Migration of Strontium,Calcium, Fluorine,and Boron in the Caucasian Coastal Area of the Black Sea

The distribution of dissolved Sr, Ca, F, and B in the mouths of small streams and the coastal areas of Golubaya and Gelendzhic bays is studied.     

Strontium isotope identification of water mixing and recharge sources in a river system (Oder River,central Europe): A quantitative approach

This study uses Sr isotope composition (⁸⁷Sr/⁸⁶Sr) and Sr content of waters of the Oder, one of the largest rivers in central Europe, to fingerprint natural and anthropogenic contributions to its Sr budget and to evaluate water mixing processes in its hydrological system. It also demonstrates a simple method of quantifying natural and anthropogenic Sr inputs in the watershed. The method has potential for environmental and archaeological research because past Sr geochemistry of river water can easily be reconstructed. For the first time, a catchment‐scale impact of anthropogenic sources on the Sr budget of a middle‐size river is shown in a quantitative way. The water of the Oder is characterized by a relatively uniform Sr isotope composition, from 0.7100 to 0.7108, contrasting with strong variations in Sr concentration, from 0.25 to 1.27 mg/L. There is a general seasonal trend in variability, with waters becoming more radiogenic and dilute with respect to the Sr in the spring time. This Sr systematics differs significantly from the Sr budgets of the majority of the Oder tributaries that exhibit more radiogenic composition and systematically lower Sr concentrations. A mixing scenario in the Oder involves Sr contribution from four principal water sources: (a) shallow ground waters with Sr derived from near‐surface weathering of silicates, (b) moderately radiogenic mine waters from the Upper Silesian Coal Basin, (c) unradiogenic mine waters from the Permian sequence of the copper district, and (d) unradiogenic ground waters from shallow‐seated Palaeogene, Neogene, and Mesozoic aquifers. The Sr budget of the Oder is primarily controlled by inputs of dissolved Sr from anthropogenic sources, which overprint the natural background, controlled by geology. Thus, about 47.5% of Sr originates from agriculture, industrial, and municipal additions, 31.5% from mine water inputs, and only 21% from natural sources, that is, rock weathering and atmospheric precipitation. Reconstruction of the past Sr chemistry of the Oder reveals that its present‐day Sr isotope composition is temporary and significantly different from that of the preindustrial times.     

Evaluation of groundwater hydrochemical characteristics and mixing behavior in the Daying and Qicun geothermal systems,Xinzhou Basin

This paper examines groundwater hydrochemical characteristics during mixing between thermal and non-thermal groundwater in low-to-medium temperature geothermal fields. A case study is made of Daying and Qicun geothermal fields in the Xinzhou basin of Shanxi province, China. The two geothermal fields have similar flow patterns, with recharge sourced from precipitation in mountain areas heated through a deep cycle, before flowing into overlying Quaternary porous aquifers via fractures. Hydrochemical features of 60 ground- and surface water samples were examined in the context of hydrogeologic information. The average temperatures of the deep geothermal reservoirs are estimated to be 125 °C in Daying field, and 159 °C in Qicun field, based on Na–K–Mg geothermometry, while slightly lower estimates are obtained using silica geothermometers. Hydrochemical features of thermal water are distinct from cold water. Thermal groundwater is mainly Cl·SO₄–Na type, with high TDS, while non-thermal groundwater is mostly HCO₃–Ca·Mg and HCO₃–Ca type in the Daying and Qicun regions, respectively. Hydrogeochemical processes are characterized by analyzing ion ratios in various waters. Higher contents of some minor elements in thermal waters, such as F, Si, B and Sr, are probably derived from extended water–rock interaction, and these elements can be regarded as indicators of flow paths and residence times. Mixing ratios between cold and thermal waters were estimated with Cl, Na, and B concentrations, using a mass balance approach. Mixing between ascending thermal waters and overlying cold waters is extensive. The proportion of water in the Quaternary aquifer derived from a deep thermal source is lower in Daying geothermal field than in Qicun field (5.3–7.3% vs. 6.3–49.3%). Mixing between thermal and non-thermal groundwater has been accelerated by groundwater exploitation practices and is enhanced near faults. Shallow groundwater composition has also been affected by irrigation with low-temperature thermal water.     

