orogeny. Recent and on-going structurally-oriented geological mapping in this region is providing new information about the geometry of the complex. The central part of the zone is dominated by a large basic complex (the 'mafic formation') which is intrusive into the surrounding gneisses. The foliation within the envelope of gneisses is deflected around the intrusive complex as if by ballooning, but in the region south-west of Monte Capio both units are folded together into a tight to isoclinal steeply plunging fold with an amplitude of c. 10 km. This fold locally inverts the stratigraphy of the layered basic group of the complex, and is thought to be the result of gravitational collapse following intrusion and inflation of a large magma body into the lower crust.
Several high-temperature shear zones have now been traced within the country rock for distances up to 20 km. The geometry of these, and their relationship to the basic complex suggests that at least some of the extensional collapse of the mafic body is related to uplift caused by intrusion of this body.
Close parallels can be drawn between the observed structure in the Ivrea-Verbano Zone (after removing the effects of late, low-temperature faulting and folding related to emplacement of the rocks into their present position), and those inferred from deep seismic reflection profiling in areas of current extension such as parts of the US Basin and Range province.     

Temporal links between pluton emplacement,garnet granulite metamorphism,partial melting and extensional collapse in the lower crust of a Cretaceous magmatic arc,Fiordland, New Zealand

Garnet granulite facies mid‐to lower crust in Fiordland, New Zealand, provides evidence for pulsed intrusion and deformation occurring in the mid‐to lower crust of magmatic arcs. ²³⁸U‐²⁰⁶Pb zircon ages constrain emplacement of the ～595 km² Malaspina Pluton to 116–114 Ma. Nine Sm‐Nd garnet ages (multi‐point garnet‐rock isochrons) ranging from 115.6 ± 2.6 to 110.6 ± 2.0 Ma indicate that garnet granulite facies metamorphism was synchronous or near synchronous throughout the pluton. Hence, partial melting and garnet granulite facies metamorphism lasted <5 Ma and began within 5 Ma of pluton emplacement. Garnet granulite facies L‐S tectonites in the eastern part of the Malaspina Pluton record the onset of extensional strain and arc collapse. An Sm‐Nd garnet age and thermobarometric results for these rocks directly below the amphibolite facies Doubtful Sound shear zone provide the oldest known age for extension in Fiordland at ≥112.8 ± 2.2 Ma at ～920 °C and 14–15 kbar. Narrow high Ca rims in garnet from some of these suprasolidus rocks could reflect a ≤ 1.5 kbar pressure increase, but may be largely a result of temperature decrease based on the Ca content of garnet predicted from pseudosections. At peak metamorphic conditions >900 °C, garnet contained ～4000 ppm Ti; subsequently, rutile inclusions grew during declining temperature with limited pressure change. Garnet granulite metamorphism of the Malaspina Pluton is c. 10 Ma younger than similar metamorphism of the Pembroke Granulite in northern Fiordland; therefore, high‐P metamorphism and partial melting must have been diachronous for this >3000 km² area of mid‐to‐lower crust. Thus, two or more pulses of intrusion shortly followed by garnet granulite metamorphism and extensional strain occurred from north to south along the axis of the lower crustal root of the Cretaceous Gondwana arc.     

Formation of cordierite-bearing lavas during anatexis in the lower crust beneath Lipari Island (Aeolian arc,Italy)

Cordierite-bearing lavas (CBL;~105 ka) erupted from the Mt. S. Angelo volcano at Lipari (Aeolian arc, Italy) are high-K andesites, displaying a range in the geochemical and isotopic compositions that reflect heterogeneity in the source and/or processes. CBL consist of megacrysts of Ca-plagioclase and clinopyroxene, euhedral crystals of cordierite and garnet, microphenocrysts of orthopyroxene and plagioclase, set in a heterogeneous rhyodacitic-rhyolitic groundmass containing abundant metamorphic and gabbroic xenoliths. New petrographic, chemical and isotopic data indicate formation of CBL by mixing of basaltic-andesitic magmas and high-K peraluminous rhyolitic magmas of anatectic origin and characterize partial melting processes in the lower continental crust of Lipari. Crustal anatectic melts generated through two main dehydration-melting peritectic reactions of metasedimentary rocks: (1) Biotite + Aluminosilicate + Quartz + Albite = Garnet + Cordierite + K-feldspar + Melt; (2) Biotite + Garnet + Quartz = Orthopyroxene + Cordierite + K-feldspar + Melt. Their position into the petrogenetic grid suggests that heating and consequent melting of metasedimentary rocks occurred at temperatures of 725 < T < 900°C and pressures of 0.4–0.45 GPa. Anatexis in the lower crust of Lipari was induced by protracted emplacement of basic magmas in the lower crust (~130 Ky). Crustal melting of the lower crust at 105 ka affected the volcano evolution, impeding frequent mafic-magma eruptions, and promoting magma stagnation and fractional crystallization processes.     

