Deep Impact photometry of Comet 9P/Tempel 1

The photometric properties of the nucleus of Comet 9P/Tempel 1 are studied from the disk-resolved color images obtained by Deep Impact (DI). Comet Tempel 1 has typical photometric properties for comets and dark asteroids. The disk-integrated spectrum of the nucleus of Tempel 1 between 309 and 950 nm is linear without any features at the spectral resolution of the filtered images. At V-band, the red slope of the nucleus is 12.5±1% per 100 nm at 63° phase angle, translating to B-V=0.84±0.01, V-R=0.50±0.01, and R-I=0.49±0.02. No phase reddening is confirmed. The phase function of the nucleus of Tempel 1 is constructed from DI images and earlier ground-based observations found from the literature. The phase coefficient is determined to be β=0.046±0.007 mag/deg between 4° and 117° phase angle. Hapke's theoretical scattering model was used to model the photometric properties of this comet. Assuming a single Henyey-Greenstein function for the single-particle phase function, the asymmetry factor of Tempel 1 was fitted to be g=−0.49±0.02, and the corresponding single-scattering albedo (SSA) was modeled to be 0.039±0.005 at 550 nm wavelength. The SSA spectrum shows a similar linear slope to that of the disk-integrated spectrum. The roughness parameter is found to be 16°±8°, and independent of wavelength. The Minnaert k parameter is modeled to be 0.680±0.014. The photometric variations on Tempel 1 are relatively small compared to other comets and asteroids, with a ∼20% full width at half maximum of albedo variation histogram, and ∼3% for color. Roughness variations are evident in one small area, with a roughness parameter about twice the average and appearing to correlate with the complex morphological texture seen in high-resolution images.     

Near-infrared light curve of Comet 9P/Tempel 1 during Deep Impact

On UT 2005 July 4 we observed Comet 9P/Tempel 1 during its encounter with the Deep Impact flyby spacecraft and impactor. Using the SpeX near-infrared spectrograph mounted on NASA's Infrared Telescope Facility, we obtained 0.8-to-2.5 μm flux-calibrated spectral light curves of the comet for 12 min before and 14 min after impact. Our cadence was just 1.1 s. The light curve shows constant flux before the impact and an overall brightening trend after the impact, but not at a constant rate. Within a 0.8-arcsec-radius circular aperture, the comet rapidly-brightened by 0.63 mag at 1.2 μm in the first minute. Thereafter, brightening was more modest, averaging about 0.091 mag/min at 1.2 μm, although apparently not quite constant. In addition we see a bluing in the spectrum over the post-impact period of about 0.07 mag in J-H and 0.35 mag in J-K. The majority of this bluing happened in the first minute, and the dust only marginally blued after that, in stark contrast to the continued brightening. The photometric behavior in the light curve is due to a combination of crater formation effects, expansion of the ejecta cloud, and evolution of liberated dust grains. The bluing is likely due to an icy component on those grains, and the icy grains would have had to have a devolatilization timescale longer than 14 min (unless they were shielded by the optical depth of the cloud). The bluing could also have been caused by the decrease in the “typical” size of the dust grains after impact. Ejecta dominated by submicron grains, as inferred from other observations, would have stronger scattering at shorter wavelengths than the much larger grains observed before impact.     

Spectropolarimetry of the Deep Impact target Comet 9P/Tempel 1 with HiVIS

High resolution spectropolarimetry of the Deep Impact target, Comet 9P/Tempel 1, was performed during the impact event on July 4th, 2005 with the HiVIS spectropolarimeter and the AEOS 3.67-m telescope on Haleakala, Maui. We observed atypical polarization spectra that changed significantly in the few hours after the impact. The polarization of scattered light as a function of wavelength is very sensitive to the size and composition (complex refractive index) of the scattering particles as well as the scattering geometry. As opposed to most observations of cometary dust, which show an increase in the linear polarization with the wavelength (at least in the visible domain and for phase angles greater than about 30, a red polarization spectrum) observations of 9P/Tempel 1 at a phase angle of 41° beginning 8 min after impact and centered at 6:30 UT showed a polarization of 4% at 650 nm falling to 3% at 950 nm. The next observation, centered an hour later showed a polarization of 7% at 650 nm falling to 2% at 950 nm. This corresponds to a spectropolarimetric gradient, or slope, of −0.9% per 1000 Å 40 min after impact, decreasing to a slope of −2.3% per 1000 Å an hour and a half after impact. This is an atypical blue polarization slope, which became more blue 1 h after impact. The polarization values of 4 and 7% at 650 nm are typical for comets at this scattering angle, whereas the low polarization of 2 and 3% at 950 nm is not. We compare observations of Comet 9P/Tempel 1 to that of a typical comet, C/2004 Machholz, at a phase angle of 30° which showed a typical red slope, rising from 2% at 650 nm to 3% at 950 nm in two different observations (+1.0 and +0.9% per 1000 Å).     