87Sr/86Sr ratios in hydrothermal waters and deposits from the East Pacific Rise at 21°N

⁸⁷Sr/⁸⁶Sr ratios of three hydrothermal waters collected on the East Pacific Rise at 21°N define a mixing line between seawater and a hydrothermal end-member at 0.7030 which is derived by seawater-basalt interaction at ca. 350°C and water/rock ratio of about 1.5. Sr concentrations are not affected in the process while Mg uptake from seawater is almost complete. Up to2/3 of this hydrothermal component is involved in anhydrite precipitation while the Sr isotopic ratio in sulfides (chalcopyrite + sphalerite) cannot be distinguished from that of sulfate. It is estimated that ca. 1 × 10¹⁰ moles of strontium are yearly cycled in the hydrothermal systems of mid-oceanic ridges, thereby affecting the⁸⁷Sr/⁸⁶Sr budget of seawater. Mass balance between river runoff, limestone precipitation and ridge basalt alteration suggests that the⁸⁷Sr/⁸⁶Sr ratios of the river runoff are in the range 0.7097–0.7113, and are largely dominated by limestone alteration.     

The Effect of a Thermal Power Station on the Concentrations of Metals and Silicon in the Water of a Small Siberian River

Studying of the distribution of elements in the Beresh River water showed the concentrations of elements to decrease according to the series Ca > Na > Mg > Si > K > Sr > Fe > Al and the river water self-purification capacity for these elements to be inadequate. Concentrations of elements dramatically increase in the river reach near the Thermal Power Station (GRES) and next increase even greater in the lower reach of the river before its emptying into the Uryup River. It is shown that the seasonal variations, typical of the river upper and middle reaches and determining the high level of anthropogenic impact of the fuel and energy complex facilities onto the river, even out in the lower reaches of the river. Specific features of seasonal and spatial variations in the element concentrations for the 8 years of observations are discussed.     

Formation waters discharge to rivers near oil sands projects

Groundwater discharges in the western Canadian oil sands region impact river water quality. Mapping groundwater discharges to rivers in the oil sands region is important to target water quality monitoring efforts and to ensure injected wastewater and steam remain sequestered rather than eventually resurfacing. Saline springs composed of Pleistocene‐aged glacial meltwater exist in the region, but their spatial distribution has not been mapped comprehensively. Here we show that formation waters discharge into 3 major rivers as they flow through the Athabasca Oil Sands Region adjacent to many active oil sands projects. These discharges increase river chloride concentrations from river headwaters to downstream reaches by factors of ~23 in the Christina River, ~4 in the Clearwater River, and ~5 in the Athabasca River. Our survey provides further evidence for the substantial impact of formation water discharges on river water quality, even though they comprise less than ~2% of total streamflow. Geochemical evidence supporting formation water discharges as the leading control on river salinity include increases in river chloride concentrations, Na/(Na + Ca) ratios, Cl/(Cl + SO₄) ratios and decreases in ⁸⁷Sr/⁸⁶Sr ratios; each mixing trend is consistent with saline groundwater discharges sourced from Cretaceous or Devonian aquifers. These regional subsurface‐to‐surface connections signify that injected wastewater or steam may potentially resurface in the future, emphasizing the critical importance of mapping groundwater flow paths to understand present‐day streamflow quality and to predict the potential for injected fluids to resurface.     

Characteristics and environmental significance of Ca, Mg, and Sr in the soil infiltrating water overlying the Furong Cave, Chongqing, China

This paper explores the influence of the local meteoric conditions,the overlying soil on the concentrations of Ca,Mg,and Sr,and the ratios of Mg/Ca,Sr/Ca,and Mg/Sr in soil infiltrating water(SIW).An in situ monitoring program was carried out above the Furong Cave throughout 2010 to collect data on SIW,monthly temperature and rainfall,and the geochemical composition and granularity of soils.The discharge of SIW responded quickly to the local rainfall,and its residence time was the primary factor affecting the Ca,Mg,and Sr content of the SIW.The high concentrations of Ca,Mg,and Sr in the SIW during April should be attributed primarily to the prolonged residence of SIW in the soil during the local dry seasons of winter and early spring.The maximum Mg/Sr ratio also occurred in April.The ratio of Mg/Ca in SIW is positively correlated with prolonged residence time and with high temperatures,which do not strongly affect the ratio of Sr/Ca.The Mg/Ca ratio was lowest when the Sr/Ca ratio was highest because plant metabolism increased the absorption of Ca and Mg,but not Sr,and also because higher temperatures enhanced the dissolution of Mg more than that of Sr.These different responses of Mg and Sr to temperature increases resulted in high Mg/Sr ratios during July and August.     

