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1.
We present absorption cross sections of propane (C3H8) at temperatures from 145 K to 297 K in the 690–1550 cm−1 region. Pure and N2-broadened spectra were measured at pressures from 3 Torr to 742 Torr using a Bruker IFS125 FT-IR spectrometer at JPL. The gas absorption cell, developed at Connecticut College, was cooled by a closed-cycle helium refrigerator. The cross sections were measured and compiled for individual spectra recorded at various experimental conditions covering the planetary atmosphere and Titan. In addition to the cross sections, a propane pseudoline list with a frequency grid of 0.005 cm−1, was fitted to the 34 laboratory spectra. Line intensities and lower state energies were retrieved for each line, assuming a constant width. Validation tests showed that the pseudoline list reproduces discrete absorption features and continuum, the latter contributed by numerous weak and hot band features, in most of the observed spectra within 3%. Based on the pseudoline list, the total intensity in the 690–1550 cm−1 region was determined to be 52.93 (±3%) × 10−19 cm−1/(molecule cm−2) at 296 K; this value is within 3% of the average from four earlier studies. Finally, the merit of the pseudoline approach is addressed for heavy polyatomic molecules in support of spectroscopic observation of atmospheres of Titan and other planets. The cold cross sections will be submitted to the HITRAN database (hitran.harvard.edu), and the list of C3H8 pseudolines will be available from a MK-IV website of JPL (http://mark4sun.jpl.nasa.gov/data/spec/Pseudo).  相似文献   

2.
《Planetary and Space Science》2007,55(10):1328-1345
The planetary fourier spectrometer (PFS) for the Mars express mission (MEX) is an infrared spectrometer operating in the wavelength range from 1.2 to 45 μm by means of two spectral channels, called SWC (short wavelength channel) and LWC (long wavelength channel), covering, respectively, 1.2–5.5 and 5.5–45 μm.The middle-spring Martian north polar cap (Ls∼40°) has been observed by PFS/MEX in illuminated conditions during orbit 452. The SWC spectra are here used to study the cap composition in terms of CO2 ice, H2O ice and dust content. Significant spectral variation is noted in the cap interior, and regions of varying CO2 ice grain sizes, water frost abundance, CO2 ice cover and dust contamination can be distinguished. In addition, we correlate the infrared spectra with an image acquired during the same orbit by the OMEGA imaging spectrometer and with the altimetry from MOLA data. Many of the spectra variations correlate with heterogeneities noted in the image, although significant spectral variations are not discernible in the visible. The data have been divided into five regions with different latitude ranges and strong similarities in the spectra, and then averaged. Bi-directional reflectance models have been run with the appropriate lighting geometry and used to fit the observed data, allowing for CO2 ice and H2O ice grain sizes, dust and H2O ice contaminations in the form of intimate granular mixtures and spatial mixtures.A wide annulus of dusty water ice surrounds the recessing CO2 seasonal cap. The inner cap exhibits a layered structure with a thin CO2 layer with varying concentrations of dark dust, on top of an H2O ice underneath ground. In the best-fits, the ices beneath the top layer have been considered as spatial mixtures. The results are still very good everywhere in the spectral range, except where the CO2 ice absorption coefficients are such that even a thin layer is enough to totally absorb the incoming radiation (i.e. the band is saturated). This only happens around 3800 cm−1, inside the strong 2.7-μm CO2 ice absorption band. The effect of finite snow depth has been investigated through a layered albedo model. The thickness of the CO2 ice deposits increases with latitude, ranging from 0.5–1 g cm−2 within region II to 60–80 g cm−2 within the highest-latitude (up to 84°N) region V.Region I is at the cap edge and extends from 65°N to 72°N latitude. No CO2 ice is present in this region, which consists of relatively large grains of water ice (20 μm), highly contaminated by dust (0.15 wt%). The adjacent region II is a narrow region [76–79°N] right at the edge of the north residual polar cap. This region is very distinct in the OMEGA image, where it appears to surround the whole residual cap. The CO2 ice features are barely visible in these spectra, except for the strong saturated 2.7 μm band. It basically consists of a thin layer of 5-mm CO2 ice on top of an H2O ice layer with the same composition as region I. A third interesting region III is found all along the shoulder of the residual cap [79–81°N]. It extends over 1.5 km in altitude and over only 2° of latitude and consists of CO2 ice with a large dust content. It is an admixture of CO2 ice (3–4 mm), with several tens of ppm by mass of water ice and more than 2 ppt by mass of dust. The surface temperatures have been retrieved from the LWC spectra for each observation. We found an increase in the surface temperature in this region, indicating a spatial mixture of cold CO2 ice and warmer dust/H2O ice. Region IV is close to the top of the residual cap [81–84°N]; it is much brighter than region III, with a dust content 10 times lower than the latter. The CO2 grain size is 3 mm and strong CO2 ice features are present in the data, indicating a thicker CO2 ice layer than in region II (1–2 g cm−2). The final region V is right at the top of the residual cap (⩾84°N). It is “pure” CO2 ice (no dust) of 5 mm grain sizes, with 30 ppm by weight of water ice. The CO2 ice features are very pronounced and the 2.7 μm band is saturated. The optical thickness is close to the semi-infinite limit (30–40 g cm−2). Assuming a snowpack density of 0.5 g cm−3, we get a minimum thickness of 1–2 cm for the top-layer of regions II and III, 4–10 cm for region IV, and ⩾60–80 cm thickness for region V. These values are in close agreement with several recent results for the south seasonal polar cap.These results should provide new, useful constraints in models of the Martian climate system and volatile cycles.  相似文献   

