Vertical and meridional distribution of ethane, acetylene and propane in Saturn’s stratosphere from CIRS/Cassini limb observations

Measuring the spatial distribution of chemical compounds in Saturn’s stratosphere is critical to better understand the planet’s photochemistry and dynamics. Here we present an analysis of infrared spectra in the range 600-1400 cm⁻¹ acquired in limb geometry by the Cassini spacecraft between March 2005 and January 2008. We first determine the vertical temperature profiles from 3 to 0.01 hPa, at latitudes ranging from 70°N to 80°S. We infer a similar meridional temperature gradient at 1-2 hPa as in recent previous studies [Fletcher, L.N., Irwin, P.G.J., Teanby, N.A., Orton, G.S., Parrish, P.D., de Kok, R., Howett, C., Calcutt, S.B., Bowles, N., Taylor, F.W., 2007. Icarus 189, 457-478; Howett, C.J.A., Irwin, P.G.J., Teanby, N.A., Simon-Miller, A., Calcutt, S.B., Fletcher, L.N., de Kok, R., 2007. Icarus 190, 556-572]. We then retrieve the vertical profiles of C₂H₆ and C₂H₂ from 3 to 0.01 hPa and of C₃H₈ around 1 hPa. At 1 hPa, the meridional variation of C₂H₂ is found to follow the yearly averaged solar insolation, except for a strong equatorial mole fraction of 8×10^-7, nearly two times higher than expected. This enhancement in abundance can be explained by the descent of hydrocarbon-rich air, with a vertical wind speed at the equator of 0.25±0.1 mm/s at 1 hPa and 0.4±0.15 mm/s at 0.1 hPa. The ethane distribution is relatively uniform at 1 hPa, with only a moderate 25% increase from 35°S to 80°S. Propane is found to increase from north to south by a factor of 1.9, suggesting that its lifetime may be shorter than Saturn’s year at 1 hPa. At high altitudes (1 Pa), C₂H₂ and C₂H₆ abundances depart significantly from the photochemical model predictions of Moses and Greathouse [Moses, J.I., Greathouse, T.K., 2005. J. Geophys. Res. 110, 9007], except at high southern latitudes (62, 70 and 80°S) and near the equator. The observed abundances are found strongly depleted in the 20-40°S region and enhanced in the 20-30°N region, the latter coinciding with the ring’s shadow. We favor a dynamical explanation for these anomalies.     

Meridional variations of C2H2 and C2H6 in Jupiter's atmosphere from Cassini CIRS infrared spectra

Hydrocarbons such as acetylene (C₂H₂) and ethane (C₂H₆) are important tracers in Jupiter's atmosphere, constraining our models of the chemical and dynamical processes. However, our knowledge of the vertical and meridional variations of their abundances has remained sparse. During the flyby of the Cassini spacecraft in December 2000, the Composite Infrared Spectrometer (CIRS) instrument was used to map the spatial variation of emissions from 10 to 1400 cm⁻¹ (1000-7 μm). In this paper we analyze a zonally averaged set of CIRS spectra taken at the highest (0.48 cm⁻¹) resolution, firstly to infer atmospheric temperatures in the stratosphere at 0.5-20 mbar via the ν₄ band of CH₄, and in the troposphere at 150-400 mbar, via the H₂ absorption at 600-800 cm⁻¹. Stratospheric temperatures at 5 mbar are generally warmer in the north than the south by 7-8 K, while tropospheric temperatures show no such asymmetry. Both latitudinal temperature profiles however do show a pattern of maxima and minima which are largely anti-correlated between the two levels. We then use the derived temperature profiles to infer the vertical abundances of C₂H₂ and C₂H₆ by modeling tropospheric absorption (∼200 mbar) and stratospheric emission (∼5 mbar) in the C₂H₂ν₅ and C₂H₆ν₉ bands, and also emission of the acetylene (ν₄+ν₅)−ν₄ hotband (∼0.1 mbar). Acetylene shows a distinct north-south asymmetry in the stratosphere, with 5 mbar abundances greatest close to 20° N and decreasing from there towards both poles by a factor of ∼4. At 200 mbar in contrast, acetylene is nearly flat at a level of ∼3×¹⁰⁻⁹. Additionally, the abundance gradient of C₂H₂ between 10 and 0.1 mbar is derived, based on interpolated temperatures at 0.1 mbar, and is found to be positive and uniform with latitude to within errors. Ethane at both 5 and 200 mbar shows increasing VMR towards polar regions of ∼1.75 towards 70° N and ∼2.0 towards 70° S. An explanation for the meridional trends is proposed in terms of a combination of photochemistry and dynamics. Poleward, the decreasing UV flux is predicted to decrease the abundances of C₂H₂ and C₂H₆ by factors of 2.7 and 3.5, respectively, at latitude 70°. However, the lifetime of C₂H₆ in the stratosphere (3×¹⁰¹⁰ s at 5 mbar) is much longer than the dynamical timescale for meridional mixing inferred from Comet SL-9 debris (5-50×¹⁰⁸ s), and therefore the rising abundance towards high latitudes likely indicates that meridional mixing dominates over photochemical effects. For C₂H₂, the opposite occurs, with the relatively short photochemical lifetime (3×¹⁰⁷ s), compared to meridional mixing times, ensuring that the expected photochemical trends are visible.     

