About the Role of Quinones in the Action of Some Polyphenols on the Streaming of Protoplasm in Nitella sp. Cells

The concentration of phenols and quinones which stopped the protoplasmic movement in the Nitella cells after 15 min was determined. The quinones (β-naphthoquinone, α-naphthoquinone, p-benzoquinone, o-toluquinone, o-bromanil) stopped the protoplasmic movement in the concentration of (1 3) 10^?4 M, phenols (m-cresol, p-cresol, hydroquinone, guaiacol, phenol, gallic acid, pyrogallic acid, resorcinol) in the concentration of (0.2 5) 10^?2 M, except catechol – 2 10^?3 M. Very high toxicity of catechol and in the prolonged experiments (3 hours) also of hydroquinone is connected with the action of quinonoid productions of its oxidation. This suggestion is confirmed by the experiments:

• – by adding the phenol solutions to Nitella shoots (catechol, hydroquinone, resorcinol) we observed the greatest increase of oxygen absorption in case of catechol (86%), less in case of hydroquinone (38%), and for resorcinol oxygen absorption practically remained on the control level;
• – the action of catechol, hydroquinone and p-benzoquinone did not take place in the presence of glutathione and cysteine (but not cystine and oxidated glutathione);
• – diethyldithiocarbamate as an inhibitor of o-diphenoloxidase reduced the ability of catechol solutions to stop the protoplasmic movement;
• – the low concentrations of benzoquinones were able to stop the protoplasmic movement;
• – for stopping the protoplasmic movement under the prolonged time of incubation from 15 min to 3 hours there was necessary a lower concentration of solutions of hydroquinone and catechol in comparison with resorcinol.

     

Oxidation of Benzo(a) Pyrene Catalyzed by Phenol Oxidases of Alga Nitella sp. and Potato Tubers

The kinetics of oxidation of carcinogenic benzo(a)pyrene (0.1 nM solution in phosphate buffer) catalyzed by enzyme protein of soil and water plants (potato tubers and alga Nitella sp.) has been studied. The benzo(a)pyrene oxidation rate is determined by the phenoloxidase activity of the enzyme protein from both sources to an equal degree and expressed by the Michaelis-Menten equation. The values for k_cat and apparent K_m were (0.97 ± 0.14) Ms^?1 and 33 ± 6 μM, respectively. The presence of other compounds (including protein substances) in acetone preparations of potato tubers considerably suppresses its catalytic activity in relation to benzo(a)pyrene. Consequently, in the polluted biosphere some water plants, such as alga Nitella sp., and potato tuber can transform carcinogenic benzo(a)pyrene (BP). As oxidation products, all three BP-quinones, i.e. 1,6-, 3,6-and 6,12-diones, were identified.     

Surfactant Enhance DLLME/FO‐LADS: Assay of Malachite Green Level in Aquatic Environment of Trout Fish

Malachite green (MG), a traditional agent used in aquaculture although is not approved; its low cost and high efficacy make illicit use likely. We developed a small‐scale, simple, and sensitive dispersive liquid–liquid microextraction procedure for the assay of trace amounts of MG in aquatic environment of Trout fish. Fiber optic‐linear array detection spectrophotometry with charge‐coupled device detector benefiting from a microcell was used for this purpose. The method is based on enhancement effect of an anionic surfactant on the extraction of MG in to very fine multidroplets of microextraction solvent which made assisted by disperser solvent. Under the optimum conditions, the enrichment factor 77.5 was obtained from a 5‐mL water sample. The calibration graph was linear up to 5 × 10^?7 mol L^?1 with detection limit of 1 × 10^?8 mol L^?1. The relative standard deviation for seven replicate measurements of 4 × 10^?7 and 5 × 10^?8 mol L^?1 of MG were 3.3 and 4.5%, respectively.     

