贵州荔波董歌洞较老石笋ICP-MS~(230)Th测年研究及古气候应用

石笋记录研究的进展与测年技术的发展密不可分,测年新技术的突破不断推动利用石笋重建古气候研究的飞速前进。在利用石笋进行古气候重建过程中,建立精确的时标是首要条件。通过对较老(>250ka)石笋的ICP-MS230Th测年研究,发现贵州荔波董歌洞D6、D7、D9石笋具有比较连续的高分辨记录,最老年龄超过400ka,通过230Th测年数据的分析为建立我国西南地区500ka以来标准剖面打下基础;对董歌洞3根大型石笋135个230Th年龄数据及生长速率的分析研究,发现石笋生长速率在大尺度的变化上与海洋沉积SPECMAP曲线δ18O记录有很好的负相关关系,并与北纬25°夏季太阳辐射能量变化曲线呈一定的正相关关系,石笋生长速率的变化在间冰期处于高值,而在冰期时为低值,在间冰期和冰期转化阶段生长速率呈跳跃式变化。通过生长速率变化分析表明,石笋生长速率记录了过去突变冷暖事件的变化,因此可以作为一个有意义的环境记录替代指标来研究古降水及古气候变化。     

A paleoclimate record of the last 17,600 years in stalagmites from the B7 cave,Sauerland, Germany

Petrographical and geochemical parameters of stalagmites from the B7 cave in Iserlohn–Letmathe (Northern Rhenish Massif, NW Germany) record Late- and postglacial climate changes (temperature and/or precipitation). Fabrics and microfacies of the stalagmite profiles lead to a differentiation of four hierarchies of rhythms. Clastic layers in the stalagmites are caused by flooding events and are time markers. Twenty-four TIMS Th/U-age-dates provide a time calibration of stalagmite growth phases. One stalagmite reveals an early growth period between 17.6 and 16.7 ka BP. Between 9.6 and 5.5 ka BP (Atlantic episode of the Holocene) the growth rate of the stalagmites was higher than before and after this time, with dominant light-porous microfacial laminae and high δ¹⁸O and δ¹³C values representing partly kinetic fractionation effects. This part of the Holocene is interpreted as a mainly warm episode with frequent interruptions of dripping. Within the past 4 ka the profiles with predominant dark compact facies reveal low isotopic values which may be interpreted as a temperature proxy record. The stalagmite records resemble records from an Irish stalagmite. Correlation with the Δ¹⁴C record from European tree rings suggests that colder periods in the North Atlantic were accompanied by drier winters in central Europe.     

Textural and carbon isotopic evidence of monsoonal changes recorded in a composite-type speleothem from Korea since MIS 5a

Textural and stable isotopic records of a composite-type speleothem from Gwaneum Cave in the eastern part of the Korean peninsula show prominent paleoenvironmental changes since MIS (marine oxygen isotope stage) 5a. Based on ²³⁰Th/²³⁴U dating, the speleothem experienced growth from 90.9 ± 6.5 ka to 1.2 ± 0.5 ka with several hiatuses. Four growth phases (A, B, C and D) are recognized based on speleothem type and texture. Very irregular and laterally discontinuous growth laminae in Phases B and C indicate that the cave coralloids grew over the stalagmite (Phase A) when the supply of dripping water became limited. Variations within the δ¹³C time series of Phase A are interpreted as responses to millennial-scale fluctuations of the East Asian monsoon intensity during MIS 5a. The monsoonal interpretation is based on the idea that δ¹³C values reflect the isotopic composition of soil-derived CO₂, which, in turn, should relate to monsoon-driven changes in terrestrial productivity above the cave during the MIS 5a. Our reconstruction reveals that the significant monsoonal changes on the Korean peninsula occurred in conjunction with changes in sea level and/or oceanic circulations during the transition period from MIS 5a to MIS 4.     

