Zur ökonomischen Bedeutung der biologischen Selbstreinigung

In twelve flowing water (Q 1.04… 30.4 m³/s, 0.5… 1.2 m/s) the self-purification efficiency in 110 river sections (L 1.3… 26.4 km) is determined as the load difference in kg · d^?1 COD-Mn as well as in g · m^?3 referred to the daily passage. In the economical comparison, the self-purification efficiency is valued as substitution for wastewater treatment plants of the same capacity. At a mean specific capacity of 8.6 g · m^?3, the self-purification efficiency of the investigated waters is equivalent to economical values of 124 · 10³… 534 · 10³ M km^?1 investment costs, 11 · 10³… 80 · 10³ M · a^?1km^?1 operating costs and 5… 81 MWh · a^?1 km^?1 expenditure of energy. The specific capacity in g · m^?3 COD-Mn shows an exponential regression to the degree of saprobity (L = 0.015 · exp (1.7358 · S)). From this empirical model the limits of the self-purification capacity of aerobic waters by oxygen input can be detected: in respective examples more than 50% of the required oxygen input are due to weirs.     

Ein Beitrag zur Bestimmung von Anilin/Phenol in Wasser/Abwasser mittels UV-Derivativspektroskopie. Teil 1: Das analytische Grundverfahren

Ultraviolet derivative spectroscopy was used as an analytical tool for the direct and simultaneous determination of aniline and phenol in water. It is shown that the diA/dλi values are proportional to aniline (i = 2, 4) and phenol (i = 2, 4 and 5) concentrations at 205.3 or 271.6 … 282.8 nm. The performance characteristics are discussed in detail. Thus the best precision resulted in both aniline and phenol for the second derivatives. The accuracy of the methods applied is independent on the derivative order and concentration levels within the dynamic range of 1 to 10 mg · 1^?1 aniline or phenol respectively.     

Groundwater Inflow Controls Acidity Fluxes in an Iron Rich and Acidic Lake

To ascertain the influence of hydrological boundary conditions on acidity fluxes in lakes influenced by acid mine drainage, acidity budgets were developed for two sediments in areas of differential groundwater inflow (approx. 1 L m^?2 d^?1 and 10 L m^?2 d^?1). In both sediments iron was deposited as schwertmannite leading to iron(III) enriched sediments (3.9…6.2 mmol g^?1, referred to dry weight). Compared to the surface water, the inflowing groundwater had higher pH (4.5 vs. 3), ferrous iron (6…20 mmol L^?1 vs. 0.8…2.0 mmol L^?1), and sulfate (5…60 mmol L^?1 vs. 8…13 mmol L^?1) concentrations. The inflow changed the sediment pore water chemistry and triggered a further increase in pH to above 5.5. In both sediments acidity generation in the surface water (10…30 mol m^?2 a^?1) strongly prevailed over acidity consumption in the sediments (> ?0.6 mol m^?2 a^?1). With advective groundwater inflow, however, more acidity was consumed due to TRIS formation (?0.12 mol m^?2 a^?1 vs. ?0.017 mol m^?2 a^?1), iron carbonate burial (upper estimate: ?0.14 mol m^?2 a^?1 vs. ?0.022 mol m^?2 a^?1), and unspecific ferrous iron retention (?0.39 mol m^?2 a^?1 vs. ?0.08 mol m^?2 a^?1). Also, less acidity was generated due to schwertmannite transformation (?2.4 mol m^?2 a^?1 vs. ?0.11 mol m^?2 a^?1). The acidity balance of internal processes in the sediment with groundwater inflow was negative, whereas it was positive in the other sediment. The study demonstrates that in acidic and iron rich lakes the hydrological boundary conditions strongly affect geochemical processes as subsumed in acidity fluxes.     

Primary Productivity in Relation to the Abiotic Factors in a Temporary Freshwater Pond

The primary production in the small pond (3.5 m long, 1.5 m wide, 1.5 m deep) was measured in winter from November to April by means of the bright-dark-flask method at an exposure for 24 hours. The following results were obtained: gross production 0.9 … 11 g C/m³d, net production 0.8 … 7 g C/m³d, respiration 0.5 … 5.6 g C/m³d, P/R quotient 19.6 … 0.18. The results are discussed in connection with chemical and hydrographie parameters as well as with the hydrological situation.     