Radio observations of Comet 9P/Tempel 1 before and after Deep Impact

Comet 9P/Tempel 1 was the target of a multi-wavelength worldwide investigation in 2005. The NASA Deep Impact mission reached the comet on 4.24 July 2005, delivering a 370-kg impactor which hit the comet at 10.3 km s⁻¹. Following this impact, a cloud of gas and dust was excavated from the comet nucleus. The comet was observed in 2005 prior to and after the impact, at 18-cm wavelength with the Nançay radio telescope, in the millimeter range with the IRAM and CSO radio telescopes, and at 557 GHz with the Odin satellite. OH observations at Nançay provided a 4-month monitoring of the outgassing of the comet from March to June, followed by the observation of H₂O with Odin from June to August 2005. The peak of outgassing was found to be around between May and July. Observations conducted with the IRAM 30-m radio telescope in May and July 2005 resulted in detections of HCN, CH₃OH and H₂S with classical abundances relative to water (0.12, 2.7 and 0.5%, respectively). In addition, a variation of the HCN production rate with a period of 1.73±0.10 days was observed in May 2005, consistent with the 1.7-day rotation period of the nucleus. The phase of these variations, as well as those of CN seen in July by Jehin et al. [Jehin, E., Manfroid, J., Hutsemékers, D., Cochran, A.L., Arpigny, C., Jackson, W.M., Rauer, H., Schulz, R., Zucconi, J.-M., 2006. Astrophys. J. 641, L145-L148], is consistent with a rotation period of the nucleus of 1.715 days and a strong variation of the outgassing activity by a factor 3 from minimum to maximum. This also implies that the impact took place on the rising phase of the “natural” outgassing which reached its maximum ≈4 h after the impact. Post-impact observations at IRAM and CSO did not reveal a significant change of the outgassing rates and relative abundances, with the exception of CH₃OH which may have been more abundant by up to one order of magnitude in the ejecta. Most other variations are linked to the intrinsic variability of the comet. The Odin satellite monitored nearly continuously the H₂O line at 557 GHz during the 38 h following the impact on the 4th of July, in addition to weekly monitoring. Once the periodic variations related to the nucleus rotation are removed, a small increase of outgassing related to the impact is present, which corresponds to the release of ≈5000±2000 tons of water. Two other bursts of activity, also observed at other wavelengths, were seen on 23 June and 7 July; they correspond to even larger releases of gas.     

R-band light curve of Comet 9P/Tempel 1 during the Deep Impact event

We present high-speed CCD photometry of Comet 9P/Tempel 1 during the Deep Impact event on 2005 July 4 UT. Approximately 2 h and 50 min of R-band data were acquired at Mount Laguna Observatory with a temporal resolution of 5.5 s. The flux increased by 9% in the first minute after impact. This was followed by a more gradual two-part linear rise, with a change in slope at 9.2 min post-impact, at which time the rate of brightening increased from ∼ to ∼. An analysis of the light curve obtained with the guide camera on the United Kingdom Infrared Telescope and yields very similar results. These findings are mildly in disagreement with the 3-part linear rise found by Fernández et al. (2007) in that we do not find any evidence for a change at 4 min post-impact. We interpret the linear rise phase as due to solar illumination of the edge of an expanding optically thick dust ejecta plume. After approximately 20 min, the light curves begin to flatten out, perhaps coincident with the start of the transition to becoming optically thin. In the large apertures (>10^″) the light curve continues to gradually rise until the end of the observations. In smaller apertures, the light curves reach a peak at approximately 50 min, then decrease back towards the pre-impact flux level. The drop in flux in the smaller apertures may be caused by the ejecta expanding beyond the edge of the photometric aperture, and if so, we can use this timescale to infer an expansion velocity of ∼, consistent with previous published estimates.     