Persistent millennial-scale climatic variability over the past 25,000 years in Southern Africa

Data from stalagmites in the Makapansgat Valley, South Africa, document regional climatic change in southern Africa in the Late Pleistocene and Holocene. A new TIMS U-series dated stalagmite indicates speleothem growth from 24.4 to 12.7 ka and from 10.2 to 0 ka, interrupted by a 2.5 ka hiatus. High-resolution oxygen and carbon stable isotope data suggest that postglacial warming was first initiated 17 ka, was interrupted by cooling, probably associated with the Antarctic Cold Reversal, and was followed by strong warming after 13.5 ka. The Early Holocene experienced warm, evaporative conditions with fewer C₄ grasses. Cooling is evident from 6 to 2.5 ka, followed by warming between 1.5 and 2.5 ka and briefly at AD 1200. Maximum Holocene cooling occurred at AD 1700. The new stalagmite largely confirms results from shorter Holocene stalagmites reported earlier. The strongest variability superimposed on more general trends has a quasi-periodicity between 2.5 and 4.0 ka. Also present are weaker 1.0 ka and 100-year oscillations, the latter probably solar induced. Given similarities to the Antarctic records, the proximate driving force producing millennial- and centennial-scale changes in the Makapansgat record is postulated to be atmospheric circulation changes associated with change in the Southern Hemisphere circumpolar westerly wind vortex.     

Decoupling of the East Asian summer monsoon and Indian summer monsoon between 20 and 17 ka

Marine Oxygen Isotope Stage (MIS) 2, with its profound environmental and climatic changes from before the last glacial maximum (LGM) to the last deglaciation, is an ideal period for understanding the evolution of the East Asian summer monsoon (EASM) and Indian summer monsoon (ISM), two Asian monsoon sub-systems. With 875 stable oxygen isotope ratios and 43 ²³⁰Th dates from stalagmites in Sanxing Cave, southwestern China, we construct and interpret a new, replicated, Asian summer monsoon (ASM) record covering 30.9–9.7 ka with decadal resolution. δ¹⁸O records from this site and other reported Chinese caves display similar long-term orbitally dominated trends and synchronous millennial-scale strong and weak monsoonal events associated with climate changes in high northern latitudes. Interestingly, Sanxing δ¹⁸O and Arabian Sea records show a weakening ISM from 22 to 17 ka, while the Hulu and Qingtian records from East and Central China express a 3-ka intensifying EASM from 20 to 17 ka. This decoupling between EASM and ISM may be due to different sensitivities of the two ASM sub-systems in response to internal feedback mechanisms associated with the complex geographical or land-ocean configurations.     

Millennial-scale variations in western Sierra Nevada precipitation during the last glacial cycle MIS 4/3 transition

Dansgaard–Oeschger (D–O) cycles had far-reaching effects on Northern Hemisphere and tropical climate systems during the last glacial period, yet the climatic response to D–O cycles in western North America is controversial, especially prior to 55 ka. We document changes in precipitation along the western slope of the central Sierra Nevada during early Marine Oxygen Isotope Stages (MIS) 3 and 4 (55–67 ka) from a U-series dated speleothem record from McLean's Cave. The timing of our multi-proxy geochemical dataset is coeval with D–O interstadials (15–18) and stadials, including Heinrich Event 6. The McLean's Cave stalagmite indicates warmer and drier conditions during Greenland interstadials (GISs 15–18), signified by elevated δ¹⁸O, δ¹³C, reflectance, and trace element concentrations, and less radiogenic ⁸⁷Sr/⁸⁶Sr. Our record extends evidence of a strong linkage between high-latitude warming and reduced precipitation in western North America to early MIS 3 and MIS 4. This record shows that the linkage persists in diverse global climate states, and documents the nature of the climatic response in central California to Heinrich Event 6.     

Speleothem evidence for late Holocene climate variability and floods in Southern Greece

We present stable isotope data (δ¹⁸O, δ¹³C) from a detrital rich stalagmite from Kapsia Cave, the Peloponnese, Greece. The cave is rich in archeological remains and there are reasons to believe that flooding of the cave has directly affected humans using the cave. Using a combination of U–Th and ¹⁴C dating to constrain a site-specific correction factor for (²³²Th/²³⁸U) detrital molar ratio, a linear age model was constructed. The age model shows that the stalagmite grew during the period from ca. 950 BC to ca. AD 830. The stable oxygen record from Kapsia indicates cyclical changes of close to 500 yr in precipitation amount, with rapid shifts towards wetter conditions followed by slowly developing aridity. Superimposed on this signal, wetter conditions are inferred around 850, 700, 500 and 400–100 BC, and around AD 160–300 and AD 770; and driest conditions are inferred to have occurred around 450 BC, AD 100–150 and AD 650. Detrital horizons in the stalagmite indicate that three major floods took place in the cave at 500 BC, 70 BC and AD 450. The stable carbon isotope record reflects changes in biological activity being a result of both climate and human activities.     

