The Planetary Fourier Spectrometer (PFS) onboard the European Mars Express mission

The Planetary Fourier Spectrometer (PFS) for the Mars Express mission is an infrared spectrometer optimised for atmospheric studies. This instrument has a short wave (SW) channel that covers the spectral range from 1700 to (1.2-) and a long-wave (LW) channel that covers 250- (5.5-). Both channels have a uniform spectral resolution of . The instrument field of view FOV is about 1.6^° (FWHM) for the Short Wavelength channel (SW) and 2.8^° (FWHM) for the Long Wavelength channel (LW) which corresponds to a spatial resolution of 7 and 12 km when Mars is observed from an height of 250  km. PFS can provide unique data necessary to improve our knowledge not only of the atmosphere properties but also about mineralogical composition of the surface and the surface-atmosphere interaction.The SW channel uses a PbSe detector cooled to 200-220 K while the LW channel is based on a pyroelectric (L_iT_aO₃) detector working at room temperature. The intensity of the interferogram is measured every 150 nm of physical mirrors displacement, corresponding to 600 nm optical path difference, by using a laser diode monochromatic light interferogram (a sine wave), whose zero crossings control the double pendulum motion. PFS works primarily around the pericentre of the orbit, only occasionally observing Mars from large distances. Each measurements take 4 s, with a repetition time of 8.5 s. By working roughly 0.6 h around pericentre, a total of 330 measurements per orbit will be acquired 270 looking at Mars and 60 for calibrations. PFS is able to take measurements at all local times, facilitating the retrieval of surface temperatures and atmospheric vertical temperature profiles on both the day and the night side.     

Global thermal inertia and surface properties of Mars from the MGS mapping mission

We present a new high-resolution map of thermal inertia derived from observations of planetary brightness temperature by the Mars Global Surveyor (MGS) Thermal Emission Spectrometer (TES) obtained during the entire MGS primary mapping mission. Complete seasonal coverage provides a nearly global view of Mars, including the polar regions, at a spatial resolution of approximately 3 km. Our map of nighttime thermal-bolometer-based thermal inertia covers approximately 60% of the surface between 80° S and 80° N latitudes. We confirm the global pattern of high and low thermal inertia seen in lower resolution mapping efforts and provide greater detail concerning a third surface unit with intermediate values of both thermal inertia and albedo first identified by Mellon et al. 2000, Icarus 148, 437-455. Several smaller regional units with distinct characteristics are observed. Most notably, a unit of low thermal inertia () and low-to-intermediate albedo (0.09-0.22) dominates the region polewards of 65° S. We consider possible causes for these characteristics and conclude that a low-density mantle formed by desiccation of a previously ice-rich near-surface layer is the most likely explanation for the observed thermophysical properties. Global comparison of thermal inertia and elevation shows that high and low thermal inertia values can be found over a broad range of elevation, with only low values (30-) occurring at the highest elevations and the highest values occurring only at lower elevations. However, the lowest values () are found only at lower elevations, implying that the distribution of low thermal inertia material is not solely controlled by atmospheric pressure and the trapping of fines at high elevations. A new estimate of thermal inertia for the Viking and Pathfinder landing sites helps establish an important link between surface characteristics observed in situ and those derived from remote-sensing data.     

Shocked plagioclase signatures in Thermal Emission Spectrometer data of Mars

The extensive impact cratering record on Mars combined with evidence from SNC meteorites suggests that a significant fraction of the surface is composed of materials subjected to variable shock pressures. Pressure-induced structural changes in minerals during high-pressure shock events alter their thermal infrared spectral emission features, particularly for feldspars, in a predictable fashion. To understand the degree to which the distribution and magnitude of shock effects influence martian surface mineralogy, we used standard spectral mineral libraries supplemented by laboratory spectra of experimentally shocked bytownite feldspar [Johnson, J.R., Hörz, F., Christensen, P., Lucey, P.G., 2002b. J. Geophys. Res. 107 (E10), doi:10.1029/2001JE001517] to deconvolve Thermal Emission Spectrometer (TES) data from six relatively large (>50 km) impact craters on Mars. We used both TES orbital data and TES mosaics (emission phase function sequences) to study local and regional areas near the craters, and compared the differences between models using single TES detector data and 3×2 detector-averaged data. Inclusion of shocked feldspar spectra in the deconvolution models consistently improved the rms errors compared to models in which the spectra were not used, and resulted in modeled shocked feldspar abundances of >15% in some regions. However, the magnitudes of model rms error improvements were within the noise equivalent rms errors for the TES instrument [Hamilton V., personal communication]. This suggests that while shocked feldspars may be a component of the regions studied, their presence cannot be conclusively demonstrated in the TES data analyzed here. If the distributions of shocked feldspars suggested by the models are real, the lack of spatial correlation to crater materials may reflect extensive aeolian mixing of martian regolith materials composed of variably shocked impact ejecta from both local and distant sources.     

