复杂矿石中滑石的测定

含滑石复杂矿石试样经650℃焙烧,使其中绿泥石、菱镁矿等变得能迅速溶于1+1 HCl中,而滑石溶解率很低。残渣用HF-HClO_4或KOH处理,用火焰原子吸收法或滴定法测定MgO,计算滑石量。10余种共存矿物在一定范围内不干扰测定。     

白云石蛇纹石化,滑石化的热力学讨论

本文结合镁质胶凝材料方面的一些实验资料,从热力学角度讨论了MgO+SiO_2蒸发生成滑石、纤维蛇纹石;白云石的滑石化、纤维蛇纹石化和白云石与滑石间的相互转变。提出以白云石代替MgO作合成生产镁质胶凝材料更加经济。     

石阡二叠纪层状滑石矿地质特征及成因初析

二叠纪层状滑石矿在湘、川两省曾有过报道,在我省尚属首次发现。本文根据野外调查和室内分析研究,对石阡地区二叠纪滑石矿地质特征进行初步分析论述,并结合沉积环境、构造、矿石化学成份及滑石区域分布特点之间的关系,提出该类滑石矿是来自地内深部含高硅、镁(?)热水在较封闭的静水条件下沉积形成的。具有较大的资源潜力和新的找矿意义。     

保靖县卡棚黑滑石矿床地质特征

保靖县卡棚沉积型黑滑石矿床,是一种新类型的滑石矿床。钙质黑滑石矿层赋存于二叠系下统栖霞组上段,呈多层韵律出现,含矿4层,厚5.3～26.3m,含滑石14.1～44.07％,属原生贫矿。产于风化带中的黑滑石粘土,是原生矿层风化淋滤后的产物,属风化带富矿。矿石物质组分简单,主要为黑滑石、方解石、石英、蒙脱石等。矿床风化分带清楚。黑滑石被认为是同生沉积后期,海解作用产物,在风化阶段又进一步相对富集。     

Treatment of high fluoride concentration wastewater by layered double hydroxides： Mechanism studies

An appropriate concentration of fluoride in drinking water is required to prevent dental cavities, but long-term ingestion of water that contains more than a suitable level of fluoride can cause bone disease and mottling of the teeth. Fluoride ions can be found in wastewater from the fluoride chemical industry, as well as the semiconductor, metal processing, fertilizer, and glass-manufacturing industries. The discharge standard for fluoride in industrial wastewater in China is 10 mg/L. Efficient treatment of fluoride-containing wastewater is therefore of major concern in China, following the rapid development of the fluoride chemical industry. Several methods have been used to remove fluoride from water, such as adsorption, chemical precipitation, electrodialysis, ion exchange and electrochemical processes. Layered double hydroxides （LDHs） are anionic clays with high anion exchange capacities which are effective adsorbents for removal of a variety of anionic pollutants. LDHs have been studied as potential adsorbents for removing toxic anionic species such as CrO4^2-, TcO4^-, SeO3^2-, pesticides, and anionic surfactants from aqueous systems. One of the main attractions of using LDHs for fluoride removal, is that unlike other chemical treatment methods, no chemical sludge should be produced. In the present study, an attempt was made to investigate the mechanism of fluoride removal by LDHs under different conditions using batch methods. In addition, the release of fluoride adsorbed on LDHs by treatment with an aqueous solution of Na2CO3 was studied. The residual fluoride was found to be 10 mg/L in a solution with an initial concentration of 1000 mg/L, which meets the discharge standard for fluoride in industrial wastewater in China.     

中国滑石矿床的含矿建造类型

本文研究和总结了我国滑石矿床的含矿建造类型,划分出:①超基性岩含滑石建造;②变质的镁质碳酸盐岩含滑石建造;③钙镁质碳酸盐岩含滑石建造;④镁质粘土岩含滑石建造等4种滑石矿床含矿建造。阐述了不同含矿建造的主要特征以及滑石的成矿作用特点,指出了滑石成矿作用的发生与否主要与下列因素有关:①岩石条件;②物质来源;③建造类型和岩石组合类型;④介质条件;⑤构造条件诸因素控制的。     

滑石粘土提纯试验的初步进展

滑石粘土提纯试验的初步进展章人骏（地质矿产部宜昌地质矿产研究所）近一两年来笔者曾采用简易可行的方法，开展滑石粘土提纯初步试验，主要利用滑石与伴生组分的物性差别（包括密度、颗粒度、、分散性、悬浮性等方面差别）把它们区分开来。现在已获得一些进展。下面将着...     

透闪石,滑石拓扑定向反应—龙溪软玉的电子衍射研究

通过对龙溪软玉中矿物纤维所进行的电子衍射研究,发现了透闪石针状晶体中存在众多(010)多链层错,透闪石和滑石以(010)为晶界面形成连生,以及滑石晶体呈纤维状存在;探讨了透闪石退变质为滑石的反应运动学和反应动力学机制;提出了拓扑定向反应系列的理论。     

Structural Evolvement of Heating Treatment of Mg/AI-LDH and Preparation of Mineral Mesoporous Materials

Although hydrotalcite, or layered double hydroxides （LDHs）, is not a common mineral, it is an important material that can be easily synthesized in laboratory. In this study, structural evolvement and BET surface area changes of heat treated Mg/AI-LDH is evaluated by XRD, TEM and N2-BET analyses. The results indicate that the magnesium-aluminum LDH with carbonate as interlayer anion, periclase-like oxides was formed at temperatures of 400-800℃. Meanwhile, 2-3 nanometer mesoporous were formed during decomposition of LDH. However, the heat treated samples still preserve the morphology of the original LDH plates. Periclase-like formed from LDH heat treatment may re-hydrolyze and recover the structure of LDH. However, crystallinity of the recovered LDH is lower than that of the original LDH. This heat treatment will result in formation of （Mg, Al）-oxide nano-crystals and nanopores among the nano-crystals. When heating temperature exceeds 1000, the periclase-like （Mg, Al）-oxide is transformed into a composite with periclase （MgO） and spinel phases. The periclase can be re-hydrolyzed and dissolved in HCl solution. After acid treatment, the sample with a high surface area is composed of spinel nano-crystals and nanopores among them. Our results will provide a new and economic way to synthesize mesoporous materials through pathways of phase transformation of precursor materials with different composition.     

湖南滑石矿床类型的划分及找矿方向

湖南滑石矿床类型可分为变质型、沉积风化残余型、中低温热液交代型三类。变质型又可分为区域动力变质和接触变质交代两个亚型。据湖南滑石矿床分布特点、成矿地质条件,全省滑石矿可划为四个成矿带、九个远景区,作为今后滑石找矿方向。     

医药矿产研究应用与发展

一、医药矿产的概念 根据天然矿产在中医药学临床应用中的功效,我们将那些在制作中成药或中药方剂中能作为药材入药,治疗和预防各种疾病,促进人体生长发育,使人健康长寿的天然矿物、岩石、化石等称为医药矿产。