The impact of landslides and salt weathering on Roman structures at high latitudes—Conway Castle, Great Britain: a case study

Conway Castle is an immense historical structure, dating back to 1289 AC. It was built on highly dipping thickbeds of indurated shale (argillite) and sandstone. It is surrounded by Conway Bay, railway lines, and tall dense forests indicating high relative humidity and rainfall in this coastal area. The castle suffers from weathering noted as honeycomb, black crust, exfoliation, and discoloration with white salt efflorescence at some parts; these are diagnostic features for salt weathering as confirmed by the laboratory investigations using scanning electron microscopy, X-ray diffraction (XRD), point XRD, and hydrochemical analysis. The salt is found to be from three sources, namely, water spray from Conway Bay that is part of the Irish Sea, chemical alteration of the mortars carbonate content into sulfate salts by acid rain, and wet deposition of air pollutants on the surface of the stone. The cracks noted in the southwestern tower of this castle are a result of landslides in this area that resulted from three factors: (a) high dip angle of the indurated sandstone and shale thickbeds (about 60–65° to the south) under this castle, (b) undercutting of these beds in the dip direction by the surface water of Conway Bay, and (c) seismic waves generated by the trains passing close to this castle. All these factors result in land sliding even at a low rate; however, the net result is cracks in the tower close to these factors.     

Impact of regional geology, land use and flow path on stream water chemistry in a small watershed

Stream water chemistry is dependent on the physical, chemical and biological processes occurring in the watershed. Understanding the governing mechanism of the stream water chemistry in a watershed is the first step for the water quality management. The study area drains a total catchment area of 1.46 km^2 and consists of forest （80%）, upland （15%） and rice paddy field （5%）. The studied area has two distinctive bedrocks, quartzite and schist. We periodically collected the stream water samples at mainstream and tributaries and the pH, electrical conductivity （EC）, alkalinity and the concentrations of cations and anions of the collected stream water samples were determined in the field and laboratory. The all collected water samples were nearly neutral and the EC and concentrations of Na, K, Ca, Sr, Si and HCO3 of the stream water samples collected from the schist terrain had greater values than those from the quartzite terrain. The mainstream running along the boundary of schist and quartzite terrains had the intermediate values of the tributaries. The stream water samples collected in and near the upland showed a high concentration of NO3^- than those of forest regardless the lithology. The stream pathway was also directly reflected on the chemistry of stream water. The stream water drained in the forest of quartzite terrain had the lowest values of alkalinity, EC and concentrations of cations and anions but the stream water drain in the upland of schist terrain had the highest values of EC and concentrations of cations and anions, especially NO3^-.     

The knowledge expression on debris flow potential analysis through PCA + LDA and rough sets theory: a case study of Chen-Yu-Lan watershed,Nantou, Taiwan

Debris flow is often performed through identifying and analyzing the soil condition, hydraulic, geomorphological factors and vegetation conditions. In the present study, a spatial information analysis system is combined with a linear statistical method (principle components analysis with linear discriminant analysis, PCA + LDA) and an advanced data mining technique (discrete rough sets, DRS) to investigate the debris flow occurrence based on geomorphological and vegetation conditions factors. The analyzed data sources include (1) digital elevation model: to investigate the variation in the landscape, and (2) remote sensing data: to analyze the vegetation and plant conditions on the ground surface. The objective of this research is to define a method with the ability to forecast the level of debris flow susceptibility through the parallel study of statistical outcomes (PCA + LDA) and data mining results (DRS). The outcomes from PCA + LDA are inadequate due to the thresholds of the influenced variables not being examined. In this study, the DRS approach not only showed satisfactory results for the thresholds of influenced variables in the study area, but also the occurrence rules of debris flow are generated. Finally, the results show superior classification accuracy (70.8% for debris flow occurrence) for the DRS method over those of PCA + LDA analysis (54.2% for debris flow occurrence) for the analysis of debris flow occurrence. Therefore, this is an encouraging preliminary approach in the hazard assessment of debris flow.     

