Combination of CFCs and stable isotopes to characterize the mechanism of groundwater–surface water interactions in a headwater basin of the North China Plain

Mountainous areas are characterized by steep slopes and rocky landforms, with hydrological conditions varying rapidly from upstream to downstream, creating variable interactions between groundwater and surface water. In this study, mechanisms of groundwater–surface water interactions within a headwater catchment of the North China Plain were assessed along the stream length and during different seasons, using hydrochemical and stable isotope data, and groundwater residence times estimated using chlorofluorocarbons. These tracers indicate that the river is gaining, due to groundwater discharge in the headwater catchment both in the dry and rainy seasons. Residence time estimation of groundwater using chlorofluorocarbons data reveals that groundwater flow in the shallow sedimentary aquifer is dominated by the binary mixing of water approximating a piston flow model along 2 flow paths: old water, carried by a regional flow system along the direction of river flow, along with young water, which enters the river through local flow systems from hilly areas adjacent to the river valley (particularly during the rainy season). The larger mixing ratio of young water from lateral groundwater recharge and return flow of irrigation during the rainy season result in higher ion concentrations in groundwater than in the dry season. The binary mixing model showed that the ratio of young water versus total groundwater ranged from 0.88 to 0.22 and 1.0 to 0.74 in the upper and lower reaches, respectively. In the middle reach, meandering stream morphology allows some loss of river water back into the aquifer, leading to increasing estimates of the ratio of young water (from 0.22 to 1). This is also explained by declining groundwater levels near the river, due to groundwater extraction for agricultural irrigation. The switch from a greater predominance of regional flow in the dry season, to more localized groundwater flow paths in the wet season is an important groundwater–surface water interactions mechanism, with important catchment management implications.     

Spatial and temporal dynamics of nitrogen exchange in an upwelling reach of a groundwater-fed river and potential response to perturbations changing rainfall patterns under UK climate change scenarios

We report the complex spatial and temporal dynamics of hyporheic exchange flows (HEFs) and nitrogen exchange in an upwelling reach of a 200 m groundwater-fed river. We show how research combining hydrological measurement, geophysics and isotopes, together with nutrient speciation techniques provides insight on nitrogen pathways and transformations that could not have been captured otherwise, including a zone of vertical preferential discharge of nitrate from deeper groundwater, and a zone of rapid denitrification linking the floodplain with the riverbed. Nitrate attenuation in the reach is dominated by denitrification but is spatially highly variable. This variability is driven by groundwater flow pathways and landscape setting, which influences hyporheic flow, residence time and nitrate removal. We observed the spatial connectivity of the river to the riparian zone is important because zones of horizontal preferential discharge supply organic matter from the floodplain and create anoxic riverbed conditions with overlapping zones of nitrification potential and denitrification activity that peaked 10–20 cm below the riverbed. Our data also show that temporal variability in water pathways in the reach is driven by changes in stage of the order of tens of centimetres and by strength of water flux, which may influence the depth of delivery of dissolved organic carbon. The temporal variability is sensitive to changes to river flows under UK climate projections that anticipate a 14%–15% increase in regional median winter rainfall and a 14%–19% reduction in summer rainfall. Superimposed on seasonal projections is more intensive storm activity that will likely lead to a more dynamic and inherently complex (hydrologically and biogeochemically) hyporheic zone. We recorded direct evidence of suppression of upwelling groundwater (flow reversal) during rainfall events. Such flow reversal may fuel riverbed sediments whereby delivery of organic carbon to depth, and higher denitrification rates in HEFs might act in concert to make nitrate removal in the riverbed more efficient.     