Spatially variable sedimentary responses to orbitally driven pluvial climate during Marine Oxygen Isotope Stage 5.1, Dakhla Oasis region, Egypt

Pleistocene basinal sediments (PBS) in the Dakhla region of Egypt's hyperarid Western Desert comprise four facies: (A) fluvio-lacustrine, (B) mixed lacustrine/pluvio-eolian, (C) pluvio-eolian, and (D) mixed eolian/pluvio-eolian. Contiguity of basins containing each facies, and their stratigraphic position between two bajada gravel formations, P/B-II and P/B-III, confirm their equivalence. Facies A and B, with lacustrine components, are attributed to orbitally forced poleward incursion of the Intertropical Convergence Zone (ITCZ), resulting in increased summer insolation/temperature/precipitation. Facies C and D, comprising pluvio-eolian and eolian sediments, reflect geologic/topographic influences overprinted on regional 'pluvial' conditions, eliminating lacustrine response. A Th/U age of ∼ 62 ka on lacustrine marl within Facies B is minimal, and an OSL age of 110 ± 18 ka on sediments immediately below Facies B is maximal. Since bajada gravels P/B-III are the youngest Pleistocene formation, they must represent the final strong incursion of the ITCZ into the Dakhla region at MIS 5.1, ∼ 80 ka. Because PBS Facies A pass rapidly up into P/B-III bajada gravels, PBS are assigned to the rising limb of the MIS 5.1 insolation/temperature/precipitation curve, slightly younger than 80 ka.     

Vegetation and climate during the penultimate interglacial of the northeastern Russian Arctic: the Lake El'gygytgyn pollen record

We present a high‐resolution reconstruction of the vegetation and climate dynamics during the penultimate interglacial, corresponding with Marine Isotope Stage (MIS) 7, based on detailed palynological analyses of lacustrine sediments from Lake El'gygytgyn, northeastern Siberia. The analysed sediments were deposited between 246 and 181 ka ago (late MIS 8 to early MIS 6.6). The interglacial vegetation was characterized by herb and shrub (mainly alder and birch) dominated plant communities. Pollen‐based biome reconstruction shows a dominance of the tundra (TUND) biome, thus indicating rather open vegetation. Warmer intervals (MIS 7.5, 7.3 and 7.1) were marked by an increase in the cold deciduous forest (CLDE) biome scores and a synchronous decrease in the cold steppe (STEP) biome scores. The thermal maximum occurred during MIS 7.1, as indicated by the highest CLDE biome scores occurring in this period, and lasted ~10 ka, possibly favoured by the high precession‐related summer insolation and the legacy of the preceding mild and dry stadial (MIS 7.2). In contrast, MIS 7.3 and 7.5 were characterized by shorter durations (~4 ka) and lower summer temperatures. The preceding cold glacial and stadial (MIS 8 and 7.4, respectively) might have led to an extensive distribution of permafrost that hindered vegetation development during the subsequent warm intervals. MIS 7.4 and 6.6 were cold and wet, probably triggered by low obliquity values and coevally low precession‐related summer insolation. As a result, these periods were marked by significantly reduced summer temperatures and an enhanced snow‐ice albedo feedback. The obtained reconstructions provide potential scenarios for future climate changes and allow a better understanding of the relationship between vegetation, climate and external/internal forcings in the high latitudes.     

Surface exposure dating reveals MIS-3 glacial maximum in the Khangai Mountains of Mongolia

This study presents results from geomorphological mapping and cosmogenic radionuclide dating (¹⁰Be) of moraine sequences at Otgon Tenger (3905 m), the highest peak in the Khangai Mountains (central Mongolia). Our findings indicate that glaciers reached their last maximum extent between 40 and 35 ka during Marine Oxygen Isotope Stage (MIS) 3. Large ice advances also occurred during MIS-2 (at ~ 23 and 17–16 ka), but these advances did not exceed the limits reached during MIS-3. The results indicate that climatic conditions during MIS-3, characterized by a cool-wet climate with a greater-than-today input from winter precipitation, generated the most favorable setting for glaciation in the study region. Yet, glacial accumulation also responded positively to the far colder and drier conditions of MIS-2, and again during the last glacial–interglacial transition when precipitation levels increased. Viewed in context of other Pleistocene glacial records from High Asia, the pattern of glaciation in central Mongolia shares some features with records from southern Central Asia and NE-Tibet (i.e. ice maxima during interstadial wet phases), while other features of the Mongolian record (i.e. major ice expansion during the MIS-2 insolation minimum) are more in tune with glacier responses known from Siberia and western Central Asia.     

