Hydrocarbon lakes on Titan

The Huygens Probe detected dendritic drainage-like features, methane clouds and a high surface relative humidity (∼50%) on Titan in the vicinity of its landing site [Tomasko, M.G., and 39 colleagues, 2005. Nature 438, 765-778; Niemann, H.B., and 17 colleagues, 2005. Nature 438, 779-784], suggesting sources of methane that replenish this gas against photo- and charged-particle chemical loss on short (10-100) million year timescales [Atreya, S.K., Adams, E.Y., Niemann, H.B., Demick-Montelara, J.E., Owen, T.C., Fulchignoni, M., Ferri, F., Wilson, E.H., 2006. Planet. Space Sci. In press]. On the other hand, Cassini Orbiter remote sensing shows dry and even desert-like landscapes with dunes [Lorenz, R.D., and 39 colleagues, 2006a. Science 312, 724-727], some areas worked by fluvial erosion, but no large-scale bodies of liquid [Elachi, C., and 34 colleagues, 2005. Science 308, 970-974]. Either the atmospheric methane relative humidity is declining in a steady fashion over time, or the sources that maintain the relative humidity are geographically restricted, small, or hidden within the crust itself. In this paper we explore the hypothesis that the present-day methane relative humidity is maintained entirely by lakes that cover a small part of the surface area of Titan. We calculate the required minimum surface area coverage of such lakes, assess the stabilizing influence of ethane, and the implications for moist convection in the atmosphere. We show that, under Titan's surface conditions, methane evaporates rapidly enough that shorelines of any existing lakes could potentially migrate by several hundred m to tens of km per year, rates that could be detected by the Cassini orbiter. We furthermore show that the high relative humidity of methane in Titan's lower atmosphere could be maintained by evaporation from lakes covering only 0.002-0.02 of the whole surface.     

Titan's 3-micron spectral region from ISO high-resolution spectroscopy

The near-infrared spectrum of Titan, Saturn's largest moon and one of the Cassini/Huygens' space mission primary targets, covers the 0.8 to 5 micron region in which it shows several weak CH₄ absorption regions, and in particular one centered near 2.75 micron. Due to the interference of telluric absorption, only part of this window region (2.9-3.1 μm) has previously been observed from the ground [Noll, K.S., Geballe, T.R., Knacke, R., Pendleton, F., Yvonne, J., 1996. Icarus 124, 625-631; Griffith, C.A., Owen, T., Miller, G.A., Geballe, T., 1998. Nature 395, 575-578; Griffith, C.A., Owen, T., Geballe, T.R., Rayner, J., Rannou, P., 2003. Science 300, 628-630; Geballe, T.R., Kim, S.J., Noll, K.S., Griffith, C.A., 2003. Astrophys. J. 583, L39-L42]. We report here on the first spectroscopic observations of Titan covering the whole 2.4-4.9 μm region by two instruments on board the Infrared Space Observatory (ISO) in 1997. These observations show the 2.75-μm window in its complete extent for the first time. In this study we have also used a high-resolution Titan spectrum in the 2.9-3.6 μm region taken with the Keck [Geballe, T.R., Kim, S.J., Noll, K.S., Griffith, C.A., 2003. Astrophys. J. 583, L39-L42; Kim, S.J., Geballe, T.R., Noll, K.S., Courtin, R., 2005. Icarus 173, 522-532] to infer information on the atmospheric parameters (haze extinction, single scattering albedo, methane abundance, etc.) by fitting the methane bands with a detailed microphysical model of Titan's atmosphere (updated from Rannou, P., McKay, C.P., Lorenz, R.D., 2003. Planet. Space Sci. 51, 963-976). We have included in this study an updated version of a database for the CH₄ absorption coefficients [STDS, Wenger, Ch., Champion, J.-P., 1998. J. Quant. Spectrosc. Radiat. Transfer 59, 471-480. See also http://www.u-bourgogne.fr/LPUB/TSM/sTDS.html for latest updates; Boudon, V., Champion, J.-P., Gabard, T., Loëte, M., Michelot, F., Pierre, G., Rotger, M., Wenger, Ch., Rey, M., 2004. J. Mol. Spectrosc. 228, 620-634]. For the atmosphere we find that (a) the haze extinction profile that best matches the data is one with higher (by 40%) extinction in the atmosphere with respect to Rannou et al. (2003) down to about 30 km where a complete cut-off occurs; (b) the methane mixing ratio at Titan's surface cannot exceed 3% on a disk-average basis, yielding a maximum CH₄ column abundance of 2.27 km-am in Titan's atmosphere. From the derived surface albedo spectrum in the 2.7-3.08 micron region, we bring some constraints on Titan's surface composition. The albedo in the center of the methane window varies from 0.01 to 0.08. These values, compared to others reported in the other methane windows, show a strong compatibility with the water ice spectrum in the near-infrared. Without confirming its existence from this work alone, our data then appear to be compatible with water ice. A variety of other ices, such as CO₂, NH₃, tholin material or hydrocarbon liquid cannot be excluded from our data, but an additional unidentified component with a signature around 2.74 micron is required to satisfy the data.     