Simulating Groundwater-Streamflow Connections in the Upper Colorado River Basin

In mountain, snow driven catchments, snowmelt is supposed to be the primary contribution to river streamflows during spring. In these catchments the contribution of groundwater is not well documented because of the difficulty to monitor groundwater in such complex environment with deep aquifers. In this study we use an integrated hydrologic model to conduct numerical experiments that help quantify the effect of lateral groundwater flow on total annual and peak streamflow in predevelopment conditions. Our simulations focus on the Upper Colorado River Basin (UCRB; 2.8 × 10⁵ km²) a well-documented mountain catchment for which both streamflow and water table measurements are available for several important sub-basins. For the simulated water year, our results suggest an increase in peak flow of up to 57% when lateral groundwater flow processes are included—an unexpected result for flood conditions generally assumed independent of groundwater. Additionally, inclusion of lateral groundwater flow moderately improved the model match to observations. The correlation coefficient for mean annual flows improved from 0.84 for the no lateral groundwater flow simulation to 0.98 for the lateral groundwater flow one. Spatially we see more pronounced differences between lateral and no lateral groundwater flow cases in areas of the domain with steeper topography. We also found distinct differences in the magnitude and spatial distribution of streamflow changes with and without lateral groundwater flow between Upper Colorado River Sub-basins. A sensitivity test that scaled hydraulic conductivity over two orders of magnitude was conducted for the lateral groundwater flow simulations. These results show that the impact of lateral groundwater flow is as large or larger than an order of magnitude change in hydraulic conductivity. While our results focus on the UCRB, we feel that these simulations have relevance to other headwaters systems worldwide.     

Identifying the origin of groundwater for water resources sustainable management in an arid oasis,China

ABSTRACT

Many oases are experiencing severe groundwater depletion due to increased population, expanding agriculture and economic development. For sustainable development, quantifying groundwater recharge resources are fundamentally important. In this study, stable isotope techniques were employed to identify recharge sources of groundwater and quantitatively evaluate their contribution ratios in the Dunhuang Oasis, northwest China. Our findings indicate that heavy isotopes in shallow groundwater are more negative than those in deep groundwater, which is attributed to shallow groundwater that was modern and deep groundwater that was old. Irrigated return water and lateral groundwater flow from the Qilian Mountains are considered as the two main sources of shallow groundwater, accounting for 35% and 65% of the total recharge, respectively. Thus, as the main groundwater source of the Dunhuang Oasis, the Qilian Mountain Front should be protected against over-exploitation. Our results provide not only fundamental knowledge for groundwater management of aquifers of the Oasis, but also valuable water management information for other similar arid oases worldwide.     

Tracking Groundwater Discharge to a Large River using Tracers and Geophysics

Few studies have investigated large reaches of rivers in which multiple sources of groundwater are responsible for maintaining baseflow. This paper builds upon previous work undertaken along the Fitzroy River, one of the largest perennial river systems in north‐western Australia. Synoptic regional‐scale sampling of both river water and groundwater for a suite of environmental tracers (⁴He, ⁸⁷Sr/⁸⁶Sr, ²²²Rn and major ions), and subsequent modeling of tracer behavior in the river, has enabled definition and quantification of groundwater input from at least three different sources. We show unambiguous evidence of both shallow “local” groundwater, possibly recharged to alluvial aquifers beneath the adjacent floodplain during recent high‐flow events, and old “regional” groundwater introduced via artesian flow from deep confined aquifers. We also invoke hyporheic exchange and either bank return flow or parafluvial flow to account for background ²²²Rn activities and anomalous chloride trends along river reaches where there is no evidence of the local or regional groundwater inputs. Vertical conductivity sections acquired through an airborne electromagnetic (AEM) survey provide insights to the architecture of the aquifers associated with these sources and general groundwater quality characteristics. These data indicate fresh groundwater from about 300 m below ground preferentially discharging to the river, at locations consistent with those inferred from tracer data. The results demonstrate how sampling rivers for multiple environmental tracers of different types—including stable and radioactive isotopes, dissolved gases and major ions—can significantly improve conceptualization of groundwater—surface water interaction processes, particularly when coupled with geophysical techniques in complex hydrogeological settings.     

