The distributions of particulate heavy metals and its indication to the transfer of sediments in the Changjiang Estuary and Hangzhou Bay,China

Particulate heavy metals (Cu, Pb, Cd) were measured following intensive sampling in June and October 1994 at 70 stations in the Changjiang Estuary and Hangzhou Bay, China. In the study area, particulate Cu and Pb have a similar level that is higher than the concentration of particulate Cd. Cu, Pb and Cd concentrations in suspended sediments are higher than those in bed load. In the middle of Hangzhou Bay, heavy metal concentrations in suspended sediments and bed load are similar. This may be the result of the frequent exchange between them, which is due to the strong dynamic condition. A negative relationship was observed between concentrations of heavy metals in bed load and bulk density. Fine-grained sediments were the main carriers of heavy metals. Sedimentary dynamics dominate the fate of heavy metals in these sites. The distributions of metals (especially Cu) in suspended sediments can indicate the transfer of sediments in this area.     

Importance of vertical geochemical processes in controlling the oceanic profiles of dissolved rare earth elements in the northeastern Indian Ocean

Vertical profiles of dissolved rare earth elements (REEs) were obtained in the Bay of Bengal and the Andaman Sea. The REE concentrations at various depths in the Bay of Bengal are the highest in the Indian Ocean. This is attributable ultimately to the large outflow of the Ganges–Brahmaputra and Irrawaddy rivers, but the dissolved REE flux to surface waters alone cannot explain the large and near-constant REE enrichment throughout the entire water column. The underlying fan sediments serve as not a source but a sink for dissolved REE(III)s. Absence of excess ²²⁸Ra in the deep waters suggests that lateral input of dissolved REEs from slope sediments is also small in these regions. Partial (<0.3%) dissolution of detrital particles, which are carried by the rivers and lateral surface currents and subsequently settle through the water column, appears to be a predominant source for the dissolved REEs. Vertical profiles showing an almost linear increase with depth are common features for the light and middle REEs everywhere, but their concentration levels are variable from basin to basin and from element to element. This suggests that their oceanic distributions respond quickly to the variation of particle flux and its REE composition through reversible exchange equilibrium with suspended and sinking particles much like the case for Th. The relative importance of the vertical geochemical processes of reversible scavenging over the horizontal basin-scale ocean circulation with passive regeneration like nutrients decreases systematically from the light to the heavy REEs. Using a model, the mean oceanic residence times of REEs in the Bay of Bengal are estimated to range from 37 years for Ce to 140–1510 years for the strictly trivalent REEs. In the deep water of the Andaman Sea, isolated from the Bay of Bengal by the Andaman–Nicobar Ridge (maximum sill depth of ∼1800 m), the REE concentrations are almost uniform presumably due to rapid vertical mixing. The REE(III) concentrations are similar to that of ∼1250 m depth water in the Bay of Bengal, consistent with other oceanographic properties. However, the REE composition of the deep water appears to be altered slightly by preferential scavenging of the light REE(III) at the bottom boundary of the basin.     

Processes of tidal channel development in salt and freshwater marshes

Mechanisms for the formation of creeks in tidal ?ats are rarely discussed in literature. There are some general theories about their formation but there are no data to support the evidence. It is generally believed that marshes inherit creeks from previous tidal ?ats that their plants colonize and further modify them. The aim of this paper is to present three mutually exclusive cases from marshes in Argentina where creeks are formed by either purely physical or biological–physical interactions. Except for Loyola Bay, this is the ?rst discussion of these mechanisms. They may represent special cases, but the fact that all three of them occur along the coast of Argentina, could indicate that similar cases may be found somewhere else. Copyright © 2003 John Wiley & Sons, Ltd.     

Preliminary results of experiments to determine the effects of suspended sediments on the estuarine copepod Eurytemora affinis

Suspended sediment did not significantly affect Eurytemora affinis, which is the numerically dominant, late winter, early spring mesozooplankton taxon in Chesapeake Bay. In preliminary analyses of survival, broods per female and nauplii development for suspended sediment concentrations from 0 to 350 mg l⁻¹, few significant differences were observed between populations exposed to no suspended sediment, and those in 50, 100 and 350 mg l⁻¹. However, in every case, highest suspended sediment levels reduced physiological or reproductive parameters in the copepod. These results suggest that current levels of suspended sediment in the Chesapeake Bay should not reduce population success of the copepod. However, copepod production could decline at slightly higher suspended sediment concentrations resulting from urban population growth and development in the watershed, as well as at levels which are typical of several European estuaries.     

