A large epeiric methanogenic Bambui sea in the core of Gondwana supercontinent?

Carbon isotope compositions of both sedimentary carbonate and organic matter can be used as key proxies of the global carbon cycle and of its evolution through ...     

Origin of Halite in the Lanping–Simao Basin, Southeastern Tibetan Plateau, China: Evidence from Sr and Cl Isotopes

The Lanping?Simao Basin is located on the southeastern Tibetan Plateau, China, and contains massive evaporites. The origin of evaporites in the basin has been hotly debated because of the strong transformation by tectonic movement. Forty halite samples from borehole MK-3 in the Mengyejing area of the basin were collected and analyzed using XRD, Cl-Sr isotopes and chemical compositions to trace the origin of the evaporites in the basin. The Br × 103/Cl ratios of the halite samples are between 0 and 0.55, most of which are synchronized with the law of seawater evaporation and at the stage of halite precipitation from seawater, indicating that the evaporites are mainly of marine origin. The 87Sr/86Sr ratios range from 0.707489 to 0.711279; after correction, the 87Sr/86Sr 145 Ma ratios range from 0.704721 to 0.707611, equivalent with the 87Sr/86Sr ratios of seawater at 145 Ma, indicating a marine origin. The decay of 87Rb in the evaporite during deposition, change of the depositional environment and the unsealed environment at a later period resulted in the present 87Sr/86Sr ratios of some samples being high. The δ37Cl value compositions range from ?0.38‰ to 0.83‰, which is consistent with the δ37Cl value composition of the world marine halite (?0.6‰ to 0.4‰), further confirming that seawater is the main origin. In addition, the high δ37Cl value of some samples at the boundary of the upper and lower evaporite layers might be related to the influence of δ37Cl-rich brine and the incomplete dissolution of the halite.     

Comprehensive diag”nostic review of the (13)~C-enriched crude oils exemplified by TD2∈ and TZ62S in Tarim Basin,NW China

The crude oils typically from the CambrianLower Ordovician source rocks of Tarim Basin, NW"China, such as TD2 and TZ62S, are13C-enriched with the stable carbon isotopic ratios(VPDB) approaching-28 %.In this paper, the main research viewpoints on this issue are summarized, and combined with results from organic and inorganic carbon isotope stratum curves of the outcrop at the Ya’erdang Mountain in Tarim Basin. In addition, more alternative interpretations are discussed. On one hand, the inverse fractionation features of stable carbon and hydrogen isotopes of these crude oils may imply their protogenous nature. On the other hand, the anisotropy of source rocks and contribution from older stratum source rocks need verifying as well. For the sake of the final resolution of this issue, some further study topics are recommended.     

Did natural fission of 235U in the earth lead to formation of the supercontinent Columbia?

Steady decline in the percentage of 235U in terrestrial uranium made natural fission impossible after about 1.8 Ga.Fission before 1.8 Ga disturbed the lead isotope system at various places worldwide,su...     

Enclosed Extent of the Saline Water and its Constraints on the Sedimentary and Salt Forming Characteristics: A Case Study of the Paleogene Playas in?Hoh Xil Basin

正1 Introduction There is a long period of hot,arid climates in the Jurassic-Neogene,in the eastern of the Neo-Tethys where is been called Western Yunnan—Qiangtang tectonic belt(Zheng et al.,2010).Especially in the Paleogene,under the control of the planetary winds and the north subtropical high pressure belts,a ribbon arid,semi-arid     

The earliest Cambrian UHT metamorphism in the Qaidam block,western China: A record of the final assembly of Greater Gondwana?

