Investigation of the force balance in the Titan ionosphere: Cassini T5 flyby model/data comparisons

Cassini’s Titan flyby on 16 April, 2005 (T5) is the only encounter when the two main ionizing sources of the moon’s atmosphere, solar radiation and corotating plasma, align almost anti-parallel. In this paper a single-fluid multi-species 3D MHD model of the magnetospheric plasma interaction for T5 conditions is analyzed. Model results are compared to observations to investigate the ionospheric dynamics at Titan as well as to understand the deviations from a typical solar wind interaction, such as Venus’ interaction with the solar wind. Model results suggest that for the T5 interaction configuration, corotating plasma is the dominant driver determining the global interaction features at high altitudes. In the lower ionosphere below ～1500 km altitude – where the control of the ionospheric composition transfers from dynamic to chemical processes – magnetic and thermal pressure gradients oppose each other locally, complicating the ionospheric dynamics. Model results also imply that the nightside ionosphere – produced only by the impact ionization in the model – does not provide enough thermal pressure to balance the incident plasma dynamic pressure. As a result, the induced magnetic barrier penetrates into the ionosphere by plasma convection down to ～1000 km altitude and by magnetic diffusion below this altitude. Moreover, strong horizontal drag forces due to ion-neutral collisions and comparable drag forces estimated from possible neutral winds in the lower ionosphere below ～1400 km altitude oppose over local regions, implying that the Titan interaction must be treated as a 3D problem. Ion and electron densities calculated from the model generally agree with the Cassini Ion Neutral Mass Spectrometer and Langmuir probe measurements; however, there are significant differences between the calculated and measured magnetic fields. We discuss possible explanations for the discrepancy in the magnetic field predictions.     

Galactic cosmic rays and N2 dissociation on Titan

The electromagnetic and particle cascade resulting from the absorption of galactic cosmic rays in the atmosphere of Titan is shown to be an important mechanism for driving the photochemistry at pressures of 1 to 50 mbar in the atmosphere. In particular, the cosmic ray cascade dissociates N₂, a process necessary for the synthesis of nitrogen organics such as HCN. The important interactions of the cosmic ray cascade with the atmosphere are discussed. The N₂ excitation and dissociation rates and the ionization rates of the principal atmospheric constituents are computed for a Titan model atmosphere that is consistent with Voyager 1 observations. It is suggested that HCN may be formed efficiently in the lower atmosphere through the photodissociation of methylamine. It is also argued that models of nitrogen and hydrocarbon photochemistry in the lower atmosphere of Titan should include the absorption of galactic cosmic rays as an important energy source.     

The lower ionosphere of Titan

Ionization of the atmosphere of Titan by galactic cosmic rays is a very significant process throughout the altitude range of 100 to 400 km. An approximate form of the Boltzmann equation for cosmic ray transport has been used to obtain local ionization rates. Models of both ion and neutral chemistry have been employed to compute electron and ion density profiles for three different values of the H₂/CH₄ abundance ratio. The peak electron density is of the order 10³ cm^?3. The most abundant positive ions are C₂H₉⁺ and C₃H₉⁺, while the predicted densities of the negative ions H^? and CH₃^? are very small (<10^?4 that of the positive ions). It is suggested that inclusion of the ion chemistry is important in the computation of the H and CH₃ density profiles in the lower ionosphere.     