Concentrations of PCBs,dieldrin and DDT residues in marine animals from Liverpool Bay

The levels of DDT residues, dieldrin and PCBs have been determined in the tissues of 15 species of marine animals from the Liverpool Bay area of the Irish Sea. In general, the concentrations of these compounds are somewhat lower than those reported earlier for fish from other British inshore areas, despite the fact that the Bay is subject to pollution, not only from the River Mersey, but also from extensive sewage sludge dumping. This difference may reflect recent controls on the use of these compounds.     

The effects of alteration and the interpretation of heat flow and radioactivity data—a reply to R.U.M. Rao

The first²²⁴Ra (t_1/2 = 3.64days) measurements from mixing zones of estuarine systems are presented for the Pee Dee River-Winyah Bay and Delaware Bay Estuaries. High-resolution gamma-ray spectrometry was used to determine²²⁴Ra,²²⁸Ra (t_1/2 = 5.7years), and²²⁶Ra (t_1/2 = 1622years) activity ratios. Desorption and diffusion from suspended and bottom sediments contributes to the non-conservative increases of the three isotopes in each systems. In Delaware Bay²²⁴Ra concentrations were nearly constant over the 2.5‰ to 15‰ salinity range where two turbidity maximum zones are located.²²⁸Th scavenging onto the suspended particles in the turbid zones may supply a regenerative source of²²⁴Ra in this system. Samples collected on the ebb and flood tide from a salt marsh along Delaware Bay have a 5-fold increase in²²⁴Ra from flood to ebb and 3- and 2-fold increases for²²⁸Ra and²²⁶Ra respectively, indicating salt marshes are another source of radium to estuarine waters.     

Distribution and Fate of Organochlorine Pollutants in the Pearl River Estuary

Samples of surface sediment and suspended particulate matter (SPM) were collected from the Pearl River estuary, China, and the distribution and concentration of hexachlorocyclohexanes (HCHs), DDTs and polychlorinated biphenyls (PCBs) were extensively studied. The concentration ranges of HCHs, DDTs and PCBs in the sediments were 0.28–1.23 ng g⁻¹, 1.36–8.99 ng g⁻¹ and 0.18–1.82 ng g⁻¹, respectively. The concentrations of HCHs, DDTs and PCBs in the SPM varied both with the sampling locations and the season of collection. Higher concentrations were recorded in the SPM as compared with sediments. The distribution pattern of such organochlorine compounds (OCs), in the Pearl River estuary, showed that sources were some major river mouths and input from Shenzhen Bay. The concentrations of OCs were, however, low as compared with other estuaries and seas. The environmental fate of the OCs during estuarine mixing was determined, in part, by physicochemical and biochemical properties. The absorption and sedimentation of SPM were also considered important factors. Marine sediments may, therefore, be regarded as an important reservoir of hydrophobic and persistent OCs.     

Impact of post-mixing chemical reactions on the major ion chemistry of bulk meltwaters draining the haut glacier d'arolla,valais, Switzerland

Until now, alpine glacial meltwaters have been assumed to consist of two components, dilute quickflow and concentrated delayed flow, the mixing of which has been regarded as chemically conservative for the major dissolved ions and electrical conductivity. Dye tracing results suggest that this two-component model adequately represents the sub-glacial hydrology of the Haut Glacier d'Arolla, Switzerland. However, laboratory dissolution experiments in which various concentrations of glacial rock flour are placed in dilute solutions show that this rock flour is highly reactive and suggest that bulk meltwaters may acquire significant amounts of solute through rapid chemical reactions with suspended sediment which occur after mixing of the two components. This view is supported by detailed analysis of variations in the hydrochemistry of meltwaters draining from the Haut Glacier d'Arolla over three diurnal cycles during the 1989 melt season. Variations in the composition of bulk meltwaters are controlled by two main factors: dilution of the delayed flow component by quickflow, and the extent of post-mixing reactions. The latter depends on the suspended sediment concentration in bulk meltwaters and on the duration of contact between these waters and suspended sediment. Seasonal changes in the magnitude of these factors result in changes in the character and causes of diurnal variations in meltwater chemistry. In June, these variations reflect discharge-related variations in residence time within a distributed subglacial drainage system; in July, when a channelized drainage system exists beneath the lower glacier, they primarily reflect the dilution of delayed flow by quickflow; in August, when suspended sediment concentrations are particularly high, they reflect varying degrees of solute acquisition by post-mixing reactions with suspended sediment that take place in arterial channels at the glacier bed.     