The final assembly of Gondwana, known as the late Pan-African orogeny, is characterized by Ediacaran–early Cambrian ultrahigh temperature (UHT) metamorphism, which is widely identified within reconstructed East Gondwana. This distinctive feature likely provides a reliable criterion for identifying new Gondwanan terranes that lack paleo-geomagnetic data. Here we present zircon U–Pb geochronology and phase equilibria calculations for a variety of granulite types newly recognized from western Qaidam, China, which provide the first evidence that the Qaidam block, at least western Qaidam, experienced high-grade metamorphism in excess of 900 °C before/at 540–520 Ma. These UHT metamorphic rocks, similar to many well-known Pan-African UHT metamorphic terranes, is inferred to evolve along a clockwise P–T path that is usually related to collisional orogens. Comparison between new metamorphic zircon U–Pb ages from western Qaidam and the published age data from the UHT metamorphic terranes within East Gondwana suggests that the UHT metamorphic rocks found in western Qaidam similarly records the final assembly of Gondwana. Although the exact paleo-geographical location of the Qaidam block during the Gondwana period is unknown yet because of lacking paleo-geomagnetic data, new Pan-African UHT metamorphic record found in western Qaidam indicates, for the first time, that the Qaidam block is a Gondwanan terrane that split from this semi-supercontinent after the Pan-African orogeny.     

Petrology and Geochemistry of Post-Collisional Early Miocene Volcanism in the Karacada? Area (Central Anatolia, Turkey)

Early Miocene (ca.?21–18 Ma) volcanism in the Karacada? area comprises three groups of volcanic rocks: (1) calcalkaline suite (andesitic to rhyolitic lavas and their pyroclastics), (2) mildly-alkaline suite (alkali basalt, hawaiite, mugearite, benmoreite and trachydacite), and (3) a single trachyandesitic flow unit. Field observations, 40Ar/39Ar ages and geochemical data show that there was a progressive temporal transition from group 1 to 3 in a post-collisional tectonic setting. The calcalkaline suite rocks with medium-K in composition resemble those of subduction-related lavas, whereas the mildly-alkaline suite rocks having a sodic tendency (Na2O/K2O=1.5–3.2) resemble those of within-plate lavas. Incompatible element and Sr-Nd isotopic characteristics of the suites suggest that the lithospheric mantle beneath the Karacada? area was heterogeneously enriched by two processes before collision: (1) enrichment by subduction-related processes, which is important in the genesis of the calcalkaline volcanism, (2) enrichment by small degree melts from the astenosphere, which dominates the mildly alkaline volcanism. Perturbation of the enriched lithosphere by either delamination following collision and uplift or removal of the subducted slab following subduction and collision (i.e., slab breakoff) is the likely mechanism for the initiation of the post-collision volcanism.     

Did prolonged two-stage fragmentation of the supercontinent Kenorland lead to arrested orogenesis on the southern margin of the Superior province?

Recent geochronological investigations reinforce the early suggestion that the upper part of the Paleoproterozoic Huronian Supergroup of Ontario,Canada is present in the Animikie Basin on the south shore of Lake Superior.These rocks,beginning with the glaciogenic Gowganda Formation,are interpreted as passive margin deposits.The absence of the lower Huronian(rift succession) from the Animikie Basin may be explained by attributing the oldest Paleoroterozoic rocks in the Animikie Basin(Chocolay Group)to deposition on the upper plate of a north-dipping detachment fault,which lacks sediments of the rift phase.Following thermal uplift that led to opening of the Huronian Ocean on the south side of what is now the Superior province,renewed uplift(plume activity) caused large-scale gravitational folding of the Huronian Supergroup accompanied by intrusion of the Nipissing diabase suite and Senneterre dikes at about 2.2 Ga.Termination of passive margin sedimentation is normally followed by ocean closure but in the Huronian and Animikie basins there was a long hiatus- the Great Stratigraphic Gap- which lasted for about 350 Ma.This hiatus is attributed to a second prolonged thermal uplift of part of Kenorland that culminated in complete dismemberment of the supercontinent shortly before 2.0 Ga by opening of the Circum-Superior Ocean.These events caused regional uplift(the Great Stratigraphic Gap) and delayed completion of the Huronian Wilson Cycle until a regional compressional tectonic episode,including the Penokean orogeny,belatedly flooded the southern margin of the Superior province with foreland basin deposits,established the limits of the Superior structural province and played an important role in constructing Laurentia.     