Anomalous cosmogenic 3He production and elevation scaling in the high Himalaya

The production rate of cosmogenic ³He in apatite, zircon, kyanite and garnet was obtained by cross-calibration against ¹⁰Be in co-existing quartz in glacial moraine boulders from the Nepalese Himalaya. The boulders have ¹⁰Be ages between 6 and 16 kyr and span elevations from 3200 to 4800 m. In all of these minerals ³He correlates with ¹⁰Be and is dominantly cosmogenic in origin. After modest correction for non-cosmogenic components, ³He/¹⁰Be systematics imply apparent sea-level high-latitude (SLHL) apparent production rates for ³He of 226 atoms g^? 1 yr^? 1 in zircon, 254 atoms g^? 1 yr^? 1 in apatite, 177 atoms g^? 1 yr^? 1 in kyanite, and 153 atoms g^? 1 yr^? 1 in garnet. These production rates are unexpectedly high compared with rates measured elsewhere in the world, and also compared with proposed element-specific production rates. For apatite and zircon, the data are sufficient to conclude that the ³He/¹⁰Be ratio increases with elevation. If this reflects different altitudinal scaling between production rates for the two isotopes then the SLHL production rates estimated by our approach are overestimates. We consider several hypotheses to explain these observations, including production of ³He via thermal neutron capture on ⁶Li, altitudinal variations in the energy spectrum of cosmic-ray neutrons, and the effects of snow cover. Because all of these effects are small, we conclude that the altitudinal variations in production rates of cosmogenic ³He and ¹⁰Be are distinct from each other at least at this location over the last ～ 10 kyr. This conclusion calls into question commonly adopted geographic scaling laws for at least some cosmogenic nuclides. If confirmed, this distinction may provide a mechanism by which to obtain paleoelevation estimates.     

Analyse der Wasserpflanzenentwicklung in Grabensystemen zur Grundwasserregulierung

The meliorated Oberes Rhinluch fen is used by agriculture as grassland with maize-cultivation on about 30 % of its area. In the ditch system of this area with water levels of 30 to 150 there were observed 67 taxa of aquatic plants and marsh plants, of which about 15 achieve covering degrees of more than 3 % and form 80 … 90 % of the biomass. Biomasses of between 20 … 184 g/m² dry weight (Lemna) and 504 … 1612 g/m² (Phragmites) are obtained in pure populations. In mixed populations the biomasses amount to between 304 and 916 g/m² dry weight. According to their density and orientation, riparian copses and trees cause a more or less intense overshadowing of ditches, resulting in a considerable reduction of the biomass of macrophytes. By copses and trees on the south side of the waters the light available may be reduced to 30 %, from which a reduction of the biomass to 10 … 30 % results. By means of such planting it is possible to control the growth of plants in order to reduce the necessary and very expensive weed-removal and bottom-clearing actions.     

Studies on Primary Productivity and some Hydrochemical Aspects of a Polluted Water-body of the Himalayan Jhelum Valley

The lake without any outlet (11 ha, 55000 m³, z_max 2,25 m) has a weak thermal stratification with maximum surface temperatures of 32.5 °C. The annual variation of temperature and depth of visibility is unimodal, with the maxima or minima in August. Phytoplankton consists mainly of Cyanophyceae. The primary production determined by the light-dark bottle technique (oxygen method) varies in the annual variation between 0.3… 0.5 g m^?2 d^?1 C (winter) and 3.4… 4.6 g m^?2 d^?1 C (summer); as the annual means of 1975 and 1976 there were found 1.9 and 2.4 g m^?2 d^?1 C, resp., gross production at a utilization of 0.42… 2.85% of the radiation energy. The chemism is a well-buffered hydrogen-carbonate water (pH 8.1… 9.0) with 74… 90 mg/1 Na and 20.5… 31.5 mg/1 K and with a good nutrient supply (20… 40 μg/1 PO₄—P and 100… 240 μg/1 NO₃—N) at the same time.     

Optical signatures of dissolved organic matter in the watershed of a globally large river (Yangtze River,China)