Spatial and temporal variability in nutrient concentrations in Liverpool Bay,a temperate latitude region of freshwater influence

This paper presents data for the temporal and spatial distribution of nutrients in Liverpool Bay between 2003 and 2009 and an analysis of inputs of nutrients from the major rivers. The spatial distribution of winter nutrient concentrations are controlled by the region of freshwater influence (ROFI) in Liverpool Bay through the mixing of riverine freshwater and Irish Sea water, with strong linear relationships between nutrient concentration and salinity between December and February. The location of highest spring and summer phytoplankton biomass reflects the nutrient distributions as controlled by the ROFI. Analysis of 7 years of data showed that the seasonal cycle of winter maximum nutrient concentrations in February and drawdown in April/May is a recurrent feature of this location, with the timing of the drawdown varying by several weeks between years. A comparison of observed nutrient concentrations in Liverpool Bay with those predicted from inputs from rivers has been presented. Nutrient concentrations in the rivers flowing into Liverpool Bay were highly variable and there was reasonable agreement between predicted freshwater nutrient concentrations using data from this study and riverine nutrient concentrations weighted on the basis of river flow, although the exact nature of mixing between the rivers could not be determined. Predicted Irish Sea nutrient concentrations in the winter were lower than those reported for the input waters of the North Atlantic, supporting findings from previous work that nitrogen is lost through denitrification in the Irish Sea.     

Monitoring the remediation of a near shore waste disposal site in Antarctica using the amphipod Paramoera walkeri and diffusive gradients in thin films (DGTs)

The water quality of a marine embayment (Brown Bay) was monitored during the remediation of an abandoned waste disposal site at Casey Station, East Antarctica, using a combination of biomonitoring and chemical methods. The Antarctic amphipod Paramoera walkeri, in field mesocosms suspended in the water column, was deployed adjacent to the site and at two reference sites for periods of 14 days, repeated three times during the remediation period (December to February). Diffusive gradients in thin film (DGT) samplers were deployed for the same periods to provide estimates of dissolved metals. No difference in mortality of amphipods was observed between Brown Bay and reference sites. There were significant differences, however, in accumulated metal concentrations between amphipods from Brown Bay and reference sites, with greater concentrations of antimony, copper, cadmium, lead, iron and tin at Brown Bay. The melt water/runoff treatment strategy employed for the remediation was successful in preventing acute toxic effects, but water quality was reduced at Brown Bay, where increased metal bioavailability may have been high enough to induce chronic effects in some biota. DGT samplers were less sensitive than amphipods in detecting differences in metal concentrations between sites, indicating that metals bound to suspended particulates were a potentially significant source of contamination.     

Levels of estrogenic compounds in Xiamen Bay sediment, China

Concentrations of seven estrogenic compounds, i.e., estrone (E1), 17β-estradiol (E2), 17α-ethynylestradiol(EE2), diethylstilbestrol (DES), nonylphenol (NP), octylphenol (OP) and bisphenol A (BPA), were determined in sediments and pore water from Xiamen Bay in China, and their distributions and potential risks in the Bay were assessed. Total estrogenic compounds concentrations varied from 49.20 to 1230.69 ng/g dw in sediments and from 102.33 to 4376.60 ng/L in pore water. The highest levels of these compounds were found at Yundang Lagoon. The results showed that estrogenic compounds in Xiamen Bay originated mainly from municipal wastewaters. Compared with other areas, Xiamen Bay was contaminated with high levels of estrogen hormones. This contamination poses a potential threat to benthic organisms. Although a good relationship (r = 0.94) was observed between the estrogenic compounds concentrations and total organic carbon (TOC) contents in sediments, which did not indicate that the sediment organic matter favors the accumulation of the detected estrogenic compounds.     

Marine organic pollution history in the Changjiang Estuary and Zhejiang coastal area--HCHs and DDTs stratigraphical records

The variations of concentrations of hexachloro-cyclohexane (HCHs), dichloro diphenyl trichloroethane (DDTs) in surface sediments from the Changjiang Estuary and Zhejiang coastal area suggests that although there is a substantial decrease of these persistent trace compounds since the last two decades, they still presented in recent surface sediments. Their concentration levels in suspended matter are still quite high. In dated sedimentary cores, the DDTs and HCHs concentration peaks appeared in 1960s to 1980s, which approximately corresponded to their production and usage history.     