Apparent thermal inertia and the surface heterogeneity of Mars

Thermal inertia derivation techniques generally assume that surface properties are uniform at horizontal scales below the footprint of the observing instrument and to depths of several decimeters. Consequently, surfaces with horizontal or vertical heterogeneity may yield apparent thermal inertia which varies with time of day and season. To investigate these temporal variations, we processed three Mars years of Mars Global Surveyor Thermal Emission Spectrometer observations and produced global nightside and dayside seasonal maps of apparent thermal inertia. These maps show broad regions with diurnal and seasonal differences up to 200 J m⁻² K⁻¹s^−1/2 at mid-latitudes (60° S to 60° N) and 600 J m⁻² K⁻¹s^−1/2 or greater in the polar regions. We compared the seasonal mapping results with modeled apparent thermal inertia and created new maps of surface heterogeneity at 5° resolution, delineating regions that have thermal characteristics consistent with horizontal mixtures or layers of two materials. The thermal behavior of most regions on Mars appears to be dominated by layering, with upper layers of higher thermal inertia (e.g., duricrusts or desert pavements over fines) prevailing in mid-latitudes and upper layers of lower thermal inertia (e.g., dust-covered rock, soils with an ice table at shallow depths) prevailing in polar regions. Less common are regions dominated by horizontal mixtures, such as those containing differing proportions of rocks, sand, dust, and duricrust or surfaces with divergent local slopes. Other regions show thermal behavior that is more complex and not well-represented by two-component surface models. These results have important implications for Mars surface geology, climate modeling, landing-site selection, and other endeavors that employ thermal inertia as a tool for characterizing surface properties.     

Investigation of water vapor on Mars with PFS/SW of Mars Express

New insight into the seasonal, diurnal and spatial distribution of water vapor on Mars has been obtained from analyzing the spectra of the short-wavelength channel (SW) of the Planetary Fourier Spectrometer (PFS) onboard Mars Express. The processed dataset, recorded between January 2004 and April 2005, covers the seasons from LS=331° of Mars Year 26 to LS=196° of the following year. In this period the mean column density around vernal equinox was 8.2 pr. μm. The maximum values during northern summer were about 65 pr. μm, located around 75° N latitude with a longitudinally inhomogeneous distribution. Regarding the atmospheric transport, the majority of polar water vapor remains in the north polar region while only about a quarter is transported southward. Geographically there are two water vapor maxima visible, over Arabia Terra and the Tharsis plateau, that are most likely caused both by atmosphere-ground interaction and by atmospheric circulation. A comparison with other instruments generally shows a good agreement, only the SPICAM results are systematically lower. Compared to the results from the PFS long-wavelength channel the results of this work are slightly higher. A strong discrepancy is visible northward of about 50° N during the northern summer that is possibly explained by a non-uniform vertical H₂O mixing. In particular, a confinement of the water to the lower few kilometers yields a much better agreement between the retrieved column densities of the two PFS channels.     

Observations of CO in the atmosphere of Mars with PFS onboard Mars Express

We have analyzed spectra of CO recorded with the instrument PFS onboard Mars Express in the (1-0) band. The dataset we used ranges in time from January until June 2004 (L_S=331^°.17 until L_S=51^°.61; end of Mars Year 26, beginning of Mars Year 27). The aim of this work was to determine the amplitude of the CO mixing ratio departures from the mean globally averaged value currently admitted (8±3×10^-4) [Kaplan, L.D., Connes, J., Connes, P., 1969. Carbon monoxide in the martian atmosphere. Astron. J. 157, L187-L192] as a function of season, local time and location on the planet. We therefore processed the data from 90 calibrated orbits. The globally averaged CO mixing ratio value we derive from our dataset, 11.1×10^-4, is compatible with the range found by Kaplan et al. [1969. Carbon monoxide in the martian atmosphere. Astron. J. 157, L187-L192], although somewhat higher than the “standard” value. However, the CO mixing ratio we retrieve exhibits large variations (roughly between 3×10^-4 and 18×10^-4). Such relative variations have been used on a statistical basis to derive main trends as a function of latitude for three L_S ranges: 331-360^°, 0-30^° and 30-52^°. For the first L_S range, we seem to have an enhancement of the CO mixing ratio towards the northern latitudes, probably linked to the CO₂ condensation in winter on the north polar cap. The situation for the two other L_S ranges is not so clear, mainly as we lack data on the southern hemisphere. We roughly agree with the work of Krasnopolsky [2007. Long-term spectroscopic observations of Mars using IRTF/CSHELL: mapping of O2 dayglow, CO and search for CH4. Icarus 190, 93-102] for L_S=331-360^°, thus confirming the effect of seasonal condensation of CO₂ on the north polar cap, but we have no agreement for other seasons.     