Meridional distribution of CH3C2H and C4H2 in Saturn’s stratosphere from CIRS/Cassini limb and nadir observations

Limb and nadir spectra acquired by Cassini/CIRS (Composite InfraRed Spectrometer) are analyzed in order to derive, for the first time, the meridional variations of diacetylene (C₄H₂) and methylacetylene (CH₃C₂H) mixing ratios in Saturn’s stratosphere, from 5 hPa up to 0.05 hPa and 80°S to 45°N. We find that the C₄H₂ and CH₃C₂H meridional distributions mimic that of acetylene (C₂H₂), exhibiting small-scale variations that are not present in photochemical model predictions. The most striking feature of the meridional distribution of both molecules is an asymmetry between mid-southern and mid-northern latitudes. The mid-southern latitudes are found depleted in hydrocarbons relative to their northern counterparts. In contrast, photochemical models predict similar abundances at north and south mid-latitudes. We favor a dynamical explanation for this asymmetry, with upwelling in the south and downwelling in the north, the latter coinciding with the region undergoing ring shadowing. The depletion in hydrocarbons at mid-southern latitudes could also result from chemical reactions with oxygen-bearing molecules.Poleward of 60°S, at 0.1 and 0.05 hPa, we find that the CH₃C₂H and C₄H₂ abundances increase dramatically. This behavior is in sharp contradiction with photochemical model predictions, which exhibit a strong decrease towards the south pole. Several processes could explain our observations, such as subsidence, a large vertical eddy diffusion coefficient at high altitudes, auroral chemistry that enhances CH₃C₂H and C₄H₂ production, or shielding from photolysis by aerosols or molecules produced from auroral chemistry. However, problems remain with all these hypotheses, including the lack of similar behavior at lower altitudes.Our derived mean mixing ratios at 0.5 hPa of (2.4 ± 0.3) × 10⁻¹⁰ for C₄H₂ and of (1.1 ± 0.3) × 10⁻⁹ for CH₃C₂H are compatible with the analysis of global-average ISO observations performed by Moses et al. (Moses, J.I., Bézard, B., Lellouch, E., Gladstone, G.R., Feuchtgruber, H., Allen, M. [2000a]. Icarus 143, 244-298). Finally, we provide values for the ratios [CH₃C₂H]/[C₂H₂] and [C₄H₂]/[C₂H₂] that can constrain the coupled chemistry of these hydrocarbons.     

The Titan N/N and C/C isotopic ratios in HCN from Cassini/CIRS

We report the detection of H¹³CN and HC¹⁵N in mid-infrared spectra recorded by the Composite Infrared Spectrometer (CIRS) aboard Cassini, along with the determination of the ¹²C/¹³C and ¹⁴N/¹⁵N isotopic ratios. We analyzed two sets of limb spectra recorded near 13-15° S (Tb flyby) and 83° N (T4 flyby) at 0.5 cm⁻¹ resolution. The spectral range 1210-1310 cm⁻¹ was used to retrieve the temperature profile in the range 145-490 km at 13° S and 165-300 km at 83° N. These two temperature profiles were then incorporated in the atmospheric model to retrieve the abundance profile of H¹²C¹⁴N, H¹³CN and HC¹⁵N from their bands at 713, 706 and 711 cm⁻¹, respectively. The HCN abundance profile was retrieved in the range 90-460 km at 15° S and 165-305 km at 83° N. There is no evidence for vertical variations of the isotopic ratios. Constraining the isotopic abundance profiles to be proportional to the HCN one, we find at 15° S, and at 83° N, two values that are statistically consistent. A combination of these results yields a ¹²C/¹³C value equal to 75±12. This global result, as well as the 15° S one, envelop the value in Titan's methane (82.3±1) [Niemann, H.B., and 17 colleagues, 2005. Nature 438, 779-784] measured at 10° S and is slightly lower than the terrestrial inorganic standard value (89). The ¹⁴N/¹⁵N isotopic ratio is found equal to at 15° S and at 83° N. Combining the two values yields ¹⁴N/¹⁵N = 56 ± 8, which corresponds to an enrichment in ¹⁵N of about 4.9 compared with the terrestrial ratio. These results agree with the values obtained from previous ground-based millimeter observations [Hidayat, T., Marten, A., Bézard, B., Gautier, D., Owen, T., Matthews, H.E., Paubert, G., 1997. Icarus 126, 170-182; Marten, A., Hidayat, T., Biraud, Y., Moreno, R., 2002. Icarus 158, 532-544]. The ¹⁵N/¹⁴N ratio found in HCN is ∼3 times higher than in N₂ [Niemann, H.B., and 17 colleagues, 2005. Nature 438, 779-784], which implies a large fractionation process in the HCN photochemistry.     