The nature of metals—sediment—water interactions in freshwater bodies,with emphasis on the role of organic matter

A review with 227 references of the title subject is presented. It is divided into two main sections, viz., nature and properties of humic matter, and water—metal—sediment interactions.The first section deals with the essential properties of organic matter which occurs naturally in drainage sediments and waters. Discussion of the basic molecular structure of humic and fulvic acids is followed by some details of the chemical nature of functional groups within these structures which are important in metal-ion adsorption and complexing reactions which these materials can undergo. Information is also presented for colloidal and polyelectrolyte properties, complexation properties, and finally a summary discussion of metal-ion—humic-acid, metal-ion—fulvic-acid stability constants for both single ligand and mixed ligand systems completes the section.The second section comprises discussions of some specific aspects of interactions between metals, sediments and waters, including metal and organic speciation studies; sorption interactions between organic matter, clays and humic acids; chemical reaction between humic acids, heavy-metal minerals, clays and other silicate minerals; metal-ion adsorption—desorption studies, oxidation—reduction reactions between metal ions and humic acids; effects of sulphide ion on some of the above interactions and finally a summary of some relevant field geochemical dispersion studies.This second section describes both laboratory and field studies for each aspect.     

The occurrence of vanadium in nature: its biogeochemical cycling and relationship with organic matter—a case study of the Early Cambrian black rocks of the Niutitang Formation,western Hunan,China

Acta Geochimica - Vanadium in the black rocks has economic and environmental impacts. In sediments, it is broadly disseminated as a multivalent metal element mainly sensitive to redox settings....     

The effect of air pollution on stone decay: the decay of the Drachenfels trachyte in industrial, urban, and rural environments—a case study of the Cologne, Altenberg and Xanten cathedrals

Severe stone deterioration is evident at the Cologne cathedral. In particular, the “Drachenfels” trachyte, which was the building material of the medieval construction period, shows significant structural deterioration as well as massive formation of gypsum crusts. The present article investigates crust formation on limestone, sandstone, and volcanic rock from the Cologne cathedral as well as from the Xanten and Altenberg cathedrals. These three buildings, showing varying degrees of deterioration, are located in different areas and exposed to varying industrial, urban, and rural pollution. Thin laminar and black framboidal crusts form on calcareous as well as silicate stone. The lack of a significant intrinsic calcium and sulfur source for the formation of the gypsum crusts on the Drachenfels trachyte indicates major extrinsic environmental impact: a sufficient offer of SO _x from pollutant fluxes as well as external calcium sources (e.g., pollution, mortars, neighboring calcite stones). Chemical analyses reveal strong gypsum enrichment within the crusts as well as higher concentrations of lead and other pollutants (arsenic, antimony, bismuth, tin, etc.), which generally can be linked to traffic and industry. The formation of weathering crusts in an industrial environment is clearly distinguishable from that in rural areas. Scanning electron microscopy observations confirm that the total amount of pollution is less at the Altenberg cathedral than at the Cologne and Xanten cathedrals. XRF analyses show that the formation of gypsum occurs in lower amounts at Altenberg. This correlates well with the measured SO₂ content and the intensity of the decay at the different locations. Furthermore, the different types of crusts, e.g., framboidal and laminar, can be differentiated and assigned to the different locations. The black weathering crusts on the silicate Drachenfels trachyte contribute to the degradation of the historic building material. They enhance mechanical moisture-related deterioration processes and the decay by chemical corrosion of rock-forming minerals. Although SO₂ concentrations in air have shown a strong decrease over the past 30 years, degradation in connection with weathering crusts is still observed. This indicates that not only contemporary or recent emissions, but also past pollutant concentrations have to be considered.     

The effect of malonate on the dissolution kinetics of albite,quartz, and microcline as a function of pH at 70°C

The effect of malonate on the dissolution rate of the reservoir minerals: albite, quartz, and microcline has been examined. The effect of pH on rate has been decoupled from the effect of the ligand by controlling pH using dilute buffer solutions at values of pH 4 through pH 10 at 70°C. Any effect of the buffer ligands (acetate and borate) or alkali cation (Na) on rate was accounted for by comparing the measured dissolution rates in buffer solutions with and without malonate. Flowing reactors were used and malonate concentration was varied from 1 to 100 mmolal.As malonate anion concentration is increased, the dissolution rate of these minerals also increases. At moderately acidic to near neutral pH in the solutions containing the highest malonate concentration, malonate most significantly increases the dissolution rate of the silicates over that expected due to simple hydrolysis. At alkaline pH the effect of malonate on the dissolution rate of these silicates is not significant, compared to the dissolution rate due to simple hydrolysis alone.     