Thermal behavior of horizontally mixed surfaces on Mars

Current methods for deriving thermal inertia from spacecraft observations of planetary brightness temperature generally assume that surface properties are uniform for any given observation or co-located set of observations. As a result of this assumption and the nonlinear relationship between temperature and thermal inertia, sub-pixel horizontal heterogeneity may yield different apparent thermal inertia at different times of day or seasons. We examine the effects of horizontal heterogeneity on Mars by modeling the thermal behavior of various idealized mixed surfaces containing differing proportions of either dust, sand, duricrust, and rock or slope facets at different angles and azimuths. Latitudinal effects on mixed-surface thermal behavior are also investigated. We find large (several 100 J m⁻² K⁻¹ s^−1/2) diurnal and seasonal variations in apparent thermal inertia even for small (∼10%) admixtures of materials with moderately contrasting thermal properties or slope angles. Together with similar results for layered surfaces [Mellon, M.T., Putzig, N.E., 2007. Lunar Planet. Sci. XXXVIII. Abstract 2184], this work shows that the effects of heterogeneity on the thermal behavior of the martian surface are substantial and may be expected to result in large variations in apparent thermal inertia as derived from spacecraft instruments. While our results caution against the over-interpretation of thermal inertia taken from median or average maps or derived from single temperature measurements, they also suggest the possibility of using a suite of apparent thermal inertia values derived from single observations over a range of times of day and seasons to constrain the heterogeneity of the martian surface.     

Mars Exploration Rover candidate landing sites as viewed by THEMIS

The analysis of six landing sites that were candidates for the two NASA Mars Exploration Rovers (MER) benefited from recently available image data from the Thermal Emission Imaging Spectrometer (THEMIS) onboard the 2001 Mars Odyssey spacecraft. The combination of daytime and nighttime thermal infrared images from THEMIS supplemented by additional data sets has lead to new or expanded insights into the nature of each landing site. In Meridiani Planum, a layer of lighter-toned, higher thermal inertia material is observable just below the hematite-bearing layer. Gusev Crater displays a more complex stratigraphy than previously observed, including an upper layer with lobate margins. The highest inertia unit of southern Isidis Planitia is confined to topographic lows in the rim/basin margin and does not appear to be due to highland material transported onto the basin floor. The enigmatic, ovoid, blocky terrain on the floor of Melas Chasma displays higher thermal inertia than its surroundings, an indication that it contains coarser or more indurated material than the adjacent aeolian bedforms. The myriad channels of Athabasca Valles display distinctive thermal signatures despite the presence of a bright layer of dust covering the region. The presence of alluvial fans produced from spur-and-gulley erosion of the walls of Eos Chasma demonstrates that mass movements have occurred following the canyon scouring floods.     

Derivation of martian surface slope characteristics from directional thermal infrared radiometry

Directional thermal infrared measurements of the martian surface is one of a variety of methods that may be used to characterize surface roughness and slopes at scales smaller than can be obtained by orbital imagery. Thermal Emission Spectrometer (TES) emission phase function (EPF) observations show distinct apparent temperature variations with azimuth and emission angle that are consistent with the presence of warm, sunlit and cool, shaded slopes at typically ∼0.1 m scales. A surface model of a Gaussian distribution of azimuth independent slopes (described by θ-bar) is combined with a thermal model to predict surface temperature from each viewing angle and azimuth of the TES EPF observation. The models can be used to predict surface slopes using the difference in measured apparent temperature from 2 separate 60-70° emission angle observations taken ∼180° in azimuth relative to each other. Most martian surfaces are consistent with low to moderate slope distributions. The slope distributions display distinct correlations with latitude, longitude, and albedo. Exceptionally smooth surfaces are located at lower latitudes in both the southern highlands as well as in high albedo dusty terrains. High slopes are associated with southern high-latitude patterned ground and north polar sand dunes. There is little apparent correlation between high resolution imagery and the derived θ-bar, with exceptions such as duneforms. This method can be used to characterize potential landing sites by assuming fractal scaling behavior to meter scales. More precisely targeted thermal infrared observations from other spacecraft instruments are capable of significantly reducing uncertainty as well as reducing measurement spot size from 10s of kilometers to sub-kilometer scales.     