Weathering,Sr fluxes,and controls on water chemistry in the Lake Qinghai catchment,NE Tibetan Plateau

Strontium (Sr) concentrations and isotopic ratios have been measured in a series of water and rock samples from most of the major tributaries of the Lake Qinghai basin on the north‐eastern Tibetan Plateau. Dissolved Sr and ⁸⁷Sr/⁸⁶Sr show ranges of 488–12 240 nmol/l and 0·710497–0·716977, respectively. These data, together with measurements of major cations and anions in rivers and their tributaries and various lithologies of the catchment, were used to determine the contributions of Sr and its isotopic expense to rivers and lakes. Our results demonstrate that the chemical components and ⁸⁷Sr/⁸⁶Sr ratios of the alkaline waters are derived from mixing of carbonate and silicate sources, with the former contributing 72 ± 18% dissolved Sr to rivers. The difference in tributary compositions stems from the lithology of different river systems and low weathering intensity under a semi‐arid condition. Variation in ⁸⁷Sr/⁸⁶Sr ratios places constraint on the Sr‐isotopic compositions of the main tributaries surrounding Lake Qinghai. The water chemistry of the Buha River, the largest river within the catchment underlain by the late Paleozoic marine limestone and sandstones, dominates Sr isotopic composition of the lake water, being buffered by the waters from the other rivers and probably by groundwater. However, the characteristic chemical composition of the lake itself differs remarkably from the rivers, which can be attributed to precipitation of authigenic carbonates (low‐magnesium calcite, aragonite, and dolomite), though this does not impact the Sr isotope signature, which may remain a faithful indicator in paleo‐records. Regarding the potential role of groundwater input within the Lake Qinghai systems in the water budget and water chemistry, we have also determined the Sr concentration and ⁸⁷Sr/^S6Sr ratio of groundwater from diverse environments. This has allowed us to further constrain the Sr isotope systematic of this source. A steady‐state calculation gives an estimate for the groundwater flux of 0·19 ± 0·03 × 10⁸ m³/yr, accounting for about 8% of contemporary lake Sr budget. Copyright © 2010 John Wiley & Sons, Ltd.     

Multiple-indicator study of the response of groundwater recharge sources to highly turbid river water after a landslide in the Tedori River alluvial fan,Japan

The large volume of groundwater stored in the Tedori River alluvial fan, Ishikawa Prefecture, Japan, is an important source of local drinking and industrial water. The Tedori River was observed to be highly turbid from the beginning of May 2015 to at least November 2017 due to a landslide in the upper reach of the river. After the landslide, the groundwater level was drawn down by several to 10 m near the middle river section during paddy irrigation periods in 2015 and 2016. This study addresses the impacts of the highly turbid water on groundwater recharge from the river and paddy fields. In 2016, we sampled groundwater, river water, paddy irrigation water, paddy ponding water, and precipitation five times at 2-month intervals. We analysed the H, O, and Sr stable isotopic compositions and major dissolved ion (and Sr) concentrations and compared our data to previous data obtained in June 2011. Ca, Sr, Cl, SO₄, and TN concentrations and δ¹⁸O values were higher in June 2016 than in June 2011; these increases were more extreme along the left bank of the Tedori River than along the right bank. We explored the mixing of Tedori River water with groundwater using a two-endmember mixing model based on their Sr concentrations and isotopic compositions. Compared to June 2011, mixing ratios were decreased near the Tedori River in 2016, and larger decreases were observed along the left bank and in the middle stream area. These results confirm that the contribution to groundwater recharge from the river decreased during the turbidity event, particularly along the left bank.     