Parallel factor analysis of fluorescence excitation emission matrices of surface water samples of a globally large river (Yangtze River, China) watershed identified three classes of fluorescent dissolved organic matter (FDOM) that had ex/em = 280/330 nm, 305/385 nm and 350/450 nm respectively, resembling “peak T”, “peak M” and “peak C” commonly identified in natural water, respectively. Peak T (a tyrosine/tryptophan-like FDOM) did not show correlations to peak M or C which were humic-like substances, while a positive correlation (r = 0.935, p < 0.001) was present between the natural log-transformed maximum fluorescence intensity (F_max) of peaks T and M indicating a tight link during their production and processing. F_max values (in Raman unit nm^?1) normalized to dissolved organic carbon (DOC) concentration were low, varying in ranges 15.93–85.95, 29.83–83.54 and 19.73–51.05 × 10^?5 nm^?1 (μmol/L)^?1 for peaks T, M and C, respectively, in line with the history of strong photobleaching of the water samples as indicated by fairly high absorption spectral slope ratios (0.75–1.53 with a mean 1.03). Intermediate fluorescence index (FI) (1.46–1.83 with a mean 1.61) and small specific absorption at 254 nm (0.64–1.93 with a mean 1.15 m^?1 mg^?1 L) of the water samples, indicated the presence of both aquatic microbial DOM (e.g. peak T) and soil DOM (e.g. peak C). Peak C could be substantially removed by UV-A (320–400 nm) irradiation, while peak M was slightly increased when a microbe-containing water was exposed to the same UV-A irradiation. Taken together, peak C was attributed to diffuse soil source while peak M was likely attributed to joint effects of microbial activities and solar irradiation on the chromophores in the sample.     

Grundwasserchemismus im Bezirk Neubrandenburg. Teil 3. Jodid im Grundwasser

The iodide contents in 389 ground-water-tapping plants of the county are compared with the geological character of the aquifer, the carbonate and non-carbonate hardness and the nitrate and chloride contents of the waters. 54% of the plants have I-concentrations of 3 … 7 μg/l. In the air-covered ground-water (hardness quotient<2.8) 2 … 50 μg/l I are found, whereas in the confined ground-water (hardness quotient >2.8) 2 … 50 μg/l I are contained. In general, the I-content increases with the carbonate hardness, a connection with till existing. Therefore, ground-waters of the Miocene have relatively low salt- and I-contents. Geogenic salt influences in the form of NaCl increase the I-contents to 50 … 100 μg/l. Anthropogenic influences in the residential area and due to waste increase the Cl^?- and I^?-concentrations. There were not detected any dependences between the I- and NO₃-contents.     

The zooplankton communities of small water reservoirs with different trophic conditions in two catchments in western Slovakia

Our study summarizes data from six small water reservoirs in West Slovakia and analyzes the occurrence of zooplankton groups in relation to physico-chemical and catchment variables. The reservoirs are in two different catchments – of the Morava and Váh rivers. A total of 103 species were identified; 64 crustaceans (in both the pelagic and littoral zones) and 39 planktonic Rotifera in the pelagic zones. Significant differences were observed in species richness, abundance and biomass of planktonic crustaceans: 48 species were characteristic of the Váh catchment, while 53 were found in the Morava catchment. The density of zooplankton in the three reservoirs of the Váh River catchment ranged from 102 ind L^?1 to 21,488 ind L^?1 and the zooplankton biomass ranged from 0.12 mg L^?1 to 103.29 mg L^?1. The density of zooplankton in three Morava River catchment reservoirs ranged from 2 ind L^?1 to 3928 ind L^?1 and the zooplankton biomass ranged from 0.1 mg L^?1 to 27.3 mg L^?1. The differences were found to be related to catchment (altitude and catchment affiliation), chemical (BOD5, DO) and biological (Chromophyta, Chlorophyta) factors. Eutrophication of reservoirs in the Váh catchment was mainly due to agriculture and fish management, resulting in high nutrient concentrations. Species richness showed an unimodal response to BOD₅ and N-NH₄ with near optimum low values, 4.6 and 0.19 respectively. The relationship to oxygen content reflects preferences for less eutrophic waters and species richness tended to decrease with increasing DO and to decrease with increasing nutrient content.     

1960年以来太湖水生植被演变

太湖的富营养化污染日益严重,针对太湖水生植被的研究工作非常重要,然而全面的太湖水生植被调查已经有将近二十年未见报道.基于2014年夏季全湖水生植被调查结果,结合历史资料,比较分析1960年以来太湖水生植被演变情况.结果表明,1960年以来,共有23种水生植物从太湖消失,其中1981、1997和2014年分别消失7、4和12种.从分布区面积来看,1960年以来太湖水生植被总体呈北部湖区水生植被消失,东北部、东部及南部湖区水生植被分布区面积持续扩张的态势,1981年全湖水生植被分布区面积占8%,到2014年已经有33.82%的水面有水生植被分布.从生物量组成来看,太湖水生植被先升后降,从1960年的10×10⁴ t,持续上升到1988年的44.72×10⁴ t,1997年下降到36×10⁴ t,2014年进一步下降到29.09×10⁴ t.但挺水植被以外的水生植被,尤其是浮叶植被的生物量一直保持上升态势.总生物量的下降与东太湖挺水植被大面积消失有关,到2014年全湖挺水植被生物量比重仅占5.15%,东太湖沼泽化问题已不复存在.从群落组成变化情况来看,苦草（Vallisneria natans）群落分布区面积锐减,马来眼子菜（Potamogeton malaianus）和荇菜（Nymphoides peltatum）分布区持续扩张.目前太湖水生植被管理面临的主要问题是北部湖区水生植被恢复和东部湖区水生植被过量生长.     