Recognition of non-Milankovitch sea-level highstands at 185 and 343 thousand years ago from U–Th dating of Bahamas sediment

Thirty-one new bulk-sediment U–Th dates are presented, together with an improved δ¹⁸O stratigraphy, for ODP Site 1008A on the slopes of the Bahamas Banks. These ages supplement and extend those from previous studies and provide constraints on the timing of sea-level highstands associated with marine isotope stages (MIS) 7 and 9. Ages are screened for reliability based on their initial U and Th isotope ratios, and on the aragonite fraction of the sediment. Twelve ‘reliable’ dates for MIS 7 suggest that its start is concordant with that predicted if climate is forced by northern-hemisphere summer insolation following the theory of Milankovitch. But U–Th and δ¹⁸O data indicate the presence of an additional highstand which post-dates the expected end of MIS 7 by up to 10 ka. This event is also seen in coral reconstructions of sea-level. It suggests that sea-level is not responding in any simple way to northern-hemisphere summer insolation, and that tuned chronologies which make such an assumption are in error by ≈10 ka at this time. U–Th dates for MIS 9 also suggest a potential mismatch between the actual timing of sea-level and that predicted by simple mid-latitude northern-hemisphere forcing. Four dates are earlier than that predicted for the start of MIS 9. Although the most extreme of these dates may not be reliable (based on the low-aragonite content of the sediment) the other three appear robust and suggest that full MIS 9 interglacial conditions were established at 343 ka. This is ≈8 ka prior to the date expected if this warm period were driven by northern-hemisphere summer insolation.     

Carbon and oxygen stable isotope compositions of late Pleistocene mammal teeth from dolines of Ajoie (Northwestern Switzerland)

Fossils of megaherbivores from eight late Pleistocene ¹⁴C- and OSL-dated doline infillings of Ajoie (NW Switzerland) were discovered along the Transjurane highway in the Swiss Jura. Carbon and oxygen analyses of enamel were performed on forty-six teeth of large mammals (Equus germanicus, Mammuthus primigenius, Coelodonta antiquitatis, and Bison priscus), coming from one doline in Boncourt (~ 80 ka, marine oxygen isotope stage MIS5a) and seven in Courtedoux (51–27 ka, late MIS3), in order to reconstruct the paleoclimatic and paleoenvironmental conditions of the region. Similar enamel δ¹³C values for both periods, ranging from − 14.5 to − 9.2‰, indicate that the megaherbivores lived in a C₃ plant-dominated environment. Enamel δ¹⁸O_PO4 values range from 10.9 to 16.3‰ with a mean of 13.5 ± 1.0‰ (n = 46). Mean air temperatures (MATs) were inferred using species-specific δ¹⁸O_PO4–δ¹⁸O_H2O-calibrations for modern mammals and a present-day precipitation δ¹⁸O_H2O-MAT relation for Switzerland. Similar average MATs of 6.6 ± 3.6°C for the deposits dated to ~ 80 ka and 6.5 ± 3.3°C for those dated to the interval 51–27 ka were estimated. This suggests that these mammals in the Ajoie area lived in mild periods of the late Pleistocene with MATs only about 2.5°C lower than modern-day temperatures.     

Several distinct wet periods since 420 ka in the Namib Desert inferred from U-series dates of speleothems

The scarcity of numerical dates of the arid areas in southern Africa is a challenge for reconstructing paleoclimate. This paper presents a chronological reconstruction in the central part of the Namib Desert, Namibia, for the last 420,000 yr. It is based on ²³⁰Th/U dates (TIMS) from a large stalagmite and a thick flowstone layer in a small cave located in the hyper-arid central Namib Desert. The results provide for the first time evidence of three or possibly four succeeding wet periods of decreasing intensity since 420 ka through which speleothem deposited at approximately 420–385 ka, 230–207 ka and 120–117 ka following the 100-ka Milankovitch cycle. Speleothem growth was not recorded for the Holocene. These wet periods interrupted the predominantly dry climate of the Namib Desert and coincided with wet phases in deserts of the northern hemisphere in the Murzuq Basin, Sahara, the Negev, Israel, the Nafud Desert, Saudi Arabia, and the arid northern Oman, Arabian Peninsula.     