Soluble ferric iron as an effective protective agent against UV radiation: Implications for early life

Some recent MER Rover Opportunity results on ancient sedimentary rocks from Mars describe sandstones originated from the chemical weathering of olivine basalts by acidic waters [Squyres, S.W., Knoll, A.H., 2005. Earth Planet. Sci. Lett. 240, 1-10]. The absence of protective components in early Mars atmosphere forced any possible primordial life forms to deal with high doses of UV radiation. A similar situation occurred on the primitive Earth during the development of early life in the Archean [Berkner, L.V., Marshall, L.C., 1965. J. Atmos. Sci. 22 (3), 225-261; Kasting, J.F., 1993. Science 259, 920-926]. It is known that some cellular and/or external components can shield organisms from damaging UV radiation or quench its toxic effects [Olson, J.M., Pierson, B.K., 1986. Photosynth. Res. 9, 251-259; García-Pichel, F., 1998. Origins Life Evol. B 28, 321-347; Cockell, C., Rettberg, P., Horneck, G., Scherer, K., Stokes, M.D., 2003. Polar Biol. 26, 62-69]. The effectiveness of iron minerals for UV protection has also been reported [Phoenix, V.R., Konhauser, K.O., Adams, D.G., Bottrell, S.H., 2001. Geology 29 (9), 823-826], but nothing is known about the effect of iron in solution. Here we demonstrate the protective effect of soluble ferric iron against UV radiation on acidophilic photosynthetic microorganisms. These results offer an interesting alternative means of protection for life on the surface of early Mars and Earth, especially in light of the geochemical conditions in which the sedimentary minerals, jarosite and goethite, recently reported by the MER missions, were formed [Squyres, S.W., Arvidson, R.E., Bell III, J.F., Brückner, J., Cabrol, N.A., Calvin, W., Carr, M.H., Christensen, P.R., Clark, B.C., Crumpler, L., Des Marais, D.J., d'Uston, C., Economou, T., Farmer, J., Farrand, W., Folkner, W., Golombek, M., Gorevan, S., Grant, J.A., Greeley, R., Grotzinger, J., Haskin, L., Herkenhoff, K.E., Hviid, S., Johnson, J., Klingelhöfer, G., Knoll, A.H., Landis, G., Lemmon, M., Li, R., Madsen, M.B., Malin, M.C., McLennan, S.M., McSween, H.Y., Ming, D.W., Moersch, J., Morris, R.V., Parker, T., Rice Jr., J.W., Richter, L., Rieder, R., Sims, M., Smith, M., Smith, P., Soderblom, L.A., Sullivan, R., Wänke, H., Wdowiak, T., Wolff, M., Yen, A., 2004. Science 306, 1698-1703; Klingelhöfer, G., Morris, R.V., Bernhardt, B., Schröder, C., Rodionov, D.S., de Souza Jr., P.A., Yen, A., Gellert, R., Evlanov, E.N., Zubkov, B., Foh, J., Bonnes, U., Kankeleit, E., Gütlich, P., Ming, D.W., Renz, F., Wdowiak, T., Squyres, S.W., Arvidson, R.E., 2004. Science 306, 1740-1745].     

Methane on Uranus: The case for a compact CH4 cloud layer at low latitudes and a severe CH4 depletion at high-latitudes based on re-analysis of Voyager occultation measurements and STIS spectroscopy

Lindal et al. (Lindal, G.F., Lyons, J.R., Sweetnam, D.N., Eshleman, V.R., Hinson, D.P. [1987]. J. Geophys. Res. 92 (11), 14987-15001) presented a range of temperature and methane profiles for Uranus that were consistent with 1986 Voyager radio occultation measurements of refractivity versus altitude. A localized refractivity slope variation near 1.2 bars was interpreted to be the result of a condensed methane cloud layer. However, models fit to near-IR spectra found particle concentrations much deeper in the atmosphere, in the 1.5-3 bar range (Sromovsky, L.A., Irwin, P.G.J., Fry, P.M. [2006]. Icarus 182, 577-593; Sromovsky, L.A., Fry, P.M. [2010]. Icarus 210, 211-229; Irwin, P.G.J., Teanby, N.A., Davis, G.R. [2010]. Icarus 208, 913-926), and a recent analysis of STIS spectra argued for a model in which aerosol particles formed diffusely distributed hazes, with no compact condensation layer (Karkoschka, E., Tomasko, M. [2009]. Icarus 202, 287-309). To try to reconcile these results, we reanalyzed the occultation observations with the He volume mixing ratio reduced from 0.15 to 0.116, which is near the edge of the 0.033 uncertainty range given by Conrath et al. (Conrath, B., Hanel, R., Gautier, D., Marten, A., Lindal, G. [1987]. J. Geophys. Res. 92 (11), 15003-15010). This allowed us to obtain saturated mixing ratios within the putative cloud layer and to reach above-cloud and deep methane mixing ratios compatible with STIS spectral constraints. Using a 5-layer vertical aerosol model with two compact cloud layers in the 1-3 bar region, we find that the best fit pressure for the upper compact layer is virtually identical to the pressure range inferred from the occultation analysis for a methane mixing ratio near 4% at 5°S. This strongly argues that Uranus does indeed have a compact methane cloud layer. In addition, our cloud model can fit the latitudinal variations in spectra between 30°S and 20°N, using the same profiles of temperature and methane mixing ratio. But closer to the pole, the model fails to provide accurate fits without introducing an increasingly strong upper tropospheric depletion of methane at increased latitudes, in rough agreement with the trend identified by Karkoschka and Tomasko (Karkoschka, E., Tomasko, M. [2009]. Icarus 202, 287-309).     

Heat balance in Titan's atmosphere

The recent measurements of the vertical distribution and optical properties of haze aerosols as well as of the absorption coefficients for methane at long paths and cold temperatures by the Huygens entry probe of Titan permit the computation of the solar heating rate on Titan with greater certainty than heretofore. We use the haze model derived from the Descent Imager/Spectral Radiometer (DISR) instrument on the Huygens probe [Tomasko, M.G., Doose, L., Engel, S., Dafoe, L.E., West, R., Lemmon, M., Karkoschka, E., See, C., 2008a. A model of Titan's aerosols based on measurements made inside the atmosphere. Planet. Space Sci., this issue, doi:10.1016/j.pss.2007.11.019] to evaluate the variation in solar heating rate with altitude and solar zenith angle in Titan's atmosphere. We find the disk-averaged solar energy deposition profile to be in remarkably good agreement with earlier estimates using very different aerosol distributions and optical properties. We also evaluated the radiative cooling rate using measurements of the thermal emission spectrum by the Cassini Composite Infrared Spectrometer (CIRS) around the latitude of the Huygens site. The thermal flux was calculated as a function of altitude using temperature, gas, and haze profiles derived from Huygens and Cassini/CIRS data. We find that the cooling rate profile is in good agreement with the solar heating profile averaged over the planet if the haze structure is assumed the same at all latitudes. We also computed the solar energy deposition profile at the 10°S latitude of the probe-landing site averaged over one Titan day. We find that some 80% of the sunlight that strikes the top of the atmosphere at this latitude is absorbed in all, with 60% of the incident solar energy absorbed below 150 km, 40% below 80 km, and 11% at the surface at the time of the Huygens landing near the beginning of summer in the southern hemisphere. We compare the radiative cooling rate with the solar heating rate near the Huygens landing site averaging over all longitudes. At this location, we find that the solar heating rate exceeds the radiative cooling rate by a maximum of 0.5 K/Titan day near 120 km altitude and decreases strongly above and below this altitude. Since there is no evidence that the temperature structure at this latitude is changing, the general circulation must redistribute this heat to higher latitudes.     