Vertical abundance profiles of hydrocarbons in Titan's atmosphere at 15° S and 80° N retrieved from Cassini/CIRS spectra

Limb spectra recorded by the Composite InfraRed Spectrometer (CIRS) on Cassini provide information on abundance vertical profiles of C₂H₂, C₂H₄, C₂H₆, CH₃C₂H, C₃H₈, C₄H₂, C₆H₆ and HCN, along with the temperature profiles in Titan's atmosphere. We analyzed two sets of spectra, one at 15° S (Tb flyby) and the other one at 80° N (T3 flyby). The spectral range 600-1400 cm⁻¹, recorded at a resolution of 0.5 cm⁻¹, was used to determine molecular abundances and temperatures in the stratosphere in the altitude range 100-460 km for Tb and 170-495 km for T3. Both temperature profiles show a well defined stratopause, at around 310 km (0.07 mbar) and 183 K at 13° S, and 380 km (0.01 mbar) with 207 K at 80° N. Near the north pole, stratospheric temperatures are colder and mesospheric temperatures are warmer than near the equator. C₂H₂, C₂H₆, C₃H₈ and HCN display vertical mixing ratio profiles that increase with height at 15° S and 80° N, consistent with their formation in the upper atmosphere, diffusion downwards and condensation in the lower stratosphere, as expected from photochemical models. The CH₃C₂H and C₄H₂ mixing ratios also increase with height at 15° S. But near the north pole, their profiles present an unexpected minimum around 300 km, observed for the first time thanks to the high vertical resolution of the CIRS limb data. C₂H₄ is the only molecule having a vertical abundance profile that decreases with height at 15° S. At 80° N, it also displays a minimum of its mixing ratio around the 0.1-mbar level. For C₆H₆, an upper limit of 1.1 ppb (in the 0.3-10 mbar range) is derived at 15° S, whereas a constant mixing ratio profile of is inferred near the north pole. At 15° S, the vertical profile of HCN exhibits a steeper gradient than other molecules, which suggests that a sink for this molecule exists in the stratosphere, possibly due to haze formation. All molecules display a more or less pronounced enrichment towards the north pole, probably due, in part, to subsidence of air at the north (winter) pole that brings air enriched in photochemical compounds from the upper atmosphere to lower levels.     

Characteristics of Titan's stratospheric aerosols and condensate clouds from Cassini CIRS far-infrared spectra

Four broad spectral features were identified in far-infrared limb spectra from the Cassini Composite Infrared Spectrometer (CIRS), two of which have not been identified before. The features are broader than the spectral resolution, which suggests that they are caused by particulates in Titan's stratosphere. We derive here the spectral properties and variations with altitude for these four features for six latitudes between 65° S and 85° N. Titan's main aerosol is called Haze 0 here. It is present at all wavenumbers in the far-infrared and is found to have a fractional scale height (i.e., the aerosol density scale height divided by the atmospheric density scale height) between 1.5 and 1.7 with a small increase in opacity in the north. A second feature around 140 cm⁻¹ (Haze A) has similar spatial properties to Haze 0, but has a smaller fractional scale height of 1.2-1.3. Both Haze 0 and Haze A show an increase in retrieved abundance below 100 km. Two other features (Haze B around 220 cm⁻¹ and Haze C around 190 cm⁻¹) have a large maximum in their density profiles at 140 and 90 km, respectively. Haze B is much more abundant in the northern hemisphere compared to the southern hemisphere. Haze C also shows a large increase towards the north, but then disappears at 85° N.     