Day-side ionospheric conductivities at Mars

We present estimates of the day-side ionospheric conductivities at Mars based on magnetic field measurements by Mars Global Surveyor (MGS) at altitudes down to ∼100 km during aerobraking orbits early in the mission. At Mars, the so-called ionospheric dynamo region, where plasma/neutral collisions permit electric currents perpendicular to the magnetic field, lies between 100 and 250 km altitude. We find that the ionosphere is highly conductive in this region, as expected, with peak Pedersen and Hall conductivities of 0.1-1.5 S/m depending on the solar illumination and induced magnetospheric conditions. Furthermore, we find a consistent double peak pattern in the altitude profile of the day-side Pedersen conductivity, similar to that on Titan found by Rosenqvist et al. (2009). A high altitude peak, located between 180 and 200 km, is equivalent to the terrestrial peak in the lower F-layer. A second and typically much stronger layer of Pedersen conductivity is observed between 120 and 130 km, which is below the Hall conductivity peak at about 130-140 km. In this altitude region, MGS finds a sharp decrease in induced magnetic field strength at the inner magnetospheric boundary, while the day-side electron density is known to remain high as far down as 100 km. We find that such Titan-like behaviour of the Pedersen conductivity is only observed under regions of strongly draped magnetospheric field-lines, and negligible crustal magnetic anomalies below the spacecraft. Above regions of strong crustal magnetic anomalies, the Pedersen conductivity profile becomes more Earth-like with one strong Pedersen peak above the Hall conductivity peak. Here, both conductivities are 1-2 orders of magnitude smaller than the above only weakly magnetised crustal regions, depending on the strength of the crustal anomaly field at ionospheric altitudes. This nature of the Pedersen conductivity together with the structured distribution of crustal anomalies all over the planet should give rise to strong conductivity gradients around such anomalies. Day-side ionospheric conductivities on Mars (in regions away from the crustal magnetic anomalies) and Titan seem to behave in a very similar manner when horizontally draped magnetic field-lines partially magnetise a sunlit ionosphere. Therefore, it appears that a similar double peak structure of strong Pedersen conductivity could be a more general feature of non-magnetised bodies with ionised upper atmospheres, and thus should be expected to occur also at other non-magnetised terrestrial planets like Venus or other planetary bodies within the host planet magnetospheres.     

Local plasma processes and enhanced electron densities in the lower ionosphere in magnetic cusp regions on Mars

Both the MARSIS ionospheric sounder and the charged particle instrument package ASPERA-3 are experiments on board the Mars Express spacecraft. Joint observations have shown that events of intense ionospheric electron density enhancements occur in the lower ionosphere of magnetic cusp regions, and that these enhancements are not associated with precipitation of charged particles above a few hundred electron volts (<300 eV). To account for the enhancement by particle precipitation, electron fluxes are required with mean energy between 1 and 10 keV. No ionizing radiation, neither energetic particles nor X-rays, could be identified, which could produce the observed density enhancement only in the spatially limited cusp regions. Actually, no increase in ionizing radiation, localized or not, was observed during these events. It is argued that the process causing the increase in density is controlled mainly by convection of ionosphere plasma driven by the interaction between the solar wind and crustal magnetic field lines leading to excitation of two-stream plasma waves in the cusp ionosphere. The result is to heat the plasma, reduce the electron–ion recombination coefficient and thereby increase the equilibrium electron density.     

A New look at the ionosphere of Jupiter in light of the UVS occultation results

Simple photochemical models cannot reconcile Jupiter's ionospheric electron density profiles with the observed neutral atmosphere. The location of the peak electron density predicted when the neutral atmosphere determined by theVoyager Ultraviolet Spectrometer is combined with simple models falls about 1000km lower than the peak determined by radio occultation. The locations and magnitudes of the peaks in electron density can be accounted for by including the effects of vertical transport of ions in the ionospheric models. This vertical transport may be induced by meridional winds in the neutral atmosphere or external electric fields. It is probable that precipitating particles and an altitude-variable H₂ vibrational temperature play important roles in determining the character of the iono?phere. In view of the complex relationship between the ionosphere and neutral atmosphere, an attempt to infer one from the other cannot succeed. However, combining independent information on the two leads to new insights into the coupling of the neutral atmosphere, the ionosphere and the magnetosphere.     