Annual survey of water vapor behavior from the OMEGA mapping spectrometer onboard Mars Express

We present here the annual behavior of atmospheric water vapor on Mars, as observed by the OMEGA spectrometer on board Mars Express during its first martian year. We consider all the different features of the cycle of water vapor: temporal evolution, both at a seasonal and at a diurnal scale; longitudinal distribution; and the vertical profile, through the variations in the saturation height. We put our results into the context of the current knowledge on the water cycle through a systematic comparison with the already published datasets. The seasonal behavior is in very good agreement with past and simultaneous retrievals both qualitatively and quantitatively, within the uncertainties. The average water vapor abundance during the year is ∼10 pr. μm, with an imbalance between northern and southern hemisphere, in favor of the first. The maximum of activity, up to 60 pr. μm, occurs at high northern latitudes during local summer and shows the dominance of the northern polar cap within the driving processes of the water cycle. A corresponding maximum at southern polar latitudes during the local summer is present, but less structured and intense. It reaches ∼25 pr. μm at its peak. Global circulation has some influence in shaping the water cycle, but it is less prominent than the results from previous instruments suggest. No significant correlation between water vapor column density and local hour is detected. We can constrain the amount of water vapor exchanged between the surface and the atmosphere to few pr. μm. This is consistent with recent results by OMEGA and PFS-LW. The action of the regolith layer on the global water cycle seems to be minor, but it cannot be precisely constrained. The distribution of water vapor on the planet, after removing the topography, shows the already known two-maxima system, over Tharsis and Arabia Terra. However, the Arabia Terra increase is quite fragmented compared with previous observations. A deep zone of minimum separates the two regions. The saturation height of water vapor is mainly governed by the variations of insolation during the year. It is confined within 5-15 km from the surface at aphelion, while in the perihelion season it stretches up to 55 km of altitude.     

Observations of non-LTE emission at 4-5 microns with the planetary Fourier spectrometer abord the Mars Express mission

We report on PFS-MEX (Planetary Fourier Spectrometer on board Mars Express) limb observations of the non-Local Thermodynamic Equilibrium emission by CO and CO₂ isotopic molecules. The CO emission is observed peaking at altitudes lower than the CO₂ emission peak. Two orbits have been considered, which explore latitudes from 75 to 15° N, located in local time at 11:30 and 06:40, and with Ls=138° and 168°, respectively. In general in the season considered (northern summer) the emission intensity increases going to lower latitudes. The peak emission height is also decreasing with decreasing latitude. The CO₂ isotopic molecules are emitting radiance out of proportion with respect to the normal isotopic abundance, which surely indicates a strong contribution from a large number of much weaker CO₂ bands, a result that will demand careful theoretical modeling. By comparison with Hitran data base we can identify, among the emitting bands, the second hot band for the 626 and 636 molecule, while for the 628 and 627 emission from the third hot bands are very possible. Other minor bands or lines are also observed in emission for the first time in Mars. In one of the two orbits considered, the orbit 1234 of MEX, we also observe at altitudes 80-85 km scattered radiation, with indication of CO₂ ice aerosols as scattering centers. At the same altitude the Pathfinder descending measurements show a temperature that allows CO₂ condensation. Pathfinder measurements were at 03:00 local time, while our observations are for orbit 1234 showing CO₂ ice signature at 11:30 local time. These non-LTE limb emissions, with their unprecedented spectral resolution in this portion of the near infrared and their sensitivity and geographical coverage, will represent in our opinion an excellent data set for testing current theoretical models of the martian upper atmosphere.     