The Accumulation of Crimidin in Some Fish Organs

The accumulation of crimidin in total samples and in some organs of five fish species was studied under experimental conditions. The species were Cyprinus carpio, Carassius carassius, Tinca tinca, Scardinus erythrophthalmus and Leucaspius delineatus. Fish were exposed to concentrations of 10 mg · l^?l and 50 mg · l^?1. During short-term experiments water and fish samples were taken at intervals of t = 0, 6, 12, 24, 48 and 72 hours, during the long-term experiment sampling was performed weekly for six weeks. Total samples were analysed for C. carassius, T. tinca, S. erythrophthalmus and L. delineatus. Samples of individual organs and tissues were taken as follows: C. carpio – gills, digestive tract, muscular tissue, kidneys, gonads; C. carassius – gills, digestive tract, muscular tissue, ovaries, testes. Crimidin was determined by gas chromatography. In samples from the short-term experiments at a concentration of 10 mg · l^?1 in the water the amount was roughly 10¹–10 mg · kg^?1, at a concentration of 50 mg · l^?1 in the water roughly 10¹ mg · kg^?1. In most cases the accumulation coefficient was lower than 1.0. The accumulation capacity of individual fish species did not differ greatly. Of the internal organs only the kidneys had a high accumulation capacity, otherwise the highest values were found in muscular tissue and the gills. After one – three weeks the amount of crimidin in most organs falls, and after transfer to clean water there is a general sharp decline. Thus crimidin is not firmly bound in the body.     

Estimating Net Primary Productivity and Nutrient Stock in Plant in Freshwater Marsh,Northeastern China

We have investigated the contributions of three dominant macrophyte species, Deyeuxia angustifolia, Carex lasiocarpa, and Carex pseudocuraica (covering about 10 304 km²), to carbon (C), nitrogen (N), and phosphorus (P) stocks in the largest freshwater marsh (17 300 km²) in China for a 3‐year period (from 2002 to 2004). The monthly biomass, seasonal, and annual net primary productivity (NPP), and nutrient concentrations of three species were measured. All three plant species showed rapid growth in the rainy season. The maximum and minimum production rates in the freshwater marsh were ～36.19 and ～9.92 g m^?2 day^?1, respectively. The total NPP accounts 1900–2700 g m^?2 year^?1 in the studied area. Total organic carbon (TOC), total nitrogen (TN), and total phosphorus (TP) concentrations in roots were higher than those in stem and leaf tissues. The vast beds of the three studied species comprise 80% of the grass covered marsh of Sanjiang plain, contributing annual nutrient stocks of ～10.99 × 10⁶, ～788.36 × 10³, and ～18.10 × 10³ t (tonnes) for TOC, TN, and TP, respectively. Our results suggest that the nutrient bioaccumulation capacity in freshwater marshes depend mainly on plant species, which are decided by hydrological conditions. The nutrient stocks in the Sanjiang plain marsh have been greatly reduced because some of the area occupied by C. lasiocarpa was replaced by D. angustifolia as a result of succession caused by the changes of water table.     

Step–pool evolution in the Rio Cordon,northeastern Italy

The principle that formative events, punctuated by periods of evolution, recovery or temporary periods of steady‐state conditions, control the development of the step–pool morphology, has been applied to the evolution of the Rio Cordon stream bed. The Rio Cordon is a small catchment (5 km²) within the Dolomites wherein hydraulic parameters of floods and the coarse bedload are recorded. Detailed field surveys of the step–pool structures carried out before and after the September 1994 and October 1998 floods have served to illustrate the control on step–pool changes by these floods. Floods were grouped into two categories. The first includes ‘ordinary’ events which are characterized by peak discharges with a return time of one to five years (1·8–5·15 m³ s^?1) and by an hourly bedload rate not exceeding 20 m³ h^?1. The second refers to ‘exceptional’ events with a return time of 30–50 years. A flood of this latter type occurred on 14 September 1994, with a peak discharge of 10·4 m³ s^?1 and average hourly bedload rate of 324 m³ h^?1. Step–pool features were characterized primarily by a steepness parameter c = (H/L_s)/S. The evolution of the steepness parameter was measured in the field from 1992 to 1998. The results indicate that maximum resistance conditions are gradually reached at the end of a series of ordinary flood events. During this period, bed armouring dominate the sediment transport response. However, following an extraordinary flood and unlimited sediment supply conditions, the steepness factor can suddenly decrease as a result of sediment trapped in the pools and a lengthening of step spacing. The analogy of step spacing with antidune wavelength and the main destruction and transformation mechanism of the steps are also discussed. Copyright © 2001 John Wiley & Sons, Ltd.     

