Detection of new hydrocarbons in Uranus' atmosphere by infrared spectroscopy

Ethane (C₂H₆), methylacetylene (CH₃C₂H or C₃H₄) and diacetylene (C₄H₂) have been discovered in Spitzer 10-20 μm spectra of Uranus, with 0.1-mbar volume mixing ratios of (1.0±0.1)×¹⁰⁻⁸, (2.5±0.3)×¹⁰⁻¹⁰, and (1.6±0.2)×¹⁰⁻¹⁰, respectively. These hydrocarbons complement previously detected methane (CH₄) and acetylene (C₂H₂). Carbon dioxide (CO₂) was also detected at the 7-σ level with a 0.1-mbar volume mixing ratio of (4±0.5)×¹⁰⁻¹¹. Although the reactions producing hydrocarbons in the atmospheres of giant planets start from radicals, the methyl radical (CH₃) was not found in the spectra, implying much lower abundances than in the atmospheres of Saturn or Neptune where it has been detected. This finding underlines the fact that Uranus' atmosphere occupies a special position among the giant planets, and our results shed light on the chemical reactions happening in the absence of a substantial internal energy source.     

Near-infrared adaptive optics imaging of the satellites and individual rings of Uranus

We present the first Earth-based images of several of the individual faint rings of Uranus, as observed with the adaptive optics system on the W.M. Keck II telescope on four consecutive days in October 2003. We derive reflectivities based on multiple measurements of 8 minor moons of Uranus as well as Ariel and Miranda in filters centered at wavelengths of 1.25(J), 1.63(H), and 2.1(Kp) μm. These observations have a phase angle of 1.84°-1.96°. We find that the small satellites are somewhat less bright than in observations made by the HST at smaller phase angles, confirming an opposition surge effect. We calculate albedoes for the ring groups and for each ring separately. We find that the ε ring particles, as well as the particles in the three other ring groups, have albedoes near 0.043 at these phase angles. The equivalent depths of some of the individual rings are different than predicted based upon ring widths from occultation measurements (assuming a constant particle ring brightness); in particular the γ ring is fainter and the η ring brighter than expected. Our results indicate that q, the ratio of ε ring intensity at apoapse vs. periapse, is close to 3.2±0.16. This agrees well with a model that has a filling factor for the ε ring of 0.06 (Karkoschka, 2001, Icarus 151, 78-83). We also determine values of the north to south brightness ratio for the individual rings and find that in most cases they are close to unity.     

The Dark Spot in the atmosphere of Uranus in 2006: Discovery, description, and dynamical simulations

We report the first definitive detection of a discrete dark atmospheric feature on Uranus in 2006 using visible and near-infrared images from the Hubble Space Telescope and the Keck II 10-m telescope. Like Neptune's Great Dark Spots, this Uranus Dark Spot had bright companion features that exhibited considerable variability in brightness and location relative to the Dark Spot. We detected the feature or its bright companions on 16 June (Hubble), 30 July and 1 August (Keck), 23-24 August (Hubble), and 15 October (Keck). The dark feature—detected at latitude ∼28±1° N with an average physical extent of roughly 2° (1300 km) in latitude and 5° (2700 km) in longitude—moved with a nearly constant zonal velocity of , which is roughly 20 m s⁻¹ greater than the average observed speed of bright features at this latitude. The dark feature's contrast and extent varied as a function of wavelength, with largest negative contrast occurring at a surprisingly long wavelength when compared with Neptune's dark features: the Uranus feature was detected out to 1.6 μm with a contrast of −0.07, but it was undetectable at 0.467 μm; the Neptune GDS seen by Voyager exhibited its most prominent contrast of −0.12 at 0.48 μm, and was undetectable longward of 0.7 μm. Computational fluid dynamic simulations of the dark feature on Uranus suggest that structure in the zonal wind profile may be a critical factor in the emergence of large sustained vortices.     