Quantification of surface water and groundwater salinity sources in irrigated lowland area of North China Plain

Seasonally variation of water salinity is observed worldwide, the mechanisms of water salinity are not well understood due to natural factors and anthropogenic activities. Quantification water salinity source are challenging since complex influence factors, especially in agricultural regions irrigated with multi-water sources. In the lowland area of North China Plain, transferred water, brackish shallow groundwater and fresh deep groundwater were combinative utilized to relieve prominent contradictions between regional water shortages and grain production. In this study, influence factors of surface water (canal water, pond water) and shallow groundwater salinity were identified and quantified through statistical analysis, deuterium excess, and ionic relationship. Salinity of canal water and pond water increased in dry season and decreased in rainy season, while salinity of shallow groundwater decreased in dry season after water transfer and rainy season, but increased in dry season. Evaporation and mineral dissolution were main factors for surface water salinity in dry season, with mineral dissolution was the more important one. The contribution ratio of evaporation and mineral dissolution for canal salinity were 4.4 and 49.1% in dry season after water transfer, 7.1 and 34.4% in dry season, and that for pond water salinity were 12.4 and 18.3% in dry season, respectively. Precipitation and surface runoff were main factors for surface water salinity in rainy season. The contribution of surface runoff for canal water and pond water salinity were 66.1 and 45.8%, respectively. Salinity of canal water and shallow groundwater was temporary decreased by water transfer. Domestic sewage from rural areas had larger influence than agricultural activities for salinity increase of pond water and shallow groundwater. Mineral dissolution was the main contributor for shallow groundwater salinity, with contribution ratio larger than 60% in different periods. This study demonstrated and quantified salinity source of surface water and shallow groundwater and may deepen our understanding of water management under multi-water resources utilization.     

Contributions of bedrock groundwater to the upscaling of storm‐runoff generation processes in weathered granitic headwater catchments

We examined the contributions of bedrock groundwater to the upscaling of storm‐runoff generation processes in weathered granitic headwater catchments by conducting detailed hydrochemical observations in five catchments that ranged from zero to second order. End‐member mixing analysis (EMMA) was performed to identify the geographical sources of stream water. Throughfall, hillslope groundwater, shallow bedrock groundwater, and deep bedrock groundwater were identified as end members. The contribution of each end member to storm runoff differed among the catchments because of the differing quantities of riparian groundwater, which was recharged by the bedrock groundwater prior to rainfall events. Among the five catchments, the contribution of throughfall was highest during both baseflow and storm flow in a zero‐order catchment with little contribution from the bedrock groundwater to the riparian reservoir. In zero‐order catchments with some contribution from bedrock groundwater, stream water was dominated by shallow bedrock groundwater during baseflow, but it was significantly influenced by hillslope groundwater during storms. In the first‐order catchment, stream water was dominated by shallow bedrock groundwater during storms as well as baseflow periods. In the second‐order catchment, deeper bedrock groundwater than that found in the zero‐order and first‐order catchments contributed to stream water in all periods, except during large storm events. These results suggest that bedrock groundwater influences the upscaling of storm‐runoff generation processes by affecting the linkages of geomorphic units such as hillslopes, riparian zones, and stream channels. Our results highlight the need for a three‐dimensional approach that considers bedrock groundwater flow when studying the upscaling of storm‐runoff generation processes. Copyright © 2014 John Wiley & Sons, Ltd.     

Hydrochemistry of groundwaters in a spa area of Korea: an implication for water quality degradation by intensive pumping

A geochemical study was carried out in a small spa area (Onyang Spa, Korea) where intensive pumping of deep thermal groundwater (1 300 000 m³ year⁻¹) is taking place. This has caused the deep fractures to lose their artesian pressure and the upper shallow fractures have been encroached by shallow, cold waters. To quantify the influence of long‐term heavy pumping on the quality of the geothermal water, groundwater sampling and chemical analysis, water‐level measurement, and well loggings were performed for the selected deep thermal wells and shallow cold wells. Chemical analysis results indicate a big contrast in water chemistry and origins between the two water types. Shallow groundwater shows a wider concentration ranges in solutes that are closely related to human activity, illustrating the water's vulnerability to contamination near the land surface. Plots of water chemistry as a function of fluoride reveal that the quality of the thermal water was greatly influenced by the shallow, cold groundwater and that intensive pumping of the deep thermal groundwater has caused the introduction of shallow groundwater into the deeper fractures. Although the deep and the shallow fractures were piezometrically separated to some extent, a mixing model based on fluoride and nitrate indicated that the cold‐water fractions in the thermal wells are up to 50%. This suggests that the thermal water is faced with water quality degradation by the downward flow of the shallow, cold water. Restriction on the total of all the pumpage permits per unit area is suggested to restore the artesian pressure of the deep thermal aquifer and to prevent cold‐water intrusion in the study area. Copyright © 2004 John Wiley & Sons, Ltd.     