The gas production of Comet 9P/Tempel 1 around the Deep Impact date

The target of the Deep Impact space mission (NASA), Comet 9P/Tempel 1, was observed from two nights before impact to eight nights after impact using the FORS spectrographs at the ESO VLT UT1 and UT2 telescopes. Low resolution optical long-slit spectra were obtained to study the evolution of the gas coma around the Deep Impact event. Following first results of this observing campaign on the CN and dust activity [Rauer, H., Weiler, M., Sterken, C., Jehin, E., Knollenberg, J., Hainaut, O., 2006. Astron. Astrophys. 459, 257-263], this work presents a study of the complete dataset on CN, C₂, C₃, and NH₂ activity of Comet 9P/Tempel 1. An extended impact gas cloud was observed moving radially outwards. No compositional differences between this impact cloud and the undisturbed coma were found as far as the observed radicals are concerned. The gas production rates before and well after impact indicate no change in the cometary activity on an intermediate time scale. Over the observing period, the activity of Comet 9P/Tempel 1 was found to be related to the rotation of the cometary nucleus. The rotational lightcurve for different gaseous species provides indications for compositional differences among different parts of the nucleus surface.     

Imaging polarimetry of the dust coma of Comet Tempel 1 before and after Deep Impact at Haute-Provence Observatory

We have observed the coma of Comet 9P/Tempel 1, the target of the Deep Impact mission, by the polarization imaging technique, before and after the impact event (−32, −7, +43 and +65 h). Our observations were conducted in the red wavelength domain from Haute-Provence Observatory (France), with the 80-cm telescope. The overall polarization of 9P/Tempel 1, as obtained near 41° phase angle, is monitored and compared to data from other (active and less active) comets studied by the same technique. The linear polarization of the dust ejected by the impact is compared to previous observations of dust present in jets, ejected during outbursts or released when comets happen to split. At phase angles of about 41°, the difference in polarization between the comets with a low maximum in polarization and the comets with a high maximum in polarization is about 1%; it may thus be difficult to conclude about the classification. Nevertheless, the overall polarization after the impact rapidly reached a value corresponding to the high polarization class of comets, and later progressively decreased to its initial value. The polarization was measured to be slightly lower (about 1%) before the impact than after it in a 26,000-km aperture. The plume formed from dust ejected by the impact was still present 65 h after it. The variations of the intensity and the polarization in the coma provide some clues to variations of the physical properties of the particles; comparison with other techniques corroborates the presence of large particles and of submicron-sized grains in aggregates.     

Swift ultraviolet photometry of the Deep Impact encounter with Comet 9P/Tempel 1

We report time-resolved imaging UV photometry of Comet 9P/Tempel 1 during the interval 2005 June 29-2005 July 21, including intensive coverage of the collision with the Deep Impact probe and its immediate aftermath. The nuclear flux of the comet begins to rise within minutes of the collision, and peaks about 3 h after impact. There is no evidence for a prompt flash at the time of impact. The comet exhibits a significant re-brightening about 40 h after the initial outburst, consistent with the rotation period of the comet, with evidence for further periodic re-brightenings on subsequent rotations. Modelling of the brightness profile of the coma as a function of time suggests two distinct velocity systems in the ejecta, at de-projected expansion speeds of 190 and 550 m/s, which we suggest are due to dust and gas, respectively. There is a distinct asymmetry in the slower-moving (dust) component as a function of position angle on the sky. This is confirmed by direct imaging analysis, which reveals an expanding plume of material concentrated in the impact hemisphere. The projected expansion velocity of the leading edge of this plume, measured directly from the imaging data, is 190 m/s, consistent with the velocity of the dust component determined from the photometric analysis. From our data we determine that a total of (1.4±0.2)×¹⁰³² water molecules were ejected in the impact, together with a total scattering area of dust at 300 nm of 190±20 km².     