3.
We report the Balmer broad absorption lines (BALs) in the quasar SDSS J2220 + 0109 discovered from the SDSS data, and present a detailed analysis of the peculiar absorption line spectrum, including the He I* multiplet at λλ3189, 3889 arising from the metastable 23s-state helium and the Balmer Hα and Hβ lines from the excited hydrogen H I of n = 2 level, which are rarely seen in quasar spectra, as well as many absorption lines arising from the excited Fe II* of the levels 7 955 cm−1, 13 474 cm−1 and 13 673 cm−1 in the wavelength range 3100∼3300 Å. Ca II H, K absorption line doublets also clearly appear in the SDSS spectrum. All absorption lines show a similar blueshifted velocity structure of Δv ≈ − 1500 ∼ 0 km·s−1 relative to the quasar's systematic redshift determined from the emission lines. Detailed analysis suggests that the Balmer absorption lines should arise from the partially ionized region with a column density of NHI ≈ 1021 cm−2 for an electron density of ne ∼ 106 cm−3; and that the hydrogen n = 2 level may be populated via collisional excitation with Lyα pumping.  相似文献   

4.
We present near-IR spectra of solid CO2 in H2O and CH3OH, and find they are significantly different from that of pure solid CO2. Peaks not present in either pure H2O or pure CO2 spectra become evident when the two are mixed. First, the putative theoretically forbidden CO2 (2ν3) overtone near 2.134 μm (4685 cm−1), that is absent from our spectrum of pure solid CO2, is prominent in the spectra of H2O/CO2=5 and 25 mixtures. Second, a 2.74-μm (3650 cm−1) dangling OH feature of H2O (and a potentially related peak at 1.89 μm) appear in the spectra of CO2-H2O ice mixtures, but are probably not diagnostic of the presence of CO2. Other CO2 peaks display shifts in position and increased width because of intermolecular interactions with H2O. Warming causes some peak positions and profiles in the spectrum of a H2O/CO2=5 mixture to take on the appearance of pure CO2. Absolute strengths for absorptions of CO2 in solid H2O are estimated. Similar results are observed for CO2 in solid CH3OH. Since the CO2 (2ν3) overtone near 2.134 μm (4685 cm−1) is not present in pure CO2 but prominent in mixtures, it may be a good observational (spectral) indicator of whether solid CO2 is a pure material or intimately mixed with other molecules. These observations may be applicable to Mars polar caps as well as outer Solar System bodies.  相似文献   