Comparisons of Cassini flybys of the Titan magnetospheric interaction with an MHD model: Evidence for organized behavior at high altitudes

Recent papers suggest the significant variability of conditions in Saturn’s magnetosphere at the orbit of Titan. Because of this variability, it was expected that models would generally have a difficult time regularly comparing to data from the Titan flybys. However, we find that in contrast to this expectation, it appears that there is underlying organization of the interaction features roughly above ～1800 km (1.7 Rt) altitude by the average external field due to Saturn’s dipole moment. In this study, we analyze Cassini’s plasma and magnetic field data collected at 9 Titan encounters during which the external field is close to the ideal southward direction and compare these observations to the results from a 2-fluid (1 ion, 1 electron) 7-species MHD model simulations obtained under noon SLT conditions. Our comparative analysis shows that under noon SLT conditions the Titan plasma interaction can be viewed in two layers: an outer layer between 6400 and 1800 km where interaction features observed in the magnetic field are in basic agreement with a purely southward external field interaction and an inner layer below 1800 km where the magnetic field measurements show strong variations and deviate from the model predictions. Thus the basic features inferred from the Voyager 1 flyby seem to be generally present above ～1800 km in spite of the ongoing external variations from SLT excursions, time variability and magnetospheric current systems as long as a significant southward external field component is present. At around ～1800 km kinetic effects (such as mass loading and heavy ion pickup) and below 1800 km ionospheric effects (such as drag of ionospheric plasma due to coupling with neutral winds and/or magnetic memory of Titan’s ionosphere) complicate what is observed.     

Cosmic ray ionization of the Jovian atmosphere

An approximate form of the Boltzmann equation has been used to obtain local ionization rates due to the absorption of galactic cosmic rays in the Jovian atmosphere. It is shown that the muon flux component of the cosmic ray-induced cascade may be especially importannt in ionizing the atmosphere at levels where the total number density exceeds 10¹⁹ cm^?3 (well below the ionospheric layers produced by solar euv). A model containing both positive and negative ion reactions has been employed to compute equilibrium electron and ion number densities. Peak electron number densities on the order of 10³ cm^?3 may be expected even at relatively low magnetic latitudes. The dominant positive ions are NH₄⁺ and C_nH_m⁺ cluster ions, with n ? 2; it is suggested that the absorption of galactic cosmic ray energy at such relatively high pressures in the Jovian atmosphere $\text{(M ? 10}{}^{18}\text{to}\text{10}{}^{20}\text{cm}{}^{\mathrm{?3}}\text{)}$ and the subsequent chemical reactions may be instrumental in the local formation of complex hydrocarbons.     

Detection of Titan's Ionosphere from Voyager 1 Radio Occultation Observations

Evidence for a marginal detection of the Titan ionosphere has been obtained from a new analysis of the dual-frequency Doppler data recorded during theVoyager 1occultation in 1980. The original report by Lindalet al.(1983,Icarus53,348–363) gave only upper bounds on the peak electron density of 3000 cm⁻³during ingress (evening terminator) and 5000 cm⁻³during egress (morning terminator). The dual-frequency ingress data imply a maximum electron density of 2400 ± 1100 cm⁻³for Titan's upper ionosphere at an altitude of 1180 ± 150 km. The egress data were determined to be of limited use for this analysis because the X-band signal was received for only a few seconds. Nevertheless, a distinct ionospheric peak is revealed in the S-band data for both ingress and egress. The height and peak density of this ionized layer are in good agreement with expectations from numerical models that invoke photoionization and energetic electron impacts.     

Possible production by lightning of aerosols and trace gases in Titan's atmosphere

Although lightning has not yet been observed in Titan's atmosphere, the presence of condensable vapors and the deposition of a significant amount of solar energy at the surface suggest the possibility of lightning activity. Based on an understanding of the relationship of lightning activity to the amount of convective energy available on Titan, a lightning energy dissipation rate of 4 × 10^?6, W/m² can be expected. This value is much lower than that for Earth or Jupiter, and is a result of both the reduced solar flux at Titan and the absorption of sunlight by the aerosols that lie above the convective layer. For this dissipation rate, the amount of HCN and C₂N₂ produced by lightning should be greater than that by solar UV, but could be less than that produced by electron precipitation and galactic cosmic rays. Equilibrium calculations indicate that large mole fractions of elemental solid phase carbon will also be produced. Using a simplified model of aerosol formation, coagulation, and settling, it is estimated that a lightning-produced aerosol could have a typical optical depth of 10^?2, with values as high as 0.1. The accumulation of soot over geological time might reach a meter or more in depth.     