Observation of the hydrogen corona with SPICAM on Mars Express

A series of seven dedicated Lyman-α observations of exospheric atomic hydrogen in the martian corona were performed in March 2005 with the ultraviolet spectrometer SPICAM on board Mars Express. Two types of observations are analyzed, observations at high illumination (for a solar zenith angle SZA equal to 30°) and observations at low illumination (for a solar zenith angle equal to 90° (terminator), and near the south pole). The measured Lyman-α emission is interpreted as purely resonant scattering of solar photons. Because the Lyman-α emission is optically thick, we use a forward model to analyze this data. Below the exobase, the hydrogen density is described by a diffusive model and above the exobase, it follows Chamberlain's approach without satellite particles. For different hydrogen density profiles between 80 and 50,000 km, the volume emission rates are computed by solving the radiative transfer equation. Such an approach has been used to analyze the Mariner 6, 7 exospheric Lyman-α data during the late 1960s. A reasonable fit of the set of observations is obtained assuming an exobase temperature between 200 and 250 K and an exobase density of ∼1-4 × 10⁵ cm⁻³ in good agreement with photochemical models. However, when considering the average exospheric temperature of 200 K measured by other methods [Leblanc, F., Chaufray, J.Y., Witasse, O., Lilensten, J., Bertaux, J.-L., 2006a. J. Geophys. Res. 111 (E9), doi:10.1029/2005JE002664. E09S11; Leblanc, F., Chaufray, J.-Y., Bertaux, J.-L., 2007. Geophys. Res. Lett. 34, doi:10.1029/2006GL028437. L02206; Bougher, S.W., Engel, S., Roble, R.G., Foster, B., 2000. J. Geophys. Res. 105, 17669-17692; Mazarico, E., Zuber, M.T., Lemoine, F.G., Smith, D.E., 2007. J. Geophys. Res. 112, doi:10.1029/2006JE002734. E05014] a supplementary hot population is needed above the exobase to reconcile Lyman-α measurements with these previous measurements, particularly for the observations at low SZA. In this case, the densities and temperatures at the exobase for the two populations are 1.0±0.2×¹⁰⁵ cm⁻³ and T=200 K and 1.9±0.5×¹⁰⁴ cm⁻³ and T>500 K for the cold and hot populations respectively at low SZA. At high SZA, the densities and temperatures are equal to 2±0.4×¹⁰⁵ cm⁻³ and T=200 K and n=1.2±0.5×¹⁰⁴ cm⁻³ and T>500 K. These high values of the hot hydrogen component are not presently supported by the theory. Moreover, it is important to underline that the two population model remains relatively poorly constrained by the limited range of altitude covered by the present set of SPICAM measurements and cannot be unambiguously identified because of the global uncertainty of our model and of SPICAM measurements. For a one population solution, an average water escape rate of 7.5 × 10⁻⁴ precipitable μm/yr is estimated, yielding a lifetime of 13,000 years for the average present water vapor content of 10 precipitable microns.     

The magnitude and albedo of Mars

A comprehensive set of magnitudes obtained between 1954 and 2006 are analyzed. The martian brightness and its variations are characterized empirically at UBVRI wavelengths. Geometrical factors including phase angle, orbital longitude and rotation angle are distinguished from geophysical factors including dust storms and changing albedo features. The phase function indicates a brightness surge near opposition at all wavelengths except possibly in the U band. The color indices reveal increased reddening with phase angle. No significant brightness difference between morning and evening hemisphere observations is indicated with the possible exception of the I band. There is no conclusive evidence for inter-annual brightness variation during the years from 1991 to 2006 when abundant photometry is available. Major dust storms caused brightness excesses that were strongest in the R band at an average of 0.15 mag more luminous than the empirical model for dust-free conditions. The storm of 2001 produced a rapid increase at the onset followed by a slower decline, while the 2003–2004 event show a more gradual increase. The return to normal brightness was linear in magnitude for both storms. Brightness excesses at longer wavelengths were about 0.20 to 0.25 mags at the peak of the 2001 storm. The observed geometric albedo of Mars is 0.059±0.001 in U, 0.089±0.001 in B, 0.170±0.002 in V, 0.289±0.003 in R, and 0.330±0.003 in I. The corresponding albedo values for all five colors exceed those recorded in the literature, with larger percentage increases at shorter wavelengths.     