Dust coma morphology in the Deep Impact images of Comet 9P/Tempel 1

We present an overview of the dust coma observations of Comet Tempel 1 that were obtained during the approach and encounter phases of the Deep Impact mission. We use these observations to set constraints on the pre-impact activity of the comet and discuss some preliminary results. The temporal and spatial changes that were observed during approach reveal three distinct jets rotating with a 1.7-day periodicity. The brightest jet produces an arcuate feature that expands outward with a projected velocity of about 12 m s⁻¹, suggesting that the ambient dust coma is dominated by millimeter-sized dust grains. As the spatial resolution improves, more jets and fans are revealed. We use stereo pairs of high-resolution images to put some crude constraints on the source locations of some of the brightest features. We also present a number of interesting coma features that were observed, including surface jets detected at the limb of the nucleus when the exposed ice patches are passing over the horizon, and features that appear to be jets emanating from unilluminated sources near the negative pole. We also provide a list of 10 outbursts of various sizes that were observed in the near-continuous monitoring during the approach phase.     

Submillimeter Wave Astronomy Satellite observations of Comet 9P/Tempel 1 and Deep Impact

On 4 July 2005 at 5:52 UT the Deep Impact mission successfully completed its goal to hit the nucleus of 9P/Tempel 1 with an impactor, forming a crater on the nucleus and ejecting material into the coma of the comet. NASA's Submillimeter Wave Astronomy Satellite (SWAS) observed the ₁₁₀-₁₀₁ ortho-water ground-state rotational transition in Comet 9P/Tempel 1 before, during, and after the impact. No excess emission from the impact was detected by SWAS and we derive an upper limit of 1.8×¹⁰⁷ kg on the water ice evaporated by the impact. However, the water production rate of the comet showed large natural variations of more than a factor of three during the weeks before and after the impact. Episodes of increased activity with alternated with periods with low outgassing (). We estimate that 9P/Tempel 1 vaporized a total of N∼4.5×¹⁰³⁴ water molecules (∼1.3×¹⁰⁹ kg) during June-September 2005. Our observations indicate that only a small fraction of the nucleus of Tempel 1 appears to be covered with active areas. Water vapor is expected to emanate predominantly from topographic features periodically facing the Sun as the comet rotates. We calculate that appreciable asymmetries of these features could lead to a spin-down or spin-up of the nucleus at observable rates.     

Observations of Comet 9P/Tempel 1 with the Keck 1 HIRES instrument during Deep Impact

We report high-spectral resolution observations of Comet 9P/Tempel 1 before, during and after the impact on 4 July 2005 UT of the Deep Impact spacecraft with the comet. These observations were obtained with the HIRES instrument on Keck 1. We observed brightening of both the dust and gas, but at different rates. We report the behavior of OH, NH, CN, C₃, CH, NH₂ and C₂ gas. From our observations, we determined a CN outflow velocity of at least 0.51 km s⁻¹. The dust color did not change substantially. To date, we see no new species in our spectra, nor do we see any evidence of prompt emission. From our observations, the interior material released by the impact looks the same as the material released from the surface by ambient cometary activity. However, further processing of the data may uncover subtle differences in the material that is released as well as the time evolution of this material.     

Chandra observations of Comet 9P/Tempel 1 during the Deep Impact campaign

We present results from the Chandra X-ray Observatory's extensive campaign studying Comet 9P/Tempel 1 (T1) in support of NASA's Deep Impact (DI) mission. T1 was observed for ∼295 ks between 30th June and 24th July 2005, and continuously for ∼64 ks on July 4th during the impact event. X-ray emission qualitatively similar to that observed for the collisionally thin Comet 2P/Encke system [Lisse, C.M., Christian, D.J., Dennerl, K., Wolk, S.J., Bodewits, D., Hoekstra, R., Combi, M.R., Mäkinen, T., Dryer, M., Fry, C.D., Weaver, H., 2005b. Astrophys. J. 635 (2005) 1329-1347] was found, with emission morphology centered on the nucleus and emission lines due to C, N, O, and Ne solar wind minor ions. The comet was relatively faint on July 4th, and the total increase in X-ray flux due to the Deep Impact event was small, ∼20% of the immediate pre-impact value, consistent with estimates that the total coma neutral gas release due to the impact was 5×¹⁰⁶ kg (∼10 h of normal emission). No obvious prompt X-ray flash due to the impact was seen. Extension of the emission in the direction of outflow of the ejecta was observed, suggesting the presence of continued outgassing of this material. Variable spectral features due to changing solar wind flux densities and charge states were clearly seen. Two peaks, much stronger than the man-made increase due to Deep Impact, were found in the observed X-rays on June 30th and July 8th, 2005, and are coincident with increases in the solar wind flux arriving at the comet. Modeling of the Chandra data using observed gas production rates and ACE solar wind ion fluxes with a CXE mechanism for the emission is consistent, overall, with the temporal and spectral behavior expected for a slow, hot wind typical of low latitude emission from the solar corona interacting with the comet's neutral coma, with intermittent impulsive events due to solar flares and coronal mass ejections.     