The role of organic haze in Titan's atmospheric chemistry: II. Effect of heterogeneous reaction to the hydrogen budget and chemical composition of the atmosphere

One of the key components controlling the chemical composition and climatology of Titan's atmosphere is the removal of reactive atomic hydrogen from the atmosphere. A proposed process of the removal of atomic hydrogen is the heterogeneous reaction with organic aerosol. In this study, we investigate the effect of heterogeneous reactions in Titan's atmospheric chemistry using new measurements of the heterogeneous reaction rate [Sekine, Y., Imanaka, H., Matsui, T., Khare, B.N., Bakes, E.L.O., McKay, C.P., Sugita, S., 2008. Icarus 194, 186-200] in a one-dimensional photochemical model. Our results indicate that 60-75% of the atomic hydrogen in the stratosphere and mesosphere are consumed by the heterogeneous reactions. This result implies that the heterogeneous reactions on the aerosol surface may predominantly remove atomic hydrogen in Titan's stratosphere and mesosphere. The results of our calculation also indicate that a low concentration of atomic hydrogen enhances the concentrations of unsaturated complex organics, such as C₄H₂ and phenyl radical, by more than two orders in magnitude around 400 km in altitude. Such an increase in unsaturated species may induce efficient haze production in Titan's mesosphere and upper stratosphere. These results imply a positive feedback mechanism in haze production in Titan's atmosphere. The increase in haze production would affect the chemical composition of the atmosphere, which might induce further haze production. Such a positive feedback could tend to dampen the loss and supply cycles of CH₄ due to an episodic CH₄ release into Titan's atmosphere.     

Appearance of Saturn’s F ring azimuthal channels for the anti-alignment configuration between the ring and Prometheus

In this article we explore the aspect of the F ring with respect to the anti-alignment configuration between the ring and Prometheus. We focus our attention on the shape of the F ring’s azimuthal channels which were first reported by Porco et al. (Porco, C.C., Baker, E., Barbara, J., Beurle, K., Brahic, A., Burns, J.A., Charnoz, S., Cooper, N., Dawson, D.D., Del Genio, A.D., Denk, T., Dones, L., Dyudina, U., Evans, M.W., Giese, B., Grazier, K., Helfenstein, P., Ingersoll, A.P., Jacobson, R.A., Johnson, T.V., McEwen, A., Murray, C.D., Neukum, G., Owen, W.M., Perry, J., Roatsch, T., Spitale, J., Squyres, S., Thomas, P., Tiscareno, M., Turtle, E., Vasavada, A.R., Veverka, J., Wagner, R., West, R. [2005] Science, 307, 1226-1236) and numerically explored by Murray et al. (Murray, C.D., Chavez, C., Beurle, K., Cooper, N., Evans, M.W., Burns, J.A., Porco, C.C. [2005] Nature 437, 1326-1329) who found excellent agreement between Cassini’s ISS reprojected images and their numerical model via a direct comparison. We find that for anti-alignment the channels are wider and go deeper inside the ring material. From our numerical model we find a new feature, an island in the middle of the channel. This island is made up of the particles that have been perturbed the most by Prometheus and only appears when this satellite is close to apoapsis. In addition, plots of the anti-alignment configuration for different orbital stages of Prometheus are obtained and discussed here.     

Stratigraphical evidence of late Amazonian periglaciation and glaciation in the Astapus Colles region of Mars