The water on a small karst island: the island of Korčula (Croatia) as an example

The island of Korčula, which has an area of 271.47 km² is located along the north-eastern coast of the Adriatic Sea. Due to the Mediterranean climate, size and karst geology its water resources are very scarce. This paper describes the natural features of the island (air temperature, precipitation, geology, hydrogeology and groundwater) which are important for the water appearance and its distribution in time and space. The water supply of the island has been managed in the following ways: through a pipeline from the mainland, by drawing groundwater and by rain harvesting. Tourism causes high seasonal water needs which are barely met by the existing water supply system. Therefore, present water resource management on the island must be improved. The paper also presents mathematical programming scheme to get optimal costs and benefits of water exploitation on the island. Besides economic aspect, linear programming is applied to social and ecological objectives, as well. This study suggests that island’s water management should be primarily based on wisely using its proper water resources.     

The role of questions about migration in UK censuses: A simple matter of counting, or a means of exerting power?

Questions about migration have appeared in various forms in British censuses since 1841, and questions about ethnicity have been included since 1991. A variety of new questions were included in the 2011 Census that increase the amount of information that is gathered about migrants, both internal and international. This paper reviews these questions, exploring their changing nature and reasons why they might be asked. Some of the new questions - notably one on intention to stay in the UK - may be harmful to the wider goal of producing accurate and useful data. More generally, the range of questions suggests a growth in scope for the census from providing an administrative count of the number of people resident in the country, to a parallel role as an instrument in expressing the power of the state. This may erode civil trust in the statistical agencies and consequently lead to poor response rates.     

Study on oil–source correlation by analyzing organic geochemistry characteristics: a case study of the Upper Triassic Yanchang Formation in the south of Ordos Basin,China

In the south of the Ordos Basin, the oil source of the Upper Triassic Yanchang Formation is confused all the time, which affects further exploration. In this study, oil sources from the oil layers of Ch6, Ch8 and Ch9 are all analyzed and confirmed. Through their carbon isotope value and biomarkers, characteristics of crude oils from the Yanchang Formation are analyzed. Then, the oil–source relation is discussed, with the source rocks’ features. Finally, the oil–source relation is calculated through cluster analysis. It is believed that the oils from the Yanchang Formation deposit in a similar redox environment, with weak oxidation–weak reduction, and have all entered maturity stage. Ch9 crude oil is more mature than crude oils from Ch6 and Ch8, and has more advanced plants and fewer algae. Gas chromatography (GC) and gas chromatography–mass spectrometry (GC–MS) analysis show that crude oils from Ch6 and Ch8 may come from Ch7, and Ch9 crude oil may not. Cluster analysis displays that crude oils from Ch6 and Ch8 have closer squared Euclidean distance with Ch7 source rocks than Ch9 crude oil does, indicating crude oils from Ch6 and Ch8 stem from Ch7 source rocks. And Ch9 crude oil has rather close squared Euclidean distance with Ch9 source rocks, illustrating Ch9 crude oil may be from Ch9 source rocks. This research may provide the theoretical basis for the next exploration deploy in the south of Ordos Basin.     

Riverbank filtration in Cairo,Egypt: part II—detailed investigation of a new riverbank filtration site with a focus on manganese

A 5-day detailed field investigation at a new RBF test well gallery in Embaba, Cairo, was conducted to evaluate the hydraulic setting and the behavior of iron and manganese. The well gallery consists of six vertical wells placed along a straight line parallel to the Nile riverbank. A low anisotropy factor for the aquifer (k_f,h:k_f,v) of 1.7 was determined by evaluation of a multi-step pumping test. Travel times between 11 days from the river toward the central wells and 22 days toward the outermost wells were estimated by groundwater flow modeling and particle tracking. The riverbed is rich in fine suspended sediments that have elevated iron and nitrogen concentrations. Depth-dependent water sampling during regular well operation indicates that the thick organic-, Fe- and Mn-rich riverbed is the primary source for ammonium, iron and manganese in the bank filtrate. Iron-rich groundwater flow from the opposite riverbank was identified as a secondary source of iron in the pumped water. The vertical position of the filter screen affects total travel times but would not reduce the portion of Mn-rich bank filtrate. The authors recommend continuous well operation for achieving stable water quality and lowering the risk of well clogging.     