Visible and near-infrared spectrophotometry of the Deep Impact ejecta of Comet 9P/Tempel 1

We have obtained optical spectrophotometry of the evolution of Comet 9P/Tempel 1 after the impact of the Deep Impact probe, using the Supernova Integral Field Spectrograph (SNIFS) at the UH 2.2-m telescope, as well as simultaneous optical and infrared spectra using the Lick Visible-to-Near-Infrared Imaging Spectrograph (VNIRIS). The spatial distribution and temporal evolution of the “violet band” CN (0-0) emission and of the 630 nm [OI] emission was studied. We found that CN emission centered on the nucleus increased in the 2 h after impact, but that this CN emission was delayed compared to the light curve of dust-scattered sunlight. The CN emission also expanded faster than the cloud of scattering dust. The emission of [OI] at 630 nm rose similarly to the scattered light, but then remained nearly constant for several hours after impact. On the day following the impact, both CN and [OI] emission concentrated on the comet nucleus had returned nearly to pre-impact levels. We have also searched for differences in the scattering properties of the dust ejected by the impact compared to the dust released under normal conditions. Compared to the pre-impact state of the comet, we find evidence that the color of the comet was slightly bluer during the post-impact rise in brightness. Long after the impact, in the following nights, the comet colors returned to their pre-impact values. This can be explained by postulating a change to a smaller particle size distribution in the ejecta cloud, in agreement with the findings from mid-infrared observations, or by postulating a large fraction of clean ice particles, or by a combination of these two.     

Hubble Space Telescope observations of Comet 9P/Tempel 1 during the Deep Impact encounter

We report on the Hubble Space Telescope program to observe periodic Comet 9P/Tempel 1 in conjunction with NASA's Deep Impact Mission. Our objectives were to study the generation and evolution of the coma resulting from the impact and to obtain wide-band images of the visual outburst generated by the impact. Two observing campaigns utilizing a total of 17 HST orbits were carried out: the first occurred on 2005 June 13-14 and fortuitously recorded the appearance of a new, short-lived fan in the sunward direction on June 14. The principal campaign began two days before impact and was followed by contiguous orbits through impact plus several hours and then snapshots one, seven, and twelve days later. All of the observations were made using the Advanced Camera for Surveys (ACS). For imaging, the ACS High Resolution Channel (HRC) provides a spatial resolution of 36 km (16 km pixel⁻¹) at the comet at the time of impact. Baseline images of the comet, made prior to impact, photometrically resolved the comet's nucleus. The derived diameter, 6.1 km, is in excellent agreement with the 6.0±0.2 km diameter derived from the spacecraft imagers. Following the impact, the HRC images illustrate the temporal and spatial evolution of the ejecta cloud and allow for a determination of its expansion velocity distribution. One day after impact the ejecta cloud had passed out of the field-of-view of the HRC.     

Imaging polarimetry of Comet 9P/Tempel before and after the Deep Impact

The NASA's Deep Impact mission was the first impact experiment to a cometary nucleus. The target of the mission was Comet 9P/Tempel, one of the Jupiter family comets. The impact was performed on July 4th, 2005. Imaging polarimetric observations were carried out by Polarimetric Imager for COmets (PICO) mounted on the Lulin One-meter Telescope (LOT) at Lulin Observatory, Taiwan. Intensity and linear polarization degree maps were obtained on July 3-5, 2005. Impact ejecta plume was clearly recognized in the enhanced intensity map. Furthermore, arc-shaped region of high polarization was recognized in the polarization map. Dust grains in this region had larger expansion velocity than the grains which provided the brightest area in the intensity map. comparing our results with the MIR spectroscopy obtained by Subaru Telescope we conclude that very small carbonaceous grains might be responsible for the region of high polarization.     