Recent modeling of the meteorological conditions during and following times of high obliquity suggests that an icy mantle could have been emplaced in western Utopia Planitia by atmospheric deposition during the late Amazonian period [Costard, F.M., Forget, F., Madeleine, J.B., Soare, R.J., Kargel, J.S., 2008. Lunar Planet. Sci. 39. Abstract 1274; Madeleine, B., Forget, F., Head, J.W., Levrard, B., Montmessin, F., 2007. Lunar Planet. Sci. 38. Abstract 1778]. Astapus Colles (ABa) is a late Amazonian geological unit — located in this hypothesized area of accumulation — that comprises an icy mantle tens of meters thick [Tanaka, K.L., Skinner, J.A., Hare, T.M., 2005. US Geol. Surv. Sci. Invest., Map 2888]. For the most part, this unit drapes the early Amazonian Vastitas Borealis interior unit (ABv_i); to a lesser degree it overlies the early Amazonian Vastitas Borealis marginal unit (ABv_m) and the early to late Hesperian UP plains unit HBu₂ [Tanaka, K.L., Skinner, J.A., Hare, T.M., 2005. US Geol. Surv. Sci. Invest., Map 2888]. Landscapes possibly modified by late-Amazonian periglacial processes [Costard, F.M., Kargel, J.S., 1995. Icarus 114, 93-112; McBride, S.A., Allen, C.C., Bell, M.S., 2005. Lunar Planet. Sci. 36. Abstract 1090; Morgenstern, A., Hauber, E., Reiss, D., van Gasselt, S., Grosse, G., Schirrmeister, L., 2007. J. Geophys. Res. 112, doi:10.1029/2006JE002869. E06010; Seibert, N.M., Kargel, J.S., 2001. Geophys. Res. Lett. 28, 899-902; Soare, R.J., Kargel, J.S., Osinski, G.R., Costard, F., 2007. Icarus 191, 95-112; Soare, R.J., Osinski, G.R., Roehm, C.L., 2008. Earth Planet. Sci. Lett. 272, 382-393] and glacial processes [Milliken, R.E., Mustard, J.F., Goldsby, D.L., 2003. J. Geophys. Res. 108 (E6), doi:10.1029/2002JE002005. 5057; Mustard, J.F., Cooper, C.D., Rifkin, M.K., 2001. Nature 412, 411-414; Tanaka, K.L., Skinner, J.A., Hare, T.M., 2005. US Geol. Surv. Sci. Invest., Map 2888] have been reported within the region. Researchers have assumed that the periglacial and glacial landscapes occur within the same geological unit, the ABa [i.e., Morgenstern, A., Hauber, E., Reiss, D., van Gasselt, S., Grosse, G., Schirrmeister, L., 2007. J. Geophys. Res. 112; doi:10.1029/2006JE002869. E06010; Tanaka, K.L., Skinner, J.A., Hare, T.M., 2005. US Geol. Surv. Sci. Invest., Map 2888]. In this study we use HiRISE (High Resolution Image Science Experiment, Mars Reconnaissance Orbiter) imagery to identify the stratigraphical separation of the two landscapes and show that periglacial landscape modification has occurred in the geological units that underlie the ABa, not in the ABa itself. Moreover, we suggest that the periglacial landscape extends well beyond the perimeter of the ABa and could be the product of “wet” cold-climate processes. These processes involve freeze-thaw cycles and intermittently stable liquid-water at or near the surface. By contrast, we propose that the ABa is a very recent late-Amazonian geological unit formed principally by “dry” cold-climate processes. These processes comprise accumulation (by atmospheric deposition) and ablation (by sublimation).     

Moonlet induced wakes in planetary rings: Analytical model including eccentric orbits of moon and ring particles

Saturn’s rings host two known moons, Pan and Daphnis, which are massive enough to clear circumferential gaps in the ring around their orbits. Both moons create wake patterns at the gap edges by gravitational deflection of the ring material (Cuzzi, J.N., Scargle, J.D. [1985]. Astrophys. J. 292, 276-290; Showalter, M.R., Cuzzi, J.N., Marouf, E.A., Esposito, L.W. [1986]. Icarus 66, 297-323). New Cassini observations revealed that these wavy edges deviate from the sinusoidal waveform, which one would expect from a theory that assumes a circular orbit of the perturbing moon and neglects particle interactions. Resonant perturbations of the edges by moons outside the ring system, as well as an eccentric orbit of the embedded moon, may partly explain this behavior (Porco, C.C., and 34 colleagues [2005]. Science 307, 1226-1236; Tiscareno, M.S., Burns, J.A., Hedman, M.M., Spitale, J.N., Porco, C.C., Murray, C.D., and the Cassini Imaging team [2005]. Bull. Am. Astron. Soc. 37, 767; Weiss, J.W., Porco, C.C., Tiscareno, M.S., Burns, J.A., Dones, L. [2005]. Bull. Am. Astron. Soc. 37, 767; Weiss, J.W., Porco, C.C., Tiscareno, M.S. [2009]. Astron. J. 138, 272-286). Here we present an extended non-collisional streamline model which accounts for both effects. We describe the resulting variations of the density structure and the modification of the nonlinearity parameter q. Furthermore, an estimate is given for the applicability of the model. We use the streamwire model introduced by Stewart (Stewart, G.R. [1991]. Icarus 94, 436-450) to plot the perturbed ring density at the gap edges.We apply our model to the Keeler gap edges undulated by Daphnis and to a faint ringlet in the Encke gap close to the orbit of Pan. The modulations of the latter ringlet, induced by the perturbations of Pan (Burns, J.A., Hedman, M.M., Tiscareno, M.S., Nicholson, P.D., Streetman, B.J., Colwell, J.E., Showalter, M.R., Murray, C.D., Cuzzi, J.N., Porco, C.C., and the Cassini ISS team [2005]. Bull. Am. Astron. Soc. 37, 766), can be well described by our analytical model. Our analysis yields a Hill radius of Pan of 17.5 km, which is 9% smaller than the value presented by Porco (Porco, C.C., and 34 colleagues [2005]. Science 307, 1226-1236), but fits well to the radial semi-axis of Pan of 17.4 km. This supports the idea that Pan has filled its Hill sphere with accreted material (Porco, C.C., Thomas, P.C., Weiss, J.W., Richardson, D.C. [2007]. Science 318, 1602-1607). A numerical solution of a streamline is used to estimate the parameters of the Daphnis-Keeler gap system, since the close proximity of the gap edge to the moon induces strong perturbations, not allowing an application of the analytic streamline model. We obtain a Hill radius of 5.1 km for Daphnis, an inner edge variation of 8 km, and an eccentricity for Daphnis of 1.5 × 10⁻⁵. The latter two quantities deviate by a factor of two from values gained by direct observations (Jacobson, R.A., Spitale, J., Porco, C.C., Beurle, K., Cooper, N.J., Evans, M.W., Murray, C.D. [2008]. Astron. J. 135, 261-263; Tiscareno, M.S., Burns, J.A., Hedman, M.M., Spitale, J.N., Porco, C.C., Murray, C.D., and the Cassini Imaging team [2005]. Bull. Am. Astron. Soc. 37, 767), which might be attributed to the neglect of particle interactions and vertical motion in our model.     