5.
High-resolution (∼0.22 Å) spectra of the north jovian aurora were obtained in the 905-1180 Å window with the Far Ultraviolet Spectroscopic Explorer (FUSE) on October 28, 2000. The FUSE instrument resolves the rotational structure of the H2 spectra and the spectral range allows the study of self-absorption. Below 1100 Å, transitions connecting to the v?2 levels of the H2 ground state are partially or totally absorbed by the overlying H2 molecules. The FUSE spectra provide information on the overlying H2 column and on the vibrational distribution of H2. Transitions from high-energy H2 Rydberg states and treatment of self-absorption are considered in our synthetic spectral generator. We show comparisons between synthetic and observed spectra in the 920-970, 1030-1080, and 1090-1180 Å spectral windows. In a first approach (single-layer model ), the synthetic spectra are generated in a thin emitting layer and the emerging photons are absorbed by a layer located above the source. It is found that the parameters of the single-layer model best fitting the three spectral windows are 850, 800, and 800 K respectively for the H2 gas temperature and 1.3×1018, 1.5×1020, and 1.3×1020 cm−2 for the H2 self-absorbing vertical column respectively. Comparison between the H2 column and a 1-D atmospheric model indicates that the short-wavelength FUV auroral emission originates from just above the homopause. This is confirmed by the high H2 rovibrational temperatures, close to those deduced from spectral analyses of H+3 auroral emission. In a second approach, the synthetic spectral generator is coupled with a vertically distributed energy degradation model, where the only input is the energy distribution of incoming electrons (multi-layer model ). The model that best fits globally the three FUSE spectra is a sum of Maxwellian functions, with characteristic energies ranging from 1 to 100 keV, giving rise to an emission peak located at 5 μbar, that is ∼100 km below the methane homopause. This multi-layer model is also applied to a re-analysis of the Hopkins Ultraviolet Telescope (HUT) auroral spectrum and accounts for the H2 self-absorption as well as the methane absorption. It is found that no additional discrete soft electron precipitation is necessary to fit either the FUSE or the HUT observations.  相似文献   

6.
Nearly ten years ago Kwan and Krolik (1979, 1981) published the firstsuccessful photoionization model of the Broad Line Region of Active Galactic Nuclei, the so-called ‘Standard Model’. Since then several efforts have been made to obtain better results using more sophisticated models. Anopen issue is that photoionization models are generally computed startingfrom the assumption that the emission line spectrum is produced by a single-slab cloud with a ‘standard’ hydrogen density nH = 109.5 cm-3, but it seems more likely that a range of densities is present in the Broad Line Region. Purpose of this paper is to review the results given by single-cloud models using the most recent photoionization code, Cloudy 84, and to investigate if the addition of one or more components with different densities does affect the line ratios. To this aim we compute the emission line ratios produced by photoionized single-slab clouds for a wide range of hydrogen densities (nH = 109.5−1013 cm−3), ionization parameters (U = 10−4− 10−0.5) and column densities (NH = 1023−1025 cm−2). Two or more populations of clouds are then combined and the resulting emission line spectrum is compared with a sample of mean observed line ratios. We find that the addition to the standard component of clouds having different densities and located at different positions from the central source introduces many changes in the line ratios, and that these changes are in the direction of a better agreement with the observed emission line ratios.  相似文献   

7.
Using a one-dimensional model, we investigate the hydrogen budget and escape to space in Titan’s atmosphere. Our goal is to study in detail the distributions and fluxes of atomic and molecular hydrogen in the model, while identifying sources of qualitative and quantitative uncertainties. Our study confirms that the escape of atomic and molecular hydrogen to space is limited by the diffusion through the homopause level. The H distribution and flux inside the atmosphere are very sensitive to the eddy diffusion coefficient used above altitude 600 km. We chose a high value of this coefficient 1 × 108 cm2 s−1 and a homopause level around altitude 900 km. We find that H flows down significantly from the production region above 500 km to the region [300-500] km, where it recombines into H2. Production of both H and H2 also occurs in the stratosphere, mostly from photodissociation of acetylene. The only available observational data to be compared are the escape rate of H deduced from Pioneer 11 and IUE observations of the H torus 1-3 × 109 cm−2 s−1 and the latest retrieved value of the H2 mole fraction in the stratosphere: (1.1 ± 0.1) × 10−3. Our results for both of these values are at least 50-100% higher, though the uncertainties within the chemical schemes and other aspects of the model are large. The chemical conversion from H to H2 is essentially done through catalytic cycles using acetylene and diacetylene. We have studied the role of this diacetylene cycle, for which the associated reaction rates are poorly known. We find that it mostly affects C4 species and benzene in the lower atmosphere, rather than the H profile and the hydrogen budget. We have introduced the heterogenous recombination of hydrogen on the surface of aerosol particles in the stratosphere, and this appears to be a significant process, comparable to the chemical processes. It has a major influence on the H distribution, and consequently on several other species, especially C3H4, C4H2 and C6H6. Therefore, this heterogenous process should be taken into account when trying to understand the stratospheric distribution of these hydrocarbons.  相似文献   