Re-Examination of the Oil and Gas Origins in the Kekeya Gas Condensate Field, Northwest China–A Case Study of Hydrocarbon-Source Correlation Using Sophisticated Geochemical Methods

This work discussed the origins, alteration and accumulation processes of the oil and gas in the Kekeya gas condensate field based on molecular compositions, stable carbon isotopes, light hydrocarbons, diamondoid hydrocarbons and biomarker fingerprints. A comparison study is also made between the geochemical characteristics of the Kekeya hydrocarbons and typical marine and terrigenous hydrocarbons of the Tarim Basin. Natural gas from the Kekeya gas condensate field is derived from Middle–Lower Jurassic coal measures while the condensates are derived from Carboniferous–Permian marine source rocks with a higher maturity. In the study area, both natural gas and condensates have experienced severe water washing. A large amount of methane was dissolved into the water, resulting in a decrease in the dryness coefficient. Water washing also makes the carbon isotopic compositions of the natural gas more negative and partially reverse. Considering that the gas maturities are higher than once expected, gas generation intensity in the study area should be much stronger and the gas related to the Jurassic coal measures could promise a greater prospecting potential. As a result of evaporative fractionation, the Kekeya condensates are enriched in saturates and lack aromatics. Evaporative fractionation disguises the original terrigenous characteristics of the light hydrocarbons associated with the natural gas, making it appear marinesourced. Thus, alteration processes should be fully taken into consideration when gas–source correlations are carried out based on light hydrocarbons. With the condensates discovered in the study area all being "migration phase", the pre-salt Cretaceous and Jurassic reservoirs may promise great exploration potential for the "residual phase" hydrocarbons. This research not only is of significance for oil and gas exploration in the southwest Tarim Basin, but also sheds light on the oil/gas-source correlations in general.     

A Middle Paleozoic shear zone in the Sierra de Valle Fértil,Argentina: Records of a continent-arc collision in the Famatinian margin of Gondwana

Geological, petrological and structural observations were obtained along a 30-km-long traverse across a segment of the Valle Fértil shear zone, central-western Argentina. On a regional scale, the shear zone appears as numerous discontinues belts over 25 km in width and is approximately 140 km in length, extended on the western section of the Sierras Valle Fértil – La Huerta mountain range. The steeply dipping shear zone with a vertical mylonitic lineation is composed of amphibolite facies ribbon mylonites and amphibolite to greenschist facies ultramylonites derived from Early Ordovician plutonic and metasedimentary parent rocks. Locally, syn-kinematic retrogression of mylonites formed greenschist facies phyllonites. During the later stages of deformation, unstrained parent rocks, mylonites, ultramylonites and phyllonites were affected by pervasive cataclasis under low greenschist facies conditions associated with localized faulting. One new ⁴⁰Ar/³⁹Ar age on biotite and published ⁴⁰Ar/³⁹Ar ages on amphibole in the shear zone yield an average cooling rate of 6.2 °C/Ma for a time period that crosses the Silurian–Devonian boundary. Since in metasedimentary rocks the youngest zircon's rims dated at 465 Ma marks the beginning of cooling, nearly continuous uplift of rocks within the shear zone occurred over a minimum time span of 55 Ma. During the period of active deformation, dip-slip movement can explain uplift of several kilometers of the Early Ordovician arc crust. The Valle Fértil shear zone, which was formed near above the inferred suture zone between the Famatinian arc and Cuyania microcontinent, is a major structural boundary nucleated within the Early Ordovician crust. The simplest geodynamic model to explain the evolution of the Valle Fértil shear zone involves the collision of the composite Cuyania/Precodillera microcontinent against the Famatinian arc.     

The Shishugou Fauna of the Middle–Late Jurassic Transition Period in the Junggar Basin of Western China

The Middle–Late Jurassic transition period is a critical period for the evolution of terrestrial vertebrates, but the global fossil record from this time is relatively poor. The Shishugou Fauna of this period has recently produced significant fossil remains of dinosaurs and other vertebrate groups, some representing the earliest known members of several dinosaurian groups and other vertebrate groups and some representing the best-known specimens of their group. These discoveries are significant for our understanding of the origin and evolution of several vertebrate lineages. Radiometric dating indicates that the fauna is aged approximately 159–164 Ma. Comparisons with other similarly-aged terrestrial faunas such as Shaximiao and Yanliao show both taxonomic similarities and differences between these faunas and indicate that the Junggar deposits might have preserved the most complete vertebrate fossil record for a Middle–Late Jurassic Laurasian terrestrial fauna.     