Dynamics of cloud features on Uranus

Near-infrared adaptive optics imaging of Uranus by the Keck 2 telescope during 2003 and 2004 has revealed numerous discrete cloud features, 70 of which were used to extend the zonal wind profile of Uranus up to 60° N. We confirmed the presence of a north-south asymmetry in the circulation [Karkoschka, E., 1998. Science 280, 570-572], and improved its characterization. We found no clear indication of long term change in wind speed between 1986 and 2004, although results of Hammel et al. [Hammel, H.B., Rages, K., Lockwood, G.W., Karkoschka, E., de Pater, I., 2001. Icarus 153, 229-235] based on 2001 HST and Keck observations average ∼10 m/s less westward than earlier and later results, and 2003 observations by Hammel et al. [Hammel, H.B., de Pater, I., Gibbard, S., Lockwood, G.W., Rages, K., 2005. Icarus 175, 534-545] show increased wind speeds near 45° N, which we do not see in our 2003-2004 observations. We observed a wide range of lifetimes for discrete cloud features: some features evolve within ∼1 h, many have persisted at least one month, and one feature near 34° S (termed S34) seems to have persisted for nearly two decades, a conclusion derived with the help of Voyager 2 and HST observations. S34 oscillates in latitude between 32° S and 36.5° S, with a period of ∼1000 days, which may be a result of a non-barotropic Rossby wave. It also varied its longitudinal drift rate between −20°/day and −31°/day in approximate accord with the latitudinal gradient in the zonal wind profile, exhibiting behavior similar to that of the DS2 feature observed on Neptune [Sromovsky, L.A., Limaye, S.S., Fry, P.M., 1993. Icarus 105, 110-141]. S34 also exhibits a superimposed rapid oscillation with an amplitude of 0.57° in latitude and period of 0.7 days, which is approximately consistent with an inertial oscillation.     

Uranus in 2003: Zonal winds, banded structure, and discrete features

Imaging of Uranus in 2003 with the Keck 10-m telescope reveals banded zonal structure and dozens of discrete cloud features at J and H bands; several features in the northern hemisphere are also detectable at K′. By tracking features over four days, we extend the zonal wind profile well into the northern hemisphere. We report the first measurements of wind velocities at latitudes −13°, +19°, and northward of +43°, the first direct wind measurements near the equator, and the highest wind velocity seen yet on Uranus (+218 m/s). At northern mid-latitudes (+20° to +40°), the winds appear to have accelerated when compared to earlier HST and Keck observations; southern wind speeds (−20° to −43°) have not changed since Voyager measurements in 1986. The equator of Uranus exhibits a subtle wave structure, indicated by diffuse patches roughly every 30° in longitude. The largest discrete cloud features on Uranus show complex structure extending over tens of degrees, reminiscent of activity seen around Neptune's Great Dark Spot during the Voyager encounter with that planet. There is no sign of a northern “polar collar” as is seen in the south, but a number of discrete features seen at the “expected” latitudes may signal the early stages of development of a northern collar.     

Mutual orbits and masses of six transneptunian binaries

We present Hubble Space Telescope observations of six binary transneptunian systems: 2000 QL₂₅₁, 2003 TJ₅₈, 2001 XR₂₅₄, 1999 OJ₄, (134860) 2000 OJ₆₇, and 2004 PB₁₀₈. The mutual orbits of these systems are found to have periods ranging from 22 to 137 days, semimajor axes ranging from 2360 to 10500 km, and eccentricities ranging from 0.09 to 0.55. These orbital parameters enable estimation of system masses ranging from 0.2 to 9.7×¹⁰¹⁸ kg. For reasonable assumptions of bulk density (0.5 to 2.0 g cm⁻³), the masses can be combined with visible photometry to constrain sizes and albedos. The resulting albedos are consistent with an emerging picture of the dynamically “Cold” Classical sub-population having relatively high albedos, compared with comparably-sized objects on more dynamically excited orbits.     