Structure of self-gravity wakes in Saturn's A ring as measured by Cassini CIRS

The CIRS infrared spectrometer onboard the Cassini spacecraft has scanned Saturn's A ring azimuthally from several viewing angles since its orbit insertion in 2004. A quadrupolar asymmetry has been detected in this ring at spacecraft elevations ranging between 16° to 37°. Its fractional amplitude decreases from 22% to 8% from 20° to 37° elevations. The patterns observed in two almost complete azimuthal scans at elevations 20° and 36° strongly favor the self-gravity wakes as the origin of the asymmetry. The elliptical, infinite cylinder model of Hedman et al. [Hedman, M.M., Nicholson, P.D., Salo, H., Wallis, B.D., Buratti, B.J., Baines, K.H., Brown, R.H., Clark, R.N., 2007. Astron. J. 133, 2624-2629] can reproduce the CIRS observations well. Such wakes are found to have an average height-to-spacing ratio H/λ=0.1607±0.0002, a width-over-spacing W/λ=0.3833±0.0008. Gaps between wakes, which are filled with particles, have an optical depth τG=0.1231±0.0005. The wakes mean pitch angle ΦW is 70.70°±0.07°, relative to the radial direction. The comparison of ground-based visible data with CIRS observations constrains the A ring to be a monolayer. For a surface mass density of 40 g cm⁻² [Tiscarino, M.S., Burns, J.A., Nicholson, P.D., Hedman, M.M., Porco, C.C., 2007. Icarus 189, 14-34], the expected spacing of wakes is λ≈60 m. Their height and width would then be H≈10 m and W≈24 m, values that match the maximum size of particles in this ring as determined from ground-based stellar occultations [French, R.G., Nicholson, P.D., 2000. Icarus 145, 502-523].     

Constraining the surface properties of Saturn's icy moons, using Cassini/CIRS emissivity spectra

We have conducted a search for emissivity features in the thermal infrared spectrum of the icy satellites of Saturn, Phoebe, Iapetus, Enceladus, Tethys, and Hyperion, observed by the Composite Infrared Spectrometer (CIRS) on board the Cassini spacecraft. Despite the heterogeneity of the composition of these bodies depicted by Earth-based and Cassini/VIMS observations, the CIRS spectra of all satellites are undistinguishable from black-body spectra, with no detectable emissivity feature. However, several materials, which have been detected on the surface of the same bodies, present emissivity features in the analyzed spectral range. In particular, water ice presents features with sufficient contrast to be detected by CIRS. Here we study the physical causes of the absence of features by simulating the effects of intimate mixtures using models of directional emissivity for optically thick surfaces for different particle sizes and abundances, and porosities. The simulations include a set of materials detected on the Phoebe's surface, like water ice, hydrated silicates, and organics. We find that featureless spectra can be produced in three scenarios: (1) ice particles with large sizes, (2) mixtures of ices dominated by dark contaminants, and (3) small particles with large porosity. Constraints imposed by the NIR spectra of the satellites favors the latter scenario as the more likely explanation to the absence of emissivity features on the icy satellites of Saturn.     

The composition of Titan's stratosphere from Cassini/CIRS mid-infrared spectra

We have analyzed data recorded by the Composite Infrared Spectrometer (CIRS) aboard the Cassini spacecraft during the Titan flybys T0-T10 (July 2004-January 2006). The spectra characterize various regions on Titan from 70° S to 70° N with a variety of emission angles. We study the molecular signatures observed in the mid-infrared CIRS detector arrays (FP3 and FP4, covering roughly the 600-1500 cm⁻¹ spectral range with apodized resolutions of 2.54 or 0.53 cm⁻¹). The composite spectrum shows several molecular signatures: hydrocarbons, nitriles and CO₂. A firm detection of benzene (C₆H₆) is provided by CIRS at levels of about 3.5×¹⁰⁻⁹ around 70° N. We have used temperature profiles retrieved from the inversion of the emission observed in the methane ν₄ band at 1304 cm⁻¹ and a line-by-line radiative transfer code to infer the abundances of the trace constituents and some of their isotopes in Titan's stratosphere. No longitudinal variations were found for these gases. Little or no change is observed generally in their abundances from the south to the equator. On the other hand, meridional variations retrieved for these trace constituents from the equator to the North ranged from almost zero (no or very little meridional variations) for C₂H₂, C₂H₆, C₃H₈, C₂H₄ and CO₂ to a significant enhancement at high northern (early winter) latitudes for HCN, HC₃N, C₄H₂, C₃H₄ and C₆H₆. For the more important increases in the northern latitudes, the transition occurs roughly between 30 and 50 degrees north latitude, depending on the molecule. Note however that the very high-northern latitude results from tours TB-T10 bear large uncertainties due to few available data and problems with latitude smearing effects. The observed variations are consistent with some, but not all, of the predictions from dynamical-photochemical models. Constraints are set on the vertical distribution of C₂H₂, found to be compatible with 2-D equatorial predictions by global circulation models. The D/H ratio in the methane on Titan has been determined from the CH₃D band at 1156 cm⁻¹ and found to be . Implications of this deuterium enrichment, with respect to the protosolar abundance on the origin of Titan, are discussed. We compare our results with values retrieved by Voyager IRIS observations taken in 1980, as well as with more recent (1997) disk-averaged Infrared Space Observatory (ISO) results and with the latest Cassini-Huygens inferences from other instruments in an attempt to better comprehend the physical phenomena on Titan.     

