广东三水盆地古近系心组生油层的元素地球化学特征

沉积物的元素地球化学特征是对沉积盆地水体环境以及古气候条件变化的响应。本文根据元素（Al、Fe、Mg、Ca、K、Na、P、V、Ni、Co、Cr、Cu、Zn、Sr、Ba、Cd、Li、Mn、Pb、Ti）的含量及其比值（Al/Ti、Fe/Mn、Sr/Ba、Mg/Ca、Sr/Ca、Na/Ca、V/Cr、Ni/Co、Ni/V）的变化，对三水盆地古近系心组红岗段生油层的沉积条件进行了系统分析。心组红岗段下部（亚段A）表现为较稳定的地球化学特征。各元素丰度及其比值指示这一时期陆源输入持续较高、且物源组成变化不大。由于海水入侵的影响，湖盆水体盐度相对较高，底部水体以弱氧化条件为主，O₂-H₂S界面位于水/沉积物界面附近。红岗段中上部（亚段B、C）的元素地球化学特征变化较为频繁且幅度很大，反映古气候和湖盆沉积条件的迅速变迁。在潮湿气候条件下，沉积物的地球化学特征表现为以Al、Ti为代表的外源元素含量及其比值较高，而Mg、Ca等盆内化学沉积元素含量较低。古氧气指标指示底部水体为还原环境，有利于有机质保存。因而，相应于较高的有机碳含量。在间歇性干旱时期，陆源输入减少，外源元素含量及其比值显著降低。随着蒸发作用的加强，水体盐度加大，内源元素丰度以及Mg/Ca、Sr/Ba、Sr/Ca和Na/Ca比值大幅度上升。底部水体为氧化环境，O₂-H₂S界面多位于水/沉积物界面或沉积物中。上述两种气候条件在红岗段中上部沉积时期交替出现。红岗段沉积后期由于淡水的长期输入，湖水出现逐渐淡化趋势。     

Ecological replacement of Valanginian agglutinated foraminifera during a maximum flooding event in the Boreal realm (Spitsbergen)

Data from agglutinated benthic foraminiferal assemblages and geochemical proxies make it possible to characterise different order sea-level dynamics —from a geological scale third-order transgressive-regressive cycle to a minor-scale, ecological range, maximum flooding-initial regressive phase—in part of the Valanginian from Spitsbergen. The transgressive-regressive cycle starts with abundance (foram/100 g) of opportunist epifaunal forms related to deep waters and low productivity conditions on oxygenated sea-bed. The increase of these foraminifera, together with increased condensation and an impoverishment of trophic resources, is associated with the maximum flooding phase. The beginning of the subsequent regression shows a progressive diminution in foraminiferal abundance as a result of the greater sedimentation rate, the mounting proportions of deep infaunal forms, and the diminution of genera of deep-water environments. This initial regressive phase is associated with more arid climatic conditions (abrupt increase of eolian detrital proxies), and high palaeoproductivity (increase of Ba/Al, Sr/Al and P/Ti ratios and TOC), determining a diminution in the oxygenation (high values in Co/Al, Ni/Al and Mo/Al ratios and hydrogen index). After the initial productivity bloom, the foraminiferal abundance decreases, whereas diversity increases, favoured by the stability of environmental conditions (no fluctuations in palaeoproductivity, detrital and redox proxies), in turn related to deceleration of sea-level fall. The peaks of maximum foraminiferal abundance (optimum) of each morphogroup during the transition from maximum flooding to the beginning of regression allow us to identify an ecological replacement inter- and intra-microhabitats. In the different phases of ecological replacement, the dominant morphogroups are distributed in distinct microhabitats (epifaunal, shallow infaunal and deep infaunal) as a result of competition.     

Impact of climate variability in the western Mediterranean during the last 20,000 years: oceanic and atmospheric responses