Influence of car body repair activities on particulate matter pollution in a suburban area (Bouzaréah City,Algiers)

This work was carried out in order to study the impact of car body repair activities in Bouzaréah City (suburban area located at the plateau of Algiers) on the air quality. Atmospheric particulate matter was targeted using high-volume sampler. Precisely, the particulate organic matter such as organophosphate esters, especially triphenyl phosphate and tributyl phosphate, was evaluated by the implementation of accelerated solvent extraction. The results of the major extractable organic components revealed that tributyl phosphate and triphenyl phosphate were found at 5.46 and 1.78 ng m^?3, respectively. On the other hand, the classical pollutants such as n-alkanes, n-alkanoic monocarboxylic acids and polycyclic aromatic hydrocarbons were also measured, respectively, at average total concentrations of 35.8, 107.4 and 9.8 ng m^?3. This work confirms that sanding and painting car bodies may contribute to air pollution, especially after detection of diethylnitrosamine which remains the most surprising compound in the particulate matter due to its volatility and can be considered as emerging contaminant.     

The geochemical and petrological characteristics of prenatal caldera volcano: a case of the newly formed small dacitic caldera,Hijiori, Northeast Japan

Evaluating the magma depth and its physical properties is critical to conduct a better geophysical assessment of magma chambers of caldera volcanoes that may potentially cause future volcanic hazards. To understand pre-eruptive conditions of a magma chamber before its first appearance at the surface, this paper describes the case of Hijiori caldera volcano in northeastern Japan, which emerged approximately 12,000 years ago at a place where no volcano ever existed. We estimated the depth, density, bulk modulus, vesicularity, crystal content, and bulk H\(_2\)O content of the magma chamber using petrographic interpretations, bulk and microchemical compositions, and thermodynamic calculations. The chemical mass balance calculations and thermodynamic modeling of the erupted magmas indicate that the upper portion of the Hijiori magmatic plumbing system was located at depths between 2 and 4 km, and had the following characteristics: (1) pre-eruptive temperature: about 780 \(^{\circ }\)C; (2) bulk magma composition: 66 ± 1.5 wt% SiO\(_{2}\); (3) bulk magmatic H\(_2\)O: approximately 2.5 wt%, and variable characteristics that depend on depth; (4) crystal content: \(\le\)57 vol%; (5) bulk modulus of magma: 0.1–0.8 GPa; (6) magma density: 1.8–2.3 g/cm³; and (7) amount of excess magmatic H\(_2\)O: 11–32 vol% or 48–81 mol%. The range of melt water contents found in quartz-hosted melt inclusions (2–9 wt%) suggests the range of depth phenocrysts growth to be wide (2\(\sim\)13 km). Our data suggest the presence of a vertically elongated magma chamber whose top is nearly solidified but highly vesiculated; this chamber has probably grown and re-mobilized by repeated injections of a small amount of hot dacitic magma originated from the depth.     

The Holocene record of Alberca de Tacámbaro,a tropical lake in western Mexico: evidence of orbital and millennial-scale climatic variability

Laminated sediments in a core from Alberca de Tacámbaro, western central Mexico, provide a high-resolution record of palaeoclimatic variability for most of the Holocene. Using compositional and textural characteristics we identified 14 facies classified in biogenic, clastic and volcaniclastic groups, in which diatoms and other algal remains are the most common components. In addition to facies analysis, high-resolution geochemical data from continuous core scanning XRF and the analysis of discrete samples for organic and inorganic carbon content, provide the basis for palaeoclimatic reconstruction. The age model indicates that the record spans from 9.4 cal ka bp toad 1760. Three main phases in the sequence are identified, controlled by millennial-scale variability. During the period between 9.4 and 5.7 cal kabp , the lake is dominated by siliceous organisms. Drier conditions between 8.2 and 6.3 cal kabp are linked to decreases in summer insolation and solar irradiance. By 5.7 cal kabp , the change in sedimentation is related to the increase in El Niño Southern Oscillation frequency. Evidence of the occurrence of dry conditions during the archaeological Late Classic period (ad 600–900) and historical droughts are also documented in the Alberca de Tacámbaro record. Unprecedented changes in the landscape are recorded afterad 1520.     

