Characterization and adsorption of disperse dyes from wastewater onto cenospheres activated carbon composites

In the present research, coal fly ash, a waste by-product of thermal power plant, has been segregated to obtain hollow and spherical cenospheres which combined with activated carbon in different ratio for effectual remediation of wastewater. Fabricated cenospheres activated carbon (CNAC) composites were characterized by ATR-FTIR, SEM, XRD, BET and CILAS for functionality, surface modification, crystallinity, surface area, pore volume, pore size and particle size analysis, respectively. Batch adsorption has been applied to appraised maximum removal of Disperse Orange 25 (DO) and Disperse Blue 79:1 (DB) dyes at varying solution pH 2 to 12, adsorbent dose 0.1 g cenospheres + 0.1 g AC to 1.0 g cenospheres + 1.0 g AC, dye concentration 10 to 100 mg/L, agitation speed 80 to 240 rpm and contact time 5 to 300 min at three different temperatures (25, 35 and 45 °C). The maximum percentage removal was found to be 79 and 76% for DO and DB dyes, respectively, at optimized condition. Langmuir isotherm showed good interaction with adsorption data, and the obtained maximum equilibrium adsorption capacity was found to be 90.91 mg/g for DO and 83.33 mg/g for DB at 45 °C. Eventually, the negative ?G° (? 7.513 for DO and ? 7.767 for DB) has suggested the feasibility of dyes adsorption on CNAC composites.     

A surface complexation model for cadmium and lead adsorption onto diatom surface

This work is devoted to the physico-chemical study of cadmium and lead interaction with diatom–water interfaces for two marine planktonic (Thalassiosira weissflogii = TW, Skeletonema costatum = SC) and two freshwater periphytic species (Achnanthidium minutissimum = AMIN, Navicula minima = NMIN) by combining adsorption measurements with surface complexation modeling. Reversible adsorption experiments were performed at 20 °C after 3 h of exposure as a function of pH, metal concentration in solution, and ionic strength. While the shape of pH-dependent adsorption edge is similar among all four diatom species, the constant-pH adsorption isotherm and maximal binding capacities differ. These observations allowed us to construct a surface complexation model for cadmium and lead binding by diatom surfaces that postulates the constant capacitance of the electric double layer and considers Cd and Pb complexation with mainly carboxylic and, partially, silanol groups. Parameters of this model are in agreement with previous acid–base titration results and allow quantitative reproduction of all adsorption experiments.     

Effects of coal storage in air on physical and chemical properties of coal and on gas adsorption

This paper investigates changes in the high-volatile bituminous Lower Block Coal Member from Indiana owing to moisture availability and oxidation in air at ambient pressure and temperature over storage time. Specifically, it investigates changes in chemistry, in surface area, and pore structure, as well as changes in methane and carbon dioxide adsorption capacities. Our results document that the methane adsorption capacity increased by 40%, whereas CO₂ adsorption capacity increased by 18% during a 13-month time period. These changes in adsorption are accompanied by changes in chemistry and surface area of the coal.The observed changes in adsorption capacity indicate that special care must be taken when collecting samples and preserving coals until adsorption characteristics are measured in the laboratory. High-pressure isotherms from partially dried coal samples would likely cause overestimation of gas adsorption capacities, lead to a miscalculation of coal-bed methane prospects, and provide deceptively optimistic prognoses for recovery of coal-bed methane or capture of anthropogenic CO₂.     

三维配管软件在储运设计中的应用

以宁波瑞福特气体储运有限公司20,000m3低温乙烯终端和配套公用工程项目的设计为例,介绍了PDSOFT三维配管软件在石油化工储运中的应用。通过项目对该软件的使用过程进行较深入的描述分析、同时对该软件在石油化工储运设计中应用前景和应注意的问题进行了说明。     

Adsorption isotherms, kinetics and mechanism for the adsorption of cationic and anionic dyes onto carbonaceous particles prepared from Juglans regia shell biomass