8.
Spatially resolved spectra in four 50-Å FUV spectral windows were obtained across the jovian aurora with the Space Telescope Imaging Spectrograph (STIS) on board the Hubble Space Telescope. Nearly simultaneous ultraviolet imaging makes it possible to correlate the intensity variations along the STIS slit with those observed in the images and to characterize the global auroral context prevailing at the time of the observations. Spectra at ∼1-Å resolution taken in pairs included an unabsorbed window and a spectral region affected by hydrocarbon absorption. Both sets of spectra correspond to an aurora with a main oval brightness of about 130 kilorayleighs of H2 emission. The far ultraviolet color ratios I(1550-1620 Å)/I(1230-1300 Å) are 2.3 and 5.9 for the noon and morning sectors of the main oval, respectively. We use an interactive model coupling the energy degradation of incoming energetic electrons, auroral temperature and composition, and synthetic H2 spectra to fit the intensity distribution of the H2 lines. It is found that the model best fitting globally the spectra has a soft energy component in addition to a 10 erg cm−2 s−1 flux of 80 keV electrons. It provides an effective H2 temperature of 540 K. The relative intensity of temperature-sensitive H2 lines indicates differences between the auroral main oval and polar cap emissions. The amount of methane absorption across the polar region is shown to vary in a way consistent with temperature. For the second spectral pair, the polar cap shows a higher attenuation by CH4, indicating a harder precipitation along high-latitude magnetic field lines.  相似文献   

9.
We report sensitive Chandra X-ray non-detections of two unusual, luminous Iron Low-Ionization Broad Absorption Line Quasars (FeLoBALs). The observations do detect a non-BAL, wide-binary companion quasar to one of the FeLoBAL quasars. We combine X-ray-derived column density lower limits (assuming solar metallicity) with column densities measured from ultraviolet spectra and CLOUDY photoionization simulations to explore whether constant-density slabs at broad-line region densities can match the physical parameters of these two BAL outflows, and find that they cannot. In the “overlapping-trough” object SDSS J0300+0048, we measure the column density of the X-ray absorbing gas to be NH ? 1.8 × 1024 cm?2. From the presence of Fe ii UV78 absorption but lack of Fe ii UV195/UV196 absorption, we infer the density in that part of the absorbing region to be ne ? 106 cm?3. We do find that a slab of gas at that density might be able to explain this object’s absorption. In the Fe iii-dominant object SDSS J2215–0045, the X-ray absorbing column density of NH ? 3.4 × 1024 cm?2 is consistent with the Fe iii-derived NH ? 2 × 1022 cm?2 provided the ionization parameter is log U > 1.0 for both the ne = 1011 cm?3 and ne = 1012 cm?3 scenarios considered (such densities are required to produce Fe iii absorption without Fe iiabsorption). However, the velocity width of the absorption rules out its being concentrated in a single slab at these densities. Instead, this object’s spectrum can be explained by a low density, high ionization and high temperature disk wind that encounters and ablates higher density, lower ionization Fe iii-emitting clumps.  相似文献   

10.
Using new laboratory spectra, we have calculated the real and imaginary parts of the index of refraction of amorphous and crystalline H2O-ice from 20 to 150 K in the frequency range 9000-3800 cm−1 (1.1-2.6 μm) at a spectral resolution of 1 cm−1. These optical constants can be used to create model spectra for comparison to spectra from Solar System objects. We also analyzed the differences between the amorphous and crystalline H2O-ice spectra, including weakening of bands and shifting of bands to shorter wavelength in amorphous H2O-ice spectra. We have also observed two spectrally distinct phases of amorphous H2O-ice.  相似文献   