Three-dimensional flow patterns at the river–aquifer interface — a case study at the Danube

The three-dimensional groundwater flow patterns in a gravel bar at the Danube east of Vienna were investigated and are discussed in this paper. The observed groundwater level gradients are highly dynamic and respond very quickly to changes in the river water levels. A variably saturated groundwater model was calibrated to the data to describe the complex dynamics of flow in the gravel bar. The model results suggest that short-term (6–48 h) fluctuations of river water levels cause variations in the exchange flow rates from − 35 l/s to 82 l/s. The highest rates occur during brief infiltration after rapidly rising river water levels. Simulations of different scenarios indicate that riverbank clogging will decrease the exchange fluxes by up to 80%, while clogging of both riverbank and riverbed essentially stops the flow exchange. The groundwater model is also used to simulate the transport of a conservative tracer. The variation of river water levels over time is shown to increase the extent of the active river–aquifer mixing zone in the gravel bar. These dynamic factors significantly enhance the dilution of conservative tracer concentrations in this zone.     

Factors Governing Sustainable Groundwater Pumping near a River

The objective of this paper was to provide new insights into processes affecting riverbank filtration (RBF). We consider a system with an inflatable dam installed for enhancing water production from downstream collector wells. Using a numerical model, we investigate the impact of groundwater pumping and dam operation on the hydrodynamics in the aquifer and water production. We focus our study on two processes that potentially limit water production of an RBF system: the development of an unsaturated zone and riverbed clogging. We quantify river clogging by calibrating a time‐dependent riverbed permeability function based on knowledge of pumping rate, river stage, and temperature. The dynamics of the estimated riverbed permeability reflects clogging and scouring mechanisms. Our results indicate that (1) riverbed permeability is the dominant factor affecting infiltration needed for sustainable RBF production; (2) dam operation can influence pumping efficiency and prevent the development of an unsaturated zone beneath the riverbed only under conditions of sufficient riverbed permeability; (3) slow river velocity, caused by dam raising during summer months, may lead to sedimentation and deposition of fine‐grained material within the riverbed, which may clog the riverbed, limiting recharge to the collector wells and contributing to the development of an unsaturated zone beneath the riverbed; and (4) higher river flow velocities, caused by dam lowering during winter storms, scour the riverbed and thus increase its permeability. These insights can be used as the basis for developing sustainable water management of a RBF system.     

Interactions between dam‐regulated river flow and riparian groundwater: a case study from the Yellow River,China

The Xiaolangdi Dam, completed in 2000, is second in scale in China to the Three Gorges Project. It has generated remarkable economic and social benefits but with profound impacts to the riverine and regional environments. This paper reports field monitoring of riparian groundwater in the Kouma section of the Yellow River to illustrate the interactions between dam‐regulated river flow and riparian groundwater. The results show that the hydrological condition in riparian zones downstream from the dam has changed from a typical wet–dry cycle to a condition of semi‐permanent dryness, resulting in degradation of the typical attributes and functions of the wetland ecosystem. Hydrological processes in the riparian zone have changed from a complex multiple flooding regime to a simple regime of dominant groundwater drainage towards the river, which only reverses temporarily during the water and sediment regulation period of the dam. Data on groundwater level and groundwater quality show that there are two key points, at ca 200 and 400 m from the river bank, which distinguish zones with different sensitivity to changes of river flow and indicate different interactions between river water and groundwater. The shallow groundwater quality also is negatively affected by the intensive agricultural development that has occurred since the dam was completed. Ecological restoration needs to be carried out to construct a protective natural riparian zone within ca 200 m from the river, this being an ecotone, which is key to the protection of both riparian groundwater and the river. The riparian zone from 200 to 400 m also should be treated as a transitional zone. In addition, ecologically sensitive agriculture and ecotourism organized by local communities would be beneficial in the area beyond 400 m. Copyright © 2011 John Wiley & Sons, Ltd.     