Methane Oxidation in the Water Column of Xiangxi Bay,Three Gorges Reservoir

Four field campaigns are carried out to quantify the methane (CH₄) oxidation rate in Xiangxi Bay (XXB) of the Three Gorges Reservoir (TGR), China. The water depth of the sampling site varied from 13 to 30 m resulting from the water level fluctuation of the TGR. The CH₄ oxidation rates are measured in situ as the decline of dissolved CH₄ concentration versus time in incubated, and those rates. The CH₄ oxidation rates range from 1.18 × 10^?3 to 3.69 × 10^?3 µmol L^?1 h^?1, with higher values and stronger variation during summer. A static floating chamber method is used to measure CH₄ emitted to the atmosphere resulting in an annual mean flux of 4.79 µmol m^?2 h^?1. The CH₄ emission rate is significantly negatively correlated with the water level. The results show that a large fraction of CH₄ is consumed in the water column with a range of 28.97–55.90 µmol m^?2 h^?1, accounting for ≈69–98% of the total CH₄ input into the water column, and more than 90% is consumed outside the summer, when the water level is lowest. Water depth, which is dominated by water level of the TGR, is a potentially important driver for CH₄ oxidation and atmospheric emission in the tributary bay.     

Physiologie des Phenolabbaus bei Rhodococcus spec. P1 Teil 1: Beziehungen zwischen Wachstum und Phenolabbau

The Actinomycetes strain of the genus Rhodococcus having been isolated from the river Saale is able to use phenol as the sole carbon source up to concentrations of 2 g/l and metabolizes phenol via the β-ketoadipic acid path (ortho-cleavage). The synthesis of the inducable enzyme system can be inhibited by chloramphenicol. In detailed experiments in discontinuous and continuous cultures the growth rate and the yield coefficient attain their maxima of 0.256 h^?1 and 0.62, resp., at phenol concentrations of 0.5 … 0.8 g/l. At higher substrate concentrations there occurs a substrate inhibition. In the range between 20 and 40°C growth and phenol utilization are highly dependent on temperature.     

滇池东北岸生态修复区的环境效应——Ⅱ.污染净化效应

研究了滇池东北沿岸带生态修复区去除水体中污染物和营养盐的能力．对修复区在重富营养水体迎风岸、无陆源污染情况下通过收获水生植物和促进悬浮物沉降方式去除的湖泊内源污染物质进行了定量的监测分析．结果显示,修复区对外来的悬浮物质具有强大的凝集、固定作用,植被区内每平方米湖面平均年沉积量达118．9 kg(干重),其中的氮、磷、有机碳含量分别达120 g／(m2·a)、70 g／(m2·a)、1080 g／(m2·a):修复区内的底质环境得到明显改善,表层沉积物中氮和有机碳含量比原初提高了4倍以上;修复区内水生植被具有极高的生产能力,仅2002年修复区就收割打捞水生植物113t(干重),由此去除氮、磷分别为30．0 g／(m2·a)和4．8 g／(m2·a).因此,沿岸带生态修复完全可以作为湖泊内源污染净化的一项工程措施在滇池东北沿岸或类似重污染水体推广应用．     

Measurements and estimation of flow velocity in mobile bed rills

Rills are primary sediment sources and hillslope water/sediment runoff transport channels. Water flow velocities in rills are easily affected by bed condition over eroding and non-eroding slopes, which is an important hydrodynamic process in soil erosion research. This research is done to demonstrate the poorly understood “feedback mechanism” related to slope independence of flow velocity to slope gradient. A series of experiments were done on silt loam soil slopes to measure water flow velocity...     