中天山东段尾亚印支早～中期石英闪长岩——陆内俯冲与原生下陆壳部分熔融

前人对东天山海西期的构造-热事件作了大量研究,得出了许多方面的重要认识.东天山印支期的构造演化到底是海西期的延续,还是受控于另一构造域,至今仍不清楚.因此,印支期岩浆岩岩相学、地球化学和同位素地质学的综合研究,对阐明本区印支期的构造演化具有重要意义.产于中天山东段的尾亚石英闪长岩形成于印支早-中期.该岩石主要组成矿物为...     

Pyrometamorphism and partial melting of shales during combustion metamorphism: mineralogical,textural, and chemical effects

Eocene shales metamorphosed by a naturally ignited coal seam in the Powder River Basin, Wyoming record a continuum of mineralogic and textural changes from relatively unaltered shale to melt developed during pyrometamorphism. Samples collected along a section 2 m in length, corresponding to a temperature range of approximately 1300°C, were examined optically and by XRD, SEM, and STEM. The low temperature samples are comprised primarily of silt-sized quartz, K-feldspar, and minor amounts of other detrital minerals in a continuous matrix of illite/smectite (I/S). Delamination of phyllosilicates due to dehydroxylation occurs early in the sequence with curling of individual layers from rim to core. Within one-half meter of melted areas, phyllosilicates have undergone an essentially isochemical reconstitution with nucleation and growth of mullite crystals with maximum diameters of 50 nm, randomly distributed within a non-crystalline phase that replaces I/S. Large detrital grains remain for the most part unaffected except for the inversion of quartz to tridymite/cristobalite. Within 1 mm of the solid/melt interface, the mullitebearing clay mineral matrix is essentially homogeneous in composition with obscure grain boundaries, caused by apparent homogenization of poorly crystalline material. This material is similar in composition to parent clays and acts as a matrix to angular, remnant tridymite/cristobalite grains. Rounded, smaller silica grains have reaction rims with the non-crystalline matrix; K-feldspar is no longer present (apparently reacted with the matrix) and the matrix contains abundant pore space due to shrinkage upon dehydroxylation. As isolated pods of paralava (glass) or fractures are approached, Fe–Ti–Al oxides become abundant. Vesicular glass is separated from clinker by a well-defined interface and contains numerous phenocrysts. XRF analyses and reduced area rastering using EDS imply enrichment of the melt phase in Fe, Ca, Mg and Mn, apparently due to vapor transport from other layers lower in the sedimentary sequence.Contribution No. 490, the Mineralogical Laboratory, Department of Geological Sciences, The University of Michigan     

Determination of REE, Y, Nb, Zr, Hf, Ta, Th and U in Geological Reference Materials LSHC-1 and Amf-1 by Solution and Laser Ablation ICP-MS

This paper presents data on REE and Y, Nb, Zr, Hf, Ta, Th and U abundances for two candidate reference materials (RMs), spinel lherzolite LSHC-1 and amphibole Amf-1, being currently developed at the Institute of Geochemistry SB RAS, Irkutsk. To determine the contents of these elements inductively coupled plasma-mass spectrometry was applied with: (i) solution nebulisation (solution ICP-MS) and (ii) laser ablation (LA-ICP-MS) of fused glass disks. The precision of results obtained by both techniques was better than 6% RSD for most elements. Accuracy was assessed by using the geochemical RMs JB-2, JGb-1 (GSJ) and MAG-1 (USGS). The trace element results by solution ICP-MS for JGb-1 and JB-2 agree with reference values presented by Imai et al. (1995, this Journal) within 1–10%. Significant differences were found for Nb and Ta determinations. The accuracy of LA-ICP-MS results evaluated by RM MAG-1 was within 4%, except for Eu (about 10%). The analytical results obtained for LSHC-1 and Amf-1 by solution ICP-MS and LA-ICP-MS were in good agreement with each other and with INAA and XRF data presented for the certification of these RMs. They can be considered as the indicative values for assigning certified values to the above-mentioned RMs.     