Vertical cloud structure of Uranus from UKIRT/UIST observations and changes seen during Uranus’ northern spring equinox from 2006 to 2008

Long-slit spectroscopy observations of Uranus by the United Kingdom Infrared Telescope UIST instrument in 2006, 2007 and 2008 have been used to monitor the change in Uranus’ vertical and latitudinal cloud structure through the planet’s northern spring equinox in December 2007.The observed reflectance spectra in the Long J (1.17-1.31 μm) and H (1.45-1.65 μm) bands, obtained with the slit aligned along Uranus’ central meridian, have been fitted with an optimal estimation retrieval model to determine the vertical cloud profile from 0.1 to 6-8 bar over a wide range of latitudes. Context images in a number of spectral bands were used to discriminate general zonal cloud structural changes from passing discrete clouds. From 2006 to 2007 reflection from deep clouds at pressures between 2 and 6-8 bar increased at all latitudes, although there is some systematic uncertainty in the absolute pressure levels resulting from extrapolating the methane coefficients of Irwin et al. (Irwin, P.G.J., Sromovsky, L.A., Strong, E.K., Sihra, K., Teanby, N.A., Bowles, N., Calcutt, S.B., Remedios, J.J. [2006] Icarus, 181, 309-319) at pressures greater than 1 bar, as noted by Tomasko et al. and Karkoschka and Tomasko (Tomasko, M.G., Bezard, B., Doose, L., Engel, S., Karkoschka, E. [2008] Planet. Space Sci., 56, 624-647; Karkoschka, E., Tomasko, M. [2009] Icarus). However, from 2007 to 2008 reflection from these clouds throughout the southern hemisphere and from both northern and southern mid-latitudes (30° N,S) diminished. As a result, the southern polar collar at 45°S has diminished in brightness relative to mid-latitudes, a similar collar at 45°N has become more prominent (e.g. Rages, K.A., Hammel, H.B., Sromovsky, L. [2007] Bull. Am. Astron. Soc., 39, 425; Sromovsky, L.A., Fry, P.M., Ahue, W.M., Hammel, H.B., de Pater, I., Rages, K.A., Showalter, M.R., van Dam, M.A. [2008] vol. 40 of AAS/Division for Planetary Sciences Meeting Abstracts, pp. 488-489; Sromovsky, L.A., Ahue, W.K.M., Fry, P.M., Hammel, H.B., de Pater, I., Rages, K.A., Showalter, M.R. [2009] Icarus), and the lowering reflectivity from mid-latitudes has left a noticeable brighter cloud zone at the equator (e.g. Sromovsky, L.A., Fry, P.M. [2007] Icarus, 192, 527-557;Karkoschka, E., Tomasko, M. [2009] Icarus). For such substantial cloud changes to have occurred in just two years suggests that the circulation of Uranus’ atmosphere is much more vigorous and/or efficient than is commonly thought. The composition of the main observed cloud decks between 2 and 6-8 bar is unclear, but the absence of the expected methane cloud at 1.2-1.3 bar (Lindal, G.F., Lyons, J.R., Sweetnam, D.N., Eshleman, V.R., Hinson, D.P. [1987] J. Geophys. Res., 92, 14987-15001) is striking (as previously noted by, among others, Sromovsky, L.A., Irwin, P.G.J., Fry, P.M. [2006] Icarus, 182, 577-593; Sromovsky, L.A., Fry, P.M. [2007] Icarus, 192, 527-557; Sromovsky, L.A., Fry, P.M. [2008] Icarus, 193, 252-266; Karkoschka, E., Tomasko, M. [2009] Icarus) and suggests that cloud particles may be considerably different from pure condensates and may be linked with stratospheric haze particles drizzling down from above, or that tropospheric hazes are generated near the methane condensation level and then drizzle down to deep pressures as suggested by Karkoschka and Tomasko (Karkoschka, E., Tomasko, M. [2009] Icarus).The retrieved cloud structures were also tested for different assumptions of the deep methane mole fraction, which Karkoschka and Tomasko (Karkoschka, E., Tomasko, M. [2009] Icarus) find may vary from ∼1-2% in polar regions to perhaps as much as 4% equatorwards of 45°N,S. We found that such variations did not significantly affect our conclusions.     

The long-term stability of a possible aqueous ammonium sulfate ocean inside Titan

We model the thermal evolution of a subsurface ocean of aqueous ammonium sulfate inside Titan using a parameterized convection scheme. The cooling and crystallization of such an ocean depends on its heat flux balance, and is governed by the pressure-dependent melting temperatures at the top and bottom of the ocean. Using recent observations and previous experimental data, we present a nominal model which predicts the thickness of the ocean throughout the evolution of Titan; after 4.5 Ga we expect an aqueous ammonium sulfate ocean 56 km thick, overlain by a thick (176 km) heterogeneous crust of methane clathrate, ice I and ammonium sulfate. Underplating of the crust by ice I will give rise to compositional diapirs that are capable of rising through the crust and providing a mechanism for cryovolcanism at the surface. We have conducted a parameter space survey to account for possible variations in the nominal model, and find that for a wide range of plausible conditions, an ocean of aqueous ammonium sulfate can survive to the present day, which is consistent with the recent observations of Titan's spin state from Cassini radar data [Lorenz, R.D., Stiles, B.W., Kirk, R.L., Allison, M.D., del Marmo, P.P., Iess, L., Lunine, J.I., Ostro, S.J., Hensley, S., 2008. Science 319, 1649-1651].     

Some consequences of meteoroid impacts on Saturn's rings

High-velocity impacts of interplanetary meteoroids on Saturn's rings are discussed. It is shown that the neutral gas emitted by impact vaporization may be responsible, to a large part, for the observed neutral ring atmosphere. Both the predicted neutral gas injection rate and the gas temperature (or kinetic energy) are compatible with the measurements (see Broadfoot, A. L., B. R. Sandel, D. E. Shemansky, J. B. Holberg, G. R. Smith, D. F. Strobel, J. C. McConnell, S. Kumar, D. M. Hunten, S. K. Atreya, T. M. Dohnahne, H. W. Moos, J. L. Bertaux, J. E. Blamont, R. B. Pomphrey, and S. Linik, Science212, 206–211, 1981). Heavy ejecta particles produce a particulate ring “halo”. The physical properties of this halo are calculated, and it appears to be identical with the tenous particle population discussed by Baum and Kreidl (1982). Erosion of Saturn's ring particles, the resulting mass balance, and regolith formation are estimated. This provides some constraints on surface properties and optical albedo.     