Retrievals of jovian tropospheric phosphine from Cassini/CIRS

On December 30th, 2000, the Cassini-Huygens spacecraft reached the perijove milestone on its continuing journey to the Saturnian System. During an extended six-month encounter, the Composite Infrared Spectrometer (CIRS) returned spectra of the jovian atmosphere, rings and satellites from 10-1400 cm⁻¹ (1000-7 μm) at a programmable spectral resolution of 0.5 to 15 cm⁻¹. The improved spectral resolution of CIRS over previous IR instrument-missions to Jupiter, the extended spectral range, and higher signal-to-noise performance provide significant advantages over previous data sets.CIRS global observations of the mid-infrared spectrum of Jupiter at medium resolution (2.5 cm⁻¹) have been analysed both with a radiance differencing scheme and an optimal estimation retrieval model to retrieve the spatial variation of phosphine and ammonia fractional scale height in the troposphere between 60° S and 60° N at a spatial resolution of 6°. The ammonia fractional scale height appears to be high over the Equatorial Zone (EZ) but low over the North Equatorial Belt (NEB) and South Equatorial Belt (SEB) indicating rapid uplift or strong vertical mixing in the EZ. The abundance of phosphine shows a similar strong latitudinal variation which generally matches that of the ammonia fractional scale height. However while the ammonia fractional scale height distribution is to a first order symmetric in latitude, the phosphine distribution shows a North/South asymmetry at mid latitudes with higher amounts detected at 40° N than 40° S. In addition the data show that while the ammonia fractional scale height at this spatial resolution appears to be low over the Great Red Spot (GRS), indicating reduced vertical mixing above the ∼500 mb level, the abundance of phosphine at deeper levels may be enhanced at the northern edge of the GRS indicating upwelling.     

Temporal variations of Titan’s middle-atmospheric temperatures from 2004 to 2009 observed by Cassini/CIRS

We use five and one-half years of limb- and nadir-viewing temperature mapping observations by the Composite Infrared Radiometer-Spectrometer (CIRS) on the Cassini Saturn orbiter, taken between July 2004 and December 2009 (L_S from 293° to 4°; northern mid-winter to just after northern spring equinox), to monitor temperature changes in the upper stratosphere and lower mesosphere of Titan. The largest changes are in the northern (winter) polar stratopause, which has declined in temperature by over 20 K between 2005 and 2009. Throughout the rest of the mid to upper stratosphere and lower mesosphere, temperature changes are less than 5 K. In the southern hemisphere, temperatures in the middle stratosphere near 1 mbar increased by 1-2 K from 2004 through early 2007, then declined by 2-4 K throughout 2008 and 2009, with the changes being larger at more polar latitudes. Middle stratospheric temperatures at mid-northern latitudes show a small 1-2 K increase from 2005 through 2009. At north polar latitudes within the polar vortex, temperatures in the middle stratosphere show a ∼4 K increase during 2007, followed by a comparable decrease in temperatures in 2008 and into early 2009. The observed temperature changes in the north polar region are consistent with a weakening of the subsidence within the descending branch of the middle atmosphere meridional circulation.     

A multilayer model for thermal infrared emission of Saturn’s rings. III: Thermal inertia inferred from Cassini CIRS

The thermal inertia values of Saturn’s main rings (the A, B, and C rings and the Cassini division) are derived by applying our thermal model to azimuthally scanned spectra taken by the Cassini Composite Infrared Spectrometer (CIRS). Model fits show the thermal inertia of ring particles to be 16, 13, 20, and 11 J m⁻² K⁻¹ s^−1/2 for the A, B, and C rings, and the Cassini division, respectively. However, there are systematic deviations between modeled and observed temperatures in Saturn’s shadow depending on solar phase angle, and these deviations indicate that the apparent thermal inertia increases with solar phase angle. This dependence is likely to be explained if large slowly spinning particles have lower thermal inertia values than those for small fast spinning particles because the thermal emission of slow rotators is relatively stronger than that of fast rotators at low phase and vise versa. Additional parameter fits, which assume that slow and fast rotators have different thermal inertia values, show the derived thermal inertia values of slow (fast) rotators to be 8 (77), 8 (27), 9 (34), 5 (55) J m⁻² K⁻¹ s^−1/2 for the A, B, and C rings, and the Cassini division, respectively. The values for fast rotators are still much smaller than those for solid ice with no porosity. Thus, fast rotators are likely to have surface regolith layers, but these may not be as fluffy as those for slow rotators, probably because the capability of holding regolith particles is limited for fast rotators due to the strong centrifugal force on surfaces of fast rotators. Other additional parameter fits, in which radii of fast rotators are varied, indicate that particles less than ∼1 cm should not occupy more than roughly a half of the cross section for the A, B, and C rings.     