Eolian input fluctuations and paleoceanographic conditions in the western Mediterranean have been reconstructed by using a multi-proxy approach to infer climate variability for the last 20,000 yr. A sediment core from the East Alboran Sea basin provides high-resolution geochemical, mineralogical and grain size distribution records from the Last Glacial Maximum onward. The accurate chronology obtained, closely related with the North Greenland Ice core Project, has provided a detailed paleoclimate reconstruction at the centennial–millennial time scale. Mineral and chemical compositions as well as sediment grain size distribution have been used to establish both fluvial and eolian input variations, deep-water current intensity, and ventilation and productivity conditions at the time of deposition. During the cold period Greenland Stadial-2a, the analyzed proxies evidence significant climate oscillations. Redox proxies, showing marked Mn/Al and Fe/Al peaks, as well as granulometric parameters, support major changes in thermohaline circulation, with active circulation triggered by the Western Mediterranean Deep Water formation. Ba/Al ratios and the presence of authigenic barite point to high productivity during the Last Heinrich event. At this time, Zr/Al, Si/Al and Ti/Al ratios as well as quartz and palygorskite contents also corroborate dryer conditions in the Alboran borderlands, with a major reorganization of atmospheric circulation at the beginning of the deglaciation and during the Last Heinrich event. In contrast, a decreasing trend in the Zr/Al ratio and increasing Mg/Al, K/Al and illite + chlorite/kaolinite ratios would indicate enhanced river runoff and supporting lower eolian dust input and wetter periods during the Bölling–Alleröd. Short-term and abrupt climate oscillations such as the Intra-Alleröd Cold Period are likewise reflected by minor yet conspicuous changes in eolian proxies. During the Younger Dryas, we distinguish an initial cold and dry phase, with major westerlies intensity, thermohaline reactivation, and high productivity levels, and a second wetter phase characterized by sporadic rainfalls over poorly vegetated surrounding continental areas. Then, during the Holocene, alternating phases of major humidity and aridity were recorded by major fluctuations in detrital input. These are also correlated with recurrent forest cover declines reported from pollen records, with a noteworthy early decline in the African Humid Period. During the Holocene, an initial demise of the Last Organic-Rich Layer is also evidenced, tentatively associated with aspiration forces promoted by intense thermohaline circulation through the Gibraltar Strait.     

Impacts of grain size sorting and chemical weathering on the geochemistry of Jingyuan loess in the northwestern Chinese Loess Plateau

Major and trace elemental compositions of loess samples collected from the Jingyuan section in the northwestern Chinese Loess Plateau (CLP) were analyzed to investigate the potential impacts of grain size sorting and chemical weathering on the loess geochemistry and to extract appropriate geochemical indices for better evaluating the East Asian monsoon variability. Based on variations of major and trace elements in different grain size fractions, seventeen elements were classified into three types: (1) Si and Na display higher contents with the increased particle sizes; (2) Al, Fe, Mg, K, Mn, Zn, Rb, Cr, V are mainly enriched in fine size fractions; (3) Ti, Ba, Zr, P, Ca and Sr show irregular variations among different size fractions. Comparison of Al-normalized elemental ratios with Zr/Rb and Rb/Sr ratios (two commonly employed indicators for grain size sorting and pedogenic weathering) indicates that Si/Al, Zr/Al, Ti/Al variations match well with Zr/Rb and grain size results, whilst Ca/Al, Sr/Al, P/Al ratios display similar variability as that of Rb/Sr ratio. Comparison of loess based proxies (e.g., elemental ratios, magnetic susceptibility, grain size) of Jingyuan section with speleothem and ice-core records confirms that elemental ratios of high-resolution loess sequences developed in the northwestern CLP can be employed to address fluctuations of the winter monsoon-induced grain size sorting and summer monsoon-related weathering and pedogenesis at glacial–interglacial and millennial timescales.     

古海洋生产力地球化学指标的研究

寻求反映古海洋生产力变化的指标是古海洋学研究的重要内容.主量元素地球化学与微量元素地球化学以及相关的同位素指标已成为追溯古海洋生产力演化的有力工具.从古生产力替代指标的示踪原理和应用的角度,综述了主量元素(A1、Fe、P),微量元素(Ba、Cu、Zn、Ni、Cd、Sr/Ca、Mo),同位素(碳、氮同位素)等在古生产力研...     