Missing role of groundwater in water and nutrient cycles in the shallow eutrophic lake Kasumigaura,Japan

A process‐based model was developed, NICE‐LAKE (NIES (National Institute for Environmental Studies) Integrated Catchment‐based Ecohydrology), which includes interactions between surface water, canopy, unsaturated water, aquifer, lake and rivers, and used it to model the shallow eutrophic Lake Kasumigaura in Japan. By estimating the spatial distribution of the hydrological cycle, the model shows that groundwater withdrawal greatly affects groundwater distribution and seepage and indirectly influences lake water level. The simulated seepage agrees excellently with the budget‐derived value calculated from the observed groundwater level, lake level and isotope analyses. The model showed that groundwater seepage and groundwater concentrations are important contributors to the eutrophication of Lake Kasumigaura, an important contribution not recognized in previous studies of the lake. Groundwater entering the lake from the north side is contaminated with high concentrations of nitrate and ammonia from intensive pig and cattle raising and cultivated fields. The simulation showed that this high nitrogen load plays an important role in the eutrophication of the lake (the nitrogen load in inflowing groundwater is 30% of river inflow and 4 times that from wastewater treatment plants) in spite of government policies to prevent overland flow of nutrients into the lake. Our results show that NICE‐LAKE is a powerful tool for forecasting how the water quality of the lake will be affected by the (illegal) disposal of animal excreta in the surrounding open fields. Copyright © 2007 John Wiley & Sons, Ltd.     

The impact of well drawdowns on the mixing process of river water and groundwater and water quality in a riverside well field,Northeast China

Riverbank filtration (RBF) has been widely used throughout the world as an effective means to regulate surface water and groundwater resources and pretreat raw water for municipal water supply. The quality of the water from a riverside well field and the mixing ratios of surface water and groundwater is primarily impacted by the hydrodynamic processes in the RBF system. The RBF system is largely controlled by the water exploiting system in addition to the natural hydrologic condition of the river–aquifer system. As one of the most important design parameters of the riverside well field, the drawdown of groundwater level greatly determines the water head differences between the river water and groundwater as well as the field flow net, which subsequently impacts the mixing of river water and groundwater and water quality significantly. This study aimed to improve the understanding of the mixing process between the surface water and groundwater and estimate the impact of the RBF on the mixing ratio of surface water–groundwater and water quality quantitatively. A set of field pumping tests with various groundwater level drawdowns were carried out independently and successively at a riverside field with a single pumping well near the Songhua River in Northeast China in August 2017. During these tests, the water levels and hydrochemical parameters of the Songhua River, the adjacent aquifer, and the pumping well were monitored. The dynamic mixing process of the river water and groundwater and water quality under various drawdown conditions were analysed systematically using analytical methods. The results obtained from Dupuit method and the Mirror Image method in conjunction with the Hydrochemical Tracing method showed that the pumping water directly from the river water reached 60% ± 10% after a steady flow net was established. The larger the proportion of the pumping water captured from the river, the better quality of the pumping water was, because the quality of the river water (only limited to some water quality parameters monitored which were minority) was better than that of the groundwater. The results also showed that total Fe, TDS, total hardness, COD_Mn, and K⁺ were relatively sensitive to the changes of groundwater drawdown, and their concentrations decreased with an increase in the groundwater drawdown. It can be concluded that both the mixing ratio of the surface water and the groundwater and the water quality of the riverside well field can be regulated through adjusting the designed drawdown of the groundwater level, which is helpful for the design and the optimization of the riverside well water intake engineering.     