Ion winds in Saturn's southern auroral/polar region

We present profiles of the line-of-sight (l.o.s.) ionospheric wind velocities in the southern auroral/polar region of Saturn. Our velocities are derived from the measurement of Doppler shifting of the H₃⁺ν₂Q(1,0⁻) line at 3.953 microns. The data for this study were obtained using the facility high-resolution spectrometer CSHELL on the NASA Infrared Telescope Facility (IRTF) on Mauna Kea, Hawaii, during the night of February 6, 2003 (UT). The l.o.s. velocity profiles finally derived are consistent with an extended region of the upper atmosphere sub-corotating with the planet: the ion velocities in the inertial reference are only 1/3 of those expected for full planetary corotation. We discuss the results in the light of recent proposals for the kronian magnetosphere, and suggest that, in this region, Saturn's ion winds may be under solar wind control.     

High-resolution spectroscopy of Saturn at 3 microns: CH4, CH3D, C2H2, C2H6, PH3, clouds, and haze

We report observation and analysis of a high-resolution 2.87-3.54 μm spectrum of the southern temperate region of Saturn obtained with NIRSPEC at Keck II. The spectrum reveals absorption and emission lines of five molecular species as well as spectral features of haze particles. The ν₂+ν₃ band of CH₃D is detected in absorption between 2.87 and 2.92 μm; and we derived from it a mixing ratio approximately consistent with the Infrared Space Observatory result. The ν₃ band of C₂H₂ also is detected in absorption between 2.95 and 3.05 μm; analysis indicates a sudden drop in the C₂H₂ mixing ratio at 15 mbar (130 km above the 1 bar level), probably due to condensation in the low stratosphere. The presence of the ν₃+ν₉+ν₁₁ band of C₂H₆ near 3.07 μm, first reported by Bjoraker et al. [Bjoraker, G.L., Larson, H.P., Fink, U., 1981. Astrophys. J. 248, 856-862], is confirmed, and a C₂H₆ condensation altitude of 10 mbar (140 km) in the low stratosphere is determined. We assign weak emission lines within the 3.3 μm band of CH₄ to the ν₇ band of C₂H₆, and derive a mixing ratio of 9±4×¹⁰⁻⁶ for this species. Most of the C₂H₆ 3.3 μm line emission arises in the altitude range 460-620 km (at ∼μbar pressure levels), much higher than the 160-370 km range where the 12 μm thermal molecular line emission of this species arises. At 2.87-2.90 μm the major absorber is tropospheric PH₃. The cloud level determined here and at 3.22-3.54 is 390-460 mbar (∼30 km), somewhat higher than found by Kim and Geballe [Kim, S.J., Geballe, T.R., 2005. Icarus 179, 449-458] from analysis of a low resolution spectrum. A broad absorption feature at 2.96 μm, which might be due to NH₃ ice particles in saturnian clouds, is also present. The effect of a haze layer at about 125 km (∼12 mbar level) on the 3.20-3.54 μm spectrum, which was not apparent in the low resolution spectrum, is clearly evident in the high resolution data, and the spectral properties of the haze particles suggest that they are composed of hydrocarbons.     