Formation of the Shuswap metamorphic core complex during late-orogenic collapse of the Canadian Cordillera: Role of ductile thinning and partial melting of the mid-to lower crust

Abstract

The early Tertiary evolution of the Shuswap metamorphic core complex is characterised by low-angle crustal detachments and nearly isothermal decompression followed by rapid cooling of rocks in the footwall of the detachments. Previous work as well as our own observations suggest that Paleogene late-orogenic extension produced the main tectonic features of the region. Furthermore, structural analysis of the migmatites and published geochronological data indicate that partial melting of the mid- to lower crust was coeval with extension in the upper crustal levels, suggesting that these two processes are linked genetically. Consequently, we propose that the formation of the Shuswap metamorphic core complex corresponds to late-orogenic gravitational collapse of the Canadian Cordillera accommodated by normal faulting of the brittle upper crust and by ductile thinning of the mid- to lower crust. The initiation and amplification of extension during the Paleocene in the Shuswap metamorphic core complex are tentatively related to partial melting of the thickened crust which caused drastic mechanical weakening of the crust.     

Residence of REE, Y, Th and U in Granites and Crustal Protoliths; Implications for the Chemistry of Crustal Melts

A systematic study with laser ablation—ICP-MS, scanningelectron microscopy and electron microprobe revealed that 70–95wt% of REE (except Eu), Y, Th and U in granite rocks and crustalprotoliths reside within REEYThU-rich accessories whose nature,composition and associations change with the rock aluminosity.The accessory assemblage of peraluminous granites, migmatitesand high-grade rocks is composed of monazite, xenotime (in low-Cavarieties), apatite, zircon, Thorthosilicate, uraninite andbetafite-pyrochlore. Metaluminous granites have allanite, sphene,apatite, zircon, monazite and Thorthosilicaie. Peralkaline graniteshave aeschinite, fergusonite, samarskite, bastnaesite, fluocerite,allanite, sphene, zircon, monazite, xenotime and Th-orthosilicate.Granulite-grade garnets are enriched in Nd and Sm by no lessthan one order of magnitude with respect to amphibolite-gradegarnets. Granulitegrade feldspars are also enriched in LREEwith respect to amphibolite-grade feldspars. Accessories causenon-Henrian behaviour of REE, Y, Th and U during melt—solidpartitioning. Because elevated fractions of monazite, xenotimeand zircon in common migmatites are included within major minerals,their behaviour during anatexis is controlled by that of theirhost. Settling curves calculated for a convecting magma showthat accessories are too small to settle appreciably, beingseparated from the melt as inclusions within larger minerals.Biotite has the greatest tendency to include accessories, therebyindirectly controlling the geochemistry of REE, Y, Th and U.We conclude that REE, Y, Th and U are unsuitable for petrogeneticalmodelling of granitoids through equilibrium-based trace-elementfractionation equations. KEY WORDS: accessory minerals; geochemical modelling; granitoids; REE, Y, Th, U     

Experimental and geochemical evidence for derivation of the El Capitan Granite,California, by partial melting of hydrous gabbroic lower crust

Partial melting of mafic intrusions recently emplaced into the lower crust can produce voluminous silicic magmas with isotopic ratios similar to their mafic sources. Low-temperature (825 and 850°C) partial melts synthesized at 700 MPa in biotite-hornblende gabbros from the central Sierra Nevada batholith (Sisson et al. in Contrib Mineral Petrol 148:635–661, 2005) have major-element and modeled trace-element (REE, Rb, Ba, Sr, Th, U) compositions matching those of the Cretaceous El Capitan Granite, a prominent granite and silicic granodiorite pluton in the central part of the Sierra Nevada batholith (Yosemite, CA, USA) locally mingled with coeval, isotopically similar quartz diorite through gabbro intrusions (Ratajeski et al. in Geol Soc Am Bull 113:1486–1502, 2001). These results are evidence that the El Capitan Granite, and perhaps similar intrusions in the Sierra Nevada batholith with lithospheric-mantle-like isotopic values, were extracted from LILE-enriched, hydrous (hornblende-bearing) gabbroic rocks in the Sierran lower crust. Granitic partial melts derived by this process may also be silicic end members for mixing events leading to large-volume intermediate composition Sierran plutons such as the Cretaceous Lamarck Granodiorite. Voluminous gabbroic residues of partial melting may be lost to the mantle by their conversion to garnet-pyroxene assemblages during batholithic magmatic crustal thickening.     