Five‐Year Soil Respiration Reflected Soil Quality Evolution in Different Forest and Grassland Vegetation Types in the Eastern Loess Plateau of China

Soil CO₂ efflux in forest and grassland over 5 years from 2005 to 2009 in a semiarid mountain area of the Loess plateau, China, was measured. The aim was to compare the soil respiration and its annual and inter‐annual responses to the changes in soil temperature and soil water content between the two vegetation types for observing soil quality evolution. The differences among the five study years were the annual precipitation (320.1, 370.5, 508.8, 341.6, and 567.4 mm in 2005–2009, respectively) and annual distribution. The results showed that the seasonal change of soil respiration in both vegetation types was similar and controlled by soil temperature and soil water content. The mean soil respiration across 5 years in the forest (3.78 ± 2.68 µmol CO₂ m^?2 s^?1) was less than that in the grassland (4.04 ± 3.06 µmol CO₂ m^?2 s^?1), and the difference was significant. The drought soil in summer depressed soil respiration substantially. The Q₁₀ value across 5‐year measurements was 2.89 and 2.94 for forest and grassland. When soil water content was between wilting point (WP) and field capacity (FC), the Q₁₀ in both types increased with increasing soil water content, and when soil water content dropped to below WP, soil respiration and the Q₁₀ decreased substantially. Although an exponential model was well fitted to predict the annual mean soil respiration for each single year data, it overestimated and underestimated soil respiration, respectively, in drought conditions and after rain for short periods of time during the year. The two‐variable models including temperature and water content variables could be well used to predict soil respiration for both types in all weather conditions. The models proposed are useful for understanding and predicting potential changes in the eastern part of Loess plateau in response to climate change.     

Inhibition Concentration of Phenolic Substances under Different Cultivation Conditions. Part I: Phenol Oxidation by Mixed Microbial Population in a Model System

The effects of oxygen supply rate and the presence or absence of nutrients on the kinetics of phenol degradation and oxygen consumption by a mixed microbial population were tested in a model system. The values for the maximum specific rate of phenol degradation (q_Smax), the saturation constant (K_S), and the inhibition concentration (S_CR) were determined for unlimited growth (K_La = 340 h^?1, growth medium) with 1.7 mmol g^?1 h^?1, 65 mg L^?1, and 190 mg L^?1. Under limitation conditions, alterations occur depending on the type of limitation. Nutrient limitations lead to values of 0.8 mmol g^?1 h^?1, 45 mg L^?1, and 160 mg L^?1, and oxygen limitations lead to 1.2 mmol g^?1 h^?1. 30 mg L^?1, and 120 mg L^?1, respectively. The results suggest that with excess oxygen, the rate of phenol degradation was higher and the inhibition effect of phenol was suppressed to some extent. Under the same high oxygen supply rate, the presence of nutrients in the model water significantly supported the phenol degradation rate.     

Residual vorticity induced by the action of tidal currents in combination with bottom topography in the Southern Bight of the North Sea

Abstract

Results are presented of calculations on the generation of residual vorticity by tidal currents over the bottom topography of the Southern Bight of the North Sea. A typical order of magnitude is 10^?6 to 10^?7 s ^?1. This is compared with current measurements on calm days, when similar magnitudes are found. At windspeeds less than about 5 m/s tidal generation of residual vorticity is important; at higher windspeeds wind effects begin to dominate. Our results are relevant in understanding the spatial variability of residual currents, because a non-zero vorticity implies the existence of horizontal gradients in the residual current field.     

A source-Sink laboratory model of the ocean circulation

Abstract

A two gyre circulation and inertial western boundary currents have been observed in a sloping bottom laboratory model of a barotropic ocean circulation. Water of viscosity v is contained in a rotating (angular velocity ω), square basin of side L (30 cm) with a flat top and a bottom slope (tan θ) such that the depth (H) varies from 12 to 15 cm. The flow is driven by a distributed source and sink at the upper surface, a plate drilled with 342 holes. The hole distribution and size is arranged so that the average imposed vertical velocity, w = w ₀ sin (2πy′/30), models the Ekman divergence from a two gyre zonal wind stress. Fluid flow is observed with the thymol blue technique over the ranges of Rossby numbers (w ₀/2ωL tan θ) from 1.44 × 10^?3 to 1.41 × 10^?2 and Ekman numbers (v/2ωH ²) from 2.13 × 10^?5 to 2.10 × 10^?3. At the largest Rossby numbers the flow pattern changes markedly, but the non-uniformity of the imposed vertical velocity also penetrates deep into the fluid in this regime.     