广西来宾铁桥二叠系剖面生物地球化学信号的解读

二叠纪被认为是全球生物繁盛的重要时期,其大气含氧量、温度等条件和现代地球极为相似,因 此,二叠纪古海洋生物和环境的研究对当代环境和气候变化研究具有重要的启示作用。通过分析广西来宾铁桥 二叠系剖面的275个海相碳酸盐岩样品的地球化学组成,考察Ca,Mg,Al,Ti 及其比值的变化特征,研究它们 的生物和环境意义。结果发现,从栖霞组沉积时期到吴家坪组沉积时期,海水中Mg/Ca值总体上呈单调下降趋 势,表明海底洋中脊扩张,洋中脊热液循环加快,全球海平面上升;Al/Ti值在栖霞组沉积时期到吴家坪组沉积 时期呈现一种起伏式的变化,其中栖霞组沉积中期和茅口组沉积后期表现出与其他时段有显著差异的高值,表 明这两个时期海洋生产力繁盛;在瓜德卢普统-乐平统界线,Al/Ti值低,与玄武岩(Al/Ti 值约为6)相近, 指示火山活动强烈,为火山活动导致生物绝灭说提供了地球化学新证据。     

Coprecipitation of Ti,Mo, Sn and Sb with fluorides and application to determination of B,Ti, Zr,Nb, Mo,Sn, Sb,Hf and Ta by ICP-MS

We examined the coprecipitation behavior of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides under two different fluoride forming conditions: at < 70 °C in an ultrasonic bath (denoted as the ultrasonic method) and at 245 °C using a Teflon bomb (denoted as the bomb method). In the ultrasonic method, small amounts of Ti, Mo and Sn coprecipitation were observed with 100% Ca and 100% Mg fluorides. No coprecipitation of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides occurred when the sample was decomposed by the bomb method except for 100% Ca fluoride. Based on our coprecipitation observations, we have developed a simultaneous determination method for B, Ti, Zr, Nb, Mo, Sn, Sb, Hf and Ta by Q-pole type ICP-MS (ICP-QMS) and sector field type ICP-MS (ICP-SFMS). 9–50 mg of samples with Zr–Mo–Sn–Sb–Hf spikes were decomposed by HF using the bomb method and the ultrasonic method with B spike. The sample was then evaporated and re-dissolved into 0.5 mol l^− 1 HF, followed by the removal of fluorides by centrifuging. B, Zr, Mo, Sn, Sb and Hf were measured by ID method. Nb and Ta were measured by the ID-internal standardization method, based on Nb/Mo and Ta/Mo ratios using ICP-QMS, for which pseudo-FI was developed and applied. When 100% recovery yields of Zr and Hf are expected, Nb/Zr and Ta/Hf ratios may also be used. Ti was determined by the ID-internal standardization method, based on the Ti/Nb ratio from ICP-SFMS. Only 0.053 ml sample solution was required for measurement of all 9 elements. Dilution factors of ≤ 340 were aspirated without matrix effects. To demonstrate the applicability of our method, 4 carbonaceous chondrites (Ivuna, Orgueil, Cold Bokkeveld and Allende) as well as GSJ and USGS silicate reference materials of basalts, andesites and peridotites were analyzed. Our analytical results are consistent with previous studies, and the mean reproducibility of each element is 1.0–4.6% for basalts and andesites, and 6.7–11% for peridotites except for TiO₂.     

鄂西地区上二叠乐平统大隆组硅质岩成因及有机质富集机理

晚二叠世是古生代环境、生物演化的关键时期,发育广泛的富有机质沉积,并成为南方重要的烃源岩层位。为了解该时期的富有机质堆积机理,我们选择了鄂西台内盆地晚二叠世大隆组富有机质硅质岩(TOC平均值为5.8%,峰值为18%)作为研究对象。硅质岩中常量元素Al/Fe均值为0.79,Mn/Ti均值为0.21,显示为大陆边缘环境下的生物成因,即非热水成因。∑REE值与Al2O3含量有着良好的正相关关系,表明当时陆源物质的输入对硅质岩的形成有很大影响。微量元素U/Th、V/(V+Ni)均说明硅质岩沉积环境为缺氧水体环境。通过对草莓状黄铁矿粒径的统计表明,大多数(64%～89%)的草莓状黄铁矿粒径小于5μm,反映缺氧甚至硫化的环境。而且,U、V、Mo的富集以及Ni、Cu元素的亏损说明水体的缺氧主要是由于海水分层,水体循环受阻造成的。TOC与氧化还原参数的变化步调基本一致,两者有着较好的正相关关系,而与生产力指标Ba/Al相关性很差,说明有机质富集主要是由水体的缺氧而不是初级生产力控制的。     

Climatic changes vs. catastrophic events in lacustrine systems: A geochemical approach