Characterising Saturn's vertical temperature structure from Cassini/CIRS

Thermal infrared spectra of Saturn from 10-1400 cm⁻¹ at 15 cm⁻¹ spectral resolution and a spatial resolution of 1°-2° latitude have been obtained by the Cassini Composite Infrared Spectrometer [Flasar, F.M., and 44 colleagues, 2004. Space Sci. Rev. 115, 169-297]. Many thousands of spectra, acquired over eighteen-months of observations, are analysed using an optimal estimation retrieval code [Irwin, P.G.J., Parrish, P., Fouchet, T., Calcutt, S.B., Taylor, F.W., Simon-Miller, A.A., Nixon, C.A., 2004. Icarus 172, 37-49] to retrieve the temperature structure and para-hydrogen distribution over Saturn's northern (winter) and southern (summer) hemispheres. The vertical temperature structure is analysed in detail to study seasonal asymmetries in the tropopause height (65-90 mbar), the location of the radiative-convective boundary (350-500 mbar), and the variation with latitude of a temperature knee (between 150 and 300 mbar) which was first observed in inversions of Voyager/IRIS spectra [Hanel, R., and 15 colleagues, 1981. Science 212, 192-200; Hanel, R., Conrath, B., Flasar, F.M., Kunde, V., Maguire, W., Pearl, J.C., Pirraglia, J., Samuelson, R., Cruikshank, D.P., Gautier, D., Gierasch, P.J., Horn, L., Ponnamperuma, C., 1982. Science 215, 544-548]. Uncertainties due to both the modelling of spectral absorptions (collision-induced absorption coefficients, tropospheric hazes, helium abundance) and the nature of our retrieval algorithm are quantified.Temperatures in the stratosphere near 1 mbar show a 25-30 K temperature difference between the north pole and south pole. This asymmetry becomes less pronounced with depth as the radiative time constant for the atmospheric response increases at deeper pressure levels. Hemispherically-symmetric small-scale temperature structures associated with zonal winds are superimposed onto the temperature asymmetry for pressures greater than 100 mbar. The para-hydrogen fraction in the 100-400 mbar range is greater than equilibrium predictions for the southern hemisphere and parts of the northern hemisphere, and less than equilibrium predictions polewards of 40° N.The temperature knee between 150-300 mbar is larger in the summer hemisphere than in the winter, smaller and higher at the equator, deeper and larger in the equatorial belts and small at the poles. Solar heating on tropospheric haze is proposed as a possible mechanism for this effect; the increased efficiency of ortho- to para-hydrogen conversion in the southern hemisphere is consistent with the presence of larger aerosols in the summer hemisphere, which we demonstrate to be qualitatively consistent with previous studies of Saturn's tropospheric aerosol distribution.     

Phosphine on Jupiter and Saturn from Cassini/CIRS

The global distribution of phosphine (PH₃) on Jupiter and Saturn is derived using 2.5 cm⁻¹ spectral resolution Cassini/CIRS observations. We extend the preliminary PH₃ analyses on the gas giants [Irwin, P.G.J., and 6 colleagues, 2004. Icarus 172, 37-49; Fletcher, L.N., and 9 colleagues, 2007a. Icarus 188, 72-88] by (a) incorporating a wider range of Cassini/CIRS datasets and by considering a broader spectral range; (b) direct incorporation of thermal infrared opacities due to tropospheric aerosols and (c) using a common retrieval algorithm and spectroscopic line database to allow direct comparison between these two gas giants.The results suggest striking similarities between the tropospheric dynamics in the 100-1000 mbar regions of the giant planets: both demonstrate enhanced PH₃ at the equator, depletion over neighbouring equatorial belts and mid-latitude belt/zone structures. Saturn's polar PH₃ shows depletion within the hot cyclonic polar vortices. Jovian aerosol distributions are consistent with previous independent studies, and on Saturn we demonstrate that CIRS spectra are most consistent with a haze in the 100-400 mbar range with a mean optical depth of 0.1 at 10 μm. Unlike Jupiter, Saturn's tropospheric haze shows a hemispherical asymmetry, being more opaque in the southern summer hemisphere than in the north. Thermal-IR haze opacity is not enhanced at Saturn's equator as it is on Jupiter.Small-scale perturbations to the mean PH₃ abundance are discussed both in terms of a model of meridional overturning and parameterisation as eddy mixing. The large-scale structure of the PH₃ distributions is likely to be related to changes in the photochemical lifetimes and the shielding due to aerosol opacities. On Saturn, the enhanced summer opacity results in shielding and extended photochemical lifetimes for PH₃, permitting elevated PH₃ levels over Saturn's summer hemisphere.     

Cassini VIMS observations of latitudinal and hemispheric variations in Saturn’s infrared auroral intensity

The intensity of Saturn’s infrared aurora is investigated using Cassini VIMS images acquired during October 2006–February 2009. Polar and main oval auroral regions were defined in both hemispheres, which extend between 0–10° and 10–25° co-latitude, respectively. Average intensities were computed for these regions and compared. While the northern and southern main oval regions covered a similar range of intensities, the southern main oval was on average more intense by a factor of ∼1.3. The emission from the southern polar region was usually less intense than the main oval emissions, while this was only the case for approximately half of the northern hemisphere images. The northern hemisphere polar region displayed intensities more than twice as high as those in the south and the difference between the two hemispheres was most pronounced on the dayside. In general, more intense polar emissions were accompanied by more intense main oval emissions. Possible explanations for the hemispheric and latitudinal differences are discussed in terms of particle energies and fluxes, ionospheric conductivity, temperature and magnetic field strength.     