Noctilucent cloud in the western Arctic in 2005: Simultaneous lidar and camera observations and analysis

We report observations of a noctilucent cloud (NLC) over central Alaska by a ground-based lidar and camera on the night of 9–10 August 2005. The lidar at Poker Flat Research Range (PFRR), Chatanika (65°N, 147°W) measured a maximum integrated backscatter coefficient of 2.4×10^?6 sr^?1 with a peak backscatter coefficient of 2.6×10^?9 m^?1 sr^?1 corresponding to an aerosol backscatter ratio of 120 at an altitude of 82.1 km. The camera at Donnelly Dome, 168 km southeast of PFRR, recorded an extensive NLC display across the sky with distinct filamentary features corresponding to wave structures measured by the lidar. The occurrence of the maximum integrated backscatter coefficient corresponded to the passage of a bright cloud band to the southwest over PFRR. The camera observations indicate that the cloud band had a horizontal width of 50 km and a length of 150 km. The horizontal scale of the cloud band was confirmed by medium-frequency radar wind measurements that reported mesopause region winds of 30 m/s to the southwest during the period when the cloud band passed over PFRR. Comparison of these measurements with current NLC microphysical models suggests a lower bound on the water vapor mixing ratio at 83 km of 7–9 ppmv and a cloud ice mass of 1.5–1.8×10³ kg. Satellite measurements show that this NLC display occurred during a burst of cloud activity that began on 5 August and lasted for 10 days. This cloud appeared 10 days after a launch of the space shuttle. We discuss the appearance of NLCs in August over several years at this lower polar latitude site in terms of planetary wave activity and space shuttle launches.     

Surfactant Enhance DLLME/FO‐LADS: Assay of Malachite Green Level in Aquatic Environment of Trout Fish

Malachite green (MG), a traditional agent used in aquaculture although is not approved; its low cost and high efficacy make illicit use likely. We developed a small‐scale, simple, and sensitive dispersive liquid–liquid microextraction procedure for the assay of trace amounts of MG in aquatic environment of Trout fish. Fiber optic‐linear array detection spectrophotometry with charge‐coupled device detector benefiting from a microcell was used for this purpose. The method is based on enhancement effect of an anionic surfactant on the extraction of MG in to very fine multidroplets of microextraction solvent which made assisted by disperser solvent. Under the optimum conditions, the enrichment factor 77.5 was obtained from a 5‐mL water sample. The calibration graph was linear up to 5 × 10^?7 mol L^?1 with detection limit of 1 × 10^?8 mol L^?1. The relative standard deviation for seven replicate measurements of 4 × 10^?7 and 5 × 10^?8 mol L^?1 of MG were 3.3 and 4.5%, respectively.     

Magnetic susceptibility and heavy-metal contamination in topsoils along the Izmit Gulf coastal area and IZAYTAS (Turkey)

The study on topsoil contamination due to heavy metals was carried out by using the Magnetic susceptibility (MS) measurements in Izmit industrial city, northern Turkey. We attempted to investigate correlations between the concentration of selected heavy metals and the MS from 41 sample sites around Izmit Gulf. These investigations let us quantify and standardize the MS method, which may have consequences for long term monitoring of anthropogenic pollution, especially in urban areas. The MS surfer contour map based on the topsoil measurements was compiled with a randomly ranged distance density. The soil samples collected throughout the industrial areas, the parks, road sides and residential areas were also analyzed by Atomic Absorption Spectrometer. Heavy metals Cu, Ni, Cr and Pb show strong correlations with MS, while Zn and Co show a weak correlation with MS. Moreover, the Tomlinson pollution load index (PLI) shows insignificant correlation with the MS.The MS was examined vertically (0–30 cm) with respect to anthropogenic and/or lithogenic influences at the fourteen sample sites. The maximum values were mostly observed in depths of 2–5 cm and the MS values on the depth profiles vary between 10 × 10^? 8 m³ kg^? 1 and 203 × 10^? 8 m³ kg^? 1. The study revealed that MS is an inexpensive, fast and non-destructive method for the detection and mapping of contaminated soils.     

Formation of iron plaque on mangrove roots receiving wastewater and its role in immobilization of wastewater-borne pollutants

Iron (Fe) plaque formed on mangrove root increased with wastewater discharge, but the extent was species-specific. For Bruguiera gymnorrhiza, Fe plaque concentration was 0.80 mg g⁻¹ root d.wt at Day 0 and increased to 4.59, 6.84 and 7.52 mg g⁻¹ at Day 75 in the fresh water control (FW), synthetic wastewater with pollutant concentrations five times of municipal sewage (5SW) and double of 5SW (10SW) treatments, respectively; the respective increases in Excoecaria agallocha were from 0.70 to 2.37, 10.73 and 13.21 mg g⁻¹. For Acanthus ilicifolius, similar increase was found in 5SW, but all of the plants were dead in 10SW at Day 75. The concentrations of heavy metals and phosphorus immobilized were positively correlated with the amounts of Fe plaque formed, but the regression coefficients varied among species. The performance of mangrove plants in wastewater treatments was related to the Fe plaque formed and its immobilized wastewater-borne pollutants.