A geochemical study of oligotrophic Lake Sanabria (NW Iberian Peninsula) allows us to distinguish the geochemical response of a lacustrine system to catastrophic events and climatic events. The main major elements analysed were: K, Na, Mg, Ca, Ti, Al, Fe, Mn, P and S. The organic matter content in the sediment of Lake Sanabria is determined by the rainfall regime of the region. Periods when sediments were enriched in Ti, Mg, K, and Al are indicative of relatively wet paleoenvironmental conditions, whereas intervals when sediments were enriched in S and P (associated with organic matter) are indicative of dry conditions. A factor analysis of the geochemical data shows a progressive temporal displacements from organic rich conditions (relatively high values of S and P) to inorganic rich conditions (relatively high values of Ti, Mg, K, Al, and Na). Maximal inorganic content occurred at the beginning of two discrete sedimentary levels: the LOL2 (cal. 1160–1230 yr AD) and the LOL1 (cal. 1510–1680 yr AD) horizons. The LOL2 and LOL1 horizons constitute two discrete events related to climatic changes during the beginning and end of the Little Ice Age, respectively. In contrast, the geochemical analysis provides evidence that the samples associated with the 1959 catastrophic event that occurred in the catchment area of Lake Sanabria do not follow the long-term geochemical evolution paths of the climate driven system.     

Millennial- to centennial-scale climate periodicities and forcing mechanisms in the westernmost Mediterranean for the past 20,000 yr

Cyclostratigraphic analysis conducted on a continuous high-resolution marine record from the western most Mediterranean reveals well-identified paleoclimate cycles for the last 20,000 yr. The detrital proxies used (Si/Al, Ti/Al, Zr/Al, Mg/Al, K/Al, Rb/Al) are related to different sediment-transport mechanisms, including eolian dust and fluvial runoff, which involve fluctuations in the atmosphere–hydrosphere systems. These fluctuations are accompanied by changes in marine productivity (supported by Ba/Al) and bottom-water redox conditions (Cu/Al, V/Al, Zn/Al, Fe/Al, Mn/Al, U/Th). Spectral analysis conducted using the Lomb–Scargle periodogram and the achieved significance level implemented with the permutation test allowed us to establish major periodicities at 1300, 1515, 2000, and 5000 yr, and secondary peaks at 650, 1087, and 3000 yr. Some of these cycles also agree with those previously described in the North Atlantic Ocean and circum-Mediterranean records. The periodicities obtained at 2000 and 5000 yr support a global connection with records distributed at high, mid, and low latitudes associated with solar activity, monsoonal regime and orbital forcing. The 1300- and 1515-yr cycles appear to be linked with North Atlantic climate variability and the African monsoon system. Thus, the analyzed record provides evidence of climate cycles and plausible forcing mechanisms coupled with ocean–atmosphere fluctuations.     

Early Jurassic anoxic conditions and organic accumulation in the eastern Tethys

The Bilong Co oil shale, located in the South Qiangtang depression, northern Tibet Plateau, may record the Early Jurassic anoxic event in the eastern Tethys. New geochemical data from the Bilong Co oil shale section are presented in order to determine the mechanism of organic accumulation and to evaluate Early Jurassic anoxia in the eastern Tethys. In organic-rich oil shales, many redox proxies including the relationship of Mo to total organic carbon (TOC), Re/Mo ratios, and pyrite framboid size distribution suggest deposition under euxinic conditions. However, the correlation between TOC and P and Mo contents indicates that organic matter accumulation was controlled mainly by primary productivity. The Sr/Al ratios and clastic influx proxies such as Si, Ti, Th, Zr, and Al concentrations suggest a continuous supply of fresh water from a nearby continent during oil shale deposition. This supply could have initiated stratification of the water so that the upper zone became favourable for marine life. Increased primary productivity could have led to formation of anoxic/sulphidic bottom waters, which enhanced the preservation of organic matter. Deposition of organic-rich oil shales terminated when primary productivity decreased, leading to more oxic bottom water conditions.     