In the present study, Juglans regia shells were used to prepare activated carbon by acid treatment method. J. regia shell-based activated carbon was used for the adsorption of two synthetic dyes namely, a basic dye malachite green and an acid dye amido black 10B. The prepared adsorbent was crushed and sieved to three different mesh sizes 100, 600 and 1,000 μm. The adsorbent was characterized by scanning electron microscopy, surface acidity and zero-point charge. Batch experiments were carried out by varying the parameters like initial aqueous phase pH, adsorbent dosage and initial dye concentration. The equilibrium data were tested with Langmuir, Freundlich, Redlich–Peterson and Sips isotherm at three different temperatures 293, 300 and 313 K and it was found that the Freundlich isotherm best fitted the adsorption of both the dyes. Kinetic data were tested with pseudo first-order model and pseudo second-order model. The mechanism for the adsorption of both the dyes onto the adsorbent was studied by fitting the kinetic data with intraparticle diffusion model and Boyd plot. External mass transfer was found to be the rate-determining step. Based on the ionic nature of the adsorbates, the extent of film diffusion and intraparticle diffusion varied; both being system specific. Thermodynamic parameters were also calculated. Finally, the process parameters of each adsorption system were compared to develop the understanding of the best suitable system.     

粘土对地下水中U（VI）的吸附作用及其污染控制研究

进行了U（VI）在粘土上吸附的批实验，其中，粘土样采自我国南方某大型铀尾矿库库底。实验结果表明U（VI）在粘土上的吸附与浸泡液的pH值呈强烈的非线性关系，在pH值近中性时，U（VI）在粘土上的吸附达到了一个最大值，而在偏酸性或偏碱性条件下，U（VI）在粘土上的吸附迅速减少；运用表面络合理论建立了U（VI）在粘土上吸附的表面络合模型（DLM），该模型很好地拟合了实验数据。模型检验表明，它可以精确预测U（VI）在不同热力学条件下的吸附行为；此外，模拟结果表明，U（VI）的粘土上吸附在酸性条件下受固液比（M／V）影响明显，而在碱性条件下主要受浸泡液中HCO3^-和CO3^2-的控制。     

Influence of hydroxybenzoic acids on the adsorption of Eu(III) onto α,γ-Al2O3 particles in mildly acidic conditions: A macroscopic and spectroscopic study

The influence of hydroxybenzoic acids (HAH_n), namely p-hydroxybenzoic acid (4-hydroxybenzoic acid, HPhbH) and protocatechuic acid (3,4-dihydroxybenzoic acid, HProtoH₂), on the adsorption of europium(III) onto α,γ-Al₂O₃ particles is studied as a function of acid concentration. After measuring the adsorption edge of the Eu(III)/α,γ-Al₂O₃ binary system, and using the previously studied binary component system Eu(III)/HAH_n—Moreau et al. (2015) Inorg. Chim. Acta 432, 81—, and HAH_n/α,γ-Al₂O₃—Moreau et al. (2013) Colloids Surf. A 435, 97—, it is evidenced that HPhbH does not enhance Eu(III) adsorption onto α,γ-Al₂O₃ in the Eu(III)/HPhbH/α,γ-Al₂O₃ ternary system. Conversely, HProtoH₂ enhances Eu(III) adsorption onto α,γ-Al₂O₃ in the Eu(III)/HProtoH₂/α,γ-Al₂O₃ ternary system. Adsorption of the acids are also found higher in the Eu(III)/acid/α,γ-Al₂O₃ ternary systems as compared with the corresponding binary systems assessing synergetic effects. For high HPhbH concentrations, a ternary surface species involving ≡AlOH surface sites, Eu(III), and PhbH^– is evidenced by time-resolved luminescence spectroscopy (TRLS). However, in the Eu(III)/HProtoH₂/α,γ-Al₂O₃ ternary system, chemical environment of Eu(III) is found to be very close to that in the Eu(III)/HProtoH₂ binary system. Ternary surface species could not be evidenced in the Eu(III)/HProtoH₂/α,γ-Al₂O₃ ternary system with TRLS because of the very short decay time of Eu(III) in the presence of protocatechuic acid.     

Serviceability limit state design for uplift of helical anchors in clay

Presently, no displacement-based design methodology exists for helical anchors subjected to tensile or uplift loading. This study investigates the statistical and probabilistic aspects of the load-displacement uncertainty associated with a database of thirty-seven uplift loading tests of helical anchors founded within cohesive soils. Initially, an ultimate resistance model is identified, and the semi-empirical uplift breakout factor statistically characterized. A relationship between ultimate resistance and slope tangent capacity is established, and used to form the basis for normalizing the load-displacement response. Hyperbolic and power law models are statistically evaluated for use in serving as a reference load-displacement model; the hyperbolic curve was selected based on goodness-of-fit statistics. Monte Carlo reliability simulations are used to establish an equivalent-deterministic load factor that associates the selected load factor with a probability of exceeding a pre-determined allowable uplift displacement, given uncertainty in the undrained shear strength, ultimate resistance model, transformation uncertainty, uncertainty in the allowable displacement, and variability in uplift loading. A practical example is provided to show the intended use of this probabilistic helical anchor displacement model.     