11.
Jeffrey R. Johnson 《Icarus》2012,221(1):359-364
Andesine-rich (An36–46) anorthosite rocks experimentally shocked to high pressures (16–57 GPa) exhibit changes in spectral features with increasing pressure in laboratory thermal infrared emission spectra (250–1400 cm?1). These results are similar to previous studies of shocked bytownite- and albite-rich rocks, albeit with differences in absorption band centers characteristic of mineralogy and composition. Typical spectral absorptions result from Si–O antisymmetric stretch motions of the silica tetrahedral (1000–1250 cm?1) and weaker absorptions due to Si–O–Si octahedral bending vibrations (350–700 cm?1). Many of these features persist to higher pressures in the andesine spectra compared to similar features in measurements of shocked bytownite. This is consistent with previous thermal infrared absorption studies of shocked feldspars and likely is related to differences in density, hardness, and Al content. A transparency feature at ~832 cm?1 observed in powdered andesine spectra also degrades with increasing pressure, intermediate between the ~828 cm?1 and ~855 cm?1 transparency features in spectra of powders of shocked bytownite and albitite, respectively. These data can be incorporated into thermal infrared spectral analyses of cratered planetary surfaces (or laboratory spectra of shocked samples) to help constrain the occurrence and degree of shock in plagioclase feldspars.  相似文献   

12.
The propagation of ionizing radiation through model atmospheres of terrestrial-like exoplanets is studied for a large range of column densities and incident photon energies using a Monte Carlo code we have developed to treat Compton scattering and photoabsorption. Incident spectra from parent star flares, supernovae, and gamma-ray bursts are modeled and compared to energetic particles in importance. Large irradiation events with fluences of 106-109 erg cm−2 at the conventional habitable zone can occur at a rate from many per day (flares from young low-mass parent stars) to ∼100 per Gyr (supernovae and gamma-ray bursts). We find that terrestrial-like exoplanets with atmospheres thinner than about 100 g cm−2 block nearly all X-rays, but transmit and reprocess a significant fraction of incident γ-rays, producing a characteristic, flat surficial spectrum. Thick atmospheres (?100 g cm−2) efficiently block even γ-rays, but nearly all the incident energy is redistributed into diffuse UV and visible aurora-like emission, increasing the effective atmospheric transmission by many orders of magnitude. Depending on the presence of molecular UV absorbers and atmospheric thickness, up to 10% of the incident energy can reach the surface as UV reemission. For the Earth, between 2×10−3 and 4×10−2 of the incident flux reaches the ground in the biologically effective 200-320 nm range, depending on O2/O3 shielding. For atmospheres thicker than ∼50 g cm−2 in the case of pure Rayleigh scattering and ∼100 g cm−2 in the case of O2/O3 absorption, the UV reemission exceeds the surficial transmitted ionizing radiation. We also discuss the effects of angle of incidence and derive a modified two-stream approximation solution for the UV transfer. Finally, we suggest that transient atmospheric ionization layers can be frequently created at altitudes lower than the equilibrium layers that result from steady irradiation and winds from the parent star. We suggest that these events can produce frequent fluctuations in atmospheric ionization levels and surficial UV fluxes on terrestrial-like planets.  相似文献   

13.
14.
Photoionization of the upper atmosphere of Titan by sunlight is expected to produce a substantial ionospheric layer. We have solved one-dimensional forms of the mass, momentum, and energy conservation equations for ions and electrons and have obtained electron number densities of about 103 cm?3, using various model atmospheres. The significant ions in a CH4H2 atmosphere are H+, H3+, CH5+, CH5+, CH3+, and C2H5+. Electron temperatures may be as high as 1000°K, depending on the abundance of hydrogen in the high atmosphere. Interaction of the solar wind with the ionosphere is also discussed.  相似文献   

15.
S.K. Atreya  T.M. Donahue 《Icarus》1975,24(3):358-362
Model ionospheres are calculated for Saturn, Uranus, and Neptune. Protons are the major ions above 150 km altitude measured from a reference level where the hydrogen density is 1 × 1016 molecules cm?3, while below 150 km quick conversion of protons to H3+ ions by a three-body association mechanism leads to a rapid removal of ionization in dissociative recombination of H3+. Electron density maxima are found at about 260 km for Saturn and Uranus and 200 km for Neptune. Present knowledge of the physical and chemical processes in the atmospheres of these planets suggests that their ionospheres probably will not be Jupiter-like.  相似文献   