Identifying spatio-temporal variation and controlling factors of chemistry in groundwater and river water recharged by reclaimed water at Huai River,North China

Reclaimed water is efficiently used to recover the dry river, but river water and groundwater may be impacted considering the water quality. Thus, it is critical to study the factors controlling water chemistry. Samples of reclaimed water, river and groundwater were collected monthly from January to September in 2010, in Huai River (North China). And samples were analyzed for major 15 physio-chemical parameters. Using hierarchical cluster analysis, 9 months are divided into two distinct groups, which show the clear temporal variation. In reclaimed water and river water, one group includes February, while the other includes other months. In shallow and deep groundwater, one group includes months from January to April, while the other encompasses others. Monitoring stations are classified into three groups. Group A with high value of ions and nitrogen (order: NH₄-N > NO₃-N > NO₂-N) includes reclaimed water and river water. Group B with moderate concentration and nitrogen (order: NO₃-N > NH₄-N > NO₂-N) includes all shallow groundwater and one deep groundwater. Group C with the low value and nitrogen (order: NO₃-N > NO₂-N > NH₄-N), includes two deep groundwater. Using multivariate analysis and ionic relationships, river water chemistry is found to be controlled by reclaimed water and evaporation process; chemistry in shallow groundwater and one deep groundwater, with type of Na–Ca(Mg)–HCO₃–Cl, is controlled by dissolution of calcite, carbonate weathering. Additionally, reactions of nitrification, denitrification and cation exchange occur in the infiltration of reclaimed water; chemistry in the other deep groundwater, with type of Ca–Mg–HCO₃–Cl, is controlled by dissolution of calcite, carbonate weathering and denitrification.     

Influence of bedrock groundwater on streamflow characteristics in a volcanic catchment

Groundwater movements in volcanic mountains and their effects on streamflow discharge and representative elementary area (REA) have remained largely unclear. We surveyed the discharge and chemical composition of spring and stream water in two catchments: the Hontani river (NR) catchment (6.6 km²) and the Hosotani river (SR) catchment (4.0 km²) at the southern part of Daisen volcano, Japan. Daisen volcano is a young volcano (17 × 10³ years) at an early stage of erosion. Our study indicated that deep groundwater that moved through thick lava and pyroclastic flows and that could not be explained by shallow movements controlled by surface topography contributed dominantly to streamflow at larger catchment areas. At the NR catchment, the deep groundwater contribution clearly increased at a catchment boundary defined by an area of 3.0 km² and an elevation of 800 m. At the SR catchment, the contribution deep groundwater to the stream also increased suddenly at a boundary threshold of 2.0 and 700 m. Beyond these thresholds, the contributions of deep bedrock groundwater remained constant, indicating that the REA is between 2 and 3 km² at the observed area. These results indicate that the hydrological conditions of base flow were controlled mainly by the deep bedrock groundwater that moved through thick lava and pyroclastic flows in the undissected volcanic body of the upper part of the catchment. Our study demonstrates that deep and long groundwater movements via a deep bedrock layer including thick deposits of volcanic materials at the two catchments on Daisen volcano strongly determined streamflow discharge instead of the mixing of small‐scale hydrological conditions. Copyright © 2015 John Wiley & Sons, Ltd.     

Hydrologic functioning of the deep critical zone and contributions to streamflow in a high‐elevation catchment: Testing of multiple conceptual models