A photochemical model of Titan's atmosphere and ionosphere

A global-mean model of coupled neutral and ion chemistry on Titan has been developed. Unlike the previous coupled models, the model involves ambipolar diffusion and escape of ions, hydrodynamic escape of light species, and calculates the H₂ and CO densities near the surface that were assigned in some previous models. We tried to reduce the numbers of species and reactions in the model and remove all species and reactions that weakly affect the observed species. Hydrocarbon chemistry is extended to C₁₂H₁₀ for neutrals and C₁₀H⁺₁₁ for ions but does not include PAHs. The model involves 415 reactions of 83 neutrals and 33 ions, effects of magnetospheric electrons, protons, and cosmic rays. UV absorption by Titan's haze was calculated using the Huygens observations and a code for the aggregate particles. Hydrocarbon, nitrile, and ion chemistries are strongly coupled on Titan, and attempt to calculate them separately (e.g., in models of ionospheric composition) may result in significant error. The model densities of various species are typically in good agreement with the observations except vertical profiles in the stratosphere that are steeper than the CIRS limb data. (A model with eddy diffusion that facilitates fitting to the CIRS limb data is considered as well.) The CO densities are supported by the O⁺ flux from Saturn's magnetosphere. The ionosphere includes a peak at 80 km formed by the cosmic rays, steplike layers at 500-700 and 700-900 km and a peak at 1060 km (SZA = 60°). Nighttime densities of major ions agree with the INMS data. Ion chemistry dominates in the production of bicyclic aromatic hydrocarbons above 600 km. The model estimates of heavy positive and negative ions are in reasonable agreement with the Cassini results. The major haze production is in the reactions C₆H + C₄H₂, C₃N + C₄H₂, and condensation of hydrocarbons below 100 km. Overall, precipitation rate of the photochemical products is equal to 4-7 kg cm⁻² Byr⁻¹ (50-90 m Byr⁻¹ while the global-mean depth of the organic sediments is ∼3 m). Escape rates of methane and hydrogen are 2.9 and 1.4 kg cm⁻² Byr⁻¹, respectively. The model does not support the low C/N ratio observed by the Huygens ACP in Titan's haze.     

The lower ionosphere of Venus

Galactic cosmic ray bombardment provides a permanent background ionosphere in planetary atmospheres. A transport technique is used to compute the cosmic ray ionization rate profile in a model of the Venusian atmosphere at altitudes between 55 and 100 km. These ionization rates are then applied to a model of ion chemistry to predict equilibrium electron and ion density profiles. Ionization rates for typical solar flare proton events are available from earlier calculations and have been included.     

Energetic particles from the sun

This paper discusses solar cosmic ray phenomena and related topics from the solar physical point of view. Basic physics of the solar atmosphere and solar flare phenomena are, therefore, considered in some detail. Since solar cosmic rays are usually produced by solar flares, we must first understand the processes and mechanism of solar flares, especially the so-called proton flares, in order to understand the acceleration mechanism of solar cosmic rays and their behaviour in both the solar atmosphere and interplanetary space. For this reason, detailed discussion is given on various phenomena associated with solar flares, proton flare characteristics, and the mechanism of solar flares.Since the discovery of solar cosmic rays by Forbush, the interplanetary space has been thought of as medium in which solar cosmic rays propagate. In this paper, the propagation of solar cosmic rays in this space is, therefore, discussed briefly by referring to the observed magnetic properties of this space. Finally, some problems related to the physics of galactic cosmic rays are discussed.Astrophysics and Space Science Review Paper.     