Determining thermal diffusivity using near‐surface periodic temperature variations and its implications for tracing groundwater movement at the eastern margin of the Tibetan Plateau

The thermal diffusivity is the key parameter that controls near‐surface temperature where periodic temperature variation is progressively attenuated and delayed with depth. This article presents the results of apparent thermal diffusivity using temperatures recorded by a bedrock temperature measurement network in the fault zones of western Sichuan. High sensitivity temperature sensors (10^?4 K) were installed at a maximum depth reaching 30 m. The apparent thermal diffusivities were deduced from both amplitude damping and phase shifting of annual temperature variations between two different depths. Under pure conduction, the thermal diffusivity determined through the phase method (α_Φ) should be equivalent to that determined through the amplitude method (α_A), whereas effects of the upward (downward) water flow are evidently reflected in the amplitude decay to make α_Φ larger (lesser) than α_A. The discrepancy between α_Φ and α_A can thus be a tracer of water movement or convective heat transfer. The calculated α_Φ of the measurement stations varies from 1.22 × 10^?6 to 3.00 × 10^?6 m²/s, and the estimated α_A ranges from 0.93 × 10^?6 to 2.41 × 10^?6 m²/s. Two regimes of heat transfer underground were suggested from the results. Conductive heat transport prevails over the nonconductive processes at five stations, which is characterized by α_Φ coincident with α_A for the same depth pair. On the contrary, the values of α_Φ differ from α_A at six stations in the intersection area of the Y‐shaped fault system, implying that convective heat transfer also plays a comparably important role. This finding is consistent with the hot springs distribution of the area. The results also indicate that water moves upward with an average Darcy velocity of approximately ?1 × 10^?7 m/s in this region. Our research provides new evidence for the hydrothermal activity in the fault zones at the eastern margin of the Tibetan Plateau.     

Effect of Single Species or Mixed Algal (Chlorella vulgaris and Scenedesmus acutus) Diets on the Life Table Demography of Brachionus calyciflorus and Brachionus patulus (Rotifera: Brachionidae)

We tested the effect of two algal diets (Chlorella vulgaris at 1 · 10⁶ cells mL^?1and Scenedesmus acutus at 0.57 · 10⁶ cells mL^?1) offered alone or in combination (50 % each, 75 % or 25 % of either alga), at a total dry weight of 14.2 μg mL^?1on the life table demography of two rotifer species, Brachionus calyciflorus and Brachionus patulus. Data on fecundity indicated that, for any given algal food type or combination of food types, B. calyciflorus had a higher rate of offspring production than B. patulus. Regardless of the rotifer species, the average lifespan varied from 4 to 6 days. The gross and net reproductive rates were higher for B. calyciflorus than for B. patulus. These values ranged from 45 to 71 offspring female^?1 lifespan^?1 and 15 to 24 offspring female^?1 lifespan^?1, respectively, for B. calyciflorus. Generation times (around 4…5 days) were similar for both rotifer species in most of the treatments. Whatever the algal food combination, the rate of population increase (d^?1) of B. patulus was less than half (i.e. 45 %) of that for B. calyciflorus. The observed differences in the life history variables of Brachionus probably explain species‐specific adaptations to the changing phytoplankton composition occurring seasonally in natural waterbodies.     

Hydrogeologic Controls on Induced Seismicity in Crystalline Basement Rocks Due to Fluid Injection into Basal Reservoirs

A series of M_b 3.8–5.5 induced seismic events in the midcontinent region, United States, resulted from injection of fluid either into a basal sedimentary reservoir with no underlying confining unit or directly into the underlying crystalline basement complex. The earthquakes probably occurred along faults that were likely critically stressed within the crystalline basement. These faults were located at a considerable distance (up to 10 km) from the injection wells and head increases at the hypocenters were likely relatively small (～70–150 m). We present a suite of simulations that use a simple hydrogeologic‐geomechanical model to assess what hydrogeologic conditions promote or deter induced seismic events within the crystalline basement across the midcontinent. The presence of a confining unit beneath the injection reservoir horizon had the single largest effect in preventing induced seismicity within the underlying crystalline basement. For a crystalline basement having a permeability of 2 × 10^?17 m² and specific storage coefficient of 10^?7/m, injection at a rate of 5455 m³/d into the basal aquifer with no underlying basal seal over 10 years resulted in probable brittle failure to depths of about 0.6 km below the injection reservoir. Including a permeable (k_z = 10^?13 m²) Precambrian normal fault, located 20 m from the injection well, increased the depth of the failure region below the reservoir to 3 km. For a large permeability contrast between a Precambrian thrust fault (10^?12 m²) and the surrounding crystalline basement (10^?18 m²), the failure region can extend laterally 10 km away from the injection well.     