Specific Features of Manganese Distribution in Natural Waters of Transbaikalia

Absract The manganese content of the surface (river, lake) and subsurface waters of Transbaikalia is determined. The geographical peculiarities of manganese distribution in natural waters are found to be due to different Mn concentrations in drained rocks and soils, as well as to the geochemical redox conditions of migration. The areas with low, medium, and high concentrations of Mn in natural waters and the sources of water in which Mn concentrations exceed MAC are revealed. __________ Translated from Vodnye Resursy, Vol. 32, No. 5, 2005, pp. 597–600. Original Russian Text Copyright ? 2005 by Kashin, Ivanov.     

Contamination status and spatial distribution of organochlorine compounds in fishes from Nansei Islands, Japan

Two species of fishes (n=52; tilapia and mullet) from industrialized and urbanized areas of Okinawa Island (Manko-Noha river, Hija river and Shikaza river) and from a remote area of Ishigaki Island (Anparu mudflat), Japan were collected between August 2005 and July 2006, and analyzed for five organochlorine compounds (OCs), viz., DDTs, PCBs, CHLs, HCHs and HCB. Concentrations and the contamination patterns of OCs in fishes varied between locations. Considerable residue levels of OCs, especially CHLs and DDTs were found in both fishes from the main Okinawa Island. These levels were relatively higher than the reported values for seafood from Japanese coasts, indicating that even now pollution sources of these contaminants still exist in this region. On the other hand, lower concentrations of OCs were detected in fishes from Ishigaki Island waters than those of other Japanese coastal waters, suggesting that this region is less contaminated by OC contaminants.     

Distribution Study of U,V, Mo,and Zr in Different Sites of Lakes Van and Hazar,River and Seawater Samples by ICP‐MS

The aim of this study is to investigate the concentrations of U, Th, V, Mo, and Zr in natural waters taken from Turkey. Among these water species, Lake Van is the largest soda lake and the fourth largest closed basin on Earth. The water samples were collected from 51 locations between 2008 and 2009. The inductively coupled plasma‐MS was used for determinations. The obtained U and Zr concentrations are in the range of 37–110 µg L^?1 and 17–78 µg L^?1 in Lake Van and 0.53–0.81 µg L^?1 and 0.15–0.19 µg L^?1 in Lake Hazar, respectively. The concentration of uranium in other studied waters varies from the lowest 0.09 µg L^?1 in Tigris (Dicle) river to the highest 4.0 µg L^?1 in Mediterranean Sea water. Mean Mo and V concentrations in the studied water samples were found to be in ranges of 0.1–17 and 2.7–113 µg L^?1, respectively. The obtained highest U concentration in Lake Van correlates with the highest Mo and Zr levels compared to the Lake Hazar and river waters. These results imply that there is a young occurrence of uranium minerals around Lake Van. It is concluded that there is about 50.000 ton of uranium in Lake Van water.     

Biogeochemical control on the temporal variability of trace element concentrations in the Oubangui river (Central African Republic)

Dissolved Ba, Cd, Co, Mn, Mo, Ni, Rb, Sb, Sr, U and V were measured in the Oubangui river (Central African Republic) during a complete flood period. The dissolved concentrations vary by factors ranging from 1.4 to 8.2 as a function of river discharge: Sr, Ba, Rb and Mo concentrations decrease with rising stage; Ni, U, Sb, Cd, V and Mn concentrations increase with rising stage. These distributions are explained by a mixing of quick flow, mostly surface runoff with delayed flow, mostly groundwater. The dual origin of stream waters is demonstrated by the major element ratios, which are close to a silicate end-member during the high-flow period and trend towards a carbonate end-member during the low-flow period. Moreover, geological heterogeneities in the Oubangui basin may play a role in the variation of concentrations observed at the basin outlet. The previously indicated presence of a subsurface carbonate sequence in the lower part of the basin is confirmed. Cd, V, Mn and Co show peak concentrations during decreasing stage. We suggest that biological processes such as release from phytoplanktonic material and dissolution of oxides or carbonate phases may explain this maximum.     