Two-micron spectrophotometry of Uranus and its rings

Multiaperture K photometry and 2.0- to 2.5-μm spectrophotometry of Uranus and its ring system are presented. The photometric results are used, together with a previously published measurement, to set limits on the geometric albedos of Uranus and the rings at ～2.2 μm: (0.74 ± 0.02) × 10(su?4) ≤ p_K (Uranus) ≤ (1.5 ± 0.3) × 10^?4, and (2.7 ± 0.6) × 10^?2 ≤ p_K (rings) ≤ (3.4 ± 0.1) × 10^?2. Reflectance spectra of Uranus and Uranus plus rings show features in the planet's spectrum which are attributed to gaseous CH₄ absorption, and a 2.20-μm feature in the combined spectrum which may be due to the rings. This feature is tentatively identified with either the 2.26-μm absorption feature of NH₃ frost, or the 2.2-μm OH band exhibited by certain silicate minerals. The results of JHK photometry of Uranus' satellite, Ariel (U1), indicate that the infrared colors of this object are very similar to those of the satellites U2, U3, and U4.     

First Spitzer observations of Neptune: Detection of new hydrocarbons

We present the first spectra of Neptune taken with the Spitzer Space Telescope, highlighting the high-sensitivity, moderate-resolution 10-20 μm (500-1000 cm⁻¹) spectra. We report the discovery of methylacetylene (CH₃C₂H) and diacetylene (C₄H₂) with derived 0.1-mbar volume mixing ratios of (1.2±0.1)×¹⁰⁻¹⁰ and (3±1)×¹⁰⁻¹² respectively.     

The web of three-planet resonances in the outer Solar System: II. A source of orbital instability for Uranus and Neptune

The motion of the giant planets from Jupiter to Neptune is chaotic with Lyapunov time of approximately 10 Myr. A recent theory explains the presence of this chaos with three-planet mean-motion resonances, i.e. resonances among the orbital periods of at least three planets. We find that the distribution of these resonances with respect to the semi-major axes of all the planets is compatible with orbital instability. In particular, they overlap in a region of 10⁻³ AU with respect to the variation of the semi-major axes of Uranus and Neptune. Fictitious planetary systems with initial conditions in this region can undergo systematic variations of semi-major axes. The true Solar System is marginally in this region, and Uranus and Neptune undergo very slow systematic variations of semi-major axes with speed of order 10⁻⁴ AU/Gyr.     

Revised ab initio models for H2-H2 collision-induced absorption at low temperatures

A revised ab initio calculation of the H₂-H₂ collision-induced absorption results in significant differences compared with the work of J. Borysow et al. [Borysow, J., Trafton, L., Frommhold, L., Birnbaum, G., 1985. Astrophys. J. 296, 644-654] for wavenumbers greater than 600 cm⁻¹ and temperatures below 120 K. The revision has significant influence on the spectra of Uranus and Neptune, and essentially removes the need for models with “super-solar” helium abundances or stratospheric hazes to explain the spectrum of Uranus.     

Photometric variability of Uranus and Neptune, 1950-2004

Photoelectric intermediate-band b and y photometry of Uranus and Neptune obtained at each apparition since 1972, combined with broadband B and V photometry from 1950 to 1966, provide a record of planetary variability covering 2/3 of Uranus' 84-year orbital period and 1/3 of Neptune's 165-year orbital period. Almost all of the data were obtained with a dedicated 21-inch photometric telescope at Lowell Observatory. The data are quite homogeneous, with yearly uncertainties typically smaller than 0.01 mag (1%). The lightcurve of Uranus is sinusoidal with peaks at the solstices. The b amplitude slightly exceeds the expected 0.025 mag purely geometrical variation caused by oblateness as the planetary aspect changes, seen from Earth. The y amplitude is several times larger, indicating a strong equator-to-pole albedo gradient. The lightcurve is asymmetrical with respect to southern solstice, evidence of a temporal albedo variation. Neptune's post-1972 lightcurve exhibits a generally rising trend since 1972 interpreted by Sromovsky et al. [Sromovsky, L.A., Fry, P.M., Limaye, S.S., Baines, K.H., 2003. Icarus 163, 256-261] as a lagged sinusoidal seasonal variation. However, the 1950-1966 lightcurve segments are much fainter than expected, missing the proposed seasonal sinusoid by 0.1-0.2 mag. A major unknown component is therefore needed to explain Neptune's long-term variation. The apparent relationship between Neptune's brightness variation and the 11-year solar cycle seen in cycles 21-22 (1972-1996) has apparently now faded away. Further interpretation of the data in this paper will be found in a companion paper by Hammel and Lockwood [Hammel, H.B., Lockwood, G.W., 2005. Icarus. Submitted for publication].     