Dynamics of particulate major and trace elements in the lower reaches of the Daugava River and adjacent area of the Gulf of Riga (Baltic Sea)

Suspended particulate matter (SPM) was collected in the freshwater-seawater mixing zone in the lower reaches of the Daugava River (Latvia) and adjacent marine area, during five cruises in 1998-2001. The study focused on biogeochemical phase exchange processes. SPM in the freshwater was found to be mainly allochthonous with a high content of organic matter, Mn and sorbed phosphate. Property-salinity plots suggested flocculation of humic-Fe complexes across the salinity gradient. The variability of sorbed phosphate was related to particulate Fe, although no dependence on pH and ionic strength was observed. The Mn contents of SPM mainly follow conservative mixing, but there are also indications of interface exchange of Mn in the mixing zone. The geochemical behaviour of particulate Al appears to differ from that of Fe. In early spring, trace element contents in SPM (Cr, Ni, Cu, Zn, Cd, Pb) correlate tightly with particulate organic matter, whose distribution is linked to phytoplankton distributions.     

Sediment profile characterisation at contaminated and reference locations in the Windmill Islands, East Antarctica

Sediment profiles for pH, Eh, 28 elements, water and organic content are presented here for human impacted and reference locations in the Windmill Islands, East Antarctica. Variations in element concentrations are observed with increasing depth, especially at Brown Bay where the impact of past human activities is most pronounced in the top 10 cm. Spatial differences were observed between sediment profiles at reference and impacted locations and were largely explained by Pb variability in the top 5 cm. Median element concentrations from surface, middle and bottom regions of the sediment profile were compared to composite sample medians (no depth stratigraphy) for 11 elements at O’Brien Bay (reference) and Brown Bay (impacted). Pronounced differences were observed for Brown Bay, particularly surface and middle sections, implying that composite samples dilute the near surface anthropogenic signal by mixing with deeper uncontaminated sediment.     

Diurnal Variations in the Hydrochemical Indices in Amur Bay

A study was conducted to assess the diurnal variations in water temperature, in-situ density, and salinity; major components of the salt composition; ion–chlorine relationships; elements of the carbonate system and their chlorine ratios; major nutrient compounds; total organic carbon content; suspended matter; dissolved oxygen and its percentage in the coastal waters of Amur Bay. The notions of zero, very small, small, medium, high, and very high relative variability are introduced.     

Seasonal and annual loads of hydrophobic organic contaminants from the Susquehanna River basin to the Chesapeake Bay

Water from the Susquehanna River was collected and analyzed for polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyl (PCB) congeners to estimate seasonal and annual riverine loads to the Chesapeake Bay. Temporal variations in the chemical loads resulted from the large changes in the water flow rates and in the particle-associated contaminant concentrations. Concentrations of PCBs and PAHs in river particles (ng/g) were twice as great as those in the northern Chesapeake Bay, indicating that the Susquehanna River is an important source of these contaminants to the bay. The river carries a majority of its hydrophobic organic contaminants (HOCs) in the particulate phase. During periods of high flow, large amounts of suspended particles in the river result in elevated HOC levels and increased loadings of these contaminants to the bay. From 1997 to 1998, 60% of the total annual HOC loading occurred in the early spring coincident with high river flows. The total PCB and PAH annual loadings from the Susquehanna River to the Chesapeake Bay were 76 and 3160 kg/year, respectively and 75% of the loaded organic contaminants were in the particulate phase. Principal component analysis of PAH and PCB congener patterns in the particles reveals that the river suspended particles were dominated by autochthonous production in the summer and by resuspended sediment and watershed erosion during the winter and early spring.     

Burst-like sediment suspension events in a sand bed river

In a much quoted paper, Jackson (1976) hypothesized that turbulent [bursting] motions such as those documented in laboratory boundary layers play a major role in alluvial sediment suspension. To date, the hypothesis remained largely untested, due to difficulties in monitoring turbulent suspension in rivers. This study provides field data documenting burst-like turbulent motions over a sandy bed channel and quantifying the role of these motions in sand suspension. The data were collected in a 10 m deep channel of the Fraser River near Mission, British Columbia, Canada. Turbulent fluctuations of both flow components, downstream and normal to the bed, along with the output of an optical suspended sediment sensor, were monitored 1 m above the river bed. Typical flow velocities averaged 0·9 ms⁻¹ at the sensors, where mean suspended sediment concentrations were 500 mgl⁻¹; decimetre height small dunes on the backs of larger, half-metre amplitude dunes covered the channel bed in the area. Brief but intense, burst-like [ejection and inrush] events were identified in the flow records, where they are responsible for a high degree of [intermittency] in shear stress over the dunes: 80 per cent of the turbulent momentum exchange across the 1 m level can be ascribed to such brief (3-8 s duration) events, active under 12 per cent of the time. In addition, the record of fluctuating sediment concentrations reveals these burst-like motions to be highly effective in vertically mixing suspended sediment and thus, ultimately, in maintaining suspended sediment transport above the dune bed. The bulk (60 and 90 per cent in two deployments) of the vertical sediment mixing was accomplished by intense events active some 10 per cent of the time. No discrete recurrence timescale for these ‘burst-like’ mixing events is evident, however. Rather, a continuous variation of return periods was observed as a function of the magnitude of vertical mixing event considered. To that extent, conceptual models of sediment transport in terms of burst events with a predictable recurrence such as proposed by Jackson (1976) may be misleading.     