用氚讨论中国西部新疆干旱区的水循环率

Tritium concentrations are used to trace water circulation in the Urumqi and Turfan basins in the Xinjiang, western China. Tritium analyses were made for 77 water samples of river waters, groundwaters, spring waters, lake waters and glacier ice collected in summers in 1992 and 1994. The tritium concentrations in the waters are in a wide range from 0 to 125 TU, most of which are considerably high compared with those of most waters in Japan, because tritium levels in precipitation in the area are over ten times as high as those in Japan. River waters originating in glacier regions contain melt glacier, the proportion of which is over 0.5 to river water. The mean resi-dence time of circulating meteoric water in the mountain regions is estimated to be about 15 years. Most groundwaters and spring waters in the flat regions are mainly derived from river waters originating in glacier regions. The groundwater of greatest tritium concentrations in wells in Urumqi City is derived from Urumqi River about 25 years ago. It takes several ten years for river water to pass the underground to many springs. Some groundwaters and spring waters have taken a long time more than 40 years to travel under the ground. Enrichment of tritium in lake water by evaporation is considered to estimate the contribution of groundwater flow to the recharge of lake. Various contributions of groundwater to lakes are inferred for the various type of salinity in closed or semi-closed lakes. The inflow rates of groundwater to salt lakes are small as against fresh water lakes.     

Migration of dissolved matter at Serebryanka R. Mouth,the basin of the Sea of Japan (Sikhote Alin Reserve)

Ions of major salt composition and dissolved forms of some microelements (F, B, Sr, Rb, Cs, V, As, Mo, U) at the mouth of the Serebryanka R. (Sikhote Alin Reserve) are shown to feature conservative behavior in July 2009. The distribution of dissolved mineral phosphorus is shown to be controlled mostly by chemical processes (desorption from river suspension), even during vegetation period, while the role of biological consumption is secondary. The behavior of dissolved organic phosphorus and silicon is nearly conservative. A considerable amount of barium (up to 46% of its concentration in river water) is shown to be removed from solution, maybe because of its sorption on particulate matter of continental runoff. Ittrium and rare-earth elements (La, Ce, Pr, Nd, Dy, Ho) show an abrupt decrease in the concentrations of their dissolved forms at the initial stages of river water penetration into the sea. This decrease is supposedly due to coagulation and flocculation of organic and organic-mineral colloids.     

Groundwater dating with 3H and SF6 in relation to mixing patterns,transport modelling and hydrochemistry

A comprehensive study of a sandy aquifer of deltaic origin in southern Poland included water chemistry, isotopes, dissolved trace gases and transport modelling. Tritium, sulphur hexafluoride (SF₆) and freons (F‐11, F‐12 and F‐113) showed the presence of modern waters in the recharge areas and shallow confined parts of the aquifer. The presence of older Holocene waters farther from the recharge areas was indicated by lack of ³H, SF₆ contents ≤0·02 fmol l⁻¹ and relatively low ¹⁴C values. The discharge from the system is by upward seepage in the valley of a major river. Pre‐Holocene waters of a cooler climate, identified on the basis of δ¹⁸O, δ²H, ¹⁴C, Ne and Ar data, were found in some distant wells. Concentrations of N₂, Ne and Ar determined by gas chromatography were used for calculating the noble gas temperatures, air excess needed for correction of SF₆, and nitrogen content released by denitrification process. The time series of ³H content available for some wells supplied quantitative information on age distributions and the total mean ages of flow through the unsaturated and saturated zones. The derived ³H age distributions turned out to be very wide, with mean values in the range of about 30 to 160 years. For each well with determined ³H age, the SF₆ data showed either a lower age range or the possibility of a lower age as expected due to shorter travel times of SF₆ through the unsaturated zone, which most probably also resulted in different types of age distributions of these tracers. Freons appeared to be of little use for individual age determinations. A quantitative estimation of two‐component mixing from SF₆ ³H relations is not possible unless the travel time of ³H through the unsaturated zone is comparable to that of SF₆. The ratio of integrals of the response function over the age range with tracer and the whole response function yields the ratio of water with tracer to total flow of water. That ratio is a tracer‐dependent function of time. Transport modelling of SF₆ tracer done with MT3D code yielded initially large discrepancies between calculated and measured tracer concentrations. Some discrepancies remained even after calibration of the transport model with SF₆. Simulation of tritium contents with a calibrated transport model yielded reasonable agreement with measured contents in some wells and indicated a need for further investigations, particularly in the eastern part of the aquifer. The existence of distinct hydrochemical zones is consistent with the tracer data; young waters with measurable ³H and SF₆ contents are aerobic and of HCO₃ Ca or HCO₃ SO₄ Ca types. Slightly elevated Na and Cl contents, as well as the highest concentrations of SO₄ and NO₃ within this zone are due to anthropogenic influences. Anaerobic conditions prevail in the far field, under the confining cover, where pre‐bomb era Holocene waters dominate. In that zone, dissolved oxygen, NO₃ and U contents are reduced, and Fe, Mn and NH₄ contents increase. In the third zone, early Holocene and glacial waters occur. They are of HCO₃ Ca Na or HCO₃ Na types, with TDS values higher than 1 g l⁻¹ and Na content higher than 200 mg l⁻¹, due to either small admixtures of ascending or diffusing older water or freshening of marine sediments, a process that is probably occurring till the present time. Copyright © 2005 John Wiley & Sons, Ltd.     