Vertical cloud structure of Uranus from UKIRT/UIST observations and changes seen during Uranus’ northern spring equinox from 2006 to 2008

Long-slit spectroscopy observations of Uranus by the United Kingdom Infrared Telescope UIST instrument in 2006, 2007 and 2008 have been used to monitor the change in Uranus’ vertical and latitudinal cloud structure through the planet’s northern spring equinox in December 2007.The observed reflectance spectra in the Long J (1.17-1.31 μm) and H (1.45-1.65 μm) bands, obtained with the slit aligned along Uranus’ central meridian, have been fitted with an optimal estimation retrieval model to determine the vertical cloud profile from 0.1 to 6-8 bar over a wide range of latitudes. Context images in a number of spectral bands were used to discriminate general zonal cloud structural changes from passing discrete clouds. From 2006 to 2007 reflection from deep clouds at pressures between 2 and 6-8 bar increased at all latitudes, although there is some systematic uncertainty in the absolute pressure levels resulting from extrapolating the methane coefficients of Irwin et al. (Irwin, P.G.J., Sromovsky, L.A., Strong, E.K., Sihra, K., Teanby, N.A., Bowles, N., Calcutt, S.B., Remedios, J.J. [2006] Icarus, 181, 309-319) at pressures greater than 1 bar, as noted by Tomasko et al. and Karkoschka and Tomasko (Tomasko, M.G., Bezard, B., Doose, L., Engel, S., Karkoschka, E. [2008] Planet. Space Sci., 56, 624-647; Karkoschka, E., Tomasko, M. [2009] Icarus). However, from 2007 to 2008 reflection from these clouds throughout the southern hemisphere and from both northern and southern mid-latitudes (30° N,S) diminished. As a result, the southern polar collar at 45°S has diminished in brightness relative to mid-latitudes, a similar collar at 45°N has become more prominent (e.g. Rages, K.A., Hammel, H.B., Sromovsky, L. [2007] Bull. Am. Astron. Soc., 39, 425; Sromovsky, L.A., Fry, P.M., Ahue, W.M., Hammel, H.B., de Pater, I., Rages, K.A., Showalter, M.R., van Dam, M.A. [2008] vol. 40 of AAS/Division for Planetary Sciences Meeting Abstracts, pp. 488-489; Sromovsky, L.A., Ahue, W.K.M., Fry, P.M., Hammel, H.B., de Pater, I., Rages, K.A., Showalter, M.R. [2009] Icarus), and the lowering reflectivity from mid-latitudes has left a noticeable brighter cloud zone at the equator (e.g. Sromovsky, L.A., Fry, P.M. [2007] Icarus, 192, 527-557;Karkoschka, E., Tomasko, M. [2009] Icarus). For such substantial cloud changes to have occurred in just two years suggests that the circulation of Uranus’ atmosphere is much more vigorous and/or efficient than is commonly thought. The composition of the main observed cloud decks between 2 and 6-8 bar is unclear, but the absence of the expected methane cloud at 1.2-1.3 bar (Lindal, G.F., Lyons, J.R., Sweetnam, D.N., Eshleman, V.R., Hinson, D.P. [1987] J. Geophys. Res., 92, 14987-15001) is striking (as previously noted by, among others, Sromovsky, L.A., Irwin, P.G.J., Fry, P.M. [2006] Icarus, 182, 577-593; Sromovsky, L.A., Fry, P.M. [2007] Icarus, 192, 527-557; Sromovsky, L.A., Fry, P.M. [2008] Icarus, 193, 252-266; Karkoschka, E., Tomasko, M. [2009] Icarus) and suggests that cloud particles may be considerably different from pure condensates and may be linked with stratospheric haze particles drizzling down from above, or that tropospheric hazes are generated near the methane condensation level and then drizzle down to deep pressures as suggested by Karkoschka and Tomasko (Karkoschka, E., Tomasko, M. [2009] Icarus).The retrieved cloud structures were also tested for different assumptions of the deep methane mole fraction, which Karkoschka and Tomasko (Karkoschka, E., Tomasko, M. [2009] Icarus) find may vary from ∼1-2% in polar regions to perhaps as much as 4% equatorwards of 45°N,S. We found that such variations did not significantly affect our conclusions.     