Jovian magnetosphere-ionosphere current system characterized by diurnal variation of ionospheric conductance

We developed a new numerical model of the Jovian magnetosphere-ionosphere coupling current system in order to investigate the effects of diurnal variation of ionospheric conductance. The conductance is determined by ion chemical processes that include the generation of hydrogen and hydrocarbon ions by solar EUV radiation and auroral electrons precipitation. The model solves the torque equations for magnetospheric plasma accelerated by the radial currents flowing along the magnetospheric equator. The conductance and magnetospheric plasma then change the field-aligned currents (FACs) and the intensity of the electric field projected onto the ionosphere. Because of the positive feedback of the ionospheric conductance on the FAC, the FAC is the maximum on the dayside and minimum just before sunrise. The power transferred from the planetary rotation is mainly consumed in the upper atmosphere on the dayside, while it is used for magnetospheric plasma acceleration in other local time (LT) sectors. Further, our simulations show that the magnetospheric plasma density and mass flux affect the temporal variation in the peak FAC density. The enhancement of the solar EUV flux by a factor of 2.4 increases the FAC density by 30%. The maximum density of the FAC is determined not only by the relationship between the precipitating electron flux and ionospheric conductance, but also by the system inertia, i.e., the inertia of the magnetospheric plasma. A theoretical analysis and numerical simulations reveal that the FAC density is in proportion to the planetary angular velocity on the dayside and to the square of the planetary angular velocity on the nightside. When the radial current at the outer boundary is fixed at values above 30 MA, as assumed in previous model studies, the peak FAC density determined at latitude 73°-74° is larger than the diurnal variable component. This result suggests large effects of this assumed radial current at the outer boundary on the system.     

Predictions of the electrical conductivity and charging of the aerosols in Titan's atmosphere

The electrical conductivity and electrical charge on the aerosols in atmosphere of Titan are computed for altitudes between 0 and 400 km. Ionization of methane and nitrogen due to galactic cosmic rays (GCR) is important at night where these ions are converted to ion clusters such as CH⁺₅CH₄, C₇H⁺₇, C₄H⁺₇, and H₄C₇N⁺. The ubiquitous aerosols observed also play an important role in determining the charge distribution in the atmosphere. Because polycyclic aromatic hydrocarbons (PAHs) are expected in Titan's atmosphere and have been observed in the laboratory and found to be electrophilic, we consider the formation of negative ions. During the night, the very smallest molecular complexes accept free electrons to form negative ions. This results in a large reduction of the electron abundance both in the region between 150 and 350 km over that predicted when such aerosols are not considered. During the day time, ionization by photoemission from aerosols irradiated by solar ultraviolet (UV) radiation overwhelms the GCR-produced ionization. The presence of hydrocarbon and nitrile minor constituents substantially reduces the UV flux in the wavelength band from the cutoff of CH₄ at 155 to 200 nm. These aerosols have such a low ionization potential that the bulk of the solar radiation at longer wavelengths is energetic enough to produce a photoionization rate sufficient to create an ionosphere even without galactic cosmic ray (GCR) bombardment. At altitudes below 60 km, the electron and positive ion abundances are influenced by the three-body recombination of ions and electrons. The addition of this reaction significantly reduces the predicted electron abundance over that previously predicted. Our calculations for the dayside show that the peaks of the charge distributions move to larger values as the altitude increases. This variation is the result of the increased UV flux present at the highest altitudes. Clearly, the situation is quite different than that for the night where the peak of the distribution for a particular size is nearly constant with altitude when negative ions are not present. The presence of very small aerosol particles (embryos) may cause the peak of the distribution to decrease from about 8 negative charges to as little as one negative charge or even zero charge. This dependence on altitude will require models of the aerosol formation to change their algorithms to better represent the effect of charged aerosols as a function of altitude. In particular, the charge state will be much higher than previously predicted and it will not be constant with altitude during the day time. Charging of aerosol particles, whether on the dayside or nightside, has a major influence on both the electron abundance and electrical conductivity. The predicted conductivities are within the measurement range of the HASI PWA instrument over most but not all, of the altitude range sampled.     