神农架全新世东亚季风演化及其热带辐合带控制*

文章基于湖北神农架山宝洞3支石笋的13个²³⁰Th年龄和505个氧同位素数据,建立了全新世8.45~0.46kaB.P.东亚季风降水序列,其长期演化趋势与33°N夏季太阳辐射能量变化曲线基本一致。神农架山宝洞与阿曼Qunf洞和贵州董哥洞的石笋高分辨率δ¹⁸ O记录整体相关(r 分别为0.75和0.94), 说明全新世东亚季风、印度季风系统的演化主要受控于同一驱动机制,即北半球夏季太阳辐射控制下赤道热带辐合带逐渐南移,导致亚洲季风降水持续减弱。功率谱分析表明:5ka以来山宝洞石笋记录具有显著的550a周期旋回,与树轮Δ¹⁴ C和北大西洋温盐环流周期基本一致。     

Orbital- and sub-orbital-scale climate impacts on vegetation of the western Mediterranean basin over the last 48,000 yr

High-resolution pollen analysis of Alborán Sea core MD95-2043 provides a 48-ka continuous vegetation record that can be directly correlated with sea surface and deep-water changes. The reliability of this record is supported by comparison with that of Padul (Sierra Nevada, Spain). Marine Isotope Stage (MIS) 3 was characterised by fluctuations in Quercus forest cover in response to Dansgaard-Oeschger climate variability. MIS 2 was characterised by the dominance of semi-desert vegetation. Despite overall dry and cold conditions during MIS 2, Heinrich events (HEs) 2 and 1 were distinguished from the last glacial maximum by more intensely arid conditions. Taxon-specific vegetation responses to a tripartite climatic structure within the HEs are observed. In MIS 1, the Bölling-Allerød was marked by rapid afforestation, while a re-expansion of semi-desert environments occurred during the Younger Dryas. The maximum development of mixed Quercus forest occurred between 11.7 and 5.4 cal ka BP, with forest decline since 5.4 cal ka BP. On orbital timescales, a long-term expansion of semi-desert vegetation from MIS 3 into MIS 2 reflects global ice-volume trends, while Holocene arboreal decline reflects summer insolation decrease. The influence of precession on the amplitude of forest development and vegetation composition is also detected.     

A detailed East Asian monsoon history surrounding the ‘Mystery Interval’ derived from three Chinese speleothem records

The ‘Mystery Interval’ (MI, 17.5−14.5 ka) was the first stage of the last deglaciation, a key interval for understanding mechanisms of glacial–interglacial cycles. To elucidate possible causes of the MI, here we present three high-resolution, precisely dated oxygen-isotope records of stalagmites from Qingtian and Hulu Caves in China, reflecting changes in the East Asian summer monsoon (EASM) then. Based on well-established chronologies using precise ²³⁰Th dates and annual-band counting results, the two-cave δ¹⁸O profiles of ~ 7-yr resolution match well at decadal timescales. Both of the two-cave records document an abrupt weakening (2‰ of δ¹⁸O rise within 20 yr) in the EASM at ~ 16.1 ka, coinciding with the transition of the two-phased MI reconstructed from New Mexico's Lake Estancia. Our results indicate that the maximum southward displacement of the Intertropical Convergence Zone and associated southward shift of polar jet stream may generate this two-phase feature of the MI during that time. We also discover a linear relationship among decreasing EASM intensity, rising atmospheric CO₂ and weakening Atlantic Meridional Overturning Circulation between the MI and Younger Dryas episodes, suggesting a strong coupling of atmospheric/oceanic circulations in response to the millennial-scale forcing, which in turn regulates global climate changes and carbon cycles.     