Nd-Sr Isotopic Geochemistry of the Late Archean-Paleoproterozoic Granitoids in the Lüliang-Wutai Terrain,North China Craton,and Implications for Petrogenesis

1 Introduction The tectono-thermal evolution of the North China Craton (NCC) in Late Archean to Paleoproterozoic times has long been attractive to many researchers (Wan et al., 2000; Zhao et al., 2000, 2002; Guo et al., 2001; Liu et al., 2002; Zhai and Liu 2003; Zhai, 2004; Yu et al., 2004; Kr?ner et al., 2005; Wilde et al., 2005). Zhao et al. (2000, 2002) proposed a tectono-thermo framework for the evolution of the NCCbased on detailed petrological and geochronological data, and they …     

A Fluid Inclusion Study of Vein-type Copper Mineralization in the East Wulasigou Pb–Zn–Cu Deposit, Altay, Northwestern China

The Wulasigou Cu-Pb-Zn deposit,located 15 km northwest of Altay city in Xinjiang,is one of many Cu-Pb-Zn polymetallic deposits in the Devonian Kelan volcanic-sedimentary basin in southern Altaids.Two mineralizing periods can be distinguished:the marine volcanic sedimentary PbZn mineralization period,and the metamorphic hydrothermal Cu mineralization period,which is further divided into an early bedded foliated quartz vein stage(Q1) and a late sulfide-quartz vein stage(Q2) crosscutting the foliation.Four types of fluid inclusions were recognized in the Q1 and Q2 quartz from the east orebodies of the Wulasigou deposit:H_2O-CO_2 inclusions,carbonic fluid inclusions,aqueous fluid inclusions,and daughter mineral-bearing fluid inclusions.Microthermometric studies show that solid CO_2 melting temperatures(T_(m,CO2)) of H_2O-CO_2 inclusions in Ql are from-62.3℃ to-58.5C,clathrate melting temperatures(T_(m,clath)l) are from 0.5 C to 7.5 C,partial homogenization temperatures(T_(h,CO2)) vary from 3.3℃ to 25.9℃(to liquid),and the total homogenization temperatures(T_(h,tot)) vary from 285℃ to 378℃,with the salinities being 4.9%-15.1%NaCl eqv.and the CO_2-phase densities being 0.50-0.86 g/cm~3.H_2O-CO_2 inclusions in Q2 have T_(m,CO_2) from-61.9℃ to-56.9℃,T_(m,clath)from 1.3℃ to 9.5℃,T_(h,CO2) from 3.4℃ to 28.7℃(to liquid),and T_(h,tot) from 242℃ to 388℃,with the salinities being 1.0%-15.5%NaCl eqv.and the CO_2-phase densities being 0.48-0.89 g/cm~3.The minimum trapping pressures of fluid inclusions in Q1 and Q2 are estimated to be 260-360 MPa and180-370 MPa,respectively.The δ~(34)S values of pyrite from the volcanic sedimentary period vary from2.3‰ to 2.8‰(CDT),and those from the sulfide-quartz veins fall in a narrow range of-1.9‰ to 2.6‰(CDT).The δD values of fluid inclusions in Q2 range from-121.0‰ to-100.8‰(SMOW),and theδ~(18)O_(H2O) values calculated from δ~(18)O of quartz range from-0.2‰ to 8.3‰(SMOW).The δD-δ~(18)O_(H2O)data are close to the magmatic and metamorphic fields.The fluid inclusion and stable isotope data documented in this study indicate that the vein-type copper mineralization in the Wulasigou Pb-Zn-Cu deposit took place in an orogenic-metamorphic enviroment.     

Plant–Arthropod Associations from the Lower Miocene of the Most Basin in Northern Bohemia (Czech Republic): A Preliminary Report