Evidence for temporal change at Uranus' south pole

Analysis of Hubble Space Telescope images of Uranus taken between 1994 and 2002 shows evidence for temporal changes in zonal brightness patterns in the south polar region. Between 1994 and 2002, a relatively bright ring developed near 70° S. The pole itself, which was the brightest area of the southern hemisphere in 1994, has become relatively dark. The polar collar at 45° S has also become brighter relative to the rest of the southern polar region. Comparison of images through different filters suggests that the change is occurring at pressures of 2-4 bars in the atmosphere. A change at this depth is consistent with radio measurements which indicate seasonal variability in Uranus' deep atmosphere. Disk-integrated photometry at visible wavelengths also exhibits variability on seasonal (∼?decades) timescales. The observed changes are not predicted by existing dynamical models of Uranus' atmosphere.     

Uranus’ cloud structure and seasonal variability from Gemini-North and UKIRT observations

Observations of Uranus were made in September 2009 with the Gemini-North telescope in Hawaii, using both the NIFS and NIRI instruments. Observations were acquired in Adaptive Optics mode and have a spatial resolution of approximately 0.1″.NIRI images were recorded with three spectral filters to constrain the overall appearance of the planet: J, H-continuum and CH₄(long), and long slit spectroscopy measurements were also made (1.49-1.79 μm) with the entrance slit aligned on Uranus’ central meridian. To acquire spectra from other points on the planet, the NIFS instrument was used and its 3″ × 3″ field of view stepped across Uranus’ disc. These observations were combined to yield complete images of Uranus at 2040 wavelengths between 1.476 and 1.803 μm.The observed spectra along Uranus central meridian were analysed with the NEMESIS retrieval tool and used to infer the vertical/latitudinal variation in cloud optical depth. We find that the 2009 Gemini data perfectly complement our observations/conclusions from UKIRT/UIST observations made in 2006-2008 and show that the north polar zone at 45°N has continued to steadily brighten while that at 45°S has continued to fade. The improved spatial resolution of the Gemini observations compared with the non-AO UKIRT/UIST data removes some of the earlier ambiguities with our previous analyses and shows that the opacity of clouds deeper than the 2-bar level does indeed diminish towards the poles and also reveals a darkening of the deeper cloud deck near the equator, perhaps coinciding with a region of subduction. We find that the clouds at 45°N,S lie at slightly lower pressures than the clouds at more equatorial latitudes, which suggests that they might possibly be composed of a different condensate, presumably CH₄ ice, rather than H₂S or NH₃ ice, which is assumed for the deeper cloud. In addition, analysis of the centre-to-limb curves of both the Gemini/NIFS and earlier UKIRT/UIST IFU observations shows that the main cloud deck has a well-defined top, and also allows us to better constrain the particle scattering properties.Overall, Uranus appeared to be less convectively active in 2009 than in the previous 3 years, which suggests that now the northern spring equinox (which occurred in 2007) is passed the atmosphere is settling back into the quiescent state seen by Voyager 2 in 1986. However, a number of discrete clouds were still observed, with one at 15°N found to lie near the 500 mb level, while another at 30°N, was seen to be much higher at near the 200 mb level. Such high clouds are assumed to be composed of CH₄ ice.     

Methane on Uranus: The case for a compact CH4 cloud layer at low latitudes and a severe CH4 depletion at high-latitudes based on re-analysis of Voyager occultation measurements and STIS spectroscopy