Methods of Analyzing Quinones in Water and Their Application in Studying the Effects of Hydrophytes on Phenols. Part 4: Accumulation of Exogenic Phenols,Localization of Endogenic Phenols and o-Diphenol Oxidase in Nitella Cells

By using Nitella, with the aid of a technique which is described in detail the uptake of resorcinol by the cytoplasm was demonstrated and quantitatively determined under different test conditions. In contrast to the phenol oxidation products of hydroquinone and pyrocatechol, the further “fate” of the resorcinol taken up by the cell substance is not yet fully clear. The rate of resorcinol absorption has been defined with a permeability constant.     

Efficiency of Pleurotus florida Laccase on Decolorization and Detoxification of the Reactive Dye Remazol Brilliant Blue R (RBBR) under Optimized Conditions

Laccase from the white‐rot fungus Pleurotus florida, produced under solid‐state fermentation conditions, was used for the decolorization of reactive dye Remazol Brilliant Blue R (RBBR). RBBR was decolorized up to 46% by P. florida laccase alone in 10 min. In the presence of N‐hydroxybenzotriazole (HBT), the rate of decolorization was enhanced 1.56‐fold. Central composite design of response surface methodology with four variables namely, dye, enzyme, redox mediator concentrations, and time at five levels was applied to optimize the RBBR decolorization. The predicted optimum level of variables for maximum RBBR decolorization (87%) was found to be 52.90 mg L^?1 (RBBR), 1.87 U mL^?1 (laccase), 0.85 mM (HBT), and 7.17 min (time), respectively. The validation results showed that the experimental value of RBBR decolorization (82%) was close to the predicted one. The disappearance of C–N and C–X groups, and a small shift in N–H groups in Fourier‐transform infra red (FTIR) spectroscopy confirms the degradation of RBBR chromophore by laccase enzyme. The phytotoxicity of RBBR was considerably reduced after the treatment with laccase. RBBR decolorization kinetics; K_m and V_max were calculated to be 145.82 mg L^?1 and 24.86 mg L^?1 min, respectively.     

Quantification of Diclofenac in Hospital Effluent and Identification of Metabolites and Degradation Products

In this study the occurrence of diclofenac and sub‐products in effluent emerging from the University Hospital at the Federal University of Santa Maria was investigated. One metabolite was identified and, in aqueous solution, three degradation products. The quantification was conducted by means of HPLC‐DAD, and the determination of metabolite and degradation products by LC–ESI–MS/MS–QTrap. For the HPLC‐DAD method, a 70:30 mixture of methanol/sodium phosphate was used in isocratic mode. For the LC–ESI–MS/MS–QTrap determinations, a mobile phase, where phase A was an ammonium acetate solution 5 × 10^?3 mol L^?1, and phase B was methanol (5 × 10^?3 mol L^?1)/ammonium acetate (9:1, v/v), on gradient mode. The LDs for the HPLC and LC–MS/MS methods, respectively, were 2.5 and 0.02 µg L^?1, the LQs, 8.3 and 0.05 µg L^?1, and the linear range from 10 up to 2000 µg L^?1 and 0.05 up to 10 µg L^?1. As expected, the LC–ESI–MS/MS–QTrap method was more sensitive and less laborious. The metabolite 4′‐hydroxy‐diclofenac was identified. Photolysis was used for the degradation studies and three products of diclofenac were identified (m/z of 214, 286 and 303) in aqueous solution. These results notwithstanding, no degradation products of diclofenac were found in the hospital effluent.     

Ultrasound‐Assisted Emulsification–Microextraction Combined with Graphite Furnace Atomic Absorption Spectrometry for the Determination of Trace Lead in Water

The ultrasound‐assisted emulsification–microextraction (USAEME) method was combined with graphite furnace atomic absorption spectrometry (GFAAS) for the determination of trace Pb using dithizone (H²DZ) as chelating reagent. Some effective parameters influenced the detection and microextraction, such as ashing temperature and atomization temperature, pH, extraction solvent, sample volume, extraction time, and extraction temperature were selected and optimized. After extraction, the calibration curves for Pb was in the concentration range of 0.1–10 ng mL^?1, and the linear equation was y = 0.097 x + 0.023 (R = 0.99). Under the optimized conditions, the detection limit of the method was 20 pg mL^?1 with an enrichment factor of 70 and the relative standards deviation (RSD) for seven determinations of 1 ng mL^?1 Pb was 11%. The proposed method was successfully applied to determine trace Pb in Yueya Lake water, pond water, and spiked samples. Furthermore, a certified reference material of Environment Water (GBW08607) was analyzed and the determined value was in good agreement with the certified value, which showed the accuracy, recovery, and applicability of the reported method.     