High‐elevation mountain catchments are often subject to large climatic and topographic gradients. Therefore, high‐density hydrogeochemical observations are needed to understand water sources to streamflow and the temporal and spatial behaviour of flow paths. These sources and flow paths vary seasonally, which dictates short‐term storage and the flux of water in the critical zone (CZ) and affect long‐term CZ evolution. This study utilizes multiyear observations of chemical compositions and water residence times from the Santa Catalina Mountains Critical Zone Observatory, Tucson, Arizona to develop and evaluate competing conceptual models of seasonal streamflow generation. These models were tested using endmember mixing analysis, baseflow recession analysis, and tritium model “ages” of various catchment water sources. A conceptual model involving four endmembers (precipitation, soil water, shallow, and deep groundwater) provided the best match to observations. On average, precipitation contributes 39–69% (55 ± 16%), soil water contributes 25–56% (41 ± 16%), shallow groundwater contributes 1–5% (3 ± 2%), and deep groundwater contributes ~0–3% (1 ± 1%) towards annual streamflow. The mixing space comprised two principal planes formed by (a) precipitation‐soil water‐deep groundwater (dry and summer monsoon season samples) and (b) precipitation‐soil water‐shallow groundwater (winter season samples). Groundwater contribution was most important during the wet winter season. During periods of high dynamic groundwater storage and increased hydrologic connectivity (i.e., spring snowmelt), stream water was more geochemically heterogeneous, that is, geochemical heterogeneity of stream water is storage‐dependent. Endmember mixing analysis and ³H model age results indicate that only 1.4 ± 0.3% of the long‐term annual precipitation becomes deep CZ groundwater flux that influences long‐term deep CZ development through both intercatchment and intracatchment deep groundwater flows.     

Influence of groundwater and topography on stream drying in semi-arid headwater streams

Non-perennial streams comprise over half of the global stream network and impact downstream water quality. Although aridity is a primary driver of stream drying globally, surface flow permanence varies spatially and temporally within many headwater streams, suggesting that these complex drying patterns may be driven by topographic and subsurface factors. Indeed, these factors affect shallow groundwater flows in perennial systems, but there has been only limited characterisation of shallow groundwater residence times and groundwater contributions to intermittent streams. Here, we asked how groundwater residence times, shallow groundwater contributions to streamflow, and topography interact to control stream drying in headwater streams. We evaluated this overarching question in eight semi-arid headwater catchments based on surface flow observations during the low-flow period, coupled with tracer-based groundwater residence times. For one headwater catchment, we analysed stream drying during the seasonal flow recession and rewetting period using a sensor network that was interspersed between groundwater monitoring locations, and linked drying patterns to groundwater inputs and topography. We found a poor relationship between groundwater residence times and flowing network extent (R² < 0.24). Although groundwater residence times indicated that old groundwater was present in all headwater streams, surface drying also occurred in each of them, suggesting old, deep flowpaths are insufficient to sustain surface flows. Indeed, the timing of stream drying at any given point typically coincided with a decrease in the contribution from near-surface sources and an increased relative contribution of groundwater to streamflow at that location, whereas the spatial pattern of drying within the stream network typically correlated with locations where groundwater inputs were most seasonally variable. Topographic metrics only explained ~30% of the variability in seasonal flow permanence, and surprisingly, we found no correlation with seasonal drying and down-valley subsurface storage area. Because we found complex spatial patterns, future studies should pair dense spatial observations of subsurface properties, such as hydraulic conductivity and transmissivity, to observations of seasonal flow permanence.     

Influence of partial confinement and Holocene river formation on groundwater flow and dissolution in the Florida carbonate platform

Much of what is known about groundwater circulation and geochemical evolution in carbonate platforms is based on platforms that are fully confined or unconfined. Much less is known about groundwater flow paths and geochemical evolution in partially confined platforms, particularly those supporting surface water. In north‐central Florida, sea level rise and a transition to a wetter climate during the Holocene formed rivers in unconfined portions of the Florida carbonate platform. Focusing on data from the Santa Fe River basin, we show river formation has led to important differences in the hydrological and geochemical evolution of the Santa Fe River basin relative to fully confined or unconfined platforms. Runoff from the siliciclastic confining layer drove river incision and created topographic relief, reorienting the termination of local and regional groundwater flow paths from the coast to the rivers in unconfined portions of the platform. The most chemically evolved groundwater occurs at the end of the longest and deepest flow paths, which discharge near the center of the platform because of incision of the Santa Fe River at the edge of the confining unit. This pattern of discharge of mineralized water differs from fully confined or unconfined platforms where discharge of the most mineralized water occurs at the coast. Mineralized water flowing into the Santa Fe River is diluted by less evolved water derived from shorter, shallower flow paths that discharge to the river downstream. Formation of rivers shortens flow path lengths, thereby decreasing groundwater residence times and allowing freshwater to discharge more quickly to the oceans in the newly formed rivers than in platforms that lack rivers. Similar dynamic changes to groundwater systems should be expected to occur in the future as climate change and sea level rise develop surface water on other carbonate platforms and low lying coastal aquifer systems. Copyright © 2012 John Wiley & Sons, Ltd.     