Suspended sediment transport and deposition over a dune: Río Paraná, Argentina

Field data from the Rio Paraná, Argentina, are used to examine patterns of suspended sediment transport over a sand dune. Measurements of three‐dimensional velocity are made with an acoustic Doppler current profiler whilst suspended sediment concentration and particle size have been quantified using a laser in situ sediment scattering transmissometer. Suspended sediment concentration and streamwise and vertical sediment flux are highest close to the bed, with an upward vertical flux over the stoss side of the dune and downward flux over the lee side. Suspended sediment concentrations are higher over the crest compared with the trough and suspended sediment is coarsest near the bed. About 17% of the suspended‐load transported over the crest is deposited in the lee side before it reaches the trough. Most of this deposited sand is coarser sediment that originates close to the bed over the crest, a result consistent with simulations based on the model of Mohrig and Smith (Water Resources Research 1996; 32: 3207–3217) for the excursion lengths of sediment dispersed in the lee side of a dune. Copyright © 2009 John Wiley & Sons, Ltd.     

The use of a spatially heterogeneous simulation model for studying biotransformation processes of nitrogen and phosphorus compounds and the dynamics of oxygen dissolved in water in the ecosystem of Neva Bay, the Gulf of Finland: 2. Input data for calculations, modeling results, and their analysis

The data collected for model calculations is systematized for natural and design conditions. The natural conditions did not take into account the effect of the complex of water-protection structures on the hydrological regime of Neva Bay and on the biogenic load onto this water area, while the design conditions, conversely, reflected the possible impact of those structures on the hydrology and ecology of the area. Numerical experiments were used to study the processes of transformation of N and P compounds and the dynamics of dissolved O₂ in Neva Bay water area. In the comparison of the calculated and observed concentrations of biogenic substances, Theil criterion was evaluated to assess the adequacy of the model in reproducing the concentration fields of the distribution of biogenic substances over Neva Bay water area. The major qualitative and quantitative features of the formation of the spatial heterogeneity and the time variations in the concentrations of biogenic element compounds over Neva Bay water area are identified. Possible improvements of the model in the reproduction of the complex of processes that are of particular importance for the development of substance transformations in shallow ecosystems are considered.     

Estimating turbidity and total suspended matter in the Adour River plume (South Bay of Biscay) using MODIS 250-m imagery

The Basque coastal waters (South Bay of Biscay) are directly influenced by the Adour River freshwater plume. The Adour outflow leads to important variations of suspended matter concentrations and turbidity, which in turn may affect biological productivity and water quality. This study aims at both developing specific algorithms and testing the efficiency of atmospherically corrected MODIS-Aqua 250-m surface reflectance product (MYD09) to map total suspended matter concentrations and turbidity within the Adour coastal region. First, regional empirical algorithms based on in-situ data were tested to retrieve the concentration of total suspended matter and turbidity from the remote sensing reflectance. Then, the respective sensitivity of MODIS surface reflectance bands 1 and 2 for water quality application was investigated as well as the quality of atmospheric corrections. Finally, selected algorithms were applied to the MYD09 product. The resulting 250-m resolution maps were then compared to 1000-m maps produced by IFREMER and comparisons between satellite measurements and in-situ sampling points were performed. Results show that MODIS-Aqua band 1 (620–670 nm) is appropriate for predicting turbidity and total suspended matter concentrations using polynomial regression models, whilst band 2 is unadapted. Comparison between total suspended matter concentration 250-m resolution maps and mineral suspended matter 1000-m maps (generated by IFREMER) produced consistent results. A high correlation was obtained between turbidity measured in-situ and turbidity retrieved from MODIS-Aqua satellite data.