乌伦古湖沉积物粒度特征及其古气候环境意义

利用乌伦古湖沉积钻孔的粒度资料,分析了粒度频率曲线、粒度参数和粒度组成等粒度特征,并探讨了乌伦古湖粒度代表的古气候意义。结果表明乌伦古湖沉积物频率曲线主要是正态单峰型,反映流水作用为主要沉积作用。岩芯下部（225197cm）沉积物分选较差,偏度和尖度较大,为浅水沉积环境;中部（197103cm）分选由差变好,物源由复杂变单一,为浅水沉积向深水沉积过渡环境;上部（1030cm）分选较好,物源单一,中值粒径减小,反映了湖水位的下降。沉积物粒度特征反映了乌伦古湖地区全新世降水、流水和风力作用以及湖面水位高低的变化。乌伦古湖一万年来的古气候环境演化大致经历了102507720cal.aBP的干旱、77202800cal.aBP的湿润和2800cal.aBP以来的偏干三个阶段。      

Integrated marine and terrestrial evidence for abrupt Congo River palaeodischarge fluctuations during the last deglaciation

We present a high‐resolution reconstruction of tropical palaeoenvironmental changes for the last deglacial transition (18 to 9 cal. kyr BP) based on integrated oceanic and terrestrial proxies from a Congo fan core. Pollen, grass cuticle, Pediastrum and dinoflagellate cyst fluxes, sedimentation rates and planktonic foraminiferal δ¹⁸O ratios, u₃₇^K′ sea‐surface temperature and alkane/alkenone ratio data highlight a series of abrupt changes in Congo River palaeodischarge. A major discharge pulse is registered at around 13.0 cal. kyr BP which we attribute to latitudinal migration of the Intertropical Convergence Zone (ITCZ) during deglaciation. The data indicate abrupt and short‐lived changes in the equatorial precipitation regime within a system of monsoonal dynamics forced by precessional cycles. The phases of enhanced Congo discharge stimulated river‐induced upwelling and enhanced productivity in the adjacent ocean. Copyright © 2001 John Wiley & Sons, Ltd.     

Geochemical Record of the Cenomanian–Turonian Anoxic Event in Tunisia: Is it Correlative and Isochronous to the Biotic Signal?

In Tunisia, five Bahloul spaced sections, Bargou, Jerisa, Guern Halfaya, Kherij and Gafsa were analyzed for biostratigraphy (foraminifera and radiolarians) and major and trace elements. This high-resolution biostratigraphic and chemostratigraphic integrated analyses for the Late Cenomanian–Early Turonian Bahloul Formation provide new insight into the palaeoceanographic evolution of the southern Tethyan margin. Relative low abundance of related terrigenous Ti/Al and K/Al ratios and enrichment of some productivity proxies such as Ba, Cu, and Ni (organic matter related trace elements) suggests that the Bahloul, deposited during a relatively short period (0.5 Ma), was of relatively elevated primary productivity and minimal detrital input. While higher D* values concurrent with lower Ti/Al ratios are interpreted as caused by enhanced fluvial material contribution, due to more humid climate during the OAE-2. Enhanced humidity triggered probably fluvial influxes, resulted in a sluggish water circulation and consequent anoxic/euxinic conditions favoring the preservation of organic matter at the bottom. Enrichments in redox-sensitive trace metals U, V, and Mo in the Bahloul Formation deposits and redox indices, such as V/(V+Ni), U/Th, V/Cr, and Ni/Co, indicate that oxygen-restricted conditions prevailed during the Late Cenomanian to earliest Turonian times and correlate well with relative abundances of some foraminiferal and radiolarian paleo-environmental relevant indicators. High Baxs values and Uauth may indicate anoxic conditions at least at the water–sediment interface during the Bahloul Formation deposition and provide information about low to moderate sulfate-reduction reactions.     

内蒙古达里湖沉积记录的中晚全新世干旱事件

最近20年位于东亚夏季风北部边缘的我国北方半干旱区遭遇更为频繁、更为严重的干旱事件。然而,有关该区域过去不同时间尺度气候干旱事件的特征及机制仍知之甚少。文章详细分析了内蒙古中东部达里湖DL04岩芯上部6.5 m沉积物中< 38 μm碳酸盐的Ca和Mg含量、δ^18O和δ^13C值以及全样有机质TOC和TN含量、TOC/TN(C/N)比值,基于高精度的AMS^14C年代标尺,恢复了最近6000年(日历年)湖区的水文、气候变化详细过程。结果表明:达里湖< 38 μm碳酸盐主要为湖泊水体沉淀的内生方解石,其Ca和Mg含量、δ^18O和δ^13C值增大反映湖水蒸发量超过补给水量,进而指示湖区干旱事件。TOC和TN含量减少以及C/N比值减小总体反映地表径流减弱引起的陆生有机质入湖减少以及湖泊初始生产率下降。达里湖沉积内生碳酸盐和有机质地球化学数据表明,在6000~5300 cal.a B.P.、3200~2800 cal.a B.P.、1650~1150 cal.a B.P.和650~300 cal.a B.P.,流域地表径流显著减弱、湖面显著降低、湖泊生产率显著下降、湖区气候显著变干、东亚夏季风显著减弱。最近6000年东亚夏季风显著减弱事件在定年误差范围内与北大西洋冰漂碎屑事件一致,而与热带西太平洋海表温度变化和太阳活动变化相关性较差,表明千、百年尺度东亚夏季风突变主要受控于北半球高纬气候变冷。     