Partial melting and retrogression during exhumation of high-grade metapelites,the Tatra Mountains,Western Carpathians

Partial melting and retrogression have been recognized in high-grade metapelites of the Tatra Mountains, Western Carpathians (Slovakia) related to exhumation during Variscan orogeny. Reaction textures and phase equilibria define a clockwise P-T path. The prograde metamorphism from ca 600 °C and 9–10 kbar to >700 °C at 11–12 kbar resulted in muscovite dehydration-melting in the kyanite stability field. Further heating at decreasing pressure led to the dehydration-melting of biotite at >750 °C in the sillimanite stability field. This was followed by nearly isothermal decompression down to 4–5 kbar, producing cordierite and some additional melt. Later nearly isobaric cooling led to melt crystallization and sub-solidus retrogression. CO₂-N₂ fluids (5–30 mol. % N₂) were generated at pressures <6 kbar by interaction between the melt-derived water and graphite at oxidizing conditions.     

Geochemical evolution of high-pressure mafic granulites from the Bacariza formation (Cabo Ortegal complex, NW Spain): an example of a heterogeneous lower crust

 The Cabo Ortegal complex (northwestern Iberian massif) is a klippen formed of several structural units stacked during the Hercynian collision. All these units include ultramafic rocks, metabasites and quartz-feldspathic gneisses affected by different metamorphic conditions. The Bacariza formation is heterogeneous showing a conspicuous layering mainly defined by alternate high-pressure ultrabasic-to-basic granulites, retrogressed garnet amphibolites of intermediate composition and rare acid rocks forming garnet trondhjemitic gneisses. This layering is inherited from a gabbroic protolith showing a composition rich in Fe and Ti. Major and trace elements of these rocks can be correlated to continental tholeiitic series of extensional settings. These high-pressure granulites are situated in normal contact between±serpentinised ultramafic rocks and other high-grade metabasites with lessevolved and more-depleted composition comparable to T-type and N-type MORB. It is suggested that the layered gabbro-type protolith was part of a continuous mafic crust. This crust was initially formed during Early Ordovician in a continental extensional setting and progressively evolved to oceanic spreading. Received: 9 February 1996/Accepted: 10 February 1997     

大别山变质岩锆石微区稀土元素和Th,U特征

对进行过微区U-Pb定年和阴极发光成像研究的大别山辛店榴辉岩、双河榴辉岩、黄镇榴辉岩和双河硬玉石英岩中锆石,进行了微区核部与边部稀土元素测定.结合U-Pb年龄和CL图象,探讨了超高压变质过程中稀土元素从原岩锆石到变质锆石的变化.结果表明,原岩锆石和变质锆石有很不相同的稀土元素含量,它取决于变质锆石是由变质重结晶还是变质增生作用形成及形成时间.一般说来,边部变质锆石比原岩锆石亏损稀土元素,特别是重稀土,并且有更低的Th/U比.变质锆石的稀土元素和Th/U比可以为变质锆石形成时的物理化学环境和变质锆石成因提供重要信息.     

The extent of U-series disequilibria produced during partial melting of the lower crust with implications for the formation of the Mount St. Helens dacites

The extent to which U-series disequilibria can be produced during partial melting of mafic lower crust is quantified using a simple batch melting model and both experimental and theoretical partition coefficients for U, Th and Ra. We show that partial melting of mafic lower crust can only produce small disequilibria between ²³⁸U, ²³⁰Th and ²²⁶Ra. Crystallisation of basalt and mixing between young basalt and crustal derived melts will have a similar or smaller effect. Consequently, U-series disequilibrium in arc andesites and dacites can generally only be an inherited feature derived from a mantle parent, unless the timescales of silicic magma production within the crust are short compared to the half-life of ²²⁶Ra. Our results have profound implications for several recent models of silicic magma production by thermal incubation and partial melting of the lower crust. We show that the ²²⁶Ra excess observed in most arc andesites and dacites requires extremely rapid differentiation and/or the involvement of mantle derived basalts less than a few thousand years old. Application to Mount St. Helens suggests that crystallisation of young mantle-derived magma is likely to be the dominant process in the formation of these dacites.     

Systematics of REE,Sc, Cr,Zr, and Th in Surface Bottom Sediments of the Nordic Seas

Doklady Earth Sciences - The systematics of REE, Sc, Cr, Zr, and Th in silty-pelitic and pelitic surface bottom sediments sampled during cruises 71, 75, 77, and 80 of the R/V Akademik Mstislav...