Terrestrial plants and insects currently account for the majority of the Earth's biodiversity, and approximately half of insect species are herbivores. Thus, insects and plants share ancient associations that date back more than 400 Myr. However, investigations of their past interactions are at the preliminary stages in Western Europe. Herein, we present the first results of our study of various feeding damage based on a dataset of nearly 3500 examined plant specimens from the Lower Miocene of the Lagerst?tte Bílina Mine in the Most Basin, Czech Republic. This site provides a unique view of the Neogene freshwater ecosystems. It has long been studied by scientists working in different branches of sedimentology, paleobotany, and paleozoology. The fossils are preserved in three characteristic horizons overlaying the coal seam (Clayey Superseam Horizon, Delta Sandy Horizon, and Lake Clayey Horizon), reflecting paleoenvironmental changes in a short time period of development. The trace fossils are classified as functional feeding groups or “guilds”, without searching for a direct cause or a recent analog host relation. Approximately 23% of specimens of dicotyledonous plant leaves were found to be damaged and associated with some leaf “morphotypes”. Deciduous plant–host taxa, and those with a chartaceous texture typical of riparian habitats, were frequently damaged, such as Populus, recorded with two species Populus zaddachii and Populus populina (57.9% and 31% herbivory levels, respectively), followed by Acer, Alnus, and Carya, averaging almost 30% of damaged leaves/leaflets. There has been evidence of 60 damage types (DT) representing all functional feeding groups recorded at the Bílina Mine, including 12 types of leaf mines and 16 gall-type DT. In total, Lower Miocene of the Lagerst?tte Bílina Mine exhibits a high level of external foliage feeding types (23.7%), and a low level of more specialized DT, such as galls (4.3%) and leaf mines (<1%). A broader comparison based on DT of the main sedimentary environments shows significance supporting different biomes by frequency of damage levels and DT diversities.     

Sedimentary Response of Different Fan Types to the Paleogene–Neogene Basin Transformation in the Kuqa Depression, Tarim Basin, Xinjiang Province

A group of alluvial fans formed in the early Paleogene represent marginal sedimentary facies at the foot of the South Tianshan Mountain, Kuqa Depression, Tarim Basin, Xinjiang province. Two types of fans occurred in the middle–late Paleogene Kumugeliemu and Suweiyi formations: one alluvial, and the other fan delta deposited in a lacustrine setting. Within the early Neogene Jidike Formation, coastal subaqueous fans developed, probably in a deeper water lacustrine setting. The three types of fans are stacked vertically in outcrop with the sequence in ascending order: bottom alluvial, middle fan-delta, and top subaqueous. The subaqueous is a typical coarse-fan deposit occurring in the glutinite member of the Jidike Formation in some wells. Laterally, from the foreland to the lacustrine settings, the distribution pattern of sedimentary facies represents the same three fan types sequentially. The spatial distribution of these fans was controlled by the Paleogene–Neogene Basin transformation, and evolution with different types of fans developed in the Kuqa Depression in response. In the Paleogene, the Kuqa Depression was a rift basin where an alluvial fan was deposited in the foreland setting, which, by early Neogene, became a foreland basin when the lake level changed. With any rise in lake level, fan-deltas migrated from lacustrine to foreland settings, whereas when the lake level fell, fan migration was reversed. In the early Neogene, with increasing slope and rising lake level, fans progressed and covered the previous fan-delta and lacustrine mudstone. Eventually, subaqueous fans developed, forming the present spatial configuration of these three fan types.     

Typical Soft–Sediment Deformation Structures Induced by Freeze/Thaw Cycles: A Case Study of Quaternary Alluvial Deposits in the Northern Qiangtang Basin,Tibetan Plateau

With the objective of establishing a distinction between deformation structures caused by freeze/thaw cycles and those resulting from seismic activity, we studied three well–exposed alluvial deposits in a section at Dogai Coring, northern Qiangtang Basin, Tibetan Plateau. Deformation is present in the form of plastic structures(diapirs, folds and clastic dykes), brittle structures(micro–faults) and cryogenic wedges. These soft–sediment deformation features(except the micro–faults) are mainly cha...     

A thousand years of loneliness? Globalization from the perspective of a city in a European periphery

Most cities face the challenge of increasing global and local change. Much of what has been said about cities in a globalized world has been concerned with large metropolitan cites. It has been postulated that increased competitiveness is the relevant response, and that urban governance has to change from managerialism to entrepeneurialism in order to cope with this challenge. The first part of the paper discusses some aspects of this body of theory, and the relevance for sub-national regional capitals. It also discusses how the scope of strategies depend on changing national and regional policies. The second part uses the case of Trondheim to discuss how these cities perceive and deal with globalization. Four policy options are discussed; the clientist strategy, the competitive strategy, the isolationist strategy and finally the option of doing nothing at all. The article concludes that global challenges will force local government in small cities to forge new strategies, but the preferred option is a clientist strategy rather than an entrepreneurial one, and the scope of strategy is national rather than global. Thus, when dealing with small peripheral cities and globalization, the range of perspectives must be extended beyond entrepreneurialism and competitiveness.     