Lindal et al. (Lindal, G.F., Lyons, J.R., Sweetnam, D.N., Eshleman, V.R., Hinson, D.P. [1987]. J. Geophys. Res. 92 (11), 14987-15001) presented a range of temperature and methane profiles for Uranus that were consistent with 1986 Voyager radio occultation measurements of refractivity versus altitude. A localized refractivity slope variation near 1.2 bars was interpreted to be the result of a condensed methane cloud layer. However, models fit to near-IR spectra found particle concentrations much deeper in the atmosphere, in the 1.5-3 bar range (Sromovsky, L.A., Irwin, P.G.J., Fry, P.M. [2006]. Icarus 182, 577-593; Sromovsky, L.A., Fry, P.M. [2010]. Icarus 210, 211-229; Irwin, P.G.J., Teanby, N.A., Davis, G.R. [2010]. Icarus 208, 913-926), and a recent analysis of STIS spectra argued for a model in which aerosol particles formed diffusely distributed hazes, with no compact condensation layer (Karkoschka, E., Tomasko, M. [2009]. Icarus 202, 287-309). To try to reconcile these results, we reanalyzed the occultation observations with the He volume mixing ratio reduced from 0.15 to 0.116, which is near the edge of the 0.033 uncertainty range given by Conrath et al. (Conrath, B., Hanel, R., Gautier, D., Marten, A., Lindal, G. [1987]. J. Geophys. Res. 92 (11), 15003-15010). This allowed us to obtain saturated mixing ratios within the putative cloud layer and to reach above-cloud and deep methane mixing ratios compatible with STIS spectral constraints. Using a 5-layer vertical aerosol model with two compact cloud layers in the 1-3 bar region, we find that the best fit pressure for the upper compact layer is virtually identical to the pressure range inferred from the occultation analysis for a methane mixing ratio near 4% at 5°S. This strongly argues that Uranus does indeed have a compact methane cloud layer. In addition, our cloud model can fit the latitudinal variations in spectra between 30°S and 20°N, using the same profiles of temperature and methane mixing ratio. But closer to the pole, the model fails to provide accurate fits without introducing an increasingly strong upper tropospheric depletion of methane at increased latitudes, in rough agreement with the trend identified by Karkoschka and Tomasko (Karkoschka, E., Tomasko, M. [2009]. Icarus 202, 287-309).     

The methane abundance and structure of Uranus' cloud bands inferred from spatially resolved 2006 Keck grism spectra

Grism spectra of Uranus obtained at the Keck Observatory in 2006, using the NIRC2 instrument and adaptive optics, provide new constraints on the vertical structure of Uranus' cloud bands and on the volume mixing ratio of methane. The best model fits to H-band spectra (1.49-1.635 μm) are found for a methane volume mixing ratio of 1.0 ± 0.25% for latitudes near 43° S and 1-1.6% for latitudes of 12° S and 33° N. Analysis of the J-band spectra are confused by discrepancies between short-wave and long-wave sides of the 1.28 μm window region. The short-wave side of the window (1.23-1.30 μm) is best fit with 1.6% CH₄, but if the fitted spectral range is extended to include the long-wave side of the window (1.2-1.34 μm), the best fit CH₄ mixing ratio is 4% or more, although many small scale spectral features are poorly fit over this range even at high methane mixing ratios, suggesting that models of methane opacity may be inconsistent in this spectral region. Most of the latitudinal variability of the H-band spectra can be fit with clouds near 2-3 and 6-8 bar, with cloud reflectivity of the deeper layer increasing from ∼2% at 33° N to 3-4% in the southern hemisphere. This layer is most likely made of H₂S particles and appears weakly reflective because it is optically thin and possibly also contaminated by absorbing materials. The reflectivity of the 2-3-bar cloud increases from 0.5% at 33° N to ∼1% at the bright band centered near 43° S, where the upper cloud is a little higher (pressure is 10% lower) and ∼25% more reflective than at nearby latitudes. The bright band is also associated with lowering of the deep cloud pressure, by ∼1.4 bar. The bright band parameters are roughly consistent with those obtained from 1975 disk-averaged spectra, obtained when the southern hemisphere was more exposed to the Sun. The lack of significant cloud particle contributions near 1.2 bar, where occultation results suggested a methane cloud, is confirmed by both spectra and HST imaging observations.     