Titan solar occultation observed by Cassini/VIMS: Gas absorption and constraints on aerosol composition

A solar occultation by Titan's atmosphere has been observed through the solar port of the Cassini/VIMS instrument on January 15th, 2006. Transmission spectra acquired during solar egress probe the atmosphere in the altitude range 70 to 900 km at the latitude of 71° S. Several molecular absorption bands of CH₄ and CO are visible in these data. A line-by-line radiative transfer calculation in spherical geometry is used to model three methane bands (1.7, 2.3, 3.3 μm) and the CO 4.7 μm band. Above 200 km, the methane 2.3 μm band is well fit with constant mixing ratio between 1.4 and 1.7%, in agreement with in situ and other Cassini measurements. Under 200 km, there are discrepancies between models and observations that are yet fully understood. Under 480 km, the 3.3 μm CH₄ band is mixed with a large and deep additional absorption. It corresponds to the C-H stretching mode of aliphatic hydrocarbon chains attached to large organic molecules. The CO 4.7 μm band is observed in the lower stratosphere (altitudes below 150 km) and is well fit with a model with constant mixing ratio of 33±10 ppm. The continuum level of the observed transmission spectra provides new constraints on the aerosol content of the atmosphere. A model using fractal aggregates and optical properties of tholins produced by Khare et al. [Khare, B.N., Sagan, C., Arakawa, E.T., Suits, F., Callcott, T.A., Williams, M.W., 1984. Icarus 60, 127-137] is developed. Fractal aggregates with more than 1000 spheres of radius 0.05 μm are needed to fit the data. Clear differences in the chemical composition are revealed between tholins and actual haze particles. Extinction and density profiles are also retrieved using an inversion of the continuum values. An exponential increase of the haze number density is observed under 420 km with a typical scale height of 60 km.     

Archaean asteroid impacts, banded iron formations and MIF-S anomalies: A discussion

The origin of mass-independent fractionation (MIF-S) of sulphur isotopes (δ³³S) recorded in sediments older than 2.45 Ga is widely interpreted in terms of UV-triggered reactions under oxygen-poor ozone-depleted atmosphere conditions (Farquhar, J., Bao, H., Thiemens, M. [2000] Science, 289, 756; Farquhar, J., Peters, M., Johnston, D.T., Strauss, H., Masterson, A., Wiechert, U., Kaufman, A.J. [2007] Nature, 449, 706-709; Farquhar, J., Wing, B.A. [2003] Earth Planet. Sci. Lett., 213, 1-13; Kaufman, A.J., Johnston, D.T., Farquhar, J., Masterson, A.L., Lyons, T.W., Bates, S., Anbar, A.D., Arnold, G.L., Garvin, J., Buick, R. [2007a] Science, 317, 1900-1903; Kaufman, A.J., Farquhar, J., Johnston, D.T., Lyons, T.W., Arnold, G.L., Anbar, A. [2007b] Deep Time Drilling Project of the NASA Astrobiology Drilling Program). Observed mid-Archaean variability of MIF-S signatures raises questions regarding the extent of atmospheric anoxia (Ohmoto, H., Watanabe, Y., Ikemi, H., Poulson, H.R., Taylor, B. [2006] Nature, 406, 908-991; Farquhar et al., 2007). Late Archaean (∼2.7-2.5 Ga) and mid-Archaean (∼3.2 Ga) sequences in the Pilbara Craton (Western Australia) and Kaapvaal Craton (South Africa), in which MIF-S data were measured, contain asteroid impact ejecta units dated as 2.48, 2.56, 2.63, 3.24, 3.26 and 3.47 Ga old (Lowe, D.R., Byerly, G.R., Kyte, T., Shukolyukov, A., Asaro, F., Krull, A. [2003] Astrobiology, 3, 7-48; Simonson, B.M., Hassler, S.W. [1997] Aust. J. Earth Sci., 44, 37-48; Simonson, B.M., Glass, B.P. [2004] Ann. Rev. Earth Planet. Sci., 32, 329-361; Glikson, A.Y. [2004] Astrobiology, 4, 19-50; Glikson, A.Y. [2006] Earth Planet. Sci. Lett., 246, 149-160; Glikson, A.Y. [2008] Earth Planet. Sci. Lett., 267, 558-570). Mass balance calculations based on iridium and ⁵³Cr/⁵²Cr isotopic anomalies (Byerly, G.R., Lowe, D.R. [1994] Geochim. Cosmochim. Acta, 58, 3469-3486; Kyte, F.T., Shukloyukov, A., Lugmair, G.W., Lowe, D.R., Byerly, G.R. [2003] Geology, 31, 283-286) and on impact spherule size distribution (Melosh, H.J., Vickery, A.M. [1991] Nature, 350, 494-497) suggest projectiles several tens of kilometers in diameter (Byerly and Lowe, 1994; Shukloyukov, A., Kyte, F.T., Lugmair, G.W., Lowe, D.R., Byerly, G.R. [2000]. In: Koeberl, C., Gilmour, I. (Eds.), Impacts and the Early Earth, Springer-Verlag, Berlin, pp. 99-116; Kyte, F.T., Shukloyukov, A., Lugmair, G.W., Lowe, D.R., Byerly, G.R. [2003] Geology, 31, 283-286). Due to incomplete preservation these impacts represent a minimum rate of the Archaean impact flux. High UV radiation associated with low ozone levels in the Archaean atmosphere may have been further enhanced by large impacts, accentuating MIF-S anomalies. The appearance of iron-rich sediments above late and mid-Archaean impact ejecta units (Glikson, A.Y. [2006] Earth Planet. Sci. Lett., 246, 149-160; Glikson, A.Y., Vickers, J. [2007] Earth Planet. Sci. Lett., 254, 214-226) may be related either to microbial oxidation of ferrous iron or, alternatively, photochemical oxidation of ferrous to ferric iron. Given post-2.45 Ga diluting of possible MIF-S anomalies by the oxygenating ocean sulfate reservoir (Pavlov, A.A., Kasting, J.F. [2002] Astrobiology, 2, 27-41), similar MIF-S anomalies may have been associated with Proterozoic and Phanerozoic impacts, although to date little evidence exists in this regard (Marouka, T., Koeberl, C., Newton, J., Gilmour, I., Bohor, B.F. [2002] Geological Society of America Special Paper 356, pp. 337-344; Koeberl, C., Thiemens, M. [2008] Multi-sulfur isotopes in cretaceous-tertiary boundary samples from the Western interior-search for photochemical effects 2008. Joint Meeting of the Geological Society of America, Soil Science Society of America, American Society of Agronomy, Crop Science Society of America, Gulf Coast Association of Geological Societies with the Gulf Coast Section of SEPM. <http://gsa.confex.com/gsa/2008AM/finalprogram/abstract_148134.htm> (abstract)). Detailed sampling and isotopic analyses across the impact ejecta fallout units are required in order to test possible relationships between Archaean impacts and MIF-S anomalies.     