Comparison of HIPWAC and Mars Express SPICAM observations of ozone on Mars 2006-2008 and variation from 1993 IRHS observations

Ozone is a tracer of photochemistry in the atmosphere of Mars and an observable used to test predictions of photochemical models. We present a comparison of retrieved ozone abundances on Mars using ground-based infrared heterodyne measurements by NASA Goddard Space Flight Center’s Heterodyne Instrument for Planetary Wind And Composition (HIPWAC) and space-based Mars Express Spectroscopy for the Investigation of the Characteristics of the Atmosphere of Mars (SPICAM) ultraviolet measurements. Ozone retrievals from simultaneous measurements in February 2008 were very consistent (0.8 μm-atm), as were measurements made close in time (ranging from <1 to >8 μm-atm) during this period and during opportunities in October 2006 and February 2007. The consistency of retrievals from the two different observational techniques supports combining the measurements for testing photochemistry-coupled general circulation models and for investigating variability over the long-term between spacecraft missions. Quantitative comparison with ground-based measurements by NASA/GSFC’s Infrared Heterodyne Spectrometer (IRHS) in 1993 reveals 2-4 times more ozone at low latitudes than in 2008 at the same season, and such variability was not evident over the shorter period of the Mars Express mission. This variability may be due to cloud activity.     

Light-toned layered deposits in Juventae Chasma, Mars

We examine hypotheses for the formation of light-toned layered deposits in Juventae Chasma using a combination of data from Mars Global Surveyor's Mars Orbiter Camera (MOC), Mars Orbiter Laser Altimeter (MOLA), and Thermal Emission Spectrometer (TES), as well as Mars Odyssey's Thermal Emission Imaging System (THEMIS). We divide Juventae Chasma into geomorphic units of (i) chasm wall rock, (ii) heavily cratered hummocky terrain, (iii) a mobile and largely crater-free sand sheet on the chasm floor, (iv) light-toned layered outcrop (LLO) material, and (v) chaotic terrain. Using surface temperatures derived from THEMIS infrared data and slopes from MOLA, we derive maps of thermal inertia, which are consistent with the geomorphic units that we identify. LLO thermal inertias range from ∼400 to 850 J m⁻² K⁻¹ s^−1/2. Light-toned layered outcrops are distributed over a remarkably wide elevation range () from the chasm floor to the adjacent plateau surface. Geomorphic features, the absence of small craters, and high thermal inertia show that the LLOs are composed of sedimentary rock that is eroding relatively rapidly in the present epoch. We also present evidence for exhumation of LLO material from the west wall of the chasm, within chaotic and hummocky terrains, and within a small depression in the adjacent plateau. The data imply that at least some of the LLO material was deposited long before the adjacent Hesperian plateau basalts, and that Juventae Chasma underwent, and may still be undergoing, enlargement along its west wall due to wall rock collapse, chaotic terrain evolution, and exposure and removal of LLO material. The new data allow us to reassess possible origins of the LLOs. Gypsum, one of the minerals reported elsewhere as found in Juventae Chasma LLO material, forms only at low temperatures () and thus excludes a volcanic origin. Instead, the data are consistent with either multiple occurrences of lacustrine or airfall deposition over an extended period of time prior to emplacement of Hesperian lava flows on the plateau above the chasm.     

Assessing the limits of the Modified Gaussian Model for remote spectroscopic studies of pyroxenes on Mars

We investigate the ability to refine pyroxene composition and modal abundance from laboratory and remotely acquired spectra. Laboratory data including the martian meteorites, Shergotty, Zagami, MIL03346, and ALH84001 as well as additional pyroxene-rich spectra obtained from the OMEGA (Observatoire pour la Minéralogie, l'Eau, les Glaces, et l'Activité) spectrometer for Mars are characterized using the Modified Gaussian Model (MGM), a spectral deconvolution method developed by Sunshine et al. [Sunshine, J.M., Pieters, C.M., Pratt, S., 1990. J. Geophys. Res. 95, 6955-6966]. We develop two sensitivity tests to assess the extent to which the MGM can consistently predict (1) pyroxene composition and (2) modal abundance for a compositionally diverse suite of pyroxene spectra. Results of the sensitivity tests indicate that the MGM can be appropriately applied to remote spectroscopic measurements of extraterrestrial surfaces and can estimate pyroxene composition and relative abundance within a derived uncertainty. Deconvolved band positions for laboratory spectra of the meteorites Shergotty and Zagami are determined within ±17 nm while remotely acquired OMEGA spectra are defined within ±50 nm. These results suggest that absolute compositions can be uniquely derived from laboratory pyroxene-rich spectra and non-uniquely derived from the remote measurements of OMEGA at this time. While relative pyroxene chemistries are not assessed from OMEGA measurements at this time, relative pyroxene abundances are estimated using a normalized band strength ratio between the low-calcium (LCP) and high-calcium (HCP) endmember components and are constrained to ±10%. The fraction of LCP in a two-pyroxene mixture is the derived value from the normalized band strength ratio, LCP/(LCP + HCP). This calculation for relative abundance is robust in the presence of up to 10-15% olivine. Deconvolution results from the OMEGA spectra indicate that the ancient terrain in the Syrtis Major region is uniquely enriched in LCP (59±10% LCP) relative to HCP while the volcanics of Syrtis Major are uniquely enriched in HCP (39±10% LCP).     