Descent motions of the Huygens probe as measured by the Surface Science Package (SSP): Turbulent evidence for a cloud layer

The Huygens probe underwent vigorous short-period motions during its parachute descent through the atmosphere of Saturn's moon Titan in January 2005, at least some of which were excited by the Titan environment. Several sensors in the Huygens Surface Science Package (SSP) detect these motions, indicating the transition to the smaller stabilizer parachute, the changing probe spin rate, aerodynamic buffeting, and pendulum motions. Notably, in an altitude range of about 20–30 km where methane drops will freeze, the frequency content and statistical kurtosis of the tilt data indicate excitation by turbulent air motions like those observed in freezing clouds on Earth, supporting the suggestion of Tokano et al. [Tokano, T., McKay, C.P., Neubauer, F.M., Atreya, S.K., Ferri, F., Fulchignoni, M., Niemann, H.B. (2006a). Methane drizzle on Titan. Nature 442, 432–435] that the probe passed through such a cloud layer. Motions are weak below 20 km, suggesting a quiescent lower atmosphere with turbulent fluctuations of nominally <0.15 m/s (to within a factor of ∼2) but more violent motions in the upper troposphere may have been excited by turbulent winds with amplitudes of 1–2 m/s. Descent in part of the stratosphere (150–120 km) was smooth despite strong ambient wind (∼100 m/s), but known anomalies in the probe spin prevent investigation of turbulence in the known wind-shear layer from 60 to 100 km.     

Measurement of the radial density gradient of cosmic ray in the heliosphere by the GRAPES-3 experiment

A radial anisotropy in the flux of cosmic rays in heliosphere was theoretically predicted by Parker and others within the framework of the diffusion–convection mechanism. The solar wind is responsible for sweeping out the galactic cosmic rays, creating a radial density gradient within the heliosphere. This gradient coupled with the interplanetary magnetic field induces a flow of charged particles perpendicular to the ecliptic plane which was measured and correctly explained by Swinson, and is hereafter referred as ‘Swinson flow’. The large area GRAPES-3 tracking muon telescope offers a powerful probe to measure the Swinson flow and the underlying radial density gradient of the galactic cosmic rays at a relatively high rigidity of ∼100 GV. The GRAPES-3 data collected over a period of six years (2000–2005) were analyzed and the amplitude of the Swinson flow was estimated to be (0.0644 ± 0.0008)% of cosmic ray flux which was an ∼80σ effect. The phase of the maximum flow was at a sidereal time of (17.70 ± 0.05) h which was 18 min earlier than the expected value of 18 h. This small 18 min phase difference had a significance of ∼6σ indicating the inherent precision of the GRAPES-3 measurement. The radial density gradient of the galactic cosmic rays at a median rigidity of 77 GV was found to be 0.65% AU⁻¹.     

High altitude haze: Influence of monomer particles on Titan’s temperature profile

The present study investigates the role of high altitude monomer particles in the energy balance of Titan’s upper atmosphere above an assumed low and high aggregate formation altitude of 385 km and 535 km. A ‘single particle approach’ was applied, where the starting point is the energy balance of an individual aerosol. In our analysis 0.01–0.06 μm radius aerosol particles were chosen for the proposed monomer formation regions. These particles absorb solar radiation, emit in the infrared, and are energetically linked to the surrounding gas by thermal conduction. To compute the monomer particle heating effect, the aerosols are assumed to radiate directly to space. We found that high altitude monomers may affect the profile of Titan’s thermosphere from 2 to 20 K depending on the formation altitude of fluffy non-spherical aggregates, the monomer size and distribution. The actual Titan temperature profile in this altitude range including all heating effects will be measured by the HASI instrument during the descent of the Huygens probe.     