Hydrochemical behaviour of dissolved nitrogen and carbon in a headwater stream of the Canadian Shield: relevance of antecedent soil moisture conditions

This paper examines the impact of contrasting antecedent soil moisture conditions on the hydrochemical response, here the changes in dissolved nitrogen (NO₃^?, NH₄⁺ and dissolved organic nitrogen (DON)) and dissolved organic carbon (DOC) concentrations, of a first‐order stream during hydrological events. The study was performed in the Hermine, a 5 ha forested watershed of the Canadian Shield. It focused on a series of eight precipitation events (spring, summer and fall) sampled every 2 or 3 h and showing contrasted antecedent moisture conditions. The partition of the eight events between two groups (dry or wet) of antecedent moisture conditions was conducted using a principal component analysis (PCA). The partition was controlled (first axis explained 86% of the variability) by the antecedent streamflow, the streamflow to precipitation ratio Q/P and by the antecedent groundwater depth. The mean H⁺, NO₃^?, NH₄⁺, total dissolved nitrogen and DOC concentrations and electrical conductivity values in the stream were significantly higher following dry antecedent conditions than after wetter conditions had prevailed in the Hermine, although the temporal variability was high (17 to 138%). At the event scale, a significantly higher proportion of the changes in DON, NO₃^?, and DOC concentrations in the stream was explained by temporal variations in discharge compared with the seasonal and annual scales. Two of the key hydrochemical features of the dry events were the synchronous changes in DOC and flow and the frequent negative relationships between discharge and NO₃^?. The DON concentrations were much less responsive than DOC to changes in discharge, whereas NH was not in phase with streamflow. During wet events, the synchronicity between streamflow and DON or NO₃^? was higher than during dry events and discharge and NO₃^? were generally positively linked. Based on these observations, the hydrological behaviour of the Hermine is conceptually compatible with a two‐component model of shallow (DON and DOC rich; variable NO₃^?) and deep (DON and DOC poor; variable NO₃^?) subsurface flow. The high NO₃^? and DOC levels measured at the early stages of dry events reflected the contribution from NO₃^?‐rich groundwaters. The contribution of rapid surface flow on water‐repellent soil materials located close to the stream channel is hypothesized to explain the DOC levels. An understanding of the complex interactions between antecedent soil moisture conditions, the presence of soil nutrients available for leaching and the dynamics of soil water flow paths during storms is essential to explain the fluxes of dissolved nitrogen and carbon in streams of forested watersheds. Copyright © 2007 John Wiley & Sons, Ltd.     

Equilibrium,Kinetic, and Thermodynamic Studies on the Adsorption of Triclosan onto Multi‐Walled Carbon Nanotubes

The increased accumulation of toxic pharmaceuticals and personal care products in the environment is a concern of worldwide relevance. Efficient technologies are needed to mitigate the level of such chemicals in natural waters. The suitability of multi‐walled carbon nanotubes (MWCNTs) to remove aqueous triclosan (a widely used anti‐microbial agent) was investigated in the present study. Tested operational parameters included the pH (3.0–11.0) value and the ionic strength (10^?3, 10^?2, and 10^?1 M). Kinetic and thermodynamic studies were conducted at different initial concentrations (4, 8, and 10 mg/L) and temperatures (288, 298, and 308 K). Results showed higher triclosan adsorption at pH 3.0 (157.7 mg/g) than at pH 11.0 (103.9 mg/g). With an increase of ionic strength from 10^?3 to 10^?2 M, the adsorption capacity increased from 136.1 to 153.1 mg/g and from 80.8 to 105.8 mg/g at pH 3.0 and 10.0, respectively, while further increase of ionic strength to 10^?1 M slightly reduced the triclosan adsorption to 149.9 and 94.7 mg/g due to the aggregation of MWCNTs. The Polanyi–Manes model (PMM) provided a best fitting of adsorption isotherms to the experimental data, and the kinetic process was well described by the pseudo second‐order kinetic model. The calculated thermodynamic parameters (ΔH⁰ = ?88.08 kJ/mol, ΔS⁰ = ?173.38 J/mol K) suggested that the adsorption of triclosan is spontaneous and exothermic in nature. The findings of the present work have significant implications for the removal of triclosan from aqueous solution with MWCNTs.