Using hydrochemical,stable isotope,and river water recharge data to identify groundwater flow paths in a deeply buried karst system

The deeply buried river‐connected Xishan karst aquifer (XKA) in western Beijing, China, has been suffering from diminishing recharge for several decades, which in turn leads to the disappearing of spring water outflows and continuously lowering of groundwater level in the area. Thus, it is important to correctly recognize the groundwater recharge and flow paths for the sustainable development of the XKA. To investigate these issues, the hydrochemical and isotopic compositions are analysed for both surface water and groundwater samples collected over an area of about 280 km². Results show that (a) the river water is characterized by high Na contents; (b) the δ²H and δ¹⁸O values in the river water are distinctively higher than those of groundwater samples, after experiencing the long‐time evaporative enrichment in the upstream reservoir; (c) the Sr concentrations and ⁸⁷Sr/⁸⁶Sr ratios of groundwater clearly indicated the interaction between water and carbonate minerals but excluded the water–silicate interaction; and (d) the groundwater samples in the direct recharge area of the XKA have the lowest Na concentrations and the δ²H and δ¹⁸O values. Based on the large differences in the Na contents and ¹⁸O values of groundwater and surface water, a simple two‐component mixing model is developed for the study area and the fractions of the river water are estimated for groundwater samples. We find that the distribution pattern of the river water fractions in the XKA clearly shows a change of directions in the preferential flow path of the groundwater from its source zone to the discharge area. Overall, our results suggest that the recharged surface water can be a useful evidence for delineating the groundwater flow path in river‐connected karst aquifer. This study improves our understanding of the heterogeneity in karst groundwater systems.     

Patterns and dynamics of river–aquifer exchange with variably-saturated flow using a fully-coupled model

The parallel physically-based surface–subsurface model PARFLOW was used to investigate the spatial patterns and temporal dynamics of river–aquifer exchange in a heterogeneous alluvial river–aquifer system with deep water table. Aquifer heterogeneity at two scales was incorporated into the model. The architecture of the alluvial hydrofacies was represented based on conditioned geostatistical indicator simulations. Subscale variability of hydraulic conductivities (K) within hydrofacies bodies was created with a parallel Gaussian simulation. The effects of subscale heterogeneity were investigated in a Monte Carlo framework. Dynamics and patterns of river–aquifer exchange were simulated for a 30-day flow event. Simulation results show the rapid formation of saturated connections between the river channel and the deep water table at preferential flow zones that are characterized by high conductivity hydrofacies. Where the river intersects low conductivity hydrofacies shallow perched saturated zones immediately below the river form, but seepage to the deep water table remains unsaturated and seepage rates are low. Preferential flow zones, although only taking up around 50% of the river channel, account for more than 98% of total seepage. Groundwater recharge is most efficiently realized through these zones. Subscale variability of K_sat slightly increased seepage volumes, but did not change the general seepage patterns (preferential flow zones versus perched zones). Overall it is concluded that typical alluvial heterogeneity (hydrofacies architecture) is an important control of river–aquifer exchange in rivers overlying deep water tables. Simulated patterns and dynamics are in line with field observations and results from previous modeling studies using simpler models. Alluvial heterogeneity results in distinct patterns and dynamics of river–aquifer exchange with implications for groundwater recharge and the management of riparian zones (e.g. river channel-floodplain connectivity via saturated zones).