Titan's corona: The contribution of exothermic chemistry

The contribution of exothermic ion and neutral chemistry to Titan's corona is studied. The production rates for fast neutrals N₂, CH₄, H, H₂, ³CH₂, CH₃, C₂H₄, C₂H₅, C₂H₆, N(⁴S), NH, and HCN are determined using a coupled ion and neutral model of Titan's upper atmosphere. After production, the formation of the suprathermal particles is modeled using a two-stream simulation, as they travel simultaneously through a thermal mixture of N₂, CH₄, and H₂. The resulting suprathermal fluxes, hot density profiles, and energy distributions are compared to the N₂ and CH₄ INMS exospheric data presented in [De La Haye, V., Waite Jr., J.H., Johnson, R.E., Yelle, R.V., Cravens, T.E., Luhmann, J.G., Kasprzak, W.T., Gell, D.A., Magee, B., Leblanc, F., Michael, M., Jurac, S., Robertson, I.P., 2007. J. Geophys. Res., doi:10.1029/2006JA012222, in press], and are found insufficient for producing the suprathermal populations measured. Global losses of nitrogen atoms and carbon atoms in all forms due to exothermic chemistry are estimated to be and .     

New Horizons Alice ultraviolet observations of a stellar occultation by Jupiter’s atmosphere

The Alice ultraviolet spectrograph onboard the New Horizons spacecraft observed two occultations of the bright star χ Ophiucus by Jupiter’s atmosphere on February 22 and 23, 2007 during the approach phase of the Jupiter flyby. The ingress occultation probed the atmosphere at 32°N latitude near the dawn terminator, while egress probed 18°N latitude near the dusk terminator. A detailed analysis of both the ingress and egress occultations, including the effects of molecular hydrogen, methane, acetylene, ethylene, and ethane absorptions in the far ultraviolet (FUV), constrains the eddy diffusion coefficient at the homopause level to be  cm² s⁻¹, consistent with Voyager measurements and other analyses (Festou, M.C., Atreya, S.K., Donahue, T.M., Sandel, B.R., Shemansky, D.E., Broadfoot, A.L. [1981]. J. Geophys. Res. 86, 5717-5725; Vervack Jr., R.J., Sandel, B.R., Gladstone, G.R., McConnell, J.C., Parkinson, C.D. [1995]. Icarus 114, 163-173; Yelle, R.V., Young, L.A., Vervack Jr., R.J., Young, R., Pfister, L., Sandel, B.R. [1996]. J. Geophys. Res. 101 (E1), 2149-2162). However, the actual derived pressure level of the methane homopause for both occultations differs from that derived by [Festou et al., 1981] and [Yelle et al., 1996] from the Voyager ultraviolet occultations, suggesting possible changes in the strength of atmospheric mixing with time. We find that at 32°N latitude, the methane concentration is  cm⁻³ at 70,397 km, the methane concentration is  cm⁻³ at 70,383 km, the acetylene concentration is  cm⁻³ at 70,364 km, and the ethane concentration is  cm⁻³ at 70,360 km. At 18°N latitude, the methane concentration is  cm⁻³ at 71,345 km, the methane concentration is  cm⁻³ at 71,332 km, the acetylene concentration is cm⁻³ at 71,318 km, and the ethane concentration is  cm⁻³ at 71,315 km. We also find that the H₂ occultation light curve is best reproduced if the atmosphere remains cold in the microbar region such that the base of the thermosphere is located at a lower pressure level than that determined by in situ instruments aboard the Galileo probe (Seiff, A., Kirk, D.B., Knight, T.C.D., Young, R.E., Mihalov, J.D., Young, L.A., Milos, F.S., Schubert, G., Blanchard, R.C., Atkinson, D. [1998]. J. Geophys. Res. 103 (E10), 22857-22889) - the Sieff et al. temperature profile leads to too much absorption from H₂ at high altitudes. However, this result is highly model dependent and non-unique. The observations and analysis help constrain photochemical models of Jupiter’s atmosphere.     