Development of partial factor design method on bearing capacity of pile foundations for Japanese Specifications for Highway Bridges

ABSTRACT

This paper shows the development of a partial factor design method on the bearing capacity of pile foundations for Japanese Specifications for Highway Bridges. Firstly, estimation design equations on the bearing capacities of pile foundations are improved by analysis of pile load test results and uncertainties in the bearing capacities are evaluated. Secondly, the reliabilities of pile foundations designed by the former specifications are evaluated based on reliability analysis considering the uncertainties in the bearing capacities and coefficients of subgrade reaction. Finally, a partial factor design method is developed based on the target reliability index obtained based on the conventional pile installation method by the pile installation methods. The factors are different for each pile installation method.     

原位载荷试验在优化土质地基基础设计中的作用

城市土质地基越来越多,但对土质地基承载力的正确认识还不够,合理地利用土质地基既安全又经济。通过几个建筑工程设计变更实例,强调了原位承载力试验的必要性,论述了土质地基承载力特征值取值合理性问题,分析了目前在对土质地基勘察设计中存在的问题。     

辽阳市某化工公司工程地质勘察与基础设计探讨

本文以某化工公司工程地质勘察与基础设计为例,阐述了该工程的岩土工程地质勘察、测试工作及数据处理,并对地基承载力进行计算,最终对地基基础做出科学设计,为工程建设的合理规划设计、施工提供可靠的地质科学依据,为相关工程设计积累经验。     

多分量重力梯度数据联合欧拉反褶积与软件系统设计

和传统欧拉反褶积相比,重力梯度数据联合欧拉反褶积具有更高的计算精度和反演分辨率。为了消除计算产生的发散解,在应用中须使用不同的筛选方法,使得计算流程变得相对繁琐。可见提供有效的筛选方法与开发一个易用的可视化软件有利于提高该方法的准确性、便捷性和使用效果。因此,本文提出基于相关系数边界识别约束的重力梯度数据联合欧拉反褶积,并依据界面直观、功能实用、代码简洁的设计原则,针对算法流程与功能需求,利用Python语言及其函数库设计了一种支持数据/文件管理、二/三维可视化、边界识别、重力梯度数据联合欧拉反褶积等功能的软件系统。通过理论模型与实测数据试验,验证了计算的准确性和软件的实用性,设计的软件系统能够提高应用效果。     

Digital model of corrected accumulated flow for peak discharge data acquisition and drainage system design

The design of a drainage system for a roofing slate quarry was implemented by the enhancement of discharge peak estimation, and the uncertainty inevitably associated with the engineering model was reduced.

The development of a topographical, geological, and vegetation cover database developed from a Geographical Information System (GIS) allowed for the definition of the drainage network for a hydraulic system, along with the calculation of the runoff coefficient. This is applied to the digital model of accumulated flow (DMF) as a weight correction coefficient, using a matrix-based model at 5×5 m resolution. The new digital model of corrected accumulated flow (DMCF) is the result of combining the thematic maps with the map of slope <3%, which was previously created from the slope model. It is demonstrated that this new model allows to apply the “Rational Method” on cartographic units defined by the GIS.

The DMCF is compared with other traditional applications of the Rational Method based on the calculation of the discharge peak considering: (1) the drainage basin as a single watershed or (2) defining an average runoff coefficient in each sub-watershed. Both approaches have bigger discharge peaks than those obtained by the DMCF since the slope, lithology, and vegetation cover have average values, and the runoff coefficient is poorly defined, increasing the uncertainty in the discharge peak.     

Arsenate and arsenite adsorption onto Al-containing ferrihydrites. Implications for arsenic immobilization after neutralization of acid mine drainage