The Mazarrón basin,SE Spain: a study of mineralization processes,evolving magmatic series,and geothermal activity

The Miocene to Present Mazarrón basin provides a window on the metallogenic role of an evolving magmatic series. High-K calc–alkaline magmas gave rise to an important cluster of Pb–Zn–Ag–Cu vein and stockwork deposits emplaced in dacitic to rhyodacitic domes, part of a complex volcanic–metallogenic province (Au, Hg, Pb–Zn–Cu–Ag, Sn) stretching for ～150 km along the Mediterranean coast of SE Spain. By Pliocene time the former magmatic series had been replaced by intraplate alkaline basaltic volcanism, thus becoming the southern branch of the Western/Central Europe alkaline province. In terms of base metal sulphide deposits, this European province is barren, although it triggered widespread, CO₂-rich geothermal activity. Modern geothermal activity at El Saladillo (Mazarrón) resulted in the deposition of carbonate sinter deposits and formation of microbial mats. Proximal facies consist of millimetric to centimetric multicoloured layers of microbial mats, including yellow-orange thin bands of calcified bacteria and mineral growths of aragonite and calcite; green layers of live thermophilic Lyngbya-type cyanobacteria; black, degraded organic matter; and pyrite as the sole sulphide phase. Except for arsenic (37–63 μg g^?1), all of the studied trace elements (Ag, Ba, Bi, Cd, Cu, Pb, Sb, Se, and Sn) appear in remarkably low concentrations in the geothermal sinters. This is consistent with compositional data for the El Saladillo waters, with no significant metal concentrations. We present the first conceptual model (Miocene to Present) for the ore-forming processes, magmatism, CO₂ degasification, and geothermal activity for this realm. We argue that the time- and space-limited character of this volcanism (small, scattered outcrops), the deep magma emplacement level, the metal sulphide behaviour in alkaline basaltic magmatic chambers, and the dry character of these magmas prevented any metallogenic interaction between the chambers and the much shallower meteoric waters that drove the El Saladillo geothermal system and others of the same kind in Spain and elsewhere in Europe.     

Impact of agricultural activity and geologic controls on groundwater quality of the alluvial aquifer of the Guadalquivir River (province of Jaén,Spain): a case study

The alluvial aquifer of the Alto Guadalquivir River is one of the most important shallow aquifers in Jaén, Spain. It is located in the central-eastern part of the province, and its groundwater resources are used mainly for crop irrigation in an agriculture-dominated area. Hydrochemical and water-quality data obtained through a 2-year sampling (2004–2006) and analysis program indicate that nitrate pollution is a serious problem affecting groundwater due to the use of nitrogen (N)-fertilizers in agriculture. During the study, 231 water samples were collected from wells and springs to determine water chemistry and the extent of nitrate pollution. The concentration of nitrate in groundwater ranged from 1.25 to 320.88 mg/l. Considerable seasonal fluctuations in groundwater quality were observed as a consequence of agricultural practices and other factors such as annual rainfall distribution and the Guadalquivir River flow regime. The chemical composition of the water is not only influenced by agricultural practices, but also by interaction with the alluvial sediments. The dissolution of evaporites accounts for part of the Na⁺, K⁺, Cl⁻, SO₄ ²⁻, Mg²⁺, and Ca²⁺, but other processes, such as calcite precipitation and dedolomitization, also contribute to groundwater chemistry.     

Kinematic analysis of a transtensional fault system: The Atuel depocenter of the Neuquén basin,southern Central Andes,Argentina

The Atuel depocenter of the Neuquén basin originated as an Upper Triassic to Lower Jurassic rift system, later inverted during the Andean contractional deformation. In order to study the extensional architecture and the kinematic evolution of this depocenter, we collected a large amount of field and sub-surface data, consisting of slip data from outcrop-scale normal faults, thickness and facies distribution within the synrift deposits, and structural data from angular and progressive unconformities. The Atuel depocenter has a NNW trend, showing a bimodal distribution of NNW and WNW major faults (first and second order faults). On the other hand, from kinematic indicators measured on outcrop-scale faults (third and fourth order faults), we found a mean NE internal extension direction, which is oblique to the general trend of the sub-basin. Taking these particular characteristics into account, we interpreted the Atuel depocenter as an oblique rift system. We evaluated two mechanisms in order to explain the development of this transtensional system: 1) reactivation of upper-crustal NNW-oriented Paleozoic shear zones, and 2) oblique stretching of a previous NNW-oriented lithospheric weakness zone.