手持X射线衍射仪(ED-XRF)在旋回地层学中的应用:以酒泉盆地青西凹陷早白垩世下沟组为例

在旋回地层学研究中,高分辨率地球化学数据作为一重要的替代指标,其一般获取方式（ICP-MS或WD-XRF）较耗费时间和经费,而手持X射线衍射仪（ED-XRF）能够高效的解决这一问题,目前将ED-XRF运用在沉积地层研究中,尤其是旋回地层学研究领域中较少.以酒泉盆地青西凹陷早白垩世下沟组深湖相泥岩、白云质泥岩为研究对象,将连续采集的岩心样品通过ED-XRF测试,该测试方法能够保证在不破坏样品的前提下,并在误差允许的范围内的条件下,短时间内（5 min）完成对单一样品的测试.通过测试精确得出24种主量及微量元素的含量,将得出的地球化学特征作为旋回地层学研究的替代指标,并针对K/Al,Ca/Al,Si/Al,Fe/Al,Ti/Al,Mn/Al,Ni/Al,Zn/Al和Pb/Al的比值进行频谱分析.数据表明W2井下沟组一段（SQK₁g1）地层旋回性表现出与天文旋回明显的对应关系.沉积地层中的旋回厚度比值为20.25:4.75:1.75:1.00,与米兰科维奇旋回中长偏心率、短偏心率、斜率和岁差的周期比值:400 ka:95 ka:37 ka:20 ka相对应.该地区的沉积记录受天文轨道周期的影响得到了证明,与此同时,为手持X射线衍射仪在旋回地层学中的应用开辟了新领域.      

Variations in chemical element compositions in different types of Holocene calcareous root tubes in the Tengger Desert,NW China,and their palaeoenvironmental significance

Calcareous root tubes (CRTs) contain abundant information about palaeoenvironmental conditions and have been used for palaeoenvironmental studies in the desert hinterlands of arid regions. However, as subclasses of CRTs, calcareous sheaths and rhizocretions are formed by different processes, and it remains unclear whether these differences produce variations in the chemical element composition. Furthermore, it remains uncertain whether variations in chemical element concentrations amongst different subclasses of the CRTs can affect palaeoenvironmental reconstructions. In this study, we collected 54 CRT samples from the Tengger Desert of northwestern China. All samples were dated by accelerator mass spectrometry (AMS) ¹⁴C dating, and the chemical element composition and concentration differences of the two CRT subclasses were determined using X‐ray fluorescence spectrometry. The CRT samples were dated to the Holocene. The calcareous sheath and rhizocretion samples contained varying concentrations of the same chemical elements. The rhizocretions had high concentrations of mobile elements (Ca, Mg and Sr) and P, whereas the calcareous sheaths had high concentrations of stable elements, including Al, Si, Ti, Zr, Rb and Ba. These differences were due to the different formation processes of the two subclasses of CRTs. Moreover, the Sr/Ca and Mg/Ca ratios in the calcareous sheaths were higher than those in the rhizocretions from the same period, but these ratio differences had little effect on palaeo‐effective moisture reconstructions at the millennial scale during the Holocene. The reconstructions were not influenced by the various CRT subclasses. The Holocene millennial‐scale moisture changes in the Tengger Desert revealed by the Sr/Ca and Mg/Ca ratios showed that there was an arid period during the Early Holocene, a humid period during the Middle Holocene and a humid to arid period during the Late Holocene.     