The cloud structure of the jovian atmosphere as seen by the Cassini/CIRS experiment

We analyze the thermal infrared spectra of Jupiter obtained by the Cassini-CIRS instrument during the 2000 flyby to infer temperature and cloud density in the jovian stratosphere and upper troposphere. We use an inversion technique to derive zonal mean vertical profiles of cloud absorption coefficient and optical thickness from a narrow spectral window centered at 1392 cm⁻¹ (7.18 μm). At this wavenumber atmospheric absorption due to ammonia gas is very weak and uncertainties in the ammonia abundance do not impact the cloud retrieval results. For cloud-free conditions the atmospheric transmission is limited by the absorption of molecular hydrogen and methane. The gaseous optical depth of the atmosphere is of order unity at about 1200 mbar. This allows us to probe the structure of the atmosphere through a layer where ammonia cloud formation is expected. The results are presented as height vs latitude cross-sections of the zonal mean cloud optical depth and cloud absorption coefficient. The cloud optical depth and the cloud base pressure exhibit a significant variability with latitude. In regions with thin cloud cover (cloud optical depth less than 2), the cloud absorption coefficient peaks at 1.1±0.05 bar, whereas in regions with thick clouds the peak cloud absorption coefficient occurs in the vicinity of 900±50 mbar. If the cloud optical depth is too large the location of the cloud peak cannot be identified. Based on theoretical expectations for the ammonia condensation pressure we conclude that the detected clouds are probably a system of two different cloud layers: a top ammonia ice layer at about 900 mbar covering only limited latitudes and a second, deeper layer at 1100 mbar, possibly made of ammonium hydrosulfide.     

Meridional variations of temperature, C2H2 and C2H6 abundances in Saturn's stratosphere at southern summer solstice

Measurements of the vertical and latitudinal variations of temperature and C₂H₂ and C₂H₆ abundances in the stratosphere of Saturn can be used as stringent constraints on seasonal climate models, photochemical models, and dynamics. The summertime photochemical loss timescale for C₂H₆ in Saturn's middle and lower stratosphere (∼40-10,000 years, depending on altitude and latitude) is much greater than the atmospheric transport timescale; ethane observations may therefore be used to trace stratospheric dynamics. The shorter chemical lifetime for C₂H₂ (∼1-7 years depending on altitude and latitude) makes the acetylene abundance less sensitive to transport effects and more sensitive to insolation and seasonal effects. To obtain information on the temperature and hydrocarbon abundance distributions in Saturn's stratosphere, high-resolution spectral observations were obtained on September 13-14, 2002 UT at NASA's IRTF using the mid-infrared TEXES grating spectrograph. At the time of the observations, Saturn was at a LS≈270°, corresponding to Saturn's southern summer solstice. The observed spectra exhibit a strong increase in the strength of methane emission at 1230 cm⁻¹ with increasing southern latitude. Line-by-line radiative transfer calculations indicate that a temperature increase in the stratosphere of ≈10 K from the equator to the south pole between 10 and 0.01 mbar is implied. Similar observations of acetylene and ethane were also recorded. We find the 1.16 mbar mixing ratio of C₂H₂ at −1° and −83° planetocentric latitude to be and , respectively. The C₂H₂ mixing ratio at 0.12 mbar is found to be at −1° planetocentric latitude and at −83° planetocentric latitude. The 2.3 mbar mixing ratio of C₂H₆ inferred from the data is and at −1° and −83° planetocentric latitude, respectively. Further observations, creating a time baseline, will be required to completely resolve the question of how much the latitudinal variations of C₂H₂ and C₂H₆ are affected by seasonal forcing and/or stratospheric circulation.     

Transient surface liquid in Titan’s polar regions from Cassini

Cassini RADAR images of Titan’s south polar region acquired during southern summer contain lake features which disappear between observations. These features show a tenfold increases in backscatter cross-section between images acquired one year apart, which is inconsistent with common scattering models without invoking temporal variability. The morphologic boundaries are transient, further supporting changes in lake level. These observations are consistent with the exposure of diffusely scattering lakebeds that were previously hidden by an attenuating liquid medium. We use a two-layer model to explain backscatter variations and estimate a drop in liquid depth of approximately 1-m-per-year. On larger scales, we observe shoreline recession between ISS and RADAR images of Ontario Lacus, the largest lake in Titan’s south polar region. The recession, occurring between June 2005 and July 2009, is inversely proportional to slopes estimated from altimetric profiles and the exponential decay of near-shore backscatter, consistent with a uniform reduction of 4 ± 1.3 m in lake depth.Of the potential explanations for observed surface changes, we favor evaporation and infiltration. The disappearance of dark features and the recession of Ontario’s shoreline represents volatile transport in an active methane-based hydrologic cycle. Observed loss rates are compared and shown to be consistent with available global circulation models. To date, no unambiguous changes in lake level have been observed between repeat images in the north polar region, although further investigation is warranted. These observations constrain volatile flux rates in Titan’s hydrologic system and demonstrate that the surface plays an active role in its evolution. Constraining these seasonal changes represents the first step toward our understanding of longer climate cycles that may determine liquid distribution on Titan over orbital time periods.