16.
Previous studies of the photochemistry of small molecules in Titan’s atmosphere found it difficult to have hydrogen atoms removed at a rate sufficient to explain the observed abundance of unsaturated hydrocarbons. One qualitative explanation of the discrepancy nominated catalytic aerosol surface chemistry as an efficient sink of hydrogen atoms, although no quantitative study of this mechanism was attempted. In this paper, we quantify how haze aerosols and macromolecules may efficiently catalyze the formation of hydrogen atoms into H2. We describe the prompt reaction model for the formation of H2 on aerosol surfaces and compare this with the catalytic formation of H2 using negatively charged hydrogenated aromatic macromolecules. We conclude that the PRM is an efficient mechanism for the removal of hydrogen atoms from the atmosphere to form H2 with a peak formation rate of ∼ 70 cm−3 s−1 at 420 km. We also conclude that catalytic H2 formation via hydrogenated anionic macromolecules is viable but much less productive (a maximum of ∼ 0.1 cm−3 s−1 at 210 km) than microphysical aerosols.  相似文献   

17.
The combination of a time-dependent spherically symmetric hydrodynamic model of stellar atmosphere pulsation and a radiation transport code, which incorporates maser saturation theory, enabled us to synthesise maps and spectra of H2O maser emission from the circumstellar envelopes of long period variable stars. The synthetic maps and spectra compare favourably with observed 22, 321 and 325 GHz H2O maser emission. As is observed in H2O maser regions the peak emission occurs between 3–8 stellar radii from the star. The calculated H2O maser regions are in conditions of nH2 = 106 − 108 cm−3, assuming a fractional abundance of 10−4; kinetic temperatures of 550–3000 K; dust ensemble temperatures of 500–1200 K and an accelerating velocity field. The IR radiation field is explicitly included in the radiation transport model, incorporating the latest absorption efficiency data for silicates from Draine. We reproduce the features seen in high angular resolution MERLIN spectral line datacubes. This shows that a mass outflow model which extends the photosphere using pulsations and incorporates radiation pressure on silicate based dust particles can produce the observed data on small (10-mas) angular scales. This revised version was published online in September 2006 with corrections to the Cover Date.  相似文献   

18.
Optical CCD imaging with Hα and [SII] filters and spectroscopic observations of the galactic supernova remnant G85.9-0.6 have been performed for the first time. The CCD image data are taken with the 1.5 m Russian-Turkish Telescope (RTT150) at TüBİTAK National Observatory (TUG) and spectral data are taken with the Bok 2.3 m telescope on Kitt Peak, AZ. The images are taken with narrow-band interference filters Hα, [SII] and their continuum. [SII]/Hα ratio image is performed. The ratio obtained from [SII]/Hα is found to be ∼0.42, indicating that the remnant interacts with HII regions. G85.9-0.6 shows diffuse-shell morphology. [SII]λ λ6716/6731 average flux ratio is calculated from the spectra, and the electron density N e is obtained to be 395 cm−3. From [OIII]/Hβ ratio, shock velocity has been estimated, pre-shock density of n c =14 cm−3, explosion energy of E=9.2×1050 ergs, interstellar extinction of E(BV)=0.28, and neutral hydrogen column density of N(HI)=1.53×1021 cm−2 are reported.  相似文献   

19.
The reactivity of C2(X1Σ+g) with simple saturated (CH4, C2H6 and C3H8) and unsaturated (C2H2 and C2H4) hydrocarbons has been studied in the gas phase over the temperature range 24-300 K using the CRESU (Cinétique de Réaction en Ecoulement Supersonique Uniforme or Reaction Kinetics in a Uniform Supersonic Flow) technique. All reactions have been found to be very rapid in this temperature range and the rate coefficients are typically ?10−10 cm3 molecule−1 s−1 with the exception of methane for which the rate coefficient is one order of magnitude lower: ∼10−11 cm3 molecule−1 s−1. These results have been analyzed in terms of potential destruction sources of C2(X1Σ+g) in the atmospheres of Titan and the Giant Planets. It appears that the rate coefficient of the reaction 1C2 + CH4 should be updated with our new data and that reactions with C2H2, C2H4 and C2H6 should also be included in the existing photochemical models.  相似文献   

20.
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