Deciphering signals of late Holocene fluvial and aeolian supply from a shelf sediment depocentre off Senegal (north‐west Africa)

High‐resolution climatic records of the late Holocene along the north‐west African continental margin are scarce. Here we combine sediment grain size, elemental distribution and mineral assemblage data to trace dust and riverine sources at a shallow‐marine sediment depocentre in the vicinity of the Senegal River mouth. The aim is to understand how these terrigenous components reflect climate variability during the late Holocene. Major element contents were measured and mineral identification was performed on three sub‐fractions of our sediment core: (i) fluvial material < 2 µm, (ii) aeolian material of 18–63 µm and (iii) a sub‐fraction of dual‐origin material of 2–18 µm. Results show that more than 80% of the total Al and Fe terrigenous bulk content is present in the fluviogenic fraction. In contrast, Ti, K and Si cannot be considered as proxies for one specific source off Senegal. The Al/Ca ratio, recording the continental river runoff, reveals two dry periods from 3010 to 2750 cal a BP and from 1900 to 1000 cal a BP, and two main humid periods from 2750 to 1900 cal a BP and from 1000 to 700 cal a BP. The match between (i) intervals of low river runoff inferred by low Al/Ca values, (ii) reduced river discharge inferred by integrated palynological data from offshore Senegal and (iii) periods of enhanced dune reactivation in Mali confirms this interpretation. Copyright © 2011 John Wiley & Sons, Ltd.     

秦皇岛石门寨亮甲山奥陶系剖面化学地层和旋回地层研究

根据秦皇岛石门寨亮甲山奥陶系剖面的化学地层和岩石地层特征,将亮甲山组(O1l)细分为下、中、上段。选取Fe/Ca、Ti/Ca作为古气候替代指标,开展时间序列分析。通过多窗谱法(MTM)和傅里叶变换法(FT),从Fe/Ca、Ti/Ca比值中共提取出两个明显的米兰科维奇旋回：长偏心率405 ka和短偏心率90 ka。基于长偏心率周期建立的天文年代标尺表明,亮甲山组沉积时长为6.2 Ma,平均沉积速率为14.68 m/Ma,其中亮甲山组下段(0.00~48.00 m)和中上段(48.00~91.00 m)的沉积速率分别为12.00 m/Ma和19.55 m/Ma;马家沟组下部的沉积速率为18.00 m/Ma。奥陶纪生物大辐射可能直接导致碳酸盐生产模式由以灰泥生产为主转变为以生物碎屑生产为主,并使亮甲山组下段与中上段之交碳酸盐沉积速率大幅增加。旋回地层分析显示,早、中奥陶世之交天文轨道周期变化引起的地球气候改变可能对奥陶纪生物大辐射有重要的调控作用。     

Sedimentary evidence of deglacial megafloods in the northern Gulf of Mexico (Pigmy Basin)

Cored sediments from the Pigmy Basin, northern Gulf of Mexico, were analyzed in order to better constrain late deglacial and early Holocene paleoenvironmental and sedimentary changes in response to North American climate evolution. Mineralogical and geochemical proxies indicate the succession of two sedimentary regimes: dominantly detrital during the deglaciation (15–12.9 cal ka BP) whereas biogenic contribution relatively increased later on during the Younger Dryas and early Holocene (12.9 and 10 cal ka BP). Geochemical data reveal that the deglacial record mainly reflects variations of terrigenous supply via the Mississippi River rather than modifications of redox conditions in the basin. Specific variations of almost all the parameters measured in this paper are synchronous with the main deglacial meltwater episode (Meltwater Spike) described or modeled in previous marine or continental studies. During this episode, most parameters display “stair-step-like” – pattern variations highlighting three successive steps within the main meltwater flow. Variations in grain-size and clay mineral assemblage recorded in the Pigmy Basin indicate that the erosional regime was very strong on land during the first part of the Meltwater Spike, and then milder, inducing more subtle modifications in the sedimentary regime in this part of the Gulf. Specific geochemical and mineralogical signatures (notably, clay minerals and trace metal geochemistry) pinpoint a dominant origin from NW North America for detrital particles reflecting meltwater outflow from the south-western Laurentide Ice Sheet (LIS) margin during the most intense freshwater discharge. The observed decrease of the sedimentation rate from about 200 to 25 cm/ka at ca 12.9 ka evidenced a drastic decrease of erosional processes during late phase of discharge, consistently with the hypotheses of major reduction of meltwater flow. The major modification at 12.9 cal ka BP is interpreted to result from both modifications of the main Mississippi fluvial regime due to eastward and northward rerouting of meltwater flow at the onset of the Younger Dryas, and the increase of sea-surface temperature linked to insolation. Finally, slight grain-size modifications suggest that some freshwater discharges may have episodically reached the Gulf of Mexico after the Younger Dryas reflecting possible small adjustments of the postglacial hydrological regime.