Enceladus: The likely dominant nitrogen source in Saturn's magnetosphere

The spatial distribution of N⁺ in Saturn's magnetosphere obtained from Cassini Plasma Spectrometer (CAPS) data can be used to determine the spatial distribution and relative importance of the nitrogen sources for Saturn's magnetosphere. We first summarize CAPS data from 15 orbits showing the spatial and energy distribution of the nitrogen component of the plasma. This analysis re-enforces our earlier discovery [Smith, H.T., Shappirio, M., Sittler, E.C., Reisenfeld, D., Johnson, R.E., Baragiola, R.A., Crary, F.J., McComas, D.J., Young, D.T., 2005. Geophys. Res. Lett. 32 (14). L14S03] that Enceladus is likely the dominant nitrogen source for Saturn's inner magnetosphere. We also find a sharp enhancement in the nitrogen ion to water ion ratio near the orbit of Enceladus which, we show, is consistent with the presence of a narrow Enceladus torus as described in [Johnson, R.E., Liu, M., Sittler Jr., E.C., 2005. Geophys. Res. Lett. 32. L24201]. The CAPS data and the model described below indicate that N⁺ ions are a significant fraction of the plasma in this narrow torus. We then simulated the combined Enceladus and Titan nitrogen sources using the CAPS data as a constraint. This simulation is an extension of the model we employed earlier to describe the neutral tori produced by the loss of nitrogen from Titan [Smith, H.T., Johnson, R.E., Shematovich, V.I., 2004. Geophys. Res. Lett. 31 (16). L16804]. We show that Enceladus is the principal nitrogen source in the inner magnetosphere but Titan might account for a fraction of the observed nitrogen ions at the largest distances discussed. We also show that the CAPS data is consistent with Enceladus being a molecular nitrogen source with a nitrogen to water ratio roughly consistent with INMS [Waite, J.H., and 13 colleagues, 2006. Science 311 (5766), 1419-1422], but out-gassing of other nitrogen-containing species, such as ammonia, cannot be ruled out.     

Venus upper atmospheric CO, temperature, and winds across the afternoon/evening terminator from June 2007 JCMT sub-millimeter line observations

The Venus mesosphere constitutes a highly variable transition region between the zonal rotation of the lower atmosphere and the diurnal circulation of the upper atmosphere. It further serves as the primary photochemical region of the Venus atmosphere. We obtained James Clerk Maxwell Telescope (JCMT, Mauna Kea Hawaii) sub-millimeter line observations of mesospheric ¹²CO and ¹³CO during coordinated space (MESSENGER and Venus Express) and ground-based observations of Venus in June of 2007. Such CO spectra line measurements support temperature, CO mixing ratio, and wind retrievals over the 80-110 km altitude range, encompassing the upper mesosphere and lower thermosphere of Venus. Five-point beam integrations were obtained across the observed Venus disk, allowing distinction of afternoon (noon to 6 p.m.) versus evening (6 p.m. to midnight) local times and northern (0-60N) versus southern (0-60S) latitudes. Distinctive diurnal variations (noon to midnight) are retrieved for both temperatures above 95 km and CO mixing ratios above 85 km altitudes. Separate CO line maps obtained on (UT) June 2, 3, 6, and 11 indicate moderate daily variability in afternoon and evening CO mixing ratios (20-50%) and temperatures (5-10 K). Average Venus mesospheric temperatures over this period were 10 K warmer than returned from 1978 to 1979 Pioneer Venus or 2000-01 sub-millimeter measurements, without evidence for the very large temperature inversions indicated by Venus Express SPICAV measurements at 90-100 km altitudes (Bertaux, J.L., Vandaele, A.-C., Korablev, O., Villard, E., Fedorova, A., Fussen, D., Quémerais, E., Belyaev, D., Mahieux, A., Montmessin, F., Muller, C., Neefs, E., Nevejans, D., Wilquet, V., Dubois, J.P. Hauchecorne, A., Stepanov, A., Vinogradov, I., Rodin, A., Bertaux, J.-L., Nevejans, D., Korablev, O., Montmessin, F., Vandaele, A.-C., Fedorova, A., Cabane, M., Chassefière, E., Chaufray, J.Y., Dimarellis, E., Dubois, J.P., Hauchecorne, A., Leblanc, F., Lefèvre, F., Rannou, P., Quémerais, E., Villard, E., Fussen, D., Muller, C., Neefs, E., Van Ransbeeck, E., Wilquet, V., Rodin, A., Stepanov, A., Vinogradov, I., Zasova, L., Forget, F., Lebonnois, S., Titov, D., Rafkin, S., Durry, G., Gérard, J.C., Sandel, B., 2007. A warm layer in Venus’ cryosphere and high-altitude measurements of HF, HCl, H₂O and HDO. Nature 450, 646-649). Measured Doppler shifts associated with June 2 and 11 ¹²CO line center absorptions indicate nearly supersonic (200 m/s, Mach 1) afternoon-to-evening (retrograde) circulation; composed of additive subsolar-to-antisolar (SSAS) and zonal retrograde wind components, which are not separable due to the particular observational geometry.     

The ultraviolet reflectance of Enceladus: Implications for surface composition

The reflectance of Saturn’s moon Enceladus has been measured at far ultraviolet (FUV) wavelengths (115-190 nm) by Cassini’s Ultraviolet Imaging Spectrograph (UVIS). At visible and near infrared (VNIR) wavelengths Enceladus’ reflectance spectrum is very bright, consistent with a surface composed primarily of H₂O ice. At FUV wavelengths, however, Enceladus is surprisingly dark - darker than would be expected for pure water ice. Previous analyses have focused on the VNIR spectrum, comparing it to pure water ice (Cruikshank, D.P., Owen, T.C., Dalle Ore, C., Geballe, T.R., Roush, T.L., de Bergh, C., Sandford, S.A., Poulet, F., Benedix, G.K., Emery, J.P. [2005] Icarus, 175, 268-283) or pure water ice plus a small amount of NH₃ (Emery, J.P., Burr, D.M., Cruikshank, D.P., Brown, R.H., Dalton, J.B. [2005] Astron. Astrophys., 435, 353-362) or NH₃ hydrate (Verbiscer, A.J., Peterson, D.E., Skrutskie, M.F., Cushing, M., Helfenstein, P., Nelson, M.J., Smith, J.D., Wilson, J.C. [2006] Icarus, 182, 211-223). We compare Enceladus’ FUV spectrum to existing laboratory measurements of the reflectance spectra of candidate species, and to spectral models. We find that the low FUV reflectance of Enceladus can be explained by the presence of a small amount of NH₃ and a small amount of a tholin in addition to H₂O ice on the surface. The presence of these three species (H₂O, NH₃, and a tholin) appears to satisfy not only the low FUV reflectance and spectral shape, but also the middle-ultraviolet to visible wavelength brightness and spectral shape. We expect that ammonia in the Enceladus plume is transported across the surface to provide a global coating.