Recognition of Early Paleozoic Magmatisms in the Supposed Proterozoic Basements of Zhalantun, Great Xing’an Range, NE China

The Zhalantun terrane from the Xing'an massif, northeast China, was used to be considered as Proterozoic basements. However, amounts of detrital zircon ages from the meta-sedimentary rocks deny the existence of Precambrian basements recently. Notably, magmatic rocks were barely reported to limit the exact ages of the Zhalantun basements. In this study, we collected rhyolite, gabbro and quartz diorite for zircon in-situ U-Pb isotopic dating, which yield crystallization ages of ～505 Ma, ～447 Ma and ～125 Ma, respectively. Muscovite schist and siltstone define maximum depositional ages of ～499 Ma and ～489 Ma, respectively. Additionally, these dated supracrustal rocks and plutons also yield ancient detrital/xenocryst zircon ages of ～600–1000 Ma, ～1600–2220 Ma, ～2400 Ma, ～2600–2860 Ma. Based on the whole-rock major and trace element compositions, the ～505 Ma rhyolites display high SiO_2 and alkaline contents, low Fe_2O_3T, TiO_2 and Al_2O_3, and relatively high Mg O and Mg#, which exhibit calc-alkaline characteristics. These rhyolites yield fractionated REE patterns and negative Nb, Ta, Ti, Sr, P and Eu anomalies and positive Zr anomalies. The geochemistry, petrology and Lu-Hf isotopes imply that rhyolites were derived from the partial melting of continental basalt induced by upwelling of sub-arc mantle magmas, and then experienced fractional crystallization of plagioclase, which points to a continental arc regime. The ～447 Ma gabbros exhibit low Si O2 and alkaline contents, high Fe2 O3 T, Ti O2, Mg O and Mg#. They show minor depletions of La and Ce, flat MREE and HREE patterns, and negative Nb, Ta, Zr and Hf anomalies. Both sub-arc mantle and N-MORB-like mantle were involved in the formation of the gabbros, indicative of a probable back-arc basin tectonic setting. Given that, the previously believed Proterozoic supracrustal rocks and several plutons from the Zhalantun Precambrian basements were proved to be Paleozoic to Mesozoic rocks, among which these Paleozoic magmatic rocks were generally related to subduction regime. So far, none Proterozoic rocks have been identified from the Zhalantun Precambrian basement, though some ～600–3210 Ma ancient detrital/xenocryst zircons were reported. Combined with ancient zircon ages and newly reported ～2.5 Ga and ～1.8 Ga granites from the south of the Zhalantun, therefore, the Precambrian rocks probably once exposed in the Zhalantun while they were re-worked and consumed during later long tectonic evolutionary history, resulting in absence of Precambrian rocks in the Zhalantun.     

The mixing of Mesozoic crust-mantle magma is the key to the source of large amounts of gold deposits in the Jiaobei uplift,ChinaSCIEI北大核心CSCD

胶东地区金矿巨量金质来源一直是学界争论的焦点,很难找到有说服力的直接证据。在没有其它更有效的直接证明巨量金质来源的情况下,本文通过胶北隆起主要地质体新鲜岩石大量微量元素地球化学数据的变化规律,间接得出中生代壳幔岩浆的混合反应是巨量金质来源的关键,即郭家岭和伟德山两期壳幔岩浆的混合反应和演化可能是巨量金质来源的主要形成机制,同时更是热量供给源,而玲珑花岗岩可能是少量金质的提供者和主要赋矿地质体。胶东地区金矿主要成矿时间(130～105Ma)与郭家岭(130～125Ma)和伟德山(126～108Ma)两期花岗岩浆演化结晶时间完全吻合,说明其关系密切,岩浆混合反应和冷凝期,岩浆热液上升运移沉淀成矿。该区中生代地质体对早前寒武纪的地球化学环境有一定的继承性,中生代地壳混合了大量地幔物质,Au丰度偏高,平均为1.31×10^-9,为地球化学高背景场。