Natural ferrihydrites (Fh) often contain impurities such as aluminum, especially in acid mine drainage, and these impurities can potentially impact the chemical reactivity of Fh with respect to metal (loid) adsorption. In the present study, we have investigated the influence of aluminum on the sorption properties of ferrihydrite with respect to environmentally relevant aqueous arsenic species, arsenite and arsenate. We have conducted sorption experiments by reacting aqueous As(III) and As(V) with synthetic Al-free and Al-bearing ferrihydrite at pH 6.5. Our results reveal that, when increasing the Al:Fe molar ratio in Fh, the sorption density dramatically decreased for As(III), whereas it increased for As(V). Extended X-ray Absorption Fine Structure (EXAFS) spectroscopy analysis at the As K-edge indicated that the As^IIIO₃ pyramid binds to FeO₆ octahedra on both Al-free Fh and Al-bearing Fh, by forming bidentate mononuclear edge-sharing (²E) and bidentate binuclear corner-sharing (²C) surface complexes characterized by As–Fe distances of 2.9 Å and 3.4 Å, respectively. The decrease in As(III) sorption density with increasing Al:Fe ratio in Fh could thus be explained by a low affinity of the As(OH)₃ molecule for Al surface sites compared to Fe ones. In contrast, on the basis of available literature on As(V) adsorption mechanisms, we suggest that, in addition to inner-sphere ²C arsenate surface complexes, outer-sphere arsenate surface complexes forming hydrogen bonds with both Al–OH and Fe–OH surface sites could explain the enhancement of As(V) sorption onto aluminous Fh relative to Al-free Fh, as observed in the present study. The presence of aluminum in Fh may thus enhance the mobility of arsenite with respect to arsenate in Acid Mine Drainage impacted systems, while mixed Al:Fe systems could present an alternative for arsenic removal from impacted waters, provided that As(III) would be oxidized to As(V).     

齐齐哈尔碾子山麦饭石物化性能及其对Pb2+、Cd2+、Cr3+的吸附行为研究

以齐齐哈尔碾子山麦饭石为研究对象,通过比表面积及孔隙分析、阳离子交换容量(CEC)测试以及p H值缓冲能力测试等,对碾子山区麦饭石的结构和性能进行表征,并进一步研究麦饭石对Pb~(2+)、Cd~(2+)、Cr~(3+)的吸附行为。结果显示:碾子山区麦饭石具有海绵体大孔结构,阳离子交换容量(CEC)13~20 mmol/100 g。碾子山麦饭石对酸碱溶液都具有较好的调节能力,尤其对酸液的调节更高效。重金属吸附性能方面,对Pb~(2+)、Cd~(2+)、Cr~(3+)这3种离子吸附关系为:Pb~(2+)Cr~(3+)Cd~(2+)。     

Application of an optimum design technique for determining the coefficient of consolidation by using piezocone test data

For normally consolidated clay, several researchers have developed a number of theoretical time factors to determine the coefficient of consolidation from piezocone test results. However, depending on assumptions and analytical techniques, it could vary considerably, even for a specific degree of consolidation. In this paper a method is proposed to determine a consistent coefficient of consolidation by applying the concept of an optimum design technique over all ranges of the degree of consolidation. Initial excess pore pressure distribution is assumed to be capable of being obtained by the successive spherical cavity expansion theory. The dissipation of pore pressure is simulated by means of a two-dimensional linear-uncoupled axi-symmetric consolidation analysis. The minimization of differences between measured and predicted excess pore pressure was carried out by the BFGS unconstrained optimum design algorithm with a one-dimensional golden section search technique. By analyzing numerical examples and in-situ test results, it was found that the adopted optimum design technique gives consistent and convergent results.     

地质环境问题的地质指标体系框架及其构建方法

面对复杂、多变、脆弱的地质环境和不断加剧的人类工程经济活动,急需建立面向多种地质环境问题的地质指 标体系。针对中国地质环境工作现状,借鉴国际地质指标工作组最新的成果和经验,对地质指标的定义、内涵进行了 修订和拓展,创建了包括调查指标体系（影响指标、状态指标、后果指标）和监测指标体系（压力指标、状态指标、 响应指标）的地质指标体系框架,并建立了从面向单一地质环境问题的地质指标体系的构建思路、实际范例,到面向 一个国家或地区的地质指标体系的构建步骤,为地质指标的创建、完善和应用指明了方向。     

基于Web的金刚石钻头模具钢体设计

介绍了应用网页技术进行金刚石钻头模具钢体设计计算的方法。该方法丰富了模具钢体设计的远程教育,免去了传统人工求解的繁杂过程,界面友好,精度高,结果可靠,具有实际使用价值。      

径流资料匮乏区域中小河流纳污能力计算耦合模型

径流资料匮乏的中小河流纳污能力计算问题，可通过常规的技术处理方法得到解决，但较为烦琐。针对区域中小河流特性和水文学原理，构建设计流量计算模型，并与改进的水质模型耦合，获得简易的径流一纳污能力计算耦合模型。经分析验证，该耦合模型的计算误差不大于设计流量计算的导入误差，可用于匮乏径流资料区域的中小河流纳污能力计算。