Timing of glaciation and last glacial maximum paleoclimate estimates from the Fish Lake Plateau, Utah

The High Plateaus of Utah include seven separate mountain ranges that supported glaciers during the Pleistocene. The Fish Lake Plateau, located on the eastern edge of the High Plateaus, preserves evidence of at least two glacial advances. Four cosmogenic ³He exposure ages of boulders in an older moraine range from 79 to 159 ka with a mean age of 129 ± 39 ka and oldest ages of 152 ± 3 and 159 ± 5 ka. These ages suggest deposition during the type Bull Lake glaciation and Marine Oxygen Isotope Stage (MIS) 6. Twenty boulder exposure ages from four different younger moraines indicate a local last glacial maximum (LGM) of ~ 21.1 ka, coincident with the type Pinedale glaciation and MIS 2. Reconstructed Pinedale-age glaciers from the Fish Lake Plateau have equilibrium-line altitudes ranging from 2950 to 3190 m. LGM summer temperature depressions for the Fish Lake Plateau range from −10.7 to −8.2°C, assuming no change in precipitation. Comparison of the Fish Lake summer temperature depressions to a regional dataset suggests that the Fish Lake Plateau may have had a slight increase (~ 1.5× modern) in precipitation during the LGM. A series of submerged ridges in Fish Lake were identified during a bathymetric survey and are likely Bull Lake age moraines.     

石笋初始234 U/238 U值的冰量周期特征及其环境意义 ——以湖北三宝洞为例

石笋氧同位素记录具有明显的2万年周期,其他记录中广泛存在的10万年周期是否在石笋中有所表现目前还鲜有报道。通过对湖北三宝洞20支石笋的铀同位素数据的分析研究发现,石笋初始234U/238U值在序列连续性较好的640.3~299.6 ka B.P.时间段有强烈的10万年周期特征。在间冰期和冰期时,初始234U/238U值分别呈增大和减小状态。初始234U/238U值的10万年周期与全球冰量、黄土磁化率、黄土平均粒度和大气CO₂变化有良好的对应关系。这些对应关系表明全球冰量、大气CO₂对喀斯特区地球化学元素富集和迁移作用有重要影响。石笋氧同位素的显著岁差周期独立于石笋微量元素、高纬冰量和全球温室气体变化,暗示了太阳辐射变化对中低纬水汽环流的直接影响。石笋初始234U/238U与氧同位素、太阳辐射在冰消期时的对应变化支持北半球太阳辐射能量变化对冰期-间冰期旋回的调控作用。     

Speleothem evidence of warm episodes in northeast France during Marine Oxygen Isotope Stage 3 and implications for permafrost distribution in northern Europe

U-Th ages have been obtained by TIMS on the growth periods of a stalagmite from the “Grotte des Puits de Pierre-la-Treiche” (northeastern France), during the middle part of the “Weichselian glaciation” (Marine Isotope Stage 3), between 55.36 ± 0.95 and 53.34 ± 0.49 ka and around 45.85 ± 0.49 ka. These episodes are contemporaneous with abrupt climatic variations recorded in Greenland ice cores (Greenland interstadials 12, 14 and 15) that have been previously recognized in European speleothems. They also coincide with two interstadials, known as “Goulotte” and “Pile” in the Grande Pile pollen sequence (eastern France), which have been correlated with the Moershoofd complex in the Netherlands. Such evidence of speleothem deposition related to temperate episodes gives a strong indication of the absence of continuous shallow permafrost during the middle part of MIS 3 in northeastern France.     

Solar influence and hydrological variability during the Holocene from a speleothem annual record (Molinos Cave,NE Spain)

We present a multi‐proxy approach to reconstructing Holocene climate conditions in northeastern Spain based on an excellent correlation among the lamina thickness, colour parameters and isotope (δ¹⁸O and δ¹³C) variations recorded in a speleothem. An age model constructed from five U/Th dates and annual lamina counting suggests that the uppermost 14.7 cm of the MO‐7 stalagmite grew between 7.2 and 2.5 ka before present but experienced a growth hiatus from 4.9 to 4.3 ka. Three spectral analysis methods were applied to 11 time series. The results reveal common solar periodicities on decennial (Gleissberg cycle) and centennial (De Vries‐Suess cycle) scales. The onset of Holocene carbonate precipitation in the MO‐7 stalagmite appears to be associated with a cold, wet period, whereas the hiatus and the end of growth are related to warm, dry periods. This environmental trend fits well within the regional Holocene climate.