Geologic context of in situ rocky exposures in Mare Serpentis, Mars: Implications for crust and regolith evolution in the cratered highlands

Global acquisition of infrared spectra and high-resolution visible and infrared imagery has enabled the placement of compositional information within stratigraphic and geologic context. Mare Serpentis, a low albedo region located northwest of Hellas Basin, is rich in spectral and thermophysical diversity and host to numerous isolated exposures of in situ rocky material. Most martian surfaces are dominated by fine-grained particulate materials that bear an uncertain compositional and spatial relationship to their source. Thus location and characterization of in situ rock exposures is important for understanding the origin of highland materials and the processes which have modified those materials. Using spectral, thermophysical and morphologic information, we assess the local and regional stratigraphy of the Mare Serpentis surface in an effort to reconstruct the geologic history of the region. The martian highlands in Mare Serpentis are dominated by two interspersed surface units, which have distinct compositional and thermophysical properties: (1) rock-dominated surfaces relatively enriched in olivine and pyroxene, and depleted in high-silica phases, and (2) sediment or indurated material depleted in olivine and pyroxene, with relatively higher abundance of high-silica phases. This is a major, previously unrecognized trend which appears to be pervasive in the Mare Serpentis region and possibly in other highland areas. The detailed observations have led us to form two hypotheses for the relationship between these two units: either (1) they are related through a widespread mechanical and/or chemical alteration process, where less-mafic plains materials are derived from the mafic bedrock, but have been compositionally altered in the process of regolith formation, or (2) they are stratigraphically distinct units representing separate episodes of upper crust formation. Existing observations suggest that the second scenario is more likely. In this scenario, plains materials represent older, degraded, and possibly altered, “basement” rock, whereas the rocky exposures represent later additions to the crust and are probably volcanic in origin. These hypotheses should be further testable with decimeter-resolution imagery and meter-resolution short wavelength infrared spectra.     

Extensive hydrated silica materials in western Hellas Basin,Mars

Near-infrared spectral data indicate the presence of hydrated, poorly crystalline silica where high bulk silica contents have been previously identified in Hellas Basin. No other aqueous phases are identified in these regions and the deposits may be nearly pure. The silica-bearing surfaces are sporadically exposed along a 650 km stretch of the western basin rim within a limited elevation range and display a variety of surface textures suggesting that the materials have been reworked, but not transported large distances. The high abundances and lack of associated aqueous phases indicate that high water to rock ratios were present in the region during the Noachian period but without elevated temperatures or for durations necessary for quartz diagenesis. The silica-bearing materials may have formed via direct precipitation from silica saturated groundwater sources, although other formation mechanisms are also plausible.     

Yearly and seasonal variations of low albedo surfaces on Mars in the OMEGA/MEx dataset: Constraints on aerosols properties and dust deposits

The time variations of spectral properties of dark martian surface features are investigated using the OMEGA near-IR dataset. The analyzed period covers two Mars years, spanning from early 2004 to early 2008 (includes the 2007 global dust event). Radiative transfer modeling indicates that the apparent albedo variations of low to mid-latitude dark regions are consistent with those produced by the varying optical depth of atmospheric dust as measured simultaneously from the ground by the Mars Exploration Rovers. We observe only a few significant albedo changes that can be attributed to surface phenomena. They are small-scaled and located at the boundaries between bright and dark regions. We then investigate the variations of the mean particle size of aerosols using the evolution of the observed dark region spectra between 1 and 2.5 μm. Overall, we find that the observed changes in the spectral slope are consistent with a mean particle size of aerosols varying with time between 1 and 2 μm. Observations with different solar zenith angles make it possible to characterize the aerosol layer at different altitudes, revealing a decrease of the particle size of aerosols as altitude increases.