Contamination status and spatial distribution of organochlorine compounds in fishes from Nansei Islands,Japan

Two species of fishes (n = 52; tilapia and mullet) from industrialized and urbanized areas of Okinawa Island (Manko-Noha river, Hija river and Shikaza river) and from a remote area of Ishigaki Island (Anparu mudflat), Japan were collected between August 2005 and July 2006, and analyzed for five organochlorine compounds (OCs), viz., DDTs, PCBs, CHLs, HCHs and HCB. Concentrations and the contamination patterns of OCs in fishes varied between locations. Considerable residue levels of OCs, especially CHLs and DDTs were found in both fishes from the main Okinawa Island. These levels were relatively higher than the reported values for seafood from Japanese coasts, indicating that even now pollution sources of these contaminants still exist in this region. On the other hand, lower concentrations of OCs were detected in fishes from Ishigaki Island waters than those of other Japanese coastal waters, suggesting that this region is less contaminated by OC contaminants.     

Copper in natural waters in Transbaikalia

Cu concentrations in surface (river and lake) and subsurface waters are determined. The geographic pattern of Cu distribution in natural water is identified. This pattern is controlled by the difference between its concentrations in drained rocks and soils and the geochemical redox conditions of its migration. Territories with low, medium, and elevated Cu concentrations in natural waters are identified. The concentrations of Cu in natural waters of the region are found to be generally lower than the Clarke values.     

Herbicide contamination and the potential impact to seagrass meadows in Hervey Bay, Queensland, Australia

Low concentrations of herbicides (up to 70 ng l(-1)), chiefly diuron (up to 50 ng l(-1)) were detected in surface waters associated with inter-tidal seagrass meadows of Zostera muelleri in Hervey Bay, south-east Queensland, Australia. Diuron and atrazine (up to 1.1 ng g(-1) dry weight of sediment) were detected in the sediments of these seagrass meadows. Concentration of the herbicides diuron, simazine and atrazine increased in surface waters associated with seagrass meadows during moderate river flow events indicating herbicides were washed from the catchment to the marine environment. Maximum herbicide concentration (sum of eight herbicides) in the Mary River during a moderate river flow event was 4260 ng l(-1). No photosynthetic stress was detected in seagrass in this study during low river flow. However, with moderate river flow events, nearshore seagrasses are at risk of being exposed to concentrations of herbicides that are known to inhibit photosynthesis.     

生物壳体锶地球化学恢复盆地古水文——以泥河湾盆地为例

本文以著名的泥河湾盆地小渡口剖面28层为实例,通过有孔虫,介形虫,腹足类微体生物壳体87Sr/86Sr比值与盆地汇水区域Sr同位素地层分布特征对比分析以及生物壳体Sr/Ca国度的相关性,来重塑沉积盆地汇水来源变更,湖水变化等古水文要素,进而可以反演区域构造－气候变化,实例研究结果表明,生物壳体87Cr/86Sr 及Sr/Ca比值等地球化学方法是恢复盆地古水文条件的重要手段。