Flowing afterglow studies of temperature dependencies for electron dissociative recombination of HCNH, CH3CNH and CH3CH2CNH and their symmetrical proton-bound dimers

A study has been made using a variable temperature flowing afterglow Langmuir probe technique (VT-FALP) to determine the equilibrium temperature dependencies of the dissociative electron-ion recombination of the protonated cyanide ions (RCNH⁺, where R=H, CH₃ and C₂H₅) and their symmetrical proton-bound dimers (RCNH⁺NCR). The power law temperature dependencies of the recombination coefficients, α_e, over the temperature range 180 to 600 K for the protonated ions are α_e(T)(cm³ s⁻¹)=3.5±0.5×10⁻⁷ (300/T)^1.38 for HCNH⁺, α_e(T)=3.4±0.5×10⁻⁷ (300/T)^1.03 for CH₃CNH⁺, and α_e(T)=4.6±0.7×10⁻⁷ (300/T)^0.81 for CH₃CH₂CNH⁺. The equivalent values for the proton-bound dimers are α_e(T)(cm³ s⁻¹)=2.4±0.4×10⁻⁶(300/T)^0.5 for (HCN)₂H⁺ to α_e(T)=2.8±0.4×10⁻⁶(300/T)^0.5 for (CH₃CN)₂H⁺, and α_e(T)=2.3±0.3×10⁻⁶(300/T)^0.5 for (CH₃CH₂CN)₂H⁺. The relevance of these data to molecular synthesis in the interstellar medium and the Titan ionosphere are discussed.     

Jupiter's hydrocarbon polar brightening: Discovery of 3-micron line emission from south polar CH4, C2H2, and C2H6

Jupiter exhibits bright H⁺₃ auroral arcs at 3-4 microns that cool the hot (>1000 K) ionosphere above the ∼¹⁰−7 bar level through the infrared bands of this trace constituent. Below the ¹⁰−7 bar level significant cooling proceeds through infrared active bands of CH₄, C₂H₂, and C₂H₆. We report the discovery of 3-micron line emission from these hydrocarbon species in spectra of the jovian south polar region obtained on April 18 and 20, 2006 (UT) with CGS4 on the United Kingdom Infrared Telescope. Estimated cooling rates through these molecules are 7.5×¹⁰−3, 1.4×¹⁰−3, and , respectively, for a total nearly half that of H⁺₃. We derive a temperature of 450 ± 50 K in the ¹⁰−7-¹⁰−5 bar region from the C₂H₂ lines.     

Laboratory kinetics of C2H radical reactions with ethane, propane, and n-butane at T = 96-296 K: implications for Titan

The kinetics of the reactions of C₂H radical with ethane (k₁), propane (k₂), and n-butane (k₃) are studied over the temperature range of T = 96-296 K with a pulsed Laval nozzle apparatus that utilizes a pulsed laser photolysis-chemiluminescence technique. The C₂H decay profiles in the presence of both the alkane reactant and O₂ are monitored by the CH(A²Δ) chemiluminescence tracer method. The results, together with available literature data, yield the following Arrhenius expressions: k₁(T) = (0.51 ± 0.06) × 10⁻¹⁰ exp[(−76 ± 30)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-800 K), k₂(T) = (0.98 ± 0.32) × 10⁻¹⁰exp[(−71 ± 60)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-361 K), and k₃(T) = (1.23 ± 0.26) × 10⁻¹⁰ cm³ molecule⁻¹ s⁻¹ (T = 96-297 K). At T = 296 K, k₁ is measured as a function of total pressure and has little or no pressure dependence. The results from this work support a direct hydrogen abstraction mechanism for the title reactions. Implications to the atmospheric chemistry of Titan are discussed.     

Removal of Titan's noble gases by their trapping in its haze

Titan's haze, formed by photolysis of C₂H₂, C₂H₄ and HCN, was found experimentally to trap Ar, Kr and Xe with efficiencies of 3.5 × 10⁻⁴, 1.9 × 10⁻³ and 6.5 × 10⁻² [noble gas atom]/[carbon atom] in the polymer, respectively. The rate of aerosol formation and settling down of 3 × 10⁻¹³ kg m⁻² s⁻¹, as inferred from our experiments on CH₄ photolysis in the far UV [Podolak, M., Bar-Nun, A., 1979. Icarus 39, 272-276], is sufficient to reduce the mixing ratios of ³⁶Ar and ⁴⁰Ar to their low values of (2.8 ± 0.3) × 10⁻⁷ and (4.3 ± 0.1) × 10⁻³, respectively, and those of Kr and Xe to below the detection limit of 10⁻⁸.