Searching for the Deep Impact crater on Comet 9P/Tempel 1 using image processing techniques

In this work we attempt to obtain direct images of the crater associated with the impact of the Deep Impact impactor spacecraft on the nucleus of Comet 9P/Tempel 1 on July 4, 2005. The impact generated a large and bright ejecta cloud that hampers the clear view of the post-impact nucleus surface. We used image restoration techniques to enhance spatial resolution and contrast on a subset of selected post-impact high resolution images. No unambiguous evidence for the crater can be found; however, indirect evidence is consistent with a crater size in the 150-200 m range.     

Ground-based visible and near-IR observations of Comet 9P/Tempel 1 during the Deep Impact encounter

We present the results of our visible and near-IR observations of Comet 9P/Tempel 1 during the Deep Impact encounter. The comet was observed before, during, and after impact from Kitt Peak National Observatory (J, H, K) and Observatorio Astronómico Nacional-San Pedro Mártir, Mexico (B, V, R, I). High time-resolution images in R, J, H, and K the night of impact with a 3^.″5 radius aperture revealed a rapid brightening which had multiple slopes and lasted for approximately 25 min before leveling off. The brightness decreased on subsequent nights and returned to near pre-impact levels by July 8 UT. The R-J, R-H, R-K, J-H, J-K, and H-K colors became bluer the night of impact. The R-J, R-H, and R-K colors remained blue on the night after impact while the J-H, J-K, and H-K colors returned to baseline levels. The observed color changes suggest the bluening was due to an increase in small grains relative to the ambient coma, an increase in ice relative to refractory dust in the coma, or a combination of the two. The ejecta were initially directed towards the southwest but had been driven southeast by solar radiation pressure by the second night after impact. The mean projected ejecta velocity was estimated at 0.20-0.23 km s⁻¹ over the first 24 h after impact.     

Ultraviolet spectroscopy of Comet 9P/Tempel 1 with Alice/Rosetta during the Deep Impact encounter

We report on spectroscopic observations of periodic Comet 9P/Tempel 1 by the Alice ultraviolet spectrograph on the Rosetta spacecraft in conjunction with NASA's Deep Impact mission. Our objectives were to measure an increase in atomic and molecular emissions produced by the excavation of volatile sub-surface material. We unambiguously detected atomic oxygen emission from the quiescent coma but no enhancement at the 10% (1-σ) level following the impact. We derive a quiescent H₂O production rate of 9×¹⁰²⁷ molecules s⁻¹ with an estimated uncertainty of ∼30%. Our upper limits to the volatiles produced by the impact are consistent with other estimates.     

Physical properties of morphological units on Comet 9P/Tempel 1 derived from near-IR Deep Impact spectra

In this paper we analyze near-infrared thermal emission spectra of the spatially resolved nucleus of Comet 9P/Tempel 1 obtained by the NASA spacecraft Deep Impact. Maps of spectral reddening, the product X^′ between the beaming function and directional emissivity, as well as surface temperature are constructed. Thermophysical modeling is used to estimate the degree of small scale surface roughness and thermal inertia by detailed reproduction of the empirical temperature map. Mie and Hapke theories are used in combination with numerically calculated beaming functions to analyze the X^′ map and place constraints on composition and grain size of the surface material. We show that it is absolutely mandatory to include small scale surface roughness in thermophysical modeling of this object, since the resulting self heating is vital for reproducing the measured temperatures. A small scale self heating parameter in the range 0.6?ξ?0.75 is common, but smoother areas where 0.2?ξ?0.3 are also found. Contrary to models neglecting small scale surface roughness, we find that the thermal inertia of Comet 9P/Tempel 1 generally is high (1000-3000 J m⁻² K⁻¹ s^−1/2), although it may be substantially lower (40-380 J m⁻² K⁻¹ s^−1/2) in specific areas. We obtain a disk-averaged reddening of 3.5% kÅ⁻¹, with statistically significant local variations around that value on a ±1.0% kÅ−1 level. Vast regions appear covered by small (∼0.1 μm) highly absorbing grains such as carbon or iron-rich silicates. Other regions appear dominated by somewhat larger (∼0.5 μm) and/or less absorbing grains such as troilite or magnesium-rich silicates. Surface variations in reddening, roughness, thermal inertia, composition and/or grain size are moderately to strongly correlated to the locations of morphological units on the surface. The existence of morphological units with differing physical properties may be primordial, hence reflecting a diversity in the building block cometesimals, or resulting from evolutionary processes.