The post-terminator ionosphere of Venus

We have modeled the near and post-terminator thermosphere/ionosphere of Venus with a view toward understanding the relative importance of EUV solar fluxes and downward fluxes of atomic ions transported from the dayside in producing the mean ionosphere. We have constructed one-dimensional thermosphere/ionosphere models for high solar activity for seven solar zenith angles (SZAs) in the dusk sector: 90°, 95°, 100°, 105°, 110°, 115° and 125°. For the first 4 SZAs, we determine the optical depths for solar fluxes from 3 Å to 1900 Å by integrating the neutral densities numerically along the slant path through the atmosphere. For SZAs of 90°, 95°, and 100°, we first model the ionospheres produced by absorption of the solar fluxes alone; for 95°, 100°, and 105° SZAs, we then model the ion density profiles that result from both the solar source and from imposing downward fluxes of atomic ions, including O⁺, Ar⁺, C⁺, N⁺, H⁺, and He⁺, at the top of the ionospheric model in the ratios determined for the upward fluxes in a previous study of the morphology of the dayside (60° SZA) Venus ionosphere. For SZAs of 110°, 115° and 125°, which are characterized by shadow heights above about 300 km, the models include only downward fluxes of ions. The magnitudes of the downward ion fluxes are constrained by the requirement that the model O⁺ peak density be equal to the average O⁺ peak density for each SZA bin as measured by the Pioneer Venus Orbiter Ion Mass Spectrometer. We find that the 90° and 95° SZA model ionospheres are robust for the solar source alone, but the O⁺ peak density in the “solar-only” 95° SZA model is somewhat smaller than the average value indicated by the data. A small downward flux of ions is therefore required to reproduce the measured average peak density of O⁺. We find that, on the nightside, the major ion density peaks do not occur at the altitudes of peak production, and diffusion plays a substantial role in determining the ion density profiles. The average downward atomic ion flux for the SZA range of 90–125° is determined to be about 1.2 × 10⁸ cm⁻² s⁻¹.     

Heavy ion formation in Titan's ionosphere: Magnetospheric introduction of free oxygen and a source of Titan's aerosols?

Discovery by Cassini's plasma instrument of heavy positive and negative ions within Titan's upper atmosphere and ionosphere has advanced our understanding of ion neutral chemistry within Titan's upper atmosphere, primarily composed of molecular nitrogen, with ~2.5% methane. The external energy flux transforms Titan's upper atmosphere and ionosphere into a medium rich in complex hydrocarbons, nitriles and haze particles extending from the surface to 1200 km altitudes. The energy sources are solar UV, solar X-rays, Saturn's magnetospheric ions and electrons, solar wind and shocked magnetosheath ions and electrons, galactic cosmic rays (GCR) and the ablation of incident meteoritic dust from Enceladus’ E-ring and interplanetary medium. Here it is proposed that the heavy atmospheric ions detected in situ by Cassini for heights >950 km, are the likely seed particles for aerosols detected by the Huygens probe for altitudes <100 km. These seed particles may be in the form of polycyclic aromatic hydrocarbons (PAH) containing both carbon and hydrogen atoms C_nH_x. There could also be hollow shells of carbon atoms, such as C₆₀, called fullerenes which contain no hydrogen. The fullerenes may compose a significant fraction of the seed particles with PAHs contributing the rest. As shown by Cassini, the upper atmosphere is bombarded by magnetospheric plasma composed of protons, H₂⁺ and water group ions. The latter provide keV oxygen, hydroxyl and water ions to Titan's upper atmosphere and can become trapped within the fullerene molecules and ions. Pickup keV N₂⁺, N⁺ and CH₄⁺ can also be implanted inside of fullerenes. Attachment of oxygen ions to PAH molecules is uncertain, but following thermalization O+ can interact with abundant CH₄ contributing to the CO and CO₂ observed in Titan's atmosphere. If an exogenic keV O+ ion is implanted into the haze particles, it could become free oxygen within those aerosols that eventually fall onto Titan's surface. The process of freeing oxygen within aerosols could be driven by cosmic ray interactions with aerosols at all heights. This process could drive pre-biotic chemistry within the descending aerosols. Cosmic ray interactions with grains at the surface, including water frost depositing on grains from cryovolcanism, would further add to abundance of trapped free oxygen. Pre-biotic chemistry could arise within surface microcosms of the composite organic-ice grains, in part driven by free oxygen in the presence of organics and any heat sources, thereby raising the astrobiological potential for microscopic equivalents of Darwin's “warm ponds” on Titan.